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By R. W. Thompkins

"PREFACEPart 1 of this paper, published in the September issue, covered the occurrence of uranium, radiation from uranium ores, the uranium series, radioactive theory, radioactive equilibrium and application to the radon series, the working level, the theory of emanation and diffusion, transport by thermal diffusion of radon emanating from porous rocks, and definitions.The October issue carried Part 2, which dealt with radiation theory applied to uranium ores, other radon migration factors, factors affecting the radon gas release rate, the measurement of radon gas emanation rates, the tunnel concept, variation of emanation rate with grade and estimating radioactivity from grade analysis.Part 3, in this issue, concludes the series by discussing the techniques for controlling radiation and providing some example calculations.17.0. Techniques for Controlling Radiation17.1. Altering the Factors In the Diffusion EquationIt has been noted that radon gas emanates from the surfaces of exposed ore to the mine atmosphere. The diffusion laws establish the rate of this flow. The fundamental relationship is that the rate of flow (J) is a function of the pore concentration and the distance from the surface. It is expressed as: []If any of these terms is varied, either naturally or artificially, the rate of gas emanation will be altered.Altering the Diffusion CoefficientThe literature describes many ways to lower the radon gas emanation rates which are dependent on changing the diffusion coefficient:1. A layer of ice on top of a tailings dam or on a soil.2. Humid clayey materials and swamped soils over a radon source."

Jan 1, 1982

By Owen Owens, W. P. Armstrong

The process of arriving at the size and grade of: (a) a newly-discovered body of mineralization, (b) a potential ore resource, (c) an orebody proposed for mining, or (d) the ore reserves in a mine, requires fundamental geological, and geometrical determinations as well as physical and chemical analyses. This paper outlines geological and geometrical features considered critical, in the authors' experience, in realistic reserve determination. These are discussed under the headings "The Four Cs". They include the Character, type or nature of the mineralization; the Continuity of various types of mineralization in the deposit; various key concerns in the Calculation besides the mathematics; and the Classification section which refers to basic considerations in classifying a mineral estimate. It is suggested that the responsibility for the calculation of a Resource or Reserve should be that of a geologist experienced in the ore type under review. Further, it should be the responsibility of the board of directors of the company owning the deposit to ensure that a sufficiently experienced person is chosen to carry out the process.

Jan 1, 1993

By Peter A. Witt

Highland Valley Copper is a conventional truck-shovel mining and flotation concentrator operation located some 75 kilometres southwest of Kamloops, B.C. (Figure 1). The ore is located within a porphyry copper deposit and is mined at a rate of 135,000 metric tonnes per day from two separate open pits. The nearby mill produces concentrates containing 375 million pounds of copper and 5 million pounds of molybdenum metal yearly. In the Valley pit, head grades are roughly 0.40% Cu at a 0.23% Cu equivalent cut-off. The Valley pit strip ratio currently sits at 0.55:1 with waste quantities made up of separate rock and unconsolidated overburden units. From the mill, concentrates are trucked to nearby Ashcroft and then hauled by rail to ocean port facilities in Vancouver. The mine employs 950 persons and is planned to operate until 2009. The operation is a partnership between TeckCominco with a 63.9% interest, BHP Billiton holding 33.6%, and others 2.5%. Management is shared by the two principal owners and directed by a management committee.

May 1, 2003

By D. S. Cronan, S. P. Varnavas

Abstract - Metalliferous precipitates from submarine hydrothermal discharges have been investigated at four inshore locations off Milos in the Hellenic Volcanic Arc. The fine fraction of the sediments shows considerable variability in the concentrations of elements frequently associated with hydrothermal activity. Manganese varies from 30 ppm to 2500 ppm, encompassing the entire range of values found off Santorini also in the Hellenic Arc. Iron occurs in lower concentrations than off Santorini and Yali, while other elements often associated with hydrothermal activity such as Pb, Zn, As, and Cu also show enrichments in sediments from the hydrothermal vent areas. Selective leaching studies have shown that most elements are variably distributed between the different phases of the sediments but with enriched Pb, Zn, and Mn mainly in easily soluble secondary phases. Hydrothermal inputs are strongest at Palaeochori Bay, less at Voudia Bay and lowest at the Airport Springs and Rivari. The weathering of sulfide and possibly other orebodies is also thought to contribute to some of the elements enriched, while background concentrations are largely supplied from detrital sources.

