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"The rocks of Notre Dame Bay form part of the Central Paleozoic Mobile Belt (Williams, 1964) of the Newfoundland Appalachians. The Central Paleozoic Mobile Belt of the northern part of the island consists predominantly of Lower and Middle Ordovician rocks overlain by Silurian elastic and volcanic sequences and underlain in the marginal zones of the belt by polydeformed metamorphic rocks of the Gander Lake Group (Kennedy and McGonigal, 1972) in the northeast and the Fleur de Lys Supergroup (Neale and Nash, 1963; Kennedy, Phillips and Neale, 1972) in the northwest. The Ordovician rocks of the Central Mobile Belt have been subdivided into a number of local groups in different parts of the region. The Lush's Bight Group was first defined by MacLean (1947) . Recently Marten (1971) has revised the definition of this group, as shown in Table 1 and his revised definition is accepted in the present paper. Plate tectonic models that have been proposed for the development of the Newfoundland Appalachian System have indicated that the mafic volcanic rocks of western Notre Dame Bay represent oceanic crust (Bird and Dewey, 1970; Dewey and Bird, 1971; Church and Stevens, 1970) which marks the remnants of the proto-Atlantic Ocean first proposed by Wilson (1966) . Such models infer that the mafic volcanic rocks constitute the upper part of an ophiolite sequence. Analyses of the lavas show that they are tholeiitic and support this conclusion (Papezik and Fleming, 1967; Smitheringale, 1972) . A complete ophiolite sequence, consisting of peridotites overlain by gabbros, overlain by a sheeted diabase dyke complex which passes upward into pillow lavas, occurs at the base of the Snooks Arm Group (Upadhyay et al., 1971 ) . Sheeted diabase dykes are known to underlie the lowest mafic pillow lavas of the Lush's Bight Group at several localities in Notre Dame Bay (Strong, 1972, and pers. comm.) . However, several conflicting points about the geology of this region suggest that although a typical oceanic crustal sequence of Lower Ordovician age is present, older rocks occur within the ophiolite terrane in several places (Williams, Kennedy and Neale, 1972) ."

Jan 1, 1972

By P. G. Lazenby

This paper describes the latest instrumentation improvements in the INPUT Airborne E.M. System, particularly the new electronic signal-processing techniques. Several anomaly examples illustrating these techniques are shown.

Jan 1, 1973

By Peter A. Hacquebard

"The coals of the Sydney and Pictou coalfields are generally classed as high volatile ""A "" and medium volatile bituminous coals but there are significant differences within and even beyond this rank. These are related to the observation that the coalification in eastern Canada is essentially post-deformational, resulting in a general increase of rank with depth in individual seams.Exploration drilling in the Sydney coalfield has shown that the rank increases offshore to M. V. bituminous at mineable depths and in the Pictou field to L. V. bituminous coal. There is also a marked easterly shift in rank within one seam at the same depth at Sydney, with the result that M. V. coal will be reached sooner in the Donkin Reserve area (at 700 m depth) than in the Lingan-No , 26 Reserve area (at 900 m depth). These rank changes are important for the manufacturing of metallurgical coke as shown with coke stability predictions based on petrographic analyses. The L. V. coal of the Pictou field can be used for blending purposes and is the only known L. V. deposit of mineable thickness in eastern Canada.In addition, the vertical rank changes between seams have been studied in ten boreholes. They are not constant within the confines of the Sydney coalfield. Four separate areas can be recognized, each with different coalification gradients, which can be related to changes in the paleogeothermal gradients . Variations of 2.5 degrees to 6. 7 degrees CI IOO m are indicated and geological causes for these changes are suggested.IntroductionThe Sydney coalfield is the largest and most important field in eastern Can ad a, and although it has been in production some 200 years, the remaining ""demonstrated "" resources of 1.6 billion metric tons can extend its production capability for at least another 100 years. All coals mined are high volatile "" A"" bituminous and have been used for both thermal and metallurgical purposes. For the latter rank variations even of a minor scale are of critical importance for the manufacturing of metallurgical coke.The significance at the present time of the Pictou coalfield, which has only modest remaining "" demonstrated"" resources of 60 million metric ton s, lies in the discovery in 1975 of a 14-million-ton deposit of low volatile bituminous coal. It is the only known low-volatile coal in eastern Canada and is suitable for use as a blend for metallurgical coal. As such, it could supply the Sydney coke ovens for a period of 30 years at the current rate o f coke production and replace imported American low volatile coal.Consequently, coal rank studies of the Sydney and Pictou fields are important not only from a geological point of view, but also because of economic considerations."

