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By R. Vergunst, E. A. Devuyst, G. Robbins

"INTRODUCTIONThe Inca process for continuous cyanide removal from industrial wastewaters was patented in 1984 by G.J. Borbely, et.al. (1). The process requires SO2, air, lime and a copper catalyst. Both free and complexed cyanide are oxidized to cyanate in the pH range 8 to 10. Cyanide bound to iron is removed by precipitation as a ferrocyanide insoluble salt and other base metals are removed as hydroxides.The process was piloted in 1982 on barren bleed solution at Campbell Red Lake Mines Ltd., Ontario (2). Since 1982, the Inca SO2-air cyanide removal technology has been applied in twelve commercial installations. The process has significant advantages over other commercial processes in the completeness of cyanide removal and lower reagent requirements and costs.COMMERCIAL INSTALLATIONSBy the end of 1988 Inca will have applied its patented cyanide removal technology to twelve commercial operations. Three of these, namely Scottie Gold Mines, Dupont of Canada Expl. Baker mill and Carolin, all in British Columbia, Canada, have ceased cyanidation operations but SO2-air cyanide destruction results were good for all mills, particularly so for over two years for the Scottie mill.Removal of cyanide from CIL slurry tailings is applied at Equity Silver (9,500 tpd) and Inca's new 1,200 tpd mill at Inca/Golden Knight. Detoxification of CIP tailings is carried out by Colosseum California (3,600 tpd) and Canamax's Ketza River operation (360 tpd). Repulped tailings from Merril-Crowe flowsheets are treated at Total Erickson's Mount Skukum mill (300 tpd) and Skyline's Johnny Mountain mill (200 tpd) and barren bleed at Inco/Queenston's McBean mill (500 tpd). Lynngold's MacLellan mill (1,800 tpd) treats pond supernatant water. Plating shop cyanide effluents are decyanized at Kuntz Electroplating in Kitchener, Ontario. Many of the above commercial operations were described in some detail in previous publications (3,4). Typical installations are described in this paper. A summary of operating results is given in Table 1."

Jan 1, 1989

By John A. Hudson, Xia-Ting Feng, Joseph S. Y. Wang

Evolution over decades and progress over last five years have been made in many topics of interests to rock mechanics, geosciences, physics, and multi-disciplinary interactions in underground research laboratories and development facilities, as well as in underground energy recoveries and environmental assessments. Rock mechanics and geotechnical engineering advances are associated with quantifications of disturbed/damaged zones and rock alternation and bursting processes and creation of underground spaces and accesses associated with deepening of shafts and lengthening of tunnels. Geophysics and earth sciences advances are associated with continuing collections of seismic, electromagnetic, and gravitational data and conducting various thermal, hydrological, mechanical, chemical, and biological investigations, both separately, simultaneously, and in different coupled ways. Astroparticle and underground physics advances are associated with many long term experiments to detect rare events and needs for increasing larger and deeper halls to accommodate next generation detectors, shielings, and isolations. There are also increasing interesting in underground settings to explore multidisciplinary and inter-disciplinary sciences and technologies. Energy and environmental sciences and assessments have evolved from traditional oil and gas focuses to recent activities associated with green resources and alternative recovery/disposal strategies. The evolution and progress of these interdependent and related fields are discussed in this quadrennial Congress.

Jan 1, 2015

By K. Gardner

"Many deposits have a geological model developed early in the project stages, which is not always reviewed or modified as the project matures and production commences. Conversely, ongoing pressures, due to a combination of declining head grades, a push for increased revenue and a multitude of other reasons, leads to processing plant modifications, with the primary aim being to increase production. Often, the ore deposit knowledge is not sustained or developed during the operational stages to the level carried out during the prefeasibility and feasibility study phases. This results in the variability within the deposit being poorly understood and a lack of data and knowledge being available to support (and ideally optimise) operations particularly in an environment where the flow sheet has changed and ore feed requirements are complex.INTRODUCTION This paper presents a case study of ore deposit knowledge development and corresponding process plant operating strategy at the Ladolam Gold Deposit, commonly referred to as the Lihir gold deposit in Papua New Guinea. The gold deposit is located in a tropical equatorial climate on the east side of Lihir Island in the New Ireland Province of Papua New Guinea. Gold mineralisation was discovered in 1982, and was followed by a major exploration campaign by a joint venture between Kennecott (Rio Tinto) and Nuigini Mining Limited. The first drillhole was drilled in 1983, and after an extensive period of drilling consisting of 343 holes for 83,500 m, the final Feasibility Study was completed in 1992. The feasibility study was based on a Reserve base of 37.9 Moz in refractory sulphide ore, with gold extraction proposed to occur via whole ore pressure oxidation due to the refractory nature of the mineralisation. The Lihir Special Mining Lease (SML) was granted in 1995 to a new PNG company – Lihir Gold Limited, and Rio Tinto established Lihir Management Company to develop and operate the mine on behalf of LGL. Mining and processing of the deposit commenced in 1997. Newcrest Mining Limited purchased Lihir Gold Limited in August 2010, and subsequently completed a major plant upgrade including the installation of additional grinding, autoclave and carbon-in-leach capacity. Post commissioning of the upgrade, Newcrest has continued to increase throughput and production. A reinvigorated ore body knowledge development program has significantly assisted this process in identifying operating strategies for the process plant and delivering recovery improvement projects to address declining head grade and recovery due to increased stockpile feed and flotation circuit use."

