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By Gonzalo Díaz, Diego Mesa, Willy Kracht

"It is well known that frothers affect the amount of water that is transferred to the froth, which has an effect on both the froth stability and the water recovery. On the other hand, since non-selective recovery by entrainment is directly related to water recovery, it can be said that frothers have an indirect effect on flotation selectivity. Recent research on this subject has shown that the non-selective recovery by entrainment, which is characterized by the entrainment factor, is frother dependent. In other words, the entrainment factor is not unique, but depends on frother type.Having different entrainment factors implies that for the same water recovery, the amount of undesired particles reporting to the concentrate may vary if one changes the frother type, which suggests, as a possible explanation, that it is not only the amount of water in the froth what is affected by frother type, but also the froth structure.The purpose of the current work is to study the effect of frother type on foam structure (two phase froth). A quasi-2D cell operated with a slot sparger was used to study the foam structure in the presence of three different frothers: Methyl Isobutyl Carbinol (MIBC), OrePrep®549, and Octanol at the same gas flow rate and reagent dosage. The foam structure was studied using image analysis, and an algorithm based on textural analysis was developed to classify the foams. The results show that it is possible to classify foams according to the frother used, which proves that frothers have an effect on the foam structure.INTRODUCTIONFrothers are usually dosed paying attention to froth stability, condition that is commonly estimated by sight, according to the operator's criteria and experience. This happens because there is not an established procedure or technique for frother characterization, generating qualitative descriptions such as “powerful” or “selective” frothers, which lack of scientific thoroughness and remain under subjective factors. Nevertheless, several works have been done in this line of research. Moyo et al. (2007) classified frothers based on their water-carrying capacity, proving that this characteristic is related with gas holdup and frother type. Previously, Trahar (1981) had related water recovery and gangue particles recovery, defining the entrainment value (ENT). Nowadays it is known that entrainment affects both hydrophilic and hydrophobic because it is not a selective process. In the last decade some studies (for example the one of Konopacka and Drzymala (2010)) delved into different entrainment behaviours dependent mainly on the flotation type (batch or continuous, agitated or columnar, etc.), but there were no studies on the effect of frother type regarding entrainment, since Rahal et al. (2001) argued that the ENT factor was independent of the frother type and concentration, and froth height."

Jan 1, 2016

By C. P. Jenney

"Exploration for copper, in a region of 7,000 square miles on the Arctic coast between longitudes 114 and 118 degrees west, has covered a period of nearly 200 years. Occurrences of native copper, used by the natives for tools and weapons, have been reported since the early part of the eighteenth century. In J 771 Samuel Hearne of the Hudson's Bay Company, in the course of his classic 3-year journey from Fort Churchill, became the first white man to see the deposits, and incidentally the first to reach the Canadian Arctic coast by land. During the next 140 years the deposits were mentioned by every explorer and traveller who passed through the area. A good historical summary of this literature has been presented by Tyrrell (1912).In 1911-12 the Douglas-Sandberg party did the first geological mapping along the Coppermine River and Dismal Lakes (Douglas, J., 1913; Douglas, G. M., 1914), and described the copper occurrences there. In 1914 J. J. O'Neill (1924) of the Canadian Arctic Expedition investigated the showings on Bathurst Inlet. In 1929-31 two Canadian exploration companies sent prospectors and geologists to the area (Gilbert, 1931; Norrie, 1931; Duncan, 1931). Since that time only brief references have been published (Kidd, 1931; Stockwell and Kidd, 1931; Lord, 1941, 1951; Washburn, 1947). In 1943-45 an area of more than 1,500 square miles was prospected by American Metal Co. of Canada, Ltd., under the direction of the writer. Forty-nine showings were examined; seven of these were mapped in detail by plane-table and two were sampled by 27 short diamond drill holes totalling 3,061 feet. All holes were in permanently frozen rock, and the deepest vertical distance reached was 206 feet. Five groups of claims were staked. These later lapsed, but one of the groups was restaked in 1951, and assessment drilling and some trenching were carried out in 1952-53. Results were disappointing, and the claims have been allowed to lapse.The area is within the Arctic Circle, northeast of Great Bear Lake and 360 miles north of Yellowknife on Great Slave Lake. For exploration purposes, access is by aircraft from Yellowknife. During the short open season heavy freight can be brought by sea to Coppermine at the mouth of the river, either from Aklavik at the mouth of the Mackenzie or around Alaska. Concentrates would have to be moved by these routes.Although none of the deposits so far found is mineable under present conditions, the total volume of copper in the numerous showings marks the district as a major area of copper mineralization, which may some day be of economic importance."

