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By R. S. Bowman, G. S. Austin, J. M. Barker, P. S. Freeman

The physical, chemical and mineralogic characteristics of zeolites allow commercially important applications. While adoption of zeolite technology is slow in the United States compared to other regions of the world, continued testing and research has shown a wide range of uses for these minerals. They are important catalysts in petroleum refining, molecular sieves able to separate gases, and chemically inert carriers of reactants. The zeolite clinoptilolite produced by St. Cloud Mining Company (clino) (SC) is used in animal hygiene and animal feed, especially concentrated animal feeding operations (CAFOs), horticulture, water treatment, floor dry, aquariums, air and other filters, and odour control. Clino can remove cations from solution, and surface-modified zeolite (SMZ) is a sorbent for the removal of anions and neutral organics from water. Specific clino applications are: control of chemical pollution in groundwater, removal of organic compounds from oil field waters, and elimination of pathogens from sewage effluent. Combining the sorption capabilities of SMZ with chemical or biological transformations can yield complete removal of toxic materials from contaminated water. Continued development and marketing of zeolite products will be a growth market far into the future. The CAFO market for zeolites is the most significant growth area in the United States over the next few years. SMZ, currently less than 1% of St. Cloud sales, will continue to gain market penetration for many years.

Jan 1, 2004

By S. McCalpine, W. Muir, P. J. Downey

"Golden Bear Operating Company Ltd. (GBOC) was a joint venture between Chevron Minerals Ltd. and North American Metals Corp. that was formed for the development of the Golden Bear Project. The mine is located at Muddy Lake, Western British Columbia, approximately 80 km northwest of Telegraph Creek and 135 km west of Dease Lake (see Figure 1). Road access to the mine was developed by Golden Bear and consists of a radio controlled 155 km gravel road originating at highway 114.A feasibility study was completed in 1987 and project approval was finalized in 1988 with Golden Bear issuing a ""Request For Proposal"" for detailed engineering in May 1988. Golden Bear also commenced negotiating with vendors at this time for the supply of the two principal process equipment packages: the dry grinding and classification system and the whole ore roaster package.Process plant engineering and plant construction was completed in October 1989 with plant startup commencing in November 1989. Two months into the commissioning phase it became apparent that the plant, as designed, would not achieve the anticipated production targets.Kilborn Engineering Pacific were subsequently contracted by GBOC to review and modify the plant design, assist the operating personnel with plant commissioning and startup and provide operator training.This Paper describes some of the problems encountered during the startup and the plant modifications incorporated to achieve design parameters."

Jan 1, 1992

By Chun-Sheng Liao, Chun-Hua Yan, Sheng Wu, Fu-Xiang Cheng

"INTRODUCTIONChina is providing more than 90% of the rare earth products consumed in the whole world. Acidic extractants are commonly used in the extraction separation of rare earths. Saponification of the acidic extractants by basic substances is usually necessary for the purpose of increasing and stabilizing their extraction capacity, and meanwhile inorganic acids are required for both scrubbing and stripping. Thus acids and bases are the main consumed chemicals, and the resulting salts are the main pollutants generated by rare earth separation processes. Currently, due to increasing environmental concerns in China, rare earth solvent extraction separation techniques are being developed to reduce both consumption and emission of chemicals, which is driving the developments on both theories and processes for solvent extraction separations.In the 1970s Prof. Xu et al. developed the Theory of Countercurrent Extraction (Xu, Li, & Yian, 1985). In recent years, the development of novel processes for rare earth separation has moved beyond the earlier theory. One rare earth separation process, the so-called hyperlink process, has been developed in the past decade and proven in industrial practice to dramatically reduce both the consumption and emission of chemicals during multi-component solvent extraction separations, and therefore is now widely used in the Chinese rare earth separation industry (Liao, Wu, Cheng, Wang, Liu, Zhang, & Yan, 2013). The present article will give a brief review of the development of the theory of the hyperlink processes, and the hyperlink separation flowsheets for typical rare earth mines in China designed using the theory.HYPERLINK PROCESSES (LIAO et al., 2013)A flowsheet of multiple-component separation consists of a couple of separation units. The units of a conventional flowsheet separately consume chemicals for saponification and scrubbing and discharge wastewater with resulting salts. In contrast, the separation units in a hyperlink process are hyperlinked and thereby the chemical demands of the whole flowsheet are decreased. For a feed containing t components of A1, A2, …, and At, it has been proved in theory that the separation mode of (AtAt-1…A2)/(At-1At-2…A1) is preferred in a single separation unit. The hyperlinking between separation units can have two forms. The link between two units locating at a same separation level, such as between (A4A3)/(A3A2) and (A3A2)/(A2A1), is known as horizontal hyperlinking. The link between two units located on different levels, such as between (A4A3A2)/(A3A2A1) and (A3A2)/(A2A1), is known as vertical hyperlinking. Both the hyperlinking forms have been proven to save chemical usage and consequently to lower the pollution emissions in industrial practices as well as in theory."

