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By M. C. Bluteau, G. P. Demopoulos

Arsenic reports in the effluents of many non-ferrous metallurgical operations. The production of scorodite, a crystalline ferric arsenate, is considered as an attractive option for the fixation of arsenic from aqueous effluents. However, scorodite solubility and long-term stability in the pH region of interest for tailings disposal have not been thoroughly investigated. In this study the long-term stability of scorodite in the pH 5 to 9 region and the mechanism of scorodite dissolution were studied. Construction of eh-pH diagrams indicated that scorodite stability is highly dependant on the nature (stability) of co-existing iron-hydroxide/oxyhydroxide. It was also found that when scorodite dissolves, a ferrihydrite phase having very small particles size (nano-scale) forms and that the growth and crystallization of this material are delayed by the presence of arsenate even under accelerated (75°C) ageing conditions. Around neutral pH and ambiant temperature (22°C) scorodite seems to reach an equilibrium with ferrihydrite after 48 weeks yielding soluble arsenic concentrations < 5 ppm.

Jan 1, 2004

By J. Lu

The impact of acid treatment in agglomeration/acid curing on copper extraction and acid consumption was investigated with respect to acid dosage and moisture. Without the addition of water, no agglomeration occurred. At an acid dosage above 15 kg/t, the acid was not completely consumed during acid curing. With the addition of 6.2% water, the particles agglomerated together. Copper, iron, magnesium and manganese were dissolved as sulfates and enriched in the fine fraction of the ore. The copper extraction and net acid consumption increased with increasing acid dosage. The copper extraction for acid curing with the addition of 6.2% water was higher than that without the addition of water due to the improved permeability and the increase in the contact with acid-soluble copper. During acid curing, the reaction of sulfuric acid with muscovite, abite and nacrite mainly took place on the surface of the particles while the reaction of sulfuric acid with clinochlore occurred not only on the surface but also inside the particles.

Jan 1, 2007

By Lorna Ortiz-Soto

A series of titiania- and silica-supported Au, Pt and Pt-Au catalysts prepared through different synthetic routes have been investigated in terms of their structural properties, adsorption of CO, and catalytic activity for the selective catalytic reduction of NO by propylene and the oxidation of and CO. Catalysts prepared by incipient wetness impregnation from individual Pt and Au precursors, exhibited characteristics very similar to those of monometallic Pt catalysts. This behavior is consistent with a model in which the two metals remain segregated due to their miscibility gap, and only Pt participates in the adsorption of CO and the reactions under consideration. In contrast, catalysts prepared from a Pt2Au4(C=CtBu)8 organo-bimetallic cluster precursor exhibited different behavior both in terms of CO adsorption and their catalytic activity for the three reactions examined. The combination of the kinetic, spectroscopic and structural characterization data suggests that in this case Pt and Au remain intimately mixed in the form of Pt-Au bimetallic particles, and that the presence of Au modifies the behavior of Pt.

Oct 1, 2003

By S. Pauly, U. Kühn, J. Eckert, I. Kaban, G. Wiehl, F. Silze

In the present work, the effect of Ga on the wetting behavior of the Cu-rich braze filler CuGa10 (wt.%) on the steel 304L was investigated. For this, the macroscopic and microscopic effects governing the wetting of pure Ga, pure Cu and CuGa10 alloy (wt.%) on the austenitic steel were analyzed and compared. Contact angle and surface tension measurements were carried out by means of the sessile drop technique and, in addition, the phase formation at the interface was determined. Pure liquid Ga spreads on 304L, which supposedly is related to the formation of intermetallic Fe-Ga phases growing into the liquid Ga. Depending on the annealing time, FeGa3 and Fe14.5Ga12 were identified. In contrast, CuGa10 as well as pure Cu show secondary wetting on the steel surface. Especially, liquid Cu prefers to spread laterally and vertically along the grain boundaries of the steel substrate. In spite of rather similar mechanisms, CuGa10 wets 304L steel at lower rate than pure Cu above the liquidus temperature.