Jan 1, 1984

By John C. Lyons

"The Wabana iron ore deposits occur as flat-dipping beds of oolitic hematite and chamosite, of Lower Ordovician age, which outcrop for 3 miles along the northwest coast of Bell Island, Conception Bay, Newfound-land, about 16 miles from St. John's.The deposits occur in three zones, Upper, Middle, and Lower beds, separated respectively by 30 feet and 215 feet of shale and sandstone. They are primary sediments laid down in a shallow tidal basin by the precipitating action of a marine environment on iron-rich fresh waters flowing into the basin.The ore-bearing zones, while of wide areal extent, are not uniform beds of hematite that can be mined wholesale. The action of waves and currents during sedimentation; the delta pattern, velocity, and transporting power of streams flowing into the basin; the contours and oscillations of the sea bottom on which the sediments were laid have all been fundamental in the emplacement of richer and thicker mineable sections, and of lean zones so intercalated with shale as to be unmineable.The preservation of the deposits is due to their location in the Conception Bay syncline and to a considerable upthrust of the country east of the bay in post-Ordovician time.The hematite deposits were first recognized as such in 1892, and soon after were acquired by the Nova Scotia Steel and Coal Co. They are now being mined by Dominion Wabana Iron Ore, Limfred, a wholly owned subsidiary of the Dominion Steel and Coal Corporation, Limited. Production started in 1895, and up to the end of 1955 totaled 58,588,516 long tons of hematite ore, having an average dry analysis of about 51 5 per cent iron, 11 8 per cent silica, 0·9 per cent phosphorus, and l ·5 per cent moisture. About 40 per cent of the total tonnage mined has come from surface stripping and on-shore mines. These areas have now been almost completely depleted, and operations are confined to submarine mines extending for two miles off shore under the waters of Conception Bay. Three sub-marine slopes are currently in operation, Nos. 3 and 4 working in the Lower Bed and No. 6 in the Middle Bed. A general picture of the workings is shown in isometric projection in Figure 1. Submarine mining has been entirely by the room-and-pillar method, with an extraction of 60 per cent. The deepest workings, at a vertical depth of 1,850 feet below sea-level, have a rock cover of about 1,500 feet. No mining is done in areas where the rock cover is less than 200 feet. To date mining has explored six square miles of a potential area that may exceed 50 square miles."

Jan 1, 1949

By W. E. Halle, G. J. S. Govett

"The Institute of Applied Geology, Manila, Philippines, is jointly sponsored by the University of the Philippines, the Philippines Bureau of Mines and the United Nations Development Programme (Special Fund). It provides, in its fourth year of operation, an interesting example of international cooperation in mineral development. Objectives include: (1) the training of mining engineers in modern techniques of mineral exploration; (2) assisting government and industry in discovering new ore deposits; and (3) providing the basis for the establishment of an economically oriented graduate school of geology at the University, the first of its kind in the country. Training of engineers requires roughly one full year, which is divided between academic study and actual field practice. Lecture and laboratory instruction include courses at university level designed specifically to up-grade those aspects of the geological sciences that are required by mining engineers now qualifying as mineral exploration engineers-economic geology, applied geochemistry, geo-physical exploration, petrology and structural geology. The field training involves direct participation in actual mineral exploration projects arranged with the co-operation of the Bureau of Mines and private interests engaged in mineral development and production. The system works well in practice, and the Institute staff and trainees were responsible for outlining new evidence of economic mineralization. It is also apparent from the application of the exploration methods available to the project -geological mapping, air photo interpretation, magnetic, electric, electromagnetic, self potential and gravity surveying as well as geochemical prospecting -that, under the humid, tropical, mountainous conditions in which the practical program was conducted, air-supported geochemical prospecting with attendant reconnaissance geological mapping affords the most economical and effective approach to mineral exploration for at least some of the deposits characteristic of the region."

