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By J. Etcheverry, E. Seguel, R. Díaz, F. Parada, R. Parra, E. Balladares

A thermodynamic and kinetic model is proposed to explain the formation of bornite, chalcopyrite and magnetite during partial roasting of enargite-containing copper concentrates. The proposed mechanism involves solid-solid-gas and solid-gas reactions between chalcocite, pyrrhotite, gaseous sulfur and oxygen. The formation of bornite could be explained by a two-step reaction: the first one involving the formation of chalcopyrite by a reaction between Cu2S, FeS and gaseous sulfur, followed by a second step in which the newly formed chalcopyrite reacts with additional chalcocite to form bornite. Although thermodynamically the direct formation of bornite is more favorable than that of chalcopyrite, the lower diffusion kinetics of bornite formation could explain the preferential formation of chalcopyrite. If the reaction occurs with stoichiometric chalcocite and pyrrhotite in the presence of gaseous sulfur to form chalcopyrite, no bornite is formed, while for the stoichiometric reaction between chalcopyrite and chalcocite in the absence of sulfur, only bornite is formed. For the formation of magnetite and chalcopyrite the mechanism could involve the partial reaction of chalcocite and pyrrhotite in the presence of oxygen. The proposed model is thermodynamically consistent with the experimental results obtained in laboratory and pilot plant. INTRODUCTION The processing of high-arsenic copper concentrates with over 0.7 wt.-% arsenic by conventional smelting-converting normally require an additional arsenic removal step to reduce arsenic content to levels below 0.2–0.3%. One of these high-arsenic copper concentrates is the one produced by the Ministro Hales Division (DMH) of CODELCO, which has the typical chemical composition shown in Table 1. Enargite (Cu3AsS4), chalcocite (Cu2S) and pyrite (FeS2) are the main mineralogical species present in these concentrates, with over 75 wt.-%, as shown in Table 2. Partial or “neutral” roasting of these concentrates under controlled temperature and partial oxygen pressure conditions at 923–993K (650–720ºC) can remove up to 95% of the arsenic as As2S3 (As4S6), which has a high vapor pressure under these conditions, leaving a calcine with low residual arsenic. In copper concentrates, arsenic is present generally as enargite and arsenopyrite. This compounds as well as others such as pyrite and covelite, decompose readily above 770 K (500ºC), releasing, in addition to gaseous arsenic trisulfide, gaseous sulfur which by oxidizing to SO2 generates most of the heat required by the process.

Jan 1, 2019

By G. R. C. Pacheco, D. M. Fonseca, R. Neuböck, G. E. Gonçalves, W. Moulin-Silva

Degradation by sulfur gases is an important lining wear mechanism in the copper industry. SO2/SO3 gases infiltrate into the pores of the basic refractory bricks, combine with their raw materials through expansive reactions and significantly modify the bricks’ structure. This study presents a comparison of the corrosion resistance against sulfur attack of different magnesia-based refractories using a simple, low-cost and quantitative method. Recipes containing sintered MgO grains showed lower resistance to corrosion by sulfur oxides compared to basic grades containing fused grains. Chromium corundum grades were used as a reference and showed very good resistance to this corrosion mechanism under the test conditions. The novel test provided relevant results that agree with what is commonly observed during operation and in previous post-mortem studies. This tool could be very useful in selecting refractory grades for the copper industry and predicting their performance. INTRODUCTION Oxidation of matte sulfides during copper production leads to the formation of sulfur oxides, which infiltrate into the pores of the refractory lining and react with the basic oxides below 1000°C to form magnesium and calcium sulfates. This reaction is accompanied by an expressive volume increase, consequent densification of the refractory microstructure and weakening of the brick bond (Malfliet et al., 2013). Thus, corrosion by SO2/SO3 is an important wear mechanism in the non-ferrous industry and the resistance to this compound should be considered when defining refractories for this application. Previous studies on this matter include expensive and complex testing methods involving pressurized SO2 gas cylinders in order to investigate the corrosion resistance of MgO-containing materials by sulfur oxides (Gerle & Podwórny et al., 2016; Fotoyi & Eric, 2011; Fotoyi, 2009; Podwórny & Piotrowski et al., 2008). The current study was based on a test developed by Pacheco & Fonseca (2018) to assess alkali infiltration and aims to provide an evaluation method of the corrosion resistance of refractories by SO2/SO3 in a simple and quantitative manner. This novel test is useful to compare the corrosion resistance of different refractory recipes and properly select the grades that should be employed in the non-ferrous industry. A case study is provided to illustrate the damage caused by sulfur oxides in refractory linings.

