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By G. E. Bogin, C. Strebinger, J. F. Brune

"Evidence shows that methane gas emanates from the mined-out area or gob of a longwall coal mine and can travel towards the working face, posing an explosion risk. Since the gob consists of varying levels of compacted rock, many researchers have modeled fluid flow through the gob as a Darcy-type porous media with a specified porosity and permeability. When studying methane gas explosions near the gob fringe, the Darcy flow assumption may not be applicable to describe the methane flame interaction with the gob. Computational fluid dynamic studies were performed modeling methane flame propagation across a simulated gob which was modeled as both a Darcy porous medium and as discrete rock objects with varying sphericity. Modeling the gob as a Darcy porous medium results in unrealistic methane flame propagation since the porous media assumption does not consider any differences in rock size and/or distribution. Additionally, the porous media model does not allow for ignition within and subsequent flame propagation through the porous medium, which must be modeled to understand the potential for methane gas explosions in the gob area. Modeling the gob as discrete rock objects produces more realistic methane flame dynamics and agrees with experimental observations. Modeling results show flame propagation across circles, hexagons, and squares, meant to represent rock rubble in the gob, produce different levels of turbulence which affects methane flame propagation velocity. This research demonstrates that modeling methane gas explosions in a longwall coal mine environment, specifically near the gob area, requires modeling obstacles, such as rock rubble, as discrete physical objects to capture the complex coupling of fluid dynamics, thermodynamics, and heat transfer. INTRODUCTION Although there are methods to mitigating methane accumulations in a longwall coal mine, explosive gas zones (EGZs) of methane and air may exist and pose an explosion risk to nearby miners and equipment (Brune, 2014) (Karacan, Ruiz, Cote, & Phipps, 2011). In the event of an explosion, the resulting methane flame and pressure wave can be catastrophic as evidenced by the Upper Big Branch explosion in 2010 that killed 29 miners (Page, et al., 2011). Since the mining process is transient, it is difficult to determine exactly where these EGZs exist, but investigative reports show in many cases, these EGZs can be near the working face, behind the shields, or within the gob area (Brune, 2014) (McKinney, et al., 2001). Additionally, miners have recounted seeing flames moving back and forth within the gob and under the roof supports (McKinney, et al., 2001) and in other cases, anecdotal evidence of hearing small pressure pops deep within the gob area (Brune, 2014)."

Jan 1, 2019

By W. J. Kuit

"Complex facilities which provide for the collection, management and treatment of effluents emanating from the Sullivan mine and concentrator tailings were made operational in October 1979. Key features of the system are the use of upgraded tailings ponds for the storage of up to 800 million litres of metals-contaminated effluents, a treatment plant employing lime in a high-density sludge process and a sludge-impoundment facility designed for maximum long-term environmental safety. The completed works are capable of satisfying a difficult range of operating requirements imposed by highly variable weather conditions, drainage flows and soluble metals loadings. Final capital expenditures for the project approached $10 million and annual operating costs are about $0.8 million.This paper discusses the Kimberley effluents treatment project and the major considerations in its development. The treatment process, major plant equipment and initial operating experience are also described.IntroductionCominco Ltd. has worked the Sullivan orebody at Kimberley, B.C. since 1909 and has operated a concentrator some 5 km distant from the mine since 1923. Over the last 70 years, in excess of 120million tonnes of ore have been mined, and production continues at an average rate of 6,500 tonnes per day. It is a well-known fact that the contribution of this operation to Canada's mining industry and, in particular, Cominco's development has been significant. However, this success has not been without some undesirable side effects.Unfortunately, the Sullivan is one of only a few major Western Canadian orebodies which may be classed as ""acidic"" in nature. That is, the primary economic minerals, galena and marrnatite, are enclosed in a siliceous host rock with abundant pyrrhotite, but with little or no accompanying alkaline gangue minerals such as calcite and dolomite. The unavoidable consequence of mining such an ore is that contact with air and water generates an acid mine drainage containing various soluble metals orginally present as minerals.This problem also arises in the concentrator's tailings ponds, which, in the case of the Sullivan, are two separate impoundments of different materials. The 1,100 tonnesl day of ""iron"" tailings are primarily pyrrhotite which is surplus to the requirements of a separate operation that produces sulphuric acid as an intermediate to phosphate fertilizers. Inert gangue minerals with only a minor sulphide content are the main constituents of the 1,200 tonnes/ day of siliceous tailings. Corresponding to the relative proportion of sulphides in the solids, the decant from the iron tailings is substantially more contaminated than that from the siliceous pond."

