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By T. Hidayat, D. Shishin, S. Sineva, M. Shevchenko

The effects of the slagging components Al2O3, CaO and MgO on the thermodynamics and phase equilibria of the gas/slag/matte system with major elements “Cu2O”-“FeO”-SiO2-S are characterised using an integrated experimental and thermodynamic modelling approach. The experimental technique included high-temperature equilibration experiments using a spinel substrate in controlled gas atmosphere (CO/CO2/SO2/Ar), quenching of the sample and subsequent measurement of the compositions of equilibrium phases with Electron Probe X-ray Microanalysis (EPMA). Thermodynamic modelling is undertaken using the computer system FactSage. In previous experimental studies on this system, the separate effects of Al2O3, CaO and MgO were determined. In the present investigation, the combined effects of these additional components are investigated at 1200oC and P(SO2) = 0.25 atm and a range of P(O2)’s. Special attention is paid to ensuring chemical equilibrium is achieved in each case, for this reason possible kinetic factors are systematically analysed. The results obtained are presented in the form of graphs showing the compositions of matte and slag phases as functions of copper concentration (matte grade). The new experimental data are used for the improvement of the thermodynamic database for multicomponent copper-containing systems. The effects of the slagging elements on this multicomponent system will be presented in the paper. INTRODUCTION Whilst Fe-O-Si form the principal components of copper smelting and refining slags, additional impurities are present in industrial practice typically at 2–5 wt.% Al2O3, 1–4 wt.% CaO and 1–2 wt.% MgO levels (Davenport, King, Schlesinger, & Biswas, 2002). These elements are introduced into the slag as impurities in concentrates and other feedstocks, in fluxes added to the process and in refractory materials. Understanding, and accurate description, of the changes that take place in the smelting process in the presence of these additional elements is of major importance to the optimization of industrial operations. Although experimental data are available on slag/copper matte equilibria, further work is needed to accurately characterise the influence of Al2O3, CaO and MgO on phase equilibria and elemental distributions of elements in gas/slag/matte systems. The individual effects of the Al2O3, CaO and MgO slagging components on equilibrium phase assemblages under selected conditions have been quantified in a recent series of studies on the Cu–Fe–O–S–Si-(Al, Ca, Mg) gas-slag-matte-metal system (Fallah- Mehrjardi, Hayes, & Jak, 2018; Fallah-Mehrjardi, Hidayat, Hayes, & Jak, 2017a, 2017b; Hidayat, Fallah-Mehrjardi, Hayes, & Jak, 2018a, 2018b; Jak et al., 2016; D. Shishin, Decterov, & Jak, 2018; Denis Shishin, Hayes, & Jak, 2018). Since, thermodynamically, the condensed phases do not behave ideally, it is to be expected that the effects of individual elements may not be additive, and the additional interactions between the Al2O3, CaO and MgO slagging components will also have to be taken into account. These additional effects are expected to be smaller than those of the individual components, so higher accuracy is needed. The present paper describes analysis of the precision and accuracy of the experimental technique on multi-component, multi-phase equilibria in these systems to enable the combined effects of Al2O3 + CaO + MgO on slag/matte/spinel equilibria, i.e. for high Fe/SiO2, to be accurately measured. The effects of Al2O3, CaO and MgO on the gas - slag - matte are analysed using a thermodynamic modelling approach with the computer package FactSage.

Jan 1, 2019

By Michael K. Watkeys, Charlesworth. E. GUY, Jacobus E. Potgieter, Anhaeusser. Carl R., Roger L. Gibson, Alexander F. M. Kisters

Abstract - Intrusive features of cupriferous noritoids from the deeply eroded Proterozoic granite-gneiss terrane of the Okiep Copper District in South Africa illustrate the emplacement of basic magmas into a mid- to lower-crustal environment. The small, easterly trending intermediate to basic intrusions of the so-called Koperberg Suite display a wide variety of geometries, occurrence and emplacement modes, including dike-, sill- and plug-like bodies. Coeval granulite-facies metamorphism, partial melting and ductile deformation of country rock gneisses during intrusion of the basic magmas led to emplacement and dilation processes of the intrusions which differ significantly from those described for dikes and sills at shallow crustal levels. Regional tectonic stresses are largely negligible due to very low differential stress (?1 - ?3) during deformation and intrusion, which permits emplacement at high angles to the principal compressive stress and which follows favorably inclined structural anisotropies. Dilation of the basic intrusions is largely determined by compositional differences of host rocks and occurs by thermal erosion, i.e., assimilation of wall rock gneisses. Low length-to-width ratios of basic to ultrabasic dikes and predominantly diaper -like outlines of mesocratic bodies are indicative of low viscosity contrasts between the mafic magmas and high-grade metamorphic host-rock gneisses. Buoyancy-controlled ascent of the basic to intermediate intrusions is expressed by a broad compositional zoning of basic bodies with respect to the granite-gneiss stratigraphy. Various intrusion modes within the stratigraphic column of the granite-gneiss sequence reflect a lithological and structural stratification of the seemingly homogeneous granite-gneiss terrane.

