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By Francis Chartrand

The Kwyjibo deposit is an iron oxide Cu-REE-F-Mo-Au mineralization of Mesoproterozoic age located in the Grenville Province approximately 120 km NE of Sept-Îles, Quebec (Figure 1). Occurring along the SE margin of the Canatiche granitic complex, the deposit is composed of several polymetallic showings that are related to different textural facies of magnetite. The mineralization process at Kwyjibo is complex, and is divided into Early Granitophile, Magnetite, Main Polymetallic and Specular Hematite stages (Cayer et al., submitted for publication). The Main Polymetallic stage, comprising chalcopyrite, pyrite, fluorite, molybdenite and REE-bearing minerals, is superimposed on pre-existing magnetiterich rocks. Discovered by SOQUEM Inc. in 1993, the Kwyjibo deposit shares many characteristics with other hydrothermal polymetallic iron oxide deposits around the world. Foose and McLelland (1995) suggested that this class of mineralization could occur in the Grenville Province. However, only a few polymetallic occurrences are known to be associated with low-Ti iron oxide deposits in the Grenville. Kwyjibo is one of the most significant examples of a polymetallic iron oxide deposit to have been found in the Grenville Province to-date.

May 1, 2003

By N. Hmidi, T. Yalcin, M. Papadakis, B. Hilscher

Mill tailings, containing iron sulphides in particular, pose an environmental concern since they constitute a potential source of acid mine drainage which can damage vegetation, harm soil and living organisms, and contaminate groundwaters. Proper disposal of acid generating tailings is therefore an important issue that must be addressed and resolved in a satisfactory manner. Placer Dome Canada operates a 4000 t/d gold cyanidation facility at Musselwhite mine, in northwestern Ontario, where the mill tailings have been classified as acid generating. This study was conducted to explore the effectiveness of froth flotation in removing the sulphide minerals from these tailings and producing a low-sulphur, non-acid generating material that could serve as a capping material for previously deposited tailings. Laboratory semi-batch flotation tests were carried out in accordance with an experimental design procedure, and a computer simulation program was developed to facilitate the evaluation of flotation performance. In this investigation, pH, collector concentration, and airflow rate were considered as the relevant flotation variables, and their effects were examined both experimentally and by simulation. Results have demonstrated that flotation can successfully desulphurize the Musselwhite mine tailings and render them non-acid generating.

Jan 1, 2004

"THE OTTAWA BRANCH, CIM, each year holds a symposium on a subject of topical interest. The symposium this year was on Canada's Offshore Mineral Resources, at which papers were presented by: Dr. Donald G. Crosby, chief, Resource Administration Di-vision, Department of Energy, Mines and Resources, Ottawa; John A. Beesley, head, Legal Division, Department of External Affairs, Ottawa; and David W. Smith, man-ager, offshore exploration and production, Shell Canada Limited, Calgary. Because of the interest which this topic holds for our members, and because of the wealth and significance of information presented, the three papers -representing the first comprehensive review of our offshore resources -are reproduced herewith. The opening remarks of the Chairman, Dr. F. K. North, Professor of Geology, Carleton University, are also recorded, together with a few of the questions asked by the large attending audience. The symposium was held February 13th, and was organized by Dr. W. M. Tupper, chairman of the Branch Program Commit-tee. Differences in the extent of the continental shelf will be noted in the papers. These differences are related to slightly different definitions of the continental shelf by the authors."

Jan 1, 1969

By J. E. Rowland

NIOCALITE is a new mineral species which has been identified in rock from the Oka district, Quebec. It occurs as prismatic crystals up to l 0 mm. in length and I mm. in width, in coarse, white, crystalline calcite with associated apatite, diopside, biotite, pyrochlore, and niobian perovskite. The crystals of niocalite are light yellow in col-our and have a vitreous lustre. The optical properties of niocalite (I) are as follows: Biaxial negative -2V = 56° a = 1.700, [ ] = 1.730 Birefringence y -a = 0.030 Optic orientation: X = b, Z/\c 12°, Y , /\a = 32° The specific gravity is 3.32 and the hardness is approximately 6 (Mohs scale). A detailed analysis performed on 2.4 gm. of hand-picked material reveals that niocalite is essentially a calcium niobium silicate. Table I gives the result of the analysis. Crystals of niocalite, apparently suitable for X-ray diffraction work, were selected, and single crystal photographs were obtained using both Weissenberg and Precession cameras. Initial difficulties were encountered in interpreting these films, and in correlating the crystal data with the optical data. The in-consistencies were explained by the fact that every grain examined was twinned to some extent.

