Search Documents

By R. O. Burt

"Gravity Concentration, the oldest form of Mineral Processing, remains of major importance to the Industry. Current applications of Gravity Concentration are briefly examined.The Paper details one approach to the development of a Gravity Concentration Plant, from laboratory and mineralogical techniques, through Pilot Plant testing, where applicable, to the actual design of the plant.INTRODUCTIONGravity Concentration, once the major method of concentrating minerals has, for much of the twentieth century been regarded, like the dodo bird, as obsolete. However, in more recent years it is enjoying something of a renaissance, and is once again being treated as a useful, economic alternative in the Mineral Processing Engineers' arsenal.An indication of the broad application of gravity concentration is the variety of minerals presently recovered. A list is given in Table 1; this list is not exhaustive."

Jan 1, 1984

By K. Ihara, T. Yamaguchi, K. Matsumoto

"Al-Fe alloy sheets having layers with different strain components were produced by unlubricated hot rolling and the recrystallization texture formation during annealing was investigated in each layer. In this study, the strain component introduced by rolling was quantitatively evaluated by measuring degree of bending of an aluminum pin embedded in the sheet. The textures before and after annealing were investigated by the SEM-EBSD technique. It was clarified that, in the middle layer, where comparatively small shear strain was introduced, ß-fiber subgrains and cube {001}<100> oriented subgrains were formed before annealing, and cube oriented recrystallized grains grew after annealing. On the other hand, in the surface layer, where large additional shear strain was introduced, shear texture components and cube oriented subgrains were formed before annealing, and shear texture was retained even after annealing, while cube oriented subgrains did not grow and were encroached. It was suggested that introduced strain components influenced the recrystallization texture formation by inducing different distribution of the subgrain size, stored strain energy and orientation relationship with surroundings before annealing.INTRODUCTION The microstructure developed during the hot-rolling process of aluminum and aluminum alloys affect the mechanical properties of the final product sheets. Especially, the crystallographic orientation in the final product sheets affects the r- value and ears during deep drawing (Humphreys & Hatherly, 2004), then the texture control in the hot-rolling process is important. When the friction between the rolling roll and rolled sheet in the hot-rolling is large, both the rolling texture and recrystallization texture tend to be heterogeneous in the thickness direction. It is known in many rolled aluminum alloy sheets that the texture in the surface layer was different from that in the middle layer because of additional shear strain. It was reported that in the vicinity of the surface layer, where large additional shear strain was introduced, the shear texture <1 1 1>//ND and < 1 1 0> // RD which contain components of {1 1 1} <1 1 0> and {0 0 1} <1 1 0> developed during rolling, and the shear texture developed even after recrystallization annealing (Sakai et al., 2002). Particularly, it is thought that the <1 1 1> // ND texture contributes to improve the r-value and press formability (Inoue & Takasugi, 2007). Therefore, asymmetrical rolling and high friction rolling have been applied to improve formability of aluminum alloys by adding shear strain in the rolled sheets as deep as possible (Kamijo et al., 1972; Inoue et al., 2005). However, few researches have been focused on the microstructures and texture before annealing and thus, the detailed mechanism is still unclear how the texture after annealing is affected by the texture before annealing. In this study, the Al-Fe alloy of commercially pure aluminum was chosen as the first material to be studied in order to clarify the fundamental process of the recrystallization texture formation. The main purpose of this study is to clarify the effect of additional shear strain on the rolling and recrystallization textures in the hot-rolled sheets by analyzing the transition of microstructure and orientation distribution through recrystallization annealing."