Jan 1, 2016

By J. Koponen, M. van de Vijfeijken, L. Bos

"The availability and reliability of large grinding mills and their Gearless Mill Drives (GMDs) are of paramount importance for the grinding process. Although GMDs have been in service for decades, and are known for their operational efficiency (reliability and robustness with reduced operating cost per ton), compared to conventional drives, in the last decade due to certain reasons some failures led to serious unscheduled shutdowns and significant insurance events.The majority of these notable ""insured"" failures have happened on GMDs installed on relatively large mills, as the financial impact of a failure is proportional to the through-put of the mill. Despite the occurrences of these events, as mining operations are driven by lower ore grades and the ability to continue reducing operating costs per ton, the trend for having larger mills is still very present and there is no reason why this trend should not continue.It is obvious that if not handled correctly, the possibility of large value GMD loss events, coupled with the continuing increase in mill size or required availability and reliability targets, could potentially lead to major conflicts as it becomes difficult for the insurance companies to judge the risk and hence may result in hesitation to insure these grinding circuits. This paper will not only describe the conflicting situation from both an insurer's perspective and from an equipment supplier's perspective, but also how these conflicting challenges can be successfully mastered. It has to be noted that not only the mining companies themselves, but also their insurance companies and the involved equipment suppliers have a common interest: to reach the highest availability and reliability in order to avoid or at least minimize unscheduled shut down times, and most importantly prevent unplanned events that result in extended production stoppages or reductions in through-put of GMD driven mills.From the very beginning onwards, the complete service concept together with emergency plans must be integrated on every level in the design of the grinding circuit. This approach must be implemented continuously and without compromises by all involved parties during all following stages, such as basic design, detail design, manufacturing, quality inspection and testing, packing, transportation, storage, installation, commissioning, operation and maintenance. The concept of formal risk analysis related to mill operations, maintenance and spare parts strategies must be an integral part of mining companies’ decisions related to the selection for installation and continued use of large mills powered by GMDs. The service concept in place for operating mills shall also have a clear focus on very early detection of any abnormalities, so that the risk can be mitigated and unscheduled shutdown times avoided. However, if a major failure occurs, then procedures and tools shall already be available in order to ensure that production impact is minimized."

