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By T. Patching

"THE FOLLOWING notes on coal mining in the Edmonton city area are based, in the main, on scattered reports and accounts as little coal mining has been done in this area for about 20 years and few people are left who were involved in what was at one time an important industry of northern Alberta. Although coal mining is not likely to be permitted in the city area itself in the future, a record of this work is warranted to indicate the ·conditions and problems that may be encountered if underground mining again is proposed in the district in the same geological formations and in similar strata. Coal mining in the Edmonton area developed with the influx of settlers in the latter part of the nineteenth century and the first part of the present century. Probably local coal was used by the Fort's blacksmith as early as 1841, and the early settlers probably were 'gopherholing' into the outcrops along the river banks by the 1870s. The first report of commercial coal mining was in 1880 when a contract was let by the Hudson's Bay Company for the provision of 300 tons. As the population in the city and northern parts of the province grew, many new mines were opened along the river and in the district, and coal was even shipped by barge to points in Saskatchewan(1 ,2) By 1909 the Department of Public Works reported that 'Edmonton stands as the second largest domestic coal producing centre in the province'. It continued to hold this position until 1942. From about 1912 to 1951 annual production from mines in the city and surrounding district ranged between 0.38 and 0.65 million tons, depending on weather, wars and strikes. Production began to decline in 1951 because of the increasing availability and consumption of natural gas which was piped into the city and then provided to other towns and rural areas in the northern part of the province. Taylor noted that between 1880 and March 1970, when the last mine within the city area closed, the total of mines and prospects within the Edmonton city area rose to 153. Most of them were small; not more than 20 produced more than a quarter of a million tonnes during their entire life, and only three produced a million tonnes or more. As described by Taylor ""within the city district workings extend discontinuously from the apex of a narrow triangle near Groat Bridge to the base of the triangle in the Clover Bar area"". The larger mines were in this latter area. Approximate locations of the old mine workings in the city are shown in Taylor's atlas. A number of other coal mines were worked in the Rabbit Hill, Big Island, St. Albert, Namao, Cardiff and Morinville districts around the city."

Jan 1, 1985

By Peter J. Barnard

Mitochondria play a key role in the regulation of apoptosis (cell death) and in diseases characterised by abnormal apoptotic responses such as cancer. Mitochondrial membrane permeabilisation (MMP), regulated by the mitochondrial permeability transition pore complex, is widely accepted as being central to the process of cell death. As a result there has been considerable recent interest in targeting mitochondrial cell death pathways in the development of new chemotherapeutic agents.(1) There is potential to overcome the two overriding problems in cancer chemotherapy?the common occurrence of drug-resistant tumour cells and the lack of selectivity of cancer drugs in differentiating between tumour cells and normal tissues. Significantly, carcinoma cells have an elevated mitochondrial membrane potential relative to normal cells and lipophilic cations are concentrated within mitochondria in response to mitochondrial membrane potentials. There is potential for the selective targeting to tumour cells with compounds having optimal lipophilic-hydrophilic character. Research stemming from the early 1980?s points to two distinct classes of Au(I) phosphine antitumour agents where an antimitochondrial mode of action has been implicated: (i) neutral linear two-coordinate Au(I) complexes such as triethylphosphinegold(I) chloride and the tetraacetylthioglucose gold(I) phosphine complex, Auranofin; (ii) cationic tetrahedral bis-chelated Au(I) phosphine complexes related to [Au(dppe)2]+.(2) Recently it has been reported that Auranofin, at submicromolar concentrations, induces MMP observed as mitochondrial swelling and dissipation of membrane potential.(3, 4) Both events are completely inhibited by cyclosporin-A, the specific inhibitor of MMP. The permeability changes were shown to occur at concentrations associated with the selective inhibition of mitochondrial thioredoxin reductase.(3) Auranofin is a potent and specific inhibitor of this enzyme due to Au(I) binding to the active-site selenol group.(5) The redox state of mitochondrial thiols may be critical in the control of MMP.(3) In general, swelling is stimulated by thiol blocking or oxidising agents and is prevented by thiol reducing agents.(1) Mitochondrial thioredoxin reductase may play an import role in the redox control of the permeability of mitochondrial membranes.(3) Our interest is in investigating the antitumour potential of Au(I) phosphine compounds using a number of different approaches. In recent work we have evaluated a series of hydrophilic analogs of [Au(dppe)2]+ containing pyridylphosphine ligands which have demonstrated greater tumour selectivity than the parent compound. To investigate the possible antimitochondrial mode of action we are studying the effect of [Au(dppe)2]+ and related compounds on isolated rat liver mitochondria. To assess whether the lipophiliccationic nature of the compounds determines the antitumour activity, we have synthesized a series of novel Au(I) complexes based on heterocyclic carbene rather than phosphine ligands. The similar chemistry and structural features of the two classes of complexes allow us to assess whether the phosphine ligands are essential for the antitumour properties.