Jan 1, 1980

By H. C. Gunning

SOME small vanadium-bearing deposits on the west coast of British Columbia about 100 miles north of Vancouver are of interest for several reasons. They are of a type that is, so far as we know, unique. They are difficult to identify as being vanadiferous so that, unless they are described, other similar deposits could easily pass unrecognized. Furthermore, although none of them has as yet been proven to be of commercial proportions, no good reason is apparent why larger, and therefore valuable, deposits should not occur under similar geological conditions. The original discovery on Quadra island was made in 1932 and has been recorded by H. V. Ellsworth and H. C. Gunning (l). Since 1932, prospecting in the area has revealed other similar deposits, one about a mile south of the original and another some ten miles to the east, near Menzies bay on Vancouver island. The Quadra Island showings are a mile and a half north of the head of Gowland harbour, a small inlet that is easily reached by gas boat from Campbell river, about four miles to the southeast on Vancouver island. The deposits were examined by the writers in the spring of 1943 in connection with field work sponsored by the Department of Geology, University of British Columbia. We are indebted to Mr. G. A. Dirom and Mr. Lothrop, of Vancouver, for helpful data on the Menzies Bay deposits, and to Dr. V. Dolmage for making a brief trip to Gowland harbour and discussing the deposits.

Jan 1, 1944

By Desmond Y. M. Lee

This paper presents a procedure to prepare input for the computerized pit design system at Iron Ore Company of Canada. The procedure is simple and requires very little training. Also, it is general enough to accept both bench (horizontal cross section) maps and section (vertical cross section) maps. The output of this procedure is data which represent blocks of ore and waste with dollar values based on mineral content. The ultimate pit design is presented in printer-generated graphs, with numbers indicating the depths of pit bottom walls. Roads are added manually by the engineer with the aid of other computer programs. Section maps and bench maps are also printed as part of the output of the ultimate pit design.

Jan 1, 1978

By Matt Manson

?? Current Exploration and Assessment ?? Overview of Potential Development ?? Infrastructure ?? Opportunities and Challenges ?? Renard? 1-10 kimberlite pipes and ?Lynx-Hibou? kimberlite dyke system within ?Foxtrot? property ?? 50/50 Joint Venture between Ashton (a subsidiary of Stornoway) and SOQUEM ?? Discovered 2001-2003 ?? Québec is routinely assessed as one of the top mining jurisdictions in the world ?? Agnico-Eagle Mines Ltd. Is Stornoway?s largest shareholder and a leading mine developer in Québec

May 1, 2008

By Kurt D. Mitchell

"This paper discusses general application for A C variable frequency drives in the mining industry. A review of induction motors characteristics, adjustable frequency controller fundamentals, and three commonly used controllers is presented. General application guidelines for the three different types of controllers; variable voltage input , current source input and pulse width modulated are then reviewed in detail, and an example of the economic benefit of this technology is discussed. IntroductionSoon after static DC variable speed drives were well established in industry, a need for static AC variable speed drives was seen. The first technical papers describing possible systems appeared in the mid-1960s, with commercially available units arriving in the early 1970s. Without exception, static AC drives are substantially more complex than their DC counterparts, but they have some very desirable properties. As compared to DC motors, AC motors are less costly, physically smaller, more reliable, require less maintenance , easily sealed, have good load regulation, are able to run at higher operating voltages, and have little danger of over-speed runaway . These properties are particularly desirable in explosion-proof, submersible or difficult accessibility applications.Variable speed AC drives are now a proven technology. available in packages from Sub-horsepower to hundreds of horsepower, from 115VAC to 4160 VAC. This paper covers the principles of operation of three common types of controllers, application criteria, motor consideration and finally an example of how an AC variable speed drive can pay for itself in terms of energy savings."

