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By Norman B. Davis

THE ceramic group of industries is comprised of those engaged in the manufacture of cement, glass, artificial abrasives, whiteware, including earthenware, stoneware, porcelain tableware, porcelain sanitary ware, electrical porcelain, floor and wall tile, porcelain enamel on metals, refractories of all kinds, sewer-pipe and structural clay products, such as terra cotta, brick, and hollow tile. The various sub-divisions of the industry produce a wide range of articles on which we depend for our creature comforts from day to day, perhaps to a greater extent than we generally realize. The industry, in turn, depends on a great number of minerals, and chemical products derived from minerals, and it is the object of this brief paper to present a list of these with notes indicating the particular applications. In order to bring home the importance of the industry to your daily life, stop and consider the many things around you accepted as a matter of course. Cement provides the smooth surfaces of many of our highways, city streets, and sidewalks. It enters into nearly all types of construction, alone or in combination with other clay products. Glass we hardly appreciate because we can see through it so easily, but it is there to serve us in windows, doors, and other light-transmitting structures. Glass is the universal means of transporting liquids and beverages, our beverages are usually served in it, and, with the recent development in fine spun glass textiles, there is a possibility of glass clothing in the future. Chinaware, a general term for table dishes, may be earthenware (not vitrified), semi-porcelain, or bone china, but it is before us three or more times a day ?and we seldom think of the minerals that have made these products possible. Floor tile, wall tile, and other ceramic specialties for interior and exterior use and decoration please the eye and provide sanitary surroundings.

Jan 1, 1938

By R. Drozd

"The Bui/moose Mine is in the northeast coal area of British Columbia, and less than $300 million was spent to bring this 2.3 million-tonnes-per-year metallurgical and thermal coal mine into production by November 1, 1983, one month ahead of schedule. The project is an unincorporated joint venture undertaking, with Teck-Bullmoose Coal Inc., a wholly-owned subsidiary of Teck Corporation, holding 51%, Lornex Mining Corporation holding 39%, and Nissho-lwai (Canada) Ltd. holding 10%. Bullmoose Operating Corporation will be the manager and operator of the project. This paper will broadly cover the history and exploration work on the property, the geology, open-pit mining plans and equipment, the preparation plant flowsheet from breaker station to clean coal silo, the 35 km highway truck haul, the railroad loadout system, manpower requirements, approvals and permits, and general financial arrangements. Introduction The Bullmoose Mine Project is located about 87 km by road south of Chetwynd, B.C. and consists of an open-pit coal mine, a plant facility in the Bullmoose Creek valley below the mine, and a separate rail loadout facility on the British Columbia Railway Branchline near the new town of Tumbler Ridge some 35 km by road to the east. The plant will be capable of producing a total of 2.3 million tonnes per year (mty) of washed metallurgical and thermal coal. Long-term metallurgical coal contracts for high-quality, medium-volatile, bituminous coal have been signed with nine Japanese buyers for 1.7 mty, and the balance of0.6 mty will be for thermal coal production. Plant construction began in the spring of 1982, and in May 1983, preproduction waste and overburden removal in the mine was started. The plant began tuning up in October and was fully operational by December 1983. Metallurgical coal began moving to the coast in unit trains during November, and first vessel loading at the Ridley Island port began in late December 1983."

Jan 1, 1985

By R. Glenn Madill

Western Canada is defined, for the purposes of this paper, as that part of the Dominion bounded approximately by the 95th and 141st meridians of longitude and the 49th and 80th parallels of latitude. It is comprised of Manitoba, Saskatchewan, Alberta, British Columbia, Yukon, and that portion of the Northwest Territories lying to the west of the 95th. meridian. The first magnetic observations made in Western Canada were in the interests of navigation by sea. Observations were made by Captain Middleton in Hudson bay at Churchill and York Factory in 1725, and along the Pacific coast by Captain Cook in 1778 and Captain Vancouver in 1792. The first systematic magnetic survey in Western Canada was made between 1819 and 1826 by Sir John Franklin in his widely distributed explorations. It is of interest to find that while the first magnetic declination observations made in Hudson bay and along the Pacific coast were purely in the interests of navigation, the next investigations, which were made in the Western Arctic, included measurements of inclination and force with those of declination. There was a valid reason for this more complete research into the magnetic field as the construction of declination charts depended on the position of the north magnetic pole. Halley promulgated a theory 1683 that " the globe of the Earth may be regarded as one great magnet, having four magnetic poles, two of them near each pole of the equator, and that in those parts of the world which lie near any of those magnetic poles the needle is chiefly governed thereby, the nearest pole being always predominate over the more remote" . The position of a magnetic pole may be defined as a point where the inclination is 90 degrees and the horizontal force zero. It is obvious that the position cannot be' defined by declination observations alone since, for some distance from the magnetic pole, .the horizontal force is too weak to give directive force sufficient to effect the pointing of a compass.