Oct 1, 2003

By Dogan Paktunc, Larry J. Hulbert, Robert C. Carne, D. Conrad Grégoire

Abstract -A thin layer of stratiform Ni-Zn-PGE sulfide mineralization of sedimentary-diagenetic origin was deposited during the Middle to Upper Devonian in the euxinic "Nick basin". The mineralized unit (2:3 cm thick), which seems to have been developed over the entire sedimentary basin of >80 km2, consists of pyrite, vaesite (NiSi), and sphalerite. The average grade of the mineralization is about 5.3% Ni, 0.73% Zn, ?770 ppb (PGE+Au), and up to 61 ppm Re. Anomalous Se, As, Mo, P, Ba and U are present. A minimum of 0.90 x 106 tonnes of Ni were deposited in the basin (based on a bed thickness of 3 cm) during the Devonian. The unique metal association, extensive lateral distribution, persistent metal grade, mineralogical makeup, and stratigraphic control demonstrate that this is a new deposit type and a new geological environment for Ni and PGE +Au. The sulfide layer occurs at the base of a Phosphatic Chert Member which is underlain by a distinctive marker unit consisting of concretionary limestone structures. The limestone spheroids may represent a vent-specific carbonate facies developed adjacent to faults that emanated nutrient­ rich hydrothermal discharges just prior to the main mineralizing event. The suite of elements associated with the Nick mineralization suggests that the ore-forming metals were originally bound to organic matter derived from decaying marine organisms. Discharge of hot brines bearing organic­ matter-bound metals took place along numerous conduits within basin faults that are now manifest as bitumen veins. Our syndiagenetic model proposes that these fluids were discharged laterally from the conduits into the unconsolidated bottom sediment (ooze). The introduction of this metalliferous fluid, rich in organic matter, stimulated biological activity and bacterial reduction of its contained S04 to sulfide. Hot, dense, laterally migrating hydrothermal fluid precipitated thin sulfide-rich 1arninae within bottom sediment. Published thermodynamic studies suggest that the diagnostic vaesite­ pyrite assemblage crystallized at approximately 138°C. The ?34:S values range from -14.7 o/oo to-10.0 o/oo and are up to 34 o/00 lighter than locally surrounding sulfides and age-equivalent mineralized strata elsewhere in the Selwyn Basin. The ?13:C values of calcite in the footwall of the mineralized unit ( -12 o/00 to -6 o/00) are isotopically much lighter than regional values. The lighter isotopic character is attributed to the hydrothermal discharge of fluids enriched in organic compounds. Although geochemical profiles of the lower Earn Group sediments that host the Nick mineralization reveal that these black shales are not distinctive, the unusual Ni, Zn, PGE, U, Ba, and P elemental associations and their anomalous concentrations in stream sediments can be used to explore for this deposit type.

Jan 1, 1992

By E. Fiset, T. Hennebel, F. Verbruggen, A. Prévoteau, K. Rabaey

Arsenic (As), bismuth (Bi) and antimony (Sb) are known to affect the quality of copper deposits in copper electrowinning operations. The codeposition of As was previously believed to occur only at current densities far exceeding the range of typical current densities for copper electrowinning. In this study, we investigate the copper electrodeposition on different pretreated stainless steel (SS) substrates from bleed electrolyte in galvanostatic mode at –45 mA/cm². Scanning electron microscopy (SEM) micrographs illustrate that during the initial phases of copper nucleation and growth, the current density was locally increased due to the pretreatments. It was reasoned that the codepostion of As could possibly occur in normal electrowinning conditions, but the risk can be substantially reduced by good SS substrate handling and maintenance practices. INTRODUCTION The presence of As, Bi and Sb is known to have a deleterious effect on the copper cathode quality in copper electrowinnings (Hiskey & Maeda, 2003; Hoffmann, 2004; Xiao, Cao, Shen, & Volinsky, 2012; Xiao, Cao, Mao, Shen, & Ren, 2014; Jafari et al., 2017). They are known to influence both the chemical and physical quality of the copper as they can contaminate the copper (Jafari et al., 2017) and affect the copper deposit structure (Hiskey & Maeda, 2003; Kim, Kim, & Chung, 2009), which contributes to a degraded market value of the copper (Tuddenham, 1984). The incorporation mechanisms of these impurities are believed to occur mainly through slime inclusion (F. Xiao et al, 2012) and electrolyte inclusion (Hiskey & Maeda, 2003). Other studies suggested that codeposition of these impurities is possible by their standard reduction potential being close to the one of copper (Xiao et al, 2014). Hiskey and Maeda (2003) investigated the copper electrodeposition on a copper electrode substrate in Cu electrolytes with a Cu, H2SO4, As, Bi, Sb composition representative for commercial copper tankhouses. The combination of voltammographic techniques and Auger electron spectroscopy showed that As was the first impurity to be electrodeposited from this electrolyte, yet at potentials where the limiting current density of the copper electrodeposition reaction is exceeded. The copper tankhouses usually operate at a current density ratio of 0.3 to the limiting current density in order to achieve tolerable copper quality deposits. The codeposition of As could be considered impossible in this current density condition. However, it is known that during the initial phases of electrodeposition on foreign substrates, a substantial part of the reaction proceeds by growth of individual nuclei where the current density is locally high and diffusion limited (Radisic, Ross, & Searson, 2006). Furthermore, it was observed that copper nucleation on TiO substrates occurred preferentially in the scratched oxide free areas which could serve as parts with high localized current densities (Chang, Choe, & Lee, 2005).