Jan 1, 1949

By W. Dziurzynski, St. Wasilewski, T. Palka, A. Krach

"Air parameter monitoring systems, regardless of gasometrical protections, provide a significant number of measurement data. The obtained data broadens the knowledge on processes taking place in underground workings and shows the relationships and influence of machines and technological processes on the variability of ventilation parameters in the areas of longwalls. Nowadays, computer simulation methods are increasingly used to reproduce the flow of air and methane mixture in the area of longwalls equipped with shearers. The paper presents the results of a research experiment covering a long-term observation of a longwall area during mining with a shearer using sensors from the mine's monitoring system. Data from sensors for methane concentration, pressure and velocity were used and additional ventilation measurements were taken to determine the parameters characterising the air flow in the area. The influence of different machine cycles in the longwall on the changes of air parameters in the area of the longwall was shown. A numerical model of the ventilation area was developed and the computer program VentZroby was used for the calculations, which allows for the simulation of the process of ventilating the area of the active longwall during the extraction of coal with the use of a shearer and haulage of the run-of-mine. Computer simulation of the influence of the shearer's operation and the methane inflow associated with the distribution of the mixture of air and methane was carried out. The results of the simulation were compared with the data recorded by the monitoring system’s sensors during the measurement experiment. Comparison of the recorded methane concentration courses with the results of a computer simulation of the air and methane flow conditions in the mining area showed changes in the gassiness. INTRODUCTION Studies carried out in the Polish and global mining industry show that methane is an obvious factor in limiting mining production due to the loss of continuity in the operation of longwall complexes in hard coal mines under methane emission hazard (Schatzel et al., 2008). In addition, methane hazards have a significant impact on the safety of the operators of machinery in the longwall. The requirements of Polish regulations and the practice of safe operation of mining longwalls require correct determination of gas concentration, volume flow, as well as pressure and temperature of the flowing air. As part of the research undertaken in the Budryk (Wasilewski, 2010) and Bielszowice (Dziurzynski et al., 2009) mines to assess the methane hazard in the longwalls and workings in the vicinity of the longwall, research experiments were carried out, during which air parameters were recorded by the mine monitoring system and additional testing equipment in different cycles of shearer operation."

Jan 1, 2019

By CH. Liu, H. X. Jiang, X. Xiao

"A study has been conducted to characterize the fatigue life in 7050-T7451 thick plate by the comparison between an experimental alloy and commercial alloy. The fracture origins were specified and their sizes were measured by scanning electron microscope (SEM). Additionally, the size, number density and spatial distribution of porosity in the experimental material and commercial material were characterized and compared, using X-ray Computed Tomography(XCT). The results showed that microporosity was the predominant site for crack nucleation and subsequent failure of the experimental alloy. However, as for the commercial alloy, fatigue cracks were found to originate from constituent particles. The presence of microporosity in 7050-T7451 thick plate reduced fatigue life of an order of magnitude or more compared to the commercial alloy. The relationships between size of origin and fatigue life were proposed. It was showed that the fatigue endurance was reduced when the size of porosity increased.INTRODUCTION 7xxx series aluminum alloys, due to their combination of high strength, high resistance to stress corrosion cracking, and good fracture toughness, are widely used in structural engineering applications where high-strength and low-density characteristics are fundamental design requirements (Williams& Starke, 2003). Every designer is striving to find an optimal combination of properties including strength, corrosion resistance and fatigue resistance (Wanget al., 2016). Based on the design principles of aircraft, a higher fatigue resistance of aluminum alloys are required. Thus, many investigations have been carried out on the microstructures and its effect on fatigue properties of the 7xxx series aluminum alloy (Robson, 2004; Schubbe, 2009).Microporosity, which is a common defect in casting materials, can lead to a significant deterioration of mechanical performance and fatigue resistance, especially in the high alloyed 7xxx aluminum alloys. The actual valid loading area decreases due to microporosity, which results in detrimental effect on the mechanical properties. Many experimental studies have been conducted in this research field. Mayer et al.(2003) investigated the fatigue properties of magnesium alloys produced by high-pressure die-casting. The results show that porosity in magnesium alloys greater than0.18mm diameter may be considered as the most important material defect for high cycle fatigue and fully reversed loading conditions. Nadot et al.(2004) found that the near surface defects are much more dangerous than the internal defects. Wang et al.(2001a) used the Weibull statistics method to analysis the influence of the microporosity, oxides and particles on the A356-T6 alloy fatigue life. The results show that, the porosity is more detrimental to fatigue life than oxide films and particles. With regard to fatigue resistance, although the deleterious effect of microporosity has been generally acknowledged, a quantitative understanding between casting microporosity and fatigue life in 7050-T7451 plate is not well established."

Jan 1, 2018

By D. G. Eskin

"It is well known that it takes some time for the solid phase to completely dissolve upon melting, especially inside the defects of insoluble particles, e.g. oxides. Until then the oxides remain active solidification substrates in the case of subsequent solidification. It is also known that ultrasonic melt treatment causes grain refinement through activation and dispersion of solidification substrates (one of the mechanisms) and also accelerates the dissolution of solid metal in the melt. In this study we combine these effects and demonstrate that the introduction of an alloy rod into the matrix melt of the same composition results in significant grain refinement, this effect being increased by the ultrasonic vibration of the rod. The achieved grain size is comparable to that obtained by a standard Al–Ti–B grain refiner. All samples were cast using a standard TP-1 mould to enable correct comparison. The effect of the temperature range of the rod introduction, as well as the effect of ultrasonic vibrations are discussed.INTRODUCTION The fact that by introducing solid metal into the melt one can achieve structure refinement is rather well known. As early as in the 1930s–1950s a series of papers and patents have been published, showing the benefits for grain refinement when dissolving solid metal in the melt before solidification (Danilov and Neimark, 1938; Scheil, 1956). Later on this way of structure refinement was developed further and dubbed “suspension casting” or introduction of “internal chills” (Madyanov, 1969; Zatulovsky, 1981). The solid metal was added in a form of cut wire, cut sheet, or powder, with the resulting grain refining, elimination of columnar grain structure in ingots and castings of steel, copper and aluminium alloys. The underlying mechanisms have been suggested as (1) rapid cooling of the melt due to the latent heat consumption upon melting of the solid metal with the resultant melt undercooling and (2) introduction of many solidification substrates in the form of crystal fragments and active non-metallic inclusions (Danilov & Neimark, 1938; Balandin, 1973). A number of patents have been filed where either the same solid alloy or a master alloy with additions (e.g. Ti for Al alloy) is introduced in the amounts up to 50% (typically less than 10%) into the melt close to the liquidus temperature (Schmidt, 1966; Talbot & Soller, 1973, Krupp, 1974; Bondarev, 1979). The main reason that this technique is not widely used in industry is the possible incomplete dissolution of the solid parts introduced into the melt with ensuing inhomogeneous as-cast structure and potential defects. Also the selection of the temperature range where the technology works the best is not clear."