Jan 1, 1948

By Milton C. Graves, Marcos Zentilli

"Gold has been reported from most geological environments in Nova Scotia; however, virtually all production (circa 2,000, 000 troy ounces; circa 60 tonnes) has come from that part of the province to the south of the Glooscap Fault which is underlain by Lower Paleozoic rocks of the Meguma Group. Over fifty concordant sets of quartz-carbonate-arsenopyrite veins have seen production. The host rocks are greenschist-grade equivalents of Cambro-Ordovician flyschoid quartz wackes and shales folded and metamorphosed during the Devonian Acadian Orogeny. The veins were emplaced under conditions of greenschist-grade regional metamorphism and under the same conditions of tectonic stress that later resulted in the regional folds and penetrative, axial-plane slaty cleavage. Rapid filling of hydraulic fractures caused by excess metamorphic pore fluid pressure under Acadian tectonic stress conditions can account for the geometry and paragenesis of these veins.The ultimate source for gold deposits in most greenschist-grade domains remains in doubt, but these domains seem to have had ample gold within them available for mobilization. The work done, to date, on the gold geology of Nova Scotia suggests that regional greenschist metamorphism was an effective mobilizer and a potential concentrator of Au, As, W, Fe and S from these vast reservoirs.In rocks of pre-Acadian age north of the Glooscap Fault, gold occurs as an important accessory in volcanogenic massive sulphide ore, as a minor constituent in other types of basemetal concentrations and in one small concordant group of quartz veins.The post-Acadian metallogenetic domain, which overlies and overprints the two older domains, contains small amounts of gold in many mineralizing environments. Veins, with stibnite and gold, cross-cut crystalline rocks. Disseminated gold is present in basal conglomerates of post-tectonic molasse. Gold has been a by-product of Mississippi Valley-type Pb-Zn-Ba-Sr deposits in Lower Carboniferous sedimentary rocks and has been reported with Pb-Zn-Ba-F in veins which cross-cut Lower Carboniferous and older rocks. Small post-glacial placers have also seen minor production."

Jan 1, 1982

By H. R. Stoger

"In 1994 world trade grew by 9%, the fastest annual increase since 1976. Dry cargo shipping rates are at an all time high.Panamax size bulk carriers are receiving19 000 US dollars per day for trans Atlantic round trip voyages. This is good news for the ship owners but not such good news for the industrial users of ocean shipping.The main emphasis of this paper will be on bulk carriers, the charter market and what industrial companies can do to reduce their costs of ocean transportation which is critical to Canadian exporters. Let us look at the charter market in general.Bulk carriers come in four main sizes:1.The Capesize bulk carriers of 110 000 to160 000 tons that are primarily used to transport iron ore and coal;2.the Panamax bulk carriers of about 70 000tons dwt. This is the largest size (with a beam of 105 ft) that can transit the Panama Canal.3.the Handymax bulk carriers of 40/45 000tons dwt; and4.the Handysize bulk carriers of 20/35 000tons dwt.The handysize vessels are usually craned or geared and carry a variety of bulk cargoes including steel. Ship sizes have increased over the years and the mining industry now uses primarily capesize or Panamax bulk carriers.International chartering is conducted through an international network of shipbrokers. There is usually one broker representing the ship owner and another broker who represents the charterer. The major chartering centers are London and New York but a great deal of chartering activity is conducted in regional markets such as Hongkong, Oslo, Montreal and Hamburg.The Biffex Index or Baltic Freight Index is a good measure of dry bulk freight rates. The Biffex is composed of ten major routes. In May1995, the Biffex was at 2310 points. A year earlier it was at 1354, an increase of about 56%."

