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By M. Sommerfeld, U. Schwarz-Schampera, B. Friedrich, D. Friedmann

The steadily growing demand for metals and their price increase at metal exchanges make the mining and utilization of marine mineral resources like polymetallic nodules, manganese crusts or sulfide deposits in the near future a viable option to potentially increase the supply of base and precious metals. For a country with low potential to mine land-based resources like Germany, the industrial recovery of metals from marine mineral resources could lead to a decreased dependency on imports. In this study, seafloor massive sulfides from the German license area in the Indian Ocean (Kairei field, Southern Central Indian Ridge) are treated to recover copper and precious metals. The aim of the project is to demonstrate the transferability of existing metallurgical techniques to the raw material of deep-sea massive sulfides. As a starting point to process this unconventional resource, samples from the Indian Ocean are chemically analyzed and mineralogical characterized. A comparison is carried out between the samples and land-based copper resources, to highlight the potential which lies in mining the deep-sea floor. This paper will show the general possibility of applying a two-stage pyrometallurgical process, based on a concentrate smelting operation, followed by a converting operation in lab-scale to the provided samples of massive sulfides. Generated slag from the concentrate smelting and the converting operation are investigated by X-ray diffraction to determine the mineralogical composition. The two-stage pyrometallurgical process is investigated by the thermochemical modelling tool FactSageTM 7.2 to evaluate the phase distribution of relevant elements between the metal, matte, slag and gas phase. The thermochemical boundaries of the pyrometallurgical process are therefore set and the results of the thermochemical study can be used as an indicator for the efficiency of an up-scaled process and the generated amount of side-streams, which need to be further treated or circulated back into the process. INTRODUCTION Seafloor massive sulfides (SMS) are the third kind of discovered deep-sea minerals besides ferromanganese nodules and cobalt-rich ferromanganese crusts (Sharma, 2017). They occur in water depths around 250–4,000 m (Koschinsky et al., 2018). SMS are characterized by a high base metal and sulfide content. They were created by fluid circulation and hydrothermal convection over time (Han et al., 2018). Commonly, areas rich in SMS are associated with hydrothermal vent fields on the seafloor (Keith et al., 2018).

Jan 1, 2019

By N. Moelans, I. Bellemans, K. Verbeken

In this work, we present a phase field model to simulate the facetted crystallization of Fe3O4 in a quaternary FeO-Fe2O3-Cu2O-SiO2 melt under different partial pressures of oxygen. An important focus in creating more realistic phase field models is the incorporation of the thermodynamic driving forces in multicomponent multiphase-field models by coupling to thermodynamic databases. The diffusion of FeO, Fe2O3 and Cu2O is considered. The ratio of FeO/Fe2O3 at the upper boundary is in equilibrium with the oxygen fugacity of the atmosphere, while conserving Fe. Two-dimensional simulations are performed with different varying oxygen fugacity in the atmosphere. For the considered composition range, the growth velocities of the spinel crystals increase with decreasing oxygen fugacity. INTRODUCTION Crystallization of silicate melts has its applications in geology, pyrometallurgy and glass making. In pyrometallurgy, the solidification of slags influences the freeze lining behaviour (Campforts et al., 2007) and the cooling of slag after tapping (Durinck, Jones, Blanpain, & Wollants, 2008). Modeling of silicate melt crystallization is frequently done on the macroscopic level, using thermodynamic equilibrium calculations to determine the fractions of all phases as a function of temperature. The Factsage software and database package (Bale et al., 2016, 2009, 2002) already proved its usefulness in pyrometallurgical applications, for example to model the phase mixture after solidification of a stainless steel slag (Durinck et al., 2008). Crystallization of phases typically results in complex morphologies on the mesoscale, e.g. dendrites or facetted growth. On this mesoscale, the phase field concept has proved to be a very powerful tool (Moelans, Blanpain, & Wollants, 2008) for modeling crystallizing microstructures, because it can treat arbitrarily complex interface shapes with minimal mathematical complexity. In contrast to macroscopic models, the diffusion profiles and crystallization kinetics can be described as well as the morphology of individual crystals. First, Kobayashi (Kobayashi, 1993) simulated a growing dendrite in a pure undercooled metallic liquid. Then, Warren and Boettinger (1995) simulated a dendrite in an isothermal system considering a binary alloy. The extension to multi-phase systems was done by Steinbach et al. (1996). This was further extended by Tiaden, Nestler, Diepers, and Steinbach (1998) to a framework with coupled diffusion and phase field equations in multi-component systems.

