Search Documents

By Mosquera. J.

Tailings Storage Facilities (TSFs) are vast structures that respond to site-specific characteristics, rate of production, placement techniques, and the physical and mechanical properties of tailings. As a common denominator, TSFs are in some degree vulnerable to failure due to liquefaction, poor management, slope instability and/or unusual climatic events. In practice, stability of TSFS is determined by calculating a minimum Factor of Safety (FOS) using the Limit Equilibrium Method (LEM). However, it has been proven that relying exclusively on the limit equilibrium approach is not accurate because it is basically a static method that does not take into account the stress-strain distribution and displacement experienced by the constitutive materials of a TSF. In order to overcome these limitations of the LEM, the finite element method - Shear Reduction Technique (SRT) has been used as a more reliable tool for TSFs stability assessment. This paper presents a comparative stability analysis between an upstream tailings storage facility (UTSF), and a water retention tailings dam (WRTD) under static and pseudo-static states using simplified and rigorous LEMs and the SRT. Additionally, and taking into consideration the intrinsic uncertainty of tailings properties, sensitivity and probabilistic analyses in the form of Monte Carlo Simulation (MCS) and the Point Estimate Method (PEM) are applied to determine the Probability of Failure (Pf) and Reliability Index (ß) of each TSF. It is shown that the friction angle of UTSF?s foundation and the core?s cohesion of the WRTD are the main variables that govern stability. Further analysis shows that the WRTD has a higher reliability index and a lower probability of failure than the UTSF.

Aug 1, 2013

By L. Dorador

"In block caving projects, the rock mass fragmentation process plays a controlling role in the design and success of the operation. Poorly understood, however, is the secondary fragmentation that occurs as blocks of caved ore move through the draw column and interact with one another. The initial size of these blocks can be considerable, as can their strength and stiffness as the presence of non-persistent joints and veining will be variable. Intuitively, more planes of weakness within the blocks should facilitate early fragmentation, but this assumption could depend on additional factors such as contact type between adjacent blocks and loads imposed through varying heights of the draw column. This paper reports the findings from a laboratory investigation examining the role of block strength and planes of weakness on secondary fragmentation. Testing was carried out on small-scale concrete cubes of uniform size, with and without embedded planes of weakness. The results obtained demonstrate the significance of veining and other planes of weakness on secondary fragmentation under one-dimensional compression, and allow for the development and constraint of empirical guidelines.INTRODUCTIONThe fragmentation process during block caving involves the initial (primary) fragmentation of rock in the cave back through stress-induced fracturing, release and fall of individual blocks onto the broken ore muck pile. This is followed by secondary fragmentation involving splitting and rounding of blocks as they move downwards through the draw column towards the draw point. The degree of secondary fragmentation achieved involves many variables related to the mechanical properties of the rock blocks as well as different operational factors. With respect to the block properties, the presence of planes of weakness in the form of veining and non-persistent joints is a topic of special interest given the significant influence it potentially has on the overall fragmentation process. However, the inherent heterogeneity and variable size of individual blocks generated from the cave back makes it difficult to develop any empirical relationships relating secondary fragmentation to compressive loading based on insitu observations and mine data. More preferable would be to keep constant block parameters, such as shape (aspect ratio and angularity) and size, through controlled laboratory testing. This work presents an efficient technique to fabricate concrete cubes in order to keep constant different block properties. These are then tested under one-dimensional compressive loading. The objective of these tests is to emulate a tight packing condition of single blocks such as that which would occur when the air gap between the cave back and broken ore in the draw column is small. When the air gap is small, detached blocks are unable to fall and rotate but instead maintain a very tidy arrangement with minimal voids left between adjacent blocks."

