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By N. Afrin

The microstructure and tensile properties of AZ31B-H24 magnesium (Mg) alloy after friction stir welding (FSW) were evaluated. The grain size was observed to increase from approximately 5 µm to about 9 µm after FSW. The obtained Hall-Petch type relationship showed a strong grain size dependence of the hardness values. While the FSW led to about half of the yield strength of the base magnesium alloy, the ultimate tensile strength after FSW could reach about two thirds of that of the base alloy. The hardening capacity of the FSWed samples was about twice of that of the base alloy. The strain hardening exponent of the base alloy was found to be about 0.1 whereas it became larger than 0.3 for the FSWed samples. After yielding the base alloy showed a high initial and almost constant work hardening rate, corresponding to linear hardening stage II, followed by stage III with a decreasing hardening rate. Stage II linear hardening was observed to be absent in the FSWed samples.

Jan 1, 2007

By Kazutoshi Haga, Batnasan Altansukh, Atsushi Shibayama

In this study, the dissolution behavior of copper and arsenic from five different copper concentrates containing 21-34.7 %wt. of Cu, 1.3-7.3 %wt. of As and 15.6-27.5 %wt. of Fe were investigated under high pressure oxidative leaching conditions. Leaching experiments were conducted using different leaching reagents such as ferric sulfate, sodium chloride, deionized water, sulfuric acid and ferric sulfate-sodium chloride mixture in order to compare the effectiveness of each on the dissolution of copper and arsenic from copper concentrates. The effects of ferric sulfate (0.1-1 mol/L), sodium chloride (0.1-0.5 mol/L) and leaching temperature (100-180C) were investigated under 1 MPa autoclave pressure , particle size >45 m, pulp density of 100 g/L, stirring speed of 750 rpm and leaching time of 60 min. Results showed that the most effective leaching reagents for the dissolution of copper are 0.34 M NaCl and a mixture of 0.1 M Fe2(SO4)3 - 0.34 M NaCl, in which As extraction did not exceed 7%. The copper concentration in the pregnant leach solution obtained after leaching using 0.1 M Fe2(SO4)3 - 0.34 M NaCl was 13-30 g/L, while the concentration of As and Fe were in a range between 0.3-1 g/L and 0.2-10 g/L at 160C. INTRODUCTION Copper sulfide minerals, such as chalcopyrite (CuFeS2), chalcocite (Cu2S) and covellite (CuS) are used for the production of copper in mining and metallurgical industries worldwide. The conventional pyrometallurgical processing followed by electrorefining is a common process for the production of high purity copper (Moskalyk, & Alfantazi, 2003; Padilla, Aracena, & Ruiz, 2012). However, the degradation of copper content and an increase in the amount of metal impurities, especially arsenic (As), antimony (Sb) and bismuth (Bi) in copper concentrates cause serious problems to the production of copper and environmental pollution (Basha, Selvi, Ramasamy, & Chellammal, 2008; Long, Peng, & Bradshaw, 2012). Hydrometallurgical processes are used to recover metals from refractory ores, concentrates and tailings by leaching (Long, Peng, & Bradshaw, 2012; Masloboev, Seleznev, Svetlov, & Makarov, 2018). During the last decades, hydrometallurgical processing for the recovery of copper from enargite-bearing copper ores and concentrates has been extensively investigated due to its relatively more environmentally benign and less capital costs than the conventional pyrometallurgical processes (Long, Peng, & Bradshaw, 2012; Masloboev, Seleznev, Svetlov, & Makarov, 2018; Choubey, Lee, Kim, & Kim 2018). However, several issues facing the hydrometallurgical processing are incomplete extraction of copper associated with the coprecipitation of iron compounds, difficult stabilization of toxic impurities and production of a contaminated copper product (Dreisinger, 2003; Safarzadeh, Moats, & Miller, 2014). Hence, a number of studies have been conducted on the selective dissolution of copper from copper ores and concentrates or selective removal of arsenic leaving a clean copper residue using various leaching reagents or lixiviants (Safarzadeh, Moats, & Miller, 2014; Mihajlovic, Strbac, Zivkovic, Kovacevic, & Stehernic, 2007; Tongamp, Takasaki, & Shibayama, 2009). More extensive studies on the selective extraction of copper from enargite- bearing copper ores and concentrates are much needed to improve copper recovery.