Jan 1, 2014

By Yasuhiro Aoki, Akihiro Sato, Mikiya Arai

In this study, a freckle formation model based on the Rayleigh number was applied to actual multi-component Ni-base single crystal superalloys and verified in large scale casting trials. Finally, new Ni-base SC superalloys having a balance between castability and creep strength has been developed.

Jan 1, 2010

Introduction ?MT involves the measurement of naturally occurring magnetic and electric field oscillations. ?The ratio of E/H (wave impedance) is measured as a function of frequency to give resistivitydepth information. ?The ratio of vertical and horizontal magnetic fields (tipper) gives information about the location of (channeled) current systems.

May 1, 2008

By W. Petruk

A study was undertaken to determine whether interrelations between mineral grains affect ore breakage during grinding, and to establish a correlation between ore breakage and mineral liberation. A base metal ore from the Brunswick No. 12 deposit in New Brunswick was ground for different periods of time in a laboratory ball mill, and both the unbroken ore and the ground products were analysed by image analysis. The results show that the mode of breakage is strongly influenced by the behaviour of pyrite. Similar size distributions were obtained for material from the 15 minute grind in a laboratory ball mill, for the grinding circuit discharge from a commercial mill, and for pyrite grains in the unbroken ore. This similarity indicates that a 15 minute grind breaks poorly bonded pyrite grains along grain boundaries, and represents the limit of easy breakage for the ore. Such a grind liberates both large separate grains of ore minerals and poorly bonded mineral grains that occur in interstices among pyrite. On the other hand the 15 minute grind does not separate moderately bonded mineral grains nor release moderately bonded interstitial minerals from pyrite; a 45 minute grind in a laboratory ball mill is required. It is assumed that, for Brunswick No. 12 ore, a 45 minute grind in a laboratory ball mill is equivalent to regrinding in a commercial mill. Grinding beyond 45 minutes in a laboratory ball mill breaks the ore by fracturing pyrite across grain boundaries and by chipping grain edges. Such intense grinding does not markedly increase sphalerite liberation from Brunswick No. 12 ore, because most of the sphalerite that can be released was liberated at the 45 minute grind. In contrast the intense grinding increases galena liberation because a significant proportion of the galena occurs as minute inclusions in pyrite. These findings show that ore breakage and coincident liberation depend upon size distributions, intergrowths, and mode of occurrence of the minerals in an ore.

Jan 1, 1988

By J. D. Gillaspie, D. T. White

"Sulphuric acid atmospheric leaching of nickel saprolite / garnierite ores was proposed in the early twentieth century, prior to the development of the pressure acid leaching process for limonite ores. Sulphuric acid leaching with alkali addition for iron precipitation as jarosite has been considered periodically since the early 1970s, shortly after the development of the jarosite process for iron control in zinc refining. In the late 1990’s a series of flowsheets were proposed and tested involving simultaneous atmospheric leaching, iron precipitation and acid regeneration. These were considered particularly suited to sequential leaching of limonite and saprolite ores. A number of laterite sulphuric acid leaching processes utilising this chemistry have been put into commercial operation. Similar sequential leaching flow sheets involving precipitation of iron as goethite were also developed and piloted. This paper will firstly describe some of the important historical developments of both the jarosite and goethite processes. It will then provide descriptions of the commercialised processes involving alkali jarosite/alunite precipitation, with special emphasis on the downstream impurity removal requirements necessary for efficient recovery of nickel and cobalt from solution.INTRODUCTION This paper is a summary and extension of previous works with which the authors have been involved, on the subject of sulphuric acid leaching of nickel laterites (Adams, et al., 2004), (Liu H. , Gillaspie, Lewis, Neudorf, & Barnett, 2004), (White, Miller, & Napier, 2006), (White, 2009), (White & Gillaspie, 2013), (White & Gillaspie, 2015). Some of the historical developments of both the jarosite and goethite leaching-precipitation processes will be described, followed by a description of the commercialised sequential nickel laterite leaching processes, involving alkali jarosite/alunite precipitation and acid regeneration, with a comparison to the equivalent goethite based processes. These will include Jarosite Atmospheric Leaching (JAL), Goethite Atmospheric Leaching (GAL) and combined Pressure Acid Leaching – Atmospheric Leaching, termed EPAL®. There will also be an explanation of the downstream impurity removal requirements necessary for efficient recovery of nickel and cobalt from solution."