Jan 1, 2017

By Y. Zedan

In this study, the statistical design of experiments (DOE) was applied to study and regulate the properties of near-eutectic Al-11%Si alloys. Develop regression equations for such response variables as hardness, yield stress, ultimate tensile stress, percent elongation, total cutting force, cutting power, and tool life together with other factors which, include the percentage composition of the alloying elements, and the requisite modification (Sr) level. These equations may be analyzed quantitatively to acquire an understating of the effects which the main variables and their interactions may have on the mechanical behaviour and the machinability of the alloy under investigation. The results reveal that increasing the levels of Cu and Fe content results in an increase in hardness, yield stress, and ultimate tensile strength in both modified and non-modified alloys. On the other hand, both Cu and Fe appear to affect the percentage elongation adversely, whereas the Sr-level has a positive effect on this parameter. It was found that Sr-levels have the most significant effect on the cutting forces and cutting power followed by the content in Fe and Cu. The results also reveal that the interaction coefficients of these variables have a significant effect on tool life compared to the main independent variables. This fact may be attributed to the formation of complex insoluble phases between Cu, Fe, Si, and Al as investigated using Scanning Electron Microscopy (SEM) attached to an EDX analysis system. The accuracy of the regression equations in predicting the expected properties has been verified by carrying out random experiments in the range of variation of these variables.

Jan 1, 2011

By K. H. J. Clarke

SINCE the beginning of this century the non-ferrous mineral industry has contributed $17,809,-000,000 to the economic growth of Canada. To contemplate the vast amount of investment capital required and the resultant beneficial distribution of these billions of dollars for labour, transportation, supplies, taxes and dividends, challenges the imagination. It is the purpose of this paper, (a) to trace the development of the industry since its formative period to the present; (b) to discuss the current situation and problems; and ( c) to attempt to peer into the hazy future. Although there are 21 metals currently being produced in Canada which are classified as non-ferrous, or as alloying metals, copper, lead, zinc, nickel-the metals which will be discussed in this paper-constitute almost 60 per cent of their total value. ;The story

Jan 1, 1961

By B. A. Strathdee

An arsenical ore containing both pyrite and arsenopyrite was heated to a temperature at which decomposition and distillation took place. The condensate consisted of metallic arsenic and arsenic disulphide, although the analysis of the ore showed that volatile arsenic and sulphur were present in proportion to produce a condensate of arsenic trisulphide and sulphur. Distillation tests on the mineral arsenopyrite also produced a condensate of metallic arsenic and arsenic disulphide. This arsenic sulphide gave a distinct x-ray diffraction pattern which was not listed in the A.S.T.M. data file. This same sulphide can be produced by heating a mixture of arsenic and sulphur in vacuo. Its chemical analysis corresponds to As2S2. The dissociation pressures of arsenopyrite and the vapour pressures of arsenic disulphide and arsenic metal were measured, using a quartz "spoon" gauge. The dissociation pressures of arsenopyrite were compared with the published data for the dissociation pressures of pyrite to account

Jan 1, 1961

By H. A. Hamza, J. Visman

"This is a report on the combined application of ""long-chain"" flocculants and classifier cyclones in the field of slimes treatment, with emphasis on the simultaneous thickening and clarifying of industrial effluents, at low cost. The principle of the process described below involves: (1) the formation of small floes of relatively great strength, by sequential dispersion and conditioning, with average floe size of about 1501 microns; (2) the floes being of sufficient strength to withstand the shearing forces operating within a cyclone and consequently behaving as solid particles with an equivalent diameter (Stokes) that exceeds the size cutpoint of the classifier cyclone; (3) the removal of flocculated solids by means of a classifier cyclone the size cutpoint of which permits effective separation of these solids from the water. Results of test work to date indicate that a broader use of cyclones in industry is possible with the above types of flocculants because the submicron particles and colloidal material are readily collected and clear water is produced, with the attendant advantages of compact construction and low cost that are characteristic of centrifugal separation. The process generally permits classifier cyclones of medium throughput capacity (e.g. 12-in. diam.) to be used for clarifying effluents that contain minus 10-micron particles."

