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By M. J. Nicol, C. van Wensveen

The kinetics of the oxidation of thiosulfate by copper(I I) in ammoniacal solutions have been studied in the presence and absence of dissolved oxygen. The formation of an intermediate mixed ammine/thiosulfate copper(II) complex ion has been confirmed and the rate of the reaction monitored by simultaneous on-line spectrophotometric, dissolved oxygen and potentiometric measurements. The rate of the anaerobic oxidation of thiosulfate by copper(II) was found to be orders of magnitude slower than that in the presence of dissolved oxygen and is inhibited in the presence of ammonia and anions such as sulfate and chloride as a result of competition with thiosulfate for the axial coordination sites on the copper(II) tetrammine complex. In the presence of dissolved oxygen, it was found that the copper(I) thiosulfate complexes are only very slowly oxidized while the copper(I) diammine complex is rapidly reoxidised to the copper(II) state. Thus, the initial rapid reaction with copper(II) leads to a pseudo steady-state condition in which the concentration of copper(I) is relatively constant and the rate of oxidation of thiosulfate can be predicted from the measured rate of oxidation of copper(I) by oxygen in ammoniacal solutions. The effects of the concentrations of ammonia and thiosulfate on the oxidation rate can be rationalized on the basis of the above coupled to the species distribution of copper(I) in the ammonia/thiosulfate system. It is shown that, with relatively simple measurements of dissolved oxygen and copper concentrations, the rate of oxidation of thiosulfate can be predicted under typical leaching conditions.

Jan 1, 2005

By Hugh S. Spence

This paper deals with an occurrence of radium ore near Wilberforce, Haliburton county, Ontario, upon which development work has recently been undertaken and which seems more likely to prove of commercial grade than any other deposit' of radioactive minerals hitherto found in Canada. This occurrence is sometimes called the Richardson property, after Mr. W. M. Richardson, the discoverer, and will be so referred to in the present paper. Occurrences of radioactive minerals are not uncommon in eastern Canada, and a number are recorded in the literature. The earliest of such references is probably that in Geology of Canada, 1863, where is mentioned an occurrence of uraninite at Mamainse, on the east shore of lake Superior. The mineral was first described by J. L. Leconte, in 1847, under the name of coracite, and was said to occur in a two-inch vein at the contact of trap and syenite. Search for this locality in recent years has proved unsuccessful. Obalski, in 1894, mentions (1) the occurrence of uraninite at a mica mine near Murray Bay, Que. In 1903, Obalski records (2) tests made on this uraninite by Rutherford and the Curies and the determination in it of the then newly-discovered element radium. In 1901, he mentions (3) the occurrence of uraninite at the Villeneuve mica mine, on the Lievre river, and of samarskite at the Maisonneuve mica mine, in Berthier county.

Jan 1, 1930

By Gordon W. Parsons, Ross E. Sampson

"THIS PAPER will trace the work done in bringing the Munro underground ""A"" •Orebody into production to replace the open pit, which was scheduled to be completed early in 1959. Included will be an outline of the exploration work and early planning, and of the final decisions on mining methods. Some of the more detailed work will be described and reasons will be given for the decisions made regarding development work, mine ventilation, ground support, and equipment. Brief mention will be made of open pit operations, as these have had some influence on underground development. Also, some of the main geological features of the ore occurrence will be de-scri0bed, as these had to be taken into consideration when making decisions on ore development and mining methods.LOCATION AND HISTORYhe Munro mine of Canadian Johns-Manville is in Ontario, approximately 50 miles east of Timmins and 40 miles west of the Que-bec-Ontari-0 boundary. The producing orebody is in the southwestern part of Munro township. Property controlled by the Company extends nortl1westerly about 2¥2 miles into Beatty township, on which two other interesting asbestos-bearing zones have been partially expl-0red. Active exploration work on the property was started in March, 194.9, and continued until the summer of 1950."