Jan 1, 2019

By Stephen G. Downs

PCF?, or Penetrating Cone Fracture, is a propellant-based technique for rock excavation, which has significant potential for the mechanization of narrow-vein mining. The technique is currently being developed for use in the narrow-vein flat-dipping gold and platinum deposits in South Africa in conjunction with major mining companies. The technique is also applicable to steeply dipping vein deposits, such as those found in North America, Australia and elsewhere. The implementation of PCF? in South Africa to date is reviewed and plans for the introduction of PCF? excavation in other areas are highlighted.

Oct 1, 2001

By A. F. Robertson

FOR several years, the rock-burst question has been given serious consideration by the operating staff at Wright-Hargreaves mine and, as a result of observations and experiences, several different methods of mining have been developed which are now in use in various parts of the mine. These are described in the following pages. It should be emphasized, how-ever, that these methods, and the views expressed in this paper, are based solely on conditions at Wright-Hargreaves mine. Such conditions may or may not be similar to those obtaining in other mines in the Kirkland Lake area, where ore occurrences, veins, wall-rock, faulting, intrusives, etc., may be entirely different. Size and shape of ore-bodies, composition of the ore-bodies and their surrounding rocks, locations of intrusives and sedimentary rocks, and direction, dip, and strength of faults, all introduce problems that are peculiar to each individual mine. Ground failure' in coal and metal mines is not at all unusual. A variety of systems of mining have been developed to delay movement of large or small blocks of ground, or, in some instances, to take advantage of the fact that ground movement, due to mining operations, is unavoidable. Ground failure may be either slow collapse or it may take place with explosive violence. It is principally with the latter condition that we are concerned in the mines of the Kirkland Lake district.

Jan 1, 1939

By M. A. Cristovici

"In the last few years CANMET has taken the initiative by investigating the possibility of reactivating abandoned old tailings dumps (for gold production) which would be of potential economic interest across Canada.Nova Scotia was one location where numerous gold processing plants were in operation in the early days. A survey of the old tailing dumps was conducted and some areas of interest were selected. Among them were the sites identified as Lake Charlotte and Forest Hill.Ore samples collected from those tailing ponds were examined for their chemico-mineralogical composition and investigated for gold extraction. Three technological concepts were tested: flotation, direct cyanidation and flotation followed by cyanidation of the flotation concentrate. The combined flotation- cyanidation variant, yielding a gold recovery in the range of 90%, was recommended for processing the tailing ore.Pilot-plant runs carried out by a commercial testing firm (data not included in this paper) confirmed the conditions and results of CANMET's technology.As a result a consulting-engineering firm designed the processing plant which is expected to begin operation in the near future.IntroductionIn the last few years CANMET initiated a research program to locate in Canada, abandoned gold-silver tailing dumps of potential economic interest and to explore the possibility of recovering the precious metals from these old deposits by modern techniques.A literature search revealed that the first production of gold in Canada was recorded in British Columbia in 1858 and that, production prior to 1900 was essentially restricted to the Yukon, British Columbia Nova Scotia and Quebec. During the early 1900s, Ontario, Manitoba and the North West Territories joined the ranks of the gold producers.Early milling and recovery methods were mainly restricted to sluice boxes, gravity stamps and amalgamation. Froth flotation and cyanidation were introduced at about the turn of the century.Recovery of gold at plants using flotation and cyanidation was very good, therefore the tailing ponds resulting from those operations would, very likely be of little or no economic importance. However, the gold recovery at the amalgamation and gravity concentration plants appeared to be lower, indicating the possibility that significant amounts of recoverable gold would have been carried with the tailings to the dump sites."

Jan 1, 1986

By G. A. Kosick, G. S. Dobby

"This paper presents the principles and application of a recently developed control system for flotation columns and column circuits. The control system uses triple pressure sensors to directly sense zone densities and level, and to help in characterizing the operating behaviour of individual columns. A complete expert system development tool is incorporated within the system to provide the facility for full operator training, an on-line help facility, and a means for incorporating the column behavioural patterns into decision making rules. The system is configurable to any number of columns and can be run in either supervisory mode or direct control through Minnovex PIO software. Additional process signals can be interfaced with the system if desired. Operating experience with the control system on the Minnovex column flotation pilot plant is described.I: INTRODUCTIONColumn flotation cells have been more difficult to control and are more sensitive to circuit changes than conventional mechanical flotation cells. This susceptibility encouraged investigation into various types of control strategies ranging from inexpensive single pressure measurements for level control, to highly instrumented and expensive systems using a variety of control methods.Flotation operators, in many cases, do not understand the column control philosophy or have not been trained to deal with this new type of cell. Some operators have subsequently absolved themselves of the column operating responsibility. Some column cells, for example, have run for hours with slurry pouring over the top or no froth coming off at all.ColumnEX is a column flotation control system which was developed from the viewpoint of an operating shift foreman who wishes to:1. control the column or column circuit through a genuine understanding of what is happening inside the columns, and2. to share this knowledge with his flotation operators and be available to guide them through times of circuit upsets."

