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By H. Tudeshki

A great amount of aggregate is utilized in civil engineering applications such as road construction, railway infrastructure, concrete production, etc. Igneous rocks are the preferred raw material due to their high strength and abrasion resistance. Rock quality assurance is a key factor and has great influence on the quality of constructions in civil engineering. One of the major problems encountered by both the producers and users of igneous aggregate rock is the fact that, with the passage of time, some specific rocks lose their strength, up to a complete loss of structure, i.e. disintegrate and degrade. This phenomenon has a great influence on the quality, strength and durability of aggregates. In the last decades, different methods and procedures such as the glycol test, the methylene blue dye test, as well as the Los Angeles test, have been introduced to distinguish rock properties, and to identify these problems. However, as these wet-chemical methods are time consuming, hard to perform, only to be applied to hand-piece samples, requiring special laboratory equipments, and are only possible to be accomplished under laboratory conditions, their application has always been severely limited. To address this widespread quality management problem of the quarry industry, a relatively quick, easy and user-friendly approach is necessary. It calls for a systematic solution with a device that can simply be used in the day-to-day routine of a mine for quality control of the quarry´s daily production. Our research is concentrated on developing a systematic method for early recognition and diagnosis of rock quality, in order to control and manage the quality of the quarry production in advance. Our new approach is based on two rock parameters: magnetic susceptibility and loss on ignition. The measurement of these parameters provides reliable information on the quality of the rock and allows the quality control process to be accomplished and performed at the borehole location. Our new approach has been assessed through extensive field and laboratory studies and has been implemented on the drill-cuttings of a basaltic andesite quarry. The results of the experiments are discussed in detail, including their impact on increasing resources and environmental protection.

Aug 1, 2013

By K. Ebrahimi-Nasrabadi

The dependence between the extent of conversion of cryptocrystalline magnesite to caustic magnesia was studied experimentally in the temperature range of 400?1200 °C and for calcination times up to 8 h. A TGA?DTA analysis showed that decomposition begins at temperatures as low as 340 °C and is completed at 600 °C. Measurements of specific surface area (SSA), iodine adsorption number (IN), crystallite size, and loss on ignition were carried out to characterize the product quality. It was found that while all the parameters are dependent on the extent of calcination, densification of the product caused by grain coarsening affects their final values. As a consequence, SSA and IN went through a maximum with time. The study showed that high quality caustic calcined magnesia can be produced in a narrow range of temperature (600?650 °C) and time (1?4 h). Medium quality caustic calcined magnesia can be made within a wider range of parameters.

Aug 1, 2013

By P. K. Kaiser, F. Amann

"Rock mass characterization for deep underground construction and mining offers many challenges. This paper first describes some of the key challenges when characterizing highly stressed brittle rocks and then offers some guidance on how to arrive at reliable rock mass strength parameters for deep mining applications. Focus is placed on characterization for rock mass strength determination. It is illustrated how the common use of currently available rock mass characterization systems tend to underestimate the strength of rock at depth. Modifications to currently adopted approaches, i.e., the use of Geological Strength Index GSI for rock mass strength determination, are presented.INTRODUCTIONFor green fields projects, the first challenge of rock mass characterization stems from a lack of access to examine the rock mass at scales larger than typical core sizes (i.e., ~63mm in diameter) until late in the mine design when the flexibility for making changes is constrained. Hence, rock mass characterization often has to rely on information derived from boreholes alone (e.g., core, logs, etc.). This challenge is lessened when mines are expanded from existing operations. A second challenge is related to changing rock mass behaviour with increasing depth and stress. At depth, the rock is highly stressed, thus closer to failure, and often highly confined which leads to a higher interlocking with elevated strength but more brittleness. The goals of rock mass characterization are to be tailored to the technical goals of an investigation. For example, for cave engineering, the workflow includes the assessment of five key engineering aspects (Brown, 2007): Caveability; fragmentation; cave performance; extraction level stability; and mine construction (rock support). Each engineering aspect has to address specific engineering questions and each design component is influenced by different rock mass behaviour aspects and thus is dominated by different rock mass properties, e.g., the vulnerability to stress fracturing (spalling), the bulking characteristics for flow control and support selection, and the confining stress impact on pillar or support design. An effective rock mass characterization program, including logging, mapping and laboratory testing, thus has to collect and interpret features that are relevant for the above listed purposes. Some of the predominant factors are: block volume of defected and non-defected rock; spalling strength; tensile strength of defects; rock mass modulus; and rock mass strength parameters for application to low and high confinement design aspects."