Jan 1, 2018

By Bryn Harris, Liming Huang, Andre Laplante

"This paper reviews flowsheets generally used in gold rooms to upgrade primary gravity concentrates particularly those of Knelsons. It is concluded that even for small operations, which treat between 250 and lo00 kg of concentrates per day, there is a strong economic incentive to include in the flowsheet magnetic removal of tramp iron, at least two shaking tables, screening of either table feed or table tails at 150-212 um, and scavenging of table tails with a small centrifuge. Headroom, rather than floor space, is often inadequate in most gold room designs, and limits gravity flow and flowsheet flexibility. Experimental data are presented to demonstrate the effectiveness of a small Knelson Concentrator to scavenge significant amounts of gold (up to 91 %) from fine table tails.RésuméCet article examine les schémas d’évolution généralement utilisés pour traiter les concentres gravimétriques d‘or, en particulier ceux produits par concentrateur Knelson. Nous en venons à la conclusion que même pour un petit circuit d’une capacité de 250 A 1000 kg/jour pourrait bénéficier des opérations unitaires suivantes : concentrateur magnétique pour extraire la feraille, au moins deux tables A secousses, criblage de l’alimentation ou du rejet d’une ou des tables i une maille de 150-212 um, et épuisages des rejets fins de table avec un centrifuge de petite capacité. C’est l’espace vertical du lieu où se fait cette concentration qui représente la contrainte la plus importante, plutôt que sa surface, puisqu’il faut maximiser l’écoulement par gravite des pulpes et s’offrir une certaine flexibilité quant à l’agencement final des opérations unitaires. Nous présentons également des données expérimentales pour démontrer l’efficacit6 d‘un Knelson de laboratoire pour récupérer jusqu’ à 91 % de l’or contenu dans les rejets fins de table."

Jan 1, 1999

By H. W. King

"Cryogenic engineering is concerned with components and machines which operate for long periods of time at temperatures within a few degrees of absolute zero. The absence of a ductile-brittle transition is thus the prime component of the specification for a suitable low-temperature alloy. The word "" cryo"" means ""frost-forming"" , and this leads to the second component of the alloy specification, which is resistance to corrosion in humid atmospheres. Further, although most early applications of low-temperature alloys were limited to the storage or transportation of liquified gases, an increasing proportion of alternative energy storage and conversion technologies are being based on the availability of high-field superconducting solenoids. The third basic component of the specification for a low-temperature alloy is thus the absence of a low-temperature ferromagnetic transition.Although the firs t two of these components of the specification can be met by using austenitic stainless steels, many of these supposedly "" non-magnetic"" alloys have been found to undergo martensitic transformations to ferromagnetic phases at very low temperatures. In addition, steels which remain structurally stable may still exhibit other magnetic transitions, e.g. to antiferromagnetic or superparamagnetic states. The successful application of these alloys in cryogenic engineering has thus required an initial basic study of the types of magnetic transition that can occur in such concentrated solid solutions, followed by a more applied study directed at an alloy formulation which will induce beneficial magnetic states at low temperatures."

Jan 1, 1981

By C. J. Farrow, M. J. Smith

"Bechtel has managed a number of test programs to establish autogenous grinding circuits and size mills for a variety of ores.This paper outlines the procedures whereby bench scale and pilot plant tests are used to select the most efficient circuit to grind the range of ore types likely in the mill feed.Five examples are given. One example traces the development of a pilot plant program; it shows how bench scale Work Indices provide a target for the grinding power requirement of an ore and relates how pilot circuits are changed as a result of interpreting the results from preceding tests. The other four examples relate the interpretation of the test results to provide design data; they illustrate a number of phenomena which have been observed.INTRODUCTIONConventional crushing and grinding circuits can be specified from bench scale test data such as Bond Work Indices. Bond Indices have been correlated to a large number of rod and ball mills and by applying appropriate factors, mills can be sized from the Work Index.For autogenous or semi-autogenous grinding circuits, bench scale tests are not sufficient to be able to specify the circuit and size of the mills for a commercial plant. It is necessary to run a series of pilot plant tests to determine how the ore behaves."

