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By M. L. F. Gameiro

The aim of this study was to check the feasibility of non-dispersive solvent extraction to recover copper from ammoniacal solutions using hollow fibres as contactors. Data of mass transfer using the B3-diketone LIX 54 as extractant was obtained. The influence of tube and shell hydrodynamics on the extraction rate of copper was studied. The overall mass transfer coefficient of copper was calculated from the experimental data by performing steady state material balance. Simultaneous extraction and stripping experiments were carried out using different volume ratios of feed phase to stripping phase. The results obtained showed that practically all the copper content was removed from the ammoniacal feed solutions. The recovery of copper reached nearly 100% in several extraction-stripping experiments.

Jan 1, 2007

By T. R. Yu, D. B. Counter

"Kidd Creek Mines primarily employs sublevel blasthole stoping for underground mining operations. During pillar recovery in No.1 Mine and panel mining in No.2 Mine, the free standing fill exposures may reach a height of 100 m or more. Consequently, a competent consolidated rockfill has been required to fill the mined openings.Since 1976, a total of more than fifty stopes and pillars have been filled with over four million tonnes of backfill. Fill exposures, up to heights of 100 m, have stood up well after blasting adjacent to the backfill.The fill material consists of a graded aggregate, Portland cement and ground slag. Sand has been occasionally mixed in the fill material to serve as avoid filler. The aggregate is prepared in a fill crushing plant, transported underground through raises, and hauled to the filling stopes by conveyors in No. 1 Mine and by trucks in No.2 Mine.Two mixing methods are currently in use. No. I Mine utilizes the free fall of gravity; the fill materials are sprayed with cement slurry as the aggregate departs from the conveyor into a mixing culvert. The other is the use of a rotary mixer on a batch basis in No. 2 Mine.This paper describes the fill systems, filling operation s, and the backfill quality control practice, together with various testing results related to improving fill quality as well as reducing fill costs.IntroductionThe Kidd Creek minesite, located 27 km north o f the city centre of Timmins, Ontario, produces 4.5 million tonnes of copper, zinc, lead, and silver ores annually from its No. 1 and No.2 underground mining operations. Both mines employ a sublevel blasthole stoping method."

Jan 1, 1983

By T. Lux, H. -J. Krassnig, I. Filzwieser, E. Hecker, R. Degel, A. Filzwieser

Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions for the primary copper production lines as well as for non-ferrous metals starting with the primary smelting of concentrate and ending with the electrolysis. PolyMet Solutions provides the process know-how whereas SMS group supplies the plants and equipment and Mettop the key components. SMS group and Mettop also cooperate in the field of tankhouse technology. Together with Montanwerke Brixlegg AG, Mettop has developed together with a parallel flow technology (METTOP-BRX Technology), allowing a current efficiency of above 98 % at a current density of 420 A/m², which is a milestone in copper electrolysis. For the secondary copper production route, SMS group and PolyMet Solutions developed an innovative refining furnace (PolyRefine) for the smelting and refining of copper scrap. The refined copper is directly charged to the Contirod line to produce copper rods and wires. The innovative cooling solutions of SMS and PolyMet Solutions come into play where furnaces have to stand the highest loads and stresses, for instance in areas of very high temperatures or temperature fluctuations, aggressive exhaust gases and slags, or at critical spots such as taphole areas. Custom-tailored cooling systems for furnace vessels make sure varying loads are compensated in a targeted and effective manner. The solutions include air cooling, spray cooling, cooling technologies with integrated copper elements such as CFM (Composite Furnace Modular) cooling systems, plate and finger coolers. The major innovation in the field of furnace cooling is the ILTEC (Ionic Liquid Cooling) Technology which paves the way for increased plant safety. This revolutionary, patented cooling technology is jointly marketed by Mettop and SMS group. It permits water-free cooling to be implemented and thus makes operation safe wherever it is applied. INTRODUCTION Non-ferrous metals or NF metals are changing the world. There is no modern industrial sector that can do without these valuable metals. Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. The importance of the non-ferrous metals market is reflected by two figures. In 2018, the production of non-ferrous metals was worth more than 237 billion Euros. This contrasts with 255 billion Euros of the value of iron and ferro- alloy production in the same year (International Organizing Comittee for the World Mining Congresses, 2018). Hence, the NF metal industry is almost as important as the iron and steel industry. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions and to enhance customer value. The prices of nearly all metals have come under pressure during the past few years. Therefore, competitive technologies are regarded a crucial factor to achieve success in this critical market situation respectively to stabilize the market position.