Jan 1, 2015

By M. Nzotta, L. Teng, S. Seetharaman, A. Chychko

The objective of the present work is to optimize the EAF practice towards Mo alloying with maximum retention of the alloying element in molten steel. During Mo additions, there were significant losses to the dust (ca 7 %) and to the slag phase (ca 2 %), which had serious economic and environmental impacts. The present work was aimed at designing a suitable Mo precursor, an alternative to ferromolybdenum, as the Mo source and a process sequence for optimal retention of Mo in the steel. The design of the Mo source should be in such a way that low cost raw materials such as MoO3 concentrate have to be used, stable during the addition so that the vapour phase losses as MoO3 are kept minimum and the dissolution of the precursor in molten steel is easy without loss to the slag phase. After thermodynamic considerations, three precursor materials were chosen, viz. CaMoO4, MgMoO4 and Fe2MoO4. Synthetic mixtures of the component oxides in each case as well as pure MoO3 were investigated by TGA and high temperature XRD in order to find out the temperature range in which the compounds were formed. Experiments were also conducted separately where the evolved gases were analyzed. All the three precursors were formed easily and the loss of MoO3 to the vapour phase was found to be extremely low. Addition of the oxide mixtures to steel melts were conducted in three different scales, viz. 16 g, 500 g and 3 tons (induction furnacle). Initial experiments showed that MgMoO4 was not suitable since the Mo yield in the steel melt was not very high. Fe2MoO4 was found to perform best, the Mo yield reaching 98 %. Further trials were conducted in the 65 ton Electric Arc Furnace (EAF) at Uddeholms AB in Hagfors. Mixtures of mill scale, MoO3 and carbon in suitable proportions were added in a pre-determined addition sequence. It was found that, in the actual practice, the Mo yield reached 99 %, equaling in performance the addition of ferromolybdenum. The process offers an effective use of cheaper raw materials and very high Mo yield avoiding a pre-treatment step like the production of ferromolybdenum. This is both cost effective and environmentally advantageous. The process has been patented and is being currently implemented at Uddeholms AB, Hagfors, Sweden.

Jan 1, 2011

By D. C. R. Espinosa, P. Aliprandini, F. P. C. Silvas, J. A. S. Tenório, M. M. Jiménez Correa

"Nickel ores are divided into two types: sulfide deposits and lateritic deposits. About 60% of nickel resources are found in laterite ore, while the remaining 40% is contained in sulfide ore. Laterite ore is usually processed via pyrometallurgical means or through hydrometallurgical techniques that include acid leaching and metal value recovery from solution. In this study, copper and nickel adsorption by Dowex M4195 ion exchange resin from an acidic sulfate liquor was investigated. The acidic sulfate liquor was collected from an atmospheric leaching process (AL) of laterite ore. Ion exchange experiments were conducted in a batch system by varying parameters such as pH, time, metal concentration and temperature. Initially, mono-elemental synthetic solutions of nickel and copper were used in the experiments and then a synthetic solution simulating AL liquor was tested. Test results showed that the resin exhibited high selectivity towards copper and nickel, however, a high concentration of iron in the synthetic AL solution interfered with the recovery of nickel and cobalt by the resin.INTRODUCTION Nickel is one of the most important industrial metals in the world. It is widely used in industrial applications, such as the production of stainless steel, magnets, electroplating and special alloys (Dizge et al., 2009). The main sources of industrial nickel production are sulphide deposits; only 40% of industrial production uses lateritic ores. However, it is estimated that 60% of global nickel resources are found in nickel laterite deposits (Kuck, 2016). Since industrial nickel demand continues to grow, the development of new technologies for the extraction of nickel from laterite ores has become an interesting research topic (Agatzini-Leonardou, 2009)."

Jan 1, 2017

By R. G. K. Morrison

As mines grow deeper, the problem of ground control becomes one of increasing importance. The literature on the subject has grown extensively in the past few years, but is still far from conclusive. Detailed and precise observations are on record covering most phases of the problem, and control measures have progressed to the point where, in a large measure, they are effective. The success of methods to date must be attributed to the efforts which have been exerted to reduce convergence of stope walls and to the realization that a regular progression of stope faces approaching longwall has a beneficial effect. This paper attempts to explain the relationship between these two factors and the general problem of ground control. The problem at present lacks the co-ordination of the practical with the scientific outlook, but fortunately as time goes on there are indications that our scientific friends are becoming more interested and more familiar with the practical issues involved. Opinions vary widely regarding the mechanism of the problem and there are several schools of thought, two only of which will be discussed. One associates the incidence of rock-bursts with the stresses built up by a sagging hanging-wall, while the other takes the view that stresses primarily responsible for the sagging hanging-wall are also the cause of rock-bursts. The first group starts its reasoning from the convergence of the walls, probably the most conspicuous feature of deep mining, and works back to the conclusion that rock-bursts are in sorne way due to the breaking up of the sagging layers. The second group begins with the stress zone apparent around excavations at depth and follows mathematical conceptions based on certain assumptions which, in the absolute sense, are known to be inaccurate, but which are justified by the similarity between the conclusions reached and the results obtained in practice. This reasoning is followed to the point where rock-bursts result from the failure, under stress, of rock in situ, quite independent of wall convergence.