Jan 1, 2012

By M. Hozayen, E. S. Radwan, P. A. Nawrocki, A. Jebbouri

"A major geomechanical study was conducted for one of the UAE onshore oil fields with the purpose of studying reservoir rock properties and stress distribution, based on which a 3D coupled reservoir geomechanical model was built. This model was later used for wellbore stability analysis and for analyzing the effect of fractures on future reservoir production performance, including fracture deformation and permeability evolution occurring due to reservoir depletion and resulting changes in local stress field. The subject of this study was a complex fractured Upper Cretaceous carbonate reservoir characterized by high degree of heterogeneity, both vertically and laterally. Wellbore instability related drilling problems were encountered while drilling the wells in this field. The problems were mainly in drilling the horizontal wells, including breakouts and mud losses. Experimental results of laboratory tests are summarized in this paper whereas wellbore stability analysis and formulation of a 3D geomechanical model that was built for that purpose is summarized in a sister paper (Part II).A suite of tests reported includes tensile strength, uniaxial and triaxial compression and permeability under stress at simulated reservoir conditions. All tested rocks have been grouped into twelve test units and reservoir geology, rock types and challenges related to designing a viable sampling and testing program for a big reservoir are discussed first followed by sample selection criteria and details of the testing program. All test units showed brittle behavior at zero confinement and some samples showed similar behavior at low confining stresses. With confining stress increase, the behavior gradually turned to plastic but some samples showed features of ductile behavior even at low confinement.Obtained experimental data have been summarized in the form of strength criteria and correlations. The Mohr-Coulomb strength equations were obtained for each test unit and also for the averaged values. It was noticed that triaxial compressive strength (TCS) increases with decreasing porosity or increasing density but their influence on TCS is getting smaller with confining pressure increase. Good correlation of porosity and density with Young’s modulus, Poisson’s ratio, unconfined compressive strength (UCS), friction angle, cohesion and tensile strength has been noticed and there was an increasing trend between the confining pressure and TCS. Rock type (mud or grain supported) was not influencing the TCS as much as porosity and density and the two lithologies encountered affected TCS approximately in the same way. These results and correlations are summarized and explained in this paper. They were further used in the numerical modelling part (Part II) of this paper, Hozayen et al. (2015). It is also concluded that rock lithology is not a decisive factor and mechanical properties of tested rocks should be rather considered dependent on porosity and permeability. This helped greatly in reducing the number of tests that had to be performed."

Jan 1, 2015

By James F. Kelly

"Research and development on the production of liquid fuels from coal is rapidly expanding worldwide. AImost every industrialized country is engaged in coal liquefaction research and process development. In Canada, the federal government, through CANMET, is actively supporting coal liquefaction research and development in a number of areas.A review of the basic principles and some of the processes in the production of liquid fuels from coal is presented with reference to the characteristics of the Canadian coal resource base. An overview of the CANMET coal liquefaction contract program is presented and specific results from the batch autoclave studies carried out with Saskatchewan lignite and Nova Scotia high-volatile bituminous coals are discussed. The development of a laboratory-scale continuous-flow coal liquefaction unit at the Energy Research Laboratories of CANMET to investigate the co-processing of coal and bitumen/heavy oil is also described.IntroductionThe CANMET coal liquefaction program is made up of two interrelated parts. The first part consists of the research and development work being carried out at the Energy Research Laboratories near Ottawa, Ontario. The second focuses on contracted research and development as part of the Coal Conversion Program of Energy, Mines and Resources Canada. The long-term objective of the liquefaction program is to contribute to Canadian liquid fuels production through the definition, research, development and demonstration of different coal liquefaction technologies for the Canadian marketplace.In coal liquefaction, the main objective is to produce liquid hydrocarbons with a higher hydrogen-to-carbon (HIC) ratio than the coal feedstock while reducing heteroatom (S,O,N) content, removing mineral matter and minimizing gas production. Typical atomic HIC ratios for a variety of Canadian fossil fuels are shown in Figure I. Canadian coals have about 500/0 of the HIC ratio present in tar sand bitumens and heavy oils and only about 20% of the ratio available in methane. In general, the cost of synthetic fuels production is related to the cost of hydrogen and, therefore, to the increase of HIC ratio between feedstock and products. On this basis, the production of liquid fuels from coal would be expected to be more costly than liquid fuels produced from bitumens and heavy oils. However, for mined tar sands and some heavy oils this difference tends to be offset by the large sand content (>90 mass %) of tar sand bitumens and the increased production costs of viscous heavy oils. For example, it can easily be shown that for equal weights of distillate <525°C) yield, current coal liquefaction processes required between two and three times less mined coal by weight than the mined tar sand s required for the most technically advanced processes proposed for bitumen upgrading."