Jan 1, 1960

By George E. Cole

"It is a truism that the metals, and particularly the precious metals tend to monopolize the attention of those interested £n the mineral industry. This is a tendency to be mildly, but actively and continuously combatted if we are to have a well-rounded mineral development." There are in the province of Ontario a number of industries centred about the non-metallic minerals. Too little is heard of the part these play in our industrial life. It is with the intention of showing what the gypsum industry is doing in Ontario that this paper is written. The writer lays no claim to any originality in the discussion and merely offers some material in an endeavour to assist in bringing about that 'well-rounded mineral development' sought for Ontario. M. Y. Williams in his "The Silurian Geology and Faunas of Ontario Peninsula and Manitoulin and Adjacent Islands"1 in discussing the industries dependent on the Silurian rocks of south-western Ontario points out that "the splendidly ordered gypsum mine at Caledonia, formerly owned by the Alabastine Company of Paris, and now owned by the Ontario Gypsum Company, is a revelation to the average man, who disconnects mining entirely with this part of Ontario". This region is better known as one of the richest and most thickly settled agricultural areas in Canada.

Jan 1, 1925

By J. S. Fox

Major-element data for unaltered, unmineralized felsic host rocks from a number of stratigraphically simple, massive volcanogenic Zn-Cu(-Pb) sulphide deposits of low metamorphic grade have been compiled. The petrochemical affinities of these host rocks have been determined (by standard means and by discriminant analysis) and compared. This comparison indicates that volcanogenic deposits in felsic terrains are not restricted to the classical calc-alkaline rock association as previously thought, but can actually be hosted by rocks showing a range of iron content. There is a positive correlation between differentiation trend and are tenor. Zn-Cu ores usually have iron-rich felsic hosts (most Canadian Shield deposits); Pb-Zn -Cu ores have iron-poor felsic hosts (Japanese, Iberian and Tasmanian deposits). This parallels the antipathetic relationship between iron content and background lead levels evident in young, unmineralized, island arcs as well as in many older belts. Correlations between differentiation trend on one hand and massive ore mineralogy and the relative proportions of various rock type (including rhyolite, quartz-porphyry and coarse pyroclastic rocks) on the other are also evident. It is concluded that the recognition of a calc-alkaline differentiation trend cannot be used as a prospecting guide, as has previously been proposed. However, in view of the above correlations, the recognition of a given trend may aid in the formulation of an effective exploration philosophy.

Jan 1, 1979

By J. E. Dutrizac, J. M. Zinck

Ferrihydrite is often the initial precipitate resulting from the rapid neutralization of Fe(III) sulphate solutions, and it seems to be a major constituent of zinc plant neutral leach residues. The most important parameters affecting ferrihydrite precipitaton are temperature, solution pH and the neutralization rate. Low temperatures and rapid neutralization rates yield poorly filterable ferrihydrite, whereas higher temperatures and slower neutralization rates produce readily filterable precipitates; in all instances, however, the precipitates are two-line ferrihydrite. Significant amounts of Zn are incorporated in the ferrihydrite precipitates, and the Zn contents increase with increasing Zn concentration, pH or temperature. Generally, the sulphate contents of the precipitates decrease as the Zn contents increase, and this may indicate that the Zn is adsorbed on the ferrihydrite. Discrete Zn phases were not detected. Neither Cd nor Tl is precipitated with ferrihydrite, although thallium jarosite co-precipitates with ferrihydrite at high Tl concentrations and elevated temperatures. Virtually all of the Sn added to the solution precipitates with the ferrihydrite, but the tin is believed to be present as intimately admixed amorphous SnO2.nH2O. Although selenite extensively precipitates with the ferrihydrite, selenate remains mostly in solution, likely because of the close similarity of the SeO4 2- ion to the SO4 2- ion which is present in high concentrations and saturates the available sites for anion adsorption.