Jan 1, 2019

By A. Tikhonov, D. Kipper, V. Korovin, A. Olifirenko, Yu. Shestak

The present paper deals with vanadium and molybdenum sorption from industrial wastes and intermediate processing products using Cybber macroporous strong- and weak-base anionites. Vanadium and molybdenum recovery by Cybber anion-exchange resins as well as desorption processes were studied in static and dynamic modes; their efficiency was demonstrated for that purpose. The results of the work may be used to design technologies for complex processing of both ores and industrial wastes containing vanadium and molybdenum.

Jan 1, 2011

By T. G. Carter

"This paper traces the introduction and use of fire-resistant (FR) fluids in hydraulic systems at underground mines in British Columbia. Reasons are given for the decision to make compulsory the use of such fluids in underground mines after January 1, 1975 by provincial government legislation. Examples are quoted of fires caused, or supported by, mineral oils which have resulted in loss of life and property.The basic principles of hydraulic systems are reviewed in order to present the effects of changing a system operating on mineral oils to one which must operate on FR fluids. Approximations of the cost of system conversions are given for certain machines and a brief survey is made of the various pieces of underground equipment which contain hydraulic systems operating on FR fluids.IntroductionIn 1948, Admiral Ben Moreel , who was then president of Jones and Laughlin Steel Corporation in the United States , wrote:""Although safe and healthful working conditions can be justified on a cold dollars-and- cents basis, I prefer to justify them on the basic principle that it is the right thing to do. ""(1)This paper will outline the introduction and use of fire resistant fluids at mine operations in the Province of British Columbia. That it was the right thing to do in enhancing the safety and well-being of every person employed at the mines was the prime consideration. That it may be justified on a cold dollars-and-cents basis is left for the reader to judge. The prime purpose of this paper is not so much to trace the efforts made by the individual mines to successfully introduce and use fire-resistant (FR) fluids in hydraulic systems, but to present an over-all picture of what occurred, in a collective sense, at the majority of mines which have ended up with a working FR fluid system. The problems attendant to the introduction of an FR fluid will be recounted in a manner which, it is hoped, will prove useful to those contemplating system conversions. Because the predominant fluid now in use is an invert, or water-in-oil. emulsion, this will be the FR fluid considered.Fluid Loss from SystemsThe quantities of various fluids required for use in hydraulic systems are extremely high. This statement in itself may appear to be redundant in that the capacities of the various systems should demand that a fixed amount of fluid is required for the initial filling of a system, with a further amount of fluid scheduled for use during subsequent fluid changes, i.e. at the recommended change intervals . If only this were the case!"

Jan 1, 1981

By K. Awuah-Offei

Long-term production scheduling optimization has been a challenging issue for the mining industry because of the size and complexity of the problem. The current planning algorithms have limitations in terms of addressing the stochastic variables underlying the mine planning problem. In this paper, an intelligent agent-based mine planning framework based on reinforcement learning is introduced. The long-term mine planning is modelled as a dynamic decision network. The intelligent agent interacts with the block model by means of a stochastic simulation and employs a Q-learning algorithm to learn the sequence of pushbacks that maximizes the net present value of the mining operation. The intelligent open pit simulator (IOPS) was implemented with an object-oriented design in Java®. A comparative application case study was carried out to verify and validate the models. The proposed method was used in planning an iron ore deposit and the results were compared to the Milawa scheduler used in Whittle® software. The outcome of the study demonstrates that the intelligent agent framework provides a powerful basis for addressing real-size open pit mine planning problems.