Jan 1, 1939

By J. Visman

"SummaryThis paper is presented as part of a programme to show the steps taken by industry and others interested in supplying a solid fuel of constant quality to 'satisfy a consuming market. The paper deals with the general principles underlying quality control in coal preparation plants, namely, constant quality and close adherance to acceptance limits. It also describes how control of ash content is ""generally hampered by the problem of coal sampling .and the long duration of the ash analysis and how these difficulties may be overcome.Quality control can be effected in several ways. Thorough blending wll reduce variations appreciably, except those of long trend. The latter can be detected by automatic sampling and quick ash analysis. At present, under favourable conditions, a system of half-hourly ash determinations with an accuracy of 0.5 to 1.0 per cent can be realized, to the effect that trends with a 'wave length' of more than two hours cu be eliminated within the limits of accuracy of the ash figures. The general solution of the problem is a combination of blending, accurate sampling, quick ash determination, and statistical analysis of the pattern of ash distribution.The use of statistical methods of analysis, such as the t test and F test, is •discussed at some length in order to emphasize the importance of the correct evaluation of observational data if there is to be confidence in the validity of test results.General ConsiderationsCOAL, as a fuel, is too cheap for a long haul across the country. The limiting distance depends on the price of the local competitive fuels, and, as the price depends to a great extent on quality, so does quality, to the same extent, command the market."

Jan 1, 1952

By E. T. W. Bailey

A HISTOR Y of the development and application of instruments, from the simplest U gauge to a modern indicating recording controller, would contain many interesting accounts of difficulties experienced and over-come. Important as is the history of development to any branch of science, this phase will, of necessity, have to be omitted from this paper and remarks confined to the results from the use of instruments in their present form. The steel industry bas, in the past decade, become increasingly instrument minded. More than ever, economy and adherence to doser specifications are demanded, and any tool that will aid in attaining these objectives by intelligent application and use finds a ready acceptance. The open-hearth furnace bas offered a field for instruments which is different from almost any other and one in which even a small percentage saved in operating costs may represent a considerable sum. Nevertheless, this department of the steel industry has been more cautions than most others in accepting the benefits which automatic control bas given on many other types of industrial furnaces, and one is puzzled why open hearths have not more generally benefited by the application of controlling instruments. The furnace operator bas to adjust the same three main valves that control fuel, combustion air, and stack draft as on most other furnaces, with the additional regulation of reversing the furnace. He is just as aware of the importance of proper draft control and correct air volume to burn most economically the applied fuel as any good boiler-plant engineer. What, then, are the special conditions that pertain to the open-hearth furnace?

Jan 1, 1939

By Hasini Wijayaratne

Anode cover material, a mixture of crushed electrolyte and alumina, is a crucial part of an aluminium reduction cell because of its important role in maintaining overall heat balance. However, until recently little attention has been given to understanding or controlling its composition and quality. The thermal conductivity of anode cover material determines the extent of the heat loss from the top of the cell. This will change as a function of the granulometry and composition of the applied cover as well as over time as the cover material consolidates on top of the cell. The ability to measure or predict the thermal conductivity of fresh and ageing cover is an important tool for managing cell heat balance. Recent studies have shown that granulometry or more correctly, voidage is likely to be the predominant determinant of thermal conductivity of anode cover materials. We have developed equipment to measure the thermal conductivity of granular cover material and tested the relative importance of composition (ratio of alumina to crushed electrolyte) and granulometry/voidage on cover thermal conductivity. In general, our results confirm that granulometry is the dominating factor. Generally, high voidages contribute to lowering the thermal conductivity especially when particles are mostly fine. However the relationships between granulometry, voidage and thermal conductivity are complex due to the varying nature of heat transfer between particles. Aging of granular cover material occur during cell operation forming a consolidated crust due to exposure to heat and fumes over time. Structure and thermal behaviour of this consolidated crust is also important in understanding the overall properties of cover. This paper presents the outcomes of laboratory studies conducted in order to understand the thermochemical behaviour of anode cover material and in particular, the role of fines in anode covers mixtures.