Jan 1, 1973

By Hongyan Qu, Lihui Zheng

"Horizontal wells in coal seams, Qinshui basin, China are prone to wellbore instability problems induced by drilling, completion and production operations due to the presence of natural cleat network, anisotropy with regard to permeability, brittleness and mechanically weak property of the coal rock. The mechanism of wellbore instability in coal seams is very different from that in conventional formations, the traditional wellbore stability study methods therefore, are not proper for wellbore stability analysis in coal.In this study, the mechanism and controlling of wellbore stability of coal seams in the Qinshui basin was investigated through theoretical modeling, laboratory experiment and field operation. Firstly, a new physical model of wellbore stability for highly-cleated coalbed was proposed, considering the combined effect of mechanical mechanism and reservoir characteristics, specifically, taking the effect of reservoir pore pressure in the vicinity of the wellbore on the wellbore stability into account. Then experiments on the triaxial stress evaluation were conducted at laboratory where rock mechanical parameters such as Poisson's ratio, Young's modulus, compressive strength, tensile strength, angle of internal friction and cohesion ability were measured respectively. The in situ stress at different depths in four wells of Zheng 1-303, Zheng 1-308, Zheng 1-309, and Zheng 1-310 in the Zhengzhuang were calculated, and the collapse pressure and formation breakdown pressure were predicted through the theoretical model we developed. Finally, by comparing the maximum collapse pressure and minimum breakdown pressure of the four wells in the coal as well as in the roof and floor of the coal seams, the fluid weight window for safe drilling in each coal seams was determined, and appropriate approaches against anti-sloughing in coal seams, Qinshui basin were applied in the field operation.The wellbore stability was found not only related to the wellbore pressure, but also affected by the pressure in the reservoir through the theoretical model. The fluid weight window for safe drilling in each coal seams varies with the coefficient of wellbore stability in the model. The laboratory experiment results indicate that the roof and floor of 3 # coal in Qinshui basin has high breaking strength, high heterogeneity, and are easy to collapse and breakdown. In addition, the whole rock mineral analysis shows that 3 # coal in the Duanshi block has high clay content, resulting in the phenomenon of hydration swelling as clay encountered water, and leading to unstable coal and extreme large drilling uncertainties. Due to the effect of the unstable rock mechanical properties of the roof and floor formation on the wellbore stabilizing, drilling parameters, drilling fluid performance and BHA were optimized during the drilling process according to the formation properties, rock mechanical properties and drilling techniques in the field operation."

Jan 1, 2015

By Frederik H. Kriel, John Ralston, Craig Priest

"Stream-based microfluidic solvent extraction offers a novel alternative to bulk-scale mixer-settler operations. However present maximum throughputs are restrictive and there are engineering challenges that need to be overcome before the technology is robust. This is especially the case for mineral processing, where circuits must be able to handle variable feed streams with long retention times and where maintenance should be minimized. This paper highlights research directed at investigating and evaluating these challenges for actual mineral leach solutions of metal ions. Molecular and particulate channel fouling is discussed. Most extraction systems studied to date show no effects that would preclude use of the technology. For rare earth elements (REE) with fast extraction rates, scale-up of volumetric throughput to 100 L/h using suitable arrays of channels, microfluidic chips and modules is shown to be achievable using a small contactor (approx. 2 m3) platform. This requires only 2–3 % of the typical aqueous phase inventory and residence time used in an equivalent mixer-settler. For a circuit with 100 contactors, the overall residence time would be less than 1 h, using an aqueous inventory of 40 L.INTRODUCTIONHydrometallurgy is of pivotal importance in many mineral processing circuits around the world, with liquid-liquid solvent extraction (SX) a key step in the separation of many base metals (e.g. Cu and Ni), radioisotopes, precious metals, and the ‘technology’ metals, such as rare earth elements (REEs) (Ritcey & Ashbrook, 1979). The standard equipment for SX in mineral processing is the mixer-settler, in which liquid dispersions are created, by agitation, to increase the surface-to-bulk ratio and, thus increase the mass transfer rate between the liquid phases. In stream-based microfluidic SX (microSX), these high surface-to-volume ratios are achieved by contacting microscopic streams (Ciceri, Perera, & Stevens, 2014), rather than forming small droplets, so that phase disengagement can be accelerated (essentially instantaneous via branching of the two streams of liquid at a channel junction). MicroSX is profoundly different from bulk mixer-settler SX operations and offers exciting opportunities for processing hydrometallurgy solutions (Kriel, Holzner, Grant, Ash, Woollam, Ralston, & Priest, 2015; Priest, Zhou, Klink, Sedev, & Ralston, 2012). Nonetheless, the advantages of using microfluidic environments are presently balanced by very significant challenges relating to throughput, process control, coupling of stages, flow stability, and fouling. If these challenges can be met using smart chip designs, process control and clever engineering, high-value/low-volume SX processes stand to benefit greatly."