Jan 1, 1982

By L. Kong, V. G. Papangelakis, L. Li

"The Eh-pH diagram of lithium-titanium-water system at 25°C, 100 °C and 200 °C was constructed. It shows that there exist thermodynamic stability areas of Li2TiO3. This indicates a thermodynamic possibility for the formation of Li2TiO3 in aqueous solution. A hydrothermal process has been applied for the preparation of Li2TiO3 using TiCl4 and LiOH•H2O as raw materials. The prepared samples were examined with X-ray diffraction, scanning electron microscopy and thermo-gravimetric analysis and differential scanning calorimetry. The results show that temperature and washing condition have significant effects on the phase composition of the product. Phase-pure Li2TiO3 powders were obtained at 200°C with Li:Ti molar ratio of 2.0.INTRODUCTIONLithium-containing ceramics enriched in 6Li, such as Li2O, LiAlO2, Li4SiO4, Li2ZrO3 and Li2TiO3, are considered as tritium breeding materials (Saito et al., 1998; Roux et al., 1998; Johnson et al., 1998; Hoshino et al., 2002). In view of its admirable properties: low-activation, good thermal stability and thermal conductivity, excellent tritium release performance and reasonable lithium atom density (Kopasz et al., 1994; Roux et al., 1996; Saito et al., 1998; Wu et al., 2008), Li2TiO3 is recognized as one of the most promising candidates of tritium breeding materials. Meanwhile, Li2TiO3, as the precursor of H2TiO3-type lithium absorbent, receives more attention as the development of extracting lithium from salt lakes (Zhong, 2004; Zhang, 2010).Several synthetic techniques have been applied to prepare Li2TiO3 powders, such as solid-state methods (Lulewicz and Roux, 2002; Ramaraghavulu et al., 2011; Mandal et al., 2012), sol-gel processes (Deptula et al., 2002; Lee, 2008) and solution combustion routes (Cruz et al., 2006; Jung et al., 2006; Sinha et al., 2010). A solid-state method may produce a series of problems, including impurity contamination and difficulty in morphology control of the obtained powders, although the process involved is simple. The solgel process is prolonged and usually demands for multi-step reactions, while solution combustion route requires plenty of energy and easily causes product contamination by the fuel used. Owing to its environmentally benign and highly suitable characteristics in fabricating materials, hydrothermal technology has been widely used and became a powerful tool in the field of material synthesis (Yoshimura and Byrappa, 2008). For example, ZnO in the form of bulk single crystals, fine particles and thin films, which is an attractive photoelectric material, was successfully synthesized by hydrothermal process (Sekiguchi et al., 2000; Ohshima et al., 2004). A hydrothermal technique was also used to the preparation of carbon nanotube, which possesses outstanding mechanical, structural and electric properties (Bernholc et al., 1997), and is superior to the commonly used method (Gogotsi and Libera, 2000). There, it provides an option for preparing Li2TiO3. Laumann et al. (Laumann et al., 2010) synthesized cubic a-Li2TiO3 by hydrothermal reaction at 180 °C for 18 h, using TiO2 powder, comprising of anatase and rutile, and lithium hydroxide in de-ionized water. However, the prepared a-Li2TiO3 is extremely unstable with a maximum lithium loss of 75% when treated in bathing experiment."

Jan 1, 2012

By Richard C. Banting

Excessive vibration is known to have an adverse affect on soft body tissue and operators of heavy mining equipment can be exposed to vibration that exceeds levels recommended in international guidelines (ISO 2631-1, for example). Research has found that many of the seat and suspension systems currently used in mine haul trucks and load haul dump vehicles are actually amplifying the vibration. This overview presentation will outline the current research being conducted at Laurentian University and the University of Western Ontario, and the roles of partners in rating the ability of a number of commonly used mine vehicle seats to isolate harmful vibration.