Jan 1, 2019

By Esa Peuraniemi, Hanna-Leena Heikkilä

Boliden Harjavalta has been operating a copper flash smelter since 1949. Thus, in 2019, the smelter is celebrating its 70th anniversary of flash smelting. Slag formation is an integral part of the smelting process; currently the processing of slag is based on froth flotation at the slag concentrator. It provides high recovery of copper but restricts slag utilization; the final copper slag is deposited in a landfill. The Harjavalta smelter commissioned a new landfill area for final slag in May 2018. This paper describes the full project from permitting to commissioning of a new landfill area. The permitting process is described comprehensively, including environmental impact assessment together with the environmental and dam safety monitoring. During the environmental impact assessment, observations on rare animals protected on European level were made as well as archaeological findings. Successful completion of the permitting allowed the construction phase to start on time. After six years of intensive work, the new landfill was commissioned in May 2018. The new landfill area provides a sustainable way to store the smelter’s slag for decades to come. INTRODUCTION Slag processing Sulphide based concentrates have always formed the main raw material stream at Harjavalta’s copper smelter. During the smelting and converting steps, the iron included in the concentrate is oxidized and fluxed using a silica-based sand. Originally, the slag was processed by using an electric slag cleaning furnace after which the final slag was water granulated. Froth flotation has been utilized for slag treatment since 1966. In the beginning, the slag was cooled in open ditches. In 1984, controlled slow cooling of slag was licenced to enhance copper recovery at the flotation plant. Today, the slag from both the smelting and converting is tapped/skimmed to slag ladles and treated in the following steps: Slag ladle transportation from the smelter to the cooling area by slag hauler Slow cooling of slag in the ladle to allow mineral precipitation Unloading the slag by tilting the ladle; causing the slag to crush as it drops from the ladle Feeding the crushed slag (-500 mm) by wheel loader to a slag concentrator’s feed funnel followed by a conveyor belt transporting the slag to the concentrator plant Crushing and grinding using lump and pebble mills Froth flotation of the valuables Recycling the slag concentrate back to the smelter feed after dewatering Pumping the final copper slag to the landfill area.

Jan 1, 2019

By L. Beiza, L. Velásquez-Yévenes

Chalcopyrite is by far the most abundant copper sulphide on Earth, but it has proved to be problematic in its processing by leaching, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface during leaching. This study is focussed on the electrochemistry of chalcopyrite dissolution in acidic chloride system, which has recently gained attention as a feasible alternative to conventional sulphate media for chalcopyrite leaching. It is well understood that chalcopyrite dissolution from mineral grains depends strongly on the solution redox potential at the mineral surface as well as the composition of the product layer that may form on its surface. The chloride ions in solution support the Cu(II)/Cu(I) couple as the primary oxidant, as they can form complexes with the cuprous ions formed, increasing the dissolution rate. Additionally, these ions increase the potential range where chalcopyrite can be oxidized. The chemical reaction that occurs on the surface of chalcopyrite in chloride solutions in the presence of cupric ions will be characterized and the coulometry of the reaction will be reported to understand what is happening on the surface of chalcopyrite. Electrochemical experiments have been carried out to investigate the behaviour of mixed potential by open circuit potential (OCP) measurement for 30 minutes using sulphuric acid at pH 1 under nitrogen at 25⁰ C. The effect of chloride was analysed at 0, 20, 50 and 100 g/L and cupric ions from 0 to 50 g/L. The potentials obtained were then used to carry out chronoamperometry tests for a period of 30 minutes in absence of cupric ions. The mixed potential did not show a significant difference with an increase in cupric concentrations in the absence of chloride. Increased mixed potentials and current densities were observed at higher chloride and cupric concentrations. Chronoamperometry tests at those potentials were used to construct a voltammogram trace which has the same trend as a normal cyclic voltammogram but with much lower current densities. INTRODUCTION As a result of the depletion of copper oxides, the leaching of copper sulphide minerals has become the focus of many studies. Chalcopyrite, (CuFeS2) which is the most abundant of copper minerals, has proved to be challenging to process via hydrometallurgy, mainly related to its refractory nature, slow kinetic rates of dissolution and the formation of an inhibiting product layer on its surface, during leaching.

Jan 1, 2019

By G. Sedelnikova, D. Kim, N. Ibragimova

"The object of this study was three samples of sulfide old tailings, which were obtained after Cu- Zn ores processing. Fine metal dissemination in sulfides as well as fine mineral intergrowth determine the refractory nature of material and low metal extraction using simple methods: gravitation 1-6%, flotation 32-48%, cyanidation 10-37%, and cause the need to use sulfide bio-oxidation to liberate gold and to recover it by heap leaching. The gold is the main valuable metal in the tailings with content 1-1.5 g/t. Heap bio-oxidation with mesophilic and moderately thermophilic bacteria was used for pre-treatment of tailings before gold heap leaching from bio-oxidation solid residues. The tailings have a low permeability < 0.3-1.2 m/day, which is caused by migration of fine particles, decreases recovery rates, and is poorly suited to heap bacterial leaching. Therefore, preliminary gold sulfide tailings with permeability < 0.3 m/day were pelletized using copper containing flotation tailings of converter slags and calcium oxide. The most gold extraction was obtained for pelletized tailings. The base metals (copper and zinc) were precipitated from bacterial solutions. Experiments have demonstrated effective bio-oxidation of all third gold sulfide tailings samples and enough high gold extraction 60-82%.INTRODUCTIONIn Russia, as everywhere, there is a trend toward deterioration in the quality of mineral resources, including non-ferrous and precious metals, manifested in lower grade and higher complexity of ores. The proportion of refractory ores is increasing, characterized by fine dissemination of metals in sulfides, intergrowth, and poor liberation of minerals during concentration, resulting in loss of base and precious metals to flotation tailings.Over the operation period, huge reserves (hundreds of million tons) of ore processing waste have been accumulated at mining and concentration operations. Because of the imperfections of the previously used ore concentration technologies, the content of precious and base metals in flotation tailings is comparable with the grades of the ores being currently processed. Therefore, old tailings can be viewed as an additional reserve of non-ferrous and precious metals. The works (DEN, 1997; Lyman, Johnson, & Guerney, 2000) demonstrate that, tailings containing sulfides (sulfur, copper, zinc, and other metals) are a potential environmental hazard since they produce acid drainage water containing toxic components. Processing those tailings would require designing an effective technology for recovering useful components and protecting the environment."