Jan 1, 1994

By D. S. Campbell

THE chief factors influencing the decision to build the Big Missouri mill underground were the topography of the country and the climate. The location underground assured certain saving in the cost of operation, such as the hearing of the mill, shovelling snow, and handling ore, which, over a period of time, would offset the greater initial cost of the mill excavation and machinery installation underground, as compared with the cost of a like plant on the surface. At Gilman, Colorado, where conditions are somewhat similar, the Empire Zinc Company, at their Eagle mine, are treating their lead-zinc ore in a mill built entirely underground. Company officials made a study of this plant before proceeding with the mill at Big Missouri. LOCATION, CLIMATE, TOPOGRAPHY The Big Missouri mine is situated on the Upper Salmon river, 22 miles north of Stewart, B.C., which is at the head of Portland canal, a narrow natural channel which penetrates 100 miles inland from the coast into the Coast Range mountains. Stewart, the distributing centre for the district, is about 600 miles north of Vancouver. The Big Missouri claims lie on and down the sides of the Big Missouri ridge, which extends north and south between the Salmon River and Cascade Creek valleys. The ridge rises to an elevation of 3,600 feet, is about half a mile wide, and to the east slopes down to the Joker flats in Cascade Creek valley. The Big Missouri camp is located on the flats at elevation 2,800 (see Figure 1). Preliminary development of the property took place from this point with an adit driven under the ridge. The western side of the ridge slopes steeply down to the Salmon glacier at elevation 1,900. Ore found on the 2,850 level extended down, and, in order further to explore the ore-body, the 2,850 level was driven through to the west side of the ridge, a surface incline tramway was built, and a lower tunnel driven at elevation 2,350, five hundred feet below the original 2,850 level, from the west side of the ridge. This tunnel development avoided the necessity of sinking, which would have been costly, as the mine makes a great deal of water (see Figures 1 and 2).

Jan 1, 1938

By Huilan Yang, Feng He

This paper intends to introduce the development of copper smelting and converting technologies in China in recent years, with a particular emphasis on the introduction of various continuous converting technologies, and moreover, it analyzes the advantages and disadvantages of those technologies, including their impact on the downstream anode refining from different points of view. INTRODUCTION At present, many converting technologies are used in copper pyro-metallurgical plants in China, including Peirce-Smith (PS) converter, flash converting furnace, multi-lance based top blowing, bottom blowing and so on. These technologies have spanned a wide range of time. PS converter technology has been applied in copper smelters for many years and most of the blister copper have been produced by this technology; flash converting technology has been developed since 1990s and been maturely applied in several plants up until now; top blowing and bottom blowing technologies have been revived in China in the past decade and boast good environmental protection performance, energy efficiency, throughput capacity and short process flow. All of the said technologies have reference operations in treating high-grade matte. As more and more attention is paid to environmental protection globally and copper smelters continuously seek for cost reduction, it is necessary to share those converting technologies, especially those new converting technologies derived in China, with copper smelting practitioners in the world. This paper aims to analyze the advantages and disadvantages of various technologies from a macroscopic view and discuss their actual application effects, current developments and future improvements. BRIEF INTRODUCTION OF VARIOUS CONVERTING TECHNOLOGIES IN CHINA China has seen a rapid development in copper smelting industry in the past 30 years and has become the largest gathering place of copper smelters in the world, most of which are operating with PS converting furnace technology, however, with the increasingly strict environmental requirements of the Chinese government in recent years, the low-level pollution issue and the disadvantage of large gas exhaust amount per unit of copper of converting furnaces are particularly prominent.