Jan 1, 1986

By R. W. Lawrence

"Biological leaching can be used to enhance the recovery of gold and silver from refractory ores, concentrates and tailings. The method liberates precious metals associated with sulphide minerals such as pyrite and arsenopyrite making them amenable to cyanidation. The chemistry and features of biological preoxidation leaching is discussed. A summary of the results obtained on various ores, concentrates and tailings is presented.INTRODUCTIONRefractory precious metal ores in which gold and silver are finely disseminated in sulphide minerals such as pyrite and arsenopyrite are becoming more important to the mining industry. This is due both to a depletion of simpler, free-milling ores and to a significant increase in the price of gold in recent years. Whereas many ores can be directly cyanided with gold solubilizations over 90% obtained, the refractory ores respond poorly to direct cyanidation and require decomposition of the precious metal-bearing sulphide minerals to increase recoveries.Decomposition of sulphides by oxidation prior to cyanidation can be carried out by several means. The oldest method is roasting which removes unwanted ore constituents by high temperature oxidation and volatilization. In Canada, for example, roasting is used at Giant Yellowknife (Connell and Cross, 1981). Another method gaining increasing acceptance is pressure hydrometallurgy which uses aqueous oxidation conducted at high temperature and pressure. Homestake Mining Company have recently completed construction of a plant incorporating pressure oxidation at their Mclaughlin property in California (Guinivire, 1984)."

Jan 1, 1985

By Shinji Shirakawa

The gold wire bonding technology is widely used for electrically connecting aluminum pads on IC devices to external terminal of semiconductor. In 1960?s, the tensile strength of gold bonding wire was about 100 MPa only. However, recently the wire with 300 MPa in strength has been developed. Since the gold bonding wire was started to use for IC package in early 1960?, the many types of gold bonding wire has been developing continuously in order to meet market?s needs, such as high density, small size and thin type of IC packages. Moreover, electronic equipments were used in automobile applications and also demanded good reliability under severe temperature environment. Thus Au-Pd alloy wire has been introduced instead of the wire with 4N(99.99wt%) purity gold to provide excellent reliability in Au-Al bond interface. The phenomena at Au-Al interface in the high temperature storage have been already explained by several studies as follows. There are five phases of inter metallic compound (IMC) between gold and aluminum. Just after bond gold ball on aluminum pad, Au5Al2 phase was formed and occupied almost all of IMC area. During high temperature storage test, Au5Al2 phase transformed to Au4Al phase, then this phase was corroded by Bromide (Br) ion that was isolated from molding resin. Thus the reliability between Au and Al degraded. In case of Au-Pd alloy wire, the concentrated palladium phase (Au-Pd-Al) was formed at the interface between Au alloy ball and Al pad. The Au-Pd-Al phase prevented from transforming between Au and Al, therefore Au5Al2 phase was hard to transform to Au4Al phase. Consequently the reliability at the interface between Au alloy ball and Al pad was less degradation. However, in recent study using several advanced analysis technique, Au4Al phase was found at the interface between Au alloy ball and Al pad same as the case of conventional gold wire (4N purity gold bonding wire). It was suggested that the formation of concentrated palladium phase (Au-Pd-Al) related the excellent reliability at ball bonding process.

Oct 1, 2003

By Dave Marsh, John Goode, Niels Verbaan, Kevin Bradley, Henrie Notzl

The mineralogy of the Avalon Nechalacho deposit is complex with significant fractions of HREEs, Zr, and Nb found in refractory minerals such as zircon and fergusonite. Sulphuric acid baking followed by water leaching can be used to extract REEs from flotation concentrates, but acid baking does not completely "crack" the zircon and fergusonite, so the extractions of Zr, Nb, and HREEs are not high. An alternative flowsheet has been developed that is able to obtain significantly improved extractions of HREEs, Zr, and Nb from flotation concentrates or acid bake residues. This is accomplished by cracking the zircon and fergusonite minerals with caustic soda at high temperatures, followed by water washing to recover excess caustic soda and soluble sodium silicates and phosphates. REEs, Zr, and Nb in the solid residue can then be solubilized with HCl or H2SO4. This paper highlights some of the findings from an extensive laboratory program and discusses several flowsheet implications.