Jan 1, 2018

By D. Virely, M. Gasc-Barbier, J. Guittard

"The valleys of the Dordogne and the Vézère (France) have been inhabited since prehistoric times, as evidenced by the famous site of Lascaux. A few miles away, the village of La Roque-Gageac is also a very popular tourist destination (about 1.5 million tourists per year): The village is sandwiched between a massive limestone cliff and the Dordogne river. The collapse of a cave roof high above the village in January 2010 led us to characterize instability together for the cave and the whole cliff and propose a adapted instrumentation to monitor the fracture openings in the rock mass that are linked to climatic variations. Measurements have been going on and been recorded for nearly 4 years. They point out the role of thermal stress fatigue in the breakdown of the rock mass. In this paper we describe the site under study, the instrumentation and its main results. INTRODUCTIONThe phenomenon of thermal fatigue has been very little studied as far as rocks are concerned, whereas it is rather well characterized for other types of materials: Elsevier published a journal dedicated to fatigue (International Journal of fatigue). In the case of rocks, thermal phenomena and their impacts on mechanical behavior have been analyzed from a micro-structural point of view, and it is now well-known that an increase in temperature causes a dilatation of crystals (Arnould et al., 2004; Berest & Weber, 1998). This dilatation may lead to the development of inter-granular traction and compression stresses, and if those stresses are greater than fracture strength, inter-granular and intra-granular cracks may take place. On the other hand, the fatigue phenomenon (cyclic repetition of a temperature variation which is less extreme than the one that may lead to this inter-granular or intra-granular fracture) is a phenomenon which has not been much studied.The principal studies on thermal fatigue on rocks come mainly from the field of geomorphology, particularly in connection with the analysis of the evolutions of past climate that can explain the present shapes of those landforms: those studies remained essentially qualitative and not quantitative. Le Ber & Oter Duthoit (1987) proposed a thermal and thermodynamic approach to analyse the disaggregation of rock masses. This analysis is dedicated to the study of paleoclimates and was implemented to better understand the formation of slope deposits in order to propose transfer models permitting the reconstruction of the climactic conditions contemporary to their appearance. Since deterioration in the cliff only appears after several cycles, it means that it is a gradual and irreversible deterioration which leads to an increase of the « disorder ». Seen from a macroscopic system point of view, this irreversible evolution is quantified by the internal creation of entropy."

Jan 1, 2015

By K. Cybulski

Coal dust explosions still remain the main hazard in the coal mining sector, notwithstanding their relatively wide recognition compared to other hazards and the development of effective methods of prevention. Coal dust explosions are still the cause of numerous catastrophes, often leading to fatalities. Fortunately, they rarely occur, and it is for this reason that their hazardous impact is often underestimated. This problem in Poland is being exclusively solved by the Central Mining Institute, Experimental Mine Barbara. Here, basic research on the phenomenon of coal dust explosions and prevention methods is carried out, as well as investigations into the causes and circumstances of past accidents. After 15 years of no coal dust explosion accidents in Poland (1987?2002), a few coal dust explosions have recently occurred, with tragic consequences. These events have taken place not only in hard coal mines, where the presence of dangerous coal dust is the result of common production cycle, and safety measures against coal dust explosions are subject to specific regulations, but also in coal-fired power plants. This is of special concern because prior to 1987, such accidents had been been reported only for coal mines and not for coal-fired power plants. In recent years, two dust explosions occurred in Polish power facilities: the Dolna Odra and Turow power plants. In both cases, coal dust explosions occurred in the fuel supply system, but biomass dust was also involved. The explosions caused significant damage to the systems and buildings. This paper gives description and schematics of the regions of catastrophic coal dust explosions that have occurred in recent years in Poland, as well as the results of post-accident investigations, presenting the coal dust explosion hazard at the accident scene The results specify in detail the state of safety measures against coal dust explosions in light of the relevant regulations in force, including amount of deposited coal dust, content of incombustible matter in coal dust, free moisture content in coal dust, state of coal dust explosion safety zones, and state of explosion barriers. The conclusions from the site inspection and post-accident investigations presented enable us to determine locations of explosion initiation, probable ignition sources, range of explosion flames, and explosion barrier performance. A complete elimination of coal dust explosion hazard at the site of dust deposition is practically impossible to achieve. Similarly, a total elimination of ignition source, which may be related to the occurrence of other natural hazards, equipment malfunction or human errors, is impossible. The examples of tragic events that took place in Polish coal mines and coal-fired power plants highlight shortcomings and mistakes made in terms of assessment and prevention measures taken against the coal dust explosion hazard.

