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By L. Xia, B. Hart, J. Nigim, Z. Chen

"Grinding ore is an important step in the flotation process. Not only does grinding reduce particle size and liberate minerals, it also creates conditions for reactions to occur on particle surfaces that can aide or inhibit flotation. There have been numerous studies examining various grinding regiments and the effect on flotation pulp chemistry, including autogenous grinding and using media of variable composition. There have been however, few studies looking at the effect of variability in grinding media size on pulp chemistry and subsequent flotation. This study attempts to link changes in pulp chemistry in response to variations in grinding media size to flotation recovery. It uses probes mounted in the grinding chamber (pH, Eh, DO, and conductivity) to monitor pulp chemistry changes during grinding of a Cu-Zn ore. Surface chemistry analysis by ToF-SIMS was performed on sphalerite from the mill discharge. Activator and depressant species were monitored on the mineral surfaces and their presence was evaluated in the context of variability in pulp chemistry linked to differences in grinding media and its ball size.INTRODUCTIONIt has been widely recognised that not only does grinding reduce particle size and liberate minerals but the grinding environment has a large effect on the flotation of sulphide minerals. This effect is attributed to Eh change, iron hydroxide coating on surfaces, oxygen reduction, precipitation from solution and galvanic coupling (Grano, 2009). As early as 1960, it was reported that after grinding the ores in an iron mill the natural floatability of sphalerite was reduced significantly (Rey and Formanek, 1960). Kocabag and Smith (1985) studied on the industrial circuits showing that the depression of sulphides flotation in a steel mill is possibly due to the coating of iron oxidation products. Peng, Grano, Fornasiero, and Ralston (2003a, 2003b) found that iron contamination from grinding media plays a dominant role in depressing galena and chalcopyrite flotation. Huang, Grano, and Skinner (2006) reported the same observation in the flotation of arsenopyrite."

Jan 1, 2016

By S. Duvah Pentiah

The transformation of an open pit coal mine to a horizontal-punch underground mine is subject to a number of challenges. These include scheduling the operation of various sizes of trucks over a long period, as well as updating delivery routes and dump site locations as the mine transformation progresses. In this process, rock is excavated from a quarry through earthworks. The bulk earthwork and quarry material delivery were initially drawn from traditional planning and experienced issues in their early phases. As a result, a traffic simulator was developed in order to validate schedules and predict achievable throughput, likely delays or blockages in the long term. The dynamic traffic simulator was also used to provide traffic density and vehicle arrival data at selected intersections in order to identify possible safety and efficiency issues.

Aug 1, 2013

By O. Lashkari, A. Charette, R. Ghomashchi

Conventional casting at low pouring temperature was employed to produce semisolid metal, SSM, billets of A356 Alloy. The deformation behavior of the as-cast SSM billets was studied using parallel plate compression viscometry. The compression tests were carried out at different applied pressures, and fractions solid. The rheological studies were conducted assuming the SSM slurry behaving like Newtonian and non Newtonian fluids respectively. The calculated viscosity numbers confirmed pseudoplastic behavior of the SSM billets and were correlated to fraction solid and shear rate proposing the following empirical equation which is valid at low shear rates, less than 0.01 s-1, and fraction solid of0.33-0.46: 0 log77 =5.56-l.38fs -(l.56fs +0.14)logy Aluminium 2006 45th Annual Conference of Metallurgists ofCIM Montreal, Quebec, Canada Edited by G. Dufour, F. Paray and J. Tessier 0.33<fs<0.46

Jan 1, 2006

By J. G. Patterson

"The depressive action of sodium cyanide on chalcocite has been investigated and found to be unstable. Flotation results show that with the addition of sodium cyanide to the system chalcocite is initially depressed but rapidly recovers with time, provided there is sufficient oxygen present.lt is proposed that the unstable depression is due to the reaction of cyanide with adsorbed xanthate and copper ions at the chalcocite surface to form soluble copper complexes. When all the free cyanide has so reacted, xanthate anions can then re-adsorb on the chalcocite surface and the flotation will recover. Results are presented to verify the the above mechanism."

