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By T. Eger

Load Haul Dump vehicles (LHD) are extensively used in underground mining however equipment design and operating conditions contribute to restricted operator?s visibility. The inability to clearly see people, objects or hazards around the machine has contributed to a number of accidents including fatal injuries. In order to identify vehicle design characteristics resulting in restricted and blocked sightlines visibility assessments are traditionally completed in the field. However, field methods are unable to evaluate visibility under dynamic operating conditions and are limited in their ability to provide feedback on the impact of various operator characteristics such as sitting height, for example. Results of this research show computer simulation and virtual reality can be successfully used to evaluate visibility during the operation of LHD vehicles. In order to benefit from virtual reality applications the work environment, LHD vehicle and human posture need to be represented as accurately as possible. A computer simulation program with ergonomic ana lysis features, Classic JACK 3.1, was successfully used. Threedimensional CAD models of LHD vehicles were developed from manufacturer specifications and pictur es taken from LHD vehicles currently in use. The LHD models were imported into the JACK environment, a digital human was positioned in the cab of the LHD vehicle and the vehicle and human where driven over a typical mine route. Real-time feedback in the JACK program was used to identify what the operator could see under different operating conditions. Machine characteristics and operating scenarios resulting in impaired visibility were successfully identified with this method. The JACK program can also provide real-time feedback on the human?s joint forces and torques, strength requirements, postural comfort, and metabolic energy expenditure. As a result, this method could be used to successfully evaluate musculoskeletal injury risk factors along with system design recommendations to improve workplace safety and productivity in any setting. The LHD VRML files imported into JACK have also been combined with environment files into other VR software packages (e.g. Maverik) to view in a VRL facility, managed by MIRARCO at Laurentian University. The VR models using these packages can be viewed in stereo to provide better appreciation of spatial visibility issues.

May 1, 2003

By J. Basi, J. A. Finch

ABSTRACT Testing the effects of bubble size (Db) in a Mo cleaning ?otation column at Highland Valley Copper mine indicated that increasing the proportion of small (< 1 mm) bubbles signi?cantly improved column metallurgical response, compared to typical operation. The results were a three- to four-fold Mo recovery increase and a 1 to 2% Mo (absolute) concentrate grade increase. The improvedcolumn operation produced a 4% Mo plant recovery increase. This study also showed that modelling the ?otation rate constant (k) as an inverse square function of Db was more accurate than considering k to be inversely proportional to Db.

Jan 1, 2010

By Véronique Falmagne

The mining sequence at Noranda?s Bell-Allard mine calls for two mining fronts retreating toward a central pillar known as the Retreat Zone between pyramids A and C. It is clear from numerical modeling and rock mass characterization that the induced stress level in the pillar will exceed the rock mass capacity. A mining plan was developed including the re-dimensioniong of stopes in the Retreat Zone, additional ground support and instrumentation in order to ensure the safety of the workforce and to maximize ore recovery while minimizing production delays. The mining strategy consists in allowing the rock mass to fracture and fail progressively while maintaining control of the existing openings with the appropriate support. A systematic analysis of rockbursting and caving hazards was conducted for all accesses and stopes in order to plan ground support and instrumentation needs.

May 1, 2003

By G. E. Agar, W. B. Kipkie, V. K. Drylie

"This paper describes mineral processing test work on drill core samples from an ilmenite deposit in Terrebonne County just north of Montreal.Mineralogical examination showed that the intimate associa¬tion between ilmenite and hematite precluded their separation. The maximum concentrate grade was therefore limited to 22.9% Ti. Liberation of gangue from the hemo-ilmenite grains occurred around 400 µm, a size which proved to be too coarse for recovery by flotation.Other physical separation techniques, such as elec¬trodynamic, magnetic and jigging, were tried in order to take advantage of the relatively coarse liberation size. An all-flotation procedure and a combination of jigging and flotation yielded similar separations.IntroductionInco Metals Company, through its subsidiary Canico, optioned an ilmenite deposit in Terrebonne County, just north of Montreal, and conducted a drilling campaign to confirm previous geological assessments of the deposit and to provide core samples for mineralogical study. Parts of these core samples were used for mineral processing studies, which will be described in this report. The objective was to identify suitable upgrading procedures, to determine the optimum combination of concentrate grade and recovery, and to provide suitable batches of concentrate for further treatment."