Aug 1, 2013

By John Lamb

"The French Mine (formerly the Oregon) is 4 miles by road south of the Nickel Plate Mine. It lies on the steep eastern slope of the Similkameen River valley at elevation 4,000 feet, between Cahill and Winters Creeks.The property was discovered in .1901 and bought 4 years later by Messrs. French and Deardorf. It was developed in a modest way by the owners and by several companies until 1947, without success. The spectacular showings of bornite and chalcopyrite in the outcrop drew attention to its possibilities for copper rather than gold. Diamond drilling by the owners in 1947 yielded several high-grade gold intersections and created new interest. In 1949 the property was purchased by Kelowna Mines Hedley Limited. Exploration drilling and geological mapping outlined sufficient ore to commence production in 1950. Except for a few months each winter the operation has been continuous, and to the end of 1954 had produced almost 30,000 tons of high grade ore. The ore is crushed at the mine and hauled 8 miles by truck to the Company mill at Hedley, where it is treated together with the ore from Nickel Plate.Regional GeologyThe country rock consists of brown tuff, flows, limestone, and cherty formations belonging to the Nicola group (Rice 1947) of Triassic age. West of and just below the mine is a large mass of granodiorite which is part of the same body that underlies Nickel Plate Mountain. Bedding attitudes in the mine area are locally complicated, but dips are generally less than 45 degrees. To the south and below the mine the beds stand almost vertical, continuing downward with this attitude for 2,000 feet to Winters Creek. The main granodiorite contact is also steep, conforming to the sedimentary formations, whereas northward towards Nickel Plate it dips gently to the northwest, slightly flattter than the thick westerly dipping pile of sediments above it. The interpretation of this structure by Billingsley (1936) is that the French mine lies near the crest of the large northeasterly trending asymmetrical anticline which contains in its gently dipping western limb the Nickel Plate orebodies. The granodiorite body conforming roughly to this shape seems to occupy the core of the anticline. Sill-like prongs of granodiorite extend upward to the east from the main mass, outcropping over wide areas at the head of Winters Creek (Figure 1). There is a possibility that overthrusting from the west, similar to that on Nickel Plate Mountain, occurs not far below the French mine.An interesting feature of the granodiorite-sediment contact is that where it dips gently westward no alteration exists in the sediments, but where it has a steep front pronounced heat effects are indicated by the presence of a thousand-foot-wide zone of reddish garnet skarn."

Jan 1, 1949

By Laurence McGonagle

"The Highland Uranium Project (HUP) is located approximately sixty miles northeast of Casper, Wyoming and is owned and operated by Power Resources, Inc. (PRI). With an annual production of680 tonnes (1.5 million lbs) U308, HUP is one of the largest uranium producers by in-situ leach (ISL) in the western world. Uranium is currently produced from four wellfields with a total flow rate of approximately 1,135 m3/hr (5,000 gpm). The carbonate leach solutions are processed by anion ion exchange at two satellite facilities located in close proximity to the wellfields. The loaded resin is transported by truck to a central processing facility for elution of the uranium. Uranium in the pregnant eluant is precipitated and washed prior to calcining.Wastewater from the satellite facilities is treated and used for irrigation at a Land Application Facility. The wastewater generated at the central processing facility is injected into a 2,750 m (9,000 ft) deep waste disposal well.When economical mining of the orebodies is complete, restoration of the groundwater is initiated. There are currently two wellfields at HUP undergoing ground water restoration. Phase I restoration consists of removal of the carbonate leach solution from the ore body. Phase II includes treating the withdrawn fluid with reverse osmosis and reinjection of the permeate into perimeter wells.Future plans include construction of additional satellite facilities at the Gas Hills Project and other economical deposits located within 240 km (150 mi) of HUP. The capacity of the central processing facility will be increased to 1,815 tonnes (4 million lbs) U308 per year by late 1999."

Jan 1, 1998

By A. E. Wraith, J. Protheroe Jones, P. J. Mackey

INTRODUCTION When Victoria became queen in 1837, that technical wonder of the 19th century—electricity— had progressed from being an exciting physical curiosity and was now a field of intense scientific investigation, invention and application. Its role in electrochemistry had been brilliantly quantified by Faraday in 1833–1834, and his earlier discoveries in electro-magnetism were to lay the foundations of electricity generation and the electric motor. In this age of electrical experiment, silver electro-plating emerged as a popular decorative art, at first using batteries to provide the deposition current, superseded by dynamos in the early 1840s. The decorative chemical and electroplating of precious metals was largely pioneered in England by the firm of G.R. Elkington and Co., founded in Birmingham by George Richards Elkington (1801–1865) in 1832, and protected by a series of patents which helped the company establish a leading position in the new field of ‘electrometallurgy’. In the same decade, the technique of electrotyping emerged, the first application of electro- forming by electrolytic deposition. Simultaneously invented by Spenser in England and Jakobi in Russia, but generally claimed for Jakobi, electrotyping involved plating a thick copper layer on to an electrically conducting mould wall embossed or incised with a pattern or profile which would consequently be replicated on the copper deposit—essentially a method of casting by electro-deposition with the mould wall as cathode. Woolrich’s invention of the low voltage magneto-dynamo in 1842 eliminated the need for batteries as a continuous source of deposition power, opening up the possibility of making more massive electroplated deposits, and by the mid-point of Victoria’s reign in 1869, the work of Wilde, Wheatstone and Siemens had produced the self-excited electro-dynamo, capable of higher voltages and yet greater deposition power. In this early Victorian period copper was extracted and refined by methods which had developed step-by-step over many decades. Only relatively rich copper ores containing more than, say, 6% Cu were economically useful, and the final copper product was far from pure. Copper production in Britain was located principally in the Swansea area of South Wales, based upon the ‘Welsh process’ of reverberatory batch smelting and refining, using locally mined coal and ore imported from Cornwall and elsewhere. Silver was an important by-product. Much of the output was exported and South Wales remained a principal supplier to the world copper market until the 1890s. It was here at Pembrey, a few miles west of Llanelli, that a new primary copper smelter was stablished in 1849 under the name Mason and Elkington, arguably to supply the Elkington company’s market for electrotype products.