Jan 1, 1990

By G. G. Bowser

Introduction Flame shots are of very infrequent occurrence in the coal mines of Nova Scotia. Probably not more than one is recorded in three months. Many shot-firers have never experienced one, and many never will. As a consequence, although all such occurrences are very carefully investigated, information concerning the cause of flame shots is somewhat meagre. In the course of the years, however, something has been learned of the practices and conditions that are responsible for them. During the past ten? years, over seventeen million shots were fired in the coal mines of Nova Scotia and only fifty-two faulty shots were reported or investigated during that time. In thirty-nine of these, flames were reported; in five, sparks only; and in eight, smoke only. In eight of these occurrences, unburned explosive was found after firing. In one of these eight, flame was seen in the back part of the hole, and an accompanying hissing sound pointed to burning explosive. In four of them, there was no evidence that gas was not ignited. All samples of explosives from these faulty shots which were submitted for analysis were found to be normal, except two, in 1937, which contained excessive moisture. These two samples were from two following shots in the same room on the same day. The initial cause of trouble with all eight shots was one or several of the following: explosives in poor condition, separation of cartridges, incorrect priming, shot hole in poor condition or not properly cleaned. In the case of sixteen or seventeen of the thirty-nine shots which flamed, data are insufficient for conclusions to be drawn as to the cause of the flame.

Jan 1, 1947

By T. H. Chuang, Y. Y. Shiue

"Rapid whisker growth was significantly alleviated in a Sn-58Bi alloy doped with 0.5 wt.% La. Experimental results showed that many thin, plate-form intermetallic phases appeared in the solder matrix. The absence of tin whiskers was correlated to the shape effect of RE-containing intermetallic plates. After reflowing, Cu6Sn5 intermetallic compounds appeared at the solder/pad interfaces of Sn-58Bi and Sn-58Bi- 0.5La packages with OSP pads, which grow linearly during the aging at 75 and 100? for various times ranging from 100 to 1000 h. In addition, the interfacial intermetallics layers in Sn-58Bi-0.5La solder joints were also observed thinner than those in undoped Sn-58Bi joints. However, RE-containing interfacial intermetallic compounds in Sn-58Bi-0.5La solder joints led to lower bonding strengths in both ball shear tests (0.4 mm/s) and high speed ball shear tests (2000 mm/s). All the reflowed and aged solder joints of both packages were ruptured through the solder balls indicating brittle characteristic INTRODUCTIONIt has been widely reported that solder alloys doped with rare earth (RE) elements reveal many beneficial effects, such as higher strength, lower melting point, improved wettability, and longer creep life (Wu et al., 2004; Ma et al., 2002; Chen et al., 2002). In addition, Dudek et al. reported that the alloying with 0.5 wt.% La in Sn-3.8Ag-0.7Cu solders resulted in an increase of rupture strain, up to 150% over undoped solders (Dudek et al., 2006). However, Chuang and Yen observed that a large amount of long, fiber-shaped tin whiskers were extruded out of the oxidized CeSn3 intermetallic clusters in the matrix of a Sn-3Ag-0.5Cu-0.5Ce solder air-stored at room temperature for several days (Chuang & Yen, 2006). Furthermore, many coarse hillocks appeared around the CeSn3 clusters in the RE-doped alloy after storage in an air furnace at 150? for several minutes. Chuang proposed a mechanism for the phenomenon of rapid whisker growth, which the predominate oxidation of CeSn3 intermetallics in Sn-3Ag-0.5Cu-0.5Ce solders induced compressive stress and extruded the tin atoms out of the specimen in the form of tin whiskers (Chuang, 2007). However, further investigation showed that Sn-9Zn-0.5Ce solders, after long term exposure at room temperature and 150?, were immune to the whisker growth; the immunity was attributed to the refining of the CeSn3 intermetallic phase in the alloy (Chuang & Lin, 2008). The inhibition of tin whiskers through the refining of rare earth containing intermetallics was further observed in Sn-3Ag- 0.5Cu-0.5Ce solders doped with 0.5 wt. Zn (Chuang & Lin, 2009). In addition to the size effect, the thin plate shape of intermetallic compounds was also shown in this study to inhibit the whisker growth on the surface of Sn-58Bi-0.5La solders."