Jan 1, 1981

By C. J. Farrow, M. J. Smith

"Bechtel has managed a number of test programs to establish autogenous grinding circuits and size mills for a variety of ores.This paper outlines the procedures whereby bench scale and pilot plant tests are used to select the most efficient circuit to grind the range of ore types likely in the mill feed.Five examples are given. One example traces the development of a pilot plant program; it shows how bench scale Work Indices provide a target for the grinding power requirement of an ore and relates how pilot circuits are changed as a result of interpreting the results from preceding tests. The other four examples relate the interpretation of the test results to provide design data; they illustrate a number of phenomena which have been observed.INTRODUCTIONConventional crushing and grinding circuits can be specified from bench scale test data such as Bond Work Indices. Bond Indices have been correlated to a large number of rod and ball mills and by applying appropriate factors, mills can be sized from the Work Index.For autogenous or semi-autogenous grinding circuits, bench scale tests are not sufficient to be able to specify the circuit and size of the mills for a commercial plant. It is necessary to run a series of pilot plant tests to determine how the ore behaves."

Jan 1, 1982

By S. Haggarty, R. Walton

Barrick&apos;s growth and development plan will add three major new mines during 2005 including the Lagunas Norte Project in the La Libertad Province of Peru, the Veladero Project in the San Juan province of Argentina, and the Tulawaka Mine in north¬western Tanzania. Lagunas Norte and Veladero are similar in that they are both green-field open pit deposits at elevations over 4,000 meters above sea level, with two stage crushing and heap leaching followed by Merrill Crowe zinc precipitation for precious metal recovery. Operating sites will each generate in excess of 700,000 ozs Au per annum with commissioning and full scale operation planned during the third and fourth quarter of 2005. Details with regards to regional geography, development schedule, production and process specifics for Lagunas Norte and Veladero will be discussed in this presentation providing an overview for the respective properties.

Jan 1, 2005

By Hrayr Agnerian

The fair market value of an exploration property is determined by its potential to host a mineral deposit. This potential is gauged by the results of previous exploration, exploration stage, meaningful past expenditures and remaining targets that are not yet tested. Values of exploration properties can be viewed as distinct points in a three-dimensional space defined by orthogonal axes, namely: Exploration Stage (x-axis); Cumulative Expenditures (y-axis); and Property Value (z-axis). In general, these values are estimated by applying activity factors on previous exploration expenditures, e.g. an activity factor of 100% for an active property with good potential and a factor of 50% for an active property but past expenditures have not upgraded the property. At certain periods, a market factor may also be applied to reflect the activity of mineral property acquisitions. For properties that do not exhibit any exploration potential, only nominal values are applied.

Jan 1, 1996

By R. Q. Honaker

It has been shown that naturally hydrophobic carbonaceous materials such as coal and graphite can be selectively coagulated and separated from hydrophilic impurities without using oily agglomerants, flocculants or electrolytes. The coagulation occurs at C-potentials significantly higher than those predicted by the classical DLVO theory, suggesting that it is driven by the hydrophobic interaction. In the present work, the energy barriers for the coagulation of a hydrophobic coal sample have been calculated using the extended DLVO theory which incorporates the hydrophobic interaction energy in addition to the dispersion and the electrostatic energies. For the coagulation of minerals present in the coal, the classical DLVO theory has been used for the energy barrier calculation. The results of these calculations provide an excellent correlation with the results of a series of Selective Hydrophobic Coagulation (SHC) tests conducted with run-of-mine coal and graphite samples.

Jan 1, 2004

By F. Mallozzi

"With the requirements of air pollution codes becoming more and more critical, the role of the ventilation engineer in industry has become an extremely important one. The ventilation engineer must provide the expertise for the selection of equipment and the design of systems which will reduce pollution to an acceptable level. Because pollution control systems involve considerable capital and operating expense, he must have the ability to select, from a wide range of products, the collector which will provide the required performance with a minimum of down time for maintenance. This paper discusses the principles of wet collection and the forces used to separate particulate matter from a gas stream. Important factors in the selection of equipment, such as collection efficiency, horsepower requirements and water consumption for the various types of collectors, are discussed in detail, as well as the construction features normally incorporated to circumvent potential problems."

