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By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By B. I. Boyko

As part of the Ministry of the Environment's Resource Recovery Program, the Province of Ontario has constructed a $13 million "Experimental Plant for Resource Recovery" in Metropolitan Toronto. The technology and unit operations involved in the processing of municipal solid wastes at a rate of 40 tons per hour at this facility are reviewed. Shredding, air separation and classification, screening, magnetic separation and composting are some of the operations featured at this plant. Recoverable commodities expected include paper, ferrous metals, an air-classified light fraction (shredded paper and film plastic), glass and compost. Existing and potential markets for these materials are discussed.

Jan 1, 1978

By M. L. Jeremic

Altered and unaltered coal from the Star-Key Mine near Edmonton, Alberta has been tested under compression and under tension. The test results showed that altered coal samples have an appreciably lower strength than unaltered coal. Altered coal samples do not give a linear load-displacement curve, peak strengths are poorly defined and yielding is observed over a range of loads, so the material can be regarded as relatively plastic. However, unaltered coal samples produce a linear loading curve with a high tangential modulus and an easily distinguished peak strength at which there is a sudden brittle failure. These findings lead to important differences in the theoretical design of ribs and pillars in underground mines in the two coal types. The substantial differences in the strength properties and behaviour of the two types of coal are governed by a higher intensity of cracks in the weathered coal. Two causes of the additional cracking can be suggested-subaerial weathering and subterranean weathering of the coal.

Jan 1, 1979

By W. D. Bonisteel

In 1976, Rio Algom Limited began the expansion of uranium production facilities at Elliot Lake. Quirke Mine was the only property in operation at the time, and plans were made to expand its milling capacity from 4,500 to 7,000 tons of ore per day. Following this expansion, other properties in the area will be reactivated to fulfill long-term contracts for uranium. As part of the expansion program, it was decided that in view of the escalating cost and impending shortage of energy, heat reclaim and conservation would be employed wherever practicable. In general terms, heat reclaim applications fall into three main classifications: ventilation, utility and process. Two of the ventilation applications and one process application will be described in some detail. Several other systems will be presented briefly as a matter of general interest. Some future possibilities will also be mentioned, together with their potential for economical heat recovery.

Jan 1, 1979

By W. K. Buah, R. K. Amankwah

Waste-activated carbon generated by gold ore processing plants that employ carbon adsorption technologies may contain very high gold values and represent a potential source of extra revenue. In this research, two methods that augment combustion of waste-activated carbon are evaluated. These are mechano-chemical activation and charcoal-enhanced ashing. It was found that mechano-chemical activation caused structural transformation of the waste carbon, which resulted in a reduction in the temperature for complete oxidation from above 700oC to 450oC. Complete oxidation was also achieved at the same furnace temperature, for a combined sample of waste-activated carbon and 50% by weight of wood charcoal. In both cases, gold was extracted from the ash by conventional cyanidation, with recoveries greater than 98% from a head grade of 3.2 kg/t.

Jan 1, 2007

By J. Laganiere

A considerable part of the sulphuric acid requirements of the Aluminum Company of Canada's Arvida smelter comes from the burning of 180-200 tons per day of zinc '"'sulphide concentrates in a 22-ft.-diam-eter fluidized bed roaster. The plant and its operation were fully de-scribed in a publication that appeared about ten year ago (1). A simplified flowsheet of the roasting and gas-cleaning sections of the plant is given in Figure 1. The wet zinc sulphide concentrates are un-loaded into a pug mixer, by means of a Pay loader, and mixed with water in a mixing tank to make a slurry of 80 per cent solids. The slurry is transferred to a .feed tank and then introduced into the roaster at a point four feet above the constriction plate, which is the height of the settled bed of zinc calcines. The roasting temperature is con-

Jan 1, 1963

By G. R. Elliott

Foreword The office of the Supervisory Mining Engineer, a branch of the l. Federal Government, is financially interested in no oil company and has no stock to sell. This office, however, is deeply interested in the proper and efficient development of Canada's natural resources. The people of Canada are interested in the petroleum development in Turner Valley for two principal reasons: As represented by the Department of the Interior, they are the largest owners of petroleum and natural-gas rights in the field; As a nation, they are vitally interested in the development of petroleum and natural gas as a national asset, and therefore, also, in all productive property, no matter who directly controls the leases. As has been stated by Mr. Charles C. Ross, Supervisory Mining Engineer, "The Department, being responsible for the administration of these public resources, necessarily requires regulations to protect them from abuse by lessees. Our portion of this responsibility is to record a complete history of all drilling operations and to see that proper drilling methods are adopted to prevent damage and wanton waste of the valuable natural resources under discussion." Not only does our position necessitate an impartial and a judicial viewpoint, but, being day by day in touch with all operations in the western provinces, we are uniquely situated to comprehend both individual and general problems.