Jan 1, 2012

By Will S. Pettitt

Fracture Network Engineering (FNE) is the engineering design of rock mass disturbance through the use of advanced techniques to model fractured rock masses numerically, and then correlate field observations with simulated fractures generated within the models. Microseismic (MS) monitoring is a standard tool for evaluating the geometry and evolution of the fracture network induced during a hydraulic treatment, principally by source locating MS hypocenters and visualizing these with respect to the treatment volume and infrastructure (Figure 1). The integrated use of Synthetic Rock Mass (SRM) modeling of the hydrofracturing with Enhanced Microseismic Analysis (EMA) provides a feedback loop in which the SRM is constrained by the information provided by the MS data and the in-situ behavior of the fracture network is better understood, leading to informed decisions on future field operations. This paper discusses the technologies used in FNE and some of the developmental challenges we face in order to provide a more efficient and robust application of the approach. One particular challenge is the accurate representation of MS source data within the models (locations, magnitudes and mechanisms), and the ability to correlate these data effectively with field results. This challenge is being overcome by the development of more efficient numerical modeling algorithms, providing simulations in three dimensions at reservoir scale, combined with validation of these algorithms using laboratory and field case studies.

Jun 1, 2012

By Masatsugu Morimitsu

This paper introduces new technology of oxygen evolution anodes which can be applied to produce copper, zinc, cobalt, and other metals by electrowinning. The anode consists of nano iridium oxide particles dispersed in amorphous tantalum oxide matrix as a catalytic layer formed on a titanium substrate. The anode can reduce oxygen evolution potential by 0.25 to 0.55 V compared to commercially available lead alloy anodes and can suppress unwanted side reactions such as manganese oxyhydroxide, lead oxide, cobalt oxyhydroxide which occur during oxygen evolution in the electrowinning solutions. This technology is effective for environmentally friendly electrowinning processes with low energy consumption and less anodic deposition.

Jan 1, 2011

By I. Spector, A. J. Smith

In 1967, BACM Industries Limited started producing walboard at Saskatchewan's first gypsum products plant, located in Saskatoon, using, as a basic raw material, gyp-sum rock supplied from the company's mine near Amaranth, Manitoba. This paper describes the geology of the Amaranth gypsum deposit, the method of mining the rock and the manufacturing facilities used to produce wall-board.

Jan 1, 1970

By D. Eriksen

Zero Emission Gas power, ZEG, is a novel concept where a high temperature solid oxide fuel cell (SOFC) is integrated with a reforming reactor producing hydrogen from natural gas through Sorption Enhanced Steam Methane Reforming (SESMR). The SOFC is used as a high temperature heat source for regeneration of the CO2-absorbent. Moreover, by using part of the produced hydrogen as fuel for the SOFC, the waste heat of the process is considerably reduced. Thus, the process has a very high thermal efficiency and produces both electricity and hydrogen from natural gas. In addition, a stream of pure CO2 is produced in the regeneration step and can be deposited or used commercially. Initial cost estimates indicate a cost of electricity and a cost of hydrogen well below today's prices. A small (1kWel + 1kW H2) demonstration set-up is under construction and experimental results and related research will be presented. This set-up comprises one 2.5kWth H2 SESMR-reactor (about 0.85 Nm3/h H2) operating batchwise with dolomite as the CO2-sorbent. The reactor developed is designed like a parallel plate heat exchanger where the mixture of sorbent and reforming catalyst is packed between the heat exchanging plates. The demonstration set-up includes a 1kW SOFC operating in a continuous mode. The set¬up will therefore demonstrate continuous simultaneous hydrogen- and electricity production, but cannot demonstrate simultanuous electricity- and CO2-production. The set?up is well equipped for on-line monitoring of gas composition, flows and temperatures. This important part of the demonstration set-up is developed and provided by Christian Michelsen Research (CMR). A minor part of the project is the development of a continuous circulating fluidized bed SESMR-reactor system and in another related project the focus is on the development of more suitable sorbents. In these two projects co-operation with University of British Columbia and Lousianna State University, respectively, is highly appreciated.