Jan 1, 1968

By S. R. McCutcheon, D. R. Lentz

"Abstract - The 12.1 Mt Brunswick No. 6 Zn-Pb-Cu-Ag massive sulfide deposit (New Brunswick, Canada) lies between two subaqueous felsic volcanic formations near the base of the Middle Ordovician Tetagouche Group. The footwall comprises rhyodacitic pyroclastic rocks (Nepisiguit Falls Formation), whereas the hanging wall comprises a sequence of rhyolitic flows, breccias, and hyaloclastites (Flat Landing Brook Formation), with an age difference of less than 3 m.y. The Brunswick No. 6 deposit is a proximal autochthonous deposit with a well-zoned massive sulfide body and a basal Cu zone that, at depth, develops into a stockwork stringer sulfide (feeder) system. The massive sulfides are capped sharply by a layered magnetite-chert unit that extends regionally beyond the deposit. The deposit has a keel shape (sheath) formed by the F1F2 interference pattern. The heterogeneous ductile deformation and upper greenschist-grade regional metamorphism has transposed many of the epigenetic stockwork structures and alteration within the host sequence. Hydrothermal alteration is much more extensive, both vertically and laterally, in the footwall (a few 100 m) than in the hanging wall (<100 m). Anomalies farther up in the hanging wall sequence seem to be associated with independent alteration systems related to the rhyolite domes. The least-altered footwall units exhibit keratophyric alteration (albite or adularia) and weak Mg enrichment (chlorite). More intense micaceous (sericite and Mg-rich chlorite) alteration occurs around the footwall sequence. The transposed stockwork stringer sulfides are typically composed of Fe-rich chlorite (± sericite, ± silica) with pyrite, pyrrhotite, chalcopyrite, arsenopyrite, and sphalerite. The (Fe2O3T+MgO)/(Na2O+K2O) and base metal alteration indices are the best practical lithogeochemical vectoring tools at this deposit. Sommaire - Le gîte de 12.1 Mt de sulfures massifs de Zn-Pb-Cu-Ag Brunswick No.6 est localisé entre deux formations volcaniques felsiques sous-marines situées près de la base du Groupe de Tetagouche d’âge Ordovicien Moyen. Le mur consiste en roches pyroclastiques rhyodacitiques (Formation de Nepisiguit Falls) tandis que le toit consiste en une séquence de coulées, de brèches et d’hyaloclastites de composition rhyolitique (Formation de Flat Landing Brook); la différence d’âge entre les deux est de moins de 3 m.y. Le gisement Brunswick No. 6 est un gîte autochtone proximal comprenant un corps de sulfures massifs clairement zoné ainsi qu’une zone cuprifère basale qui passe progressivement à un stockwork de filonnets de sulfure en profondeur (feeder). Les sulfures massifs sont abruptement surmontés d’une unité laminaire de chert et de magnétite dont l’extension par delà le gisement est régionale. Le gisement affecte la forme d’une quille (fourreau) résultant d’un patron d’interférence F1F2. Plusieurs des structures épigénétiques du stockwork et des patrons d’altération de l’encaissant ont été transposés par la déformation ductile hétérogène ainsi que par le métamorphisme régional au faciès des schistes verts. L’altération hydrothermale est beaucoup plus importante, tant verticalement qu’horizontalement, dans le mur (quelques 100 m) que dans le toit (<100 m). Les anomalies situées plus haut dans le mur semblent être reliées à des systèmes d’altération indépendants associés aux dômes de rhyolite. Les unités les moins altérées du mur une altération kératophyrique (en albite ou en adulaire) ainsi qu’un faible enrichissement en Mg (chlorite). Une altération en mica (séricite et chlorite magnésienne) plus intense est présente autour de la séquence du mur. Les sulfures du stockwork de filonnets transposés consistent typiquement en chlorite ferrifère (± séricite, ± silice) accompagnée de pyrite, de pyrrhotite, de chalcopyrite, d’arsénopyrite et de sphalérite. L’indice d’altération (Fe2O3T+MgO)/(Na2O+K2O) et l’indice des métaux usuels sont les outils d’exploration les plus appropriés dans ce gisement."