Jan 1, 2019

By T. Kalliomäki, A. T. Aji, M. Lundström, J. Aromaa

The settling properties of anode slime in copper electrorefining have crucial effect on copper cathode quality. Anode slime settling is affected by electrolyte composition and temperature, electrolyte circulation, and the sizes and density of the slime particles and agglomerates. Typically, the industrial copper electrolytes contain 40–60 g/dm3 Cu2+, 130–220 g/dm3 H2SO4, 0.04–25 g/dm3 Ni2+, 0.005–30 g/dm3 As, and have operating temperature of 55–70°C. In optimal electrorefining process, the settling rate of anode slime is sufficiently high to avoid the risk of getting the slime entrapped in copper cathodes. In this research the settling properties of copper electrorefining bottom slimes, mainly consisting of Cu, Ni, Ag, Se, Pb, As, Bi, Sb and Ba compounds, were studied by settling rate tests. The tests were conducted in water and synthetic electrolytes with known viscosities and densities. In addition, the effect of agglomeration was taken into account – it was observed that breaking the agglomerates which existed in the as-received slimes decreased the particle sizes on average 56–73%, which decreased the settling rate. The results of this study provide detailed information of anode slime settling and thus clarify the conditions causing cathode contamination risks in copper electrorefining. INTRODUCTION Settling rates of Cu-ER anode slimes affect the purity of cathode copper and faster settling rate decreases the contamination risk (Davenport et al., 2002; Shi & Ye, 2013). The settling rates are affected by the properties of anode slime particles (Wills & Napier-Munn, 2011; Aaltonen, 2014; Kiviluoma, Aaltonen, Aromaa, Lundström & Forsén, 2016) as well as viscosity and density of the electrolyte (Davenport, King, Schlesinger, Biswas, & Robinson, 2002; Shi & Ye, 2013). Thus, it is crucial to find out how the viscosity and density affect the settling rates. Small spherical particles with diameter below approximately 50 µm obey Stokes’ law (Equation 1) (Wills & Napier-Munn, 2011). v = gd 2 (ρS – ρF) (18η) -1 (1) where v is terminal velocity (m/s), g acceleration due to gravity (m/s2), d diameter of particle (m), ρS density of particle (kg/m3), ρF density of fluid (kg/m3), and η dynamic viscosity (Pa∙s). The approximate effects of kinematic viscosity (ν = η / ρS), density (ρS) and particle sizes on settling rates defined for small anode slime particles based on Stokes’ law are presented in Figure 1. However, Stokes’ law does not take into account other than spherical shapes, and it is only applicable for small particles. Consequently, the real settling rates of the particles are lower than these (Wills & Napier-Munn, 2011). Moreover, some of the anode slime particles are larger than 50 µm (Aaltonen, 2014).