Jan 1, 1971

By W. Dietzel

Fracture mechanics based techniques are used to gain insight into the phenomenon of stress corrosion cracking (SCC) and to develop guidance for avoiding or controlling SCC. From constant extension rate experiments under rising load or rising displacement conditions the susceptibility of high strength steels, aluminum, magnesium and titanium alloys to SCC and hydrogen embrittlement can be assessed. Such tests on pre-cracked specimens are also well suited for studying the mechanisms leading to SCC by employing appropriate models for the degradation of metallic materials which take into account the uptake of atomic hydrogen from the corrosive environment. Measurements of crack growth resistance curves using the crack tip opening displacement as fracture parameter can be compared with simulated R-curves obtained from modeling of the mechanism of hydrogen embrittlement. The materials investigated are a high strength steel and a magnesium alloy both exposed to environmental conditions which fostered the uptake of hydrogen.

Jan 1, 2010

By Richard E. Barrett

SOME YEARS AGO I was associated with a mining operation which, because of its isolated location, burned wood for heating purposes. Year after year the tractors and tucks hauled the cordwood in from the edge of the ever-growing clearing. Each year the cartage costs became greater. The degree to which transportation distances affect the economics of fuels obviously varies with many factors, but the main criterion is the amount of heat a unit weight of the fuel will produce. For in-stance, wood is limited in most cases to a haulage distance of a few miles. Coal can be shipped hundreds of miles, whereas petroleum and gas ?can be transported thousands of miles. The world is now on the brink of having a new fuel -uranium. It has the virtue of being so concentrated that transportation costs can, for all practical purposes, be disregarded.

Jan 1, 1958

By A. Warczok

The computer simulator of slag cleaning in an electric furnace is based on a set of mathematical models describing heat liberation, the rate of slag reduction and gravitational coalescence of matte and metallic copper inclusions. The simulator consists of a mass and heat balances as a frame, in which the kinetic equations of the slag reduction and phase separation are incorporated. Friendly user-screen interface allows for dynamic control of process parameters in real time together with simulation of typical operations, such as furnace charging with liquid slag, solid reverts and coke, tapping out of the slag and matte, motion of electrodes and control of the transformer. The batch, semi-continuous or continuous process can be simulated. The process parameters are displayed and continuously recorded for further analysis. The computer simulator is a powerful tool for process optimization, training of furnace operators and the design of new slag cleaning installations.

Jan 1, 2007

By D. Djokic

One of the most attractive features of electron beam curing as a process for manufacturing composite structures is the potential for attaining very low levels of residual stress as compared to thermal curing. This residual stress reduction is important both for the potential to reduce composite failure strains at low operating temperatures and the associated reduction in process-induced deformation. Previous work has demonstrated that it is possible in some cases to significantly reduce residual stress development during irradiation and also avoid development of additional residual stress during post cure. In this paper, simple L-shaped composite laminates were used to study the development of residual stress and deformation during thermal post-cure of specimens that were already partially cured using different radiation doses. Following post-cure, these specimens were also subjected to high-temperature loads to study creep behaviour under service conditions. Aerospace

Jan 1, 2006

By RALPH R. STEA, John H. Fowler

Clay, quartz sand and lignite deposits overlie Carboniferous rocks in central mainland Nova Scotia. Recent evidence indicates that these deposits are fairly extensive. Sands consist of almost pure angular quartz grains. Clays are highly plastic and range in colour from black through grey and blue to mottled red and white. Palynologica/ information dates the sediments as Ear{y Cretaceous, and mineralogical studies show them to consist primarily of quartz, kaolinite and mica. There is not yet enough evidence for detailed stratigraphic description, but sequence and thickness of sediments are known to vary greatly over short distances. Drill logs from Musquodoboit Valley recorded Cretaceous sediments at 168 m thick. Of the three active pits in Cretaceous sediments of central Nova Scotia, two are for silica sand production and are located at Elmsvale and Brazil Lake while a third pit at Shubenacadie produces clay for manufacture of structural clay products.