Jan 1, 1998

By G. B. Langford

UOCK bursts are a phenomenon about which insufficient is known. This l.~ statement has a twofold meaning. In the first place, far too many people, both inside and outside of the mining industry, are woefully ignorant of the whole subject, and secondly, as those who are face to face with the problem in the mines realize, our knowledge of rock bursts is inadequate. The first group embraces the general public, who have never been enlightened on the subject, and a great many geologists and engineers who have never shown more than a curiosity about it. Such technical men do not realize what a vital problem it is to our mining industries. They are usually thankful that bursting ground is not their problem, and leave it to those unfortunate enough to run into it. From such men one often hears the pious opinion that if proper mining methods were used there would be no problem. It is hoped that this paper will give these people a different viewpoint. Those in the second group deserve much credit for what they have done and are doing. They are fighting a large and difficult problem. In the pages that follow, I have tried to give a bird's-eye view of that problem, and suggest new ways in which it may be attacked.

Jan 1, 1941

By K. N. Bolatbaev, S. S. Naboichenko

The initial rates of dissolution of pyrite, chalcosine, sphalerite and galena in acidic sulphate solutions under oxygen pressure were measured in the range of Poe = 0.2-1 MPa, 130-180 °C, [H2SO4]0 = 0.2-0.7 M, and in the presence of surface-active agents and agitation producing Re = 4-16 x 103. Reaction orders, activation energies, and values of reaction constants for these oxidation reactions were established. The reactions also were shown to be diffusion-controlled; and the rates demonstrate a linear dependence on the surface area of the sulphides. A surface reaction model, in which oxygen is transported through a solid layer of surface products, has been advanced. The initial stage of high-temperature interaction at pH <7 is suggested to involve a chemical activation of the sulphide surface and is described by the following general reaction: MenSm + H3O+ Men-1 Sm-1 (HS-)s + H2O The subsequent oxidation of surface complex HS- to S0 or SO2-4 occurs with the assistance of Fe(III), Cu(II) ions depending on temperature and the redox potential of the medium, which are defined by oxygen pressure and composition of the reaction mixture, especially concentrations of H2SO4 and metals with variable valence. General process kinetics are complicated due to the formation of by-products on the basis of Fe3+ Pb2+, Cup ions, which displace the kinetics into the diffusion region.

Jan 1, 2004

By P. Pal Roy, R. B. Singh

"This paper focuses on a number of interesting results to establish the theory and principle of air-deck blasting. It also gives the mechanism of breakage that takes place in air-deck blasting under varying charge load conditions. With these aspects in mind, the mine management can implement this up-coming technology to enhance safety and higher productivity. IntroductionThe method of air-decking has become an increasingly popular technique in production and presplit blasting. In the blasthole, an explosive column is combined with an airchamber. The main aim of the technique is to control breakage through effective distribution of explosive energy and thereby enhance uniform rock fragmentation. An air column lowers the initial pressure of the explosive products and simultaneously increases the time of interaction for the detonation front with the surrounding rock, which enhances rock breakage.To study air-deck blasting, CMRI initially conducted experiments using indigenously developed, low-cost wooden spacers of different sizes and strengths. Air-deck blasting was first tried using these spacers in 1993 at Jambad OCP, ECL and Chasnalla OCP, IISCO. The experiments were extended in 1994 at Bermo Mine, DVC. The results were subsequently published by Pal Roy et al., in 1995. It is worth mentioning that the performance of air-deck blasting during this period was only compared with conventional blasting practices without going into detail of the theory behind the process."

Jan 1, 2001

By M. Barati, K. Ebrahimi-Nasrabadi, P. W. Scott

"The conversion of cryptocrystalline magnesite to caustic magnesia was studied experimentally at temperatures of 400–1,200°C and for calcination times of up to 8 h. A differential thermal analysis– thermal gravimetric analysis showed that decomposition begins at temperatures as low as 340°C and is completed at 600°C. Specific surface area, iodine adsorption number, crystallite size, and loss on ignition were measured to characterize the product quality. It was found that high-quality caustic calcined magnesia can be produced in a narrow temperature (600–650°C) and time range (1–4 h).RÉSUMÉ La conversion de magnésite cryptocristalline en magnésie caustique a été étudiée de manière expérimentale à des températures de 400 à 1200 °C et pour des temps de calcination atteignant 8 heures. Une analyse thermique différentielle – analyse thermique gravimétrique montre que la décomposition commence à des températures aussi basses que 340 °C et qu’elle est complète à 600 °C. La surface spécifique, l’indice d’adsorption de l’iode, la taille des cristaux et la perte au feu ont été mesurés afin de caractériser la qualité du produit. Il a été trouvé qu’une magnésie caustique calcinée de grande qualité peut être produite dans un petit écart de température (600 à 650 °C) et dans une période de temps variant entre 1 et 4 heures."