Jan 1, 1980

By L. Bichler, C. J. Verdon

In this work, the effect of doping yttria stabilized zirconia (YSZ) with 5, 10 and 15 mol% erbium oxide (Er2O3, erbia) was investigated using spark plasma sintering (SPS) technique. Sintering was carried out at 1300°C with 30 and 60MPa uniaxial pressures and a 5min hold time. Densification kinetics were studied using displacement response from the SPS machine. As-sintered microstructure characterization was carried out via scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques, while chemical composition was characterized by energy dispersive X-ray spectroscopy (EDS). The results suggest that sintering carried out at 60MPa produced high density composites even though erbia dopants were found to inhibit material densification and grain growth during sintering. 5, 10 and 15mol% erbia- YSZ had cubic crystal structures, as verified by XRD analysis.

Jan 1, 2014

By James Ransford Dankwah

This work investigates the effect of waste plastics addition on the reduction of iron oxide by sawdust. Composite pellets of iron oxide containing sawdust (SD), high density polyethylene (HDPE) and blends of SD/HDPE were fired under argon in a horizontal tube furnace at temperatures between 1300 and 1500 °C. Reduced samples were weighed after 10 minutes of reduction and the extent of reduction was calculated from the measured oxygen contents of the compact. The results showed improved extent of reduction when SD was blended with HDPE. The highest extent of reduction was achieved at SD:HDPE ratio of 2:3.

Jan 1, 2014

By E. Herrera Alarcón, L. Mariscal Samaniego

The Teniente Converter (wet charge type) was commissioned in august 1995 and was designed to smelt 744 tpd (metric tons per day) of dry copper concentrates. Its products are white metal (73% Cu) that is sent to the Peirce Smith converters, slag that is cleaned in Reverberatory Furnaces and the process gases that are sent to the Sulfuric Acid Plant. Since its start up, the Teniente Converter smelting capacity was increased 1.6 times, from 800 tpd to 1,280 tpd using 33% oxygen-enriched air, and reaching an operative availability of 97%. By the other hand its campaigns have reached a record duration of 530 days without hot patching tuyeres and a partial refractory lining repair in the last four campaigns. This paper describes the most relevant improvements, as well as the strategies that had been used to reach these achievements.

Jan 1, 2007

By A. H. Winckers

"CAMIRO, The Canadian Mining Industry Research Organization, formerly known as MITEC, is a collaborative research organization of Canadian Mining Companies. It is comprised of Exploration, Metallurgical Processing and Mining Divisions.The Metallurgical Processing Division (MPD) has the mandate to contribute to the profitability, competitiveness, safety and growth of the Canadian mining industry by improving the efficiency and effectiveness of mineral processing and extractive metallurgy in an environmentally conscious manner through the development of innovative technology by managing cooperative industry focused research programs.Current membership includes about ten Canadian mining companies. Past research has largely focused on base metal mineral processing. The Division wants to expand its research base to include all areas of mineral processing and extractive metallurgy.Past performance and plans for the future will be highlighted in the presentation."

Jan 1, 1998

By T. Melfi, M. James

Attaining required mechanical properties in welds made using the double submerged arc welding (DSAW) process is difficult, and it is becoming more difficult as the strength level of the base materials continues to increase. Producing weld metal with adequate mechanical properties involves factors that are often overlooked and not taken into consideration. Not least amongst these problems is simply finding information to use in selecting the appropriate flux/wire combination. Most of the available data on flux/wire combinations provided by consumables manufacturers is generated using the multiple pass welding procedures required for classification per specifications such as AWS A5.17 and A5.23. This data really gives no insight into the properties that can be expected in a DSAW application. Also, base plate composition plays a very significant role because of the fact that base plate dilution can be as high as 70% in DSAW welds. This means that if any elements are present in the base metal that are deleterious to mechanical properties, they will also be present in significant quantities in the weld deposit. Some of these elements can decrease toughness and increase hardness (increased hardness is a concern if the pipe is intended for sour service). Some of these problems can be mitigated by proper selection of welding consumables. Selection of proper welding consumables means selecting an electrode that provides the appropriate alloying elements to obtain the desired level of impact toughness while also keeping the hardness within any specified limits. In order to attain the necessary impact toughness, selection of a flux with an appropriate composition (in terms of its basicity and its ability to control the nitrogen content of the weld deposit) is required. As with all welding processes, the mechanical properties of DSAW welds are also highly dependent on the welding procedures. This work clarifies how to select appropriate consumables to meet a given set of requirements, and also how to achieve the optimum mechanical properties from those consumables.