Jan 1, 2005

By Niraj Bala

Boiler tubes of coal-fired boilers suffer severe erosion-corrosion (E-C). One method to counteract this problem is by the use of therma, spray protective coatings. Cold spray coating process was used to deposit Ni-20Cr powder on SA 516 (Grade 70) boiler steel. The bare as wel, as the coated steels were subjected to cyclic experimenta, studies, in the superheater zone of a coa, fired boiler. The weight change technique was used to establish kinetics of the erosion-corrosion. XRD, FE-SEM/EDS and X-ray mapping techniques were used to analyse the as-sprayed and corroded specimens.

Jan 1, 2010

By M. Tanaka, T. Oishi, K. Koyama, S. Alam

"A novel hydrometallurgical process for copper recovery from waste printed circuit boards has been proposed, which consists of selective leaching of copper metal as Cu(I) by Cu(II) in ammoniacal alkaline solution, purification, and electrowinning. The distinct feature of this process is much lower power consumption during the electrowinning than that during the conventional one from acidic copper sulfate media, because the deposition of copper metal from Cu(I) at the cathode and the oxidation of Cu(I) to Cu(II) at the anode take place in the present method. In the laboratory-scale tests using waste printed circuit boards, high purity copper which contains 1.1ppm of impurities was obtained in a chloride system. INTRODUCTIONThe recovery of various metals from waste materials is an important issue in order to conserve the environment and metal resources. Copper is used for cables, electric appliances, etc., and is currently a very important material for industries and will continue to be in the future. Among the wastes that contain copper, one of the most complex recycling materials is electronic scrap like printed circuit boards (PCB), which generally contain 10-30% copper as well as plastics, fibreglass and other metals. There are two ways to recover copper, either pyrometallurgical or hydrometallurgical. Hydrometallurgical treatments generally have more flexibilities in the process scale and control. The separation processes tend to become complicated because of the poor selectivity during the leaching in the sulphuric and hydrochloric acid media. On the other hand, the use of ammonia as a complexing agent, gave a higher selectivity for copper leaching (Nigo, Majima, Hirato, Awakura, & Iwai, 1993; Majima, Nigo, Hirato, Awakura, & Iwai, 1993; Zhou, Shinme, & Anezaki, 1995; Koyama, Tanaka, & Lee, 2006) .In this study, recycling process containing leaching, copper deposition at a cathode and oxidation of copper(I) at an anode from ammoniacal alkaline solutions containing Cu(I) or Cu(II) is introduced. Furthermore, copper recovery from a waste printed circuit boards and impurity behaviour was examined in ammonia-ammonium sulfate (sulfate system) and ammonia-ammonium chloride (chloride system) systems."

Jan 1, 2012

By T. Mulja, Michel Boily, Anthony E. Williams-Jones, Pierre Pilote

"The Preissac-Lacorne batholith is composed of suites of early metaluminous calc-alkalic gabbroic to granodioritic intrusives, three late peraluminous monzogranite plutons and numerous Li, Be and Ta-bearing granitic pegmatites. The Lacorne pluton is dominated by biotite and biotite + muscovite monzogranites containing abundant Be and Ta-bearing granitic pegmatites (40-80% volume). The pluton is surrounded by swarms of unzoned or poorly zoned spodumene-rich pegmatite dykes. The La Motte pluton is composed of biotite monzogranites, biotite+ muscovite monzogranites and rare muscovite + garnet monzogranites. Li, Be and Ta-bearing pegmatites are less abundant than in the Lacorne pluton and are commonly associated with molybdenite bearing quartz-muscovite-K-feldspar veins. In the Preissac pluton, muscovite + garnet monzogranites and muscovite + biotite + garnet monzogranites are the dominant rock types. The pluton rarely contains granitic pegmatites and these are generally barren. However, numerous molybdenite bearing quartz and quartz-feldspar-muscovite hydrothermal veins are observed.Li, Be andTa-bearing pegmatites display a crude spatial zonation around their parent monzogranites. Spodumene-rich pegmatites are generally unzoned or poorly zoned and are confined to the surrounding metasedimentary or metavolcanic rocks or crop out in the early gabbroic to granodioritic intrusives surrounding the monzogranites. Ta and Be-bearing pegmatites are usually concentrated towards the margins of their parent monzogranites. The highly fractionated nature ofmonzogranites (high Rb/Sr, low K?Rb, Ba?Sr, Zr/Nb ... ), their peraluminous composition (corundum normative and muscovite bearing) and the numerous occurrences of Ta and Be-bearing pegmatite dykes represent important criteria for the exploration of fertile granites."