Jan 1, 2006

By Kristine Haug

Although most in situ operations in Alberta do not encounter significant problems during resource extraction, there have been a few documented occurrences of oil or steam releases as a result of compromised caprock seals. The objective of the Oil Sands Caprock Integrity Project (OSCRIP) is to characterize the units above and below bitumen zones to determine which geological factors affect the quality of the caprock seal. In addition, geomechanical properties and stress measurements of the bitumen reservoir and overlying units will be examined to provide a better picture of the containment conditions in which in situ operations occur. The information from this study will aid regulatory staff and industry in determining the zone-specific geological and geomechanical factors that could affect the design, operation, and feasibility of in situ recovery projects. The OSCRIP study area (Townships 87 to 99 and Ranges 1 to 13, West 4th Meridian) encompasses the surface mineable area, the northeast extent of the Wabiskaw-McMurray bitumen deposit and the Clearwater Formation, as well as a wide band of the Devonian salt-dissolution zone. Regional geological mapping of the Cretaceous strata focuses on the spatial extent and thickness of the caprock seal. Mapping of the underlying Devonian strata is targeted at better understanding the potential effects of salt dissolution and collapse of overlying strata on the integrity of the caprock seal. Examination of LiDAR (Light Detection And Ranging) bare earth DEM in the study area has revealed localized depressions that may represent sinkholes rooted in subsurface collapse features in Devonian carbonate and evaporite strata. Mapping the location and understanding the timing of salt dissolution-related features and deformation in the Devonian strata will help address questions about the possible effect that geological structures, such as sinkholes, have on the integrity of the caprock, as well as the potential for localized variations in the stress regime of the bitumen zone and overlying units. The stress regime in units above 350 m is such that any induced fractures are believed to be horizontal, and therefore, there would appear to be no mechanisms that would allow these fractures to reach the surface. However, recent incidents have shown that vertical pathways can occur, linking the subsurface to the surface. The final phase of the project will evaluate the changes that may occur in the stress regime under thermal operating conditions in the study area.

Jun 1, 2012

By M. B. Kime

"A set of experimental batch leaching tests studied the effect of pH, time, temperature, and stirring speed on the relative Cu, Co, Ni, and Fe leaching yields of an oxidized copper-cobalt ore sample in an aqueous hydrochloric acid solution. The results were statistically analyzed and modelled using the structural equation modelling method. Models showed that Cu, Co, and Ni leaching yields were strong functions of the leaching time and leaching temperature, whereas the Fe leaching yield depended on the leaching temperature, stirring speed, and pH. Under optimum leaching conditions yields were 99.8% Cu, 82.4% Co, 91.3% Ni, and 30.6% Fe.RÉSUMÉ Une série d’essais expérimentaux de lixiviation en bâchée ont été menés pour étudier l’effet du pH, de la durée d’attaque, de la température et de la vitesse de brassage sur les rendements relatifs de lixiviation du cuivre (Cu), du cobalt (Co), du nickel (Ni) et du fer (Fe) d’un échantillon de minerai de cuivre-cobalt oxydé dans une solution aqueuse d’acide chlorhydrique. Les résultats ont été analysés et modélisés statistiquement à l’aide de la méthode de modélisation par équation structurelle (SEM, de l’anglais structural equation modelling). Les modèles ont montré que les rendements de lixiviation du Cu, du Co et du Ni dépendaient énormément de la durée d’attaque et de la température de la lixiviation ; le rendement de lixiviation du Fe, quant à lui, dépendait de la température de la lixiviation, de la vitesse de brassage et du pH. Dans des conditions optimales de lixiviation, les rendements étaient de 99,8 % pour le Cu, de 82,4 % pour le Co, de 91,3 % pour le Ni et de 30,6 % pour le Fe. INTRODUCTIONThe Katanga province in the Democratic Republic of Congo hosts the northwestern part of the Central African Copperbelt. This region abounds with large, rich deposits of sulfide and oxidized copper-cobalt ores. In general, the main valuable minerals present are malachite (CuCO3Cu(OH)2) and heterogenite (CoO(OH)). Common impurities found in heterogenite are Cu, Ni, Si, Al, Mn, and Fe. The substitution of Co by other cations (e.g., Cu, Ni, and Fe) has an influence on the crystallinity of heterogenite (Deliens, 1974). In general, well-crystallized varieties of heterogenite have lower impurity contents, whereas amorphous heterogenite types usually contain more impurities (Thys et al., 2009). Further, in heterogenite, Co can occur in the 2+ and 3+ oxidation states. The gangue generally consists of quartz (SiO2), talc (Mg3Si4O10(OH)2), kaolinite (SiO2·Al2O3·2H2O), limonite (Fe2O3·3H2O), and goethite (FeO(OH)). Oxidized copper-cobalt ores are often treated by hydrometallurgical methods, whereas sulfide ores are often treated by flotation or pyrometallurgy, depending on their grades. Hydrometallurgical methods typically entail selectively dissolving the metals of interest (Cu, Co, and Ni) in aqueous solutions (leaching), transferring the dissolved metals to an organic solution, and retransferring these to a second aqueous solution (solvent extraction). Copper and nickel are readily dissolved in an acidic aqueous media. In contrast, cobalt is difficult to dissolve, especially if it is present in the third oxidation state; however, this species becomes soluble after it is reduced to Co2+ (Mwema, Mpoyo, & Kafumbila, 2002; Kime & Makgoale, 2016)."