Jan 1, 1984

By P Kovacs, D. L. Flock

For the purpose of reservoir-performance calculations a balance can be made between the materials with-in the reservoir and the production from the reservoir. The material balance equation, a relationship which holds under or near equilibrium conditions, has been used in many forms by the Petroleum Engineer for the determination of initial oil-in-place in the reservoir and the calculation of performance into the future. One of the more recent methods developed by Tracy, utilizes a modified form of the Schilthuis material balance. In the latter case, values of incremental production are assumed for a particular pressure drop, a value of the gas-oil ratio found and a check of this estimate made by calculation"' the initial oil-in-place. Tracy's method utilizes an estimation of the instantaneous gas-oil ratio and by trial and error a value of the gas-oil ratio is

Jan 1, 1961

By J. B. Brodie, C. Pelletier

"The vulnerability of Canadian and U.S. companies, their directors, officers and employees to onerous penalties associated with violations of environmental statutes and common law actions has provided the impetus for the increasing use of environmental audits. This trend is developing in direct proponion to the cost and difficulty of obtaining liability insurance. Companies operating in British Columbia should be cognizant of developing legislative and enforcement trends and their implications for individual and corporate responsibility. Canadian mining companies doing business in the U.S. should be particularly aware of the environmental exposure which may be assumed with property acquisition or by operations which produce or use any of an ever-increasing list of regulated substances.The environmental audit is now a key component of prudent business planning which will identify noncompliances and environmental liabilities, outline defensive strategies, and assist in a legal defence should charges be laid. This paper will discuss the purpose and mechanics of an environmental audit with emphasis on those features which will maximize protection against statutory and common law actions.IntroductionThe environmental audit is but one weapon in a comprehensive defensive strategy for corporate and individual survival in an increasingly litigious world. The principles of the environmental audit have been formulated as a logical response by management to an ever-growing list of environmental vulnerabilities, which often have the potential to result in plant shutdowns, prosecutions or fmancial liability of major proportions. Accordingly, the audit may play a critical role in maintaining profitability as well as assisting in the defence of a company and its employees against actions taken by regulatory agencies and citi7.cns under statute and common law. Should convictions result from these actions, the penalties are likely to be ameliorated by the demonstration of due diligence through management policy supporting the audit procedure.An awareness of environmental sensitivities, strict adherence to licensing requirements, and planning for environmental emergencies are now generally considered to be as important to profitable performance as operating costs, metal prices, and labour peace. Why is this so? The increased priority given to environmental matters is partly a result of changing attitudes amongst the mining profession, but perhaps more importantly, it is also a direct consequence of the proliferation of ever more stringent environmental legislation, the targeting of management for responsibility and the draconian penalties imposed for violations of such legislation. Contributing to this trend are recent court decisions involving disputes of an environmental nature in which the standard of care required for a successful defence now requires almost super-human diligence in environmental management. The principle of ""strict liability"" (in which negligence or permit violation does not have to be shown) is also being increasingly applied in the resolution of civil actions."

Jan 1, 1988

By Bob Butler

Brunswick Mine has been involved in a comprehensive research program investigating site specific aspects of thiosalt management to eliminate its adverse environmental effects. Minimum annual reagent cost estimates for thiosalt treatment using hydrogen peroxide and sodium hypochlorite are $400K and $1.5 million respectively. Also, minimum costs for the use of bicarbonate to buffer the pH depression associated with thiosalt oxidation in the receiving environment is in the order of $400K annually. A design of experiment (DOE) research program identified that natural UV radiation, temperature, DO and water chemistry are key factors influencing the natural oxidation rate of thiosalts within Brunswick?s water management system. A DOE surface response model was used to describe the thiosalt oxidation kinetics, which were then used to develop a predictive oxidation model for thiosalt and pH control of the mill?s reclaim water system.

Nov 1, 2002

The Millennium deposit, located in northern Saskatchewan between the McArthur River mine and the Key Lake mill, has considerable potential for becoming an operating mine. Located in the Athabasca Basin, Millennium is blessed with both the riches and the challenges that this basin offers. The potential for ground water inflows during shaft sinking, and the unconventional challenges associated with underground uranium mining, render the successful development of a new mine in this area especially rewarding. The preliminary design and engineering of the Millennium Project has tapped into the experience of other operations in the area, and has utilized new applications of geophysics technology to enhance the understanding of the local geological structure. This discussion will focus on the innovations, and the challenges specific to uranium mining, for a deposit that is poised to be one of the next mines to supplement Saskatchewan&apos;s uranium resources.

May 1, 2008