Jan 1, 1996

By J. Dubinski

Underground mining of copper ore in the Legnicko-Glogowski Copper District basin generates a number of seismic events, whose energy often exceeds 108 J (Butra, 2010). The number of tremors and their location shows that the area of rock mass involved in the deformation and failure processes significantly exceeds the area of mining operations. Locations of seismic foci of high energy tremors, as well as the aftershocks that accompany them, extend hundreds of metres, confirming that processes to restore the energy balance of rock mass occur in a short amount of time and over a wide area. Thus, an area of similar size should be considered in predictive analyses of the tremor?s position. It should be emphasized that a large portion of the rock mass still has a level of freedom resulting from the way the rock mass is held together and its geometric continuity. This level of freedom is dependent on the scale and duration of mining, the number and size of natural structures, and rock mass pressure, including gravitational pressure constricting individual fragments of rock mass in the area (Burtan, 2012). It can therefore be assumed that in real conditions, areas where mechanical strength of the layers has been exceeded may be located a considerable distance from each other and do not necessarily need to coincide with the working area location. In this sense, a rock mass influenced by mining exploitation is essentially a rock mass in which numerous fragments with concentrated energy exist simultaneously. Energy will be released within these rock mass areas each time rock mass strengths are exceeded by the induced stress changes related to mining operations. This paper presents a discussion on how to predict the location of seismic activity areas based on a change of position of seismic energy equivalents. This parameter is calculated for a given set of seismic tremors with defined foci coordinates. For a given set of seismic tremors, the location of seismic energy equivalents may be used for predicting the location of high-energy seismic events.

Aug 1, 2013

By V. Labiouse, M. Souley, N. Lafrance, C. Auvray

"Chalk rocks have been used for centuries as a strong building material and for the production of lime. The shallow underground room-and-pillar quarries where the chalk was extracted are now abandoned and endure the effects of time and weathering, increasing their risk of collapse. The risk of instability, involving natural or anthropic underground structures, is an issue for more than 10 000 towns in France.In order to investigate the causes of underground quarry collapse and to aid prevention strategies, we carried out a study of the physico-mechanical behaviour and ageing of chalk in abandoned pillars in two underground quarries, in situ-instrumented by INERIS, in the Parisian Basin, France. Core samples were drilled horizontally from pillars in the Saint-Martin-Le-Noeud dolomitic chalk quarry (Oise, France) and the Estreux glauconitic chalk quarry (Nord, France).Uniaxial tests were performed on dry and saturated cylindrical plug samples extracted perpendicular to the cores at regular distances along their lengths. Physical and mechanical properties were obtained. The dolomitic chalk (Saint-Martin-Le-Noeud) exhibits variation in mechanical and physical properties with horizontal pillar depth. Both density and compressive strength seem to increase outwards from the pillar-core to the pillar-wall. This is the opposite of that would be expected from a purely mechanical point of view. SEM analysis revealed progressive degradation and homogeneity of the grains from the edge to the inside of the pillar. At the pillar wall, the crystal faces are well-defined, almost euhedral, and the grains are of variable size. In contrast, at the inside of the pillar, crystals are finer-grained and are anhedral with highly degraded edges. In the physico-mechanical tests and SEM analyses performed on the Estreux samples, no significant variation was observed between the pillar-walls and pillar-core. However, dissolution marks were observed along the entire length of the half-pillar core."

Jan 1, 2015

By K. Hawboldt, J. E. Halfyard, C. Bottaro, I. A. Harrison

"The removal of elemental sulfur from leach residues derived from massive sulfide concentrates via hydrometallurgical routes has been demonstrated in a laboratory setting by converting water-insoluble sulfur to water-soluble polysulfides. The approach was applied to leach residue from Vale's nickel hydromet demonstration plant in Argentia, Newfoundland, which contained significant amounts of elemental sulfur. This technique offers an alternative treatment protocol for residues with a sulfur component not amenable to standard flotation/hot filtration processes. The practical considerations of a proposed flow sheet will be discussed including the impact of other sulfur species (e.g. thiosulfate and sulfides) and key process variables. INTRODUCTIONPresently, large scale elemental sulfur extraction from hydrometallurgical leach residue is performed by Teck Resources using a process of sulfur flotation followed by hot filtration (Chalkley et al., 1993). As mentioned, the technique proves viable for residues derived from specific concentrations - in this case zinc - whose residues constituency is primarily elemental sulfur itself. However, problems arise when this constituency is altered as happens when, for example, a mine containing one particular concentrate is mixed or replaced with a differing concentrate from a second mine. Such cases can often strain the effectiveness of current sulfur removal processes (D'Odorico, 2004). If hydrometallurgical residue containing elemental sulfur cannot be effectively treatment by flotation, the residue is stored subaqueously as is the case in some 'grass roots' hydrometallurgical plants (those not coupled with smelting operations). Hydrometallurgical processing of concentrates involving pressure leaching is becoming increasingly common throughout the mining world, the genesis of which can be found in research performed by Sherritt in Fort Saskatchewan since the 1950’s (Ozberk et al., 1995).The investigation of elemental sulfur removal by means other than flotation includes the uses of sulfide salts (NH3S or Na2S) effecting the conversion of hydrophobic elemental sulfur to hydrophilic polysulfides. The work of Kunda et al. (1974) and Olper et al. (2007) shows that elemental sulfur can be quantitatively removed from hydrometallurgical leach residue via the formation of a mixture of polysulfides."