Jan 1, 2011

By A. S. Dawson

"IntroductionTHE PURPOSE of this paper is to describe the results of a preliminary investigation of a method thought to be useful in interpreting geological structures in un-metamorphosed sedimentary rocks. The writer is not aware of the method having been described or investigated previously, although no thorough search of the literature has been made.The method to •be described is based on the assumption that, in argillaceous sedimentary rocks, certain ceramic properties are diagnostic for certain beds within areas of variable limits.Two ceramic properties• have been investigated: pyrometric cone equivalent (P.C.E.), and bloating characteristics of shales. The enquiry has been directed toward testing the usefulness of these properties in determining the following:A -The correlation of shale beds and, by inference, of coal seams, sandstone beds, or other such structures associated with them.B.-The location of contacts between marine and non-marine shales where lithological, palaeontological, or other evidence is lacking.Limitations of time and facilities have prevented a thorough investigation of this problem. The results given in the present paper are preliminary only. It is hoped, however, that they will occasion discussion or even lead to more thorough investigation of the method by individuals or organizations.There are, admittedly, various limitations to the proposed method. It is thought to show some promise when used in conjunction with the well-known and established methods used in stratigraphic correlation and, more particularly, when the conventional methods are not applicable."

Jan 1, 1952

By Adrian E. Scheidegger

"AbstractThe possibilities of deriving pertinent information about fractures in an oil pay from data obtained by core analysis are investigated. It is shown that it is possible to obtain an estimate of the fractured area per unit volume of the pay, and that the size of the fractures can be estimated if their shape is known. A suggestion of a routine procedure for the analysis of fractures is given.1.-IntroductionMany oil fields are producing essentially from cracks or fractures. Where this is the case, it is important to be able to obtain a knowledge of the size and distribution of those fractures in the oil pay. This knowledge has to be derived from the analysis of cores taken from the fields, as it is generally impossible to follow a fracture through the pay by direct means. The necessity of using statistical methods to extrapolate the meagre information obtained from the cores of the wells is therefore indicated.It is known that the fractures are much bigger than the diameter of the cores; thus, if they strike a core, the latter will generally fall into two pieces. The angle of the fracture with the vertical can be measured and, if oriented cores are taken, the exact position of the surface element representing the intersection of the fracture with the drill stem can be determined. Sometimes the edge of a fracture can be seen in a core. The number of •Cores that show such an edge can be noted. Of course, one has to be careful to distinguish between original fractures in the pay and fractures in the core caused by drilling operations. Only the former are relevant."

Jan 1, 1955

By Douglas R. Schmitt

In general, knowledge of the state of stress within the Antarctic lithosphere remains largely unconstrained due in part to Antarctica?s inaccessibility and because of the paucity of seismic focal mechanism solutions. As such, an important component of the ANDRILL project was to acquire new information on the stress directions and magnitudes within the upper crust. Extensive fracture mapping of the core and oriented ultrasonic televiewer logging were carried out to provide strong constraints on both stress orientations and the faulting regime. The first hydraulic fracturing stress determinations in Antarctica were also carried out to provide complimentary stress magnitudes. These measurements were accomplished using a wire-line transported hydraulic fracturing system consisting, essentially, of two synthetic polymer packers that were inflated to isolate the 1-m long pressurization interval. The tests were conducted at the end of the drilling and logging in a ~130-m section specially drilled below 1000 mbsf (nearly 1500 m from the rig floor) for hydraulic fractures. This zone was drilled primarily through competent, dense, and low permeability diamicts. The core fracture and televiewer logging information was used to site twenty separate measurements. Classic hydraulic fracturing pressurization records with unambiguous breakdown and fracture closure pressures were obtained in about half of the measurements. The remaining tests provided fracture propagation and closure pressures that are consistent with the classic breakdown curves, but they did not include a clear breakdown pressure and are indicative of the reopening of either natural or drilling induced fractures in the wellbore wall. The preliminary analysis of the results are in generally good agreement with the stress directions indicated by the core fracture logging and the stress regime suggested by the character of the drilling induced core fractures.