Jan 1, 2008

By J. M. Turnbull

THE primary objective of the young graduate, after the war, will be to obtain a suitable position within the Industry, with adequate pay and opportunity to advance. The positions available to meet this demand will depend on the magnitude and organization of the industry. The size of the mining industry, in particular, will depend on a number of factors, including depletion; new discoveries of mineral deposits; beneficiation of new kinds of mineral deposits, based on research; technical improvements, also based on research, enabling the mining of lower grade deposits; and complex social factors. The organization of the industry will depend on its control and management, which may be greatly affected by social conditions and changes, and may include a wider or a narrower use of technical services. The corresponding training or qualifications of graduates, to meet these conditions, calls for a consideration of educational requirements and facilities in relation to the conditions that are likely to occur. Some forecast of the probable future of the Industry, after the war, based on consideration of. the above factors, is necessary as a basis of discussion, since the graduate must find his place in the industry of that time, and find his work in maintaining and improving it, within the existent social framework. Social factors are pressing and? important at present and their future impact is uncertain. In considering these, a few quotations and extracts may be in order. "A new economic order, based on free access to the sources of raw materials, means free use of the world's wealth by all civilized nations" (The Pope. Also advocated by Churchill and Roosevelt in the Atlantic Charter). "Every citizen should have a voice in the conduct of business or industry which is ?carried on by means of his labour" (Archbishop of Canterbury).

Jan 1, 1943

By Chenming Liu, Xiao Lin, Bo Wang, Hongbin Cao, Xingang Li

Over 2 million tons of NH3-N were discharged in China per year recently, rare earth industry contributed 7.03% of NH3-N pollutant from industrial wastewater in 2007. Wastewater containing NH3-N and heavy metals mainly produced in RE extraction saponificated with ammonia and precipitated by ammonia bicarbonate. Generally, 1 ton REO cost 0.6-1.2 ton ammonia for extraction and 1.6 ton ammonia bicarbonate for precipitation, and produce 35-100 ton wastewater. Processes, like Na-saponificated, Ca-saponificated and Non-saponificated technique, are widely studied to reduce the adverse environmental effect of RE industry, while traditional processes still have advantage in production cost, process stability and product quality. In this study, a novel process that combines distillation and air-stripping is developed. NH3-N is removed and recovered based on relative volatility difference of NH3 and H2O. Phase equilibrium, heat equilibrium are calculated to determine process parameters. Hydrodynamic performance like flow field distribution is also simulated. Then, design parameters for distillation trays or structured packing are determined based on calculations and simulations. Besides, the phase diagram of (NH4)2SO4-NH4Cl-H2O in 30°C - 100°C, the typical salts composition of nonferrous wastewater, is studied to ensure commercial plants’ continuous operation. Ammonia removal tower (ART) with different high efficient column internals is designed to fit RE wastewater treatment requirement. The novel process has been commercialized in RE industry in Jiangxi, China. The commercial project operation results show the novel process reached a nearly zero-emission with >99.5% NH3-N was removed and then recovered as ammonia. Combined the novel process, the traditional REO separation process using ammonia and ammonia bicarbonate could achieve NH3-N reuse and the effluent quality meets the discharge standards.

Jan 1, 2016

By R. W. Guill

"The Apex Mine is currently scheduled to be brought back into production by Hecla in the first quarter of1990. Its projected productivity rate will be exceptionally high for a small underhand cut and fill mine.The ore mined at the Apex Mine occurs within a pipe-like structure as a series of iron oxides containing both gallium and germanium, plus significant amounts of silver, zinc, lead, and copper.Ground conditions in and around the ore zone have dictated that unique approaches be utilized. To date, these have included a prototype 0.5 cu. yd diesel LHD, and the use of fibrous shotcrete in 4ft by 7ft headings, and the first pneumatically-placed cemented backfill in North America. Above all else, it is the combination of new technologies with a small and dedicated workforce which has allowed for the successful development of this ore body.IntroductionThe Apex Mine is an example of the typical small underground project. It has high grade, but low tonnage and is deposited in poor ground. In such cases, conventional planning and thinking generally results in an uneconomical evaluation and negative production decision. Fortunately, some unconventional thinking was allowed to take place during the planning and evolution of the Apex Mine development. The result now serves as an example of how such unconventional thinking can lead to the type of innovations described below.The job necessitated the development and use of new equipment and materials to execute a highly flexible underhand cut and fill mine design/pneumatic backfill concept, that must be constantly modified as different than assumed conditions become evident in and around the ore zone."

