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By A. D. Pittuck

Refractory minerals .containing uranium and columbium have been successfully treated at Queen's University, Kingston, to produce high-grade concentrates. Recoveries of over 90 per cent of the uranium and columbium have been obtained when treating concentrates containing euxenite, fergusonite, betafite, and pyrochlore. The processes ?consisted -of leaching the columbium with hydrofluoric acid, and the uranium with nitric acid, sulphuric acid, or sodium carbonate solutions. The leach liquors were extracted with organic solvents from which the values were stripped and precipitated, producing final products assaying 45 to 55 per cent Ob2O5 and 60 to 70 per cent U3Os.

Jan 1, 1958

"4.1. IntroductionThis chapter reviews the geochemistry of the platinum-group elements (POE) in sulphur-poor silicate rocks, and the limited data on POE in silicate, oxide, sulphide, arsenide and sulpharsenide minerals. The earliest geochemical studies of POE in silicate rocks, minerals and meteorites were carried out mainly by Goldschmidt, the Noddacks and their co-workers, and are reviewed in Crocket (1969). These researchers established the siderophile character of the POE, emphasized the common association of the group with sulphides in ultramafic-mafic rocks and suggested that very low concentrations of POE are typical of sulphur-poor silicate rocks and minerals. Much of these data were for Pt and Pd only and are more than 50 years old. Because of the poor sensitivity typical of the available analytical methods, few reliable data were obtained on silicate rocks in these early studies. Surveys of POE geochemistry demonstrate that the data base for sulphur-poor silicate rocks is very restricted, although considerable highquality data for Pd and Ir have been accumulated (Wright and Fleischer 1965, Yushko-Zakharova eta/., 1967, Mertie 1969, Crocket 1969, 1979, Keays 1981).Two recent publications, Vol. 71, No. 7 (1976), of Economic Geology (An Issue Devoted to Platinum-Group Elements) and Vol. 17, Part 2 (1979), of The Canadian Mineralogist (Nickel-Sulphide and Platinum-Group-Element Deposits), are of special interest. These volumes are clear testimony to the impressive progress made in the last decade toward describing the mineralogical and geochemical aspects of POE ore deposits, but at the same time demonstrate the constraints in modelling POE ore genesis due to our meager knowledge of the. POE content and distribution among minerals in the source rocks of ultramafic and mafic magmas. It is clear that the phases hosting POE in mantle source rocks are poorly understood. Nevertheless, Naldrett and Duke (1980) have shown that the absolute and relative concentrations of POE in magmatic sulphide ores are related to the degree of partial melting of mantle peridotites, and subsequent processes of batch equilibration and fractional segregation of sulphides."

Jan 1, 1979

By W. Rostoker

Packing Experiments The porosity and most of the other physical properties of a coherent mass of any material built up by the packing together of discrete particles will obviously vary with, and be governed by, the manner of association of the particles. The relation of packing to powder metallurgy has been discussed in some detail by at least two authors. Packing Theory Theories of particle packing have been put forward by C. C. Furnas and A. E. R. Westman. Although their approach to the problem is not the same, their conclusions are similar. In the process of packing, they visualize the voids of a uniformly sized material becoming filled with particles of a smaller size, and the voids between these being filled in turn with still finer particles. Obviously, if this process is carried ad infinitum, the resultant mass will have the same density as the constituent particles. In practice, of course, such a density of packing is never attained. In addition, the premise is made that successive particle sizes must fit into the voids left by the immediately larger particles- an assumption requiring definite size gradations and also particle shapes. It remained, then, for theory to correlate relative diameter ratios, and proportions and numbers of sizes of particles, for requisite packed densities. Briefly, the following principles were postulated: (a) For an infinite diameter ratio between largest and smallest sizes, an infinite number of particle sizes in proper proportion is required to give natural density. (b) For a given diameter ratio, there is a maximum number of permissible particle sizes for maximum packed density (Furnas). (c) Provided the particle shape is spherical, or approximately so, the proportions o particle sizes can be calculated. (d) The ratios of successive diameters of particles are in geometric progression.

