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By Rosie Moore, Harvey Keats, Kerry Sparkes, A. J. Naldrett

"Abstract-The Voisey’s Bay Ni-Cu-Co deposit was discovered in late 1994 as the result of prospecting initiated in the summer of 1993. By July 1995, proven mineable reserves were 31.7 x 106 tonnes grading 2.83% Ni, 1.68% Cu and 0.12% Co, and current total resources in all categories are quoted to be in the order of 150 X 106 tonnes. The deposit is associated with a body of troctolite belonging to the Nain Anorthosite (1.35 Ga - 1.29 Ga) suite, which was emplaced across the boundary between the Proterozoic "Rae" Province to the west and Archean "Nain" Province to the east.The deposit can be described in terms of three geological settings. The "Ovoid" is a 600 m long by 350 m wide by 100 m deep lens of massive sulfide, covered by 10 m to 20 m of glacial overburden, and separated from the underlying country rock quartz-plagioclase-biotite gneiss by a breccia of gneissic fragments in troctolite known as the Basal Breccia Sequence. To the west of the Ovoid lies the "Western Extension", comprising disseminated and massive sulfides in a north-dipping sheet of troctolite which ranges from upper unmineralized troctolite down through troctolite with increasing amounts of sulfide (up to 50%), to massive sulfide (in some places only), and then to Basal Breccia Sequence. East of the Ovoid, the troctolite sheet broadens out into a troctolite intrusion, within which occurs the "Eastern Deeps", a zone of massive and disseminated sulfide up to 100 m thick that is currently being explored. The mineralization of the Eastern Deeps lies along the line of intersection of a feeder sheet with the base of the intrusion. The current interpretation is that the three geological environments represent different erosional levels through a single mineralized intrusion. In this model, the deepest erosional level lies to the west and exposes the feeder to surface, whereas the Ovoid represents the base of the intrusion at surface, and the Eastern Deeps the base of the intrusion overlain by 600 m to 900 m of troctolite. Sulfides and gneissic fragments were brought up by magma flowing quickly through the feeder, and settled out where the flow rate decreased as the sulfide-bearing magma mixed with magma already emplaced in the intrusive body."

Jan 1, 1996

By G. Lyle

Since its inception CEMI (Centre for Excellence in Mining Innovation) has focused on facilitating innovative solutions to the mining industry in six strategic research areas; GeoRisk, ConstructMine, ValueMine, FindMine, SustainMine and MineTech (visit www.miningexcellence.ca for details). This paper focuses on CEMI?s largest project to date, Ventilation on Demand (VOD). Energy consumption in mines can account for upwards of 40% of a mines operating cost, with a significant portion of this been consumed by the ventilation requirements. VOD provides a significant opportunity to reduce overall mine ventilation requirements and subsequently energy costs, while potentially increasing mine productivity. CEMI is currently in year 2 of an assessment of VOD, focusing on the financial, physical and equipment viability of utilizing such systems in both new and existing mines. This two year program, to be completed by March 31, 2011, is designed to systematically assess such a system to determine if and when it could effectively be applied in underground mines. The paper will describe the process by which the project was initiated, the demonstration projects established to capture data, the means to interpret the data and the modelling developed to calibrate and predict ventilation system requirements.