Jan 1, 2015

By J. G. Mieczaniec

"A key element for a successful mining operation is the grinding circuit. It must be reliable, maintainable and must perform to or above design capacities for 95% of the time. Once chosen and installed major modifications are either prohibitive or very expensive. The selection of mills and drive system is probably the single most important decision made within the concentrator complex.Economic studies revealed that the optimum expansion for Lornex was a 68070 increase in plant throughput. This indicated that the new mill would have to be larger than the existing 32-foot mills.The Lornex ore has a wide range of hardness which has a great influence on mill throughput (Table 1). To smooth out the fluctuations, a blending program ha s always been in effect at the mine, coupled with ball charge control for the primary mills. As can be appreciated, an optimum balance is difficult to achieve. A sudden change to so ft ore with a high ball charge puts the mill into jeopardy with a constant speed drive.The blending philosophy would continue after the expansion, but with the addition o f a second primary crusher, it was envisaged to have the new mill process harder ore to maintain production targets. In theory, the new mill would have a proportionally larger ball charge than the existing mills.This scheme makes the new mill vulnerable for processing so ft ore for a fixed speed mill. Thus, variable speed seemed an attractive option.In early 1979 prominent mill manufacturers were invited to submit proposals for the new mill. Fixed and variable speed mills were to be considered with mill size ranging from 32-foot to 36-foot diameter. The proposals were to include the drive, ball charge, % critical speed, couplings, gears, etc. - the complete package. The recommendations were variable with most manufacturers submitting several alternatives. Recommended mill speed varied from 68% to 78% critical. The concept of variable speed was becoming more attractive, Lornex ultimately decided on a twin DC motor drive system for a 34-foot diameter mill.After start-up it was discovered that best throughput occurred at 78% mill critical speed or top speed of the drive motors. The motor speed range was adjusted upward from 186 to 200 rpm. Today the mills operate at 79% critical or a motor speed o f 193.5 rpm.Clearly the selection of the variable speed mill allowed the flexibility to optimize throughput."

Jan 1, 1985

By V. Falmagne

The mining sequence at Noranda?s Bell-Allard mine calls for two mining fronts retreating toward a central pillar known as the Retreat Zone between pyramids A and C. It is clear from numerical modelling and rock mass characterization that the induced stress level in the pillar will exceed the rock mass capacity. A mining plan was developed including the re-dimensioning of stopes in the Retreat Zone, additional ground support and instrumentation in order to ensure the safety of the workforce and to maximize ore recovery while minimizing production delays. The mining strategy consists in allowing the rock mass to fracture and fail progressively while maintaining control of the existing openings with the appropriate support. A systematic analysis of rockbursting and caving hazards was conducted for all accesses and stopes in order to plan ground support and instrumentation needs.

Apr 1, 2004

By Jochen Petersen, Caroline Muzawazi

The technical feasibility of ammonia leaching of PGM bearing Platreef flotation concentrates was investigated as an alternative method for the recovery of base metals prior to precious metal recovery. The composition of the concentrates includes 2.02% Cu and 3.17% Ni, and the major base metal minerals are chalcopyrite and pentlandite. Optimal leaching conditions were initially established in shake flask experiments to be a solution containing 4 M NH4OH, 4 M (NH4)2CO3 and a pH range between 9 and 10. These were used as base case conditions in column and batch stirred tank reactor tests, where the effects of total ammonia concentration and operating temperature were explored further. At optimal conditions nearly 100% Cu and Ni extraction were obtained in the batch stirred tank reactor, and 95% Cu and 60% Ni extraction was obtained in columns. The activation energy for chalcopyrite and pentlandite was 36 kJ/mol and 16 kJ/mol, respectively, in both reactors, indicating different reaction pathways for the two minerals. Gas-liquid mass transfer appears to be the limiting reaction step in columns much more than in tanks, and the degree of ammonia loss to air is significant. This initial test work indicates the feasibility of using ammonia leaching for this and similar materials as an alternative route to conventional smelting and refining prior to PGM recovery, but a number of technical challenges still need to be overcome.

Jan 1, 2014

By W. Mueller, M. Rocheleau, E. Dimroth

The paleogeographic evolution of the Abitibi Belt is subdivided into three phases, namely: 1) a phase of the growth of a submarine volcanic chain, 2) a phase of the emergence and growth of volcanic islands and 3) a phase of uplif t and erosion of volcanic islands. Isostatic calculations suggest that the volcanic sequence in the south of the Abitibi Belt rests on oceanic basement or on the mantle; the volcanic sequence in the north of the belt rests on about 13-14 km of tonalitic basement. 10-15 km of plutonic material accreted to the volcanic islands during paleogeographic phases 1 and 2, and caused the uplif t during paleogeographic phase 3.