Jan 1, 2012

By A. Mehinrad, F. Rafia

"The Dez River flows from the Zagros Mountains into the great Khuzestan plain, Southwest of Iran. The 203 m high Dez Dam is a double curvature thin concrete arch dam, with a Pulvino, founded on thick bedded to massive conglomerate of Bakhtiary Formation, mainly horizontal and very less jointed at the dam site. Construction work was completed in 1963, creating a reservoir with a total storage volume of 3’315 million m3. The dam body, with some 350’000 m3 volume and (W/H=1.1/1.0), is the dominant feature of the project.Geological and geotechnical studies at the dam site started in 1957 and continued during the whole period of dam construction. Simultaneously, two extensive programs of laboratory testing were carried out in New York and Milan.Most of the results were recorded in the project design documents and in two very well-known papers of Talobre et. al. (1964) and Dodds (1966), however, no detail results are available for most of tests.In order to estimate geomechanical parameters of the rock mass foundation for numerical modeling of the dam body and its foundation, reassessment of the in-situ and laboratory test results using the recent rock mechanics methods was required.This paper explains how the outcomes of those tests, performed more than 50 years ago, were reevaluated and how the definitions and parameters presented in the project reports were re-interpreted using the recent rock mechanics concepts and definitions. Also, the results of classification of Bakhtiary conglomerate using GSI system and application of Hoek & Brown failure criterion for estimating rock mass parameters have been described.INTRODUCTIONThe Dez River flows from its headwaters in the Zagros Mountains into the great Khuzestan plain. Just before entering the plane, the river passes through a narrow, steep gorge that is about 17 km long. The Dez Dam is located at the entrance to this gorge, some25-km upstream of the city of Dezful and 150-km upstream from the provincial capital Ahwaz (Figure 1)."

Jan 1, 2015

By N. Erarslan, M. Ghamgosar

The size of rock fragments depends on the nature of the loading applied the strength of the minerals and the texture of the rock. Research in the literature demonstrates that there is a distinct difference in the rock fracturing process for static and cyclic loading. The tensile strength of brittle rocks is also one of the most significant parameters influencing the rock fracturing process and the propagation of micro-fractures on the crushing, blasting and cutting of rock. The Brazilian indirect tensile test, one of the methods approved by the International Society for Rock Mechanics (ISRM), has been used to determine rock fracture behaviour under different cyclic loading modes. In this study, the dimensions of Brisbane Tuff specimens have been selected according to the method outlined by the ISRM. The main aim of this study is to evaluate the effect of cyclic loading amplitude and frequency on the Fracture Process Zone (FPZ) at the micro-, meso- and macro-scales. The post-failure behaviour of the Brisbane Tuff specimens was obtained under cyclic loading with frequencies varied from 1 to 10 Hz. The amplitude was varied from 10% of Ultimate Tensile Strength (UTS) up to 80% UTS. Laboratory investigations of rock fragment size revealed that different loading frequencies and amplitudes produce different FPZ dimensions. Multivariate Analysis of Variance (MANOVA) results demonstrated that the FPZ dimension is relatively sensitive to the frequency change. Fragment size analysis showed that the FPZ is a consequence of the initiation, propagation and coalescence of micro-fractures and depends on the nature of the loading. Laboratory evidence showed that the FPZ dimension, for the cyclic tests performed on Brisbane tuff, is ranged from 0.07 to 20 mm. The achievement of this study highlights a key finding in the understanding of fracture patterns and propagation models in the FPZ under cyclic loading, which is the dominate mechanical action in the oscillator disc cutter (ODC).