Jan 1, 1968

By T. A. Utigard

To improve recoveries of Ni, Cu and Co in the Inco flash furnace, a new operating concept was investigated. By adding sufficient coke to form a supernatant coke layer, a reducing barrier would form allowing for improved reduction of descending oxidized sulfide mineral particles formed in the flame. The objective of this investigation was to study the kinetic mechanism and efficiency of the coke layer to produce a sulfur deficient matte. The mechanism and rate of carbon reduction of each of the phases formed in the flash flame, i.e. sulfides and oxysulfides were investigated by means of X-ray visualization tests. Graphite-slag reduction was also conducted for comparison purposes. In the case of slag, poor wettability and the formation of a gas film on the surface of the carbon reductant are often blamed for limiting the reaction surface area that ultimately results in poor reaction kinetics. The X-ray visualization tests confirmed that matte and oxysulfide wet coke better than slag and that the rates of reduction of matte and oxysulfide are faster than that of slag.

Jan 1, 2005

By D. Brand

"The risk management objective of the AMIRA Code of Practice for Metal Accounting has seldom been systematically investigated in the literature up to the authors’ knowledge. Risk is defined in the Australian Standard on Risk Management (AS/NZS 4360:2004), as “the chance of something happening that will have an impact on objectives”. The simplified economic analysis performed in this paper has lead to define “something happening” as measurement non-representativity and “impact on objectives” as NSR loss from the optimal NSR. This has pinpointed a missing link being the establishment of a relation between NSR in flotation plants and measurement representativity. The proposed framework, referred to as the total cost of representativity, answers the previously unanswered question of how much accuracy/reproducibility is fit for purpose in a given flotation plant. Authors readily acknowledge that it is way easier to assess the cost of accuracy/reproducibility than the cost of inaccuracy/irreproducibility. However, this exercise not only answers previously unanswered questions but also establishes an essential link with operational excellence. This paper exposes why such operational excellence could neither be attained nor proved without a state of the art metal accounting system. This should impact not only how metal accounting systems are audited/designed/refactored, but also how flotation plants are designed.IntroductionBecause representative metal accounting is a vital source of information for the financial accounts of a mining/metallurgical company, the need for a code on metal accounting was recognized in 2001 and a team was formed in 2003, under the sponsorship of several major mining houses, to produce such a code. Table 1 exposes the two main objectives of this AMIRA Code of Practice for Metal Accounting."

Jan 1, 2017

By Julian V. Simela

Conventional methods of underground surveying use theodolites/total stations and 3D laser scanners to obtain information about the underground environment. Current methods of geo-referencing these instruments to a mine reference system include triangulation, trilateration and resection. However, despite technological advancements, surveying procedures have remained slow, laborious and relatively unchanged during the last half-century. Recent innovations in the robotics community have shown that automated mapping of underground mining tunnels can be undertaken using 2D/3D laser scanners. These techniques have the potential to, in turn, improve upon current underground surveying and mapping methods. Automating surveying and mapping using current surveying tools without changing the setting up procedures or removing current constraints, or even changing the type of equipment used, does not change the status quo. The problem of moving from a static, tripod based surveying and mapping system to an unconstrained mobile surveying and mapping system is the subject of this paper. A current challenge for automated mapping is the ability to automatically geo-reference a mobile mapping system to a mine reference system. For a mobile mapping system that uses a horizontally mounted 2D laser scanner to gather data of the underground environment, the challenge of determining its position and orientation within the mine environment is magnified even more. This paper introduces Mobile Automated Scanner Triangulateration (MAST), a technique under development at Queen?s that is designed to geo-reference a mobile mapping system to a mine reference system for the purposes of underground mine surveying. MAST quickly and automatically determines scanner 2D position and orientation (azimuth) in a mine reference frame by using minimal human input.