Jan 1, 1990

By F. J. West

This paper deals with Jones & Laughlin Steel Corporation's new Adams mine, near Kirkland Lake, Ontario. After a brief discussion of ore structure, type, reserve tonnages, etc., the main body of the paper discusses the establishment of an open-pit limit based on economic considerations. The method used by J & L to arrive at an economically sound open-pit boundary its outlined fully. Physical limitations to open-pit boundaries are mentioned briefly. The paper concludes with a few remarks on the mining equipment in use and on its productivity

Jan 1, 1966

By J. Cayouette

In 1995, Louvicourt mine started one of the first paste backfill operations in Canada. From 500 000 t in 1995, the annual paste backfill tonnage produced reached 800 000 t in 1999. The maximum throughput of the surface plant (including binders) is 3500 tpd with a final density of 75% to 76% solids which gives a slump of 15 cm to 17 cm. Following the start-up of the paste backfill plant, the backfill strength performance levels were well below the pilot plant’s predictions. The introduction of ferrous slag, laboratory tests on various binder ratios with or without additives, and the desliming of the tailings enabled us to optimize the mix and operation costs. Primary and secondary stopes are filled respectively with a paste containing 4.5% and 2% binders in a mixture of 20% cement to 80% ferrous slag. In certain stopes, the binder ratio may vary from 2% to 7%, but always in a ratio of 80/20. Six years after start-up, or 4.5 Mt of paste backfill later, this paper discusses the present operation and the major changes that have occurred over the years to optimize both the operation and the paste fill quality.

Jan 1, 2003

By L. M. Cumming

"The contact between dolomite of the St. George formation (Cambro-Ordovician) and limestone of the overlying Table Head formation (Middle Ordovician) is a regional disconformity. This is best illustrated from exposures on Pointe Riche Peninsula, near Table Point, and along Port au Port Bay. The contact occurs along 180 miles of the west coast of Newfoundland from St. John Island in the north to the western part of Port au Port Peninsula in the south. A disconformity of the same age occurs between the Romaine and Mingan formations on the north side of the Gulf of St. Lawrence.Dolomitic beds beneath the disconformity locally contain concentrations of base-metal sulphides. Sphalerite occurs in dolomite pseudobreccias of the St. George formation at Zinc Lake, 7 miles northeast of Daniels Harbour. The 'Western Newfoundland Lower-Middle Ordovician regional disconformity is interpreted as having originated on and near the edge of a broad platform, and to have provided an important regional geological control in the localization of zinc mineralization."

Jan 1, 1968

By F. Parada Luna, F. Parada Torres, J. Salvo, A. Reghezza

In the pyrometallurgical processes of copper concentrates, arsenic is preferentially concentrated in the dusts carried by the gases as a result of their volatility and subsequent condensation in the gas cleaning train. In this work results obtained by alkaline leaching of the dusts from Ministro Hales roasting plant, belonging to Codelco, are presented. For the Ministro Hales plant the alkaline leaching would be an alternative to the recirculation of dusts to the roasting furnace. The experimental study considered NaOH and NaOH plus NaHS leaching of two samples of dusts, with 4.24 and 2.55% arsenic respectively. The results show that it is feasible to extract 90% of the arsenic and 50% of the antimony at room temperature using only NaOH, and when the temperature increases to 95ºC, the extractions of As and Sb increase. Copper remains in the solid residue with less than 1% dissolution, and the NaOH net consumption was approximately 140 kg/t of dust. In leaching tests with NaOH + NaHS, two types of methods were tested, baking plus leaching with water and direct leaching with a NaOH+NaHS solution. With the second method arsenic extraction increased to 95% and copper dissolution was less than 0.01% at 85ºC, NaOH 100 g/L, NaHS 90 g/L, 1.5 h and L/S ratio of 5/1 (L/kg). The bismuth remains stable in the solid in all cases. INTRODUCTION The presence of arsenic in copper concentrates has increased with time and the environmental regulations are becoming increasingly more stringent. In concentrate treatment pyrometallurgical plants, most of the arsenic is volatilized condensing in the gas train and is collected along with the entrained solids to form the flue dusts. Under these conditions, in smelters of copper concentrates with high arsenic content, the dusts are being treated in hydrometallurgical plants to extract and stabilize the arsenic, which also means that most of the copper contained in the dust is co-extracted with the arsenic. This affects the recovery of copper in the smelter and an alternative such as the selective alkaline leaching of arsenic, would allow the copper from flue dust to be recovered.