Jan 1, 2015

By D. D. Campbell

The Hat Creek coal deposit s occur within folded and faulted Tertiary (Eocene) strata of the Coldwater Group, which comprises weakly lithified shales, siltstones and conglomerates underlying the floor and lower flanks of the valley of Upper Hat Cr eek . This upland valley,16 miles in length and 2-4 miles in width, is located within the eastern foothills of the Coast Mountains, 120 miles northeast of Vancouver, approximately midway between the towns of Lillooet and Ashcroft, in the Interior Dry Belt of British Columbia . Most of the valley floor is covered by till and glacial outwash deposits ranging up to 500 feet in depth. Became of this overburden cover , the majority of the data on the coal deposit have been obtained from diamond drilling done during 1974?76 by the property owner, B .C. Hydro and Power Authority. Because of the limitations imposed by the lack of out crop, the Tertiary geology at Upper Hat Creek is imperfectly known; however, it appears from correlation with other coal-bearing Tertiary remnants in the southern interior of the province that these remnants, including Upper Hat Creek, may represent preserved segments of the western shoreline of a Tertiary continental sea along which deltaic swamps developed and were sustained for unusually long stable periods, giving rise to the world&apos;s thickest known coal beds.

Jan 1, 1977

By R. MacRosty

The demand to increase production levels in smelting furnaces has driven the increase in the power levels. Consequently, greater cooling capacity of the furnace shell has been necessary, resulting in the widespread use of water-cooled elements to protect the refractory linings. Since water ingress into the furnace is an explosion hazard, monitoring and maintenance of the water-cooled elements is of key importance. Some of Hatch&apos;s recent research and development efforts have been focused on methods to provide an increased level of monitoring of water-cooled furnace elements; this paper focuses on two technologies developed for this purpose. The first involves the installation of a fibre optic temperature sensor in a water-cooled tapblock. The sensor is capable of providing high accuracy temperature measurements with a fine spatial resolution throughout the tapblock. Hatch has already developed a diagnostic system that uses multivariate statistical analysis to interpret the large quantities of data generated by the sensor. A second technology under development is concerned with enhancing the operating integrity and safety through detection of leaks in the water circuits. A successful leak detection strategy requires minimal maintenance and the ability to detect minute leaks. An instrument that meets these criteria has been investigated and is currently under development. This paper focuses on the technology and results from the test work that has been completed to date.

Jan 1, 2007

By J. S. Godard

The mining developments in western Quebec have shown the ores of this district to be more complex in character than was at first expected. When the initial discoveries were made it was thought that the ores would be similar in character to those of Kirkland Lake and Porcupine areas. Developments have since shown that although the ores along the southern margin of the belt are somewhat similar, those within the belt, constituting by far the greater proportion, are vastly different, being complex mixtures of base-metal sulphides carrying values in the precious metals. These mixtures of base-metal sulphides of copper, zinc, and iron, present several problems to the metallurgist, especially in their concentration into marketable products. For the purpose .of this paper the following classification may be made of the ores of the district. Group I. - Milling Ores: (a) Ores in which~ arsenopyrite is the predominating sulphide. In this class of ore the gold occurs in fractures in the quartz and is associated to a lesser extent with the arsenopyrite and pyrite. Examples of this class of ore are the Granada, south of Pelletier lake, and the O&apos;Brien and the Thompson in Cadillac township. (b) Ores in which iron pyrite is the predominating sulphide and gold is the valuable constituent. This may also be classed as a concentrating ore-Group III.