Jan 1, 1999

By Rodney Allen

Background: Development of the Project ?European GEODE collaboration 1999: considers possible projects, including a VMS project, to continue after GEODE ?GEODE-CODES-Canada collaboration 1999: Questionaire, database ?Workshop at CODES 2000: project theme and strategy selected ?GEORANGE (Sweden-EU) 2001 supports development of Global VMS Project: interest from 12 nations ?Skellefte VMS Project set up as Sweden?s component of Global VMS, 2002; other projects in Spain, Canada collaborate ?Low metal prices ---> little funding from mining industry 2001-2003, change in strategy ?IGCP/UNESCO support 2004: enlargement to over 20 nations

Apr 1, 2005

By Benoît Plante

La mine Tio (QIT Fer et Titane Inc.) exploite à ciel ouvert un gisement d?ilménite massive depuis 1950, générant jusqu?à maintenant plus de 70 Mt de roches stériles potentiellement génératrices de drainage neutre contaminé (DNC), dont une partie est submergée dans le lac Petitpas, au nord de la mine. Si généralement l?ennoiement des rejets miniers a un effet bénéfique pour limiter la contamination des eaux, cela reste à prouver pour ce qui est des stériles générateurs de DNC. Des essais en réservoirs ont été réalisés afin d?évaluer la réactivité de trois différents types de stériles submergés, qui ont été choisis en fonction de leur teneur en ilménite. Afin d?évaluer l?impact de la matière organique sur la réactivité des stériles submergés, chaque type de stérile est étudié en immersion simple ainsi que combinée à des sédiments prélevés au lac Allard, à proximité de la mine, d?où l?eau utilisée dans les essais a aussi été prélevée. L?évolution des teneurs en Ca, Mg, Si et Ni durant les 8 premiers mois d?étude démontrent que les stériles immergés sont réactifs, mais l?impact de la matière organique demeure pour l?instant difficile à préciser. Tank tests on Tio mine waste rock The Tio mine (QIT Iron and Titanium Inc.) exploits a massive ilmenite ore as an open pit since 1950, producing over 70Mt of potentially contaminated neutral drainage (CND)-generating waste rocks. While the underwater disposal of mine wastes generally show a beneficial effect on water contamination, this method still needs to be approved for CND-generating waste rocks. Tank tests were realized in order to evaluate the reactivity in underwater conditions of 3 different waste rock types, chosen with regards to their ilmenite content. In order to evaluate the impact of organic matter on the reactivity of underwater waste rock, each waste rock type was studied in simple immersion and in combination with sediments sampled at Allard lake, located near the mine, where the water for the tests was also sampled. The evolution of Ca, Mg, Si and Ni during the 8 first months of testing show that the waste rocks are reactive underwater, but the impact of the organic matter is till hard to define.