Jan 1, 2017

By P. O. Parfitt

The Critical Path Method has proved its usefulness at Mcintyre Porcupine Mines Ltd. This paper illustrates the techniques of network construction and analysis, and the application of the method at the Mcintyre copper mine to various projects in the gold mine. C.P.M.'s use in a mill maintenance project is also discussed.

Jan 1, 1966

By R. C. Gilmore, J. F. Brune

"Pulverized limestone rock dust used in United States underground coal mines to prevent and suppress coal dust explosions must easily disperse by forces of a methane or coal dust explosion. Moisture in the mine environment causes caking of the dust. Colorado School of Mines researchers performed dispersibility tests in a full-size explosion test drift. Tests included conventional, hydrophobized, and rock dust approved for German mines. Conventional and German standard rock dust products partially agglomerate, which may not be effective in suppressing a coal dust explosion, while hydrophobic rock dust retains better dispersibility.INTRODUCTIONA coal dust explosion devastated the Upper Big Branch mine in 2010 resulting in the death of 29 miners, the worst mining accident in the United States since 1972. The explosion propagated through approximately 65 km of active mine workings, but was extinguished in areas that had been properly rock dusted (Page, 2011). Researchers have long studied and established the ability of inert limestone rock dust to suppress coal dust explosions, see Richmond et al. (1975), Cybulski (1975), and Sapko et al. (2000).To be effective, rock dust must contribute to a total inert content of > 80% by weight and 100% of rock dust particles must pass through an 850 µm sieve, while 70% of the rock dust must be finer than 74 µm. This is established in US regulations 30 CFR §75.2. Dry rock dust is a nuisance that prevents mining work downwind from rock dusting activities. To overcome this problem, dust manufacturers have proposed applying the rock dust as a wet slurry or foam. After drying, manufacturers expected the slurry or foam-applied dust to have the same explosion suppression capabilities as dry-applied rock dust.Researchers at the Colorado School of Mines (CSM) designed and built a full-scale, underground Explosion Test Facility (ETF) at the CSM Edgar Experimental Mine in Idaho Springs, Colorado about 20 miles west of the CSM Golden, Colorado campus. To disperse the different rock dust products, researchers produced an air pressure pulse using a mesh array of PETN detonation cord. This method is simpler, more reproducible and safer than other methods considered, including methane-air explosions and a compressed air cannon. The detonation cord blasts produce a wind velocity of 30 to 50 m/s, the minimum velocity at which coal dust explosions can propagate, based on research by Nagy (1981) and Cybulski (1975)."

Jan 1, 2019

By J. F. Henderson

THE National Advisory Committee on Research in the Geological Sciences was established seven years ago - in 1949. In 1952, shortly after the Committee had really begun to function and had issued its first report, a paper ( l) was presented describing the objectives and organization of the Committee and the progress to that time. Another four years have gone by and the Committee feels a further progress report may be of interest. HISTORY Ten years ago, in 1946, the Geology Division of the Institute set up a Committee on Geological Research. This Committee, under the Chairmanship of Dr. J. E. Hawley, recommended that "a National Advisory Committ.ee on Research in the Geological Sciences be formed" (2). With the backing of the President and Council of the C.I.M. this recommendation went forward to the then Minister .of Mines and Resources and, with his approval, to the Committee on Scientific and Industrial Research of the Privy ?Council. As a result, the National Advisory Committee was set up in 1949.