Jan 1, 1930

By D. J. Scarpato

"Slope construction in shale can present some interesting challenges for geotechnical design engineers and contractors alike. There are challenges that can be expected and designed-for; however, all too frequently, such challenges manifest themselves as “surprises” in the field. Common constructability challenges can include those such as drill hole deviation during drilling for controlled blasting; and, excavation slope instability arising from inconsistent perimeter control drilling. Drill hole deviation results from the cumulative effects from both drilling mechanics and rock mass conditions. Once a hole has initiated the deviation trajectory, it is difficult to rectify drill steel position. Although such challenges are not necessarily unique to shale, they are often exacerbated by weak, weathered and transversely isotropic nature of bedrock conditions. All too often, the working assumption is that shale is “soft” and easily excavatable; however, this blanket assumption can prove to be costly. This paper is intended to provide design professionals and contractors with the practical considerations needed to avoid the “surprises” associated with drill hole deviation, and minimize the potential for costly claims.INTRODUCTIONFor all the slopes that have been excavated worldwide, and for such advancements in excavation technology and field characterization, one might be tempted to believe that the industry almost has slope development down to a science. This is frequently not the case, especially for weak/weathered and anisotropic bedrock. Excavation contractors are still pushed to the limits of what their technology can achieve, and engineers are all too often called to the field during construction, to make potentially risky onthe- fly decisions relative to excavatability, short and long-term slope stability, and project safety. Although there have been a host of other research papers and journal articles that have been written on the subject of deviation over the past 30 years (Brown, Geen, Sinha, 1981), the problems associated with drill hole deviation are still all too frequent. This fact is especially true for civil engineering surface excavations in bedrock."

Jan 1, 2015

By Y. Gordon

ABSTRACT A methodology based on a two-stage approach was developed for process technology selection. The first stage includes evaluation of available technologies, followed by shortlisting the best technologies based on mass and energy balance modelling, financial analysis, and risk analysis. The second stage involves detailed analysis using refined input data, mass and energy balance modelling, and capital and operating cost estimation, as well as a more detailed financial analysis. A case study covering the selection of ironmaking technologies for a company in the Russian Federation is presented to illustrate the critical elements of the methodology and the analysis process.

Jan 1, 2014

By Jay F. Colinet

Researchers at the Pittsburgh Research Laboratory (PRL) of the National Institute for Occupational Safety and Health (NIOSH) work to reduce respirable dust exposures in mining operations. One focus of this research is silica dust control for surface and underground operations in the metal/nonmetal mining industry. PRL researchers analyze dust sampling results from the Mine Safety and Health Administration (MSHA) to identify high-risk occupations to guide research efforts. Research is then conducted in an effort to improve existing technologies and/or develop new controls for reducing worker exposure to airborne silica dust. During the last few years, PRL researchers have conducted research related to the following goals: improving protection provided by enclosed cabs on mobile surface mining equipment, reducing dust generation from surface drills, reducing dust levels in iron ore operations, and developing a new method to clean dust from workers? soiled clothes. A description of each of these controls and subsequent dust reductions quantified through site surveys will be provided.

May 1, 2007

By D. J. Hains

IN this paper we shall examine the Why, Where and How concerning the agglomeration of iron ores and concentrates. Fig. l answers the questions @f why there is so much interest at the present time in the art of agglomeration. The use of sinter or pellets in the blast furnace has materially increased their rated •capacity. ':'President Hains Company Ltd. Engineering J. S. McMahon ( 1) reports an increase from 653 tons of .pig iron per day to 1140 tons of pig iron per day with the use of a 100 per cent sinter burden on one of his blast furnaces. In the United States the use of 100 per cent pellets has increased pig iron production from approximately 1800 tons per day to over 3000 tons pig iron per day (2). In our economic system the general objective is to produce more and better commodities cheaper. Fig. 2 shows the decrease in coke consumption with increased tonnages from the furnaces when using -