Jan 1, 2019

By Lassi Klemettinen, Ari Jokilaakso, Dmitry Sukhomlinov, Pekka Taskinen

The solubilities and distributions of molybdenum and iridium in iron silicate slag and copper-iron mattes were studied using an equilibration-quenching technique and subsequent direct phase composition analyses by EPMA (Electron Probe X-ray Microanalysis) and LA-ICP-MS (Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry). The equilibrations were carried out on a wide matte grade interval, ranging from 55 wt-% Cu to 75 wt-% Cu, in pSO2 = 0.1 atm at 1300°C. The results in equilibrium with a solid iridium-molybdenum alloy indicated an iridium solubility of 150–500 ppmw in the sulphide matte, depending on the matte grade, and a molybdenum solubility of 100–600 ppmw. Iridium was distributing predominantly in the sulphide matte with the distribution coefficient of 10+3 - +4 but molybdenum deported predominantly in the slag with Lm/s(Mo) = 0.02–0.1. The effects of alumina and lime additions in the smelting slag were also examined. INTRODUCTION Iridium is a highly siderophile element (HSE), which means that it is incompatible with the sulphide forming elements and possesses a small solubility in mattes, such as copper- and nickel-iron sulphide melts. Molybdenum behaves only modestly in that way (Walker & Li, 2008; Righter et al., 2017). They both are known to be trace elements accompanying copper and nickel sulphide ores. No solubility data, however, are available for them in copper-rich sulphide mattes. Geochemical data on the behaviour of Ir and Mo deal mostly with low-iron silicate systems, e.g. basaltic melts, and high-sulphur sulphide solutions and mattes (Ertel et al., 2008; Fonseca et al., 2007). They also indicate that Ir and Mo dissolve in silicate melts primarily as oxides and not as electrically neutral metal species. Most geological data of iridium focus on high-sulphur systems of the monosulphide composition and typically Fe-Ni mattes where copper is a trace element (Fleet et al., 1996; Sattari et al., 2002). Direct solubility measurements for mattes and iron-lean silicates have also been made using pure Ir or an Ir alloy as the saturation phase (Borisov & Palme, 2000; O’Neill & Eggins, 2002; Makovicky & Karup-Møller, 1999; Ertel et al., 2008; Mungall & Brenan, 2014). A recent summary about the solubilities of HSE’s in iron- and sulphur free silicates is available in Laurenz (2012). The thermodynamics of molybdenum partitioning between oxides and Fe-S-O melts was studied by Mengason et al. (2011). Their results indicate strong accumulation in the iron-rich sulphide in reducing conditions (pO2 = 10-9.6 atm in Ni-NiO equilibrium at 1050°C). Molybdenum dissolves in iron-lean silicate melts as MoO3 species in oxygen pressures above the Fe-FeO equilibrium and as MoO2 in more reducing conditions (Farges et al., 2006; Righter et al., 2017).

Jan 1, 2019

By N. P. Hristov, L. V. Kuzev

"A simulation study of the fill factor of a drum mill was conducted using two types of grinding media: balls and tetraballpebs. Each medium was composed of equal number of grinding bodies having equal weight but different shape. The difference was in the density of the two grinding media.Standard spherical grinding bodies (balls), which were used in practice, and equivalent (by weight) grinding bodies in the shape of spheroidal tetrahedrons (tetraballpebs) were studied. The simulation was conducted in a module of a 1.2 m diameter drum mill, whose length exceeded twice the diameter of the corresponding grinding body. The grinding balls had a few percent (3 to 6) higher fill factor than the grinding tetraballpebs in the same shell.Vertical sections of the grinding medium were taken across the studied shell module along its axis. They showed the location of each grinding body in the fill volume. Defects in the packing of the grinding bodies and the contacts between them and with the inner surface of the shell were also show. Differences in the contact points of the balls and the tetraballpebs were noted. For the tetraballpebs, we observed contacts both between the spherical surfaces and with the edges and vertices of the grinding bodies.The topography of the grinding media is shown visually.INTRODUCTIONThe grinding balls have been studied extensively. It is the traditional grinding medium in ore processing industry. The parameter characterising the grinding medium is its density. It is the mass of the grinding medium per unit of volume. The parameter may have a range of values. It depends on:• The physical properties of the material they are made of;• The shape of the grinding body;• The dimensions of the body;• Size distribution of the grinding bodies in the grinding media.In comminution, the fill factor of the mill shell is the process parameter that is representative of the grinding medium. Some publications have indicated the disadvantages of ball grinding. For example, Wu, Xiang, Glen, and Duan (2008) note in the analysis of the mechanism of grinding that the balls are not the best grinding media and disadvantages include among others:• Easy over-grinding resulting from the point contact between the balls;• Attrition surface is the smallest in the grinding media;• Poor selective exposure of minerals resulting from the accidental and often significantly more powerful impact on the feed;• The grinding efficiency drops as the fineness of grind is increased;In the Handbook of mineral processing, Polkin (1950) noted that the shape of the grinding bodies determines the volume of the void spaces therein and therefore the shape affects the grinding efficiency per unit of volume of the grinding medium."