Jan 1, 2019

By Masami Nakamoto

Controlled thermolysis of gold(I) thiolate complex, [C14H29(CH3)3N][Au(SC12H25)2], at 180 °C for 5 h under an N2 atmosphere produces novel gold nanoparticles passivated by alkyl groups derived from the precursor complex, the TEM photograph of which shows spherical particles with average diameter 26 nm. Since Brust et al. reported the two-phase reduction of AuCl4 - by NaBH4 to afford monodispersed gold nanoparticles passivated by alkanethiolate ligands (1), plenty of preparative investigations on gold nanoparticles (2,3) and its surface modification (3,4) have appeared, because of their potential applications in microelectronics (5). However, those preparative methods generally involve the reduction of AuCl4 - by reducing agent NaBH4 in the presence of suitable organic stabilizers such as alkanethiol (1-4), phosphane (5), quarternary ammonium salts (6), surfactants (7) or polymers (8). On the other hand, O?Brien et al. recently reported the preparation of organically capped gold nanoparticles at 190 °C, where tri-n-octylphosphine oxide and/or n-octadecylamine are used both as a reaction medium and as a passivating ligand (6), but this procedure also needs NaBH4 as reducing agent. Our strategy of novel preparative method of gold nanoparticles is the combination of reductive elimination of thiolate ligands and simultaneous attachment of organic moiety on the growing nuclei. Gold(I) thiolate complexes with ammonium cations were useful for our preparative method. We now report the controlled thermolysis of gold(I) thiolate complexes, [R(CH3)3N][Au(SC12H25)2] and [R(CH3)3N][Au(SC6H4-p-R?)2] (R= C14H29, C12H25; R?= C8H17, CH3), under an N2 atmosphere, where the powder of gold(I) thiolate complexes completely melts to afford the precursor liquid and then the liquid gradually decomposes. In spite of no use of reducing agent and solvent, reduction reaction is thermochemically induced to afford novel gold nanoparticles passivated by alkyl groups rather than by alkanethiolate ligands. Figure 1a shows a typical transmission electron microscopy (TEM) image of gold nanoparticles prepared by thermolysis of [C14H29(CH3)3N][Au(SC12H25)2] at 180 °C for 5 h, indicating a controlled growth of spherical gold nanoparticles. As shown in Fig. 1b, these spherical gold nanoparticles display the size distribution ranging from 5 to 50 nm. Although the particle size is larger than that of thiol-derivatized gold nanoparticles (less than 5 nm) prepared by NaBH4 reduction (1-3), the aggregation of gold nuclei is smoothly regulated and the growth of core gold is limited to be 26 nm in average diameter in spite of thermal procedure.

Oct 1, 2003

By B. McFadzean, I. Achaye, T. Chidzanira, J. Wiese

"Froth stability has an overriding effect on metallurgical recovery and grade for many ore types. Froth recoveries of less than 10% are common for low stability froths such as those in sparsely mineralized ores or in cells at the back end of flotation circuits. It is well known that, aside from chemical factors such as frothers and electrolytes, the mineral particles themselves have the dominant influence on froth stability. The particle properties of size and hydrophobicity are expected to have the greatest effects on froth stability. The aim of this study was to understand the effects of particle size on froth stability and to quantify these relationships.The study compared a synthetic ore of pyrite and quartz, with carefully controlled size ranges and hydrophobicity, with conventionally milled platinum-bearing UG2 ore and the bulk reverse flotation of hematite ore. A novel bench-scale continuous column flotation cell and continuous mechanical hybrid cell with large relative froth volumes, as well as a three-phase froth stability column were used to characterize the froths.It was found that froth stability could be related to the concentrate particle surface area by a Langmuir-type relationship. This is indicative that the mechanism by which particles stabilize the thin films in froths is similar to the mechanism by which surfactants lower surface tension. Different froth stabilities were found for different ores and this was thought to be the result of different particle sizes and distributions, which resulted in different packing densities in the thin films and Plateau borders. Interestingly, there was a clear relationship between the feed particle size and the froth stability even though froth stability was dependent on the concentrate particle surface area. It seems that the feed particle size is a good predictor of the surface area of particles in the concentrate. Concentrate particle size did not show a clear relationship with froth stability since it was already shown that it is both the size and the amount of the particles in the froth that contribute to the stability.INTRODUCTIONThe stability of the froth in froth flotation is important to the recovery and grade of the valuable mineral. Too stable a froth and the grade is reduced; not stable enough and the recovery may be compromised. Platinum-bearing ores with fragile, poorly mineralised froths are known to have froth recoveries that are routinely less than 10% (Crosbie et al, 2009). There are a number of chemical, physical and operating parameters that can affect froth stability, including reagent dosages, air flow rate, pulp density and particle properties. Arguably, the largest contribution to froth stability is from the particles that stabilise (or destabilise) the thin films in froths. Particle size, hydrophobicity and shape all affect froth stability to some extent."