Jan 1, 1961

By C. D. Rowe, H. S. Mitri, J. Malki, I. Vennes

Ore extraction at great depths creates high stresses around mine openings, which can result in violent rock failure in one of various forms of strainburst. This is especially true with strong and brittle rocks, which can store a large amount of strain energy that is suddenly released at failure. The strength and brittleness of rocks have been extensively investigated in the past. The most widely accepted method for the determination of rock burstability is the strain energy storage index obtained from a non-destructive uniaxial load–unload test. However, the results of this method are not always conclusive, showing less repeatability when the target test load is changed. This study concerns itself with the introduction of microscopic analysis as a tool to help validate the strain energy index results when burstability cannot be warranted based on mechanical property tests alone. In this study, two types of rocks, namely, basaltic komatiite (BK) and felsic norite (FNOR) obtained from Canadian underground mines are examined. The selection is based on the premise that felsic norite is known to be burstable from the mine experience, whereas basaltic komatiite is not necessarily burstable. A total of 60 mechanical properties tests were conducted including uniaxial compressive strength, Brazilian tensile strength, and load-unload tests. Laboratory tests on FNOR consistently exhibit high burstability; however, the results for the BK tests are not conclusive. To seek explanations for the mechanical rock behavior, 18 thin sections were examined with optical microscopy and image analysis. The findings show the tested BK specimens are dominated by alteration products, and all primary igneous minerals are lost. There is minor quartz, garnet, carbonate minerals, talc, and serpentine, which give the rock its ductile properties. The FNOR specimens are found to be relatively fresh and supported by a strong network of plagioclase with minor pyroxene, biotite, and secondary micas, explaining the higher stiffness. This study demonstrates how optical microscopy can complement mechanical property tests to evaluate burstability of rocks.

May 4, 2025

"11.1. IntroductionThe recovery of platinum-group elements (POE) from ores is a subject which has received almost no mention in the literature. Edwards (1975) refers to the process used for refining of the POE, throughout the Western World, as a so-called ""conventional"" process .... ""not because of the simplicity or convenience of the operations, but more probably because of the inertia of established processes and the aura of secrecy with which the major platinum refiners have surrounded this process."" There is no doubt in this writer's mind that the latter is also applicable to the dearth of knowledge of the mineralogy, geochemistry and ore deposits of PGE and that the poor recoveries, mainly attributed to the mineral beneficiation stages of concentration, are also affected by this traditional secrecy. Fortunately, this attitude is changing, due no doubt to the advantages that accrue from more open research which may be critically assessed in the literature in the traditional manner. Examples of this more open approach to recoveries and recovery problems are represented by Newman (1973), who gave some typical recovery percentages for Merensky Reef ores, and the recent encouragement and cooperation on mill samples from the Sudbury area by lnco Metals Company (cf. Cabri, 1981a).In general, platinum-group elements are recovered from an ore by the use of a physical concentration method, such as gravity separation or flotation, followed by further upgrading using further physical, wet chemical or pyrometallurgical techniques. The final process of refining in which the individual platinum-group elements are produced in pure form is outside the scope of this chapter.Platinum-group element deposits naturally fall into different categories according to the recovery process best suited for them, viz. those amenable to gravity separation, those amenable to flotation, and those where platinum-group elements are by-products of base metal sulphide, chromite and miscellaneous other deposits."