Jan 1, 2019

By J. Bigu, M. G. Grenier, S. Hardcastle

"This study was undertaken in a belt conveyor drift of an underground hard rock mine. The conveyor transported ore or waste from a crushing operation located upwind from the drift sampling locations. A 250 m section of this drift was selected and several types of measurements were taken. Average respirable concentrations in the drift were 0.43 mg/m3 and 0.19 mg/m3 for total and silica dust, respectively. From the respirable dust concentration profile along the drift, it may be possible to estimate the contribution from extended sources such as dust produced by the belt and return idlers.The airborne dust in the drift had an average mass-median aerodynamic diameter of 4.2 micron. A continuous dust monitor showed that the crushing operation produced fairly high dust concentrations (sometimes greater than 4 mg/m3) over short periods of time.IntroductionAirborne dust in the respirable range is known to be the cause of various forms of lung ailments . In underground mines, respirable dust sources are created at many stages of production. All mining operators are responsible for de signing and establishing means of reducing airborne dust. In some cases, sources of dust are well defined and suppression methods are standard.In the case of interest here, the airborne dust cloud was formed from the contribution from many sources, which may be either discrete or extended. At the experimental site, the discrete or point sources were the crushing operation and the belt conveyor transfer point (tail pulley). These sources may be controlled by proper dust capture and scrubbing systems as well as dilution ventilation. Examples of extended dust sources in the area include dust produced by the re-entrainment of settled particles along the drift. Ventilation air movement and vehicular traffic both contribute to this phenomenon. Dust produced by the conveyor is another example of an extended dust source. Caked deposits on the return strand and idlers as well as the transportation of dry material on the belt, can be major contributors. Proper wetting of roadways and muck as well as proper belt cleaning techniques can help reduce these emissions. The cleaning apparatus, used on the belt where these experiments were conducted, is shown in Figure I. These and other belt cleaning techniques are described in more detail elsewhere."

Jan 1, 1987

By John Smith

"The RTZ Corporation PLCFrom a company's point-of-view, a good investment decision is one which results in the purchase of an asset that is worth more than it costs. Thus, in order to judge the merit of an investment opportunity, it is necessary to estimate the value of the assets to be acquired.Discounted cash flow (DCF) analysis has become widely adopted by companies in assessing potential new investments. The principle is a simple one: invest in projects which have a positive net present value, and reject those which do not. However, perhaps because of its apparent simplicity, DCF analysis is frequently misused. Good practice in the use of the technique is discussed, together with several common misconceptions.Sound analysis requires sound data; thus, the valuation process relies heavily upon a wide range of specialists to provide the basic input from which cash flow forecasts can be built up. The analyst must maintain close liaison with these specialists from the outset in order to ensure that the data provided is indeed relevant and complete.IntroductionBefore turning to the main subject of this paper ""How Companies Value Properties"", it is of interest to consider first a slightly different question ""Why do Companies value Properties""? In other words, for what purposes are such valuations prepared? Certainly the commonest, and probably the most important circumstance in which a valuation is required is when the company is considering an investment opportunity. This may be the direct purchase of a property or group of properties from a third party, but could also be the opportunity to develop a new operation or expand an existing one.A very simple objective in making any kind of investment is to make our shareholders richer than they would otherwise have been. That is, to make investments whose value to shareholders exceeds the consideration required to acquire them. Thus the investment decision focusses on the difference between an asset's value and its cost.This distinction between ""value"" and ""cost"" is an important one. Study of a company's balance sheet may tell a lot about the cost of this company's assets, but very little about their value. Then again, it is sometimes argued that a business should be bought because this will result in assets being acquired for less than their replacement cost. This merely compares one cost with another, it says nothing about value."

Jan 1, 1991

By J. G. Whellock, R. J. Phillips, J. W. Matousek, P. J. Marcantonio

"Stillwater Mining Company (SMC), a partnership of Chevron Resources and Manville Corporation, produces a copper-nickel, platinum-palladium flotation concentrate at its Nye, Montana mine. The concentrate is then toll processed in Europe. Recognizing the economic advantage of treating the concentrates at the mine site and of retaining this strategic resource in the United States, the Company commissioned Tolltreck International Limited and International Process Research Corporation to conduct pilot scale smelting tests with a flowsheet that would maximize metal recoveries while satisfying the environmental requirements of operations at Stillwater.Primary smelting was conducted in a single phase, 50 k W, submerged-arc, electric furnace. Refining the product mattes to copper-nickel ""white-metal""; containing approximately 2% iron, was accomplished in a Tolltreck, IV-litre, top blown rotary converter. Over-all platinum and palladium recoveries were approximately 99%; copper and nickel recoveries averaged 94%. INTRODUCTION(l-4)Stillwater Mining Company (SMC) a partnership of Chevron Resources and Manville, operates a copper-nickel, platinum palladium mine and concentrator at Nye, Montana, located in the valley of the Stillwater River, approximately, 100 km southwest of Billings. It is North America's only primary producer of these precious metals. The Stillwater area was mined for chrome ore during World War U and the Korean War, but it was not until 1961 that attention was drawn to the similarities between the Stillwater Complex and the Bushveld Complex of South Africa with its deposits of platinum group metals.A concentrated search for platinum was begun by Manville Corporation in 1967. Its presence, together with palladium, in mineable quantities was confirmed in the period 1976-1978, and the first partnership to develop the deposits was formed by Manville and Chevron in 1979. Anaconda joined the group in 1983, and in 1985 its share was purchased by Lac Minerals. In 1988 the interests of Lac Minerals were purchased by Chevron and Manville.The decision to develop the mine and build a concentrator was made in 1986. Construction began in the fall of that year, and the first concentrate was produced six months later, in March 1987. Underground mining is done in a two-shift, five day- week operation. Since startup, the concentrator has operated on a 24 hour/day, 7 day/week schedule, treating an average of 635 tonnes of ore per day and producing approximately 10 tonnes of concentrate."