Jan 1, 2014

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By D. M. Hausen

"Refractoriness in Carlin-type gold ores results mostly from fine locking of gold in pyrite, locking in various gangue phases, notably quartz, and a ""preg robbing"" condition attributed to organic carbon. All three conditions may occur in any given deposit, including Newmont &apos;s Carlin and Gold Quarry deposits in Nevada, where types of ref ractoriness occur locally in minor amounts.Measurements of specific gravity, water absorption and screen size distributions of gold in alteration rock types from Gold Quarry show transitional changes from siliceous cherts through decreasingly silicified and increasingly argillized siltstones.Low permeability of siliceous ores contributes to ""size dependent"" refractoriness in cyanidation test work. Colligative physical and chemical measurements demonstrate that silicified cherty ores are difficult to grind, poorly permeable, and less amenable to cyanidation. Refractoriness in pad or column leaching of coarsely crushed siliceous siltstones and cherts is shown to correlate with interrelated measurable mineralogic and physical parameters.IntroductionMetallurgical treatment of variably amenable and refractory types of gold ore may be guided by both analytical and mineralogic data on the interlocking of gold (microscopic an d sub- microscopic) in assorted gangue/sulphide phases. Most oxidized ores from the Carlin gold mine, north of Carlin, Nevada, are amenable to direct cyanidation. The permeability of most oxidized ores from Carlin coupled with the fine size of the gold < 1.5 um) yields rapid extractions and high recovery without fine grinding.Small portions of the Carlin ore body, and also the nearby Maggie Creek and Gold Quarry orebodies, are less amenable to cyanidation, and are classified as refractory. Refractory conditions may be attributed mostly to the association or interlocking of gold with pyrite and /or microcrystalline quartz or chert, and also by the adsorption of leached gold by deleterious forms of carbon, termed ""preg-robbing"" carbon. Each of these conditions are described and defined, with emphasis on a form of silica-locking, which has been referred to as "" size dependent"" refractoriness."

Jan 1, 1985

By Flavio Rojos-Tapia, Samuel Sánchez-Pino, Marcelo Fernández-García, Samuel Sánchez-Baquedano, Rainer M. Imhof

"Pneumatic flotation was introduced to the Chilean copper mining industry in 1993 by Ingeniería de Minerales S.A., being implementation in 1994/95. The technology is based on the designs and development of Dr. Rainer Imhof from Germany and from Chilean copper processing experience.Pneumatic flotation has been successfully used for sulphide and oxide copper minerals and copper slag, iron ores (reverse flotation), gold and promising results with molybdenum as product. Extremely hard conditions were applied in flotation process such as roughing, cleaning, scavenging. Pneumatic flotation can be applied for any type of mineral which has to be separated by flotation. Even very dense and heavy slurries can be processed, the range of the particle sizes to be collected is very wide, and the number of cleaning stages needed normally is one in our experience until now.The good performance of the technique can be explained by the high gas hold-up and the very effective micro-turbulences which boosts the attachment to the bubbles changing dramatically the flotation time concept. Some economic high lights are: less energy consumption, less maintenance costs, simple and reliable to operate and it is required a small area to install the circuits.As a result of the Chilean mining industry experience, it can be concluded that the pneumatic flotation can be regarded as an excellent alternative to the conventional way of Mineral Processing.INTRODUCTIONDerived from seventies, works in Germany about pneumatic flotation with Prof. Simonis (Technical University of Berlin) and Prof. Bahr (Technical University of Clausthal), it has been developed an interesting flotation technology in Mineral Processing, with the designs developed by Dr. Rainer Imhof, who has been known for more than ten years (Imhof, 1998) by his contribution at Ekof, KHD, Allmineral and the actual company Maelgwyn Mineral Services where he is a Technical Director. Ingeniería de Minerales S.A. has been working ten years deeply involved with the technology developed by Dr. Imhof and is more than ten years experienced with pneumatic flotation, from Wits University and Mintek in South Africa (Sánchez, 1990), (Sánchez, 1990)."