Jan 1, 2019

By H. R. McCabe

"The study of a detailed series of structure and isopach maps of the Palaeozoic strata of southwestern Manitoba indicates that the principal Palaeozoic tectonic elements -the Williston Basin and Elk Point Basin -have been modified to a considerable extent by major tectonic features of the Precambrian basement. The principal basement feature is the break between the Churchill and Superior provinces, which coincides roughly with the Manitoba-Saskatchewan border. East-west-trending orogenic belts within the Superior crustal block may also be reflected to some extent in later Palaeozoic movements. In addition, the Superior crustal block, as a whole, appears to have had a slightly different response to the tectonic forces, giving rise to both basin subsidence and basin uplift. During periods of deposition, especially during Ordovician time, the Manitoba portion of the basin appears to have undergone a relatively higher rate of subsidence, whereas during periods of erosion relatively greater amounts of uplift and truncation have occurred. As a result, the depositional and erosional patterns for most of the Palaeozoic formations in southwestern Manitoba are somewhat anomalous relative to the regional basin framework.Some prominent Palaeozoic structures probably are the result of salt solution and differential compaction caused directly or indirectly by relatively minor tectonic movements related to Precambrian basement features. In particular, the prominent hinge line at the edge of the Devonian Prairie Evaporite salt basin may be due, in large part, to salt solution. Numerous other small structural lows, structural highs and isopach thicks, probably resulting from salt solution, occur along the salt edge and have been important in modifying and controlling Mississippian oil accumulation in the Daly-Virden producing area."

Jan 1, 1967

By Ali M. Ghazi, Ronald J. Goble, Lowell S. Whiteside

"Geerite (Cu1.6S) is a rhombohedral copper sulphide which occurs naturally in epitactic replacement of sphalerite; cell dimensions closely approximate those of the host sphalerite.Geerite-type structures can be produced by leaching digenite (Cu1.8S) in ferric sulphate solutions. X -ray diffract ion and electron microprobe studies indicate that eight metastable geeritetype structures can be produced, depending upon the concentration of f erric sulphate solution used and the duration of the each. Although compositions cluster on or near values observed for natural phases, optical properties indicate that we are dealing with polymorphs of these phases. Leaching of chalcocite (CU2Sj in dilute f erric sulphate solutions produces similar results. In contrast, leaching of chalcocite in more concentrated solutions seems to produce true analogues of natural minerals.During froth flotation, sphalerite is activated with a monolayer of floatable copper sulphide with the composition, CuS, of the mineral covellite. However, covellite is not significantly more floatable than sphalerite, and has an incompatible structure because of the presence of covalently-bonded atoms of sulphur. Leaching ofdigenite was used to produce a polymorph of covellite with a geerite-type structure, compatible with that of sphalerite. This polymorph has a flotational behaviour similar to copper-activated sphalerite, suggesting that the monolayer has a geerite-type CuS structure. IntroductionIn an ideal close-packed sulphide structure the distance between sulphur layers, D, is equal to 2R 2/3, where R is the radius of the sulphur atoms. In sulphides with covalently-bonded sulphur layers, such as covellite (Fig. I), D will be an average of the number of covalentl y-bonded and close-packed sulphur layers, weighted as to the relative number of each type of layer. Both D and R are spacings which are readily identifiable structurally and on X-ray diffraction patterns. Goblel has shown that for copper-iron sulphides with metal-to-sulphur ratios between 0 and 2 and copper-to-total metal ratio s between 113 and I there are strong correlations between composition and measured D and R distances (Fig. 2). D can be represented by a single empirical equation relating interlayer spacing to composition; R must be represented by three equations relating the radius of sulphur atoms to composition. One of these equations (R, in Fig. 2) represents ideal close-packed behaviour, the other two represent sulphur radii greater than (R1) or less than (Rh) the ideal."

Jan 1, 1988

By Anthony J. Deevy

"Abstract -The Magino gold mine is located 45 km northeast of Wawa, Ontario. There was limit­ ed gold production in the Iate thirties. The present operation was officially opened in October 1988 and produced gold until September 1992. It was a 635 tonnes per day, decline-accessed mine, with ore coming from several small blast hole and shrinkage stopes.The host for the gold is the Webb Lake granodiorite stock which was intruded into the Goudreau Lake Deformation Zone. This east-northeast-striking deformation zone overprints the generally east­ west-striking isoclinally folded metavolcanic and metasedimentary rocks, which make up the east end of the Michipicoten greenstone belt. The ore-shoots are controlled by dextral delatancy associated with the Goudreau Lake Deformation Zone. Shearing, bleaching and silicification accompanied the gold emplacement."