Oct 1, 2010

By Henrik Saxén, Mikko Helle, Hamid Ghanbari

In this study, a process integration approach in a primary steelmaking is investigated to evaluate future operation concepts of a steelmaking site considering sustainability issues. Mathematical programming is used to study the integration of the steel plant with chemical units for utilization of available off-gases in the system, and carbon capturing and sequestration unit. Different industrial carbon utilization options are considered to find the best route of development. A multi-period optimization model is developed based on site-wide mass and energy balances by considering the availability of the fuels and by-product gases and their consumption in the production system and a conceptual polygeneration system. The objective is to reach maximum economic profit while environmental aspects of integrated system are considered for different fuel systems, alternative blast furnace reductants and implementation of new process technologies. The model can provide useful information concerning techno-environmental and economic aspects for decision-making and can estimate optimal operational condition of current and future primary steelmaking under alternative scenarios. The results of the work illustrate the potential to develop steelmaking towards more sustainable operation in the future.

Jan 1, 2015

By L. Cifuentes, J. M. Casas

The treatment of aqueous CuSO4-H2SO4- As-Sb solutions by electrodialysis in order to separate and concentrate species of interest has recently been studied. Results show that it is possible to separate copper from arsenic in electrodialysis cells. The separation of copper from antimony is also possible. Transport rate ranges that could be achieved, depending on experimental conditions, are 0.2 to 0.6 mol per hour per square metre of membrane for copper, 0.65 to 2.8 for sulphate, and 0.016 to 0.03 for arsenic. Transport rates for antimony were inconclusive due to its very low solubility in the studied systems. Solution agitation and increasing temperature markedly increased the process rates. Advancements in this area require further work in both the thermodynamics (speciation) and kinetics of complex CuSO4- H2SO4-H2O systems, where impurities, other than As and Sb, and additives should be taken into account to gain a deeper understanding of the application of ED to copper electrorefining electrolytes

Jan 1, 2004

By Franco Oboni

Numerous voices are raising around the world to show how misleading and fuzzy commonly used risk assessments methods are. These criticisms come at a time when public trust in ?proponents of new projects?, operators, private or governmental, seems to have hit a low and the legal system ?targets? public officers. It is common that technical experts and the public strongly disagree in their analysis of risks. Risk definition requires the evaluation of probability and consequences and those words are oftentimes enough to stir great worry to the public. Thus it is nowadays commonly understood that ?reality? is not scientific, but resides in public opinion, hence urging technical people to communicate better, more transparently. Blatant failures on both counts have lead to the emergence of ?new myths? used to justify complacency using ?complexity? and other buzz words as an alibi. This paper (together with its companion presented elsewhere) explores how poor ?common practices? in Risk Assessment contribute to biasing project team, design teams opinions, skew decision-making process and finally misrepresent reality to the public resulting precisely in the raise of public distrust, legal implication witnessed around the world. The discussion first reviews the pitfalls of common approaches (FMEA, Probability Impact Graphs) pinpointing them as possible causes of future legal liabilities. An alarming disconnect also comes from various codes, ISO 31000 itself has this flaw, invoking the term ?acceptable?/?tolerable? without defining it or giving any guidance for its determination. Wide-spectrum public consultation could be developed to define a ?modern? social acceptability criteria helping all the stakeholders making/understanding decisions. Another alarming disconnect comes from the poor definition of consequences of mishaps and their societal ripple effects. This aspect is indeed mostly ignored in codes, leaving ample room to biases and censoring applied to potential losses. In our society no one seems to have anymore the possibility of hiding behind a shroud of ?carefully maintained? misrepresentation. It is time to act and ?write the book? for proper risk assessments avoiding misrepresentations.

May 1, 2013

By Christoph Mueller

Mining operations today are characterized by a high degree of mechanization and single machine automation. However, their potential for cost cuttings and increase of productivity in the future is quite limited. Enabled by newest IT and networking technology, the operation of underground mines more and more can be seen from a process related point of view: Standardized Ethernet and Wireless LAN are the basis for a seamless and unified communication backbones providing an integrated infrastructure for data, telephony and video. All the components are available as off-the-shelf devices leading to an excellent cost efficiency. Basing on this standardized infrastructure, the equipment is able to become part of the infrastructure. To enable machines to be integrated smoothly into IT networks, the machine also has to have enhanced networking capabilities. This results in a new system architecture for the on board machine electronics separating real time control from IT and networking level functionality which can be implemented by a Machine Server. This machine server communicates with all kinds of above ground systems using mainly standardized formats like html or the IREDES standard. This information is made available mainly in 3D mine visualization tools. The paper explains this technology and shows implementations by two working examples.