Aug 1, 2013

By David Thomas, Charles Harper, Brian Watters

The Star-Waddy Lakes area lies withjn the northeasterly-trending early- to mjd-Proterozoic volcanoseilimentary-pl utoruc belt referred to as the La Range Domllin. In the area investigated the domajn is composed of the Central Metavolcaruc Belt which is bordered by metasedimentary belts of the Crew Lake and MacLean Lake Belts to the northwest and southeast respectively. The boundaries between the Central Metavolcanic Belt and the flanking belts are generally marked by prominent zones of shearing. The volcanosed imentary succession is intruded by a variety of ultramafic to felsic plutons which, on the basis of lithology, field relations and geochronology, can be broadly subdivided into three groups or episodes. These are: a) an 'early' (ea. 1866 Ma), possibly subvolcanic, episode marked by composite intrusions ranging from gabbro-diorite to granite, b) an 'intermediate' (ea. 1854 Ma) plutonic event distinguished by more homogeneous felsic intru ions ; and c) a 'later' (ea. 1835 Ma) event characterized by leucocratic quartz-rich grani te intrusions. The La Range Domain has undergone polyphase deformation with a strongly developed northeast-trending structural grain. Large scale folding is manjfested by large regional sy nforms, arcuate and triangular patterns associated with many of the plutons and by tight to isoclinal folds within the adjacent metasedimentary belts. Inhomogeneous strain characterizes much of the Star-Waddy Lakes area. With strain gradients being typically very steep, zones of high strain consisting of zones of extreme extensional fabrics, discrete shearing, as well as broader zones of cataclasis and structural slicing, are often juxtaposed with areas of relatively minimal deformation . Dilation structures tend to favour these zones of highly contrasting strain. Late, brittle fractures, faults and shear zones are widespread and appear to be particularly important as loci for gold mineralization. Metan1orphic mineral assemblages indicate that upper greenschist to middle amphibolite facies conditions were attained. Geological and geochenucal evidence indicates that the Central Metavolcanic Belt evolved in an island arc environment. Metavolcanic rocks from both the Waddy and Star Lakes areas display similar characteristics on variation diagrams (e.g. AFM and the Jensen cation plot) in that the dominant trend is calc-alkaline with some basic to intermediate types having a mildly tholeiitic character. A few samples from the southern end of Lower Waddy lake display komatiitic to basaltic-komatiitic afl'injties. The relatively immobile minor and trace elements (e.g. Ti , Zr, Nb, Y, Cr) provide reliable characterization of the metavolcanics, particularly of the basalts, which have highly distinctive trace element properties. Geochemical patterns for the basalts are similar to those for modem volcanic arc basalts. Low initial 87Sr/86Sr ratios (0.7017 - 0.7019) are consistent with a subduction-related origin for the volcanics. The major plutons have chemical properties typical of volcanic arc granites and are largely calc-alkaline in character, showing little chemical variation from the volcanics.

Jan 1, 1986

By Pierre Beaudoin

"This paper deals with the repairs made on two damaged mills. It investigates briefly the causes of the damage, explain its nature and the design of the repair. It explains the detrimental effect on operation and the solutions implemented to reduce them. Finally, to review the follow-up required for such repairs. LOCATIONThe Holt McDermott Mine is located 75 kilometers Northeast of Kirkland Lake and 30 kilometres west of the Quebec border in Northeastern Ontario. The town of Kirkland Lake is located approximately 500 kilometres north of Toronto. HISTORYThe discovery of gold in Holloway Township dates back to early 1920. In 1984 Barrick Resources, which amalgamated with Camflo Mines, acquired more claims on the property and initiated an extensive drilling program. By 1985, the drills indicated reserve increased to 2,500,000 tonnes grading 6.8 g/mt. In 1986 a production decision was made and in 1988 the mine was officially opened.As of December 31, 1998, 4,691,507 tonnes grading 5,66 g/tonnes have been milled from 4 ore-bodies. The mill started up in June 1988."

Jan 1, 2001

By Sib N. Mukherjee

Main ventilation fans are used in all the mines and they run continuously 24 hours a day and 365 days in a year. Any improvement in their performance can lead to considerable power saving. The basic principle for selection, operations, and related measures are discussed in brief in the paper. The contributions of different elements of mine fan on its performance are discussed in brief. The means to improve efficiency of a running fan is also discussed and the importance of saving even 1 Kwh is elaborated. It is found that the cost of the energy saved may even permit a replacement fan to be procured in a few years time.