Jan 1, 1984

By Franz Xaver Spachtholz

K+S Potash Canada GP (KSPC) is part of the K+S Group, one of the world's leading suppliers of standard and speciality fertilizers and the world?s leading salt producer. Globally, the K+S Group employs more than 14,000 people. The K+S share ? the only commodities stock on the German DAX index ? is listed on all German stock exchanges. Legacy, K+S Group?s most recent project, is a greenfield solution potash mine and production plant in the south of the Canadian province of Saskatchewan. Therefore K+S will invest 4.1 billion CAD. With the expected commissioning in summer 2016 the company projects to reach the two-million-tonnesmark of production capacity at the new location at the end of 2017. The gradual extension of the annual capacity to 2.86 million tonnes of potash products will occur afterwards. The Legacy Project will be Saskatchewan?s first new potash mine in nearly 40 years. It is one of the world?s most economically attractive potash projects. The project will contribute to Saskatchewan?s growth through employment, tax revenues, utilities, and local partnerships. Located in the southern part of Saskatchewan?s potash belt, the deposit is too deep to be mined conventionally due to rock mechanics and high temperatures. Legacy will therefore be a solution mine. Proximity to the urban centers of Regina and Moose Jaw is imperative, with their workforces and economy, as well as access to highways, railway carriers and, most importantly in the prairies, water. With this unique project setting and mining technique, we are convinced that Legacy will be one of the most efficient, economic, sustainable and safe potash facilities in the world.

Aug 1, 2013

By Roger D. Plouffe

In today's mining industry, it is possible to retrieve, from small-diameter holes, geophysical data for qualitative interpretation in exploration and quantitative interpretation in the development of orebodies. The primary objectives in the exploration stage are to identify where, within a hole, economic minerals are, and to help in lithological interpretations. Other aspects, which are more quantitative, are the interpretation of downhole logs for parameters which can be used in surface geophysical methods (i.e. density for gravity surveys, acoustic velocities for seismic surveys, and magnetic susceptibility for airborne and ground magnetic surveys). Recent advances in equipment design, portability and durability have made downhole logging in exploration more inexpensive and reliable. This new equipment is being used to generate very precise quantitative results. This is especially true on uranium development projects. The interpretation of gamma logs for eUJOS values has finally become precise enough that they have begun to replace chemical values in reserve calculations. Another part of development data is density and equilibrium information, which, with today's technology, is being derived from downhole probing. In the years to come, the trends for many metals are toward neutron activation techniques, or "in-situ assaying", and the use of multiple logs for better lithological and physical rock property determinations.

Jan 1, 1981

By R. P. Chapman

The geochemical interpretation of results of statistical analysis of published multi-element stream sediment data from southwest and northern New Brunswick is presented. Element concentrations in southwest New Brunswick are low and comparable to element concentrations in background areas in northern New Brunswick. Deposits of copper and nickel are indicated in southwest New Brunswick. Anomalous element concentrations occur in several areas in northern New Brunswick and the elements most commonly associated with these anomalies are Cu, Pb, Zn, As and Ag; and also Mo, Wand Sb. Bedrock geology greatly influences element concentrations and may cause false anomalies. Manganese has a pronounced effect on the dispersion patterns of Co and also Zn, Mo, Pb, As, Ba and Ni. Nickel and Cr are strongly sympathetically related and this association is independent of bedrock type.