May 1, 2006

By L. Hacini, N. Van L ê, P. Bacher, D. Thibault

Manufacturer welded components may suffer from high level of residual stresses which can cause premature cracking and decrease the life of the components if they reach values close to the yield strength of the material. In the present work, a robotized hammer peening technique is simulated by an impact machine and the residual stresses generated by the indentation are measured. To better understand phenomena behind residual stresses relaxation by hammer peening, the impact energy level was changed. 304L steel plates were hammer peened with 10 impacts. The contact between the hammer and sample surface was always at the same location. The strains on the surface close to the impact location were recorded during the test using strain gauges to follow residual stresses variations. At the end of the test residual stresses were measured indepth using hole drilling technique at 8mm from the impact center. The micro-hardness was monitored to evaluate the affected zone by the hammer peening. This approach gave a good estimation of the energy and number of blows to be used for efficient relaxation of the manufactured parts.

Jan 1, 2006

By H. Wotruba, K. Neubert

Dual-energy X-ray transmission (DE-XRT) imaging is known from safety luggage inspections at airports. The use of DE-XRT technology for sorting applications in the primary raw materials industry has been the subject of numerous investigations. Beside other metal ores, X-ray transmission sorting is already used for the preconcentration of tungsten ore, gold ore and coal. The applicability of DE-XRT sorting is limited to ore types where differences in metal concentrations are measurable, based on an interpretation of X-ray images. Metal contents in particles occur in large varieties in terms of concentration, grain sizes, spatial distribution and mineralogy and therefore influence the X-ray absorption. As a result, each ore has to be tested individually for its suitability for DE-XRT sorting. The objective of current research at the Department of Mineral Processing (AMR) at RWTH Aachen University is to assess parameters influencing the detectability of rare earth oxides. Two approaches were followed: (1) Practical test work, based on artificial ore samples of defined compositions and (2) Computer-based simulation of absorption features of identical particle compositions. In total, more than 300 artificial samples of various compositions and metal grades were produced and X-ray images from DE-XRT sorting were analyzed. Results from the DE-XRT sensor were put into correlation with metal grades and particle sizes, to analyze influences and limits on the detectability of rare earth oxides. In addition, a new approach was tested in which the X-ray absorption of particles of various compositions was determined based on a Monte Carlo (MCNP) simulation. During the simulation, similar compositions, as used for the artificial samples, were tested and the X-ray absorption behavior during DE-XRT sorting was determined. A comparison of results from both approaches is used to assess the applicability of the MCNP-simulation for the prediction of the X-ray attenuation behavior during DE-XRT sorting.

Jan 1, 2016

By Manqiu Xu, Pete Winn, Steve Wilson

"In the flotation of ultramafic ores at Thompson mill, Inco Limited, CMC is used as both a floatable rock depressant and electrostatic serpentine slime dispersant. CMC, being a high molecular weight polymer, creates a serious handling problem in its introduction into the flotation processes. Typically, it is added as a 1-3% solution. This requires an enormous handling facility and makes its metallurgical gains uneconomical.Laboratory studies have shown that dry CMC addition as opposed to wet addition is feasible, as long as sufficient conditioning time is provided. Dry CMC addition into the grinding mill is also possible but its effectiveness is slightly reduced as compared to dry addition after grinding mills. Dry CMC addition using a vibratory feeder into the mill discharge is successfully applied in the treatment of ultramafic ores at Thompson mill.INTRODUCTIONManitoba Division MineralogyAt Inco’s Manitoba Division, two distinctly different sulphide ores are processed at the Thompson mill - primarily by froth flotation. The Thompson and Birchtree mines are both located within the Thompson Nickel belt. Sulphide mineralogy is relatively simple and includes both hexagonal and monoclinic pyrrhotite, pentlandite and minor chalcopyrite hosted in metasedimentary and metavolcanic rocks. The significant difference between the two mines is the amount of ultramafic rock associations in the host material. Increasingly, more of the ultramafic associated ores from the Birchtree mine are being processed through the mill with a characteristic poor metallurgy."