Jan 1, 2016

Purpose of TSUG Continuous Improvement in Mining Share Best Practises Exchange Ideas Network for Frontline Supervisors and Middle Management Meetings ? Two per Year -Spring and Fall ? Thirty Five to Forty Attendees ? Rotate Between Host Properties ? Host Mine Provides ? Meeting Room for One Day Tour of Mine and Maintenance facilities on Second Day

May 1, 2010

By Antoine Fournier, Karen St. Seymour

"Responding to market developments, interest in locating deposits of wollastonite has grown significantly. The many occurrences in the Grenville marbles of Quebec can be grouped into disseminated type and discordant vein-type deposits. Disseminated-type wollastonite occurrences have the disadvantages of lower grade, the need for more elaborate mineral separation, and failure to meet ""long grain"" technical specifications. Vein-type deposits have better grades and technical characteristics; exploration should be focussed on these and in the contact-metamorphic aureoles of fluid-rich intrusions. SOMMAIREEn réactions aux nouveaux de bouches, l&apos;interet pour les gîtes de wollastonite a crû de façon marquée. Les nombreux indices sis dans la province de Grenville au Québec peuvent être regroupes en deux catégories soit: les indices dissémines et les indices en veines discordantes. Les indices dissémines ont le désavantage d&apos;être moins enrichis, de requérir une séparation minéralogique plus complexe, et leur wollastonite ne possède pas le degré d&apos;acicularité voulu. Les indices en veines sont plus enrichis en plus de rencontrer les critêres techniques; les efforts d&apos;exploration devraient se porter vers ce type de gites et aussi, sur les auréoles métamorphiques de contact d’intrusions riches en fluides."

Jan 1, 1992

By H. Kuboyama

The synergistic effects of polymer additives such as gelatin and polyethylene glycol) (PEG) and Cl- on Cu electrodeposition have been investigated by measuring the polarization curves for Cu deposition, by rotating ring-disk electrode technique and by AC impedance measurements. The cathode potential for Cu deposition was greatly polarized in solutions containing both Cl- and gelatin or PEG, showing evident synergistic effect of polymer additives and Cl- on Cu deposition. The cathode potential was shifted to the less noble direction with increasing the concentration of Cl- in solutions containing polymer additives and showed the maximum polarization at Cl- concentration range between 0.1 and 1 mmol/L. The rotating ring-disk electrode technique revealed that Cu deposition in solutions containing small amounts of Cl- proceeded with initial formation of adsorbed intermediate CuClad. The Cole-Cole plots obtained by AC impedance techniques suggest that the reduction of CuClad is suppressed by polymer additives. The morphology of Cu deposited from solutions containing both PEG and Cl- showed the compacted surface composed of smaller grains due to an increase in the overpotential for Cu deposition.

Jan 1, 2007

By Terry McNulty

"Previous papers (McNulty 1998 and 2004) have dealt with the causes of successful and less successful achievement of design production rate by new processing plants in the minerals industry. Examination of many case histories has allowed the construction of curves or profiles that represent projects with similar characteristics that equate to differing degrees of care exercised during the project development phase. Simplistically, decreasing care is reflected by increasing risk and a heightened likelihood of poor technical and/or financial performance.This contribution provides an update, including recent case histories, and presents a modified Series 1A curve that includes the best 23 case histories, out of a total of 81 examined, or 28%. This is done to show that some very carefully developed and executed projects can ramp-up quickly and that owners of new projects should avoid being too pessimistic in projecting early cash flow if they are certain that they have done their homework. The role of metallurgical process development in the reduction of project risk is discussed and several financial analyses are presented that express the potential monetary value of a well-designed and professionally executed metallurgical program."