Jan 1, 2003

By O. A. Ojo, O. A. Idowu, N. P. Wikstrom, M. C. Chaturvedi

Transient Liquid Phase Bonding (TLP) of a Nickel base superalloy, Inconel 738, was performed to study the influence of holding time, filler gap size, and temperature on the joint microstructure. Insufficient holding time for complete isothermal solidification of liquated insert caused formation of eutectic-type microconstituents along the joint centerline region. An increase in the eutectic thickness with increase in initial filler gap size was observed in joints prepared at a constant temperature and holding time. In agreement with prediction by conventional TLP diffusion models, an increase in bonding temperature for a constant gap size, resulted in decrease in the time, tf, required to form a eutectic-free joint by complete isothermal solidification. However, a significant deviation from these models was observed in specimens bonded at and above l 175°C. A reduction in isothermal solidification rate with increased temperature was observed in these specimens, such that a eutectic-free joint could not be achieved by holding for a time period that produced complete isothermal solidification at lower temperatures. Considerable enrichment of the liquated insert with base metal alloying elements at higher temperatures is suggested to be an important factor contributing to the observed departure from conventional TLP prediction.

Jan 1, 2006

By Alfred W. G. Wilson

MR. F. E. LATHE: In studying any subject whatever, one should at least occasionally stand back from the canvas, as it were, and take a broad view of the picture. It is such a view of the subject of industrial minerals that Dr. Wilson has given us today, and, in consideration of our efforts to utilize Canada&apos;s resources to the utmost in the present emergency, it seems most timely. I shall confine my remarks on the subject to the resources of the atmosphere and hydrosphere. We seldom stop to realize our dependence upon the atmosphere, not merely as a source of the oxygen we breathe but also of other indispensable elements. As recently as the beginning of the present century, grave concern was felt lest the rapidly increasing population of the world should ultimately starve for lack of the nitrogen required for crop growth. I recently noticed a reference to the Scientific American for March, 1890-just fifty years ago-in which an account is given of work on the fixation of nitrogen, which, said the article, "leads to the conclusion that while cyanides and ammonia may be thus produced experimentally, there are as yet insuperable difficulties in the way of adapting those methods to industrial purposes". Y et, in the early part of the present century, the development of the arc, cyanamide, and synthetic ammonia processes of nitrogen fixation was such as to remove, for all time to come the possibility of a shortage of nitrogen. Today, the atmosphere is by far our greatest source of nitrogen, and the capacity of the nitrogen fixation plants of the world is at least 4,000,000 tons annually-much more than can at present be utilized. Pure oxygen or oxygen-enriched air offers great possibilities in metallurgy and industrial chemistry, but, so far, little application has been made. In a paper presented to the Institute in 1926, 1 pointed out the theoretical savings which could be effected by the use of oxygen in burning carbon-when the gases pass off at 2,460°F., the fuel saving is no less than 50 percent. The use of oxygen on a commercial scale is intimately tied up with the question of refractories, but we should not forget that the possible changes in metallurgical practice by the use of oxygen are truly of revolutionary character.