Jan 1, 1957

By S. Castro

Hydrolysis of metallic ions depends on pH and the products of hydrolysis either activate flotation or can lead to inadvertent activation of gangue particles, but can also depress flotation of valuable components. One of the most recently studied topics is the use of seawater in flotation. Seawater is a concentrated NaCl solution (about 0.6 mol/L) that also contains considerable amount of Mg2+ and Ca2+ ions. The hydrolysis products of Mg2+ strongly depress flotation of molybdenite over the pH ranges over which they form in the process water. This effect can be eliminated by removal of hydrolysing ions from the process water or by carrying out the flotation at the pH over which such a hydrolysis can be avoided. The former can be exemplified by prior precipitation of the harmful hydrolysing ions as, for example, in the University of Concepcion Patent. The latter can be exemplified by the use of metabisulfite to depress pyrite in the flotation of Cu-Mo sulfide ores in seawater, the process that is carried out at much lower pH, which avoids formation of Mg2+ hydrolysis products.

Jan 1, 2017

By Sadough vanini Ali

Charpy impact energy of functionally graded steels produced by electroslag remelting in crack divider configuration has been modeled in various strain rates. It has been well known that majority of materials indicate different behaviors under different strain rates and temperatures. Therefore, modifying the elastic-plastic model considering the effects of strain rates and temperature gives us an acceptable prediction of these composites behaviors in impact test. In this investigation, graded steel was divided in to several layers in which the layers have the same strains under the impact. Constitutive equation describing the flow stress variations as a function of strain rates and temperatures, have been used to express the stressstrain behavior of layers. The parameter values of constitutive equation determined for all the layers via using the boundary conditions based on composite graded behaviors which were the characterized ferrite, austenite, bainite and martensitte phases. Consequently by applying the rule of phase mixtures and ascribing the impact energy of each layer to the area of stress-strain curve of the same layer, the whole impact energy of composite is the sum of layers impact energy with considering the layers volume fraction.

Oct 1, 2011

By K. Karan

Oxygen reduction reaction in PEM fuel cell cathodes involves participation of three reactants - oxygen, hydrogen ions, and electrons. Electrochemical reaction in the catalyst layer is, therefore, influenced by how these species are transported to the reaction site. The two-phase boundary locations at which percolating networks of ionically conducting electrolyte and electronically conducting Pt/C meet are feasible reaction sites. The electrolyte phase also provides pathway for the transport of dissolved oxygen. Most of the 3-D models describe the catalyst layer as an ultra-thin layer, thereby, losing useful information on the distribution of electrochemical reaction rate. In this paper, we extend our previous work on 2-D cross-the-channel modeling of PEMFC cathode based on agglomerate catalyst layer. In particular, we take a closer look at the influence of proton conductivity on the reaction rate distribution in the catalyst layer. As well, we re-examine the role of anisotropic transport coefficient of the porous transport layer (PTL), commonly known as the gas diffusion layer, on the current density distribution under the channel and the rib of the flow-field plates. Results from both a 2¬D and a 3-D models will be presented.

Jan 1, 2005

By V. G. Papangelakis, I. Guzman, S. J. Thorpe

Pressure oxidation (POX) leaching has been commercially applied to refractory gold ores since the 1980s. In the process, sulphide material is oxidized and dissolved in order to release the gold encapsulated in the sulphide matrix, making the gold available for further recovery. Redox potential is a significant parameter during POX, however it is only measured ex-situ at atmospheric conditions. In-situ redox potential measurement would provide instant information that allowing adjusting the process parameters accordingly. In the present study, redox potential measurements were performed during POX of sulphide material at high temperatures and high pressures. The working electrode was an Ir electrode combined with a flow-through reference electrode in a novel and robust configuration. Experiments were performed in a 2 L titanium autoclave, at 200–220°C, 50–110 psi oxygen overpressure, and 10–30% solids mass fraction. Temperature and oxygen pressure conditions were selected in order to reflect POX of refractory gold ores. Results show that the Ir electrode is consistent with theory and is able to perform well under these conditions, showing promise as a new in-situ sensor.