Jan 1, 1928

By M. S. Fotheringham

Recognition of the Growing Importance of Iron and Steel Few Canadians have yet become aware that Canada&apos;s vast iron ore resources, the greater part of which is only now beginning to be developed, will inevitably have a profound effect on the entire Canadian economy, benefitting in some measure the lives of all Canadians. The great iron mining developments of Ontario, Newfoundland, Quebec, and Labrador are destined to make Canada one of the world&apos;s major producers and exporters of this material, on which our industrial civilization is?based. These developments will create new employment, new communities, new transportation facilities, and new investment opportunities. Iron ore is the foundation and the keystone of modern mechanized civilization. The most prosperous nations of the world are the highest per capita consumers of iron and steel, and in these countries the per capita consumption is increasing steadily despite the advent of light metals, plastics, and other competitive materials. Three-quarters of the human race have too little steel -and consequently too little mechanization -to provide for themselves the necessities and comforts of civilized living. Progressively they will demand, and acquire, the machines, the transportation and communication facilities now lacking, and they will win them by making greater use of the world&apos;s iron resources. It is the good fortune of this generation that Canada&apos;s &apos;iron age&apos; is just getting well under way.

Jan 1, 1951

By CRO CRO

Elk Valley Coal?s Cheviot Project is located in the Alberta foothills south of the town of Hinton. The mine has been in operation now for the 3 years. The start up and subsequent operation of the Cheviot project has been directly influenced by the Cardinal River Mine. As the Cardinal River Mine was winding down due to reserve depletion in 2004, the price of seaborne traded metallurgical coal jumped to record levels and customers began aggressively seeking new sources of supply. Several months later, the owners of Elk Valley Coal decided to begin mining at the Cheviot mining area, extending the life of the area?s operations by over 25 years. The Cheviot Project had been delayed by low coal prices, ownership changes and a complicated and lengthy regulatory process fueled in large measure by stiff opposition from a number of major environmental organizations. Chief to the startup of the project was the construction of a 23-kilometer-long haul road that would connect the new coal measures to the existing Cardinal River processing and rail facilities. Construction of this road was completed with the first coal truck making its first trip in October 2004. This paper will look at some of original assumptions, the actual mining experiences and the lessons that were learned while moving from the drawing board to the current development as it exists today.

May 1, 2007

By J. E. Hawley

"IntroductionA STUDY of the trace elements in the ash •of coals from nine seams in the Sydney coalfield, Nova Scotia, was undertaken at the suggestion of Dr. W. A. Bell, Geological Survey of Canada, as a part of a larger study of these and other Nova Scotia coals being made by the Geological Survey and the Nova Scotia Department of Mines under the direction of Dr. P. A. Hacquebard.The main purpose of this investigation has been to •determine if a knowledge of the trace element distribution might be of assistance in the recognition of individual seams, the distinction of which is not always easy or positive in folded and faulted strata by ordinary stratigraphic and structural means.The study has been so conducted as to afford information on the variation of trace elements in individual petrographic intervals or divisions in each of the seams examined, intervals determined by Dr. Hacquebard on the basis of their banded ingredients, vitrain, clarain, durain, fusain, etc, as observed under the microscope in polished sections. The results, as well, indicate the trace element composition of the coals of the area as a whole, and quantitative data for fifteen elements are given, along with concentrations of thirteen other elements, stated in terms of intensity ratios. Data on distribution of germanium, though considered here along with other elements, are dealt with elsewhere*."