Jan 1, 2019

By D. Warkentin, M. Tomlinson, A. Nacu

"This study focuses on comparing the “blinding” effectiveness of various organic additives as part of a general review of using organic additives to mitigate preg-robbing and improve gold recovery during cyanide leaching of carbonaceous gold ores. The laboratory results compared the impact of various organic additives on the prevention of gold adsorption using both activated carbon and ore samples containing carbonaceous matter, generally referred to as total carbonaceous matter (TCM). Although several organic reagents were found to have a significant blinding effect on activated carbon, these results did not translate into increased gold leaching efficiencies with actual ore samples.INTRODUCTION Preg-robbing refractory ores, which contain carbonaceous matter, have been problematic in cyanide plants for many years. In industry, preg-robbing by carbonaceous matter may be mitigated using various techniques including flotation, to remove the carbonaceous matter; addition of blinding agents, to passivate the carbon surface and prevent adsorption of gold cyanide complex; roasting, to partially or fully destroy the carbonaceous matter; chemical oxidation (Abotsi & Osseo-Asare, 1986); pressure oxidation; or microbial deactivation (Dunne, Staunton, & Afewu, 2013). Carbon-in-Leach and Resin-in-Leach are also used as process alternatives in which activated carbon or resins are used to compete with the carbonaceous matter for gold cyanide adsorption. For highly preg-robbing ores, thiosulphate leaching may be considered as an alternative to conventional cyanide chemistry (Baláz, et al., 2000). Natural carbonaceous matter is composed mainly of hydrocarbons, organic acids, and graphitic/amorphous elemental carbon. Natural elemental carbon that behaves as activated carbon is considered to be the main reason for preg-robbing, although the true nature of this phenomenon is not fully understood (Tan, Feng, Lukey, & van Deventer, 2005). In general, the hydrocarbon fraction is assumed to have negligible interaction with gold, while organic acids, such as humic acids, may form complexes with gold, inhibiting its extraction in cyanide solutions. Organic reagents have been used for blinding carbonaceous matter in gold ores prior to cyanidation. Abotsi & Osseo-Asare (1987) tested various organic compounds, with two possible effects in mind. First, the organic compounds were expected to adsorb onto the surface of the solids as anionic/cationic species; the resulting electrostatic interactions between the Au(CN)2- anion and the negatively/positively charged surface would inhibit/enhance the gold uptake. Second, the organic reagents were expected to coat the surface of the carbonaceous component in the ore, limiting the available adsorption sites and reducing gold losses. Optimal reagent dosage depends on ore mineralogy, maturity and surface area of the carbo"

Jan 1, 2019

By W. Keith Buck

Introduction During World War II years, the magnetometer was used by various field parties of the Geological Survey of Canada, specifically in the search for chromite, a strategic war mineral. Throughout the summer of 1944, Professor J. W. Ambrose used the instrument experimentally on eight separate projects (1). Since then, several members of the Survey have come to consider its use to be of valuable assistance in the season's mapping. Dr. C. H. Stockwell, in particular, regards use of the magnetometer as a necessary part of detailed geological survey work. Throughout the field season of 1949, the magnetometer was used by Dr. Stockwell?s party as an aid to mapping in detail, to the scale one thousand feet to the inch, the south-west quarter of Dasserat township, Temiskaming county, Quebec. The principal geophysical project that was undertaken was the location of the Horne Creek fault and the Diabase fault in the area approximately midway between Arntfield and Kearns, on the Quebec side of the Interprovincial border. The location of these faults on either side of this central area was known. The Horne Creek fault is a subsidiary fault to the Cadillac 'break' which extends ?westward from Val d'Or through Cadillac to beyond Larder Lake. It lies to the north of that major fault zone and has a general southwesterly trend.