Jan 1, 2017

By N. C. Clarke, T. Wu, M. le Page, K. J. Henley

In 1994, Gold Mines of Australia acquired the rights to the historic Mt. Lyell copper mine, and commenced a feasibility study into expanding production. The ore was shown in laboratory tests to be amenable to single-stage, fully autogenous grinding (FAG) of underground primary crushed ore, and this route offered the maximum cost savings. Flotation performance was expected to be enhanced. However, batch flotation tests done on pilot-scale autogenously ground ore showed an unexplainable recovery loss of between 1% and 3% Cu. A second pilot plant trial was set up, with the ground product feeding banks of continuous flotation cells. Single-stage FAG, FAG/pebble and FAG/ball circuits were tested. Results confirmed a loss of about 3% recovery with single-stage FAG milling. The FAG/ball circuit eliminated the loss. Analyses showed that autogenous milling probably produced more chalcopyrite/pyrite composites and that recovery of these composites was lower than with ball milling. In size fractions below about 53 microns, where chalcopyrite is well liberated, copper recovery was less affected by milling method and flotation selectivity. It was concluded that for the Mt. Lyell situation, a FAG/ball circuit was preferable to single-stage FAG.

Jan 1, 2002

By J. E. Udd

"In early 2000, CANMET-MMSL was engaged by the Ontario Ministry of Labour (OMOL) to conduct an international study of the practices, in several key mining jurisdictions, of determining the criteria that are used to decide when the wire ropes used in mine hoisting are to be retired from service. Subsequently, the author visited key officials and institutions in Canada, the United States, the Republic of South Africa, the United Kingdom, Germany, and Poland. Material from the Australian province of New South Wales and Hungary was also included.The report that resulted included, among other sections: (1) the history of wire ropes and trends in manufacturing technology; (2) a review of mine hoisting practices; (3) the requirements regarding safety factors; (4) a review of the various operations and their potential future development; (5) the criteria for rope replacement; (6) potential future developments that could take place in both hoisting and rope inspection practices in Canada; and (7) recommendations.Subsequently, the report was issued by OMOL, and as a CD-ROM by CANMETMMSL. In this paper the author presents the key findings and the recommendations made in the study."

Jan 1, 2004

By J. Buckle

"Recognition of the diamond potential of the Wawa subprovince was initially determined from regional data using a kimberlite model. The world’s largest stable Precambrian craton, the Superior Province, is considered to be favourable for the emplacement of diamondiferous kimberlite. The Wawa area is located near the intersection of intra-craton structures visible in the regional magnetic data.The Enigma project is located north of the town of Wawa in northern Ontario. From field evidence and background research, it became obvious that in the Wawa area there were at least two potentially diamond-hosting events, Archean lamprophyric volcaniclastics and Proterozoic kimberlites. The host lamprophyric rock does not contain the classical KIM signatures. However, to complicate the Enigma, stream sediment samples within 200 m of the diamond-bearing lamprophyre produced a typical suite of kimberlite indicator minerals.The micro- and macro-diamond content of the Wawa lamprophyric volcaniclastic rocks is typically 0.2 ct/t to 1 ct/t, although it can be higher locally. The economic diamond potential of these Archean dykes, sills and irregular lamprophyre bodies is still under-explored (Kaminsky, 2002, unpubl.). Oasis Diamond Exploration is currently exploring the area using geophysical, geochemical, and geological data."

Jan 1, 2002

By C. Siac

"It is a widely held view that in the 21st century, the mining industry will be dominated by a relatively small number of large companies, truly global in scope and internationally staffed (Gooding, 1997). Interestingly enough, most of the exploration and exploitation activities are being carried out by junior and major mining companies from common law jurisdictions in civil law countries, in particular in Latin America, where in recent years, the region has ranked first as a destination for exploration dollars, thanks to the reforms undertaken by some countries to amend their legal framework to attract foreign investment. From a lawyer’s point of view, this is where the main challenge lies: how to bridge the gap between the two legal systems.In order to avoid pitfalls, common law lawyers should be more diligent and proactive when dealing with civil law jurisdictions, given the different systems of law, standards, traditions and customs. Common law lawyers cannot be expected to be well-versed in civil law but they should not be completely unfamiliar with it either. A balance should be struck to ensure clients’ needs are professionally taken care of and that common law requirements and standards are met."