Jan 1, 2005

By Patrick Pelletier, Pierre-Alexandre Bossé, Julie Fournier, Gianni Bartolacci, Jayson Tessier, Ahmed Bouajila, Carl Duchesne

"This paper summarizes research into the study of the control of flotation processes based on froth images. The use of numerical image analysis techniques for the extraction of significant patterns (froth structure and colour) from industrial flotation froths is discussed.First, the froth was analysed by the use of the Multivariate Image Analysis (MIA) method to extract the spectral variation contained in a RBG image. The Partial Least Squares (PLS) was applied to develop the empirical model for the prediction of froth grade. The results of this application are illustrated using one industrial case study.Second, the froth was also analysed by Gray Level Co-occurrence Matrix (GLCM) and Wavelet Transform Analysis (WTA) to extract features related more to morphological aspects. Since there is useful information hidden in froth texture, these methods are used as texture descriptor to classify different types of froths.Third, a control strategy based on a froth structure indicator was developed and implemented on an industrial zinc flotation circuit. The feedback controller uses a reagent flow-rate in order to maintain the froth structure at its set point. Process improvements obtained with the implemented control strategy are highlighted.Finally, the feasibility to implement a hybrid control strategy consisting in a froth structure supervision controller based on the froth concentrate grade estimated by MIA and recovery inferred by image analysis is discussed.INTRODUCTIONThe development of control strategies to achieve satisfactory control performance has always been a great challenge for engineers and the need for improved process diagnosis, control and optimization has become more and more evident for the mineral processing industry in the last decades. That is why new process variables need to be measured particularly in highly multivariable processes such as flotation. This industrial process is subject to a wide variety of disturbances mainly generated by frequent and sometimes abrupt changes in physical and/or chemical ore characteristics and also, due to some irregularities in manual process operating procedures. A flotation circuit scheme is always a complex network of more than two dozens slurry streams. Information about those streams (% solid, metal content analysis and flow rates) is important for process diagnosis performance evaluation and control. Also, because of the grade decrease and increasing complexity of the new processed ores, more instrumentation outputs and more powerful and significant pr"

Jan 1, 2005

By S. K. Paul

"This paper briefly describes the underground crushing and conveying system at Sherritt Gordon Mines&apos; Ruttan Mine. A series of three steel-cord belted conveyors, with a total length of 2J55 metres and a total vertical lift of 407 metres, convey the muck from the underground crushing station to the mill at the surface. The maximum size of the crushed rock is 6 in. All the conveyors are provided with numerous safety and fire suppression devices. IntroductionThe Ruttan Mine of Sherritt Gordon Mines Limited is located 20 km east of the town of Leaf Rapids, 760 km north of Winnipeg. The orebody is multilensed, with lens width varying from 6 to 45 m. Ore production started in 1973 with the opening of a 10,000-tpd open-pit mine. Initial development of the underground mine was started in 1972 with the driving of parallel conveyor and access declines at minus-2507o gradient to the I 220-m level, and then the access ramp was further extended to the 1160-m level. Exploration drifting was done on the 1280-m and 1160-m levels from the access ramp. The final development plan for the underground project was approved in January 1977, and full-scale development and constructionwere resumed.At present, Ruttan Mine is in a period of transition from open-pit to underground mining. Ore production is now coming from both operations. By mid-1980, open-pit production will cease and all production will come from the undergroundmine.The underground mining method at the Ruttan Mine is sublevel open stoping with delayed backfilling. The orebody is divided along strike into a series of 27-m-long stopes and 15-m pillars, both 60 m high."