Jan 1, 1977

By H. J. McQueen

Aluminum was hot worked at 400 - 500°C and strain rates (e ) of 0.004 -0.1s-1, under reversing strains (c) of 0.5 to 0.2 or 0.5 to 0 and also advancing from 0.5 to 1 or 0.5 to 5. Under similar test conditions for different parts of the strain paths, the average measured flow stresses are found to agree with each other. In the forward and backward strain path tests, the almost identical steady state plateaus affirm the occurrence of dynamic recovery (DRV). On reversal of strain direction at constant e , there was generally negligible Bauschinger effect. In specimens annealed at 400°C, static recrystallisation (SRX) was followed microstructurally. mainly by disappearance of elongated grains with serrated boundaries because the new grains were only little a finer than the old due to low strain energy. The only influence of reversing strain path observed was the effect of change of grain boundary area as grains elongated or returned towards equiaxed. In optical microscopy, elongated grains with serrations and deformation bands confirmed DRV in forward path specimens. In reverse path specimens, equiaxed grains were gradually restored with retention of serrations and bands. In low magnification polarized optical microscopy, grain alignment increased with strain for forward path specimens; whereas it decreased in reverse path ones, supporting DRV. Orientation imaging microscopy (OIM/SEM) revealed that elongated grains are broken up as deformation bands rotate during the forward path and that grains return to equiaxed appearance on backward straining. Comparative studies using optical microscopy in polarized light (POM), OIM/SEM and transmission electron microscopy (TEM) revealed that while subgrains remain equiaxed and constant in size and character during the forward and backward paths, the fraction of low angle facets decreased while that of high angle grain facets increased with increasing strain; these are coupled with a fairly low fraction of medium angle boundaries. The results contribute to the understanding that dynamic recovery in aluminum maintains sub-boundaries with low misorientation but as grains elongate and more subgrain become adjacent to grain boundaries the fraction of high angle boundaries rises (with backward straining it was vice versa).

Jan 1, 2007

By A. Liem, R. L. Johnson, C. Sturgess, E. Kuzub

New challenges in mineral processing arise as high-grade ores become less available and the mining industry is forced to exploit lower grade ores. One of the challenges in beneficiating lower grade ores is the liberation of mineral particles while maintaining control over material management. Lower grade ores need fine grinding to free valuable minerals, but finely divided particles can cause severe problems, such as dustiness and flowability, in subsequent stages of material management. There are at least two approaches that can be taken to resolve this dilemma, both of which relate to particle size enlargement. First, the application of a dust suppressant can be used to control that aspect of material management. The optimal choice of dust suppressant agent depends on effectiveness and cost, both of which can be strongly influenced by the selection of application method. Second, agglomeration combining small particles into larger units-can reduce dust and improve the flow characteristics of the material at the same time. There are several mechanisms that can be employed to agglomerate mineral materials. Although agglomeration adds a new processing step, it is often cost effective. This paper describes these two approaches and their respective challenges, as they relate to a mined ore. We report on modified or newly developed procedures for characterizing mineral ores with respect to material management. On the same material, we use agglomeration processing to capture fines within larger particles and show how dustiness and other aspects of material handling are affected. We conclude by discussing their specific application in accordance with the mineral properties and processing needs.

Jan 1, 2004

By Zhong Zhang, Xijia Wu, Prakash C. Patnaik

"The integrated vehicle health management (IVHM) aims to provide life cycle management decisions for military platforms and their propulsion systems with reduced life cycle cost and increased operational readiness and safety. Among all the issues of IVHM, understanding the physics of failure and predicting lifetimes of the critical components are at the core: the decision makers have to know when and how components may fail in order to plan ahead. The difficulties to tackle failure problems lie in determining the material response to cyclic and dwell loading in a hot and/or corrosive environment, which all combined to induce multiple deformation and damage mechanisms, resulting in mix-mode failures. Decisions on component replacement (material substitution) and mission planning must be based on quantitative knowledge of the failure physics to mitigating the risk. This paper addresses the critical failure issues including creep, low cycle fatigue (LCF), thermomechanical fatigue (TMF); and presents a mechanism-based approach to life prediction. The mechanism-based approach, by its physics, is widely applicable over the entire operational spectrum of both structures and engines, and therefore is suitable for IVHM purposes."

Jan 1, 2015

By R. Darlington, S. Ji

"High pressure die casting is a promising process to make thin-wall components with high dimensional accuracy and excellent surface quality. However, the non-uniformity is one of the important features in castings. The inhomogeneity in tensile properties and microstructural characteristics were studied for the castings with different thicknesses made by high pressure die-cast Al-Mg-Si alloys. For the local mechanical properties in the die-castings, the casting skin provided the highest, whereas the casting centre provided the lowest yield strength, UTS and elongation. The yield strength, UTS and elongation were significantly decreased towards the casting centre. The microstructural inhomogeneity is characterised by the segregation of coarse fragmented dendrites, the reduction of solute concentrations of Mg and Si, and the increase of porosity level from the surface to the centre of castings. The growth velocities of eutectic a-Al phase estimated using the Jackson-Hunt model confirm that the growth variation is larger in the thin castings than that in thick castings.INTRODUCTION Inhomogeneity is an inherent characteristic in as-cast microstructures of a variety of alloys because of their non-uniform chemistry, microstructure, defects, topology and the resultant mechanical properties in the different ranges of localization (Campbell, 2003). Generally, three types of inhomogeneities characterise casting microstructures, which include (a) the casting defects of shrinkage and gas porosity, misruns, cold shuts, inclusions, hot tears and hot spots; (b) the non-uniform microstructure from the surface to the centre of castings; and (c) the non-uniform microstructure from the dendrites grown from primary solidification and the structure formed during the subsequent eutectic solidification in inter-dendritic regions. The chemical composition and the morphology between the primary dendrites and the inter-dendritic eutectics also differ in the as-cast microstructure. Obviously, the inhomogeneity is different in the castings obtained from different casting processes."