Jan 1, 1951

By S. Malopheyev, I. Vysotskiy, R. Kaibyshev, S. Mironov

"In this work, the effect of pre-strain rolling on the annealing behavior of friction-stir welded 6061-T6 aluminum alloy was studied. To this end, the as-welded material was rolled to 10 or 20 pct. of thickness reduction prior to the standard post-weld T6 heat treatment. Three rolling directions were the 3-mm thick sheet were considered: along the welding direction, perpendicular to the welding direction, and at the angle of 45° to the welding direction. At relatively low pre-strains (10 pct.), the annealing behavior was found to be very sensitive to the rolling path, and rolling along the welding direction was most effective in suppressing abnormal grain growth. On the other hand, increasing the pre-strains to 20 pct. of thickness reduction inhibited abnormal grain growth irrespective of the rolling path.INTRODUCTION Heat-treatable wrought Al-Mg-Si alloys are widely used due to attractive combination of strength, ductility, excellent corrosion resistance and low cost (Polmear, 2006). To provide the optimal balance of mechanical properties, these materials are typically commercially available in appropriately work- and precipitation-hardened conditions (Polmear, 2006). During conventional fusion welding, however, the prior strengthening effect is totally lost due to elimination of the work hardened structure and dissolution of the strengthening precipitations. An innovative friction-stir welding (FSW) technology may partially overcome this problem. Due to the solid-state character of this process, which involves very large strains, the welded material is characterized by fine-grained microstructure with moderate-to-high dislocation density, and thus the prior work hardening effect may be preserved or even enhanced (Threadgill et al., 2009; Mishra & Ma, 2005). However, heat input associated with FSW inevitably leads to dissolution and/or coarsening of strengthening precipitates, thus giving rise to the undesirable material softening. In an attempt to restore the strength of the friction-stir welded material, the standard T6 post-weld heat treatment has been applied, but this approach was found to lead to abnormal grain growth (Malopheyev et al., 2016; Mironov, 2013, Mironov et al., 2015)."

Jan 1, 2018

By M. G. Lipsett

"The Mining Information Technology User Group considers information to be a strategic enabler to improved business performance in mining. This ad hoc group has been meeting since 2000 to share knowledge and leverage their efforts in effectively using IT in mining. In this paper, core issues to mining IT are reviewed, along with initiatives to engage industry professionals and decision-makers in the potential for improved use of information in their operations. Relevance of IT to Canadian MiningMining operations always drive to improve their performance, and so far they have succeeded by using different technologies. While economies of scale have come in fragmentation and material handling, and energy usage has improved through conservation and design of integrated mineral processing plants, these systems have the net result of tightening operational constraints, through reduced excess capacity. There are higher opportunity costs of lost production when integrated, large-scale systems are operating in a sub-optimal way.The problem is that it is profoundly difficult to run a mine in an optimal way. Optimization requires a defined objective function (e.g., profit), which is hard to pose, let alone solve, because so many inter-related aspects of an operation affect the bottom line. Even for a small, well-defined process state, it is difficult to measure all the pertinent information with sufficient accuracy to ensure that the system is performing well in real time.The art of mining remains making good decisions with uncertainty: in the orebody delineation; in the allocation of resources; in the efficiency of the operation; in the reliability of components and systems; and in responding to the downstream market. As well, individual decision-makers need to know how their decisions affect other processes and systems, so that improvements in one part of an operation do not result in such degraded performance in the rest of the plant that overall profitability goes down."