Jan 1, 2015

By E. H. Chown

Scattered outliers of the Chibougamau Formation and the more continuous Mistassini and Otish Groups lie unconformably on an Archean basement abutting the Grenville Front. All the Aphebian rocks are deformed and offset by faulting related to the Front. The older Chibougamau Formation is exclusively elastic in origin, whereas the two later, time-equivalent groups include carbonatedominated (Mistassini) and elastic (Otish) sequences. Known syngenetic mineralization within these formations is limited to various radioactive showings in the Mistassini and Otish elastics, and the iron formations of the upper Mistassini Group. Three distinct types of epigenetic mineralization occur within the sedimentary rocks; pitchblende fracture fillings in all types of rocks in the Otish Group, widespread Mississippi-Valley type galenasphalerite showings at certain levels in the Mistassini Group, and chalcopyrite-pyrite bearing veins in or near argillaceous horizons of the Mistassini Group and Chibougamau Formation. The Otish elastic basin is part of a large area of the central Ungava peninsula which contains a variety of radioactive showings, the most promising being of the unconformity type, The final control for many individual showings appears to be local physico-chemical changes within faults and fracture zones. The overall structural control is in part supplied by the faulting episode related to the Grenville Front, which in turn limits the mineralization to the depth zone appropriate for open fracturing. The lead-zinc showings exhibit a strong stratigraphic control as well as close ties to secondary porosity developed by f aulting. The ore solutions were probably derived during the low grade metamorphism of the formations. Chalcopyrite- pyrite veins have provi ded the only mine production (Icon Mine) to date. They appear later than the low-grade metamorphic fluid circulation, and deposition is related to favourable structures and stratigraphy. The veins are clearly related to major faults. Thus, whereas stratigraphic settings appropriate to individual types of deposits are important, an overall structural setting may be demonstrated for a wide range of mineralizations. Detailed structural interpretations of individual showings may be the most fruitful pursuit in developing a concrete prospecting model.

Jan 1, 1984

By Paul Hammond

Abstract The Allard Lake ilmenite deposits, which are currently being developed on a large scale, occur as a series of dykes or lenticular, flat-lying bodies within the northeastern part of a large, oval shaped anorthosire mass of Precarnbrian age which lies with its long axis paralleling the gulf of St. Lawrence. The Lac Tio deposit, discovered by Kennco Explorations, Limited, in 1946, is the largest body of titanium ore of its type now known in the world. It contains upwards of 112,000,000 short tons of ilmenite ore averaging 32 per cent TiO2 and 36 per cent Fe. The ore is an aggregate of ilmenite with oriented microscopic blades of hematite. The deposits appear to be high temperature, late magmatic injections containing only a small amount of volatiles, and bear a genetic relationship to the anorthosite rocks in which they occur. * * * Introduction Recent developments on the ilmenite deposits in the Allard Lake district of Quebec indicate the probability of a major industry, and one which may make Canada the world's greatest producer of titanium pigments and, ultimately, of titanium metal. The presence of ilmenite in this district was first reported by the Quebec Department of Mines following a reconnaissance shore-line geological survey in the year 1941. The ensuing report by Retty describes the occurrence of a number of small ilmenite lenses about the shore of Allard lake and' along two smaller lakes in the vicinity. These showings were later staked by Toronto and Montreal interests who carried out a certain amount of development work, and were described in more detail by Longley for the Quebec Department of Mines. The claim groups were later optioned by Kennco Explorations, Limited, Canadian subsidiary of Kennecott Copper. None of the deposits in themselves constituted a sufficiently large body of ore to warrant the major construction expenditures necessary for their exploitation on a profitable basis. The surrounding anorthosite areas, however, were considered favourable for the possible occurrence of other ilmenite deposits

Jan 1, 1949

By Jr. Carmichael

"THE MAYO AREA was prospected as early as 1887. The first major activity started in 1898, when the Stewart River and its tributaries were examined for placer deposits, and in succeeding years the district became a small producer of placer gold. The first discovery of the lead-zinc-silver mineralization which has become the main interest of the district occurred in 1906, when a vein was found in the canyon of Galena Creek on the northwest slope of Galena Hill. This deposit was later known as the Silver King mine. In 1919 further discoveries were made on Keno Hill, approximately 15 miles east of the Silver King, the most important being the No.9 vein. Directly or indirectly, these finds are attributable to the search for placer gold, as galena was frequently found in the stream gravels.The 1919 Keno Hill discoveries were acquired by Yukon Gold Co. and operated through a subsidiary, Keno Hill Ltd., from 1920 to 1923. Most of the production came from No.9 vein. In 1921 Treadwell Yukon Corporation entered the field and acquired the Ladue mine. This company continued to operate for 21 years. It acquired in succession the Ladue, Sadie, Friendship, Lucky Queen, Elsa, Silver King, and Calumet mines. Its record of successful operations is very largely the achievement of the late Livingston Wernecke. Under his direction, the Treadwell Yukon Corp. produced metals with a gross value in excess of $21,000,000, in the face of greater transportation problems than exist today and with considerably lower metal prices.Treadwell Yukon ceased operations in 1942. Its entire assets were acquired in 1946 by United Keno Hill Mines Ltd., which has substantially increased the original holdings. It has drawn the bulk of its production from the Hector mine, adjacent to the Calumet. The Hector was not developed by Treadwell Yukon because of legal disputes among the vendors. It has proven to be the largest deposit yet discovered in the district."