Jun 1, 2012

By A. M. Christie

Acknowledgements The following account has been compiled mainly from records and maps of Eldorado Mining and Refining (1944), Limited, hereinafter called the Crown Company. This work was done under the supervision first of R. F. Murphy, Chief Geologist, and later of E. B. Gillanders, Eldorado Mine Manager and Manager of Eldorado Exploration Division. W. F. James and B. S. W. Buffam are consulting geologists. Since 1946, S. N. Kesten has supervised geological work for the Company in the Goldfields area. Where maps of Eldorado properties have been included in this paper, the name of the geologist who examined the property is acknowledged on the map. Outline of General Geology The geology of the area is described in the Goldfields and Martin Lake preliminary maps of the Geological Survey and accompanying Paper 49-17. In brief, the Tazin series of Precambrian age, consisting mainly of sediments with minor interbedded volcanics and basic intrusives, is intruded and replaced by granite, now generally gneissic. The late-Precambrian Athabaska series of conglomerate and arkose, with interbedded basalt and andesite flows, rests unconformably on the older rocks. All these rocks are cut by small diabase dykes. The geological terms used in this paper and in the accompanying figures are standard with the exception of the term 'mafic rocks'. These include all the basic or dark coloured rocks of the Tazin group, such as amphibolites, biotite schists, and chlorite-epidote rocks (greenstones), whether they be of extrusive, intrusive, or sedimentary origin.

Jan 1, 1949

By D. R. Pyke, R. S. Middleton

"Three main types of base metal sulphide mineralization are present in the Timmins area:(1) -Massive and stringer-type copper-zinc deposits occurring mainly in pyroclastic rocks, as typified by the mines of Kam-Kotia, Jameland and Canadian Jamieson, or within or close to possible breccia pipes as shown by the Genex and Kidd Creek mines. With the exception of the Kidd Creek mine, all of these orebodies occur northwest of Timmins (Kamiskotia area) and appear to lie within or close to a major center of volcanic activity characterized by a thick accumulation of felsic pyroclastic rocks and subordinate epizonal intrusions. The margins of the rhyolitic pile are interfingered with mafic volcanics; overlying sedi-ments mark the termination of a vol-canic cycle. The copper-zinc deposits in the Kamiskotia area are confined to a particular stratigraphic unit. Ore-bearing solutions were probably derived from the intrusive complex of the volcanic pile.(2) -Porphyry copper deposit of the Mcintyre mine. The deposit occurs in a quarz porphyry intrusion related to the volcanism in the area (Hurst, 1936). Mineralization was probably introduced at the time of intrusion, and subsequently redistributed within the porphyry during deformation. (3) -Massive and disseminated nickel mineralization, associated with serpentinized alpine-type ultramafic intrusions, as shown by the Alexo, McWatters, Hart, Inco and Texmont deposits. The nickel mineralization occurs at or near contacts of the serpentinites with felsic or mafic volcanics, or sulphide-bearing iron formations. The nickel deposits south of Timmins are confined to a particular stratigraphic unit along the margins of domical-shaped structures which appear to outline former volcanic centers. Sulphurization as pro-posed by Naldrett (1966) appears to be a workable hypothesis for the formation of some of the deposits."

Jan 1, 1971

By S. Perez

Core drilling is a fundamental process in the mineral exploration industry. As deep exploration in hard rocks is accelerated due to the depletion of near ground mineral resources, deep-drilling operations need to reduce their reliance in operators experience and begin to implement new technologies in order to increase efficiency and cost-effectiveness of the overall process. Currently, lack of real-time information on the bit/rock interaction is a major problem. Therefore the mechanism behind the acoustic emission, which is a proven technique for remote monitoring, generation in mechanical rock cutting must be understood in order to provide real time information about the rock. This paper aims to identify the influence of mineral composition of granitic rocks on the acoustic emission (AE) during rock abrasivity test with a single contact tool and to evaluate the feasibility of AE as a means to infer Cerchar Abrasivity Index (CAI). Single contact tool will provide precise and accurate description of the source of AE. To provide constant grooving speed Cerchar apparatus was modified to monitor AE during rock/tool interaction. Tests on the modified Cerchar apparatus are carried out under the static load of 70N and cutting speed of 1 mm/s. A Scanning Electron Microscope (SEM) is utilized to visualize the groove in the rock and to identify the mineral composition through Back-Scattered Electrons (BSE) reflected from the rock sample. Based on the microscope images, it was found that biotite shows a larger groove area and plate-like fractures accompanied with burst-type AE signal, whereas plagioclase and quartz, which are characterized by similar hardness and BSE brightness, possess shattered-like fractures and more continuous-type AE signals. In addition, a-value of the Gutenberg-Richter scale has been found to well correlate with Cerchar Abrasivity Index (CAI).