Jan 1, 1994

By Niklas Frank

Ore and waste transports form an integral part of any mining operation and represents a substantial portion of the mine´s total operating cost. Mine layout, truck fleet and size, production rates, haulage distances, shift schedules, maintenance strategies etc. are all important and not at all static variables. They all change during the life of a mine and interact in a dynamic way. It is therefore essential for the successful mine management to constantly analyse and optimise the mine's transport systems. Önnerlöv has recently conducted a life-of-mine haulage simulation project for Zinkgruvan Mining, a medium sized, underground zinc producer, located approximately 60 kilometers south of Örebro, Sweden. The main objective of the project was to analyse and optimise the investments required to provide ore and waste haulage under changing conditions over an +10- years period: Deepening of the mine, increased production rates, changed mine layout, changed truck fleet etc. A large number of scenarios has been tested in the simulation model in order to identify the "lowest cost per ton" solution. This paper comprises an introduction of Zinkgruvan Mining and a brief background to the actual project, a description of the simulation model, project conclusions and some useful hands-on tips for mining engineers and project managers how to run a successful simulation project.

May 1, 2003

By Paul Hughes

Purpose of Research ? What are the loading mechanics of paste against barricades? ? What is the capacity of the composite paste fill fences? ? Based on the loading mechanics of the paste, do the fill fences pose a risk of failure? Outline ? Glossary of Terms ? General Introduction ? Research Methodology ? Site Description ? Instrumentation Program ? Results ? Analysis ? Conclusions ? Recommendation for Future Work

May 1, 2008

By J. M. Gregg, C. J. Persellin, I. D. Somerville, E. A. Atekwana, K. L. Shelton

"Zn-Pb sulfide mineralization at Abbeytown mine and Twigspark quarry comprise the only known car¬bonate-hosted base metal sulfide deposits in the Sligo syncline, northwest Ireland. Limestone sedimentation occurred uniformly throughout the region during the Early Carboniferous (Mississippian) as observed by field relationships and lithofacies; however, petrographic and stable isotope evidence indicate that host-rock dolomitization occurred under different conditions at localities to the west and east of the Ox Mountains inlier, suggesting significant uplift and geologic isolation of these areas prior to dolomitization. Localized fluid flow systems are thought to be responsible for sulfide mineralization and associated epigenetic carbonate cements. West of the Ox Mountains inlier at Abbeytown, evidence of three geochemically distinct fluids are observed: (1) a lower-temperature, lower-salinity fluid (70°-130-°C, 4-9 wt.% equiv. NaCl); (2) a lower-temperature, higher-salinity fluid (70°-140°C, 15-24 wt.% equiv. NaCl); and (3) a higher-temperature, moderate-salinity fluid (165°-220°C, 8-14 wt.% equiv. NaCl). Similar fluid types were observed at the Twigspark deposit. The source of the higher-salinity fluid is likely seawater evaporated to near the point of halite precipitation. The higher-temperature fluid is thought to have been derived from deep circulation of basinal brines. It is speculated that mixing of the higher-salinity fluid with the high-temperature fluid was vital for ore formation at Abbeytown because fluid inclusions in sphalerite have homogenization temperatures and salinity values that fall along a mixing trajectory of these end member fluids. Also, areas where the high-salinity end member fluid is absent are barren of sulfides. Less complex fluid systems are indicated for sites east of the Ox Mountains inlier where no sulfide mineralization was observed. Data from base metal sulfide prospects in northwest Ireland indicate no connection with the regionally extensive flow system thought to be responsible for Zn-Pb deposits throughout the Irish Midlands.Les minéralisations en sulfures de Zn-Pb de la mine Abbeytown et de la carrière Twigspark sont les seules gîtes de métaux usuels à encaissant carbonaté connus dans le synclinal de Sligo, au nord-ouest de l’Irlande. Ces carbonates se sont déposés d’une manière uniforme dans la région au Carbonifère inférieur (Mississippien) tel que l’indiquent les relations de terrain et les lithofaçiès; les données pétrographiques et d’isotopes stables indiquent toutefois que la dolomitisation de l’encaissant s’est faite sous des conditions différentes aux localités situées à l’ouest ou à l’est de la boutonnière des Ox Mountains, ce qui suggère un soulèvement et une isolation géologique significative de ces secteurs avant la dolomitisation. L’action de systèmes de circulation locaux sont considérés être à l’origine de la minéralisation sulfurée et des ciments carbonatés épigénétiques qui leur sont associés. À Abbeytown, à l’ouest de la boutonnière des Ox Mountains, on note les effets de trois fluides géochimiquement distincts: (1) un fluide à basse température peu salin (70°-130°C, 4-9% poids équivalent NaCl); (2) un fluide à basse température fortement salin (70°-140°C, 15-24% poids équivalent NaCl); and (3) un fluide formé à plus haute température et salinité modérée (165°-220°C, 8-14% poids équivalent NaCl). Des fluides similaires ont été observés au gîte Twigspark. La source présumée du fluide le plus salin est de l’eau de mer amenée par évaporation près du point de précipitation de la halite. Le fluide à plus haute température est probablement dérivé de la circulation profonde de saumures dérivées d’un bas¬sin sédimentaire. Il est possible que le mélange du fluide à haute salinité avec celui à haute température ait joué un rôle central dans la genèse de la minéralisation d’Abbeytown parce que les températures d’homogénéisation et les valeurs de salinité des inclusions fluide"