Jan 1, 2016

By K. Hashiba, Y. Z. Liang, K. Fukui, M. Koizumi

"Efficiency and penetration rate during percussive rock drilling significantly affect the speed of tunneling and excavation. Many researchers and engineers have continuously engaged in the advancement of rock drilling performance. Development and modification of the rock drills based on test data are timeconsuming and costly. Hence it is essential to make effective use of numerical simulation. However, most of the numerical models proposed in previous studies were too simple in comparison with the actual percussive rock drilling in which many factors are involved. The objective of our research project is to construct a new realistic numerical model of continuous percussive drilling, which is based on the previous Okubo-Nishimatsu’s model. In this study, the parts of the previous model involved in stress wave propagation and attenuation were modified. The two models were prepared for HD712 hydraulic rock drill mounted on crawler drills and HD210 hydraulic rock drill mounted on drilling jumbos. Stress wave propagation was computed with the discretized one-dimensional wave equation. The calculated results were compared to the stress waves measured on a rod during percussive drilling. In both models for HD712 and HD210, the measured stress waves can be reproduced with the one-dimensional model of the same acoustic impedance as the actual piston, shank rod and rod combined with the CI+spring model as a rod joint. The calculated results indicate that the spring constant in the model of a rod joint needs to be set appropriately depending on drilling conditions. INTRODUCTIONEfficiency and penetration rate during percussive rock drilling significantly affect the speed of tunneling and excavation. Many researchers and engineers have continuously engaged in the advancement of rock drilling performance. Components related to the percussive drilling are a drill body, a piston, a shank rod, rods, rod joints, a bit and rock. The piston in the drill body is reciprocated by hydraulic pressure and collides with the shank rod a few thousand times per minute. Stress waves generated by the collision propagate and attenuate in the rods and rod joints, and then reach the bit. The bit penetrates and crushes rock. During percussive drilling, the components mutually affect each other and self-induced oscillation occurs. The number of blows and the rate of penetration are determined by the practical drilling conditions such as hydraulic pressure, thrust force, number of rods and mechanical properties of rock. Development and modification of the rock drills based on test data are time-consuming and costly. Hence it is essential to make effective use of numerical simulation. However, most of the numerical models proposed in previous studies were too simple in comparison with the actual percussive rock drilling in which many factors are involved."

Jan 1, 2015

By Henk Dijkman, Wageningen University, Paula Gonzalez Contreras, Irene Sánchez-Andrea, Jan Weijma, Silvia Vega

"More than 20 years ago, Paques B.V. introduced innovative biotechnologies to recover metals and to remove sulfate from aqueous streams. These technologies find their origin in the exploration of microorganisms involved in the global sulfur cycle. Currently, several sulfur cycle biotechnologies are applied successfully at full-scale. The sulfur cycle is closely linked with the iron cycle, and also the latter offers opportunities for application of innovative biotechnology for the mining industry. Microorganisms of the natural iron cycle carry out reactions that are not feasible by chemical methods such as ferrous iron oxidation with oxygen at pH below 4. Iron oxidation with oxygen can be conducted using microorganisms living at pH between 0.5 and 7 and at temperatures between 0 and 95ºC. Remarkably these microorganisms can also carry out arsenite oxidation at similar acidic conditions and high temperatures. Making use of the extreme features of these microorganisms, Paques and Wageningen University have developed a biological process to precipitate arsenic as scorodite. This biological formation of scorodite is a novel combination of biological oxidation and biocrystallization. Depending on the level of saturation, biological oxidation rates and operational conditions, we could control the formation of the iron precipitates such as jarosite and scorodite. Currently new microorganisms have been harvested from hot springs and rock acid mine drainage to foster the growth of specialized microbial communities with potential high iron and arsenic oxidation capacities and higher resistance to other metals. In our paper we address the ongoing research and development of the bioscorodite process.THE USE OF IRON TO REMOVE ARSENIC In 2015 several environmental disasters related to the release of mine wastewater and tailings occurred. On August 5th, a waste water spill occurred from the Gold King Mine near Silverton, Colorado. A dam holding the tailing pond was damaged and spilled three million US gallons (11 ML) of mine wastewater and tailings, including elements such as cadmium, lead and arsenic, into Cement Creek, a tributary of the Animas River in Colorado. “At their peak, arsenic levels were 300 times the normal level and lead was 3,500 times the normal level” (The Guardian, 2015). In early November, another collapse of a mining dam in the Brazilian state of Minas Gerais spilled between ten and sixteen thousand US gallons of water and sediment after a dam failed from an iron ore mine. Arsenic and mercury polluted the Doce River, arsenic levels were found more than ten times above the legal limit in some places of the river (The Guardian, 2015). Waste production is inevitable during Mining. However, a preventive waste management strategy could have minimised waste production, maximised waste reuse and classified waste by their hazardous degree."