Oct 1, 2010

By D. Larouche, M. Mardan

Hot tearing is a complex defect in aluminium castings which is produced during solidification when a certain amount of liquid phase remains and weakens tensile resistance of the alloy. In direct chill casting of aluminium alloys, hot tears initiate at the surface of sheet ingots just after the primary cooling zone, where the microstructure is particularly vulnerable. In order to study the hot tearing susceptibility of these alloys, and the effect of grain refiners on their thermo-mechanical behavior , tensile tests were carried out in the semi-solid state ( ~95% solid) and at low strain rates using an apparatus called DCSS, for Direct Chill Surface Simulator. This apparatus, originally developed at Alcan Arvida R&D Centre (ARDC), is an instrumented rig test reproducing the conditions prevailing during the primary cooling stage of the DC casting process. The mechanical behavior of solidifying shells and the hot tear formation under applied tensile loads were measured and the occurrence of hot tearing was observed. Temperature in different locations of the casting, applied load and surface strain were monitored during the tensile tests conducted on aluminum alloys AA5182, AA6111 and AA3104. The microstructure of the tested samples was examined using the optical microscope to evaluate their columnar or equiaxed aspect and their effect on the mechanical response of the alloy. A special emphasis has been given to the evaluation of fractions solid existing in the castings at the start of the tensile tests, taking into account the local temperature, thermal gradient and cooling rates experienced. It was found that excessive grain refiner additions decreased the strength of solidifying shells because of the increased level of porosity induced by easier nucleation of new phases (gas included). It was also observed that cooling rates increased with the level of grain refiner, a phenomenon that was associated to the higher number of contact points obtained with small equiaxed grains. Finally, the concept of a stress based criterion for hot tearing was reinforced by the strengths obtained on not grain refined AA5182 and AA6111 showing similar fraction solid near the surface, but significantly different grain sizes.

Jan 1, 2006

By P. Dinham, G. C. Summerton, N. McCulloch, S. Dowling, D. C. Craig

"Development of a process for the treatment of a nickel copper matte rich in the minerals heazlewoodite, chalcocite and bornite has demonstrated significant base metal recoveries and metal separation efficiencies. The determination of chemical and mineralogical changes occurring in the individual leaching stages in laboratory experiments has enabled a better understanding of the complex leaching chemistry. The chemistry and mineralogy of the piloting and laboratory processes are discussed.INTRODUCTIONThe nickel-copper sulfide ores of the South African Bushveld Complex are among the most important Platinum Group Metal (PGM) bearing ores, and contain the world’s largest reserves of platinum. The treatment used in the recovery of PGMs from these ores includes three types of processes, namely ore concentration using physical techniques such as flotation and gravity separation, concentration by pyrometallurgical means, hydrometallurgical extraction of the base metals followed by the PGMs. Following milling of the ore, flotation involves the separation of high value minerals from gangue by taking advantage of the differences in their hydrophobicity. These differences are generally maximized through the use of a surfactant or wetting agent. Concentrates are then thermally treated and melted which brings about physical and chemical changes that enable the recovery of base metals and PGMs. The main aim of the smelting and converting process is to separate and eliminate the valuable metals from the bulk of the unwanted gangue and essentially all of the iron and to concentrate the metal VALUES (into a high grade converter matte. The matte can be further enriched by magnetic separation, producing a PGM-rich magnetic fraction and a base metal-rich non-magnetic fraction. The magnetic fraction is treated by hydrometallurgical processes to produce a PGM concentrate which is further refined to separate and purify the individual metals. The non-magnetic fraction is treated to produce marketable metal VALUES (such as nickel, copper, cobalt and to a lesser extent PGMs. The principal objective of any hydrometallurgical extractive process is to leach the desired elements selectively into an aqueous phase so as to separate them from the bulk of the material. (Crundwell, Moats, Ramachandran, Robinson and Davenport, 2011; Hundermark, Mncwango, de Villiers and Nelson, 2011)."

Jan 1, 2012

By Claude Deveau

"With ever decreasing feed grades, finer mineralogy and increased demand for product, it became obvious that a major step in equipment performance was required to reduce operating costs and increase production. Offsite testwork indicated that a Centrifugal separator was capable of recovering fine tantalum and that the newly developed C Series Falcon concentrator would be capable of replacing many pieces of aging equipment and provide improved performance. Further investigation led to the rental and the purchase of a Falcon C20 concentrator followed by a C10 to maximize circuit performance.Falcon Concentrators Inc’ s practice of working with the customer mirrors Tantalum Mining Corporation of Canada’s (Tanco) philosophy of continuous product development. This synergy honed valve design for continuous operation in a highly abrasive ore environment.Tanco has recently purchased two more Falcon concentrators for the recovery of additional tantalum from its spodumene circuit. These new units have additional user friendly operating features partially based on developments made at Tanco.The Falcon C Series units have enabled Tanco to maximize recovery of tantalum that was otherwise lost while using the original conventional gravity circuit."