Jan 1, 1989

By M. S. Greenfield, E. Cocchiarella, S. Chubbs

"At Dofasco sNo.4furnace a variation of the basic oxygen steelmaking process, Klockner Oxygen Bottom Maxhutte (K-OBM), is used to produce steel. Large amounts of hot gases and particulate are evolved during the oxygen blowing phase. A quencher and a venturi scrubber are used to collect over 99.5% of the particulate. In 1990, the authors investigated the effect of foamy slag on the particulate emissions from the furnace. The amount of lime added early in the oxygen blowing cycle was reduced, making the slag more viscous and foamy for a six minute period. Instantaneous particulate emissions were monitored throughout the blow by analyzing quencher and venturi scrubber water samples. Particulate emissions were reduced up to 59% during the foamy slag period.IntroductionThe reduction of the amount of waste generated or control of emissions at source is at the top of the ""3R"" hierarchy of waste management (Reduce, Reuse, Recycle). Process and operating practice changes are often the most economical ways to control emissions. At Dofasco, they investigated the effect of operating practice changes, specifically the formation of a foamy slag, on particulate emissions from steelmaking furnaces. They wanted to determine if a foamy slag changed the quantity and nature of the fume evolved from the K-OBM furnace over the oxygen blowing phase.The Basic Oxygen Steelmaking ProcessesThe basic oxygen steelmaking process (BOP) generates large quantities of very fine metal oxide fume during the production of steel. In this process, scrap steel and molten iron (hot metal) from blast furnaces are charged into a steelmaking furnace. Then pure oxygen is injected and a lime flux added . The oxygen reacts with carbon dissolved in the molten iron to form carbon monoxide. Oxygen lances can have secondary nozzles which introduce oxygen above the bath. This secondary oxygen, known as post-combustion, bums some of the carbon monoxide radiating the heat back to the bath. Particulate and gases rich in carbon monoxide are ejected from the furnace during the oxygen blowing phase and are collected by a gas cleaning system. Typically, more than 99.5010 of the particulate is scrubbed from the gases by high energy venturi scrubbers or electrostatic precipitators. The oxide sludge or dust collected may have elevated zinc and lead which is unsuitable for recycle to blast furnaces. Due to the presence of these undesirable elements, treatment and disposal of steelmaking oxide dust is difficult and costly."

Jan 1, 1993

By G. N. Nnadi, R. J. Mitchell

"The response of cemented backfills subjected to simulated blast loadings is studied using centrifugal modelling techniques. Scaling requirements for centrifugal modelling are developed and the results of the similitude analysis show that an acceleration field is required to capture the true dynamic response of backfill models. Experiments have been conducted at various centrifugal accelerations. The effects of ring blasting were simulated by an impact loading on the exposed fill face. The behaviour of the cemented backfill was monitored with accelerometers as well as dynamic stress gauges.Cemented backfill response to impact loadings was found to depend strongly on simulated gravitational stress level. Results also show that the characteristics of the response changes with distance from the impact. Finally, the results of the models were used to predict prototype peak accelerations, velocities and displacements. The results reported in this study indicate that centrifuge modelling may be a useful tool for dynamic studies of blast damage to backfills. Centrifuge modelling can be carried out at low costs and can be used to design prototype instrumentation systems. IntroductionThe response of cemented mine backfills to blast loadings is of concern to the mining industry because these backfills provide local and regional support during ore pillar extraction. Considerable research has been reported on the static stability (Smith et al., 1983) and on effects of reinforcements on cemented backfills (Mitchell, 1989). However, information regarding dynamic aspects of cemented backfill is limited. O'Hearn and Swan (1989) reported on the response of cemented backfill to blast loading, but these blasts were not very dose to the backfill . A schematic representation of a rock-backfill system is shown in Figure I.The mechanics of transfer of explosive energy to rock and subsequently to the backfill, and the resulting responses, are complex. Achison (1968) listed more than twenty factor s affecting the blast fragmentation of rock and grouped these into the categories of explosive parameters, charge parameters and rock parameters. Although significant advances have been made, during the past two decades, in understanding the mechanics of blasting, the degree of uncertainty associated with predicting the behaviour of backfills subjected to dynamic loadings makes the application of simple design safety factors insufficient. Comprehensive testing programs or prototype instrumentation is required to evaluate the risks associated with blast or earthquake loadings on backfill."