Jan 1, 1990

By W. R. Tyson

Pipelines for the transport of gas and oil are being designed to operate at increasing pressures in increasingly harsh environments. The steel used to construct these pipelines must have adequate toughness to tolerate weld imperfections (i.e. withstand bending strains) and to arrest running cracks (i.e. to prevent propagation of axial fractures). The problems posed in specifying suitable toughness parameters and the approaches currently being used to measure them are discussed.

Jan 1, 2005

By B. A. McKee, T. Adamcewicz

For a capital expenditure of only $46,000, Caland Ore Company has successfully converted its three dry grinding center peripheral discharge rod mills to dry grinding ball mills. The conversion has resulted in a significant capacity increase, operating cost reductions and in-plant environmental improvements. This paper describes why and how• the conversion was made.

Jan 1, 1972

By Marc Piard

In a cool mine, tapping high-pressure lines through reducing valves lowers the temperature beyond remedy. It is the writer's suggestion that, for low-pressure work, law-pressure air ,should be generated in a compressor installed underground adjacent to the work, and that the jacket-water of the compressor should be utilised for re-heating purposes. Such a system of compressed air distribution, designed especially for service in cool mines, is described in the following notes. The suggested system includes a three-wire pole line from the sub-station to the opening nearest to the working face, with a cable connection extending to the latter from the openings; an electrical centrifugal unit; a reservoir excavated in the ground; and a distribution line, re-heated by jacket-water. As regards the reservoir, it may be pointed out that in many mines there are blind or abandoned tunnels that could be used for the purpose. The centrifugal type of compressed air machine is a comparatively new departure, and it was formerly considered that such a machine, operating at less than 1,000 kilowatts per unit, would be commercially impracticable. At the present time, however, these machines are being built in Europe for as little as 400 kilowatts per unit, and as much as 110 lb. per sq. inch pressure. One advantage which these centrifugal machines have over other types is that they may be driven by plain induction motors, without the help of special starters-a consideration of the first importance where the electrical regulations are severe.

Jan 1, 1926

By Chas. L. Emery

"The laws of rock mechanics apply equally well to all rock structures, and open pits are not exceptions. The concepts and some arguments about the emphasis to be placed on various aspects of open-pit design are discussed in this article.RocksROCK can be described as a granular material consisting of grains and glue. The grains may be fragments of other rocks or polycrystalline aggregates. The glue may be ferruginous, calcareous, argillaceous, siliceous or other material connecting the grains. In a crystal intergrowth, the outer layers of the crystals in contact with each other may be considered to act as a glue. Water may be a glue in clay or a grain in a crystal structure. Air and other fluids or gases are grains if they occupy spaces in a granular mass. Such grains are functional either chemically or mechanically or both."

Jan 1, 1966

By W. S. Dyer

Introduction In northern Ontario, refractory clay is found on four rivers of the James Bay watershed: the Abitibi, the Mattagami, the Missinaibi, and the Moose. The clay all belongs to the same geological formation ( the Mattagami of Lower Cretaceous age) , and occurs within a structural depression or 'basin', the boundaries of which have never been defined but which appears to cover at least 1,500 square miles of territory. The recently constructed James Bay extension of the Temiskaming and Northern Ontario railway crosses the northeast end of the basin at the Onakawana lignite field, which by rail is 126 miles north of Cochrane, 605 miles north of Toronto, and 60 miles southwest of Moose Factory. Smoky Falls, the northern terminus of the railway owned by the Spruce Falls Power & Paper Company, Limited, is 7 miles south of one other point in the basin, i.e., the outcrops of refractory clay, sand, and kaolin at the foot of Long rapids on the Mattagami river. Smoky Falls is 50 miles north of Kapuskasing. In a very early report(l) , Dr. Robert Bell, of the Geological Survey of Canada, described '"light coloured marl in horizontal beds" from the Missinaibi river, and noted that the lignite also occurring in the river was probably :associated with the marls. This was undoubtedly the Cretaceous refractory day. Other early writers noted the occurrence of fire-clays, but it was not until Joseph Keele(2), of the Geological Survey, visited thee region in 1919 and studied the clays that their real significance was known.

Jan 1, 1933