Jan 1, 2016

By Dogan Paktunc, Larry J. Hulbert, Robert C. Carne, D. Conrad Gregoire

A thin layer of stratiform Ni-Zn-PGE sulfide mineralization of sedimentary-diagenetic origin was deposited during the Middle to Upper Devonian in the euxinic "Nick basin". The mineralized unit (=3 cm thick), which seems to have been developed over the entire sedimentary basin of > 80 km2, consists of pyrite, vaesite (NiSz), and sphalerite. The average grade of the mineralization is about 5.30/0 Ni, 0.73% Zn, =770 ppb (pGE+Au), and up to 61 ppm Re. Anomalous Se, As, Mo, P, Ba and U are present. A minimum of 0.90 x 106 tonnes of Ni were deposited in the basin (based on a bed thickness of 3 cm) during the Devonian. The unique metal association, extensive lateral distribution, persistent metal grade, mineralogical makeup, and stratigraphic control demonstrate that this is a new deposit type and a new geological environment for Ni and PGE + Au. The sulfide layer occurs at the base of a Phosphatic Chert Member which is underlain by a distinctive marker unit consisting of concretionary limestone structures. The limestone spheroids may represent a vent-specific carbonate facies developed adjacent to faults that emanated nutrientrich hydrothermal discharges just prior to the main mineralizing event. The suite of elements associated with the Nick mineralization suggests that the ore-forming metals were originally bound to organic matter derived from decaying marine organisms. Discharge of hot brines bearing organic matter-bound metals took place along numerous conduits within basin faults that are now manifest as bitumen veins. Our syndiagenetic model proposes that these fluids were discharged laterally from the conduits into the unconsolidated bottom sediment (ooze). The introduction of this metalliferous fluid, rich in organic matter, stimulated biological activity and bacterial reduction of its contained 804 to sulfide. Hot, dense, laterally migrating hydrothermal fluid precipitated thin sulfide-rich larninae within bottom sediment. Published thermodynamic studies suggest that the diagnostic vaesitepyrite assemblage crystallized at approximately 138°C. The 034S values range from -14.7 0/00 to -10.00/00 and are up to 340/00 lighter than locally surrounding sulfides and age-equivalent mineralized strata elsewhere in the Selwyn Basin. The Ol3C values of calcite in the footwall of the mineralized unit (- 12 0/00 to -6 0/00) are isotopically much lighter than regional values. The lighter isotopic character is attributed to the hydrothermal discharge of fluids enriched in organic compounds. Although geochemical profiles of the lower Earn Group sediments that host the Nick mineralization reveal that these black shales are not distinctive, the unusual Ni, Zn, PGE, U, Ba, and P elemental associations and their anomalous concentrations in stream sediments can be used to explore for this deposit type.

Jan 1, 1992

By K. Schrijver, G. Beaudoin

"Four occurrences of galena-cemented sandstones, exposed in the Lower St. Lawrence - Gaspésie area, are described. They constitute a new, insufficiently explored type of deposit in Quebec.One mineralized body, a minor occurrence, is hosted in Lower Devonian rocks deposited in an estuarine, intertidal river channel during a marine regression; major cements are dolomite and sulphides. Another occurrence, a drilled prospect, is hosted in Upper Silurian rocks deposited unconformably on Cambro Ordovician basement during a marine transgression. With galena and quartz as main cementing minerals, it is similar to some well-known, economic sandstone-lead deposits. A third and fourth, a drilled prospect and a minor occurrence, are hosted in Upper Cambrian rocks deposited on continental slopes. In both, sulphides mainly occupy a secondary porosity. The differences between the third and fourth occurrences are: (1) cementing translucent minerals (carbonates and barite in one; chlorite in the other); (2) chronology of final subsurface dissolution (prior and subsequent to sulphide precipitation, respectively); and (3) important fracture porosity only in the barite-bearing deposit.The diversity of the four occurrences, and the unequal geological knowledge of their respective features, prohibit the formulation of uniform guidelines for further exploration.IntroductionThe attention of the mineral exploration community is drawn to four occurrences of galena-cemented sandstones (Fig. 2A) in the Cambrian of the Taconian Orogen and in the Siluro-Devonian basin of the Lower St. Lawrence and Gaspésie area (Fig. 1). In view of the fact that sandstone-lead deposits (Bjerlykke and Sangster, 1981) are, or have been, mined in several countries (e.g . Laisvall in Sweden: see Rickard et al., 1979; Largentiere in France: see Foglierini et al., 1980), the mere presence of occurrences in Quebec indicates that the mineral potential of some parts of the Appalachians requires further evaluation.Exploration for the deposits considered here is essentially restricted to geological methods and drilJing (e.g . Mainguet Suares and Samama, 1969), since the response to geophysical methods is virtually nil, at least in the initial, surficial stage of an exploration program. As the particular disciplines of geology utilized in exploration depend a great deal on the geological setting of a mineral occurrence, the diversity of the Quebec deposits is of prime importance. Therefore, the four occurrences (Fig. I, Table 1) studied by the authors are herein briefly described with emphasis on their stratigraphic and tectonic setting, and on the evolution of pore space and sequential occlusion of pores and fractures. Prior to further research in and around the occurrences, now in progress (e.g. Beaudoin, 1987; Beaudoin et al., 1987), it is hoped that the following outline will be useful to the explorationist."