Jan 1, 1949

By W. Holyk

"Although lead, zinc, copper, and iron sulphides have been known for many years in the Bathurst region, the existence of large massive deposits was not known until the discovery of the Brunswick orebody in 1952. This was followed by the discoveries of the Anacon orebody in 1953 and the American Metals orebodies in 1954. There is no question as to the great importance of these large massive sulphide deposits, and no doubt that other sulphide deposits are to be found. The problem, of course, is where and how to find them.The discovery of the Brunswick and Anacon orebodies is attributed to geophysical work. The original discovery of the American Metals deposit is generally attributed to a regional airborne electromagnetic survey.It is generally stated that the Bathurst area is a geophysical camp, and this is essentially true, but in this highly competitive search for orebodies it is obviously impossible for an individual company to cover the entire area by a comprehensive geophysical survey. Some means other than geophysics must be used to narrow the target. The quickest, cheapest, and simplest method is geological investigations.It has been stated that nothing can be accomplished by geology in the Bathurst region, since the camp is largely covered with overburden. This is true only insofar as detailed work on certain properties is concerned. It is not true of the larger regional picture. Outcrops are scarce, but angular float is abundant, and precedent shows that angular float has moved but a short distance from its source.GeologyAeromagnetic maps published by the Department of Mines and Technical Surveys are the best guides to the geology and structure of the area. These maps supply factual information concerning the underlying rocks. When coupled with field investigations, they are very useful in the interpretation of regional geology and the selection of favourable areas. The discussion of the geology is accordingly centred upon the aeromagnetic maps. The following is essentially a working theory, based on geological facts as best reconciled with all other available information,"

Jan 1, 1949

By H. Yasuhara, N. Kinoshita, S. Nakashima, K. Kishida

"In this study, flow-through experiments in fractured rocks have been conducted under different stress, temperature, and pH conditions so as to understand the evolution of permeability induced by these conditions. Throughout the experiments, the confining pressures and temperatures are well-controlled. Effluent concentrations are also measured for the ten elements of Si, Al, K, Fe, Ca, Na, Mg, Ti, S, and Cl that are included mainly in the targeted rocks. In the early stage of the experiments, the fracture permeability measured abruptly decreases with time, and subsequently reaches quasi-steady state within a relatively short period. In contrast, the permeability in the intact rocks monotonically increases with time. The permeability increase and decrease are attributed likely to the relative dominance of mineral dissolution in the pore spaces and to that of mineral dissolution/crushing at the propping asperities within the fracture and/or mineral precipitation onto the free surfaces, respectively. The evolving rates and magnitudes of the permeability are likely to be controlled by the stress exerted over the contacting asperities, temperatures, and pH of the permeant. Thus, this complicated behavior should be attributed to the coupled chemically- and mechanically-induced effects, which should be examined in more detail for longer period to contribute to the safe entombment of radioactive wastes. INTRODUCTIONUnderstanding of the flow and transport characteristics of porous/fractured rocks is required for the safe and long-term geological isolation of energy-related by-products (i.e., high level radioactive wastes and anthropogenic CO2). Notably, under relatively high temperature and stress conditions, mechanically- and chemically-mediated processes may alter the pore structures in rocks, resulting in an irreversible evolution of the flow and transport behavior. Augmentation in permeability may result from mechanical dilation due to shearing and mineral dissolution within the pore spaces, while reduction may result from reversible or irreversible mechanical compaction, mineral dissolution at the contacting areas, and clogging of pore spaces by precipitation of secondary minerals."