Jan 1, 1940

By Dan Zou, Ji Chen, Deqian Li

"Bayan Obo mixed RE concentrate is the largest RE source in the world. RE elements occur dominantly in bastnaesite and monazite. This paper describes a clean and green technique for processing Bayan Obo mixed rare earth (RE) concentrate. A two-step oxidation method can lead to the effective recovery of REs, thorium (Th), fluorine (F) and phosphorus (P). Ce has a property of valency change, enabling the separation of it from other RE(III) elements. Making use of the interactions of cerium (IV) (Ce(IV)), F and P, a new extraction system was created to separate Ce(IV) effectively from other RE(III) while recovering F, P and Th by complexing F and P following the oxidation of Ce(III) to Ce(IV). The method includes two parts. Firstly, bastnaesite is oxidized by air roasting and sulfuric acid leaching. And then a first leach liquor containing Ce(IV), F and P is obtained. Secondly, monazite was converted into REhydroxide through alkaline attack and then Ce(III) in the RE-hydroxide was oxidized into Ce(IV) by wetair oxidation. After sulfuric acid leaching the oxidized RE-hydroxide, a second leach liquor is obtained. The two parts of leach liquor containing Ce(IV), F and P are then extracted by Cyanex923 to obtain CeO2, CeF3 and CePO4 based on the complex of Ce(IV) with F and P. The raffinate was further extracted by the primary amine N1923, and Th-product was recovered as ThO2. The RE elements recovery yield during the whole process is greater than 92%. The new technique not only provides a new way for Bayan Obo RE ore utilization, but also avoids resource waste and environment pollution.INTRODUCTIONRare Earths (REs) refer to lanthanides, including scandium and yttrium. Owing to the similar structure and property of RE(III), it is difficult to separate them from each other, especially for the adjacent elements. According to the United States Geological Survey, in 2010, the whole world has about 142 million tonnes of rare earth reserves. In that, China ranks the second with 22% following Brazil which ranks first with 32% (Cheng, 2011). There are three main RE ore types in China with about 80% mixed ores in Bayan Obo, 10% bastnaesite ores in SiChuan and ShanDong province and 2.9% ion adsorption ores in Southern China. Bayan Obo mixed RE concentrate consists of bastnaesite and monazite. The concentrate contains CeO2/_REO of 50% and there are 7–8% F, 4-6% P and 0.2–0.3% Th."

Jan 1, 2016

By M. Okada

Consumption of refined copper in Asia, especially in China and India, has soared, and the copper price is at its historic height. New smelters and refineries have been built in the region with state-of-the-art technology to meet the unprecedented demands. Supply of copper concentrate, on the other hand, has fallen short of the growing demand for concentrate by the smelters and refineries with expanded production capacities. The shortage of copper concentrate is attributable to the delay in the mining development, caused by the prolonged price slump of before 2005. The mismatch between supply of concentrate and smelting and refining capacities may cause disorderly movement of copper price, and hamper the sound development of the industry. The recent high copper price may prompt substitution with alternate materials. With electrical and thermal conductivity and workability, copper is one of the most customer-friendly materials. It is regrettable for both customers and suppliers if the high copper price would become an impediment to promoting copper use. Some outdated and environmentally unfriendly facilities still operate. In view of recent lower-grade copper concentrate with higher sulfur content, these facilities must reform their equipment to environmental-responsive one. The current level of per capita consumption of refined copper in Asia shows that the demand of copper will further grow. It is necessary to realize stable supply of refined copper and stable copper price, to help developing countries including China and India to economically take off. Hence, it is essential that the development of the copper industry be accompanied by environmentally friendly facilities, and harmoniously increased capacities between mining and smelting and refining.

Jan 1, 2007

By A. Singh

Two alloys Mg96.9Zn2.7Ho0.4 and Mg93Zn6Ho have been processed by direct extrusion at 300°C and 200/230°C to produce various microstructures containing icosahedral quasicrystalline phase with different grain sizes. The alloys were mechanically tested in tension and compression. The mechanical properties were related to the grain size and microstructures studied by transmission electron microscopy. The extruded alloys showed a mixture of nano-sized icosahedral and monoclinic Mg4Zn7 phase, as well as icosahedral phase particles a few hundred nanometers in size distributed in the matrix. Coarse icosahedral phase particles several micron in size also remained after extrusion. The alloys Mg96.9Zn2.7Ho0.4 and Mg93Zn6Ho extruded at the same temperature of 300°C produced very different grain sizes of 15 and 3 µm, respectively. The alloy Mg96.9Zn2.7Ho0.4 extruded at 200°C and Mg93Zn6Ho extruded at 230°C produced grain sizes of 0.7 µm and 1.5 µm, respectively. Both the alloys showed yield stresses of about 300 MPa in both tension and compression with elongations of about 18%. Hall-Petch parameters are calculated for the alloys.