Jan 1, 1947

By J. Guha, A. Gobeil, P. Pilote, A. Tremblay, E. Dimroth

The Mount Bourbeau Lac Berrigan area is located just to the north of the Town of Chibougamau. The axial trace of the Chibougamau syncline borders the northern part of both areas. The area contains Archean rocks of the Roy Group, intruded by the Cummings Complex and the Line Lake tonalite stock. Proterozoic sedimentary rocks occur in a series of outliers. Various Cu, Zn, Pb, Ag, Au and Mo showings are dispersed over the area in a wide range of time and space. Pre-Kenoran (stratiform and stringer) showings related to volcanic activity may be distinguished as well as the syn-or post-Kenoran (vein) types whose nature is imprecisely known. In this area, the stratiform showings occur in the Gilman and Blondeau Formations, whereas the vein type showings occur for the most part in fractures or breccias within or along the contacts of the various sills of the Cummings Complex. Mount Bourbeau is distinguished by the greatest variety of showings as well as the proximal volcanic facies of the Blondeau Formation. A volcanic centre is presumed to lie a short distance north or east of the locality. Locally, the Line Lake stock contains significant silver, molybdenum and gold mineralization. Its role as a metal reservoir, a source of heat for the circulation of hydrothermal fluids and its control of the local tectonic style remains to be determined.

Jan 1, 1984

By K. D. Hester

This paper will review the metallurgical aspects of the completed expansion program at Quirke, and the current rehabilitation and refurbishing program at Panel. During the Quirke program, completed at the end of 1977, the plant capacity was increased from a nominal 4,500 to 7,000 short tons per milling day. The expansion of crushing, grinding, neutral thickening and filtering, leaching, partial neutralization, sand-slime separation, sand washing, C.C.D., clarification, ion exchange, mine water treatment, and tailings neutralization and pumping will be considered. The application of Enviro-Clear thickeners in the mine water treatment circuit and in the C.C.D. will be briefly reviewed. An automatic grinding and classification circuit for limestone will also be covered. The refurbishing program underway at Panel will be discussed. The Quirke and Panel plants will be contrasted and compared. In particular, reference will be made to environmental considerations. The innovative system for producing yellow cake at Panel, LAMIX, will be considered as well as the proposed treatment system for Panel tailings.

Jan 1, 1979

By Harold S. King

TWO summers ago I had the privilege of visiting No. 18 colliery at Glace Bay. Underground, we travelled along the haulage-way behind a powerful electric locomotive. The motor in this locomotive began to smoke badly and a carbon tetrachloride type of extinguisher was used several times during the trip. At the time, I noted a strong odour of phosgene. On my return to Sydney, I spoke to Mr. Harold Gordon, Assistant to the General Manager of the Dominion Steel and Coal Corporation, and warned him of the danger of using this type of fire extinguisher in confined spaces, since it is a well known chemical fact that phosgene, a dangerously toxic gas, is formed by the decomposition of carbon tetrachloride. This danger does not seem to be widely recognized, so it seems advisable that a more general warning be published. Attention was first drawn to the danger by the death of two men in the United States Navy Department subsequent to breathing fumes from carbon tetrachloride used in a fire, and when an employee of the Bureau of Mines also was overcome while fighting a fire with carbon tetrachloride liquid. These accidents led to an investigation of the decomposition products of carbon tetrachloride by a group of workers in the Research Laboratory of the Pittsburgh Experimental Station, U.S. Bureau of Mines, the results of which were published in the October, 1920, number of the Journal of the .Franklin Institute (1). Their experiments were conducted by two methods. The first consisted in applying the liquids to actual fires and -to hot metal in a closed room of 1,000 feet capacity, where the gaseous products, mixed with air, could be retained and analyzed. The second method was to pass the vapour:s in air through heated tubes of iron or quartz, where the humidity of the air and the temperature could be controlled.