May 1, 2007

By N. Schmalbein, L. von Ketelhodt, L. Kotelo

"The mining industry continues to remain challenged. Lower commodity prices, increasing labor costs and more importantly diminishing reserves are amongst some of the primary factors contributing to the difficulties faced. Ore sorting technologies have demonstrated their potential to improve the downstream beneficiation performance. The general processing route sees all primary crushed material milled for liberation and then processed in accordance with characteristics of the gold therein, i.e.: refractory golds would require direct leaching or oxidation whilst free gold would follow the conventional cyanidation process, after gravity concentration. Ore dilution increases the associated operating costs within each stage of this process. The opportunity to process the same throughput at a higher grade can only be achieved through pre-concentration. Sensor based sorting has been examined on numerous occasions by various gold producers. Test work carried out on different bulk low grade gold ores has shown the successful applicability of ore sorting to remove waste, whilst maintaining high recovery rates of gold. The results of a combined XRT/Laser sensor sorter have shown grade improvements of over 300% from feed grades of 0,25g/t to 1,15g/t at gold recoveries of 66% and waste ejection rates of 85%. This paper presents some of the results from the work undertaken by STEINERT with respect to gold sulphide ore sorting and presents a modelled financial scenario, which can enable a company to target and reclaim low grade ores.INTRODUCTION The mining and minerals processing industry presents with many different challenges including, volatile commodity prices, increasing labor costs and more importantly diminishing reserves. Conventional processing routes will continue to play a crucial role in the beneficiation process, however innovative methods of reducing operating costs and optimizing on the overall circuit performance is where technologies such as sensor based sorting come into the fore. Sensor based sorting as a dry mechanical process not only reduces water consumption by eliminating unnecessary waste but also reduces the requirements for reagents in the downstream processes. Sensor based sorting under dry conditions presents a highly efficient alternative to wet pre-concentration methods such as dense medium separation (DMS)."

Jan 1, 2017

By L. V. Chugaev

In the course of the hydrothermal refining of copper-nickel products containing covellite, oxidation of Fe2+ ions by the CuS?Cu2+ pair takes place, and iron is precipitated as hematite. Lower copper concentrations in the solution and higher solution acidity lead to the partial oxidation of sulphide sulphur, whereupon hematite is reduced by covellite causing iron to go back in solution. It is demonstrated that in the process of hydrothermal treatment of the covellite-containing solid product in pure water covellite oxidises millerite to polydymite (Ni3S4). Formation of polydymite during the process of refining seems to be due to millerite oxidation both by covellite and the CuS?Cu2+ pair.

Jan 1, 2007

By Scott Martin

This paper will discuss the challenges currently facing the mining industry. By sharing experiences gained in the CIM Leading in Mining Course, I will highlight what’s working, what’s not, what are the challenges, what are the concerns, what are the opportunities, what needs to happen. Specifically, I will discuss what is currently happening with leadership and leadership development in members’ own organizations, what skill sets are important to develop in different hierarchical groups and how comprehensive leadership courses like the leading in Mining course can help improve leadership within individuals and the industry. Leadership development is a process not an event.

Jan 1, 2014

By C. J. Brown

Controlling the level of impurities in copper refinery electrolytes is essential to achieving acceptable cathode purity. Purge of electrolyte is not an entirely satisfactory solution since the cost of neutralization, waste disposal, and replacement acid can be appreciable. The APU® process utilizes ion exchange resin to sorb sulphuric acid while rejecting metal salt impurities. Extensively employed for recovery of waste pickling and anodizing acids since 1977, the system is now being used at several refineries for removal of contaminants such as antimony, bismuth, iron, and nickel. The purified acid, which is recovered from the resin by water elution, is recycled back to the refinery tank-house, while the metals are typically recovered from the de-acidified by-product solution by precipitation.

Jan 1, 2005

Phelps Dodge has recently operated a commercial scale, super fine grinding circuit of copper concentrates for use in a medium-temperature pressure leaching process. Two 355 kW vertical stirred mills were installed in series, targeting a grind of 80% passing 7.5 µm and 98% passing 15 µm as outlined in Phelps Dodge's concentrate leaching patent portfolio. This paper details the operation and results of the test program at Bag dad, as well as some of the operating challenges encountered.

Jan 1, 2007

By I. S. Parrish

The Sullivan Mining Group has been exploring the mineral deposits of the Mount Pleasant area of southern New Brunswick since 1967. Sullivan geologists have logged over sixty miles of drill core, mapped over five miles of underground workings and studied numerous surface exposures. Several mineralized zones have been defined and two higher-grade porphyrytungsten bodies delineated. Within these bodies, wolframite occurs as disseminated specks and grains up to one-half inch in diameter. The host rock is a brecciated rhyolite porphyry that has intruded quartz-feldspar porphyry of Mississippian age . The host rock is itself intruded by an acid porphyry called transition rock and is underlain by a microgranite. The mineralized zones, host rock, transition rock and microgranite are all thought to be derived from the same magma, and to represent progressive fractions from that magma.