Jan 1, 1956

By T. N. MacAuley

"The Ingerbelle and Copper Mountain deposits are located near Princeton in southern British Columbia. They are owned by Newmont Mining Corporation's wholly owned subsidiary, Similkameen Mining Company Ltd. The property includes the Copper Mountain mine, a former producer. Ore reserves recoverable by open-pit mining are estimated to be 76 million tons containing 0.53% copper. Production commenced during 1972 at a rate in excess of designed capacity (15,000 tpd). All of the known major copper deposits in this area lie in a 14,000- by 3,500-foot belt of Triassic volcanics (Nicola Group) that is situated between a well-defined syenitemonzonite- diorite stock on the south and a variable intrusive complex on the north. The Nicola rocks consist of andesitic tuffs and agglomerates with lesser amounts of flows and some lensy siltstone layers. The orebodies are essentially disseminated sulphide deposits, although fracture-fillings are also important in many areas. Total sulphide content is usually less than 5%. At lngerbelle, and at Pit 2 and most of Pit 1 at Copper Mountain, the sulphides are chalcopyrite-pyrite. In part of Pit 1 and most of the former underground mine they are chalcopyrite-bornite. At lngerbelle the predominant alteration associated with mineralization is a pale greenish-gray bleaching of the dark andesitic rocks. This has been identified as albitization, with lesser amounts of epidote, chlorite, biotite, scapolite and calcite. This bleaching is plentiful at Pit 2, but K-feldspathization is also evident here. These orebodies can better be classified with pyrometasomatic deposits than with typical porphyry coppers. Their relationship to intrusives, the probably extensive metasomatic replacements, the evidence of pneumatolytic activity, the formation and redistribution of magnetite, and the irregular distribution of mineralization are all characteristic of this class. Deep-seated faults probably acted as channelways for mineralization; fracturing, faulting and rock contacts influenced ore localization in detail."

Jan 1, 1973

By A. J. Reed, W. R. Bergey, Carr. J. M.

"The Highmont copper-molybdenum deposits are at Gnawed Mountain in the Highland Valley porphyry copper district, 125 miles northeast of Vancouver. This district is near the center of the lower Jurassic Guichon Batholith, where a north-trending swarm of porphyry dikes is crossed by west-northwesterly structural belts in which fracturing, intrusion of porphyry and breccia, and mineralization areconcentrated.The Highmont deposits are 2 miles southeast of, and in the same southernmost structural belt as, the Lornex deposit. The main deposits occur on either side of a composite dike of granodiorite, porphyry and breccia which strikes west-northwestward in fractured quartz diorite. North of the dike, the adjacent Nos. 1 (East) and 2 (West) zones together contain 150 million tons of open-pit ore mineable in two separate pits. These two zones will support a 25,000-tpd mill with a grade in the first five years of approximately 0.46 per cent copper equivalent. South of the dike, the Nos. 3 and 4 zones are partly explored and will provide large additional reserves. In these various zones, chalcopyrite, bornite and molybdenite form disseminations and fracture-fillings accompanied by quartz, K-feldspar, tourmaline, sericite, specular hematite and other minerals. Bornite extends for varying distances north of the dike, beyond which chalcopyrite is locally accompanied by pyrite. Higher-grade mineralization tends to coincide with fracture swarms, or with shear zones and faults which largely parallel these swarms. The ore zones are reflected by geochemical soil anomalies which show some glacial dispersion. LP. surveys gave weak but significant responses, expressed as per cent frequency effect. The ore zones occur within a strong magnetic gradient, but do not show a significant magnetic response."