Nov 1, 2008

By R. W. Thompkins

"PREFACEPart 1 of this paper, published in the September issue, covered the occurrence of uranium, radiation from uranium ores, the uranium series, radioactive theory, radioactive equilibrium and application to the radon series, the working level, the theory of emanation and diffusion, transport by thermal diffusion of radon emanating from porous rocks, and definitions.This Part 2, which follows, deals with radiation theory applied to uranium ores, other radon migration factors, factors affecting the radon gas release rate, the measurement of radon gas emanation rates, the tunnel concept, variation of emanation rate with grade and estimating radioactivity from grade analysis.The series will conclude with Part 3, in the November issue, which will discuss the techniques for controlling radiation and provide some example calculations.10.0. Radiation Theory Applied to Uranium Ores10.0.1. The processes of diffusion transport of radon gas, through rock from the fundamental physics is a function o f the radon gas concentration in the interstitial pore spaces and the distance from the surface. Expressed by Fick's first law of diffusion, it is expressed: [ ]10.0.2. The maximum concentration is a function of the emanating power (ß), thus the above equation may be expressed: [ ]10.1. The Effect of Porosity10.1.1. If a constant emanating power is assumed (ß), a family of curves can be obtained for concentrations at varying distances and rock porosities. The curves as originally plotted assumed a constant emanating power of 5 x 10-4 pico curies/litre/sec and show the maximum expected concentrations in the pores in pico curies per litre. Because these concentrations are proportioned to the emanating power, this set of curves can be structured to show the fraction of maximum concentrations possible at various porosities of the rock.10.1.2. Notice that at 10, 20 and 30% porosities a 5-cm sample (hand-sized and drill-sized pieces) has no practical increase in pore concentration. Thus, by measuring the emanating power of hand-sized pieces of ore, the actual radon gas production into any pile of broken ore could be estimated readily."

Jan 1, 1982

By A. M. Cann, C. I. Godwin

"The Kemess porphyry copper-molybdenum deposit occurs in the Intermontane Belt of north-central British Columbia. The deposit is in andesitic to basaltic flows and tuffs which may be correlated with the Savage Mountain Formation of the Upper Triassic Takla Group. Most known chalcopyrite and molybdenite is associated closely with a 500-m-diameter zone of intense quartz-sericite-pyrite alteration. A zone of supergene enrichment, up to 30 m thick, underlies a leached capping about 20 m thick. The age of mineralization and the surrounding granodiorite and quartz monzonite pluton is Early Jurassic. K-Ar and Rb-Sr analyses indicate that the mineralization and alteration is slightly younger (l82±6 Ma) than the granitic intrusion (KAr: about 205±6 Ma; Rb-Sr: 190±4 Ma). The low 87Sr/J6Sr initial ratio for the granodiorite is typical of plutons in the Intermontane Belt.IntroductionKemess is a medium to small porphyry copper-molybdenum deposit with significant gold and silver values (Pilcher and McDougall, 1976). This paper describes the lithologies and alteration at this property; geochronology by Rb-Sr and K-Ar methods defines the ages of mineralization and surrounding plutons to be Early Jurassic.The property, located in the Thutade Lake area of northcentral British Columbia (NTS Map 94E; lat. 57°04'N; long. 126°44'W), is about 425 km northwest of Prince George (Fig. 1). Closest road access is 35 km southeast of Kemess. Final access must be by float plane or helicopter. The British Columbia Railway right of way passes 70 km to the southwest of theproperty.A prominent gossan zone at Kemess was staked in 1967 by Kennco Explorations (Western) Ltd. following detection of geochemical anomalies during stream sampling the previous year. During 1968, 1969and 1971, Kennco completed 232 m of X-ray diamond drilling, conducted geological mapping and carried out geochemical sampling of silts and soils (Stevenson, 1969; B.C. Ministry of Energy, Mines and Petroleum Resources, G.E .M., 1969 and 1971). Getty Mines Ltd. optioned Kemess in 1975and 1976. They remapped the area and diamond drilled 12 BQ and NQ holes, totalling 2065 m (B.C. Ministry of Energy, Mines and Petroleum Resources, Expl. B.C., 1975)."