Jan 1, 2000

By Raja V. Ramani, Sukumar Bandopadhyay

"The dispersion of diesel contaminants into the mine atmosphere is a variant of general class of diffusion-dilution problems relevant to underground mining practice. The equipment operations in underground mining are characterized by different activities with different time duration s, i.e. varying duty cycles. Therefore the volume and quality of diesel emissions and consequently, instantaneous concentrations are quite variable. Design of mine ventilation systems under these conditions becomes complex. In this paper, the development and use of mathematical models of mine production system, the engine exhaust air quality and engine exhaust transport in the design of ventilation system are discussed.IntroductionThe turbulent diffusion of suspended matter in an atmosphere is not only a topic of considerable intrinsic interest to the mathematical physicist and meteorologist, but also a problem of great practical interest. Release of particulate matter into the atmosphere at large has created o ne of the acute problems of the present day. Pollution of environment by industrial and domestic smoke, fumes and grit is widespread and has necessitated extensive studies in order to determine the concentration and distribution of pollutants in various areas. Pollutants discharge from stacks, whether chemical or radioactive, give rise to similar, but more localized, problems. The laws which govern turbulent diffusion in the atmosphere are also applicable to the study of the diffusion of toxic gases and the deposition of radioactive dust from nuclear explosion.The dispersion of diesel contaminants into the mine atmosphere is but a variant of a general class of diffusion-dilution problems relevant to underground mining practice. Most of the mine air pollutants, such as respirable dust, methane, diesel exhaust, and blasting fumes are produced in the face areas and haulage ways. Understanding of their dispersion in the mine airways is important to calculate their concentrations. In this paper, the development and use of mathematical models of mine production system, the engine exhaust air quality and engine exhaust transport are discussed. The over-all objective of this research effort is to evaluate the impacts of dieselization on production and ventilation systems and to aid in mine planning and design, as shown in the flow model in Figure I."

Jan 1, 1983

By W. Dziurzynski, St. Wasilewski, T. Palka, A. Krach

"Air parameter monitoring systems, regardless of gasometrical protections, provide a significant number of measurement data. The obtained data broadens the knowledge on processes taking place in underground workings and shows the relationships and influence of machines and technological processes on the variability of ventilation parameters in the areas of longwalls. Nowadays, computer simulation methods are increasingly used to reproduce the flow of air and methane mixture in the area of longwalls equipped with shearers. The paper presents the results of a research experiment covering a long-term observation of a longwall area during mining with a shearer using sensors from the mine's monitoring system. Data from sensors for methane concentration, pressure and velocity were used and additional ventilation measurements were taken to determine the parameters characterising the air flow in the area. The influence of different machine cycles in the longwall on the changes of air parameters in the area of the longwall was shown. A numerical model of the ventilation area was developed and the computer program VentZroby was used for the calculations, which allows for the simulation of the process of ventilating the area of the active longwall during the extraction of coal with the use of a shearer and haulage of the run-of-mine. Computer simulation of the influence of the shearer's operation and the methane inflow associated with the distribution of the mixture of air and methane was carried out. The results of the simulation were compared with the data recorded by the monitoring system’s sensors during the measurement experiment. Comparison of the recorded methane concentration courses with the results of a computer simulation of the air and methane flow conditions in the mining area showed changes in the gassiness. INTRODUCTION Studies carried out in the Polish and global mining industry show that methane is an obvious factor in limiting mining production due to the loss of continuity in the operation of longwall complexes in hard coal mines under methane emission hazard (Schatzel et al., 2008). In addition, methane hazards have a significant impact on the safety of the operators of machinery in the longwall. The requirements of Polish regulations and the practice of safe operation of mining longwalls require correct determination of gas concentration, volume flow, as well as pressure and temperature of the flowing air. As part of the research undertaken in the Budryk (Wasilewski, 2010) and Bielszowice (Dziurzynski et al., 2009) mines to assess the methane hazard in the longwalls and workings in the vicinity of the longwall, research experiments were carried out, during which air parameters were recorded by the mine monitoring system and additional testing equipment in different cycles of shearer operation."