Jan 1, 2018

By Leroy G. Hagenbuch

"IntroductionAn integrated Truck Management Information System (Truck MIS) evolves as seemingly separate functions combined to yield a single homogeneous result / product. The concept of a computer integrated Truck MIS includes truck dispatch, truck maintenance management and truck weighing.A truck management system is only as good as the information / data bases input to it. The concept of an integrated system works best with automated data gathering. Automated data gathering provides timely and normally, the most accurate historical information/data bases. Data bases are, however, historical, which is a problem to be overcome in a computerized truck management information system, especially in regards to a truck dispatch system as loading sites / loading conditions and some dump site conditions continually change. As these changes occur, data base s must change as well, and thus the need for the continual update of data bases that the computer uses for a Truck MIS.For a truck dispatch system to achieve reliability / viability, dispatch decisions need to revolve around real time data gathered in an automated way. Integration of all truck management function s through automated data gathering lead s to the best over-all system.An integrated system is a combination of many different factors and is only as good as each factor / building block put in the system. With the proper building blocks, an integrated Truck MIS is very feasible - an MIS System that includes weighing, time and motion study, truck maintenance and maintenance management, as well as truck dispatch.Truck MISAn integrated Truck MIS provides for truck dispatch as the ultimate end result, a truly automated /integrated truck dispatch system (to function non-operator-dependent). The following comprises its central building blocks:-Time.- Haul Cycle Segments.Truck Status, i.e. Load on truck,- being loaded,- loaded,- unloaded,- in service,- out of service.- Vehicle Location.Loading Equipment Status.- in service,- out of service.Optional- distance travelled in each haul segment.With this data provided on a non-operator dependent basis, it is possible to build good data bases so a computer can make truck dispatch decisions. Knowing what information is needed as the central core to a good Truck MIS, how can this information be automatically gathered and fed into a central control computer?"

Jan 1, 1986

By W. D. Robbson

DR. G. W. RAMSEY (l): A study of our non-treatment silicosis autopsy material for the years 1940-43 inclusive, in addition to the common findings of fibrosis, nodules, and emphysema, shows marked thickening of the alveolar walls. This change is due to one or more of the following factors: congestion, edema, accumulation of both small and large monocuclear cells within the interstitial tissues and large monocuclear cells attached to the lining membrane of the alveolar sacs. This alteration in the alveolar walls, we believe, is one of the most important factors in producing impaired pulmonary function. Comparison of our first autopsy material of a case receiving twenty aluminium treatments beginning June, 1943, shows a striking change in the alveolar walls. In all areas free of silocotic nodules and fibrous tissue, the alveolar walls approach normal thickness and are free of cellular deposits. No change was noted in the old processes and none was expected. We believe that these changes in the alveolar walls were brought about by the aluminium therapy and that they constitute a major factor in the improved pulmonary ventilation noted in treatment cases.

Jan 1, 1945

By M. K. Gangal, A. E. Hall, S. B. V. Stewart

"An investigation into the problem of atmospheric fog in Canadian mines is described. Fog occurs in several mines and the reduced visibility can result in the closure of workings for safety reasons. Information on the mechanisms of fog formation are discussed and the methods for improving conditions are reviewed with their relative costs.INTRODUCTIONAtmospheric fog occurs in several Canadian mines during spring and summer. The fog which reduces visibility, contributes to loss of production and increased accident risk . Closure of ramps in mechanized mines causes mining to be stopped or rescheduled, and stoping and grade control may be affected . Increased corrosion of equipment may result from acidic fog .Fog is commonly caused by saturated air being compressed and heated by an inlet fan and then being circulated in an ascensional system with heat transfer to the walls of wet airways. This causes supersaturation and water droplets condense to create fog, with liquid water contents of 0.5 g/kg to 3 g/kg of air. These concentrations reduce visibility to less than 10m and prevent mining. Less severe fog is usually tolerated as a nuisance, about which little can be done."