Jan 1, 2015

By D. Duff, R. A. Cameron, R. E. S. Whitehead

"Although CO2 content indicates the quantity of carbonate in altered basaltic rocks, it does not measure the intensity of carbonate alteration. CO/CaO molar ratios, which correlate with the relative proportions of individual carbonate species, measure the intensity of carbonatization. The Timmins gold area is characterized by pervasive carbonatization, with large parts of the area having CO2/Ca0 ratios greater than 1, representing C02 supersaturation relative to CaO. The mean CO/CaO in the Timmins area is0.67, compared to 0.13 in two unmineralized control areas. Regional arsenic abundance in the gold-bearing area averages 4 ppm, compared to about 0.35 ppm for the non-mineralized areas. The average K20 and Rb abundances are similar in both mineralized and non-mineralized areas (about 0.30% K20 and 7 ppm Rb). Although there appears to have been no wholesale addition of K20 or Rb to the mineralized area from external sources, these alkalies have been redistributed internally, resulting in patterns of local enrichments and depletions which are characteristic of the mineralized region.Local target anomalies associated with known mineralization consist of CO2/Ca0 > 1.5, As > 10 ppm and K2O > 0. 75%. Not all three values are required to be above these thresholds in order to identify local targets. Combinations such as C02/ Ca0 > 1.5 and As < 10 ppm, CO/CaO 1-1.5 and K20 > 0. 75 or K20 > 0. 75 and As > 10 ppm are equally indicative of proximity to gold occurrences. Gold-bearing veins and associated anomalies occur throughout the entire volcanic succession and are not restricted to any particular stratigraphic horizons. The levels and patterns of alteration and occurrences of gold appear to be structurally controlled."

Jan 1, 1982

By A. E. Aho

"The material presented in this paper will be subject to modification as new data become available, but it is presented in the hope that it will inspire more intensive mineral exploration and geologic studies of what appears to be one of Canada's richest mineral provinces. A metallogenic province 400 by 150 miles in extent, lying mostly northeast of Tintina trench, encompasses most of the base metal deposits of Yukon, as well as deposits of other metals. Its main features are northwesterly trending arcuate fold belts, with several orogenic axes, which include most of the metamorphosed rocks, granitic intrusives and mineralization; and which are modified by regional uplifts, northwest-striking fault trenches, and lesser transverse folding and faulting.The main base metal occurrences and their regional controls are summarized briefly. Most of the replacement-type deposits are localized in late Proterozoic to early Paleozoic rocks, particularly Lower Cambrian -probably because these are the most physically and chemically favourable hosts encountered in an appropriate temperature and pressure environment; perhaps because of early age of deposition. Most of the deposits also occur near heat sources or intrusives with associated structural uplift, which has, moreover, served to expose the older rocks. They also tend to occur near known or suspected regional fault trenches, such as Tintina, Macmillan and Hess, although this relationship may be fortuitous. In detail, they may be localized in fold axes, flat-lying beds or other appropriate structural traps. Vein-type deposits are fracture-controlled and localized by dilational localfties, the competence of wall rocks and ""damming"" effects.In the Anvil district, large stratiform iron-zinc-lead replacement deposits lie parallel to gently plunging flex-ures in phyllite in a zone parallel to the Tintina trench, along the southwest flank of the arch-like Anvil batholith. About 80 million tons of massive sulphide ore probably existed before erosion of the Faro orebody, the Vangorda deposit could have been of similar magnitude before erosion and much more tonnage probably remains to be discovered in the district. The Anvil deposits may differ from others found to date in Yukon, but resemble the Sullivan orebody of southeastern British Columbia in their large size, localization in essentially non-limy peptic to arena-ceous host rocks of Proterozoic or early Paleozoic age and proximity to the Rocky Mountain -Tintina trench sys-tem. These features suggest an origin from primordial subcrustal sources.More major ore deposits, not only of lead, zinc and copper but probably of other metals as well, will no doubt be found in similar environments in Yukon or Alaska. Thus, the base metal province of Yukon offers challenging opportunities for prospecting, development, field studies and basic research."