Jan 1, 2019

By R. Biss

"Niobium or columbium, as usually called in North America is becoming a more and more important metal in the industrial world because of its attractive properties.Eventhough discovered in the early nineteenth century, it was not until the 1930's that its use became more widespread. The discovery of large commercial deposits in the late 1950's and the demand of industry for steel with high strength and toughness further promoted its use. To assure its adequate supply new or-e processinr technologies had to be developed. So, beside the traditional gravity concentration, the flotation process was employed for the partial upgrading of pyrochlore concentrate at S8ve (Norway) plant in 1953. The flotation process was equally used at St-Lawrence Columbium plant in the province of Quebec, Canada. The new plants at Araxa and Catalao in Brazil and at St-Honore, Canada, which supply almost of all niobium used today in the non-Communist world, also adopted the flotation process. The processes using long chain aliphatic rnonoarnines, diamines or sulfonates as collectors proved to be difficult especially on weathered types of ores or on those having a substantial content of silicate gangue minerals. They almost completely failed in case of alkaline intrusive rocks as syenites, nepheline syenite, ijolites and pyroxenites, composed almost entirely of silicate minerals. A lot of effort was devoted all around the world on research of new, more efficient flotation processes. So in 1982, Les Services T.M.G. Inc. (Niobec), sole producer of pyrochlore concentrate in North America, developed the direct pyrochlore flotation process from carbonatites. In 1983, at about the same time, the Quebec Department of Natural Resources Laboratories and Les Services T.M.G. Inc. announced a successful recovery of niobium Minera1s from a low grade nenheline syenite ore."

Jan 1, 1984

By M. S. Moats

"The effects of commercial copper electrorefining additives (glue and thiourea) on the electrochemical removal of bismuth are of importance in copper production. It was found that Bi(III) electrodeposition occurs readily from acidic sulfate solution via a diffusion-controlled quasi-reversible reduction. The diffusion coefficient of Bi(III) was measured and found to be less than reported values of copper in similar solutions. The presence of thiourea and/or glue was found to accelerate or de-polarize Bi(III) reduction on stainless steel as compared to the inhibition or polarization of Cu(II) reduction. The additives also inhibited the dissolution of the Bi-Cu co-deposit during cyclic voltammetry. During short term deposition studies, the additives increased the concentration of Bi in co-deposited Cu-Bi products from solutions with low concentrations of Cu (<2 g/L). Bi deposition was significantly suppressed by increasing the Cu(II) concentration in the solution. The formation of a copper layer on the stainless steel electrode appeared to significantly suppress the reduction of Bi(III). This study demonstrates that glue and thiourea depolarize the deposition of bismuth on stainless steel. Therefore, the additives could be used to improve Bi impurity removal during third stage liberation.INTRODUCTIONThe production of high purity copper has been steadily increasing due to the wide application of the metal and its alloys in electrical and electronic products, infrastructure construction, industrial machinery and equipment, general products and transportation (Moskalyk et al., 2003). Most high purity copper is manufactured from copper sulfide mineral concentrates and/or scrap via a pyrometallurgical process followed by electrorefining (Navarro et al., 1999). During the electrorefining process, cast anodes of 99-99.5% purity are electrochemically dissolved into an acidified copper sulfate solution while high purity copper (>99.99%) is plated on stainless steel blanks or copper starter sheets (Davenport et al., 2002). The control of cathode deposit growth (purity and morphology) while maintaining a high current efficiency is of significant importance for copper refining (Ilkhchi et al., 2007). At typically applied current densities for industrial copper electrorefining, mass and charge transfer play important roles in the quality of cathodic products (Hiskey et al., 1998). If the real current density at some surface points is substantially higher owing to uneven current distribution, then rough spots can and will grow faster leading to nodules (Suarez et al., 1992). Nodulated deposits tend to capture solution and anode impurities (slimes) resulting in unacceptable cathode quality (Afifi et al., 1987). Furthermore, these nodules can grow until they eventually contact the anode leading to short circuits and current efficiency reduction (Ilkhchi et al. 2007)."