Jan 1, 2016

By E. Ghali, W. Zhang, M. Robichaud, G. Houlachi

"The performances of six mesh and one plate dimensionally stable anodes have been investigated in the zinc electrolyte at 38oC and compared to conventional silver-lead alloy anodes. The electrochemical behaviour of these anodes was studied by cyclic voltammetry, galvanostatic, potentiodynamic, open circuit potential and electrochemical noise measurements. It was observed that at the end of 24 h of galvanostatic polarization at a current density of 50 mA/cm2 in the zinc electrolyte at 38oC, the mesh V had the lowest potential followed by mesh III, mesh VI, plate-V, mesh IV, mesh I, and mesh II electrode. When the potentials for mesh I, mesh III, mesh IV, VI and plate-V, mesh V were compared with that of the Pb-0.7%Ag anode (1920 mV/SHE), they were found to be 6%, 16%, 7% 10%, 17% lower, respectively.After 16 h decay following the 24 h polarization, the mesh III had the lowest corrosion rate (51 mS/cm2) among the seven specimens, followed by the plate-V, mesh V, VI, IV, I and II (221 mS/cm2). For the fresh surface as received, after two hour open circuit potential measurements, mesh I had the most positive (noble) potential (1382 mV/SHE) among the seven electrodes followed by the plate-V electrode, mesh V, mesh IV, mesh VI, mesh III and mesh II (751 mV/SHE). After consecutive series of electrochemical testing, mesh V, mesh III, mesh VI had lower corrosion rates (~ 343± 6 µA/cm2) than that of mesh IV, mesh I, plate-V, and mesh II (~ 644± 143 µA/cm2).INTRODUCTIONThe continued use of lead based anodes in the electrowinning process has been mainly due to their relatively low cost as compared to other materials (Msindo, Sibanda, & Potgieter, 2010). They have good electrical conductivity, stability during electrolysis, very good corrosion and wear resistance (Ivanov, Stefanov, Noncheva, Petrova, Dobrev, Mirkova, Vermeersch, & Damaerel, 2010). However, lead-based anodes give their high energy consumption and low corrosion resistance for electrowinning. To overcome these problems, Dimensionally Stable Anodes (DSAs) has been chosen (Msindo et al., 2010). Comparing to the traditional lead anodes, the DSA anodes have many advantages: (1) no contamination; (2) no loss of anode material, pure electrolyte; (3) lower gas bubble effect through special anode designs; (4) use of higher current densities (Msindo et al., 2010). The success of DSA anodes has been attributed to their chemical stability that allows them to maintain nearly constant dimensions during the life of the anode even when operating in environment with low pH values. Due to their stability, the consumption rates of DSA are as low as 1 mg/amp.y (Alfantazi & Moskalyk, 2003)."

Jan 1, 2016

By J. A. E. Bell

"Inco has shifted part of its traditional extractive research effort at its J..Roy Gordon Research Laboratory in Mississauga toward new, value-added products. Most of the effort is being expended on new Ni powders for batteries and new Ni-coated products which will be produced in Inco's carbonyl nickel refineries. New products under development are Ni-coated powders, Ni-coated fibres and ultra-fine Ni powders. Other new products for advanced material applications include controlled expansion composites, NiGOLD strip, Thermal barrier coatings on Inco alloys, and plasma coatings.Research and Corporate Strategic ThrustsThe newest strategic thru st of the company is to increase the value of the primary metal products. These new products are to be in addition to any new alloys or downstream alloy fabrication.Historically Inco has had the highest research expenditures in the extractive metallurgy field in North America. This has resulted in many new processes including flash smelting , matte separation, fluid bed roasting, pressure carbonyl refining and cobalt electrowinning which have contributed to establishing Inco as the lowest cost nickel producer. The recession of the 1980s caused a restructuring of Inco research and corporate goals .As shown in Figure I, from 1975-1982, i.e. pre-recession, Inco spent around 33 million dollars per year on research. Some 48070 of that sum was spent in Corporate Laboratories in Sterling Forest in the United States and in the United Kingdom , mostly on alloy associated research. A further 10% was spent on alloy research at the alloy production facilities in Hunting- ton, West Virginia, and Birmingham and Hereford in the United Kingdom. On extractive research, 13% was spent by process technology groups at the plant s, 20% at the pilot plants in Port Colborne and 9% at the J. Roy Gordon Research laboratory.The relative research expenditures (Fig. 2) have decreased so that today they are at the same level as 1975-80. The research as a per cent of sales has been cut from 2.2% to 1.2% of normalized sales. A normalized sale price of $4.00/lb Ni was used in the 1988 figures. This was partly achieved by closing Corporate Laboratories. Most of the essential alloy research was moved to producing plants and total alloy research is now 27%.A new thrust initiated in the 80s was mining research which now accounts for 20% of research expenditures. Over a period of the past five years this research has doubled the mining productivity in Inco. The pilot plant expenditures have been cut in half. One entire research station at Port Colborne was converted into a platinum group metals intermediate refinery. The decrease in pilot plant expenditures has been compensated by full scale plant trials devoted to the S02 abatement program at Sudbury."