Jan 1, 1991

By Ali M. Ghazi, Ronald J. Goble, Lowell S. Whiteside

"Geerite (Cu1.6S) is a rhombohedral copper sulphide which occurs naturally in epitactic replacement of sphalerite; cell dimensions closely approximate those of the host sphalerite.Geerite-type structures can be produced by leaching digenite (Cu1.8S) in ferric sulphate solutions. X -ray diffract ion and electron microprobe studies indicate that eight metastable geeritetype structures can be produced, depending upon the concentration of f erric sulphate solution used and the duration of the each. Although compositions cluster on or near values observed for natural phases, optical properties indicate that we are dealing with polymorphs of these phases. Leaching of chalcocite (CU2Sj in dilute f erric sulphate solutions produces similar results. In contrast, leaching of chalcocite in more concentrated solutions seems to produce true analogues of natural minerals.During froth flotation, sphalerite is activated with a monolayer of floatable copper sulphide with the composition, CuS, of the mineral covellite. However, covellite is not significantly more floatable than sphalerite, and has an incompatible structure because of the presence of covalently-bonded atoms of sulphur. Leaching ofdigenite was used to produce a polymorph of covellite with a geerite-type structure, compatible with that of sphalerite. This polymorph has a flotational behaviour similar to copper-activated sphalerite, suggesting that the monolayer has a geerite-type CuS structure. IntroductionIn an ideal close-packed sulphide structure the distance between sulphur layers, D, is equal to 2R 2/3, where R is the radius of the sulphur atoms. In sulphides with covalently-bonded sulphur layers, such as covellite (Fig. I), D will be an average of the number of covalentl y-bonded and close-packed sulphur layers, weighted as to the relative number of each type of layer. Both D and R are spacings which are readily identifiable structurally and on X-ray diffraction patterns. Goblel has shown that for copper-iron sulphides with metal-to-sulphur ratios between 0 and 2 and copper-to-total metal ratio s between 113 and I there are strong correlations between composition and measured D and R distances (Fig. 2). D can be represented by a single empirical equation relating interlayer spacing to composition; R must be represented by three equations relating the radius of sulphur atoms to composition. One of these equations (R, in Fig. 2) represents ideal close-packed behaviour, the other two represent sulphur radii greater than (R1) or less than (Rh) the ideal."

Jan 1, 1988

By P. C. Thurston, T. Setterfield, D. H. Watkinson

"The Maybrun copper deposit IS In a succession of pillowed basaltic flows in the Wabigoon sub-province, northwestern Ontario. The rocks have primary flow morphologies and remarkably well-preserved crystallization textures, including quench-textured plagioclase, in spite of metamorphism to the amphibolite facies. The sulphide assemblage chalcopyrite-pyrrhotite-cubanite with minor sphalerite and pyrite is primarily in interpillow spaces and is stratabound. Basaltic rocks immediately enclosing the copper sulphide minerals have an enrichment in Fe, Mg and K and depletion in Ca and Na relative to surrounding flows. The Maybrun deposit is interpreted to have formed contemporaneously with volcanism and alteration, and was subsequently metamorphosed with the enclosing basalts.IntroductionThe association o f significant base metal accumulations with mafic submarine flows in the Archean is as yet poorly documented. Such deposits, where noted, have typically been small, and are therefore commonly over looked. The Maybrun Mine, a 2.6 x 106-tonne copper deposit in pillowed basalt, has many similarities with large, well-documented volcanogenic deposits. Given the interpretation of the Maybrun Mine to be volcanogenic in origin, there is n o reason why similar processes could not produce large deposit s. This is an important realization in an area where Archean submarine mafic rock s are very common, but frequently are examined only superficially. As gold commonly occurs in deposits such as Maybrun, even modest-sized deposits may be economic. The basalts at Maybrun are remarkable for amphibolite-facies rocks because of their extremely well-preserved delicate volcanic textures, including quench textures.The Maybrun Mine is one kilometre south of Atikwa Lake, in the Wabigoon sub-province of the Superior structural province, 75 km southeast of Kenora, northwestern Ontario, at longitude 93°35'W, latitude 49°25'N (Davies, 1973). Archean metavolcanic and metasedimentary rocks and intrusions underlie the area. Goodwin (1970) concluded that the mafic and minor felsic metavolcanic rocks, as well as the overlying metasedimentary rock s, were an eastward extension of the lower cycle of the Keewatin type section for the Lake of the Woods area. He estimated that the stratigraphic thickness of Keewatin rock s in this area is about 6900 m, of which 87% is basalt. The flows contain numerous interlayered sills, predominantly of basaltic composition; they have been extensively folded, faulted, metamorphosed to amphibolite facies and intruded by numerous felsic bodies, most importantly the Atikwa Batholith."