Jan 1, 2016

By Robert B. Parsons

"New Brunswick Finance Minister John Baxter pulled something out of a hat for the mining industry in April, but there is a general concensus in the industry that he should put II back where it came from.The industry has never been in the mood f or progressive rate structures, but that is exactly what New Brunswick &apos;s 1984 budget offers to this depressed sector of the economy.IntroductionThe Province of New Brunswick stunned the Canadian mining community in April with the announcement that the province&apos; s 16% mining tax rate would be replaced with a progressive rate structure effective January 1, 1984 (Table I). The proposed change, contained in the bud get papers tabled by Finance Minister John Baxter on April 17, caught the industry totally by surprise. The move to a progressive rate structure was completely unexpected for a variety of reasons:• Generally speaking, relations between the province and the industry have been relatively good, yet the industry was apparently not consulted with respect to the proposed measure and had no indication that a change of th is nature was coming. This is in stark contrast to the mood which prevailed during the major revamping of the province&apos; s mining tax regime in 1977: at that time, the industry was invited to contribute in advance to the province&apos;s plan for a new tax structure.• The new structure would appear to make th e province less competitive in terms of mining tax rates with Ontario , Quebec, and other provinces, despite indications in the past that New Brunswick is very cognizant of this competitive factor in formulating mineral policy.• A joint report in November 1978 by federal and provincial officials to federal and provincial finance and resource ministers, which was careful not to directly criticize Ontario and Quebec&apos;s progressive mining tax rate structures, recommended that provincial "" tax regimes be examined to ensure the inclusion of appropriate mechanisms to avoid the excessive taxation of cyclical type profit "" , and that ""the federal and provincial governments consider the concern over progressive tax regimes expressed by the industry and examine mining and royalty tax regimes and the income tax regime with a view to alleviating the effect of such regime on the aggregate marginal tax rate"". In this context, any move to a progressive rate structure would be viewed by many observers as retrograde."

Jan 1, 1984

By T. Crivits, I. Bellemans, K. Verbeken

In the metallurgical industry, furnace cooling is often employed to enhance furnace lifetime. Hence, the pyrometallurgical phase comes in close contact with a non-air coolant. The proximity of the pyrometallurgical phases to the coolants may lead to dangerous situations. In case of a breach of the cooling circuit, the contact between a hot and a cold liquid may cause a vapour explosion. The outcome of this vapour explosion includes a pressure wave which could result in damage to the furnace, bodily injuries or even casualties. To prevent such dramatic events, the origin of vapour explosions is currently being studied in more detail. For this purpose, OpenFOAM was used to perform Computational Fluid Dynamics (CFD) simulations. In a first step, simulations were run to get a better idea of the influence of the compressibility on the simulations. The obtained results help in getting a better insight on the need of computational power, and possible numerical errors using compressible or incompressible solvers in future simulations. In a second step, systems without vapour explosions were simulated and compared to experimental results with mercury and aluminum. INTRODUCTION Humanity started using metals for tools around the Chalcolitic (~7400 cal BC), when copper was melted in small furnaces (Radivojevic, Rehren, Farid, Pernicka, & Camurcouglu, 2017). Nowadays, metallurgy has grown into a major industry and it has become impossible to imagine society without metals. In the pyrometallurgical industry, coolants (low temperature liquids, for example water) and pyrometallurgical phases (high temperature liquids, such as slags, mattes and alloys) are typically present in close proximity of each other. The interaction between these two phases can have catastrophic consequences (Tveit et al., 2008; Ferguson & Zsamboky, 2017). A vapour explosion may occur as the consequence of the rapid evaporation and expansion of the coolant. Whereas the volume of a gas increases linearly with the temperature (approximately a factor four by heating from 100°C to 1300°C), a simple calculation of the ratio of the two specific volumes shows that evaporation causes the volume of water to increase by a factor of 1700 at 100°C and ambient pressure (Table 1 and equation (1)), a number that was also found in literature (George, Nexhip, George-Kennedy, Foster, & Walton, 2006). The volume change occurs so fast that it resembles an explosion, hence the name vapour explosion. Such an explosion at industrial scale can cause economical losses, bodily injuries or even fatalities.