Jan 1, 2016

By Corby G. Anderson

"Laboratory testing using industrial electrowinning solutions was performed to determine the best Faradic cell efficiency for copper cathode recovery. The variables tested were solution flow rate, recycle ratio, reagent addition combinations of guar and thiourea, and addition amount of acid mist suppressant CAL FAX DBA-70. The ideal flow rate was determined to be 37.85 litre/min. Additionally, the ideal recycle ratio was determined to be 10:1. The reagent addition scheme from testing which showed the highest efficiency was with 680 g/tonne guar of cathode copper won and with 135 g/tonne thiourea of cathode copper won. These values for reagent addition only reflect the best efficiency and should not be assumed to be the best reagent concentration for copper purity. The amount of foaming agent that showed the best efficiency was the test with 2 ppm of foaming agent. Again this amount of reagent is based on efficiency and should not be taken as the amount of reagent that does the best acid mist suppression. Additional proprietary surface characterization work indicates these additives may have enhanced the cathodic reduction surface morphology of some noble minor impurities. Subsequently, these operating parameters were introduced into the plant operation and proved successful after their implementation.BACKGROUNDCopper electrowinning has become a dominant technology for the production of marketable high grade copper cathode products. The literature is robust with applications, optimizations, additives and developments in this field (e.g., Classens & Harris, 1990; Pfalzgraff, 1999; Tozawa, Su, & Umetsu, 2003; San Martin, Otero, & Cruz, 2005; Houlachi, Edwards, & Robinson, 2007; Romero, Avila, Fester, & Yacher, 2007; Marsden, 2008; Beukes & Badenhorst, 2009; Vainio & Weatherseed 2009; Bender, 2010; Joy, Staley, Moats, Perkins, Uhrie, & Robinson, 2010; Khouraibchia & Moats, 2010; Moats, 2010; Rutledge & Anderson, 2015).Tests of forty hours duration and at room temperature were performed for this project using samples of actual industrial electrowinning solutions. These industrial solutions were comprised of 60 g/L Cu plus 65 g/L Ni, 3 g/L Fe, and 30 g/L free sulfuric acid. Other confidential minor impurities were also present including some solubilized precious metals. The testing apparatus utilizing stainless steel anodes and cathodes is illustrated in Figures 1 and 2."

Jan 1, 2016

By Philip M. J. Gray

"The real cost of conversion from ore to semi-fabricated non-ferrous metals has been increasing for many years. Consumer resistance and improved knowledge and techniques now available justify investment in revolutionary as well as evolutionary methods of extraction. Metallurgical factors in current practice which preordain high production costs are identified as: smelters&apos; demand for clean minerals, use of processes with low intensity of working per unit of reactor volume, use of low-velocity reactions, use of long reactor retention times relative to the speed of reactions, dilution of values in solution and commitment to electric power as a source of energy.Six new types of flowsheet are proposed for processing from ore to metal, composed of steps which are economic to construct and maintain and making maximum direct use of fossil fuel and the energy content of minerals. The basic knowledge and technology for developing these flowsheets exists. It is very tentatively suggested that these routes might reduce the capital and production cost for conversion of ore to metal by 30-50%."

Jan 1, 1980