Jan 1, 1980

By Malcolm R. Gent

"The presence in Saskatchewan of sixteen kimberlite pipes of probable late Albian age has been reported. An abundance of aeromagnetic anomalies possibly attributable to kimberlite pipes have been identified and it is anticipated that industry has acquired reasonable proof of the presence of more than seventy k imberlite pipes in Saskatchewan. Historical reports of diamonds, the discovery of kimberlite pipes and these aeromagnetic anomalies indicate the Phanerozoic Basin and some parts of the exposed Shield in Saskatchewan have an excellent potential f or the occurrence of economically exploitable diamond deposits. The presence of some igneous minerals found in some salt solution breccias also indicates the probable occurrence of extensive diatreme activity during the Devonian.A Laramide Orogeny-induced crustal hinging or arching of the eastern margin of the Phanerozoic Basin and probably dextral wrenching-induced arching and faulting within the basin are proposed as major factors in the emplacement of Cretaceous or younger kimberlites. Zones of crustal weakness between subcratonic Archean blocks and internal faults are also thought to be significant controlling factors in the location of kimberlites in Saskatchewan.Mapped aeromagnetic anomalies interpreted as being possibly due to kimberlite pipes generally tend to be concentrated in, areas underlain by a basement of or with components of Archean age. Within Saskatchewan, these anomalies occur within the probable Trans-Hudson Orogen zone; the Rae-Hearn Craton margin; and the northeast flank of the Elkpoint Basin. Recognized areas of potential f or kimberlite emplacement are the Phanerozoic basin margin, the western limit of the Superior Province adjoining the Churchill Province, and a swath approximately 150m wide along the northeast-southwest trending Shaunavon linear and other areas of inner basin arching."

Jan 1, 1992

By H. Sipilä, H. Vartiainen, H. Paarma

"The carbonatite massif of Sokli includes several low-grade Nb showings composed of ores and wastes as identified by routine analyses. More detailed lithologic proportions were determined in two orebodies in the Kaulusrova Nb-mineralized area by a careful geological study and by thorium radiation measurement on 10 cm-long drill core cuttings with a total length of 460 metres. The distribution of Nb in eight X-ray spectrometrically analyzed drill core sample intervals (totalling 35.8 m) was determined by analyzing the intervals semi-continuously by an X -MET analyzer. The geological studies suggest that Nb-mineralized bodies are feasible fo r the sorting of are and waste. This was confirmed by the semi-continuous determination of Nb on the X-MET analyzer.IntroductionThe Sokli carbonatite complex is located in eastern Finnish Lapland. The main ore of the carbonatite massif is a regolithic phosphorus ore in the weathered crust. Large-scale geophysical measurements and diamond drillings have also established several niobium showings within the magmatic carbonatites. Owing to the complicated geology of the massif, the niobium showings occur as irregular zones o r areas displaying complicated structure, texture, mineralogy and geochemistry (Vartiainen and Paarma , 1979; Vartiainen , 1980). The tonnages in areas such as this are large but the grades in-situ are low . The most intensely studied niobium showing is the Kaulusrova area.The exploitation of these showings depends on the feasibility of applying a sorting technique to upgrade the feed and to minimize the amount of material to be treated in the concentration plant. These possibilities o n the Kaulusrova area have been viewed by a detailed geological and X-MET an analyzing study."

Jan 1, 1985

By L. A. Gomieroa

The Caetité-Brazil uranium facilities produce about 340 t/y of uranium from an ore averaging 0,25 U %. The process steps are ore crushing, heap leaching with sulfuric acid, U separation and purification by solvent extraction with tertiary amine followed by stripping with sodium chloride solution and precipitation as ammonium diuranate that is dryed. A change in the milling process is being evaluated to increase the production and the uranium recovery. Heap leaching will be changed to conventional tank agitated leaching of the ?590 ground ore slurry in sulfuric acid medium. The replacement of the stripping reagent is also being considered.

Aug 1, 2010

By K. Fujita, T. Kikuchi, Y. Sakamoto

Ceramic fibers were classified as a category 2 carcinogen by The European U legislation. Therefore we developed non-fibrous insulating castable which utilizes n porous aggregate, which is composed of Calciumhexaluminate. Although at beginning we applied alumina cement as binder for non-fibrous insulating castable, kind of formulation had a poor resistance to spalling. We developed non-fibrous insulating castable without alumina cement. This solved a problem which pre\ formulation had a poor resistance of spalling. We applied a new non-fibrous insub castable for reheat furnace in steelworks, then we could achieve good result which condition equivalent to ceramic fiber insulating castable.