Jan 1, 2019

By Gary S. Anderson

Rajant Corporation is the global leader in mining communications systems implemented a vision to develop a wireless network that is rapidly deployed, self-powered and managed, for portable or fixed configurations ? Mobile, Portable, Self-Powered, Secure and High Bandwidth. The network configures itself allowing for very rapid deployment without the time delay and personnel typically required for set-up and configuration. Rajant?s proprietary technology ?InstaMesh®? is incorporated in a device called a BreadCrumb®. Rajant has filed several patent applications on its proprietary technology and has received trademark protection on its brand names. The BreadCrumb® uses technology which allows mining, military and first responders to easily establish internet connections at remote sites or situations where existing internet communications has been disrupted. The BreadCrumb® products are standards-based Wi-Fi 802.11 a/b/g compliant, ruggedized, lightweight, portable; self-meshing and the system can be established by just turning on several of the BreadCrumb® units. The Rajant Network has evolved in the ?One Network? philosophy and has been deployed by both the military and homeland defense organizations. With multiple radios, transmitting on multiple frequencies as the same time, bandwidth is doubled, the speed of the network is enhanced, management is simplified, and manageability is made easier. Rajant has partnered with world class integrators and partners, including ten CAT dealers, a world-wide mining technology company, a mining and construction software company and leading technology innovators in mining automation and operations. Recently, Rajant provided a significant network to Rio Tinto?s Iron Ore of Canada Mine in Labrador City, Newfoundland, Canada, Kennecott Utah Copper Mine, and is currently the wireless standard at Peabody Energy and several mines in Australia. These networks range from 20-250 BreadCrumbs®. The result is a meshed mobile broadband network capable of operating in a vast open pit active mining space. Simultaneous applications currently running on these BreadCrumb® networks in the mining sector consist of Caterpillar?s VIMS?s, CAESultra grade control and Aquila Drill Management Systems, Carlson Grade Control systems, Jigsaw Technologies and Modular Mining fleet management system, Ground Probe Radar, an Automatic Train Operation and various video and VoIP applications. All vendor applications have been turned off and all applications are running on Rajant?s ?One Network?.

May 1, 2010

By A. Mular, T. Bond, G. D. Farnell, J. F. Kingston

"ABSTRACT:-A 60—cm semiautogenous grinding-(SAG) mill was designed -for continuous wet operation in closed circuit with a vibrating screen. The circuit is fully instrumented and automated. Part of the control system incorporates Foxboro SPEC 200 controllers around the pump box to maintain level. The rest of the control system involves an ACTION model BC2 basic direct digital controller that handles all other inputs/outputs and contact closure sensing:·The success of the control system is attributed to the uniqueness of specially designed mass flow metering systems. Various control strategies are possible. Employed to date has been control of a mill load set-point by cascading the deviation from load set-point as the set-point to the fresh feed rate ""controller"". Mill feed water is ratioed to total flow rate of solids fed to the mill. The performance of the circuit is being correlated with the performance of full scale SAG circuits in British Columbia to develop models, to assess the feasibility of scale up and to investigate the effects of design variables on responses such as circuit throughput. 1 INTRODUCTIONWhere ore types are appropriate, semiautogenous grinding and/or autogenous grinding (AG) has replaced conventional grinding. Secondary/Tertiary crushing plants are thereby eliminated so that capital expenditures are less and overall comminution costs can be lower (Barratt 1982). To establish the suitability of an ore for SAG circuits, pilot scale tests with 1.7 to 1.8 M diameter mills are often conducted. At least one test per ore type in a deposit has been necessary. Often, each test involves a large amount (up to 50 tonne) of sample, so that the testwork can be expensive and may discourage the use of SAG or AG circuits. However, MacPherson (1977) has employed a continuous 45 cm dry Aerofall mill circuit closed with screens and an air classifier to determine whether ores are suitable for SAG milling. The amount of sample per ore type is of the order of 60 kg or less. Thus an established SAG mill scale up procedure that employs small circuits is highly desirable.The purpose of this paper is to describe a small 60 cm wet continuous SAG/ AG mill pilot circuit assembled at the University of British Columbia to study the feasibility of scale up, to assess the influence of design variables, to develop mathematical models and to evaluate the effects of alternative control strategies on circuit performance"

Jan 1, 1988

By A. Roca, V. A. Quezada, O. A. Benavente, M. Cruells

The leaching pretreatment of copper ores is widely used in the Chilean mining industry. Agglomeration and acid curing have been identified as the most useful pretreatments. Of these, acid curing was recognized as beneficial in the dissolution of copper minerals, even in sulphides such as chalcopyrite. Extensive acid curing times have an impact on copper extraction, generate a homogeneous acid distribution in the mineral bed and benefit the inhibition of aluminum-silicate minerals (acid consumers). This document describes some of the theoretical background and results regarding the effect of acid curing in a chalcopyrite sample with 74% purity according to Qemscan analysis and a 28.5% of total copper. Leaching tests are carried out at 25, 50 and 70°C, evaluating the effect of a pretreatment on the chalcopyrite dissolution. The original sample and products generated were characterized by X-ray diffraction analysis and Scanning Electron Microscopy (SEM). The performed experiments indicate a direct relation between the effect of curing time and temperature in copper extraction. 92% of copper can be extracted in a leaching at 70°C and with 15 days of curing. Elemental sulfur, jarosite and copper polysulfide (CuS2) have been detected in leaching products. INTRODUCTION The copper extraction from minerals is a technique that has been developed for hundreds of years in the world. In 2017, the largest copper producer was Chile, exported 5.5 million tons (COCHILCO, 2018). However, in order to preserve this production level means overcoming multiple challenges. In the case of the Chilean copper deposits, the average copper grade in 2016 was 0.65%, lower than the 1% declared in 2004 (Consejo Minero, 2018). This is mainly due to the deeper of the deposits reaching sulfide mineral zones, mainly chalcopyrite. Traditionally, these sulfurized zones ore are treated through concentration by flotation and subsequent pyrometallurgical treatments. However, for some copper companies it is complex to process by this alternative, due to the high costs and high rates of water consumption. The mineral resources of these companies are known as "low-grade sulfides" and do not allow, economically, the treatment of these minerals through concentration by flotation. This is how hydrometallurgy becomes an alternative for the treatment of this type of deposits. In addition, several companies have hydrometallurgical plants, which would allow the operational continuity of these plants.