Jan 1, 1979

By T. Plikas, T. Porretta, M. Al-Dojayli, B. Pretorius, J. Woloshyn, H. Ghorbani

"Water-cooled ducts represent an integral part of high temperature off-gas systems in metallurgical processes. Typically, off-gas enters these ducts at significantly elevated temperatures; therefore, water cooling may be required to maintain the duct skin temperature within allowable design limits. These off-gases are typically of high mineral content that could lead to dust buildup, and there is a possibility of slag buildup / molten metal splashing. Therefore, dust cleaning provisions may be necessary in order to remove or minimize accretion on the duct wall, which could otherwise impact the water cooling and the system process efficiency. These ducts may have complex geometry and experience a wide range of loading, including gravity loads, water and gas pressures, cyclic thermal loading and dynamic impact forces. Consequently, the thermo-mechanical assessment of such water-cooled ducts is critical and requires consideration phenomena such as high temperature gradients, potential nucleate boiling, thermal ratcheting and fatigue failures. Such assessment is not comprehensively covered by design-by-rule design codes and guidelines due to its complexity. This paper presents a successful implementation example of design-by-analysis methodology to improve the design and extend the life of a water-cooled furnace transition duct using Computational Fluid Dynamics (CFD) and Finite Element Analysis (FEA).INTRODUCTION Water-cooling represents an important part of high temperature off-gas systems in metallurgical processes. Typical temperatures of the off-gas in the furnace uptake are in excess of 1400°C, and thus there is a need to maintain the water-cooled duct and jacket skin temperatures within their material allowable design limits. Water-cooled channels have been used effectively in arc furnace roof design (Sosonkin et al., 1972; Smolyarenko and Khainson, 1988) and other furnaces as well as in furnace fuming jackets (Scholey et al., 1994). The design of these systems was based on one-dimensional analysis to ensure sufficient cooling is available under extreme furnace conditions (Smolyarenko and Khainson, 1988; Scholey et al., 1994). With advancement in furnace and fuming system designs, water-cooled duct designs have become more complicated in geometry. Numerical techniques, such as three-dimensional fluid flow and heat transfer modeling, are therefore needed to more accurately calculate water velocity, temperature and convective heat transfer coefficients in the water-cooled channels (Haywood et al., 2002; Henning et al., 2010). This is of particular importance around geometric corners where stagnant water flow may lead to local nucleate boiling at the critical heat flux, causing hot spots (Bergman et al., 2011). High wall skin temperatures increase the risk of failures due to thermal stresses as well as increasing corrosion rates (Gelfi et al., 2012), leading to costly equipment downtime and potential safety risks."

Jan 1, 2017

By Gregg Hodges, Fred Schoenbrunn, Steve Slottee, Chad McCleary

"In December, 1999 Stillwater Mining Company (SMC) commissioned a new paste /cement backfill plant to supplement the existing sand backfill system for the cut and fill mining operation at it’s Nye, Montana mine. The new plant uses the Baker Process Deep Cone TM Paste Thickener to thicken the total concentrator tailings from 30% solids slurry to a 71% solids paste. This paper describes both general paste formation concepts and the evolution of the SMC paste plant operation from original design criteria, through problem solving and plant modifications, to the operation of the existing plant.Although the original process design was not effective for consistently producing and delivering acceptable paste to the stopes for backfill, SMC was able to make the mechanical and process modifications which allow the plant to now produce and deliver an acceptable product to the stopes. Ongoing test work is targeted at increasing the pumping range of the system, increasing the paste solids concentration from the Deep Cone Paste Thickener and reducing the operating and maintenance costs of the system.INTRODUCTIONThe authors would like to thank both Stillwater Mining Company (SMC) and Baker Process for their assistance in the preparation of this paper. Stillwater Mining Company chose not to participate directly in this paper due to time constraints, but was very helpful in answering questions concerning their approach to problem solving and specific details with regard to engineering criteria.This paper will begin with a general review of the technical and mechanical concepts in paste formation and then focus on the overall design, start-up and problem solving process for the paste backfill operation at SMC’s mine and concentrator near Nye, Montana."

Jan 1, 2001

By M. Jahazi, J. Gholipour

Design and manufacturing of parts using hydroforming process require knowledge about material behaviour and tribological effects during hydroforming. Lubrication is one of the key issues in successfully hydroform the tubes. A Ni-based super alloy tube with 50.8 mm (2 inches) outer diameter and 0.9 mm (0.035 inches) thickness is considered for this research to study the effect of lubricants on the formability of the tubes. Hydroforming of a hollow compressor blade is considered for this project. A combination of press forming and hydroforming is employed to produce the part. LS-DYNA, an explicit dynamic finite element code, is used to model the experiments. Different lubricants are modeled using different coefficient of friction in the model. Predicted results for strain distribution at a critical section of the tube are extracted for each case to evaluate the effect of different lubricants on the process.