Jan 1, 2000

"In mineral exploration and mining applications, it is sometimes necessary to reduce sampling error in order to improve representivity of individual sample assays. Historic efforts to reduce sampling error have relied on the belief that larger samples exhibit less sampling error. Justifications for this belief traditionally have coupled the binomial theorem with an ideal geological material consisting of ore and gangue particles of equal size and shape (an equant grain model) and empirical tests of geological materials, to illustrate an inverse relationship between sample size and sampling variance. To date, no proof exists of this sample size-sampling variance relationship in real geological materials exhibiting variations in grain size, shape, composition, and degree of liberation.Using first principles calculus and the formula for the mean, sample mass and sampling variance are proven to be inversely proportional in all geological materials. Distribution assumptions and physically ideal geological models are not used in this proof. Furthermore, algebraic manipulations of expressions describing the variances of equant grain models consistent with binomial, hypergeometric, and Poisson distributions reveal that these models also exhibit an inverse sample size-sampling variance relationship. Thus, the sampling behaviors of these models are numerically consistent with the sampling behaviors of real geological materials, and these models can be used to estimate sampling errors in real geological materials using simple sampling parameters."

Jan 1, 2007

By J. P. Messervey

THE story of the efforts made by the Department of Mines of Nova Scotia in the search for and investigation of mineral resources for the Canadian war effort began in the spring of 1937. During the past five years, however, heavy enlistments in the Active Service Forces by employees of the mining industry of the Province caused a recession in the production of coal, salt, and other essential minerals required to keep industry rolling on a wartime basis. A marked increase was shown during the period in prospecting for 'strategic' minerals, not only by individuals but also by some of the foremost mining companies. The Provincial Government offered encouragement in this field of endeavour by the enactment of legislation whereby the prospector was enabled to secure the maximum area of ground in a prospecting license at a minimum of cost. The labour requirements on the ground staked, however, remained unchanged. The Nova Scotia Department of Mines continued active investigation of minerals vital to the war effort. These included fluorspar, barytes, diatomite, limestone, and coal. Fundamental knowledge concerning the geology and mode of occurrence of these minerals was accumulated and extensive diamond drilling was carried out on the promising occurrences. Work in these fields is being continued.

Jan 1, 1945

By M. H. Haycock

Introduction The property of Rouyn Merger Gold Mines, Limited, is in Rouyn and Joannès townships, Western Quebec, seven miles east of the town of Rouyn. Traversing it is the east-west trending Cadillac-Bouzan fault. Diamond drilling in 1944 and 1945 along a shear zone south of the fault indicated an ore deposit lying at the contact between sedimentary and volcanic rocks and dipping approximately 60° to the northwest. In the summer of 1945 it was decided to sink a shaft to investigate the indicated ore zone. In the immediate vicinity of the deposit, bed-rock is overlain by clay beds, in some places as much as 70 feet thick. Consequently, possible shaft sites were limited to those locations where overburden would not be excessive. The most favourable site was about 125 feet to the south of the ore zone as projected vertically from bed-rock to the surface. Accordingly, it was decided to sink the shaft at this point, with an inclination of 60° N. W., paralleling the dip of the ore zone.

Jan 1, 1948

By Wendy L. Naysmith

This paper deals with the various options considered and factors that influenced the final selection of the headframe, shaft layout and hoisting systems required at the Impala No 16 Shaft in order to hoist both the required 3 Mt of ore per annum, and transport men, material and equipment between the surface and the underground workings to a depth of 1640 m. The layout and construction method used for what is at present the world?s tallest concrete headframe is discussed together with the integrated hoist room foundations designed to suit multiple mechanical and electrical hoist supplier?s solutions. The mechanical components of the two tower mounted 6,5m 4 rope Koepe hoists and deflection sheaves and their layout is dealt with in detail. Various features of the bearing type, brake units and brake control system are also discussed. Installation of the mechanical and electrical hoist equipment in the headframe took place during the sinking phase of the project and placed severe restrictions on the use of the heavy lifting facilities. This required a well-managed and systematic approach to delivery of the hoist components and associated equipment, as well as close co-operation between all contractors on site.