Jan 1, 2019

By D. C. Brady

"Within six months from award of a project management contract, Les Mines Dumagami Limitée, Cadillac, Quebec, was operating its new hoisting facility. This was accomplished with less than a six-week shutdown of mine production while still maintaining shaft access for underground maintenance.The work involved installing a refurbished /3.5 ft diameter double drum hoist, replacing a timber headframe with a newsteel headframe, increasing the ore bin capacity from 500tons to 1000 tons, constructing a new substation, and upgrading related facilities.This paper describes the work and methods used by various contractors, Les Mines Dumagami Limitée and J.S. Redpath Mining Consultants Limited to bring this project to a successful completion. It discusses the history of the project from proposal stage through to the design, procurement, scheduling, and construction management. The paper also comments on problems that were encountered and the methods used to overcome them.IntroductionThe Donald J. Laronde Mine of Les Mines Dumagami Limitée (Dumagarni), a gold and copper producer, is located in northwestern Quebec, approximately half way between Val d&apos;Or and Rouyn. The mine started production in the spring of 1988 and the first gold bar was poured in June 1988.Following a request by Dumagami, on February 22, 1989, J.S. Redpath Mining Consultants Limited(Redpath) delivered a proposal to increase hoisting capabilities from 1500 tpd to a minimum of 2500tpd. Although various concepts were considered, Redpath proposed a new hoist house along the same shaft axis as the existing hoist, and located on the site of the existing substation. They would then provide a new substation, replace the headframe with a largersteel structure , gain extra storage capacities by increasing the bin heights, and raising the roof of the bin house accordingly.Although underground mining would have to be stopped for a month, the mill production would be maintained by feed from Dumagami&apos;s open pit.Figure 1 shows the original plant layout and Figure 2 represents the general arrangement after the project was completed . Table 1 compares the original hoisting facilities to the new facilities.On March 2, Dumagami awarded Redpath a contract that included preliminary engineering, detailed engineering, procurement and contract administration, and later added construction management. The preliminary engineering refined the initialconcept, selected major equipment, and prepared schedules and capital cost estimates for the total project."

Jan 1, 1991

By M. K. Walter

"The underground operations of Kidd Creek Mines uses an average of 450 U.S. gpm water during regular operations, and discharges an average of 800 U.S. gpm through consecutive staged pumping lifts of 1200f t.Water is used as a flushing medium for the drilling operations and as a dust suppressant for drawpoint mucking. The water retains an average of 5% suspended solids by weight which is removed underground before being pumped to the surface. This paper outlines the treatment of the mine water for the removal of suspended solids which are chemically treated to settle out as a sludge product of 60% solids by weight. This process reduces the sludge handling operation by 50%. The sludge is systematically disposed into the ore passes.IntroductionThe Kidd Creek minesite, located 27 km north of Timmins, Ontario, produces 4.5 million tonne s of copper, lead, zinc and silver ores annually from its No. I and No.2 underground mining operations. Both mines use a sublevel blasthole stoping method of extraction.Water from the underground operation passes through a series of surface settling ponds, where it is treated to remove heavy metal ions from solution. A blend of the pond effluent with fresh water from Kidd Creek, supply the underground with water at an average rate of 450 U.S. gpm. Water flows from the production zones through coarse sumps and into a main pumping station. There are five main pumping stations underground, three in No. I Mine and two in the No.2 Mine.The No. 2 Mine pumping stations are located on the 4800 level and the 3600 level. All water below the 3600 level to the shaft bottom is controlled from the 4800 pumping station. The water from the 4800 pumping section is combined with water from the remaining levels of the No.2 Mine at the 3600 pumping station. Water from the 3600 pumping station is pumped to the 2400 pumping station in No. I Mine.The No. I Mine pumping stations are located on 2800, 2400, and 1200 levels. All water below the 2400 level to the shaft bottom is controlled through the 2800 pumping station. This water is pumped to the 2400 pumping station. The 2400 pumping station also controls the water below 1600level to 2400 level."