Jan 1, 1939

By M. Tardif, F. L. -Lavoie, M. Ruel

"In mineral processing, it is often very difficult to reliably measure several key operation variables. The harsh environment and high temperature encountered in pyrometallurgy processes lead to some difficulties when selecting the instruments, valves and actuators. If an important variable cannot be measured or manipulated adequately, controlling it can really become a big challenge. Sometimes, it is simply impossible to find the perfect equipment for the task. To help overcome these difficulties, a different approach is required. This approach will not correct the inherent problems related to the instruments and valves, but will cope with these problems. This article will demonstrate how modern process control techniques can be used to solve complex problems while remaining easy to implement. In this article we will described how soft sensors and multivariable fuzzy logic control were implemented at Koniambo Nickel to stabilize the furnace feed and allow for safe and reliable operation of an 80 MW DC arc furnace.INTRODUCTION Process Overview The process plant at Koniambo Nickel SAS is located in the North Province of New Caledonia, 310 km north of Noumea. The nickel-bearing ore is mined in the nearby Koniambo massif. After being screened and crushed, the ore is transported to the processing plant using a 12 km conveyor. After stacking in two blending piles, the ore, containing 2.3% nickel, is fed to the processing plant where it will go through the NST process (Nickel Smelting Technology) before being sent to refining and shotting. This article will focus on the improvement to control of the NST processes. The first steps of this process consist of milling the ore and removing all moisture through calcining (Figure 1)."

Jan 1, 2017

By M. N. Bassim, W. W. Tennese

"Concepts of linear elastic fracture mechanics were applied to study two cases of failure, namely an equalizing beam from a tandem rear axle of a highway tractor unit and the main beam of a flat bed trailer. In the first case, the presence of a crack, initiated by stress corrosion cracking followed by significant fatigue crack propagation produced a state of stress which was sufficient to produce brittle failure. Calculation of the fatigue life agreed with the number of cycles that the structure experienced before final fracture. In the second case, it was demonstrated that a combination of low temperature and high loading rate was sufficient to cause brittle fracture.IntroductionFailure analysis of engineering components has generally been carried out without the benefit of fracture mechanics. It is generally understood that real structures inevitably contain internal or surface flaws which under an applied load, may propagate to fracture. Fracture mechanics relates the applied stresses to the crack size in specified geometries. Since its introduction approximately thirty years ago, fracture mechanics has evolved as a design philosophy which can be used to develop fracture-safe designs. It can be also applied in analysis of failures, to ascertain if sound design and fabrication methods have been used."

Jan 1, 1985

By D. B. Dreisinger, M. Mokmeli, B. Wassink

Dissemination of selenium and tellurium in sulphide minerals results in the contamination of pregnant leach solutions and electrolytes in the hydrometallurgical treatment of sulphide ores and residues. The selenium and tellurium content of the copper sulphate-sulfuric acid solution may be reduced into insoluble precipitates of copper selenides and tellurides using cuprous ion. This study presents the use of the thermodynamics and kinetics for the removal process of selenium and tellurium in real life application. Dominant species of selenium and tellurium in acidic copper sulfate solutions were identified and the reduction rates of species were compared. The findings were applied to industrial conditions by modeling the Vale’s CRED (Sudbury, Canada) plant’s selenium and tellurium purification circuit. Rate reducing factors on selenium and tellurium removal were identified and discussed.

Jan 1, 2014

By K. B. Young

Possibly the most complex fatigue problem associated with the development of the axial-flow 'gas turbine is discussed in its broader aspects from the metallurgical viewpoint. Reference is made to nodal patterns, interference diagrams, etc. The use of such data in analysis of a turbine :blade failure is illustrated. Special attention is given to the influence of some metallurgical variables affecting fatigue strength and, in particular, heat treatment is shown to have a pronounced effect on .the relative fatigue and creep strength properties of a nickel-chromium-cobalt base alloy suitable for turbine blade applications.

Jan 1, 1958

By D. Tao

The adverse effects of clay particles on coal and mineral processing processes such as gravity separation, flotation, filtration, and thickening are well known in the mining industry. In particular, the presence of ultra-fine clay particles deteriorates froth flotation performance, which has been attributed largely to slime coatings that inhibit bubble attachment and to adsorption of the frother and/or collector by the clay particles. The present study was conducted to evaluate the performance of clay binding agents developed by Georgia-Pacific Resins, Inc. in enhancing coal and mineral flotation performance. Mechanical and column flotation tests were carried out using coal and potash samples. Process parameters investigated include slurry solids percentage, impeller rotation speed, binder dosage, collector dosage, etc. Flotation results show that use of GP reagents significantly enhanced flotation efficiency under different conditions. The required binder dosage and conditioning time was about 1 lb/t and 0.5-1 min, respectively. More significant improvements in process performance were observed at higher solids percentage and higher impeller rotation speed.