Jan 1, 2016

By Sarah Bélair, Denis Beltrami, Deka Moussa Ragueh, Valérie Weigel

"Scandium is a highly valuable element belonging to the rare earth elements (REE) but it has different chemical and physical properties from those of lanthanides. This metal is generally used in aluminum-scandium alloys and in fuel cells but the development of its market is slowed down by its high price (more than 1000 US$/kg for a 99.0% grade product). Indeed, the low scandium content in the continental crust (an average of 22 ppm) and the difficulties to extract it selectively from solutions containing high impurity concentrations increase the cost of the recovery processes. Nowadays, scandium is primarily recovered as a byproduct.ERAMET is developing a hydrometallurgical process in Gabon (Mabounié) in which the scandium content in the deposit reaches 10 to 100 ppm. The Maboumine project consists in the extraction and purification of uranium, niobium, tantalum and REE from Mabounié ore. In the frame of this hydrometallurgical project, ERAMET had also studied the feasibility to recover scandium as a byproduct. During the ore leaching, uranium and rare earth elements including scandium are solubilized into the pregnant leach solution (PLS). Among the various methods investigated to recover scandium from the PLS, liquid-liquid extraction using Primene JM-T as extractant was chosen and tested first at laboratory scale and then at pilot scale. Selective stripping of the loaded organic was carried out by using phosphoric acid solution, allowing the selective recovery of scandium from thorium and zirconium partially extracted from the PLS by Primene JM-T under the process conditions."

Jan 1, 2016

By David S. Robertson, Richard F. Douglas

"Uranium is a lithophile element of relatively low natural abundance. Concentrations of uranium form through processes of erosion and sedimentation, and over 90 per cent of the western world's uranium ore reserves are in sedimentary rocks.Proterozoic quartz-pebble conglomerates contain about 60 per cent of the known uranium reserves. These are all similar in appearance, in mode of distribution and in manner of origin. They carry uranium minerals and/or gold and abundant pyrite. Their unique distribution in Huronian time required a pre-existing crust well enough evolved to have plentiful quartz and abundant gold, uranium and pyrite. The materials of value were deposited as detrital heavy minerals prior to the appearance of an oxidizing atmosphere in late Proterozoic time.Epigenetic uranium deposits occur in arkosic sedimentary rocks through the entire geological column. About 30 per cent of the western world's known ore reserves are in _these rocks. This type of deposit is particularly prominent in semi-arid parts of the United States, having yielded most of the uranium ore produced and containing nearly all of the known reserves.The Western States type"" of deposits occur in lenticular, permeable stream-laid sedimentary rocks. The de-posits are believed to have been precipitated from moving ground water at locations where plant debris or other organic matter had accumulated. The uranium may be derived from volcanic sediments, which are commonly associated with the units containing the ore, or it may be leached from exposed granite surfaces or from granitic debris which forms the sediments.A significant part of the world's uranium resources are in black shales and lignitic rocks. The lignites that contain uranium are virtually valueless as potential sources of heat. Uranium concentrations at levels such as to be potential sources of by-product uranium occur in many phosphorites.Reworked sediments may provide uranium in pegmatites and vein-like deposits."