Jan 1, 2003

By F. Hassani, D. O’Donnell, M. Momayez, P. Guevremont

Shotcrete is a practical and economical support system in many Canadian underground mines. Although shotcrete technology has gained acceptance in the mining industry, there are some problems that have emerged with respect to quality assessment and thickness measurement of the liner. This paper presents recent tests performed with miniature seismic reflection technology (MSR) developed and patented at McGill University primarily for thickness measurement of this heterogeneous liner. MSR is also capable of providing information regarding the quality of shotcrete in terms of its mechanical properties such as modulus of elasticity and Poisson’s ratio. Work was performed on site in an underground mine in Ontario, Canada. This paper also presents the results from laboratory tests performed on fiber-reinforced and non-reinforced shotcrete panels that were used to assess the P-wave velocity in both materials. The results of these tests were used in a second site investigation. The NDT thickness measurements showed good agreement with direct thickness measurement such as coring. In addition, the MSR technology has the advantage of being more accurate and more affordable compared to other non-destructive testing (NDT) systems in the market.

Jan 1, 2002

By R. W. Schutz

"Titanium possesses an exceptional and wide-range resistance to chlorides and their compounds when compared to most corrosion-resistant engineering alloys (CRAs) used in the chemical process industry. This natural resistance to chlorides stems from titanium’s protective, tenacious, and readily rehealable titanium oxide surface film, which is chemically stable over a wide range of pH and redox potentials in aqueous environments. This passive film explains titanium’s elevated resistance to anodic pitting, crevice and stress corrosion, and erosion-corrosion in aqueous chloride environments.Guidelines for successful selection and application of industrial titanium alloys are derived from an extensive laboratory test database and more than forty years of industrial/chemical service experience. These guidelines are simplified, and alloy corrosion performance is assessed with respect to four basic aqueous chloride service categories where selection or consideration of titanium is highly merited. An overview of historical titanium alloy applications in chloride-rich environments in a wide variety of process industries substantiates their exceptional chloride tolerance. These industrial titanium alloys are cost-competitive with stainless steels and nickel alloys, readily commercially available, and routinely fabricated and welded in the shop and field via well-established methods."

Jan 1, 2002

By G. Langlands

"R. Tenbergen Is this flotation machine suitable in the flotation ofInco ball mill discharges where we have a coarse feed at 60% solids?Reply Experience has shown that there is not a significant increase in the wear life of these machines when handling coarse material (8 mesh) at 60% solids. A common practice in Europe is shut down on the week-ends.The material is allowed to settle and on start-up an injectic of air for 15 seconds is sufficient prior to start-up. At,mining we put our unit in the middle of a bank of 44 cells and in order to ensure severe sanding we shut the aker cell down while the remaining cells kept running. After 20-25 seconds of air the cell started without trouble.P. Mahant Is there a build-up inside the impellor shaft housing? Falconbrige Ltd.Reply There is no sand build-up but rather a scale build-up which due to a flexing action frees itself periodically. Part of the design of the machine permits a water injection into the shaft housing to free any build-up. This is done in Europe during the week-end shut down."

Jan 1, 1984

By Jean-François Doyon

Les aspects environnementaux des activités minières d?exploitation réalisées sur le territoire québécois sont encadrés par divers cadres légaux, réglementaires ou autres (directive, politique, guide) tant au niveau provincial que fédéral. Ces cadres s?appliquent à l?un ou l?autre des trois grandes étapes du projet, soit lors de l?étude d?avant projet, pendant l?exploitation ou à la cessation des activités d?exploitation. Comme la réglementation environnementale est de plus en plus nombreuse, ces dernières années, cette présentation vise à exposer les principaux cadres provinciaux et fédéraux actuellement en application au Québec pour le secteur minier et à en dégager les particularités. ABSTRACT The environmental aspects of mining activities carried out across Quebec fall within the scope of various legal, prescribed or other frameworks (directives, policies, guides) at provincial and federal levels. These frameworks apply to one or another of the three major steps of a project: preliminary design, mining and closure. As the number of environmental regulations has greatly increased during the past few years, the object of this presentation is to state the main provincial and federal frameworks currently applicable in Quebec for the mining sector and to identify their special features.