Jan 1, 1988

By Gordon E. Agar

"The effectiveness of two this compounds for copper sulphide depression in molybdenite flotation has been examined with batch bench scale tests.Both thioglycollate and trithiocarbonate proved to be good depressants producing results similar to those f or cyanide and hydrosulphide. Ferrocyanide was ineffective on the samplematerial tested.The depressing effect of thioglycollate was readily reversed by an addition of xanthate.IntroductionThe separation of molybdenite from copper sulphide minerals has been practised for a long time(1,2). The predominant scheme is to depress the copper sulphides while capitalizing on the ready floatability of molybdenite to effect the separation. There are many recipes for depressing the copper minerals(3), among them the addition of sodium cyanide, particularly if the copper is present primarily as chalcopyrite; some form of sulphide whether as sodium sulphide, sodium hydrosulphide or phosphorous pentasulphide when there is a mixture of copper sulphides such as bornite, chalcocite and chalcopyrite; potassium ferro cyanide may be used when chalcocite is the principal copper sulphide; peroxide or hypochlorite; as well as heating in the presence of lime. There are different mechanisms by which these reagent s depress the copper sulphides. Sodium cyanide and the sulphide-producing compounds apparently reduce the potential of the copper sulphides to the point where they ar e rendered unfloatable by xanthates . Another study(4) showed that after cyanide addition, chalcopyrite was rendered un floatabl e until the REDOX potential (measured with a gold electrode with a saturated calomel reference) had become more positive than -250 mY. If the chalcopyrite pulp was conditioned after the cyanide addition the REDOX potential increased slowly, whereas if air was introduced during the conditioning the potential r ose much more rapidly. The difference in time to reach the desired level of - 250 mV was as much as 20 minutes&apos; 25 minutes being required when air was absent but less than 5 minutes when air was admitted . These observation s demonstrate some of the problems encountered when using cyanide to depress sulphides such as chalcopyrite . The system adjusts to counteract the depressing effect of the additive. To overcome this tendency it is necessary to either add an overdose at the beginning or to more or less continuously add the regulating reagent. In this study cyanide solution was added under automatic control to maintain a specified REDOX potential."

Jan 1, 1984

By R. J. Mitchell

"High narrow backfills of significant strike length approach the stress conditions associated with a free standing wall but this lower bound design approach is not considered efficient for earth structures. This paper considers the design of high narrow backfills using upper bound limit analysis, retaining wall theory with backfill arching and centrifuge model tests. Complex toe support situations pertaining to operational factors at Falconbridge&apos;s Lockerby Mine are investigated. It is shown that the susceptibility of high narrow fills to toppling is much lower than anticipated from the retaining wall analysis and that toppling can be avoided by a suitable toe support. It is also concluded that adhesion between the fill and an adjacent pillar can markedly increase the stability of the fill. INTRODUCTIONFalconbridge&apos;s Lockerby Mine pillar projects will expose cemented tailings backfills to heights (H) up to 55 m. The exposed backfills may have strike lengths (L) greater than the heights but are relatively narrow, having widths (w) of up to 12 m. The bulk cement content of the fills varies from 8.3% (12.1 T:C) to 3.0% (33.1 T:C). Exposed faces may have up to a metre of overhang due to stope overblasting, as shown in Figure 1. These fills have a solids specific gravity of close to 3.0 and were placed at a pulp density of about 68%. The tailings have a fairly uniform grain size with 32% less than 0.075 mm (200 sieve) and about 12% slimes (less than 0.02 mm sizes). The fill exposed by early pillar removal will be backed by adjacent, near vertical, ore pillars. Future pillar removal may expose similar fills which are not supported by an adjacent ore pillar but which will be backed by either an open void or by uncemented backfill. Furthermore, these fills may be undercut when the pillar slot is driven, further reducing stability (case 3, Fig. I) or a wedge could be left to help support the fill (case 2, Fig . 1). This paper presents limit equilibrium analyses for these various backfill conditions in a 22: 1 T:C fill and com- pares the results to data from centrifuge model studies at a scale factor of A= 157 as indicated in Figure I. Prototype fills have a 6 m deep cone plug of 16:1 T:C which is accounted for in the comparison of centrifuge model test with analytical results."

Jan 1, 1989

By Eric D. Jamieson

"How well is the Canadian coal industry able to expand in the tough competition with other fuels in Canada and with other suppliers in the international, metallurgical and thermal coal trade? Coal production as a whole decreased between 1950and 1960 and, although there has been a tripling of production since then, underground production continued to decrease until 1975. This trend has been reversed to a certain extent as a result of the modernization of mines in Cape Breton, but in 1978 over 85% of coal production came from surface mining.Against this background, the paper reviews current Canadian mining operations as described in papers presented at the 1979 CIM Annual General Meeting. Conclusions are then drawn regarding some of the longer-term mining applications in relation to the latest coal demand forecast, which indicates a potential Canadian production requirement of 160 million tonnes per year by 2000. IntroductionThe Canadian &apos;coal industry is experiencing a period of expansion and a new record for production is set with each passing year. This growth pattern over the last IS years has been based on two main markets-the generation of electricity in Canada and the export of coking coal to Japan. Supply to those markets has entailed either the development of mining, coal preparation and transportation systems for the delivery of large volumes of products with predetermined specifications or the establishment of minesite plants designed specifically to suit the characteristics of the coal in the adjacent deposits (Fig. I).Coal is a low-value commodity in relation to its bulk, and the economics of coal use become progressively less attractive with increasing distance from the producing mine. The transportation component in the export trade and in the movement of western coal to Ontario is a major cost factor. In the latter case, it approaches the cost of coal produced at the mine. In addition, the .international competition among coking coal producers chasing diminishing markets in a worldwide steel recession as well as the competition from U.S. coals and other fuel s for Canadian thermal coal have introduced a tight set of parameters to govern mining practices in all parts of the country. Some appreciation of the required changes in mining techniques brought about by declining traditional markets and the rigorous demands of the new bulk markets can be gained by comparing production from surface and underground mines over the past 25 years (Fig . 2)."