Jan 1, 2003

By Kazutoshi Haga, Batnasan Altansukh, Yasushi Takasaki, Mohd Yazid Bin Abdul Razak, Atsushi Shibayama

"In this study, the volatilization behaviour of arsenic (As) and antimony (Sb) from arsenicantimony bearing minerals such as tennantite (Cu12As4S13)/tetrahedrite (Cu12Sb4S13) in copper ore was investigated using a roasting process. Specifically, the thermal decomposition of tennantite and the arsenic volatilization were investigated under nitrogen and air atmosphere. The roasting experiments were performed at temperatures ranging from 500 to 1,200oC and different retention times using a laboratory electric furnace. The results indicated that over 95% volatilization was achieved at 700oC. On the other hand, when the temperature increased to 1,200oC, volatilization rate of Sb reached to 90%. Therefore, volatilization of Sb requires high temperature compared to As. It suggests that As and Sb can be separated using temperature difference. Selective removal of As is possible at 700oC, subsequently Sb can be recovered as a volatilized product by increasing the temperature to 1,200oC. Meanwhile, volatilization of Cu and Fe was not observed on these conditions. The content of As and Sb in the residues obtained from roasting at 700 and 1,200oC was less than 0.3 and 0.75 mass%, respectively. The Cu content in solid residue at 1,200oC increased to 34 mass%. The clean copper concentrate with lower amounts of arsenic and antimony was obtained from the process. INTRODUCTIONRecently, arsenic (As) and antimony (Sb) contents in copper (Cu) concentrates are increasing year by year. Arsenic and antimony are present with Cu minerals such as enargite (Cu3AsS4), tennantite (Cu12As4S13) and tetrahedrite (Cu12Sb4S13) that associate with copper sulfides [chalcopyrite (CuFeS2) and bornite (Cu5FeS4)]. They are normally concentrated by flotation and treated in copper smelters. However, treatment of copper concentrates containing high amounts of arsenic and antimony by a smelting process is difficult due to environmental implications of toxic arsenic and antimony. As demand for copper continues to grow, the need to source copper from several types of resources including those that contain high levels of As/Sb becomes necessary. Therefore, a novel processes for the treatment of As/Sb bearing Cu concentrates are required. Reviews on copper resources such as enargite, tennantite and tetrahedrite containing high amounts of arsenic and antimony are covered widely in literatures by many researchers (Padilla et al., 1998; Welham, 2001; Vinals et al., 2003; Guo & Yen, 2005; Balaž & Achimovicova, 2006a; Filippou et al., 2007; Mihajlovic et al., 2007; Lattanzi et al., 2008)."

Jan 1, 2016

By P. R. A. Andrews

"The sillimanite group minerals, kyanite, sillimanite and andalusite are identified as alumino-silicate minerals with the common chemical composition AIP3.Si02' so that each possesses similar physical properties. Kyanite is the most abundant mineral and mainly occurs in Quebec, Ontario and British Columbia; sillimanite occurs in Ontario and Manitoba; and andalusite in Nova Scotia. The main use for the sillimanite-group minerals is in refractory applications for the production of refractory bricks and shapes. In refractory applications, the main performance criterion is the relative percentage of mullite formed within the material during firing. This phase gives a greater degree of resistance to creep deformation and slag attack, and improves the ability of the refractory to withstand high temperatures under load. The beneficiation of refractory silicate minerals has been the subject of many investigations at CANMET, and the former Mines Branch. Eighteen kyanite, two sillimanite, and three andalusite evaluation studies were conducted between 1933 and 1987. A review of some of the more important studies is presented, which includes information concerning mineralogy, beneficiation methods and flotation data."

Jan 1, 1995

By M. Abdollahi, M. R. Khalesi, Y. Kianinia, A. Khodadadi Darban

High cyanide consumption during the processing of gold ores with high sulphide minerals can make the typical cyanidation uneconomic. Also cyanide is a toxic material and environmental concerns of cyanide compounds are serious. Optimization of cyanide consumption requires a methodology to estimate the amount of exposed cyanicides, the kinetic of their dissolution and estimation of formation of cyanide complexes which consume the free cyanide. In this paper, a methodology to estimate cyanide consumption by modeling the minerals and gold leaching kinetic based on a liberation model and speciation of all possible cyanide related species in the solution is presented. The results showed that this methodology could successfully estimate the cyanide consumption based on mineralogical data with very lower number of parameters compared to empirical models present in the literature, while it offers the prediction of formation of all cyanide complexes which could be used for optimization purposes.

Jan 1, 2017