Nov 1, 2002

By G. W. Neumann

"In order to avoid pollution of water in Flemming Brook and Little River, which drain the area in which the Brunswick No. 12 Mine and Concentrator are located, the company has gone to considerable expense in preparing tailings storage and effluent setting ponds. The attached drawing gives a plan of the six settling ponds together with elevations of the dikes and the effluent weirs.All original dikes for the six ponds were constructed from humus-free clay and rock material, which was obtained, preferentially, by excavating from within the dike area. Run-off water, precipitated on the outside slopes of the dams will drain off without contacting the tailing material. A ditch was made north of the dam site to deflect surface run-off to the east into a branch of Flemming Brook.A secondary dike, made from tailings, has recently been erected on No. 1 and No. 2 tailings pond inside and above the earth-filled dike which serves as a roadway. Run-off from the tailings dikes will be retained inside the ponds by ditching between the roadway and tailings dike into ponds 4 and 6."

Jan 1, 1969

By Steve R. McCutcheon, Cees R. Van Staal, John P. Langton, Leslie R. Fyffe

Abstract -The volcanic-dominated Tetagouche Group in northern New Brunswick contains numerous massive-sulfide deposits and intimately associated metalliferous sediments. The massive sulfides are generally hosted by Llanvirnian-Llandeilian volcaniclastic sedimentary rocks of the Nepisiguit Falls, Patrick Brook, and Boucher Brook formations. These formations are intercalated or closely associated with rhyolitic-dacitic flows and/or domes, and minor continental tholeiites of the Flat Landing Brook Formation. Pyroclastic rocks are relatively scarce in the silicic volcanic complex. Tuffites and epiclastic sandstones, of the Nepisiguit Falls and Patrick Brook formations, respective­ ly, generally occur along the fringes of the silicic volcanic complex. The flows and tuffites are intruded by quartz- and feldspar-phyric rhyolite (porphyry) dykes, sills, and domes. Although the volume of the silicic volcanic complex is large, evidence for a previously proposed collapsed-caldera model is lacking. On the basis of host-rock type and stratigraphic position, the sediment-hosted massive sulfides have been divided into three groups: the Brunswick-, Caribou- and Halfmile Lake-type deposits. Syngenetic feeder pipes and asociated alteration zones are generally not present beneath the Caribou- and the Halfmile Lake-type deposits and, if present at all, are poorly developed underneath the Brunswick-type.

Jan 1, 1992

By Michio Okada

Dissociative adsorption of hydrogen (deuterium) on thin gold films grown on Ir{111} surface has been studied with temperature-programmed desorption using a quadrupole mass spectrometer and nuclear reaction analysis. Thin Au{111} films are epitaxially grown on Ir{111}. Surprisingly, H2 (D2) can dissociatively adsorb on these Au{111} films, although it is well known that Au surfaces are noble enough not to dissociate hydrogen molecules [B. Hammer and J.K. Nørskov, Nature 376, (1995) 238]. We attribute this to the sensitivity of hydrogen to changes in the local surface properties, e.g., electron localization (the narrowing of the s-band, the s-band center model), which could explain the upto now unexpected high for the reactivity of a thin Au{111} surface. Moreover, we found that H (D) atoms can be confined into a Au thin film and/or the interface between an Ir surface and the thin Au film. We demonstrate how anomalously reactive thin Au films grown on an Ir surface are, and also compare the Au films with Ag films grown on Ir to test the validity/generality of our proposed s-band center model.

Oct 1, 2003

By W. Dan Hausel

"Hundreds of diamonds have been found in the United States. The majority of the discoveries occurred during the 19th century as a by-product of placer gold mining. Most of these early diamond finds have no known source, and in many cases are situated in areas unfavorable for diamond exploration based on current models that require kimberlite or lamproite to be emplaced in a stable Archean craton or Proterozoic craton margin.Diamonds have also been recovered in situ from lamproite at Murfreesburo, Arkansas, from kimberlite in the Lake Ellen region of Michigan, and in several kimberlites in the Colorado–Wyoming State Line district. Unverifed reports also suggest that diamonds may have been recovered from other related intrusions at a number of localities in the United States.IntroductionTo date, diamonds have been recovered in situ from kimberlite in the Colorado–Wyoming State Line district and from a kimberlite in Michigan. Additionally, diamonds have been recovered from lamproites in Arkansas. Diamonds have also been reported from kimberlite in Kansas, and from peridotite in New York and Maryland. However, these latter reports have not been verified."

Jan 1, 1995