Jan 1, 1980

By Orlando Rojas, Javier Pizarro, Romke Kuyvenhoven, Francisco Soto

"The concept of geometallurgy has been extensively mentioned and used in the mining industry in the past years. However, each mining firm has a different understanding of what geometallurgy means, and its actual value varies significantly from site to site. Even in the case of properly constructed geometallurgical models, it is fairly common to observe a sub-utilization of the model in the actual operation, because of its low production forecasting capability on the short term. This disconnect between the geometallurgical model and operations is typically caused by a lack of tuning between the original model and the actual plant operation. Also, the absence of procedures and other standards for reconciliation, affects the confidence and the predictive quality of the model. The geometallurgical model should consist of three different levels: (I) adequate capture of information, (II) data analysis and modelling, and (III) development of the block model. Once the geometallurgical in-situ model is finalized, a process model should be developed of the plant at industrial scale, in order to scale up the in-situ geometallurgical parameters from their base or standard condition, to the actual operating reality of the plant. Finally, the stage of reconciliation will close this process, assuring that any deviation between the geometallurgical model and the actual plant operation is not due to lack of tuning, but due to operational issues such as unattended maintenance requirements or poor process control in the operation. The methodology as described in this paper has been applied at several large mining sites in Chile. The paper presents the characteristics of the proposed methodology, and quantitatively describes its benefits with examples from actual operations.INTRODUCTIONIt probably is fair to say that geometallurgy became widely used in greenfield projects in the Andes region during the mining boom of the 90’s, when massive orebodies were studied and developed, and upfront metallurgical characterisation proved its use for accurate economic evaluation including estimates of plant throughput, energy consumption, final product quality and overall recovery. A few examples of such greenfield studies for concentrator plants in the 90’s are Minera Los Pelambres (Antofagasta Minerals, Chile), Minera Escondida, Laguna Seca (BHP Billiton, Chile), and Rio Blanco (then Montterrico Metals, Peru). Large size hydrometallurgical operations such as Cerro Colorado, Quebrada Blanca and Lomas Bayas (all in Chile), also recognised early on the importance and value of relating ore mineralogy, geological characterisation and metallurgical behaviour."

Jan 1, 2016

By D. L. Mckay

"Texasgulf&apos;s 25-foot-diameter Kidd Creek No. 2 Shaft is situated next to the company&apos;s No .1 Shaft, so that both shafts can share common surface and underground facilities. Shaft construction, covering a span of five years from collaring to commissioning , started by freezing the 50 feet of grey varved clay covering the bedrock. After first completing the concrete headframe, sinking to the 5/00-foot horizon utilized two different shaft construction methods. The top 2800 feet was excavated by slashing a 6-foot-diameter borehole and hoisting the broken material up the 3OO0-foot-deep No.1 Shaft; the remaining 2300 feet was excavated by conventional benching methods. Prior to installing the 5100 tons of galvanized shaft steel on the completion of the sinking operation, the sinker was able to install all thirteen armoured electrical cables in one pass with his modified galloway stage. All loading and lip pockets were installed along with the steel guides and bun tons during the equipping operation.IntroductionOn November 21,1978, Texasgulf completed the No.2 Shaft at Kidd Creek Mine. This shaft is the largest shaft (volumewise) in North America and is unique in many respects . The purpose of this paper is to outline some of the unique features of this shaft as well as to record how this facility was constructed.Soon after sinking No.1 Shaft, Texasgulf started a program of exploratory diamond drilling from the 2800 level in No. 1 Mine. The drilling outlined sufficient ore below that level to justify a second mine. Feasibility studies demonstrated that production could be increased by one-third exclusively from this deep ore . The study called for a 25-foot-diameter shaft to the 5100-foot horizon to service a mine producing 5,000 tons of ore per working day.The site chosen for No.2 Shaft and head frame is 350 feet southwest of No.1 Shaft. This, along with No.1 Shaft, will be away from the influence of ground subsidence when mining at depth. The collar and head frame foundations are located on a flat rock ledge some 70 feet below surface. This flat ledge was found by test holing through the overburden by diamond drilling. It is fortunate that this location best satisfied the surface layout and logistics for both surface and underground ore and waste handling."