Jan 1, 2015

By Derek H. C. Wilton, David T. W. Evans

"Abstract - The Midas Pond gold prospect, central Newfoundland, is hosted by sheared and altered felsic and mafic pyroclastic rocks of the Tulks Hill volcanics, Victoria Lake Group, and has been trenched and tested by 19 diamond-drill holes. Gold values are sporadic, with the best diamond-drill intersection assaying 7.3 g/t over 0.9 m, and the highest grade channel sample containing 14.7 g/t over 1.15 m. Alteration and mineralization are confined to a 200 m wide brittle-ductile shear zone. This shear zone formed in response to regional D1 deformation, and the shear zone fabric parallels the regional S1 foliation. D2 deformation resulted in broad Z-shaped flexuring of the shear zone. The deformation was probably related to the ca. 396 Ma to 420 Ma Salinic Orogeny.Advanced argillic alteration and an extensive halo of Fe-carbonate and pyrite surround the gold mineralization. Alteration minerals include pyrophyllite, paragonite, quartz, plagioclase, chlorite, fluorite, Fe-carbonate, and pyrite. As such, the alteration seems to reflect combined epithermal (argillic) and mesothermal (carbonate) mineralizing environments. The argillic alteration and fluorite represent a regional hydrothermal effect on the felsic volcanic rocks; whereas, the Fe-carbonate and pyrite represent a mesothermal alteration associated with auriferous quartz veins. The Au, which is spatially associated with pyrite, occurs in three structurally-controlled vein sets. These veins are confined to the contact between a highly deformed breccia (the banded mafic tuff) and structurally overlying, altered felsic tuffaceous rocks. The vein sets include: V1 boudinage veins that parallel the shear-zone fabric (C-shear veins), and V2 and V3 extensional fracture veins which are controlled by an S2 fracture cleavage. V1 veins are the earliest and contain the lowest concentrations of Au. V2 and V3 veins are concentrated within the hinges of the D2 flexures.Pb isotope data for galena separates indicate that the Pb in the vein systems was probably of local derivation. Sulfur, C, and O isotope data for mineral separates are similar to data for typical mesothermal lode gold deposits. Fluid inclusion data suggest the presence of at least three hydrothermal fluid types in the region, viz., (1) an early saline fluid which produced the argillic alteration, (2) a CO2-bearing fluid directly related to the auriferous mineralization, and (3) H2O-NaCl fluids which flowed through the Midas Pond shear zone at a lateral distance from the zone of mineralization. The mineralizing fluids are interpreted to have been CO3 -2-rich types which originated through metamorphic dehydration and decarbonation of mixed island-arc and continental crustal rocks. Gold precipitation resulted from the reaction of these fluids with the Fe-rich breccia unit. Pre-existing and simultaneously crystallizing pyrite served as loci for Au precipitation."

Jan 1, 2000

By A. A. Holland

Introduction The world's largest known deposits of natural sodium sulphate (Glauber salt), generally termed 'alkali ' throughout western Canada, are located in the Province of Saskatchewan: reserves are estimated to exceed 200,000,000 tons. These are surface deposits resulting from the recent or present-day natural evaporation of brines, in which respect they are similar to those occurring in certain other parts of the world, as in semi-arid sections of the United States, Russia, Germany and Austria. In some areas, underground deposits formed hundreds of thousands of years ago have been _encountered in drilling, and indications are that they also were formed under arid or semi-arid conditions. The master key to the formation of deposits of natural sodium sulphate, wherever they occur, is a climate, either past or present, under which evaporation exceeds precipitation over a considerable period of time. Commercial development of the Saskatchewan deposits began about thirty years ago. Previously, the demand for sodium sulphate had largely been met by salt cake produced as a by-product in the manufacture of hydrochloric acid from common salt. The rapid increase in the production of Kraft paper and, more recently, the development of synthetic detergent materials, have caused a marked increase in the market for sodium sulphate. This chemical gives the extra toughness to Kraft paper and is used in detergent compositions in proportions as high as 75 per cent. Saskatchewan now has six commercial plants producing natural sodium sulphate. Production from each in the fiscal years 1947 and 1948 is shown in Table I. The newest and latest plant is that of Saskatchewan Minerals, at Chaplin, which 1s designed to produce up to 150,000 tons of salt cake, 98.5 to 99.5 per cent pure, yearly. This is equivalent to about 24 percent of the total United States production of crude commercial salt cake for 1947.