Oct 1, 2010

DOME MINES, Limited, is a gold producer situated in the Porcupine area of Ontario, 500 miles north of Toronto. During the year 1960, '71 4,600 tons of ore were milled, yielding gold bullion valued at $6,025,370. Prior to conversion to natural gas, an average of 3,200 tons of coal was consumed annually, one third of which was obtained from Canadian sources with the remainder coming from the United States. Due to the distances involved, the freight charges increased the pithead cost by as much as ISO per cent. Steam is generated at a central boiler plant and used for timber treatment, plant heating and process steam. Until August, 1960, steam was supplied during the winter months by two water tube coal-fired boilers, each rated at 200 boiler horsepower at 100 per cent output. Steam requirement was as high as 150 per cent of boiler rating in the colder periods. The summer load was

Jan 1, 1962

By C. Patel, George H. Hope

"INTRODUCTIONThe Hemlo area is located in Northern Ontario, some 350 km east of Thunder Bay along highway 17. Hemlo is Canada's largest, recent discovery of gold ore. Three companies, Lac, Noranda, and Teck are currently developing mines and processing facilities in the area. A combined milling capacity of approximately 10,000 tonnes per day will ultimately be available in the area. The gold yield will be between 750,000 to 1,000,000 ozs. per year. This will slightly more than double Ontario's gold production but only represents 2.5% of the total world gold production.Lac Minerals Ltd. is substantially committed to the gold mining business. Lac currently operates four (4) gold mines and mills and produces 300,000 ozs. per year. Lac's Hemlo development will put the company in the position of number one gold producer in Canada.The Lac Hemlo ore body has an estimated reserve of 37 million tonnes at 6.2 g/t. The mining will take place at an initial rate of 3,000 t/d commencing in the first quarter of 1986. The mine and plant will be expanded to 6,000 t/d in 1988. At this capacity, Lac will be the largest producer in the Hemlo area.1. GEOLOGYThe orebody is divided into two (2) zones for mining purposes. The 'A' Zone is to the east and dips to the Northeast from surface to 300 m below surface. This zone has a strike length of 250 m to 300 m at an average width of 20 m. The upperpart of the zone will be mined by open pit and the remainder from underground. The 'B' Zone, to the north west of the 'A' Zone, although lined up is not necessarily an extension of 'A' Zone. 'B' Zone has a known strike length of 600 m and is open to depth and along the strike. It is over 70 m wide in the core. This zone holds most of the property's known reserves. 'C' Zone with narrow gold zones is under exploration in the south west portion of the property."

Jan 1, 1985

By T. S. Li, D. Ilievski, I. Livk

Micromixing of the fluid and the particulate phases in a continuous gibbsite precipitator was investigated for three different micromixing states, namely maximum mixedness (MM), complete segregation (CS), and maximum mixedness of the fluid but complete segregation of the particulates (MMF-CSP). The influence of the micromixing on continuous precipitation of gibbsite was studied at different precipitation conditions via simulation. Three different cases were considered with respect to the precipitation kinetics: (1) gibbsite secondary nucleation is favoured with slow crystal growth and agglomeration rates; (2) gibbsite crystal agglomeration and growth are dominant mechanisms with secondary nucleation suppressed; and (3) gibbsite crystal growth is the only relevant phenomenon. Simulation results for the cases (1) and (3) showed that the crystalline products for both the MM and MMF-CSP micromixing states were very similar, but the product obtained from the CS micromixing state was considerably different. This indicates that at those precipitation conditions the fluid micomixing has the dominant effect on the product properties, and the particulates micromixing effect is insignificant. However, when operated under the conditions of fast crystal growth and agglomeration kinetics, i.e. case (2), both the fluid and the particulates micromixing were found to affect the precipitation process, resulting in a significantly different product. Computational Analysis in Hydrometallurgy 35th Annual Hydrometallurgy Meeting held in conjunction with the 44th Annual Conference of Metallurgists ofCIM Calgary, Alberta, Canada Edited by