Jan 1, 1983

By R. Augsten, K. K. Feng, K. C. Cheng

"Methane emission and the desorption characteristics of vertical borehole coal samples of Greenhills multiple seams in the vicinity of Elkford, British Columbia were investigated. Three vertical boreholes at depths of 335 m, 380 m and 395 m were drilled along the west wall of an active open pit mine and 44 core samples from various coal seams were obtained for desorption studies.The results are presented in three tables and illustrated with six figures. The methane content was found to increase significantly at depths greater than 200 m. The adsorption equation by Kim and the properties of the coal have been used to predict the methane content and these were compared with the measured values by the direct method.IntroductionThe coalification of plant material in the sedimentary rock produces different ranks of co al and gases of various composition. The gas mixtures are retained in coal beds and rock strata under pressure. The gas content in a coal bed varies considerably depending on the rank of coal and the depth of overburden. The gas content is defined as the volume of gases adsorbed in a unit weight of coal materials. The net amount of gases remaining in a coal seam depends on the difference in the rate of generation of methane by geo-thermal heat and the rate of diffusion of the gases out of the coal bed through sedimentary cover. The major factor that causes the change in rank and the liberation of gases is the temperature, which is governed by the thermal conductivity of sedimentary cover and the heat flux through the underlying rocks. The rate of diffusion of the gases out of the coal is governed by the porosity of the overlying rocks and the degree of fracture. The measured values of gas content in major North American coal beds are from zero up to 24 cm3 per gram of coal(1,2). A gas content of 2.5 to 9 cm3/g is considered ""gassy"" and that of 9 cm3/g or higher is considered ""very gassy"" for underground mining(3). Normally, the gas mixtures released from bituminous coal in Canada contain 90 to 98% methane and the remainder is made up of CO2, N2, 02, H2, He and other hydrocarbons(4)."

Jan 1, 1984

By W. F. Moore

"In January 1981, Quintette Coal Limited (QCL) signed a 2a-year coking coal sales agreement with the Japanese Steel Industry which was followed by the commencement of mining operations in October 1982 and preparation plant operation in November 1983. During the mine 's startup, the town of Tumbler Ridge, the Anzac rail spur line, coal port facilities at Ridley Island plus numerous related elements of infrastructure were completed to support QCL and the neighbouring Bullmose operation in northeastern British Columbia. QCL's annual product coking coal levels have accelerated from 2.9 to 5.2 Mt between 1984 and 1986 with related increases in total mined volume from 14.8 to 41.0 M BCM between 1983 and 1986. This paper presents an overview of QCL 's current operation and related infrastructure. Development BackgroundDuring the 1970s, the Japanese Steel Industry (JSI) was forecasting a steady and significant growth in its steel production. By 1980 they were expecting crude steel production to increase from about 105 Mt in 1980 to 125 Mt by 1985 and almost 140 Mt by 1990.Discussions between Quintette Coal Limited (QCL) and the JSI for the development of the QCL project began in the 1970s and continued over a period of several years. During that time detailed and regular meetings took place, at which technical and commercial presentations were made to the JSI. The geology of the project area and the alternative mining methods and sequences were studied in detail. The new rail line which would connect the mine to tidewater was a critical factor and received particular attention. Alternate routes for the rail line from Tumbler Ridge to Prince George were the subject of much detailed study and discussions. The Anzac route was chosen in the best long-term interest of the northeast area development, after careful consideration and advice from the Japanese side.The new bulk coal terminal on Ridley Island at Prince Rupert was also a key factor and completed the development of an independent and new major coal field to supply the JSI. The QCL project and the development of the northeast area of British Columbia was a major strategical initiative of the JSI. It provided Japan with an important new coal field which was both self-sufficient and distinct from the traditional Japanese coal field resources in southern Canada, Australia, and the United States."

Jan 1, 1988

By M. Melashvili

"The SART Process was introduced to the gold mining industry in the late 1990s and several commercial plants were built over the following 10 to 15 years. Most of these plants have operated well and enjoyed plant performance in line with expectations based on the underlying chemistry of the process. However, two of the plants have consistently suffered from high reagent consumption and poor product quality, which has motivated a re-examination of the process fundamentals.The primary product in the SART Process is synthetic chalcocite, Cu2S, and the stoichiometric requirement for sulphide addition is therefore 0.5 moles per mole of copper in solution. It is shown here that when sulphide is added in excess of this amount (generally with the express purpose of lowering residual copper in solution) it not only fails in its intended purpose, but can have a negative impact on the settling and filtration characteristics of the copper sulphide product, as well as the final product quality. Moreover, these problems are exacerbated the higher the selected operating pH in the pH 3 to 5 range, and the longer the residence time of slurry in this pH range.Freshly precipitated copper sulphide compounds are known to be very fine and slimy, with poor settling and filtration characteristics. It is therefore important to engineer the SART Process in such a way as to encourage growth in the average particle size of the precipitate crystals. This was the rationale for recycling a portion of the thickener underflow to the primary reactor when the SART Process was developed. However, the theory of crystallization predicts that compounds of extremely low solubility, such as chalcocite (Cu2S: KSP = 10-48), are unlikely to experience growth in crystal particle size through heterogeneous nucleation and are more likely to grow through aggregation. On this basis, the SART practice of recycling a portion of thickener underflow to the primary reactor in the commercial plants is unlikely to lead to crystal growth via nucleation, and could in fact promote breakage of the aggregates that formed in the thickener. Recycling thickener underflow could therefore have the opposite of the desired outcome. The result of testwork that is reported here lends credence to this theory and questions the wisdom of recycling in the SART process."