Jan 1, 2006

By L. M. Southwick

"The history of extractive metallurgy is replete with examples of commercializing new processing technologies. The successes are widely reported, but failures seldom are. This is unfortunate, for usually we can learn more specifics on how to succeed in technology development by studying and thoroughly understanding their failures. Frequently one encounters a red herring that caused the whole effort to fail. A thorough and objective due diligence up front would have identified those red herrings and prevented the pursuit of a bad idea and the resulting destruction of capital. Due diligent analyzes performed before construction of three such bad ideas will be discussed. One is an EAF dust process, which pursued the red herrings of a poor understanding of the business, a naïve view of past experience, and false confidence in the technology. Another will examine the effort to commercialize a new pressure copper leach process that followed the red herrings of inadequate testing of the raw material, application of processing conditions that were inherently unsafe, and an improper assessment of the inherent advantages of past developments. The last is an alternative iron-making process, where the red herrings were incomplete and superficial assessment of prior pilot plant and demonstration plant tests, an assumption that the commercialization model of “build it and we will make it run” was viable, and a technology whose technical fatal flaws had already been identified. Unfortunately, capital destruction often also closes the window to more intelligent pursuit of technology development. TECHNOLOGY COMMERCIALIZATIONThe development and commercialization of new technology is a vital part of keeping industry profitable, able to deal with new sorts of feed stocks and current with economic, product, operational and environmental requirements. This is a difficult task in the best of times, and can be compounded when the developers become enamored of a particularly favorable characteristic of the project or of the product. These “red herrings” divert project focus away from the arduous path to success and, in the end, result in project failure."

Jan 1, 2012

By D. Mas Ivars, K. Suzuki, J. A. Vallejos

"A comprehensive geotechnical characterization has been undertaken at the El Teniente mine to describe and determine the rock mass behaviour strength properties of the primary copper ore. The Synthetic Rock Mass (SRM) modelling approach is used to simulate the mechanical behaviour of this heavily and unfractured rock mass. The micro-parameters of the model have been calibrated against mechanical properties and scaling laws for intact rock and veins, in order to represent virtual samples of four different geotechnical units. Results can be used to predict the rock mass scale effects, anisotropy, and brittleness properties that cannot be obtained using empirical methods.INTRODUCTIONThe primary copper ore at the El Teniente mine is described as very competent and massive, given that it exhibits a brittle behaviour (Rojas, Cavieres, Dunlop, & Gaete, 2000). This description is coherent with the geological description of the rock mass, which does not have discontinuities match as the definition provided by International Society of Rock Mechanics (ISRM, 1981). Only faults can be classified as discontinuities, but they are widely spaced. The primary copper ore has a high frequency of veins, where the cooper mineralization is hosted, these vein network structures are known as stockwork. Soft veins containing weak minerals as infill (chalcopyrite and anhydrite) control the disassembling of the rock mass during caving (Brzovic & Villaescusa, 2007).Presently, there are mainly two traditional methods used to estimate the strength of the rock mass: 1) determination of the strength envelope of the rock mass using scaling parameters from laboratory tests and 2) using numerical modelling based on back analysis of previous experiences of failure observed and measured in mining or civil excavations. The primary copper ore of El Teniente mine has no fractures; therefore, it is difficult to determine a rating that would enable to scale laboratory data, such as, RMR (Laubscher, 1977) or GSI (Hoek, 1994). This is the reason why the first option is not valid unless the entry data is manipulated or adjusted in order to obtain reasonable results. The second option requires, in general, a good characterization of a previous failure event in the rock mass, which is not always available. In recent years, new techniques of numerical modeling have been developed (PFC3D, ELFEN, Abaqus). Those methodologies are the third way to estimate the strength of the rock mass, but they are still in development. Particularly, the concept of SRM developed by Itasca is implemented in this study (Pierce, Mas Ivars, Cundall, & Potyondy, 2007; Mas Ivars et al., 2011), aiming to capture the real behaviour of the rock mass."