Jan 1, 1949

By Brian Lewis

"IntroductionThe leaching method selected for the dissolving of uranium ore depends in part on the physical characteristics of the ore, as well as the uranium mineralization. There are two main methods of leaching employed in uranium circuits in North America, one being ""Carbonate Leaching"" on sandstone, and pitchblende type ores, and ""Acid Leaching"", on quartzite type ores.This chapter deals with the acid leaching of uranium ores found in the Elliot Lake area, using sulphuric acid, for the leaching reagent, and ""pachucas"" for the contactor.The basic leaching process involves the pregrinding of the ore and the mixing of the ore with hot sulphuric acid, the mixture is air agitated, the air being used to oxidize the ore as well as produce agitation. The chemical reaction is as follows: Uranium Oxide + Sulphuric Acid = Uranyl SulphateThe following equations show the actual dissolution of the ""Hexavalent Uranium"", which show that more than one ion or complex of uranium is possible.Uranium DissolutionsI. UO, + 2H-(UOJ + H,O2. (UO,) + SO, = -UO, SO, (Uranyl Sulphate)3. UO, + SO,-(UO, (SO,),)=4. (UO, (SO,),)= -(UO, (SO,),)'Test work carried out in the laboratory as well as in the plants has determined the most efficient methods of extracting the uranium from the ore. A very important factor that has to be determined during initial test work are the amount of acid consumers in the ore. Within the Elliot Lake orebodies are minerals such as chlorite schist, diabase, and basement material, all very high acid consumers, consuming up to 1000 lbs. of acid per ton of ore. Of these minerals only the chlorite schist contain any uranium at all.The following are the operating parameters that have to be controlled in the plant:I. sulphuric acid concentration2. temperature of the mixture3. agitation4. liquid solid ratio5. reaction time6. particle size of ground ore"

Jan 1, 1989

By K. E. Waters, E. R. L. Espiritu, G. R. da Silva

"Rare earth (RE) elements are essential components of emerging green technologies. The increase in demand for these applications have driven the search and development of new rare earth deposits such as the Niobec project in Quebec, Canada. This deposit consists primarily of dolomite with significant amount of RE minerals bastnäsite and monazite, the primary sources of RE elements. Due to the minerals’ fine liberation sizes, flotation is commonly used as a concentration method. To develop an efficient process, the electrokinetic properties of the minerals must be understood. In this study, the surface properties of bastnäsite, monazite (RE minerals) and dolomite (a common gangue mineral) were investigated by zeta potential measurements. These measurements are affected by various ions present in solution; for bastnäsite, monazite and dolomite, some of these ions are H+, OH-, PO43- and CO32-. Dolomite, being a sparingly soluble mineral and a primary component of the ore, may be the greatest contributor of these ions in solution in the form of CO32- ions. Thus, different sources of CO32- ions (from dolomite dissolution and from Na2CO3) were investigated. The research work aims at elucidating how these reagents may influence the minerals’ surfaces. The results have shown that dolomite supernatant and sodium carbonate greatly affect the electrokinetic properties of each minerals. The addition of dolomite supernatant have resulted to relatively similar zeta potential of the minerals; while, sodium carbonate have affected them differently. These observations could be useful in efficient flotation of bastnäsite and/or monazite from bastnäsite-monazite-dolomite system.INTRODUCTIONThe increase in the demand for rare earth (RE) elements has driven the search and development of new deposits. Out of 53 rare earth projects in the world, 19 can be found in Canada (Hatch, 2015). These include the Niobec project of Magris Resources Company in Quebec. This deposit contains a significant amount of rare earth minerals (such as bastnäsite and monazite), with carbonates (such as dolomite) as the primary gangue minerals."

Jan 1, 2016

By A. F. Banks

"IntroductionThe typical potash processing plant recovers and/ or upgrades from 10% to 20% of its production through the recrystallization process. The feed to the recrystallization section consists of preconcentrated slurries of fine crystal size that cannot be raised to the required product grade by flotation and fine dusts also of low grade and too fine for compaction feed. It produces high grade white potash crystals that can be marketed as a high grade product or blended into the flotation products to raise their grade. In this chapter, a typical leaching (dissolving) and recrystallization operation will be discussed.The crystallization process makes use of the three phase system chemistry of NaCl, KCl, and H,O. The normal potash process operates on a temperature range of 75°F to 95 °F. A three phase slurry feed to the dissolving circuits will be within that range. The potash (KCl) is dissolved by heating the slurry in the presence of sufficient brine to a temperature of 190°F to 200°F. As the slurry is heated, the potash (KCI) dissolves and the salt (NaCI) precipitates. The potash rich brine is then clarified and the salt and other undissolved solids removed by thickening. Clarified brine becomes the crystallizer feed.The hot brine is cooled in evaporative cooling crystallizers. In cooling, the potash precipitates as a high grade white crystal. Crystallization is done in multiple effects to permit energy recovery and control of the process. In a four effect crystallizer the cooling is done by recycling mother liquor counter currently through the first two effect condensors and using brine pond brine for the cooling of the last two.The crystallizer product is removed from the last effect as a slurry at normal process temperature and is fed either to its own centrifuging and drying circuit or blended with the flotation product for centrifuging and drying."

Jan 1, 1989