Jan 1, 2006

According to the principle of similarity, the physical and chemical configurations of a system can be defined by ratios of magnitudes within the system and do not de-pend on the size or nature of units of measurement. In the present work, the similarity principle was utilized in evaluating the reducibility of various iron ores in a rotary batch furnace under optimum operating conditions. It was then used successfully to extrapolate the results, first to the operation of a 20-ft. pilot-plant kiln and then to an industrial-size 80-ft. kiln. By means of this systematic analysis of kiln operation, it was possible to increase the production capacity of the kiln considerably. T HE kilns used by the Strategic-Udy process for the partial reduction of iron ores are, in most aspects, similar to conventional calcining kilns. Iron ore is fed continuously in the upper (feed) end of the kiln and, as the latter rotates

Jan 1, 1964

By B. W. Raymond, D. W. Zandee

"IntroductionCoal deposits are found in many regions in Canada and vary widely in their age, quality and rank. All classifications of coal except anthracite are found in significant quantities in this country.Deposits in the Maritimes are mainly bituminous; Lignite is found in Saskatchewan and Ontario and sub-bituminous coal in the plains region of Alberta. The Rocky Mountain coalfields of Alberta and British Columbia contain low and high-volatile bituminous coal and, in a few places, semi-anthracite. The British Columbia interior contains deposits of semi-anthracite, bituminous, sub-bituminous coals and lignite. The Yukon and Northwest Territories also contain substantial deposits of bituminous coal and lignite.Currently Nova Scotia produces both thermal and metallurgical coal, Saskatchewan produces lignite and Alberta produces both sub-bituminous and bituminous coal for thermal purposes. Large deposits of metallurgical coal are now being exploited in the Rockies arefl of British Columbia and Alberta by open pit methods. The raw coal is treated in large capacity preparation plants to remove refuse and upgrade the product to a consistent metallurgical quality with respect to ash, moisture, volatile matter and coking properties.The treatment of coal involves crushing, screening and cleaning by dense medium, jigs, water-only cyclones, tables and froth flotation to produce a diverse range of coal products differing in quality and size for various end uses.The chapter on Crushing and Screening Circuits was concerned mainly with crushing of metalliferous ores to produce a concentrate of one or more valuable minerals which normally constitute a small portion of the original mass of the material treated.Coal differs physically from ores in many ways such as lower specific gravity, relatively large volumes but low tonnage of product, and its habit of absorbing moisture requires extensive dewatering processes more complicated than settlement and filtration. Most significant, for this paper at least, is the fact that crushing coal is not as energy intensive and much smaller equipment is applicable.Crushing and screening of ores is intended to reduce the size of all constituents as quickly and efficiently as possible to allow liberation of the mineral particles. The crushing of coal is different in that the coal is not the minor constituent and the production of fines, in the initial stages at least, is highly undesirable. The basic objectives of crushing coal are the reduction of run-of-mine material to sizes suitable for cleaning or further reduction of coal to market sizes."

Jan 1, 1989

By J. Chelsey Dawson

In presenting a thesis on this subject it is advisable to explain a few of the reasons for its seeming incompleteness. World progress has brought us to a position where approximations are not only to be condoned, but regarded as absolute essentials. Production in anticipation of demand is always accompanied by mistakes on the part of the producers. Only through trial and sometimes erring hypotheses may there be evolved the true course and theory upon which the steady triumphant march of world-wide industry depends. The average person likes to have everything placed ?before him in a clear and convincing manner. It is the impossibility of doing this which, in many cases, arises to confound the writer on shales. All that one can do is to present, as lucidly as possible, the known hypotheses' and theories on the subject and leave the reader to study and work out the truth for himself. Many theories have been advanced on the origin of oil-shales ; some may be correct in certain instances and not in others; however, the writer will attempt no decision as to which are and which are not correct, but .will merely point out the relative merits of each. The figures given for reserves of oil and shale in different countries are only approximations and give but a rough idea of the true conditions.

Jan 1, 1925

By Y. Thibault, G. Deschênes

An open-pit mine, located in Mexico, processes an ore a rate of 4000 tpd, using conventional cyanidation and AYR. A laboratory study was conducted to increase silver extraction and to reduce the concentration of cyanide in leaching. The sample contained 0.41 g/t Au, 125 g/t Ag, 99% gangue minerals, 0.7% pyrite, 0.07% sphalerite, 0.03% chalcocite. Silver was present as acanthite, stromeyerite, silver mercury/halogen, silver with copper in solid solution and jalpaite. The plant conditions (2400 ppm NaCN) produced 90.2% gold extraction (residue at 0.04 g/t Au) and 92.7% silver extraction (leach residue at 9.1 g/t Ag). The CELP (CANMET Enhanced Leaching Process) produced 97.0% silver extraction (residue at 3.8 g/t) and 90.2% gold extraction using 500 ppm NaCN. The incremental gross revenue was estimated at $US7.6 million and the reduction of cyanide costs was $2.9 million per year (79%).

Jan 1, 2011