Jan 1, 2016

By Julian Baldry

"This paper begins by describing the parameters of high-speed underground tracked drifting operations and the mucking cycle, and-discusses their variations. The railbound Haggloader 8HR is then described, as well as the Hagglund shuttle trains, outlining the advantages and disadvantages of the system. A comparison with conventional mucking operations is then given.IntroductionDrift and tunnel rounds are mucked by one of two major methods, either trackless with diesel loaders and trucks or with track loaders and cars. The aim of this paper is to compare the conventional tracked mucking cycle with the Hagglunds system alternatives.For many years, the traditional method of attacking the mucking cycle has been with a rocker shovel loader, a string of cars and a locomotive. The rocker shovel loads the first car and when full it is taken to a side drift, cherry picker or some other transfer point and is exchanged for an empty one. This empty car is then pushed back into the face and the loading continues until all cars are full . Then the whole train is taken out to a dump point where the cars are emptied. Normally the train's capacity is less than the volume of the muckpile, so the cars go back to the face. This loading cycle is repeated until all muck is removed from the heading. The last train out from the heading usually takes the loader and parks it in a side drift before continuing on to the dump where the cars are emptied.This simplified version of the traditional loading cycle excludes the ancillary work elements such as track laying and so on, but does point out that the cars must be transferred when full and that the whole train normally makes at least two round trips from the dump to the face. The prime aim in drifting is to cycle a round whithin a working shift which necessitates that no one part absorbs so much time as to prevent the completion of the cycle.Mucking, drilling and loading and the ancillary work such as rock bolting, vent and service pipe hanging typically each take one-third of the available work time. Drilling or mucking can and often do, because of various factors, take nearly half of the total cycle time. Once any segment of the operation starts to take this portion of the shift, the likelihood of missed rounds becomes increasingly greater."

Jan 1, 1981

By Naoki Takada, Dae-Sung Cheon, Minoru Sato, Masaji Kato, Manabu Takahashi, Weiren Lin

"The permeability and specific storage of rocks and sedimentary layers deep underground are critical parameters for issues related to the buried evaluation of natural gas and oil, CO2 aquifer storage, various kind of waste storage and so on.The Shirahama sandstone of the Wakayama prefecture, Kii peninsular in central Japan, consists mainly of quartz grains with no cracks and rock fragments that are aggregations of various kind of minerals. The quartz grains have an average size of about 150 micron. The pre-existing pore sizes were distributed dominantly at approximately 1 micron, and the total porosity was about 13%.During the hydrostatic compression test, we measured permeability of Shirahama sandstone by Transient Pulse test for three mutually perpendicular directions. Permeability of Shirahama sandstone remained fairly constant while increasing the effective confining pressure. Permeability anisotropy was observed slightly in the normal and two parallel directions to the bedding planes.We used micro focus X-ray CT with high resolution of 10 micron to visualize and measure the voids space information in Shirahama sandstone. Three-dimensional data were obtained in the intact and stressed sandstone simultaneously. Pore structures and grain boundaries were clearly distinguished. Pore closure and grain movement were clearly observed with increasing confining pressure. Micro focus X-ray CT is an effective tool to visualize and measure the geometrical information in rocks.Three-dimensional medial axis (3DMA) method was introduced to quantify the flow-relevant geometric properties of the voids structure in Shirahama sandstone using µfocus X-Ray CT data. The number of connecting path between two faces, tortuosity and the shortest path distribution within an arbitrary region of Shirahama sandstone specimen were analyzed. Geometrical information on the number of connecting path shows reasonable correlation between permeability anisotropy and mutually perpendicular directions normal and parallel to bedding planes. In addition, we introduced numerical simulation of fluid flow of pressurized Shirahama sandstone by LBM, to discuss the permeability change caused by pressurization on effective confining pressure. We obtained the detailed distributions of fluid pressure and fluid velocity in relatively narrow voids space more than 10 µm. It was confirmed that pressurization effect on permeability caused by the decrease of the connecting path and the shortest path between arbitrary faces, and then caused a complex condition on fluid pressure and fluid velocity."

Jan 1, 2015

By Jean-Paul Drolet

"The ultimate aim of the Law of the Sea Conference, held under the auspices of the United Nations, is to ensure that all aspects of the use of the sea are covered by international law. The question facing the nations of the world can be stated as: "" Who will control and benefit from the use and the wealth of the sea?""The United Nations Conference on Law of the Sea - known as UNCLOS - which reconvened in New York during the latter part of August 1978 was the third such Conference in the UN's history. The concepts of sovereignty over the territorial sea and freedom on the high seas have remained fundamental to the international law o f the sea until our time. The legal regime based on these two concepts developed initially from state practice meant that the unilateral actions taken by one or more countries were eventually accepted and followed by others.It was not until 1958, during the first Geneva Conference on the Law of the Sea (pursued in a second Conference in 1960) that the Law of the Sea was codified and modified to a certain extent by the then independent nations of the world in the four multilateral conventions on territorial sea and contiguous zone, continental shelf, high seas, and fishing and conservation of living resources.A third Conference got under way many years later when the members of the UN met in New York at the end of 1973 for preliminary discussions . This meeting stemmed largely from the need to fill gaps in existing international legislation which did not cover the new uses of the sea. The Conference was subsequently reconvened a number of times - in Caracas (1974), in Geneva (1975) and twice in New York (1976) for what was called "" substantive negotiating sessions."" A sixth session was held in New York in 1977; a seventh, held in Geneva at the beginning of 1978, recessed and reconvened in New York at the end of August 1978. This is what is referred to, in international jargon, as the seventh session of the Third United Nations Conference on the Law o f the Sea. The following dates are the principal markers of a saga which began some twenty years ago with the purpose of regulating the use of the oceans."