Jan 1, 1987

By Edouard Asselin, Tasawar Javed

This study was conducted as a part of ongoing work to characterize sulphide concentrate leach residues generated under CESL (Cominco Engineering Services Limited) and Vale pilot and demonstration plant medium temperature (150 °C) process conditions. Three different samples were analyzed. Derivative samples were prepared by extracting gypsum, sulphur and amorphous/poorly crystalline iron oxyhydroxide phases from the leach residues. Thermal behavior of the samples was studied by thermal gravimetric analysis (TGA) and differential thermal analysis (DTA) in the temperature range 25 to 800 °C in both air and nitrogen atmospheres, with XRD analyses both before and after heating. Thermal transformation temperatures for different iron oxides/oxyhydroxides present in hydrometallurgical leach residues vary over a wide range which suggests the variable crystallinity of the phases. Raman spectroscopic analysis was carried out to help identify the type of iron phases in the residues. Furthermore, hydroxylamine hydrochloride (HaHC) and oxalate extractions were used to compare the fractionation of the amorphous/poorly crystalline iron phases in the residues. Given the compositions of the residues, any thermal events in the temperature range of 200 °C to 480 °C were attributed to amorphous/poorly crystalline iron phases.

Jan 1, 2014

By C. P. Moore, G. W. Taylor

Vertically dipping lenses of nickel-copper ore at Dumbarton Mines Limited are being mined by a modified blasthole stoping method. The principal access to the mine is provided by a 15-degree decline, which, in conjunction with the use of ramps and declines for secondary access, maximizes the accessibility and mobility of trackless mining equipment. Sublevels are driven in ore on 80-foot vertical intervals and subsequently the ore, ranging in thickness from 15 to 30 feet, is slashed to its limits by a procedure of face sampling and test holing. Two longhole drill jumbos are used to drill off 40-foot vertical slices above and below these levels. Following blasting, the ore falls by gravity to the 500-foot horizon, where it is removed from drawpoints by load-haul-dump units and transported by truck to the main orepass. The rock is crushed to minus 3-4 inches and conveyed to surface by a 30-inch-wide wire rope suspended conveyor. This is achieved in two flights, a lower one of 290 feet and a main flight of 2260 feet. All aspects of the mining operation are discussed in the paper, including ventilation, services and safety.

Jan 1, 1973

By D. D. Tannant, H. Ozturk

Thin spray-on liners are increasingly being used as rock support in underground mines. The adhesive strength between the liner and the rock surface is an important design parameter. Adhesion tests were conducted to assess the impact on adhesion of the presence of oil, water, and dust on a substrate, and the roughness and grain size of different substrates. Other factors such as curing time, loading rate, and liner thickness were also considered. Adhesion was measured using a pull test of a 33 mm diameter elevator bolt attached to an over-cored section of liner with strong epoxy. Most tests were performed using Tekflex liner material, although five other liner products were also tested. Adhesive strengths of about 2 MPa can be achieved with Tekflex under optimal conditions. Long-term creep tests showed that the adhesive strength could drop by at least 50% when the liner carries load for about a month. Where the rock surface is contaminated with dust or the rock is weak in tension, it may be difficult to reach adhesion strengths of 1 to 1.5 MPa. As the thickness of the liner increases, the adhesive strength to a substrate appears to decrease.

Jan 1, 2007

By Arthur A. Cole

Although the metal silver has been known and prized from very ancient times, it is in the New World that the greatest silver camps have been found. This is shown in the following comparison: [] For the last few years, the World's annual production of silver has averaged about 240 million ounces troy. Of this total, the North American Continent contributes approximately three quarters, Mexico leading with 38 per cent, followed by the United States with 27 per cent, and Canada with nearly 9 per cent.[] Of the largest silver producers in Canada, the Sullivan takes first place. Although primarily famous as a lead and zinc mine, it produced, in 1926, more than 4.5 million ounces of silver. The Premier mine, in northern British Columbia, produced more than 3 million ounces. In Ontario, the largest producers in 1926 were the Nipissing mine, .with 1.9 million ounces, and the Keeley mine, with 1. 7 million ounces. The Mining Corporation produced 1.1 million ounces from mines in the Cobalt district proper, and an equal amount in South Lorrain; while from the Castle-Trethewey mine, in Gowganda, there was an output of slightly less than one million ounces.