Jan 1, 1978

By D. F. Hambley

"In designing are passes f or underground mines specific consideration should be given to unimpaired flow of broken rock, the dump point, and typical practices f or overcoming operational difficulties. Design features such as branches, bends, and knuckles should also be considered. This paper pro vides engineering information and various criteria for designing are passes, draw points. feeders, and support systems, together with several illustrative examples.IntroductionOre passes are the primary mean s o f vertical transfer of mined ore to the ore bins and loading pocket from which the o re is hoisted to the surface (Fig. 1) . While the words "" ore"" and ""ore pass"" are used here, such transfer systems ca n be used for any broken rock.The most extensive ore pass systems are found in caving and sublevel stoping mines. Extensive ore pass systems are also found in multilevel mines having steeply dipping orebodies. In more flat-lying orebodies , ore pass systems are sometimes used in conjunction with conveyor systems .Two decades have passed since the principles of the flow of bulk solids were formulated (Jenike, 1961, 1964; Johanson and Colijn, 1964; Kvapil , 1965). However, few published papers are available that discuss the design criteria for ore pass systems. Therefore, the aim of this paper is to provide the information necessary for good o re pass design .Rock Flow in Ore Pass SystemsIf an ore pass system is to fulfill its function, the transfer o f material must occur in an orderly fashion and in such a way that the full size of the opening is employed effectively. Apart from un controlled flow at the drawpoint, or outlet , whose design will be considered later in this paper, two occurrences may impede flow in an ore pass, namely:• Hangups due to interlocking arches.• Hangups due to cohesive arches.Prevention of each of these problems will be discussed in succeeding sections of this paper. A third problem piping, is related to the ratio of the drawpoint size to the o re pass size and will be discussed under drawpoint de sign."

Jan 1, 1987

By D. Berkley

"The competitive pressure, the increasing energy costs and the environmental regulations impose substantial challenges to the definition of power plants serving industrial facilities. Primary mining and metallurgical facilities have even greater challenges because they are often located remotely, where the fuel supply can be a problem. The absence of a power grid imposes challenges on the reliability and quality of the electrical energy supply. In addition, the facilities usually require thermal energy too, not only electricity.This paper outlines these types of issues that have to be considered when defining a cogeneration plant integrated with a remotely located industrial facility. It is addressed to the “users” of cogeneration facilities rather than to “generators.” The focus is on analyzing various site-specific design considerations to prescreen the feasible cogeneration alternatives and minimize the number of options to be analyzed from the economics viewpoint. This approach could substantially reduce the engineering effort and schedule during the feasibility phase of the project.The front-end of the paper provides a basic understanding of cogeneration plants of various types to establish a common language. Subsequently, the paper outlines and analyzes specific issues that could be of help in the definition of cogeneration installations for remotely located industrial facilities, with a focus on mining and primary metallurgical plants"

Jan 1, 2003

By Fabian Mohr

The methyl substituted binuclear cyclometallated gold(I) complexes [Au2(?-n-MeC6H3PPh2)2] [n = 4, 5 and 6] all undergo oxidative addition reactions with halogens and, in the case of the 4- and 5-methyl substituted analogues, with dibenzoyl peroxide to give metal-metal bonded digold(II) complexes [Au2X2(?-C6H3-n-MePPh2)2]. The 4- and 5-methyl substituted digold(II) compounds on warming or exposure to light undergo carbon-carbon coupling reactions to give gold(I) complexes containing the corresponding 2,2'-n,n'-biphenylyldiphenylphosphines. The 6- methyl substituted digold(II) complexes rapidly isomerise above ca. -20° C to binuclear heterovalent gold(I)/gold(III) compounds [XAu(?-2-Ph2PC6H3-6-Me)AuX{?2-(6-MeC6H3-2-PPh2)}], containing a fourmembered cyclometallated ring on a gold(III) centre. Surprisingly, no carbon-carbon coupling could be induced for any of the 6-methyl substituted compounds, even under forcing conditions. This difference in reactivity of the 6- methyl derivative, compared to that of the 5-methyl and unsubstituted analogues was studied by ab initio calculations using a series of model compounds. The results are in excellent agreement with the experimental findings and suggest that the key-step in the C-C coupling reaction is the partial opening of the Au(III)-P bond in one of the transition states. In the 6-methyl system this transition state is energetically inaccessible and hence no C-C coupling occurs.

Oct 1, 2003