Jan 1, 1981

By L. M. Gould

"Syncrude Canada operates the largest oil sands crude oil production facility in the world and produces over 13% of Canada’s total oil requirements. To achieve this, Syncrude mines the oil sands in open pits, extracts the raw oil known as bitumen from the sand using water-based processes and upgrades it into sweet light crude oil by fluid coking, hydroprocessing, hydrotreating and reblending. The final product, Syncrude Sweet Blend (SSB), is sent by pipeline to three Edmonton area refineries and then to pipeline terminals which ship the SSB to refineries in Canada and the United States.As parts of the Mildred Lake base mine reached their economic life, they were replaced with new facilities at the Aurora Satellite mine. Aurora is situated on Oilsand Leases 10, 12 and 34, 35 km northeast of the Mildred Lake facility (Fig. 1).In 2000, the first hydrotransport low-energy extraction production train started up at Aurora. A second production train is scheduled for start-up in 2003. Open pit mining at Aurora occurs using two hydraulic shovels, two cable shovels, and trucks ranging from 320-ton to 380-ton payload capacities (Fig. 2).Once the oil sands is excavated, the trucks dump the ore into a crusher designed to break up the big lumps of oil sands and rock at peak rates of 11 000 t/hr. The ore is then transferred by conveyor to a surge pile and then to a mixing box which combines the oil sands with hot water. Following bitumen separation in the primary separation vessel, froth is delivered to Mildred Lake for processing via the intersite pipeline (Fig. 3).The goal of this paper is to illustrate how high precision shovel GPS (HPGPS) is being used at the Aurora mine to aid in mine planning. This can be accomplished by first describing the function of the mine planning department, describing the Aurora orebody, and finally explaining how the HPGPS system functions and how it is employed at Aurora.The short range mine planning department ensures a steady supply of ore is delivered to the plant at the desired grade in a sequenced and economical manner. This is done by creating a mine plan that consists of shovel dig locations that require the shovels to mine in a specified area at a specified elevation."

Jan 1, 2002

By F. C. Lendrum

"This paper had its origin in a panel discussion organized by the Canadian Uranium Producers Metallurgical Committee (CUPMC) at their Annual Meeting in Blind River in May, 1964. The reason for the panel was the formation of the National Uranium Tailings Research Program funded in the amount of ten million dollars by the Federal government. According to the bureaucrats in charge the program would seek to solve the perceived problems as well as any actual problems they believed existed with uranium tailings. Dr. Allan Ashbrook of Eldorado Nuclear chaired this panel and his summation of the panel's purpose was set out as ""Regulation and the Regulatory Process in the Nuclear Industry, Where Have We Been, Where Are We Now and Where Are We Going""?"" This paper will try to relate these questions to the whole mineral industry.The Canadian Mining Association has been telling us our natural resources are today required only if they are competitively priced with those produced in so called ""third world"" countries where labour rates are lower, environmental restrictions may be less and every effort is made by the local government to sell their product. It is in this hostile economic climate that the Canadian mining industry now finds itself. Before going further I want to stress these comments apply only to: a) Mines financed by private capital in a free enterprise society.b) Mining companies want to operate in an environmentally safe manner. However, they must earn a profit because no company financed with private capital can borrow money ad infinitum.WHERE HAVE WE BEENNone of us today would want to return to the days when the mill waste management system consisted of pumping the tailing to the nearest slope and letting nature's law of gravity do the rest. This was the way it was in early gold mines in Nova Scotia, tin mines in Cornwall, England or silver mines in Cobalt, Ontario and survives today in countries where climate, customs and methods of doing business are far different from Canada. As mill tonnage rates increased, more sophisticated systems evolved often designed for mining areas with different climates. Systems imported from arid climates such as south-west United States retained the solids but allowed bacterial oxidation of the sulphides promoting acid drainage. Environmental regulations were introduced and Canadian mines learned to handle tailings in our climates."