Jan 1, 1955

By F. E. Patton

"IntroductionAT NORANDA, the strength of the ore and wall-rocks per-mitted mining in large open stopes. While some of the orebodies were small and could be mined out in one stope, in most cases their size was such that it was essential that ore pillars be left during the first stage of mining. In these cases, backfilling has been necessary for ground control and to facilitate the later recovery of the ore in these pillars.This paper discusses the development of the •backfill and •its use in pillar recovery.GeologyThe ore bodies at Noranda occur as replacement deposits in a block of rhyolite flows and breccias, bounded on the north by the Horne Creek fault and on the south by the Noranda Andesite fault. Mineralization consists of pyrite, pyrrhotite, magnetite, chalcopyrite, sphalerite, gold, and various tellurides.The main orebody is a massive sulphide deposit designated the 'H' orebody. It is elliptical in plan, measuring roughly 400 feet by 800 feet, and is divided into two zones -Upper H, extending from surface to the 1,500-foot level, and Lower H, from the 1 ,500-foot level to just below the 3,000-foot level.Mining MethodsOpen stope mining in both Upper H and Lower H zones has been fully described in previous publications (1). A brief review only of the mining methods will be given here."

Jan 1, 1952

By R. J. R. Schaller

NO. 3 winze, the sixth shaft to be sunk on the San Antonio property, is practically a duplicate of No. 3 shaft, which was the main shaft prior to the installation of the larger hoisting equipment in 1939. It is collared on the tenth, or 1,500-ft., level, and goes down vertically to the sixteenth, or 2,500-ft., level, with a loading pocket, spill pocket, and sump below this. It is 1,000 feet east of No. 3 shaft. All ore, men, and materials are handled through the latter. The winze location with reference to the rock formation is shown in Figure 1. (In plan, this section strikes N.30°E. and cuts most of the main orebodies of the mine normal to their strike.) It is collared eighty feet inside the footwall contact of the basalt and cuts through it before reaching the eleventh level. In this location there will be no ore tied up in shaft pillars, as the closest ore to the shaft is on the tenth level, and here it is eighty feet northeast of the collar. The winze headframe and hoist-room straddle the main haulage to the No. 3 shaft, on the tenth level (see Figure 2). At no time during the excavation for the headframe and hoist-room was the general routine work of this haulage held up.

Jan 1, 1941

By A. Haldar

The major problem encountered in the casting of hypereutectic Al-Si alloys is the stoppage of flow below the rigidity level of solid fraction. In this study, the flow stoppage mechanism was studied using three Al-Si alloys with 14%, 18% and 22% silicon. The horizontal foam patterns used were 12.50 mm (0.50 inch) wide with two section thicknesses 12.50 mm (0.50 inch) and 6.25 mm (0.25 inch) with a common sprue. The primary silicon distribution along the length of the casting was studied to determine the mechanism of flow stoppage. It was found that the surface of the flow tip of Al-14%Si alloy was smooth with a few undulations. As the silicon level increased, undulations at the flow tip increased. The number and size of undulations were maximum for the Al-22%Si alloy. Microstructural analysis using optical image analyzer revealed that the flow tip consisted mainly of eutectic silicon in the aluminum matrix and a few primary silicon crystals (PSC). The PSC were in the interlocked condition few centimeters behind the flow tip. It was also found that the gap between the flow tip and the PSC concentrated area increased with an increase in silicon level. Phase characterization was done with SEM-EDX to identify the precipitating phases.

Jan 1, 2007

By A. R. Chambers

Malagash received its name from the Indians many years ago on acco.unt of its turbid (milky) waters, although,&apos; the red men did not appreciate the significance of this turbidity, and were, of course, entirely ignorant of the crystal beds of pure salt that lay beneath their feet. The salt lake of the Mississippian, or Lower Carboniferous period, in which these beds occur, was apparently a large one, for there is evidence of its existence at intervals all the way from Sydney, Cape Breton, to St. John, New Brunswick, 300 miles as the crow flies, and there is no knowing what its other dimensions may have been, as much of this horizon is now buried on the one side beneath the waters of the Gulf of St. Lawrence, and on the other underneath the Atlantic ocean. About midway of the area and underlying the counties of Colchester and Cumberland, there occurs a synclinal basin of which the Malagash salt outcrop forms only a small portion of its northern limit. This basin has been described very fully by A. C. Hayes. (1) The operations carried on at Malagash since Hayes wrote his report have brought to light very little in the way of new geological data, except to confirm his pre-dictions as to the probable faulting of the salt strata, and the effect which these faults would have on mining operations.

Jan 1, 1924