Jan 1, 1990

By S. Zador

"IntroductionIn the past decade, metallurgical and mining companies have shown an increased interest in the licensing of technology. When licensing technology, it is usually to the benefit of the parties, to have at least some of the technology to be licensed protected by a patent.This paper is intended to bridge the gap between the engineer in the field of mining, metallurgy and mineral processing who is interested in exploiting an invention commercially, and the patent agent or intellectual property lawyer whom he/she might retain to prepare a patent application and then prosecute the application to obtain a granted patent. It is also intended to encourage the inventor or a small business concern to consider the value of patents in the sale and licensing of technology. The lawyer may subsequently advise and assist the inventor in licensing his/her invention.A brief outline of some of the basic features of the patent system follows. The nature of the information, which the patent professional requires from the inventor to enable him/her to draft a patent application, will also be considered in general terms. Furthermore, various types of licenses which may be drawn up between a licensor of specific technical information and a licensee, will be listed and briefly discussed. No attempt, however, will be made to give a comprehensive and detailed account of the above aspects; the interested reader should consult legal publication and reference books, and patent professionals for further specific information.A granted patent is a document which describes an invention and how to practise it. The claims of the granted patent, figuratively speaking, fence off the intellectual property the inventor regards as his invention. The Commissioner of Patents, representing the Government, grants to the inventor or his assignee the exclusive right of making, constructing and using the invention, and selling it to others to be used, for a limited period of time, in exchange for disclosing the invention to the public. Thus, a patent prevents others from practising the claimed invention but it does not, necessarily, bestow the right to the patentee to practise his own invention. The term of a patent now in Canada and in most of the developed countries of the world, is 20 years from the date of filing the patent application. In the United States the patent term is still 17 years from the date of issuance of the patent. In Canada, the term was changed to 20 years in the new Canadian Patent Act which came into force on October 2, 1989. Any patent application filed prior to that date or granted before it, retains a 17 year life, commencing at the time of grant."

Jan 1, 1991

By B. Goard

"IntroductionCemented backfill has been placed underground in slurry form in Inco Limited's Ontario Division mines since the early 196Os. The slurry was traditionally mixed on surface at between 65 and 70 wt% solids* and transported underground via gravity through a borehole-pipeline distribution system. This method of placement, while simple and dependable, has proven to be costly because of the large amounts of transport water involved.A significant quantity of the slimes buildup on mine levels is caused by the backfill water carrying cement and other fine material out of the stopes. The level cleanup and eventual pumping or hoisting of the slimes and water back to surface result in substantial indirect backfilling costs.The cement that remains in the stope is always overhydrated because of the high water cement ratios that exist. As a consequence, high concentrations of Portland cement must be added to the backfill to produce the fill strengths required for the different mining methods.Pouring backfill at these densities also demands extensive fill preparatory work in the stopes to withstand the hydraulic heads created by the slurried fill. This, along with the delays in pouring necessary to allow for water drainage, result in significant losses in productivity.These negative aspects of slurry placed fill has led Inco Limited to investigate several methods of transporting backfill underground via pipeline, at higher densities (i.e. 75 to 95 wt.% solids). Three separate transport methods are presently being experimented with by the Company's Mines Research Department. Each utilizes a different technique or form of flow transport, i.e. concrete pumping technology, high density slurry flow, and pneumatic conveying."

Jan 1, 1987

By A. Philipp, A. S. Middleton, G. A. Harron, A. B. Durham

"Basal till sampling techniques were used to search for gold mineralization in the Timmins, Ontario area. During 1978 and 1979, approximately 90 overburden sampling drill holes were completed in Murphy and Hoyle Townships to test specific geophysically defined target areas. A conventional tricone dual tube drill system, and a unique retractable tricone/rock coring system were used to various advantages.First pass till sampling at 800 to 1200 ft intervals perpendicular to ice transport direction yielded anomalous gold values in till and carbonatized quartz pyrite-rich bedrock chips, and lateritic soil. Subsequent induced polarization-resistivity surveys defined the areal extent of a pyritic carbonate alteration zone. A second pass till sampling/limited rock coring program evaluated the gold mineralization potential of the alteration zone. Diamond drilling has substantiated the till and bedrock gold anomalies. Further evaluation of this mineralization is currently in progress. IntroductionThis paper describes an integrated geochemical/geophysical gold mineralization discovery case history in Hoyle Township. This discovery is on a property jointly owned (I983) by Canamax Resources Inc. and Du Pont of Canada Exploration Limited. Exploration of the property began in 1978 by Rosario Resources Canada Ltd. and in 1979 a joint venture agreement was signed with Du Pont of Canada Exploration Limited. Rosario Resources Canada Ltd. was taken over by Amax Minerals Exploration in 1981, which became Canamax Resources Inc. in 1982.The work described in this paper deals with a gold mineralization discovery located three-quarters of a mile northwest of the gold deposit currently being readied for underground exploration and development. Further drilling is required to investigate the economic potential of the gold mineralization herein described."