Jan 1, 1986

By D. Kachongo, Y. Cheng, A. Kashala, D. Samal, G. Mitshabu

Many copper processing flowsheets in the Democratic Republic of Congo include the leaching of oxide ores containing copper and cobalt, copper solvent extraction, copper electrowinning, and precipitation of cobalt salt. Recently, cobalt price gained momentum, driven mostly by the fast-growing electric vehicles battery market. The ore blending scenarios tend to prioritise high cobalt grade ore, whatever the content of copper and other impurities. Therefore, many copper solvent extraction circuits are running below design capacity. The variability of feed induces a variability of the leach solution with respect to copper, manganese, and silica contents. It is thus important to adjust hydrodynamic and metallurgical parameters of the solvent extraction plant to optimise metallurgical performance, production cost, and the quality of the copper electrolyte. This paper presents some results on how solvent extraction plant parameters have been managed in two solvent extraction plants running with lower than designed copper input. INTRODUCTION Referring to a report of the chamber of commerce of the Democratic Republic of Congo (DRC) the online publication Agence Ecofin (2019) indicated that the DRC ranks in the fifth position of the world top copper producing countries with over 1.2 million tons produced in 2018. The same year, 66% of the world’s cobalt was produced in the DRC at over 106,000 tons. If the political situation remained stable and the new tax regime introduced in 2018 did not deter private investors, copper production could reach 1.4 million tons/a in 2020 as pointed out in Mining.com (2019). Forecast figures for DRC cobalt production vary widely depending on analysts. The DRC online magazine Actualité.cd (2018) referring to a ministerial source forecasts over 141,000 t cobalt/a for 2020. The reality will depend on many factors, including the selling price, the supply compared to the demand, and finally the reaction of investors to the new DRC tax regime. The growing electric vehicle batteries market has been the major key driver of the price of cobalt. The five years historical cobalt price graph in figure 1 from infomine.com (2019) shows that the price of cobalt peaked at over 40 USD/lb in the first quarter of 2018. Cited by the online Magazine Creamer Media, Smith (2019) has indicated that the long-term demand of cobalt will likely remain strong.

Jan 1, 2019

By James A. Finch

"I offer a personal view of what the next 30 years holds for mineral processing. Re-stating that mineral processing will remain a vibrant industry in raw material production, growth opportunities in waste management are identified. The processing sequence familiar now (mining -mineral processing -extraction) will become more interwoven. In situ processing (i.e., milling underground) will evolve from concept to demonstration. Opportunities to exploit physical properties altered in chemical (pyro-and hydro-) processing will present themselves. In primary grinding, the path to AG/SAG milling will progress with little deviation but opportunities in regrinding are wide open. Flotation will see the trend to designing bubble/particle reactors accelerate simultaneously with a vigorous response from mechanical cell suppliers. Gravity separation remains a bastion of the lone inventor but I anticipate that the new lines will come from the waste management business. I finish by examining the ""research cycle"", identifying growth in small ""high tech"" companies and university research centres.IntroductionI have been asked to offer a personal view of""where we are going in mineral processing?"". Gazing into crystal balls is quite a cottage industry as we approach the end of the millennium. Academics are often asked to assume the role of visionary, I presume because it is considered in their mandate, to reflect and philosophize (or, less charitably, because they are considered to have the time). Since this is the 30th Annual Canadian Mineral Processors Operators Conference, I am tempted to suggest the next 30 years as my frame of reference. This is about equivalent to one engineer's career or, given it takes typically 15 years to go from concept to realization in mineral process engineering (Napier-Munn, l 997a), about 2 ""invention cycles"". With this length of cycle, much that is familiar now will remain so over the 30 years.Research and development (R&D) is in response to need. The overarching need in mining is to find new ore bodies. Process developments cannot compensate for a depleting deposit or a declining commodity price. Mineral processing R&D is characterized by incremental gains, aimed at pushing the mine down the cost per tonne league table. Breakthroughs are the exception (flotation at the turn of the century was one). This must be kept in mind when trying to predict the future in our business."

Jan 1, 1998

By Pierre Lacombe

"The operation of the Louvicourt Mine will have to rely on stringent grade control and on the optimization of the amount of blocked ore made available per given development effort. All of the above being necessary to obtain the highest throughput at the lowest mining cost.To assist in achieving these objectives, the need for production of a competent fill with short curing time was recognized early by the project partners. As well, operating costs associated with the selected method should be as low as possible while meeting the technical criteria.A feasibility study comparing filling methods showed potential benefits in all aspects of the paste fill use, except for its higher capital costs and increased operational complexity. This last consideration was tackled by the conservative design approach adopted in the flowsheet development of the paste fill plant.Since commissioning of the plant has just been completed at this time, the paper will focus on the feasibility study and its background, the design of the plant and testwork results at pilot plant and plant scale.RésuméLe succès de l 'opération de Louvicourt Mine dépendra d' un contrôle serré des teneurs du minerai et de la maximisation de la quantité de minerai développée par effort uni ta ire. Ces critères devant etre respectés afin d'obtenir le taux de production le plus élevé au coût le plus bas.De façon à satisfaire ces contraintes, les partenaires du projet ont reconnu tôt la nécessité de produire un remblai de qualité tout en maintenant un temps de curage court. De plus, les coût d'opération associés a cette opération se devaient d'être des plus avantageux sans sacrifier l'atteinte des objectifs techniques.Une étude de faisabilité comparant différentes méthodes de remblayage a démontré que le remblai en pâte offre des aspects positifs sous taus les angles, si ce n'est de son coût en capital initial élevé et de sa complexité relative d'opération. Ce dernier point fut considéré de près par l'adoption d' une approche conservatrice lors de la conception de l'usine de rernblai.Puisque la mise en service de l'usine n'a été faite que les détails de l 'étude de faisabilité et ses fondements, 1 'usine et des résultats d' essais obtenus a l'échelle de l'usine seront discutés."

Jan 1, 1995