Jan 1, 2014

By S. Markstrom

The Boliden AITIK copper mine is located 100 kilometres north of the Arctic Circle in northern Sweden. A pre-feasibility study was conducted in 2005 with the aim of increasing the capacity of the existing processing plant. After analysis, options to upgrade the existing plant were abandoned in favour of building a new processing plant, with higher capacity and therefore greater profitability. A new plant could be designed with greater flexibility to make potential future expansions easier. A feasibility study for a new 36 Mt/y processing plant including fully AG grinding circuits and flotation was completed in 2006. The project was approved by the Boliden board shortly thereafter. Construction started in the beginning of 2007 and was completed during 2009. Commissioning of the new plant was undertaken in the first half of 2010. The grinding circuit consists of two lines with each line consisting of a 22.5 MW AG mill and a 10 MW Pebble mill in closed circuit with a spiral classifier. The nominal production level is 2 200 t/h for each grinding line. This paper presents the start-up and operation of the grinding circuit.

Jan 1, 2012

By Andrew Bamber

Outline ?Background to Mine-Mill Research at UBC ?Mine Mill Integration ?In situ mining methods ?Underground Pre-concentration ?System Design and Supporting Technologies ?Case Studies: ?INCO -McCreedyEast Mine ?Placer Dome ?Porcupine JV ISL Study ?Musselwhite, South Deep ?Falconbridge ?Fraser Copper ?Thayer Lindsley ?Wayside Gold, other scoping studies? ?System Designs ?Summary ?Future work ?Conclusion

May 1, 2006

By Kevin Ross

Feasibility Study Team Processing / Engineering?Hatch, Vancouver Mining / Reserves?Australian Mine Consultants, Brisbane Geology / Resources?Roscoe Postle Associates, Vancouver Environmental / Permitting?Rescan, Vancouver Tailings BGC, Kamloops Probable Mine Components Mining tending towards caving methods Underground mine accessed by shaft /conveyor & decline Processing plant producing copper concentrate containing gold Concentrate trucked to rail head for export Non saturated tailings disposal

May 1, 2006

Partnership with MiHR ? AHRC and MIHR jointly developed Mastering Aboriginal Inclusion for Mining ? Customization specific to mining Mining is unique? ? History of Aboriginal peoples and the land ? Unique community needs ? Effects of Impact Benefit Agreements ? Remoteness of mines ? 1200 Aboriginal communities located w/in 200km of active mines or exploration ? Long term effects of the land

May 1, 2009

By Jason Prno

Context ? Climate change an issue of global significance ? Research is lacking ? Study initiated by the David Suzuki Foundation, led by ArcticNorth Consulting Industry Surveying ? 34% and 48% of respondents indicated climate change is already affecting operations ? Majority believed climate change would have negative impacts in the future ? Cost and uncertainty of Future impacts are major barriers to adaptation

May 1, 2010

By K. .. Sadayappan

The increasing cost of selenium made the conventional low lead alloys such as EnviroBrasses not economically viable. Efforts were made to develop newer alloys without selenium for plumbing applications. Recently a new copper alloy, C89836, was introduced. This paper discusses the properties of the new alloy including mechanical properties at ambient and elevated temperatures as well as corrosion behaviour.

Jan 1, 2007

By Paul MacLean

MAC TSM ?Mining and Biodiversity Conservation 1.Corporate biodiversity conservation policy, accountability and communications 2.Facility-Level biodiversity conservation planning and implementation 3.Biodiversity conservation reporting ?Activities indicative of level AA -AAA (formerly 4-5) performance: ?Independent verification ?Integration into broader business strategy and planning processes ?Engagement with communities of interest ?Commitment to actively partner with other organisations for biodiversity conservation

May 1, 2011

By Andrew Thrift

Overview ? Problem ? Research question ? Literature review ? Methodology ? Results ? Discussion and recommendations ? New developments Problem ? Increasingly higher expectations ? Inadequate consultation leads to conflict rather than collaboration ? Consultation practice is often weak on decision-making ? Influence of consultation on planning is Unclear Research question ? Are Structured Decision Processes (based on decision analysis) an effective methodology for involving stakeholders in consultative decisionmaking in the mining industry?

May 1, 2006