Jan 1, 1981

By J. R. Goode

"The Las Cristinas deposit in Venezuela contains reserves of 12.8 million ounces of gold at a grade of 1.20 g/t (Crystallex, 2004). The deposit comprises fully oxidized saprolite (SAPO) overlying a layer of sulphide-enriched saprolite (SAPS) which lies above carbonateleached bedrock (CLB) and carbonate stable or un-leached bedrock (CSB). Gold occurs at about the same concentration in all lithological groups. The bedrock units contain minor amounts of copper (about 0.1%) as chalcopyrite, while SAPO contains virtually no copper which has been leached and deposited in the SAPS zone.A previous owner began investigation of the Las Cristinas deposit in 1991. Over the next seven years, the company drilled 1,174 holes with a total length of 159 km, conducted extensive metallurgical testwork, including pilot plant operations, and completed feasibility studies. Construction was started in 1997 and again in 1999, however, on each occasion was suspended.Crystallex has been producing gold inVenezuela since the early 1990s. In 1997, Crystallex acquired Inversora Mael which had held two of the claims to the Las Cristinas concessions since 1986. In September 2002, Crystallex entered into a definitive agreement with the Corporación Venezolana de Guayana (CVG) to develop the Las Cristinas deposit.An extensive program of studies and testwork was started in late 2002 to determine an optimum development plan for Las Cristinas. Mine Development Associates, SNC–Lavalin Engineers and Constructors, SGS Lakefield Research Limited, J.R. Goode and Associates, and A. Laplante at McGill University acted as the main contractors.Because of the potential value of by-product copper, earlier flowsheets used carbon-inleach for SAPO, but processed all other ore types by flotation to produce a gold-copper concentrate with cyanide leaching of cleaner tailings to maximize gold recovery. Cyanide recovery was necessitated by the high copper content of the leach feed. Initial studies of available data by Crystallex revealed that direct leaching of all ore types would provide about 11% more gold recovery than the previously selected flotation route with reduced capital and operating costs.Bench and pilot-scale studies have confirmed that a SAG-ball mill-gravity-CIL route is very effective for all ore types and will give about 89% gold recovery. This paper describes the testwork conducted in 2003, discusses a 20,000 t/d plant design, and presents economic data."

Jan 1, 2005

By M. Massinaei, S. Abasi, M. Oliazadeh

Reliable measurement and control of the pulp-froth interface (froth depth) in the flotation columns is critical to achieve the desired metallurgical performance. Shallow froths result in a reduction of grade because of particle entrainment and deep froths reduce recovery because of the drop back of entrained and weak hydrophobic particles to the pulp zone. The cleaner circuit at Miduk copper concentrator consists of three parallel MicrocelTM flotation columns 4 m in diameter and 12 m in height. The interface level of the flotation columns is measured by two pressure sensors located at 1.4 and 2.4 m from the cell lip (in the collection zone). In this study the performance of the level detection system at different operating conditions was evaluated. A calibrated float-ultrasonic location system was used for measuring the actual froth depth. The results indicated that the existing level control system was subject to considerable error. The absolute error was found to be 33.27 cm. This was mainly attributed to the constant set-point value assigned to the froth density (ρf=0.3 g/cm3), which actually varies with the operating conditions. The actual froth density at different conditions was calculated and its average value (ρf=0.12 g/cm3) was re-set in the control system. This resulted in substantial reduction in the level-detecting error. Recommendations for more accurate measurement of the interface level were presented. INTRODUCTION Froth flotation is a complicated process because of many involved variables. One of the most significant controlled variables in the flotation process is the pulp-froth interface (froth depth). The froth depth has a profound influence on the metallurgical performance parameters (i.e. grade and recovery). Shallow froths result in grade reduction because of particle entrainment and deep froths reduce recovery resulted from the drop back of entrained and weak hydrophobic particles to the pulp zone (Finch and Dobby, 1990). Various techniques have been developed for measuring the interface level of the flotation cells in the last few decades. These techniques can be classified as: Techniques based on hydrostatic pressure measurements (Finch & Dobby, 1990), Techniques based on the density gradient (float) (Moys & Finch, 1988), Techniques based on conductivity measurements (Uribe-Salas, 1991), Techniques based on temperature measurements (Moys & Finch, 1989).

Jan 1, 2019

By G. S. Dobby, J. A. Finch

"I. INTRODUCTIONA significant development in flotation over the past few years has been the increasing industrial use of flotation columns, primarily in Canada. The column differs dramatically from conventional mechanical flotation machines, both in design end operating philosophy, which has been a principal reason for its slow acceptance by the mineral industry. Boutin, Tremblay and Wheeler (1. 2) developed the concept in the early 1960's and since then plant and laboratory columns have been marketed commercially by Column Flotation Company of Canada Ltd. In 1980-81 at Mines Gaspe, Quebec, three columns replaced 13 conventional cleaners in a molybdenum upgrading circuit, with superior results (3). Since then many of the copper producers in British Columbia have installed columns for copper and molybdenum cleaning, including Gibraltar, Lornex, Highmont and Island Copper. There now appears to be widespread interest in flotation columns.The column is particularly attractive for applications involving multiple cleaning stages and can upgrade In a single stage compared with several stages of mechanical cells. This results in simpler, more controllable circuits. Importantly, the column itself is well suited to computer control. A significant problem, however, has been that of translating laboratory data to plant performance. The purposes of this communication are to address the problem of column scale-up and to describe some of the transport mechanisms of a flotation column, leading to a kinetics based model.A schematic of a flotation column is shown in Figure]. Industrial columns are up to 13 m high and 0.3 to 1.8 m in cross section (either square or circular). Three zones can be identified:a collection zone, with feed entering 2 to 3 m below the top of the column and descending against rising bubbles generated at a gas sparger; a washing zone, where a packed bubble bed is generated by a downward flow of wash water; and a conventional froth (2 - 5 cm thick), the sole purpose of which is particle transport to the launder. The tailings withdrawal at the bottom of the column is controlled at a rate slightly greater than the feed flowrate (called a positive bias).An important element is the washwater, added just below the froth zone. The component of the washwater that flows downward (to make up the bias) is sufficient to prevent coalescence of rising gas bubbles. The packed bubble beg so generated is very efficient at suppressing gangue entrainment to the concentrate."

Jan 1, 1985