Jan 1, 1971

By Paul W. Kingston

In New Brunswick, during the 1970&apos;s, rocks of the Lower Carboniferous Windsor Group in the Moncton Basin of the Fundy Epieugeosyncline have been the target of intense exploration and drilling programs. Sylvinite ore was discovered in three structural basins of the Moncton Basin near Sussex through a drilling program sponsored jointly by the Federal Department of Regional Economic Expansion and the New Brunswick Department of Natural Resources. In 1973, exploration and development rights to the western end of the Moncton Basin were awarded to the Potash Company of America. One high-grade sylvinite unit, varying between 15 and 70feet in true thickness, with a strike length in excess of 5 miles, is located near the stratigraphic top of the assymetric, semi-diapiric, locally overturned anticline. Late in 1975, exploration and development rights to the Marchbank Syncline were awarded to International Minerals and Chemical Corporation (Canada) Limited. To date, a stratigraphic evaporite sequence, forming the semi-diapiric core of the syncline, has been shown to contain one major high-grade sylvinite unit averaging 70 feet in true thickness over a strike length in excess of 2 miles. Both properties appear to have potential considerably in excess of that revealed by the exploratory drilling, and both, because of numerous mineralogical, structural and stratigraphic similarities, are thought to be depositionally contemporaneous. Both potash deposits lie within 50 miles of the Saint John all-weather deepwater port, thus affording easy access to eastern and mid-western U.S. markets. Further opportunities for potash exploration in New Brunswick are considered excellent, as there are large untested areas with favourable geology and known potassium water anomalies and negative gravity anomalies occurring in the Moncton and Cumberland basins, and in the Central Basin of New Brunswick.

Jan 1, 1979

By H. Dean

"Mine hoisting machinery, of which wire rope is an essential part, is developing, in Canada as well as in other parts of the North American continent, into highly sophisticated equipment. Heavier payloads are now required to be raised from steadily increasing depths at higher rates of speed and production. These hoisting conditions have, of necessity, brought about a major change in the production of steel roping wires and the wire ropes manufactured from them.Operators and designers of hoisting equipment are requesting a very much more efficient ratio of strength to weight in hoisting ropes, so that heavier loads may be raised from greater depths by ropes which will provide a predeterminable life span on which the operator may depend.The cost of wire rope to the operator is very low indeed, usually less than $0.01 per ton of payload, but the cost of unexpected shutdown periods, due to rope maintenance or change, can be extremely high -particularly in operations where a continuously high rate of production is an absolute necessity. Mine hoist ropes with a higher strength to weight ratio are now being made and used in some areas of Canadian mining, and a general understanding of the performance we may expect from them is required."

Jan 1, 1968

By K. Östcrdahl

We are developing a cost-saving and environmentally friendly process with low energy consumption to recover the metal content and recycle the acid from spent pickle baths. The metals are precipitated as metal fluorides, which can be turned into metal oxides and hydrofluoric acid by thermal hydrolysis. In the proposed process the solution is concentrated by nanofiltration and the metals are precipitated in a subsequent crystallization step. Different nanofiltration membranes have been evaluated in experimental batch tests. The membrane MPF-34 from Koch Membrane Systems offered both good flux and acceptable metal retention even after long periods of acid storage. The solubility of B-FeF3.3H20 has been measured at varying acid concentrations and at different temperatures. The solubility decreases with increasing hydrofluoric acid and nitric acid concentrations. This suggests that the crystallization process should be operated at high acid concentrations. The crystal growth rate of B-FeF3.3H2O is found to be quite low but increases significantly with temperature. This suggests that the crystallization process should be operated at higher temperatures (40 - 60°C). Within the project a pilot plant has been constructed where the spent pickle bath solution is concentrated by nanofiltration to the desired metal fluoride supersaturation, and B-FeF3.3H2O is crystallized in a 10 L continuous crystallizer.

Jan 1, 2006

By C. H. Knight

"THE OBSERVATIONS that follow are confined to simple wet cyclones such as the cylindro-conical unit developed by the Dutch States Mines and marketed in America under the trademark 'Dorr-Clone'. Energy to do the work comes from the inlet velocity of the feed slurry, which is usually pumped' to the unit by a centrifugal pump.Such cyclones are simply classifiers of enormous capacity and depend for their separating effect on differences in rates of particle settlement. These particle settling rates, of course, vary with particle size, particle density, particle shape, pulp viscosity, and pulp density.The dilution of the overflow product affects both pulp viscosity and pulp density. In most operations, the temperature and the composition of the liquid -hence its viscosity --are fixed, but both pulp viscosity and pulp density can be changed by changing pulp dilution.Since the separating effect depends on differences in rates of particle setting, a perfect split with 100 per cent of the particles coarser than a given size in the underflow and 100 per cent of the finer sizes in the overflow is not possible. Just how far the separation departs from this perfection can be calculated rather exactly from the following principles, which also apply to mechanical classifiers. In removing or settling out of the overflow product all particles up to a specified size, some of the finer particles must settle out simultaneously."