Jan 1, 1989

By D. Mills, W. J. Brantina

"Mechanical and magnetic characteristics of ferromagnetic materials were investigated by a pulsed ultra-sonic technique. Two instruments, the Ultrasonic Attenuation Comparator (Sperry) and the standard type Reflectoscope (Sperry) were used for measurements of the attenuation of the ultrasonic pulse. The effects of elastic tensile and compressive stresses on the attenuation of annealed and cold worked material are described. In addition, the effects of plastic de-formation, relaxation and aging processes and different ultrasonic test frequencies are reported. The results for Armco iron, SAE 1020 steel, SAE 4340 steel and AISI 420 stainless steel are shown. Under the test conditions, the attenuation was found to be largely a sum of two components; a ""dislocation"" component associated with the losses accompanying the oscillations of dislocation line segments and a ""ferromagnetic"" component associated with the microeddy currents generated by magnetic domain wall oscillations. Either of these components might be dominant depending on the nature of the particular specimen and the test conditions. Finally, the possibilities of using ultrasonics in residual stress determinations, in fatigue studies and in the study of the ductile-brittle transition in ferrous materials, are briefly discussed."

Jan 1, 1960

By M. H. Moys, J. A. Engelbrecht

"Large-diameter flotation columns are subject to severe axial mixing which has reduced column recovery and has generally limited it to cleaner applications. It has been assumed that columns with diameter greater than 1 m should be baffled to reduce axial mixing, but little work has been reported quantifying the effectiveness of baffling. Tests were done on a 0.2 m by 2 m column fitted with baffles of different geometry. It was generally found that the inclusion of baffles in the column worsened rather than improved mixing conditions in the column. This is explained in terms of a model for the effect of poor gas distribution on the behaviour of the column; this showed that under typical conditions a 16% excess of gas flux in the one compartment of a two-compartment column could result in one of the compartments being ""dead"" (i.e. with no net flow of slurry through it), resulting in a substantial loss of performance. The quality of mixing in the laboratory column was only reliably improved when the baffle was raised so that its top was positioned above the froth-slurry interface level. It should be possible to increase column recovery substantially with this configuration. The improved residence time distribution also means that columns can be used more effectively in roughing and scavenging applications. IntroductionFlotation columns have generally been used in cleaner applications, starting with their dramatic success at Mines Gaspe(1). Their lack of applications as roughers and scavengers is probably due to their poor residence time distribution (RID) when compared to the conventional cells they would replace. Espinosa-Gomez et al,(2) recently used them in rougher applications but installed three columns in series, presumably to cope with this disadvantage.Dobby and Finch in their seminal papersl(3,4) on the scale-up of flotation columns were the first to quantify the impact of axial mixing on the performance of industrial flotation columns. Laplante et al.(5) collected further data from the literature for column diameter D, ranging between 5 cm and 183 cm, gas superficial velocity Jg ranging between 0.7 cm/s and 2.8 cm/s and per cent solids in the feed S ranging between 3% and 52%. These data were analyzed with reference to the axial mixing model using the boundary conditions for closed vessels (the latter are more appropriate for flotation columns but the model is more difficult to use because analytical solutions for the RID are not available). The data were correlated by:"

Jan 1, 1993

By Y. M. Shneerson, P. V. Zaytsev, I. V. Fomenko, M. A. Pleshkov

A thermodynamic description of the equilibrium in liquid and gas phases under specific conditions of refractory gold pressure oxidation was generated using the HKF theory. The gold behavior was considered at 190-225°C in the presence of 1-100 mg/L of chloride ion, and under oxidationreduction potential (ORP) of +700 to +1030 mV. The calculations show that the predominant form of gold(I) occurrence is [AuOH]° compared to [AuCl2]?. High ORP favors the formation of [AuCl4]? as a predominant form of gold(III). It is noted that this complex is responsible for the gold losses buildup during POX. Laboratory test results for double refractory concentrate POX are shown. The combined negative effect of (i) organic carbon of the concentrate and (ii) dissolved chlorides in POX slurry on gold recovery is demonstrated. The effects of carbonate blending to the POX feed concentrate and incomplete oxidation of sulfides on POX performance were studied. The pilot tests results of continuous pressure oxidation are also shown and generally confirm the laboratory results and theoretic dependencies. A comparison of the experimental data with the results of thermodynamic calculations is made. As a result of current research, an effective process for POX treatment of carbonaceous sulfide concentrates in the presence of chlorides was developed.

Jan 1, 2014