Jan 1, 2004

By Murray W. Grabinsky

This paper considers thickening mine tailings to dense non-segregating slurry or paste for surface disposal. The driving motivation for this initiative is the elimination of ponds, reduction in containment dams and significant decrease in water being sent to the tailings basin. This inherently reduces risks of environmental and structural failure. Some of the engineering challenges in creating a stable stack of thickened or paste tailings are identified, and possible field and laboratory testing techniques in support of design are discussed. Finally, the integration of monitoring activities into the ongoing management of the surface disposal site is considered.

Nov 1, 2002

By Lyall J. Lichty

THE property of New Calumet Mines, Limited, is on Calumet island, in the Ottawa river, about sixty-six miles northwest of Ottawa. Lead and zinc orebodies were discovered here in 1893. A gravity concentration plant was built in 1912 but was not a success metallurgically, and the plant was later destroyed by fire. A programme of diamond drilling on the property, started in 1937 and continuing to 1942, indicated ore reserves amounting to 1,300,000 tons averaging 2.75 per cent lead, 8.82 per cent zinc, and 0.041 oz. gold and 6.24 oz. silver per ton( l ). These orebodies have been developed underground by cross-cutting and drifting from a three-compartment vertical shaft, sunk to a depth of 745 feet. 'The ore is a contact metamorphic deposit occurring in rocks of the Grenville series, on or near the contact between biotite gneiss and an overlying calcareous amphibolite(2,3). It consists chiefly of iron-bearing sphalerite, galena, pyrrhotite, pyrite, and minor amounts of chalcopyriteand argentite. The gangue minerals closely associated with the ore are calcite, quartz, and various lime-silicate minerals.

Jan 1, 1945

By Arthur Lieu

Outline Removal mechanisms of Se and Mo in the Key Lake Bulk Neutralization circuit Bulk circuit Detail process modification in the Key Lake BN circuit Process performance after commissioning Objective Legacy effects of Se and Mo from the historical operation of Key Lake mill were shown to have an negative effect on the regional biota in the downstream environment. The water treatment circuit was not designed to remove Se and Mo from the effluent. Reduce Se and Mo concentrations in final effluent under0.028 0.028 ppm ppm and 0.3 and ppm ppm(CNSC regulatory limits).(limits).??????

Nov 1, 2011

By Alan L. Sangster

Abstract -Auriferous, bedding-parallel veins occur in zones of carbonaceous, argillaceous and sulfidic turbidites in the Lower to Middle Cambrian sandy flysch of the Goldenville Formation. The ?34S values for vein and wall-rock arsenopyrite and pyrrhotite, and for regional pyrite and pyrrhotite, are highly positive. The values are similar to those from Cambro-Ordovician sediment-hosted deposits of other types, and display trends that increase upward in the stratigraphic sequence. The similarity in composition of vein and wallrock sulfides indicates a seawater-sulfate source for sulfur, derived from the enclosing rocks at the time of vein formation. The upward increase in ?34S values is consistent with closed system sulfate reduction in the anoxic portion of a stratified water-column. Published ?18C and ?18O values for Meguma Group vein carbonates are unlike those of other gold-vein carbonates, but are similar to those of diagenetic-metamorphic carbonates from the Meguma Group and elsewhere. These data indicate that the source for the vein-related sulfides and carbonates may be the host strata; possibly the arsenic and gold were derived from the same source.