Jan 1, 2009

By B. Y. Park

This paper develops a series of three-dimensional simulations for the Bayou Choctaw Strategic Petroleum Reserve. The U.S. Department of Energy plans to leach two new caverns and convert of one of the existing caverns within the Bayou Choctaw salt dome to expand its petroleum reserve storage capacity. An existing finite element mesh from previous analyses is modified by adding two caverns and increasing the size of existing Cavern 102. The structural integrity of the three expansion caverns and the interaction between all the caverns in the dome are investigated. The impacts of the expansion on underground creep closure, surface subsidence, infrastructure stability, and well integrity are quantified. The results show that from a structural viewpoint, the locations of the two newly proposed expansion caverns are acceptable, and all three expansion caverns can be safely constructed and operated.

May 1, 2009

By Marcin Ziemski

This paper reports on an energy efficiency analysis completed as part of a research project looking at energy reduction opportunities in minerals processing operations. The plant discussed is a gold production facility owned by Newmont Gold in the Tanami region of central Australia. Due to its remote location, lack of nearby gas pipeline or power grid, the operation has been completely dependent on diesel fuel for its electricity generation and transport needs. The mine and processing plant use electrical power at a rate of 12MW to 18MW, resulting in a monthly electricity cost of over US$1.5M. The high cost of diesel combined with an impending power generation capacity shortage drove Newmont to undertake the energy efficiency study. An energy audit of the plant showed opportunities for significant energy savings through the strategic use of waste heat, fuel replacement alternatives and renewable energy sources.

May 1, 2007

By Jim Wickens, Andy Cole, John Pekrul

"The roaster facility at Barrick Goldstrike Mine treats double-refractory sulfidic/carbonaceous gold ore. Prior to oxidation in the roasters, the ore is ground in two parallel dry grinding circuits utilizing 19’ Ø x 75’ double rotator mills. The design plant throughput was 12,000 dstpd. However, process improvements have significantly increased throughput rates by 25-50%. The current daily throughput record is 20,078 dstpd. Grinding circuit improvements contributing to this success include feed size reduction, ball size optimization, automatic ball charging optimization, and operating strategy changes. In addition to the changes already made, this paper discusses future optimization initiatives including on-stream particle size analysis and “real-time” ore hardness determination techniques.INTRODUCTIONBarrick Goldstrike Mines is located 29 miles Northeast of Carlin, Nevada, USA. Through 2001, the property has produced over 23 million ounces of gold making it one of the premier gold operations in the world.Prior to Barrick’s ownership, the property began producing gold from a small heap leach operation in 1975. The small-scale heap leach production continued through 1986, and in January 1987, Barrick acquired the property. Increased exploration activity by Barrick significantly increased gold reserves. In August 1988, a 4,500 dstpd mill facility was commissioned to treat high grade oxide ore. Also, heap leach operations had significantly expanded. In 1990, the mill was expanded to 6,000 dstpd, and the first autoclave was commissioned to treat refractory sulfide ore. By the end of 1996, the mill and pressure oxidation facility had expanded to 16,000 dstpd and heap leaching had ceased as oxide reserves were exhausted. In 2000, a roaster facility was commissioned to treat double-refractory sulfidic/carbonaceous ore."