Jan 1, 2005

By Jian Li, Robbie McDonald, David Robinson

"The pressure oxidation of sulfide minerals at temperatures above 200°C enables the extraction of base metals, improves the extractability of gold from refractory ores, enables solubilisation of PGEs and can be used to hydrothermally upgrade base metal-containing feeds. Fundamental studies reveal that the solution chemistry (and mineralogy of the solids) during pressure oxidation can be manipulated with outcomes that include (1) increased leaching rates, (2) lower oxygen requirements and (3) the formation of chemically more stable residues. This paper presents examples describing how these outcomes might be achieved based upon fundamental investigations.INTRODUCTION The application of pressure oxidation to the processing of gold ores and concentrates dates back several decades and continues to be the process of choice at operations such as Pueblo Viejo (pyritic gold) which host the largest autoclave of its kind in the world (Barrick Gold Corporation, 2016). Commercial application to the processing of base metals and PGMs resides with long established processes such as the Sherritt process, ore specific applications such as by Noril’sk, at Sepon etc. or has not proceeded to date beyond pilot scale testing (e.g. Phelps Dodge, CESL, Activox, Platsol). Recently there has been significant interest in hydrothermal upgrading options for concentrates including the NONOX and Toowong processes (Rohner et al., 2016; Weidenbach et al., 2016). The latter options suggest directions where sound knowledge of the underlying fundamentals enables novel outcomes and efficiencies to be obtained. It comes as no surprise that investigations similar to those underpinning these developing processes can be traced back several decades. It is not the subject of this paper to provide a historical perspective of the relevant autoclave chemistries but rather, to present some potential opportunities suggested by studies in our laboratories. Topics to be discussed in this paper include (1) control of metal extraction rates, (2) control of iron-residue composition and (3) control of sulfur oxidation and hence acid generation and oxygen requirements. The work described will focus upon the pressure oxidation of a nickel concentrate."

Jan 1, 2017

By A. G. Matyas

Process improvements which have reduced the lead content of slag from the Brunswick lead blast furnace are described. Microscope examination and electron microprobe analyses, supported by the results of slag settling and viscosity tests, showed that typically about 70% of the lead in the lead blast-furnace slag was present in the form of entrained prills of metallic lead. The total lead content was found to increase with the magnetic susceptibility of the slag. Measurements in the furnace settler indicated the presence of a magnetite-rich layer between bullion and slag, arising from high magnetite levels in the slag. This layer was believed to inhibit the settling of entrained lead from the slag. Tracer tests showed that the average slag residence time in the settler was less than 2 minutes. Improvements in coke quality and sizing, which led to a reduction in the slag magnetite content, and the installation of a larger settler and a continuous Roy tapper, have all contributed to a significant decrease in the slag lead content.

Jan 1, 1977

By R. K. Kandasami

"Naturally occurring geomaterials such as sandstone, limestone and other soft rocks, residual soils are composed of a particulates held together through a cohesive matrix, usually composed of argillaceous or siliceous cementing agents. Geo-materials such as these have been reconstituted in the laboratory using ordinary Portland cement in lieu of the naturally occurring cohesive matrix, in addition to using sand particulates. This cohesive frictional granular ensemble is an ideal model material for understanding the mechanical behaviour of transitional geomaterials such as soft rocks. An important consequence of this cohesion that pervades the inter particulate system is the enhanced tensile strength when compared to a purely granular ensemble. The assessment of strength of these soft rocks and cemented sands is often understood in the framework of continuum mechanics, i.e. considering the cemented sand to be a continuum, and performing simple elemental tests such as uniaxial compression or tension tests. A simple model to describe the behaviour of these cemented sands has been to use elements such as springs, sliders, and dashpots in parallel to describe the existence of a cohesive and frictional component of strength (Jiang et al. 2007). In the framework of continuum mechanics, the mechanical response of these cemented sands have been modeled using traditional plasticity theory, for example utilizing variants of the traditional Mohr Coulomb model, Modified cam clay (Sun and Matsuoka 1999) etc. The typical sand models are amended to include the effects of cohesion, as proposed by Lagoia and Nova (1995).The mechanical response of cemented sands is understood to be transitional to the behaviour of a typical particulate assemblage and a quasi-brittle material. However, the effect of length scale in these material systems has not been investigated. This paper presents a series of uniaxial compression experiments conducted on weakly cemented sand specimens of various sizes. The effect of length scale in these weakly cemented sands is investigated through unconfined compression tests."