Jan 1, 1992

By E. A. Haack, L. A. Warren

Microbial biofilms are essentially biologically driven, geochemically reactive interfaces between solid surfaces and aqueous solution. Field investigation of acid rock drainage (ARD) associated biofilms at the Onaping nickel mine (Onaping, ON, Falconbridge Ltd.) characterizing: (1) micro-geochemical gradients (pH and 02) (2) metal fractionation amongst biofilm solid components, and (3) microbial communities; over both seasonal and diel timescales, indicates biofilms are highly metal reactive. Results show that biofilms accumulate metals seasonally within two microbially controlled solid fractions: amorphous hydrous manganese oxide (HMO) biominerals and the organic biofilm matrix. The biofilm geochemical microenvironment, driven largely by microbial activity, dynamically impacts biofilm metal behaviour over diel timescales. These results indicate that microbes can play significant roles in bulk system reactive metal transport. On-going investigation seeks to characterize the microbial players and the microbial-geochemical linkages involved in Mn oxyhydroxide formation and subsequent metal sequestration, with the goal of engineering this microbial activity as a bioremediative approach. This approach will have utility beyond specific application to the Falconbridge Onaping site to ARD mine environments in general, as the likely microbes involved in these processes are typically common across ARD systems.

Jan 1, 2004

By Masakazu Daté

Moisture effect has been studied for the CO oxidation over Au/TiO2, Au/Al2O3 and Au/SiO2, in the range of H2O concentration over four orders of magnitude. It has been found that the catalytic activity is generally enhanced by moisture in the reactant gas. The enhancement is as large as two orders of magnitude. Response to the moisture concentration, however, depends on the support oxide, indicating different contributions of the support to the reaction steps. The moisture effect is reversible and the activity is mainly determined by the amount of moisture absorbed by the catalyst. The apparent activation energies are not significantly influenced by moisture for Au/TiO2 and Au/Al2O3. On the contrary, non-uniform conversion curves versus temperature observed for Au/SiO2 are drastically changed, which indicates that the reaction over Au/SiO2 does not take place at low temperatures without moisture. The moisture effect may be probably attributed to the decomposition of carbonate species accumulated during the reaction, while the ?OH group might directly participate in the reaction pathways as a promoter.

Oct 1, 2003

By Selvia Tourn, Liliana Castro

"Abstract - Argentina, a large country with an important agriculture industry, needs an ever-increasing amount of phosphorus and potassium, as essential elements for plant growth. Current requirements are met from imports, but potential resources exist in Argentina. For example, several phosphatic occurrences are known in paleo-marine basins, the most significant of which are in Tertiary units in Patagonia. In addition, two types of potassium deposits are also known in Argentina: evaporite deposits in the Neuquén Basin at depths of 750 m to 1500 m contain 22 to 25 wt% K2O equivalent; and glauconitic sandstone containing about 6 wt% K2O has been identified in Patagonia.Several experiments were undertaken to test unprocessed phosphate rocks as slow-release, direct-application fertilizers, with good results. In addition, it is proposed that direct application of glauconitic sands would provide an efficient and economic alternative source of potassium. Tests with glauconite samples are still in progress. The existence of both phosphate and glauconitic rocks in Patagonia suggests that development of an extractive industry for these materials would not only help Argentina approach self-sufficiency in fertilizer usage, but also assist in the socio-economic development of this region."

Jan 1, 2003

By Alan L. Sangster

Auriferous, bedding-parallel veins occur in zones of carbonaceous, argillaceous and sulfidic turbidites in the Lower to Middle Cambrian sandy flysch of the Goldenville Formation. The 0348 values for vein and wall-rock arsenopyrite and pyrrhotite, and for regional pyrite and pyrrhotite, are highly positive. The values are similar to those from Cambro-Ordovician sediment-hosted deposits of other types, and display trends that increase upward in the stratigraphic sequence. The similarity in composition of vein and wallrock sulfides indicates a seawater-sulfate sourCe for sulfur, derived from the enclosing rocks at the time of vein formation. The upward increase in ?34S values is consistent with closed system sulfate reduction in the anoxic portion of a stratified water-colurnn. Published ? 13C and ? 18() values for Meguma Group vein carbonates are unlike those of other gold-vein carbonates, but are similar to those of diagenetic-metamorphic carbonates from the Meguma Group and elsewhere. These data indicate that the source for the vein-related sulfides and carbonates may be the host strata; possibly the arsenic and gold were derived from the same source.

Jan 1, 1992