Jan 1, 2003

By Richard J. Kolada, Ian R. Muirhead

"This paper reports on a CANMET-funded examination of less conventional underground coal mining methods. These methods are documented and those that show the most promise for application to western Canadian conditions are discussed in detail.IntroductionIn recent years, mining considerations and economics have encouraged a transition from underground mining to surface mining. However, a change in market conditions or the development of superior underground mining methods may reverse this trend . Should this happen, the industry must be quick to respond and have information available on the latest developments of underground mining technology. In time, deposits of high-quality coal, which are easily accessible to surface mining, will be depleted and a change to underground mining methods will require consideration. The economic transition point between surface to underground will be a major determinant in maintaining a competitive edge. For these reasons, it is important to keep abreast of improvements in underground mining methods. To meet this objective, CANMET awarded a research contract to Monenco Consultants Limited, to investigate unconventional underground mining methods that show a potential for western Canadaoi. This paper presents the results of this investigation."

Jan 1, 1988

By J. B. Gilliatt

The discovery of ore at Wabana was quickly followed by the mining of the ore beds where they outcropped in the land areas. The third phase, as at present carried out, consists of extensive submarine operations, which were commenced in 1908, by driving a pair of slopes out under Conception bay, opening. the mine for a distance of a mile and a half from the shore. Two other slopes, now driven just beyond the shore line, are being sunk to the submarine territory where, it is generally recognized, huge reserves of ore lie under the bay. The process of erosion of the land, the solution and re-disposition of its iron-bearing minerals in thick beds of ore have been considered elsewhere, but these bear small relation to the physical forces which have acted upon the ore-beds since the deposition of the strata. These physical changes are made manifest by jointing and cleavage and faulting. The discussion of these, the relation they bear to each other, and to the folding of the strata, is the purpose of this article. For the benefit of those who may not be familiar with the formation in which the ore occurs, I include a general summary of the geology of Be!! island and its environs; also a description of conditions that prevailed during the period of deposition, so that the reader may appreciate some of the later changes that took place during or subsequent to its emergence from the sea, and the folding or tilting of the strata to the position it now occupies.

Jan 1, 1924

By D. Allen

Faced with decreasing ore grades and harder ores, many mines today are forced to become more efficient with their approach to processing. Variability in ore hardness, mineral liberation, reagent consumption, sliming, and leach responses are all a function of the minerals present and their concentration. Modern semi-automated X-ray Diffraction (XRD) analyses using Rietveld refinement techniques, in conjunction with high speed quantitative Near Infrared (NIR) analyses, provide reliable quantitative mineralogical ore profiling. By the implementation of XRD with NIR, mining, milling and leaching operations no longer need to be dependant on visual estimates for GeoMetallurgical Modeling and are provided with a valuable forecasting and production control tool. This paper will illustrate the development, plant implementation and application of XRD and NIR at several copper operations.

Jan 1, 2007

By G. V. Sirianni, G. E. Viens, R. A. Campbell, G. N. Banks

A combination shaft-electric furnace for the smelting of ores and the melting of metallized feed is being developed at the Mines Branch. When iron oxide pellets are smelted in this unit, they are preheated and partially reduced in the shaft before being transferred to the electric furnace where smelting is completed. Also, limestone flux added with the pellets is-preheated and calcined in the shaft. It has been demonstrated that, in smelting iron oxide in this unit, the throughput of the 250-kva electric furnace can be approximately doubled and the amount of electrical energy required can be very significantly reduced when the shaft furnace is operated in conjunction with the electric furnace. These benefits are achieved mainly by utilizing the sensible heat and latent energy contained in the arc furnace off-gases.