Jan 1, 1927

By H. S. Fowler

The Consolidated Mining and Smelting Company has been in the business of mining and exploration since its incorporation in 1906. The Company has reports written as early as 1890. Consequently, its files contain a very large number of reports, and also of maps, of ail descriptions. REPORTS Before describing the filing of maps, a brie{ note on our general system of filing reports will perhaps clarify the discussion. Reports of a non-periodic nature, primarily those based upon examinations by field engineers, are separated from all other data and filed in what we know as the Mine Series System. Each property on which reports are written is given a serial number, known as the Mine Series Number. This serial number is assigned at the time the first report is filed and it remains permanently identified with the property, regardless of its state of activity. Our mine series numbers now total over 5,000. The serial number for a property may be found by referring to an alphabetical index of properties. MAPS We found it necessary to divide maps into two groups: (1) Maps of properties (2) Maps of areas

Jan 1, 1944

By R. B. STEWART

A few days ago, while reading a report of the late Dr. Robert Bell in preparation for this afternoon's meeting, I found some impressive figures concerning the magnitude of the Hudson Bay basin. From the waters of the Bay itself, this great territory extends eastward 500 miles, westward l,300 miles to the Rocky mountains, and southward to the source of the Red river. It has a width of 2,100 miles from east to west, and a length of l,500 miles from north to south. Its area is almost three million square miles. It is not, of course, my intention to review the natural resources of this vast territory, but to confine my remarks to that portion of it adjacent to the waters of Hudson bay. A number of erroneous ideas exist in the minds of many concerning this northern country, especially as regards its latitude and climate. Burwell, at the entrance of Hudson strait, is in the latitude of 60 degrees or roughly that of the north of Scotland. The southern end of James bay has about the same latitude as the northern end of Vancouver .island.

Jan 1, 1928

By Shahé Shnorhokian

Remnant pillars evolve towards the latter stages of mining in an orebody and act as repositories of mining-induced stress. It is therefore crucial to plan ahead as to their dimensions and location with respect to the local geology. A case study of a Canadian base metal mine was examined for the planned mining sequence scenario to identify the stress regimes acting on a future remnant pillar occurring between levels 4800 and 5100, near a brittle dyke. A mine-wide model was constructed in FLAC3D and input parameters included results from field measurements of the direction and magnitude of the principal stresses, and the geomechanical properties of the different formations. Prior to the study, the model was calibrated based on a 6-year record of mining-induced seismicity and rockburst events, focusing on large event clusters. The mining sequence followed at the mine was then used in the model to study the planned future extraction program around the remnant pillar. It is shown that the distance of the remnant pillar from the dyke and another orebody plays an influential role on the stress levels developed in the pillar.

Jun 1, 2012

By H. Rozovsky

This paper deals with the large iron ore concentrating plant owned by the Iron Ore Company of Canada. The plant is part of the Carol Project, which is being developed in the Wabush area of western Labrador. The mining and milling operations were officially opened in July of this year. The handling of fine material has always been considered a serious operational problem. The crushing, grinding and sizing of 50,000 tons of iron ore per day, in a dry state, could present sizeable problems in maintenance and orderliness. The operation, as a whole, embraces many recent developments in the iron ore industry. Mining operations include the latest techniques of jet piercing and blasting. Primary crushing involves a single crusher, which handles the complete production. Grinding of the ore includes the latest concepts of dry autogenous grinding in air-swept mills. The actual concentration of the ore is per-formed, in the wet state, by the use of spiral concentrators, with provision for possible flotation or magnetic separation, if required. The upgraded concentrates are either stored or pelletized, prior to shipment by rail to Seven Islands.

Jan 1, 1962

By A. J. Antony Chettupuzha

During a construction project, it is important to ensure that accurate and pertinent knowledge is delivered on time to appropriate personnel. The criticality of documents exchanged or referred to by various parties, evolves over the course of the project lifecycle. Determining the criticality of documents at different stages of the project can aid companies with managing the flow of information in an organized manner, while providing for the detection of potentially disruptive, erroneous material that could result in delays and costs. Therefore, it is crucial to determine documents which have the potential to disrupt a process (by virtue of being incorrect versions etc.) so that they may be isolated or prevented from entering or interfering with the active flow of information in a project, while also ensuring standard revisions of documents are recognized and accessed accordingly. Electronic Product and Process Management [EPPM] systems provide the capability to establish and map information flow between different parties in a construction project. Analyzing an EPPM system may yield information about the criticality of certain documents within an activity, as well as isolate characteristics peculiar to documents which can assist in risk mitigation. We propose methodology that identifies such critical documents.

Aug 1, 2013