Jan 1, 1987

By Neil McMillan

"By any measure of common practice, Claude Resources' Seabee Gold Mine in Northern Saskatchewan should not now be operating. Not because reserves dwindled, or grade dropped or prices weakened or technical problems arose, but because a host of unimaginable other problems beset the project, any one of which would normally have led to the mine's failure.The success of the Seabee Mine, and it is extremely successful, is a story of the vision and blunt determination of two men. Neither is remarkable in his own right but each possesses the characteristics which were necessary to forge a highly productive and profitable narrow-vein mine in the midst of the most bizarre and unpredictable events which likely have ever beset a mine start-up in Canadian history.Together, Bill MacNeill, a Saskatchewan born, former bush pilot and Ray Gagnon, a big hearted, hard-fisted, miner with 44 years of experience in Canada's underground, built the Seabee Mine.They didn't accomplish this with brilliant geology, outstanding engineering or nimble corporate manouvering but rather a stubbornness and raw common sense which likely are all too often, ingredients missing in failed projects.The Seabee Mine is 100% owned by Claude Resources, a Saskatoon based company taken over by Bill MacNeill, its current chairman, in 1982. The company is listed on the TSE and produces 1200 barrels of oil per day and about 60,000 oz of gold per year. The company has a strong balance sheet, is very profitable and has 18 million shares outstanding.The Seabee property in Northern Saskatchewan started out like many other gold exploration properties in Canada.It was discovered in the l 940's by what is now Cominco, and, while highly regarded by that company the property sat largely dormant until acquired by Claude Resources in 1985.Claude did what most junior exploration companies would do and went looking for a company with a depth of expertise to joint venture the property.That company was Placer Development who could earn a 55% interest in the Seabee by delivering a bankable feasibility study on the Project by July 1988 and providing financing to production.Placer Development was an excellent company and spent over $8 million dollars on the Seabee over a 3 year period. Unfortunately for Claude Resources, Placer Development merged with Dorne Mines in 1987 and the new merged company, Placer Dome, established a minimum production threshold greater than the 50,000 oz per year which the Seabee appeared capable of supporting at that time. Placer Dome's request for an indefinite extension of the joint venture agreement to allow it to drill off a larger ore body was rejected by Claude Resources and the Seabee Property was returned to Claude in 1988."

Jan 1, 1998

By G. Stokreef, B. R. Davis, M. Kadiyski, Alvear Montenegro, H-P. Loock, V. Montenegro

An optical probe for burner monitoring in copper flash smelting, first developed at the University of Concepcion, is being industrially tested in a collaboration between Kingston Process Metallurgy, Aurubis AG, and Queen’s University. The sensor uses fibre-optics and optical emission spectroscopy to analyze the light emitted from combusting particles in the furnace reaction shaft. Information that can be extracted from the emission spectrum includes the temperature and brightness of the flame, as well as emission lines or bands from excited atomic and/or molecular species. Laboratory proof of concept testing of the sensor was first completed in a continuously fed drop tube reactor using O2/S stoichiometric ratios between 0.8–4.0. These O2/S stoichiometries capture the industrial operating condition, which is typically less than 1. The results from lab testing justified a plant trial of the optical probe, which was done in the Aurubis Hamburg flash furnace in September 2018. From this trial, approximately 31 hours of spectral data were collected and synchronized with furnace operating data. The results from both drop tower test work and the plant trial are discussed with implications for process monitoring in the commercial furnace. INTRODUCTION Flash furnace smelting is a continuous feed, batch tap, pyrometallurgical process. It is used to treat copper sulphide concentrates and small amounts of secondary materials, such as dust generated by the process. O2 enriched air and the concentrate blend are fed into the furnace reaction shaft through the concentrate burner. As the particles fall through the reaction shaft, they heat up and ignite, causing rapid, exothermic reactions that oxidize the iron sulphide, some copper sulphide and impurities in the feed. Reacted particles fall into the settler of the furnace, melt and separate into a matte and slag, while the SO2 enriched off-gas is carried out of the furnace for heat recovery and H2SO4 production. Operation of the furnace is achieved by adjusting a limited number of control variables. The main variables are the blast feed rate, blast oxygen enrichment, SiO2 flux feed rate and CH4 combustion rate (CH4 is used when the chemical energy of the concentrate is low) all measured relative to a set feed throughput. (Davenport & Partelpoeg, 1987; Davenport, King, Schlesinger & Biswas, 2002) The batch tapping nature of flash furnaces makes operation difficult because these control variables impact each other, and product quality can only be measured when matte and slag are tapped from the furnace. This means that operation of a furnace is based on feedback control from matte and slag assays. Because of the time-delay associated with understanding product quality, there is interest in using technology to monitor the combustion reactions that happen in the furnace reaction shaft.

Jan 1, 2019

By N. Shi, T. G. Joseph

ABSTRACTA series of algorithms were developed to perform geometric and kinematic analyses of cable shovel dipper-ground interactions for a given set of mining face conditions. The routines examine and analyze (a) the position of the dipper in relation to the shovel; (b) the dipper in relation to the face conditions; (c) the dipper position in relation to possible interference or collision with crawler tracks during digging cycles; and (d) kinematic and geometric considerations with respect to any point on the dip-per as it conducts a duty cycle. In all cases, field measurement verifcation provided good agreement(within 4% variance).

Jan 1, 2011