Jan 1, 1969

By Laszlo Imreh, Pierre Trudel, André C. Tessier

"The Siscoe gold mine is ranked as the fourth largest mine in the history of the Val d' Or mining district with a total production of 27.4 tAufrom1929 to 1949. Most of the gold mineralization occurred in quartz veins, hosted in a small (.69 km2) intrusion of altered quartz gabbro known as the Siscoe stock. The southern contact of the Siscoe stock is crosscut by a major shear zone (the ""K"" zone) trending 295/80 NE and from which gold mineralization was also exploited within the limits of the stock. Field and petrographic observations of the Siscoe stock combined with chemical analyses of major, trace and rare earth elements of the stock and its volcanic host rocks (Dubuisson Formation) suggest that:The Siscoe stock comprises four alteration facies formed from a homogeneous precursor: 1) the actinolite - Mg-chlorite facies, characterized by low FeOt,Na2O andTiO2 , and highAlp3 and MgO; 2) the albite- Fe-chlorite facies, containing high concentrations of FeOt and Nap; 3) the Mg + Fe-chloritefacies, which is transitional between the actinolite- Mg-chlorite and albite- Fe-chloritefacies; 4) the carbonate-chlorite facies, which consists of rocks that were subjected to extreme hydrothermal alteration, is spatially associated with mineralized veins and part of the K-zone. The first three facies are depleted in SiO 2, CaO and Au, and enriched in MgO, relative to fresh rocks of the Siscoe stock and the equivalent rocks of the Dubuisson Formation.Hydrothermal fluids introduced mainly along the K-zone ""channelway"" induced three types of element remobilization, resulting in the various alteration facies: 1) redistribution of elements within the stock from one facies to another (e .g., FeOt, Nap, Ti02 migrated from the actinolite- Mg-chlorite facies to the albite- F e-chlorite and Mg + Fe-chlorite facies); 2) remobilization of elements from the intrusive rocks into veins (e.g ., SiO 2 and CaO ); 3) introduction of elements by hydrothermal fluids in rocks of the Siscoe stock (e .g., Al2O3, MgO, H2O, CO2 and FeOt).The Siscoe stock and the Dubuisson Formation form part of the same tholeiitic suite. Similarly, the Bourlamaque batholith and the Val d'Or Formation belong to a single calc-alkaline suite. In view of this relationship, dissimilarities between the petrochemistry of the Siscoe stock and the Bourlamaque batholith suggest that the two intrusions are not co-magmatic.Finally, gold may have been leached from rocks of the Siscoe stock and remobilized into the quartz-carbonate mineralized veins. In order to account for the total production at the Siscoe mine, approximately 1.2 km3 of the Siscoe stock is thought to have been partially leached of its gold."