Jan 1, 1980

By Francisco Tamargo

"This paper refers to a new process for the full recovery (above 98%) of zinc and other valuable metals (Pb, Ag, Au) accompanying zinc in its concentrates while iron is separated as a marketable product free of any harmful impurities and suitable for sale to the cement industry. The process has been especially designed to achieve the following goals: maximizing the recovery of zinc and those valuable metals that are present in most zinc concentrates (lead, silver, gold); allowing the recovery of other valuable metals such as indium or germanium that could be present in some zinc concentrates; avoiding or minimizing the need for residue disposal in safe areas as it is the common practice nowadays in the zinc industry. Finally, the process achieves the previously related goals at a competitive cost, in line with the existing more efficient operations while using conventional equipment working under atmospheric conditions. The new process can be easily implemented in those smelters using the jarosite or goethite processes as well as in those smelters using direct leaching as a part of the processing facilities. A study has already been conducted on the use of jarosite in the cement manufacturing process, in the raw mix preparation as well as for a set controller. It shows that use of clean jarosite in the manufacture of ordinary Portland cement can result in improved quality of the clinker. Jarosite showed compatibility to influence the burning characteristics of the cement raw mixes. The presence of SO3 bearing mineral phases such as natrojarosite showed the suitability of clean jarosite for use as a set controller in cement production.INTRODUCTION Iron is by far the most abundant impurity accompanying zinc in its concentrates, and consequently, iron residue disposal is a major environmental concern for many zinc smelters in the world. This is especially true during the last 30 years when environmental restrictions became more and more strict. Much research work has been carried out during the last 30 years to try to find a solution for this important issue, but with little success. Only the jarofix process represents a partial solution to this problem as jarofix is stored nearby the smelters with certain limitations as a non-contaminant residue. However, it does not avoid the need to dispose of an important amount of residues every year, representing an environmental liability. Meanwhile, the number of countries limiting or banning the disposal of iron residues generated by the zinc smelters is growing, so that the solution to this problem is becoming an urgent matter right now. At the same time, the lack of appropriate available land for iron disposal is also a major concern in many cases."

Jan 1, 2016

By O. S. Perry, G. H. Charlewood, K. Griffin, S Ogryzlo, H. Hopkins, G. MacIntosh

"The gold mines of Kirkland Lake are in Teck township, Timiskaming district, Ontario, latitude 48°9'N. and longitude 80°3'W., at an elevation of 1,038 feet above sea-level.There are seven contiguous producing mines in a length of 3;1/2 miles along the general east-west strike of the deposits. The seven mines are, in order from west to east, Macassa, Kirkland Lake, Teck-Hughes, Lake Shore, Wright-Hargreaves, Sylvanite, and Toburn.The first discovery of gold in the zone was made by W. H. Wright in 1911 on the east claim of the Wright-Hargreaves property, and the following year the Tough brothers and H. Oakes found gold in what is now the No. 1 vein_ at the Toburn. Production began at the Toburn in 1915, followed by Teck-Hughes in 1917, Lake Shore in 1918, Kirkland Lake Gold in 1919, Wright-Hargreaves in 1921, Sylvanite in 1927, and Macassa in 1933.To the end of 1946, 31,938,350 tons of ore had been milled at the Kirkland Lake mines, from which 16,132,700 oz. gold, having a value of $498,517,600, were recovered. The bullion varies from mine to mine between 800 and 900 fine, the average for all the mines being 853. The average fineness of the native gold is 941.The workings of some of the mines are more than 6,000 feet deep and sinking to depths below 7,000 feet is now in progress.GENERAL GEOLOGYThe regional structural geology of the area in which the mines of Kirkland Lake occur is described in a preceding paper in this volume by J. E. Thomson."

Jan 1, 1954

By D. Assmus, S. Daly

"Poor fragmentation, high toe areas, excessive shovel wear and tear and frequent re-drilling and blasting of certain tough waste rock zones in the Lomex pit in the early 1980snecessitateda better understanding of these zones.A combination of geotechnical mapping, penetration rate data, toe elevation contouring and observations on shovel and drill performance were used to determine the character and extent of these zones. This complementary information was brought together by the geotechnical mapper and the explosives supervisor.Distinct zones with particular geological characteristics were determined. A classification system with three types of blast and dig-ability was developed for the Lomex pit and later applied to the Valley pit, with considerable success. The three blast zone types are called ""poor"", ""f air"", and ""good"". This system will be described in detail.The explosives supervisor adjusted the blasting parameters to each zone, in particular, pattern spacing and burden. The resulting powder factors showed considerable variation between the poor, fair and good zones within each pit as well as between the two pits. Pattern geometry and length of collar were also adjusted to improve fragmentation. Cost savings resulted from less re-drilling and less wear and tear on drills and shovels in the poor zones and more efficient use of explosives in all the zones. An annual estimated cost savings of well in excess of $1,000,000 is realized at Highland Valley Copper. A by-product of the mapping was the determination of unstable structures and water flowing zones. Blasting was then adapted to this information for enhanced slope stability."