Jan 1, 1955

By Wm. F. Wuest

INTRODUCTION THE Western Canada sedimentary basin has one feature in common with the Precambrian Shield area: it also was a great chemical laboratory. The mining industry of Canada exploits the end products of chemical experiments that occurred on the Shield during periods of repeated disturbances in Precambrian times. The petroleum industry on the other band exploits what also appears to be the final results of chemical experiments that took place throughout all of post-Precambrian up to Tertiary times. Since the subject of this paper is a factual study of Alberta well waters, no attempt is made to answer significant questions pertaining to the probable role waters play in the generation of oil, or to the significance of the effects of structure and depth on waters. Data from several hundred well-water analyses were compiled by the writer in a series of charts and diagrams, of which those included in this paper are representative. Early studies indicated the possibility that outstanding anomalies in general concentration of waters and in greatly increased concentration of elements such as calcium, magnesium, bromine, and iodine for example, might be expected from wells that produced oil or were in the immediate vicinity of producers. The water analyses from wells which? were drilled at a later date did not confirm this possibility, and it is suggested that, aside from their initial value to the petroleum engineer or to. those interested in the commercial possibilities of brines, no definite significance as an aid in oil discovery can be attributed to water analyses.

Jan 1, 1951

By J. A. Beesley

This paper reviews contemporary international law concerning the seabed, current developments in the United Nations on the seabed, and the main outstanding problems. It emphasizes the importance that the Canadian government attaches to this area.

Jan 1, 1969

By A. F. Robertson

FOR several years, the rock-burst question has been given serious consideration by the operating staff at Wright-Hargreaves mine and, as a result of observations and experiences, several different methods of mining have been developed which are now in use in various parts of the mine. These are described in the following pages. It should be emphasized, how-ever, that these methods, and the views expressed in this paper, are based solely on conditions at Wright-Hargreaves mine. Such conditions may or may not be similar to those obtaining in other mines in the Kirkland Lake area, where ore occurrences, veins, wall-rock, faulting, intrusives, etc., may be entirely different. Size and shape of ore-bodies, composition of the ore-bodies and their surrounding rocks, locations of intrusives and sedimentary rocks, and direction, dip, and strength of faults, all introduce problems that are peculiar to each individual mine. Ground failure&apos; in coal and metal mines is not at all unusual. A variety of systems of mining have been developed to delay movement of large or small blocks of ground, or, in some instances, to take advantage of the fact that ground movement, due to mining operations, is unavoidable. Ground failure may be either slow collapse or it may take place with explosive violence. It is principally with the latter condition that we are concerned in the mines of the Kirkland Lake district.

Jan 1, 1939

By J. D. T. Steyl

"This paper presents a phenomenological model of the rate of iron(III) precipitation in batch and continuous autoclaves at medium temperature operating conditions. The rate expressions are based on information obtained from the literature and experimentation at low and high pulp densities. Special allowance is made for the formation of surface nuclei, which appears to be promoted at a higher iron(III) precipitate surface area, especially in suspensions of lower terminal acidity. This leads to the formation of secondary particulates and provides the required link to simulate high pulp density leaching-precipitation systems, using low pulp density batch precipitation data. In particular, the model allows direct application of the simulation to the autoclave oxidation of iron-containing copper sulfide concentrates and provides a good estimation of the relative precipitation rate of hematite, the preferred product, compared to hydronium jarosite. Some interesting mechanistic understandings of iron(III) precipitation in autoclaves are further elucidated.INTRODUCTIONThe objective of this work is to describe the rate of iron(III) precipitation and the relative amounts of hematite compared to hydronium jarosite precipitation during batch and continuous chalcopyrite oxidation under medium temperature (MT) (~130 to 160ºC) autoclave conditions. Published information has not yet revealed sufficient mechanistic insights about this sparingly soluble salt system under these conditions. The rate expressions in this paper are based in part on current literature information, supplemented by qualitative experimental observation at low pulp density conditions, in particular the high-resolution backscatter electron (BSE) images and particle size distributions (PSDs) of the precipitates. A summary of this work and insights from the literature are presented first, after which the behaviour of iron(III) in high pulp density leaching systems is used to derive a phenomenological expression of the effect of existing iron(III) precipitate surface area on the precipitation rate. The overall regression encapsulates all the experimental results, i.e., those obtained in both batch and continuous autoclave configurations (Steyl, 2012a)."

Jan 1, 2012