Jan 1, 1970

By J. B. Boisvert, P. Oshust

A significant source of uncertainty in the diamond resource contained in kimberlite pipes is the volume of the pipes. Often the material within a pipe will be mined as ore, leaving the actual geometry of the pipe as a significant source of uncertainty. It is desirable to use stochastic techniques, rather than deterministic methods, to model pipe geometry because stochastic techniques generate multiple realizations that are reproducible and can be used to assess uncertainty in pipe geometry. The proposed methodology uses sequential Gaussian simulation of pierce point locations interpreted from drillholes through a kimberlite pipe. Kimberlite pipes are approximately cylindrical in shape; therefore, the data are transformed to cylindrical coordinates to facilitate the simulation of pipe geometry. Rather than using xyz coordinates to define the pierce points, z, ??and pipe radius are used. The radius variable can be simulated in z-??space to generate multiple realizations of pipe volume. Uncertainty in the volume of the pipe can then be evaluated. This methodology is demonstrated with a kimberlite pipe at BHP Billiton’s Ekati diamond mine.

Jan 1, 2008

By A. M. Esteves

This paper offers an overview of local content policies and practice in the mining sector. Specifically, the paper aims to answer the question of how national and regional governments, industry and civil society can work together to seek an optimal outcome while pursuing their diverse objectives. The paper begins by defining local content and its scope at the subnational level. Specific recommendations for the design of local content policies to mitigate social, economic and governance risks are developed. The document then offers some recommendations regarding the role of partners in design, implementation, monitoring, and enforcement of local content policies.

Aug 1, 2013

By B. C. Jago, H. Derbuch

"The Freightrain kimberlite is located on the Brodeur Peninsula, Baffin Island, Nunavut. Twin Mining is exploring the pipe and adjacent land (79 claims/655 km2) using a combination of airborne geophysics, soil sampling, diamond drilling, trenching and bulk sample processing. The pipe originally was discovered by Cominco Limited in 1975, re-evaluated in 1993 by Lumina Investment Corporation, when it was staked as the Zulu pipe, and subsequently covered by three claims in 1998 by Helix Resources who called it Freightrain.The Freightrain pipe coincides with a strong, ovoid-shaped aeromagnetic anomaly. It is the only surface exposure of kimberlite within a 30 km long linear trend of fourteen aeromagnetic anomalies that are up to 600 m in diameter.The pipe is exposed in the crater facies, near the transition into diatreme facies as indicated by the occurrence of pyroclastic kimberlite characterized by abundant olivine macrocrysts, juvenile lapilli and kimberlite autoliths set in a serpentine-calcite matrix. Olivine, Cr-pyrope garnet and chromite are the most abundant macrocrysts; clinopyroxene, ilmenite and phlogopite mica occur in minor to trace amounts. Garnet and chromite harzburgite, garnet lherzolite, garnet-spinel lherzolite and rare eclogite dominate the xenolith population.Garnet and chromite mineral chemistry indicate encouraging diamond prospectivity and that potentially diamondiferous garnet and chromite harzburgite were the principal sources of diamond in the mantle at the time of kimberlite eruption.Single clinopyroxene grains define an ~42 mW/m2 sub-continental geotherm that is rooted in the diamond stability field. This compares to a slightly hotter geotherm (~48 mW/m2) for adjacent Somerset Island kimberlites with an origin in the graphite stability field. This data accords with the general lack of sub-calcic Cr-pyrope garnet, diamond inclusion chromite and diamond in Somerset Island kimberlites."

Jan 1, 2002

By L. M. Dwarkin

Strip mining in Western Canada, though of considerable importance, is a fairly recent development for many of the operators in the district. Adding to the difficulty of unfamiliarity is the fact that a great deal of the stripping is done on pitching seams, for which the engineering and economic principles of setting the most advantageous strip ratio are not readily apparent. The novelty of the operation combined with the complexity of the principles involved can easily lead to misconceptions as to the determination of the economic ratio. Definition of Strip Ration There are two commonly accepted meanings of the term strip ratio: (1) The ratio of feet of overburden to be stripped per foot of coal recoverable. (2) The ratio of cubic yards of overburden per cubic yard or ton of coal. The first definition is inapplicable to pitching seams so, throughout this paper, strip ratio will be taken as the ratio of cubic yards of overburden to be removed per cubic yard of coal recoverable. Economic Ratio In the case of flat seams, the strip ratio is fixed by existing natural conditions, and the magnitude of this ratio determines whether stripping is economically feasible. With pitching seams, however, the strip ratio is a variable. On the outcrop, there is usually some coal which can be obtained with little or no stripping. As the work is carried down the pitch of the coal seam, the proportion of overburden continually increases until a point is reached where it is no longer economical to continue the operation. The question immediately arises as to the location of this point, and this resolves into the problem of determining the most favourable strip ratio, or, to use the accepted term, the economic ratio.