Jan 1, 2015

By K. Hawboldt, J. E. Halfyard, C. Bottaro

The removal of sulfur from leach residues has been practised in the zinc industry using a combination of flotation and hot melt filtration. The process is highly dependent on the nature of the concentrate and the subsequent residue. When the mineral constituency of the residue alters, the process can encounter significant operational challenges. An alternate method of converting elemental sulfur to water-soluble polysulfides was applied to leach residue from Vale's nickel demonstration plant in Argentia, Newfoundland. Reaction parameters, sulfur purity and other key indicators are discussed as is the potential commercial application.

Jan 1, 2011

By W. Tse, D. Wong

Dense medium separation (DMS) is one of several preconcentration methods used for early waste rejection from run of mine ores at relatively coarse particle sizes prior to additional milling and beneficiation. DMS has been used extensively in the coal, diamond and iron ore industries but lab scale and pilot test work has demonstrated successful separation and upgrading of other minerals such as lead, zinc, copper and lithium based ores using DMS. This paper reviews historical dense media systems, results from the pilot scale Condor DMS system as well as associated laboratory heavy liquid separation (HLS) test work.

Jan 1, 2014

By Dao Dac Tao

The Vietnam coal industry in recent years has achieved the rapid growth. However, in the process of industrialization and modernization of the country, the demand for coal for energy is constantly increasing. This paper presents the Vietnam coal industry in the last stage: the opportunities and challenges facing the coal industry as it strives to become modern, highly effective and capable of meeting the demands of national energy security, all in harmony with socio-economic and environmental needs.

Aug 1, 2013

In this study, flotation of fine galena, chalcopyrite and pyrite was performed after grinding with different extent of oxidation-reduction condition adjusted by grinding media. Sodium dithionite and iron ions were added in mill to simulate pulp potentials and iron oxidation species produced by grinding media, respectively. The types and quantities of the metal oxidation species on mineral surfaces were determined by EDTA extractions, while the surface electrical properties of minerals and interaction of different types of metal oxidation species were studied by zeta potential measurements. It was found that the nature and concentration of the absorbed metal oxidation species were dependent on oxidation atmosphere controlled by the iron amount of grinding media. These species interacted with each other and had an important role in determining flotation of fine galena and chalcopyrite as well as activation of fine pyrite by lead and copper.

Jan 1, 2006

By G. McIsaac

"This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development, and mining method. Based on practical considerations, maximum rates are set for each zone’s development and production capacity. For the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum daily development capacity is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Also, the fixed cost of operating the mine is taken into consideration whenever mining activities take place.Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analyzed. “Whatif” scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan."

Jan 1, 2005

By G. McIsaac

This paper discusses the formulation of a linear program with the objective of maximizing the cash flow of the long-term plan of an underground operation. A mine is split into eleven independent ore zones, each characterized by its reserves, required development, and mining method. Based on practical considerations, maximum rates are set for each zone?s development and production capacity. For the total mine plan, a minimum daily production rate is set along with a minimum feed grade to the mill. A maximum daily development capacity is set based on the equipment and labour available. Proven and probable ore is mined preferentially over possible ore in the early years of the plan. Also, the fixed cost of operating the mine is taken into consideration whenever mining activities take place. Once the linear program is solved, it can be critically reviewed, and unrealistic results can be identified. Some resource allocations constraints can then be changed in certain sectors, and new results can be analyzed. ?Whatif? scenarios can also be examined, such as determining the impact of hiring a contractor to develop a given sector, or dropping an ore zone completely from the plan.

Sep 1, 2005

By Han Xing, Cui Jianzhong, Qin Ke, Shao Bo, Zhang Haitao

In this paper, a new approach that uses hot-top DC casting process to producing multi-alloy ingots is present. The different type and size of composite and coated ingots (4045/3004/4045 three-layer composite ingots with section 630mm by 1500mm and 4045/3003 coasted ingot with F140mm/F110mm in diameter) are cast by this approach. The macro-morphologies and microstructures of the composite ingots, the temperature distribution and the element distribution in the interface zone were investigated, also and the interface bonding strength was measured. Results show that the solid supporting layer formed on the cooling plates plays a key role in the casting process of composite ingots. The solid supporting layer can prevent the blending of two melts by resisting the impact of alloy melt, which ensures the stable casting process and casting high quality composite ingots, because the contact height is increased using hot-top DC casting. In addition, fabrication and properties of 4045/3004/4045 three-layer composite ingots with section 630mm by 1500mm are reported in detail.

Jan 1, 2015