Jan 1, 2006

By S. Ivanova

The results presented in this paper show that the gold solution dilution is a key parameter to control the dispersion of gold on ?-Al2O3 the selected support. The variation of concentration leads to changes in pH which modify the nature of gold complexes from HAuCl4 formed in the solution. These complexes are presented. Some of them (AuCl3(OH)- and AuCl2(OH)2 -) react with the surface of alumina and give interesting interaction. AuCl2(OH)2 complex has been considered as an ideal complex because of the strong anchorage of a bidentate species on the alumina. This complex is formed mainly in a solution of gold with a concentration of 10-4 M giving a pH of 3.5-4.5. The nature of the anchorage and the amount of chlorine, has an influence upon the formation of Au-Cl bridges which modify the dispersion of the gold on alumina of the final catalyst as shown by TEM.

Oct 1, 2003

By T. Xue, A. Singhal, D. Wrana, I. Mihaylov

"At Vale's Thompson Nickel Refinery, the copper and arsenic in the nickel electrolyte are removed by precipitation using H2S, generating a sulphide precipitate containing about 40% Cu, 8% Ni, 2 to 4% As and 30% S. This residue has been typically stored in impoundment ponds within the plant site. Various options for reprocessing it have been investigated over the years. One of the options involved oxidative pressure acid leach, whereby over 95% Cu, Ni and As were extracted. More recently, an atmospheric alkaline sulphide leaching process for selective removal of 70 to 90% As was developed and mini-plant tested. After alkaline sulphide leaching, the dissolved arsenic is precipitated as stable basic ferric arsenate (BFA) with the addition of ferric sulfate, while the low-arsenic Cu/Ni sulfide is suitable for processing in Vale's operations elsewhere in Canada.INTRODUCTIONVale’s Thompson Nickel Refinery was commissioned in 1961 and currently it has the capacity to produce about 56,700 tonnes per year of electrolytic nickel as cathode slab and rounds products. A sulphate and chloride mixed electrolyte is used in the Thompson refining process and it typically contains 75 to 85 g/L Ni, 50 to 60 g/L Cl, 90 to 120 g/L SO4 2-, 25 to 30 g/L Na and 8 to 9 g/L boric acid. The main impurities in the Thompson anolyte are copper, cobalt, arsenic, iron and lead.The simplified Thompson electrolyte purification flowsheet is shown in Figure 1 (Oliver & Wrana, 2009, Goble & Chapman, 1986); it consists of precipitation of copper, arsenic and lead with H2S, followed by nickel replenishment with ground matte and acid and removal of cobalt and iron with Cl2 and NiCO3."

Jan 1, 2012

By R. Stauffer, S. Lindsay

"Sherritt Gordon Mines Limited utilizes pressure hydro-metallurgical techniques to recover nickel, copper and cobalt from su1phidic concentrates, mattes and various other metal-bearing materials.A brief description of the nickel refinery operation is given. In the nickel refinery process, an ammonia pressure leach is employed to treat the feed materials to dissolve the non-ferrous metals as their respective ammine complexes. The resulting leach solution goes through a series of steps which removes copper as copper sulphide and further purifies the solution prior to nickel precipitation by hydrogen reduction. The reduction end solution, containing the cobalt which was originally present in the leach solution as well as residual nickel, is treated with hydrogen sulphide. The resulting nickel-cobalt sulphide precipitate feeds the soluble cobaltic ammine process, which separates the nickel and cobalt and recovers the cobalt as a pure powder.A detailed description of the cobalt recovery process is given. Included are the various steps, comprising: acid leaching of the mixed sulphides, solution purification, ammine complex formation and cobaltous oxidation, two-stage nickel precipitation, cobalt conversion and reduction. A brief description of cobalt powder handling is included, along with typical physical properties and chemical analyses of the cobalt product. In general, the purpose of this paper is to describe the present plant practices employed in the recovery of cobalt as a by-product of the nickel refinery operations."

Jan 1, 1967