Jan 1, 1990

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020

By G. Roy, D. R. Lentz, A. O. Wills

"Abstract - Diamond-drill hole DDH-B357, located 1.5 km north of the Brunswick No. 6 Zn-Pb- Cu-Ag volcanic-sediment-hosted massive sulfide (VSHMS) deposit, intersects three exhalative horizons within variably altered felsic volcanic rocks of the Nepisiguit Falls and Flat Landing Brook formations. These three petrographically indistinguishable iron formation intervals (Fe2O3T = 21.4 wt.%) likely represent cogenetic hydrothermal sedimentary units because they display a common geochemical signature: Fe2O3T = 42.9 ± 10.5 wt.%, MnO = 5.4 ± 3.1 wt.%, elevated base metal values (Zn+Pb = 1999 ± 1091 ppm), strong enrichment in additional exhalative components (CaO = 5.3 ± 3.9 wt.%; P2O5 = 1.43 ± 1.00 wt.%), oxidized signature (Fe/Mn = 10 ± 6), as well as a common immobile element signature (Zr/TiO2 = 0.025 ± 0.007) representative of a pelagic source. The calc-alkaline to transitional host volcanic rocks can be discriminated by Zr/TiO2, and to a lesser extent by Th/Nb: Nepisiguit Falls Formation: Zr/TiO2 = 0.053 ± 0.004, Th/Nb = 1.08 ± 0.37; Flat Landing Brook Formation: Zr/TiO2 = 0.107 ± 0.043, Th/Nb = 0.86 ± 0.17. A symmetrical repetition of the footwall-iron formation-hanging wall stratigraphic sequence is observed in DDH-B357, with distinct felsic volcanic rock domains separated by the three iron formations. This is best explained by parasitic F2 folds on the west flank of the south-plunging Brunswick antiform, similar to the fold closures known to host massive sulfide accumulations in the Brunswick No. 6 and No. 12 mines. Iron formation geochemistry and felsic volcanic rock chemostratigraphy from drill core sampling can provide an effective mineral exploration tool for the structurally complex rocks of the Bathurst Mining Camp. Sommaire - Le forage au diamant DDH-B357, situé à 1.5 km au nord du gisement de Sulfures Massifs à Encaissant Volcanique et Sédimentaire (SMEVS) de Zn-Pb-Cu-Ag Brunswick No. 6 recoupe trois horizons exhalatifs au sein des roches volcaniques felsiques diversement altérées des formations de Nepisiguit Falls et de Flat Landing Brook. Ces trois intervalles de formation de fer, impossibles à distinguer pétrographiquement les uns des autres, représentent vraisemblablement des unités sédimentaires hydrothermales cogénétiques sur la base de leur signature géochimique commune: Fe2O3T = 42.9 ± 10.5 % poids, MnO = 5.4 ± 3.1 % poids, des teneurs élevées en métaux usuels (Zn+Pb = 1999 ± 1091 ppm), un fort enrichissement en composantes exhalatives additionnelles (CaO = 5.3 ± 3.9 % poids; P2O5 = 1.43 ± 1.00 % poids), une signature oxydée (Fe/ Mn = 10 ± 6), ainsi qu’une signature d’éléments immobiles communs (Zr/TiO2 = 0.025 ± 0.007) indicative d’une source pélagique. Les roches volcaniques encaissantes calco-alcalines à transitionnelles peuvent êtres reconnues par leur rapport Zr/TiO2, et à un moindre degré par leur rapport Th/Nb: Formation de Nepisiguit Falls: Zr/TiO2 = 0.053 ± 0.004, Th/Nb = 1.08 ± 0.37; Formation de Flat Landing Brook: Zr/TiO2 = 0.107 ± 0.043, Th/Nb = 0.86 ± 0.17. Une répétition symétrique de la séquence stratigraphique Mur-Formation de Fer-Toit a été observée dans le forage DDH-B357, avec des domaines distincts constitués de roches volcaniques felsiques séparés par les trois formations de fer. La meilleure explication est que le flanc ouest de l’anticlinal Brunswick à plongée sud est affecté par des plis parasites F2, similaires aux zones de charnière contenant les sulfures massifs des mines Brunswick No. 6 et No. 12. La géochimie des formations de fer et la chimiostratigraphie des roches volcaniques felsiques en forage peuvent fournir un outil d’exploration minérale efficace dans les roches structuralement complexes du Camp Minier de Bathurst."

Jan 1, 2006

By Guoxiang Chi

This paper consists of two parts: the first part describes the principles and functionality of the BsnMod program, and the second part presents preliminary application of this program to paleo-fluid flow modeling in the Anticosti Basin. The BsnMod program simulates fluid flow and heat transfer during the evolution of sedimentary basins through numerical solution (finite difference method) of three partial differential equations, which describe sediment compaction, fluid continuity, and heat conservation. It can be used to estimate the evolution of fluid overpressure, flow rate, and temperature during the basin history. The program was written in C++, works under Windows environments, and has a user interface allowing inputs in dialogues and outputs in both tabular and graphic forms. The program was applied to the Lower Paleozoic Anticosti Basin in eastern Canada. The basin history consists of a passive margin stage and a foreland basin stage. Preliminary simulation results indicate that no significant fluid overpressures were developed in the passive margin stage and during the early period of the foreland basin stage, but strong overpressures were developed within the foreland basin succession during the middle and late periods of the foreland basin stage. Fluid flow rates were generally slow, and thermal profiles were not significantly disturbed by fluid movement throughout the basin history. Potential source rocks of hydrocarbons were found in the foreland basin succession. The strong overpressures in the foreland basin succession could have been a major driving force for hydrocarbon migration from the source rocks to the underlying potential reservoir rocks.

May 1, 2001