Jan 1, 1992

By S. E. Kesler, C. M. Moore, J. C. Van Loon

The possibility that chlorine and fluorine form complexes with ore metals, thereby having a strong effect on the mobility of these ore metals during late magmatic and hydrothermal processes, suggests that the abundance of chlorine and fluorine in igneous rocks could be used to distinguish intrusions that have generated ore deposits. The simplest and most economical measure of this chlorine and fluorine is the water-leachable chloride and fluoride that is released from fluid inclusions in the rock during crushing of the sample. In order to evaluate the possible use of this technique, measurements of water-leachable chloride and fluoride were made with selective ion electrodes on samples from nine intrusive complexes. There does not appear to be any simple relation between the abundance of chloride and the presence of mineralization. Fluoride values in mineralized intrusions appear to be higher than those in barren intrusions.

Jan 1, 1973

By S. Zador

"IntroductionIn the past decade, metallurgical and mining companies have shown an increased interest in the licensing of technology. When licensing technology, it is usually to the benefit of the parties, to have at least some of the technology to be licensed protected by a patent.This paper is intended to bridge the gap between the engineer in the field of mining, metallurgy and mineral processing who is interested in exploiting an invention commercially, and the patent agent or intellectual property lawyer whom he/she might retain to prepare a patent application and then prosecute the application to obtain a granted patent. It is also intended to encourage the inventor or a small business concern to consider the value of patents in the sale and licensing of technology. The lawyer may subsequently advise and assist the inventor in licensing his/her invention.A brief outline of some of the basic features of the patent system follows. The nature of the information, which the patent professional requires from the inventor to enable him/her to draft a patent application, will also be considered in general terms. Furthermore, various types of licenses which may be drawn up between a licensor of specific technical information and a licensee, will be listed and briefly discussed. No attempt, however, will be made to give a comprehensive and detailed account of the above aspects; the interested reader should consult legal publication and reference books, and patent professionals for further specific information.A granted patent is a document which describes an invention and how to practise it. The claims of the granted patent, figuratively speaking, fence off the intellectual property the inventor regards as his invention. The Commissioner of Patents, representing the Government, grants to the inventor or his assignee the exclusive right of making, constructing and using the invention, and selling it to others to be used, for a limited period of time, in exchange for disclosing the invention to the public. Thus, a patent prevents others from practising the claimed invention but it does not, necessarily, bestow the right to the patentee to practise his own invention. The term of a patent now in Canada and in most of the developed countries of the world, is 20 years from the date of filing the patent application. In the United States the patent term is still 17 years from the date of issuance of the patent. In Canada, the term was changed to 20 years in the new Canadian Patent Act which came into force on October 2, 1989. Any patent application filed prior to that date or granted before it, retains a 17 year life, commencing at the time of grant."

Jan 1, 1991

By A. T. Robles, L. Buckingham

"When certain gold ores containing pyrite, graphite, humates and fumates or other organic compounds which are possibly adsorbed on clay minerals are treated with aqueous solution of alkali metal cyanide, the aurocyanide complex which forms is adsorbed by these ""pregrobbing"" species in the ore. Dissolution of gold proceeds until chemical equilibrium is attained between the cyanide complex adsorbed by the ore and in solution.Sodium lauryl sulfate (SLS) may be used to decrease the adsorptive activity of the prerobbing species in the ore. It has successfully improved recovery at Holt-McDermott Mine and is highly biodegradable.INTRODUCTION Precious metal-bearing ores containing preg-robbing species are poorly amenable to standard cyanidation techniques. The ""preg-robbing"" impurities with which they are associated tend to adsorb the gold cyanide complexes and carry them through the circuit to the tailings. Also, gold may be associated with these impurities in the ore and not be leached by the cyanide complexing agents used in conventional cyanidation techniques.Methods for dealing with the problem of preg-robbinq impurities in gold ores are:Carbon-in-Leach (CIL), in which granular activated carbon is added to compete with preg-robbing species for the gold cyanide complexes. This process can improve gold recovery in mildly preg-robbing ores especially when fine carbons with very high activities are used. However, with severely graphitic ore, the carbon associated with the rock may outperform the granular activated charcoal.Chemical Oxidation, in which the ore is subjected to preliminary chemical oxidation techniques to oxidize carbonaceous materials using such diverse reagents including ozone, sodium hypochlorite, calcium hypochlorite, chlorine gas, permanganates, perchlorates, chlorates and oxygen prior to subjecting the oxidized ore to standard cyanidation treatment to extract gold. This is generally a costly method and will not prove economical on a low-grade ore."