Jan 1, 1949

By A. W. Jolliffee

ANY attempt to forecast the mineral resources of a largely unknown region is hazardous and, in the case of the Northwest Territories, such a task is even more hazardous than usual. This is not merely because of the immense territory involved (over a million and a quarter square miles), only a small fraction of which has ever been explored or prospected, but also be-cause both the geology and mineral deposits thus far examined show many unique features, and, finally, because the region is being actively prospected at the present time. However, in view of the present widespread interest in Canada's mineral resources, a brief compilation of what is known regarding mineral occurrences and geology in the explored parts of the far north seems timely. From these assembled data, a few inferences are warranted as to future mineral production from this region. HISTORY The story of mineral discovery in the Canadian northwest is a fascinating one. As well, it abundantly illustrates the importance of mineral occurrences in indicating future mining possibilities. The same sequence of events has repeated itself too often to be merely fortuitous.? In most cases, the dis-covery of a mineral deposit of possible economic value has been foreshadowed by the finding of the valuable mineral or an associated mineral in the same district, generally in small quantity, by an early explorer or traveller. Thus, John Franklin reported oil seepages from the base of Bear Rock, near Nor-man, at almost the very spot where oil was struck nearly one hundred years later. Again, some would-be Klondikers, deterred by the hardships of the route, remained to prospect around Great Slave lake, and were the first to report the Pine Point lead-zinc occurrences there and the gold-bearing veins on Yellowknife bay. Sporadic prospecting followed at the latter locality for over thirty years before the recent rich strikes were made. Similarly, in 1847, Dr. John Rae picked up a boulder of copper ore south of Rankin inlet, on Hudson bay. More than eighty years later, a body of copper-nickel sulphides carrying values in platinum metals was found at this locality. Also, the report of cobalt bloom on the east coast of Great Bear lake brought back by a Geological Survey of Canada party in 1900 was a factor in the events leading to the discovery of silver and radium there in 1930.

Jan 1, 1937

By P. M. Pearson

This paper describes the principles ()f systems engineering and their application to the various transport problems confronting the mining industry. The organization of mining operations into sub-system design problems is explained.

Jan 1, 1970

By C. A. Y. Shephard, H. L. Brusset

Pressure maintenance by water flooding in the Pembina Field made consideration of wet crude dehydration and disposal of the produced water mandatory. Crude dehydration, the treatment and disposal of produced water, as well as the sale of gas and crude oil were expected to be handled more efficiently at one central point than at several conventional batteries. This plan was effected by routing the produced fluids to the central station by way of several well testing batteries referred to as satellites. To realize the full efficiency inherent in such consolidation the entire system was made self-regulating. Programming ensures the testing and proper routing of all products to their destination. Forty producing wells have been self-operated during the winter 1959 -1960 with gratifying results.

Jan 1, 1960

By A. D. Huffman

This paper covers the major salt deposits of Canada, with a brief summary of the early history of the industry and a more extended outline of progress since the second world war. Both dry mining and solution mining are covered, and the future of salt mining in Canada is discussed.

Jan 1, 1968

By C. A. Pickles, K. Mackowiak, D. Gajonera

"Shake-flask oxidation tests were performed on Red Dog mine waste to study the initial dissolution behaviours of lead, zinc, and iron. The conditions for accelerated acid generation in terms of Eh and pH were determined. Each mineral behaved distinctly, with galena dissolving first, followed by sphalerite, then pyrite, although there was some overlap in behaviour. Iron was not detected in solution until approximately day 40 and was present at low concentrations. The experimental conditions and the theoretical model results indicated the formation of iron oxyhydroxides at low weathering times and jarosite at longer times.RÉSUMÉ Des tests d’oxydation par agitation en flacon ont été effectués sur les déchets miniers de l’exploitation Red Dog afin d’étudier les comportements initiaux de dissolution du plomb, du zinc et du fer. Les conditions entraînant la production accélérée d’acide en termes d’eH (potentiel d’oxydoréduction) et de pH (potentiel d’hydrogène) ont été déterminées. Chaque minerai se comportait différemment ; la galène a été la première à se dissoudre, suivie de la sphalérite, puis de la pyrite, mais un certain chevauchement des comportements a été observé. La présence de fer en solution n’a été détectée qu’après environ 40 jours et ce, à de faibles concentrations. Les conditions expérimentales et les résultats du modèle théorique signalaient la formation d’oxyde-hydroxyde de fer sur de courtes périodes d’altération atmosphérique, et de jarosite sur des périodes plus longues."

Jan 1, 2017