Jan 1, 1971

By B. Andreaus

In spite of tremendous efforts in research and development of polymer electrolyte fuel cells (PEFCs), essential properties of the actual catalyst material, supported Pt or Pt-alloy nanoparticles, are not yet well understood. Fundamental understanding of the catalyst structure and the prevailing kinetic mechanisms is, however, of utmost importance for further progress. In the present study, we investigate catalyst activity for CO oxidation from a theoretical point of view. Electrochemical CO oxidation serves as an important test reaction for the study of the fundamental properties of supported Pt nanoparticles. Recent experiments have revealed strong effects of catalyst particle size and supporting material on catalytic activity. It was found, that the activity towards CO oxidation decreases significantly when the particle diameter drops below 2.5 nm. We perform kinetic Monte Carlo simulations of CO oxidation on supported catalyst particles to elucidate this particle-size effect. The simulations are based on the active site concept, highlighting the role of active site formation and finite surface mobility of adsorbed electroactive species for catalyst activity. For comparison with experimental results, potential step experiments were simulated. The Monte Carlo simulations consistently reproduce effects of particle size and electrode potential found experimentally. In comparison with our simulations, analytical mean field models and nucleation and growth models exhibit inferior agreement with experimental data. In summary, our findings support an oxidation mechanism via active site formation. The reason for the slow reaction kinetics on catalyst particles with diameters below 2.5 nm is a rather low CO surface diffusivity. The rates of active site formation, diffusion and CO oxidation via recombination with adsorbed OH can be determined from the simulations.

Jan 1, 2005

By L. A. Melis, J. W. Rowson

"Cluff Mining operates the Phase II uranium mine and mill at Cluff Lake, northern Saskatchewan. During the Phase I operation, uranium tailings were generated by acid leaching of a gravity concentrate and high-grade ore for uranium recovery. The pre-treatment gravity process, as well as the high-grade nature of the ore, led to a concentration of gold in the tailings which justified the installation of a small circuit to recover the contained gold. The operating circuit consists of tailings repulping, grinding, cyanidation, carbon-in-pulp, gold recovery, and cyanide destruction by acidification, volatilization and re-neutralization. The process is described and typical operating parameters are provided. 1.0 INTRODUCTIONCluff Mining, a Saskatchewan partnership, is owned 20 percent by Saskatchewan Mining Development Corporation (SMDC) and 80 percent by Amok Ltd./Ltee. (Amok), manager and operator of the partnership.The current operation includes the Phase II uranium mining and milling facilities, located at Cluff Lake 700 km north of Saskatoon, capable of processing 300,000 tonnes of ore to produce about 4,000,000 lbs. U308 (1500 tonnes of uranium) per year.The Phase I operation was initially established to process the very high grade ""D"" uranium orebody from 1980 to 1983. The leach tailings from the operation Phase I mill operation were found to contain elevated levels of gold. These high gold values were partially due to the gravity pre-concentration step included in the uranium recovery circuit, and to the naturally high levels of gold associated with the uranium mineralization in the ""D"" orebody."

Jan 1, 1988

By W. C. Ferguson

"This paper could be more appropriately titled ""The Application of Vacuum Filters to Underground Minewater Treatment. in a previous paper co-authored by the writer (1) the history and development of minewater treatment at the Sudbury District Operations of the International Nickel Company was outlined. It is the intention of this paper to dwell more specifically WIth the the application of the vacuum filter to a problem found in most, if not all, underground mining operations. In the preparation of this paper the writer has made liberal use of the illustrations and text of the paper previously noted.Last year we heard Mr. Nemeth discuss the basic mechanisms involved in vacuum filtration (2), and today Yr. Cunliff has exposed us to the selection of the filter media (3). I will now briefly review the various vacuum filter designs that generally lend themselves to metallurgical dewatering applications.DRUM FILTERSThe revolving drum-type which filters on its outside periphery is illustrated in Fig. 1. This is the Oliver or Drum filter and represents the first commercially available continuous vacuum filter. The original design dates back more than 50 years, but with the exception of the method of discharge, is identical to the units being marketed today. This filter is generally applied to slow filtering slurries. The cake may be discharged in several ways; strings, scraper blades, rolls or by passing the filter cloth over a small diameter discharge roller (belt discharge).THE DORRCO FILTERThe revolving drum type which filters on its inside periphery is illustrated in Fig. 2. Here the slurry lies in the drum and the cake discharges through a chute or conveyor. This type of filter is most often applied to fast-filtering slurries.THE DISC FILTERThe revolving filter which filters on the vertical plane of the disc is referred to as the Disc or American-type filter. This represents the most inexpensive design in terms of cost per square foot of filter area. This filter is widely applied, but is probably more suitable for slower draining pulps."

Jan 1, 1971