Jan 1, 1992

By J. C. Loretto

"OPENING REMARKS Yesterday and today we have heard some very interesting papers on operating matters and some of you are probably wondering what we are now doing talking about Communications in Plant Design. Let me tell you! Before the techniques we have heard being discussed can be used, there has to be a properly operating plant. It is certainly a fact that many mineral processing plants achieve only limited success and a number of them can even be said to be failures. Some of you sitting here are probably living with operating problems that are clue to errors in the design.If the histories of these problem plants are examined, it will be found that in many cases, the necessary skills were available during the period of the plant design. There was extensive operating know¬ledge together with a full range of project expertise. Why then the failures? In a substantial number of cases it can be traced to the old, old problem of communications. As plants get bigger, money costs more and smooth startups become more important, it becomes less and less economic to fix up any design errors during plant operations.During our careers in mineral processing, nearly all of us will be involved in at least one plant design and I feel that it is as well if we understand some of these communication difficulties that can lead to a problem plant. There is little point in us being experts in mineral processing if the knowledge we have acquired doesn't somehow get incorporated into the plant.I would, therefore, like to present this short paper that mentions a few of the significant communication problems that can occur during the design of mining and mineral processing plants, together with some thoughts on answers to these problems."

Jan 1, 1973

By Ioannis K. Kapageridis

The lignite deposits of the Kozani-Ptolemais-Amyntaio basin in western Macedonia (North-West Greece) present a difficult modelling problem. Each deposit consists of several thin lignite layers ranging from a few centimetres to a few tens of centimeters in thickness, and thin intercalated sterile layers of marly limestones, marls, clays, and sands. These layers are practically impossible to model individually due to fast lateral transition of lignite layers to humus clay and vice versa and the lack of reliable and detailed stratigraphic correlation, leading to compositing methods being applied prior to any interpolation and modelling. The complexity of the deposit is further increased by the presence of a number of faults. This paper presents the modelling and estimation procedures applied during the most recent study of the South Western Field ? a new deposit that is considered for development and lignite production over the next years and will support the operation of a new power station in the area. Special focus is given to drillhole database structuring, fault modelling, stratigraphic correlation, mineable lignite intervals compositing, and resource estimation. The use of specialised mine planning software in all stages of modelling and estimation is thoroughly explained.

Oct 1, 2009

By M. Tanaka, H. Narita, K. Morisaku

"The selective separation of palladium (Pd), platinum (Pt), and rhodium (Rh) from a hydrochloric acid solution by solvent extraction was investigated using amide-type extractants, i.e., N,N,N’,N’-tetra-n-octyl-thiodiglycolamide (TDGA) and N-n-hexyl-bis(N-methyl-N-n-octyl-ethylamide) amine (BisAA). The separation experiments employed two separation schemes: (1) extraction of Pd with TDGA and that of Rh and Pt with BisAA; and (2) extraction of Rh, Pd, and Pt with BisAA. Separation scheme 1 achieved the highly selective separation of each metal. For separation scheme 2, Rh can be recovered prior to Pd and Pt, despite having a lower selectivity for Pd/Pt than separation scheme 1. INTRODUCTIONThe recent increase in the use of platinum group metals (PGMs) in industry (especially auto catalysts containing palladium (Pd), platinum (Pt), and rhodium (Rh)) has lead to their increasing waste; therefore, improvements in the recovery techniques for PGM have received significant attention. In metal refineries, PGMs are mainly separated and purified by solvent extraction (Cox, 2004). The extraction process used in INCO’s Acton precious metal refinery is one of the most famous commercial processes and is utilized worldwide. In this process, silver is first removed as a residue (AgCl), and then gold, Pd and Pt are extracted from hydrochloric acid (HCl) solutions using dibutylcarbitol (DBC), dialkylsulfide (DAS), and tri-n-butylphosphate (TBP), respectively. Finally, Rh remains in the raffinate (Barns & Edwards, 1982).The development of a successful solvent extraction process depends on the choice of the appropriate extractants. We have studied the extraction of PGM using N,N-disubstituted amide compounds (Narita, Tanaka, Morisaku, & Abe, 2004; Narita, Tanaka, Morisaku, & Tamura, 2006; Narita, Tanaka, & Morisaku, 2008a, 2008b). They are relatively stable against acids, and their metal extractability can be improved by changing the side chain length and/or introducing additional donor atoms like sulfur and nitrogen. We have recently found that thiodiglycolamide and an amide-containing tertiary amine have good extractabilities for Pd and Rh, respectively."

Jan 1, 2012