Jan 1, 2015

By Stephen A. Gasiorowski, Frank J. Hrach, James D. Bittner

Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. The environmentally friendly process can eliminate wet processing and required drying of the final material. The process requires little if any pre-treatment of the material other than grinding and operates at high capacity - up to 40 tonnes per hour by a compact machine. Energy consumption is low, approximately 1 kWh/tonne of material processed. Since the only potential emission of the process is dust, permitting is typically relatively easy. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs. The triboelectric particle charging is effective for a wide range of materials and only requires particle-particle contact. The small gap, high electric field, counter-current flow, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features of the ST separator. The high efficiency multi-stage separation through charging / recharging and internal recycle results in far superior separations and is effective on fine materials that cannot be separated at all by the conventional electrostatic techniques. Since 1995, this triboelectric process has been extensively used for the beneficiation of coal fly ash with eighteen separators in place and over 100 machine-years of operation at locations in North America and Europe. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash.

Jan 1, 2012

"Introduction The first documentary record of coal nurung on Vancouver Island was that of the Hudson Bay Company operations in the Suquash area in 1836. Between 1836 and 1862, the Hudson Bay Company mined some 65,000 tonnes from this Suquash field and the Nanaimo coal fields discovered in 1851. However, systematic mining of coal did not take place until the Hudson Bay Company holdings were sold to the Vancouver Coal Company in 1861, and a rival company under Robert Dunsmuir was established in 1869. These two interests under various organizational names and jointly as the Canadian Collieries (D) Ltd. (1928) developed and exploited the coal seams of the Nanaimo and Comox Basins from 1852 to 1966. Because of the proximity of the coal outcrops to tidewater, the coal was readily marketed to ocean-going and coastal ships for fuel. However, during the turn of the century the main market was to meet the demand of the developing cities along the west coast of Canada and the United States for residential and commercial heating. Island-based copper smelters and brick factories, and the coming of the railroads motivated by steam engines increased the demand. This economic success of the industry continued until 1922 when a peak production of over 1,750,000 tonnes was reached. Following 1922 labour unrest in the industry, which affected the certainty of supply, and the availability of alternatives in the form of California petroleum and mainland coal combined to cause a rapid and steady decline in the demand for Island coal. In spite of post-and pre-wartime prosperities the trend could not be reversed. Serious coal mining phased out in the Nanaimo area in 1939 and in the Comox area in 1967. puring the 114 years in which the industry flourished over 75 million tonnes of coal were mined from more than 30 mines and a minimum of ten new mining communities were established on Vancouver Island."

Jan 1, 1985

By D. J. MacDonald

UNDERGROUND development at the Lynn Lake property of Sherritt Gordon Mines, Limited, was begun in 1948 with the sinking of the A shaft in the area of the A orebody. By June, 1949, the shaft was completed to a depth of 1,024 feet. Twelve stations were cut, with the bottom level at 992 feet below the collar. Since completion of the shaft, lateral work has been carried out on the 12th level in order to expose the known orebodies and to provide openings from which deeper exploration could be conducted. Dur¬ing the change-over from sinking to lateral work, preliminary diamond drilling was done from the 12th level station to locate the A? ore-body. Later, drilling was carried out from the 5th and 9th level sta-tions, where, also, the outline of the A orebody was established. As the work progressed on the 12th level, and with the commence-ment of drilling below that level, the geological picture was found to be complicated by numerous faults. Instead of operating two drills it became necessary to use at least four. The original plans had provided air sufficient to drive two headings and to operate two diamond drills. The addition of two more air-driven drills resulted in a serious shortage of power.

Jan 1, 1951

By D. M. Maijer, S. L. Cockcroft, S. Modak, A. B. Phillion

"A comparison between hydrogen-diffusion-based micro-porosity formation and growth behaviour of two important aluminium foundry alloys, B206 (Al-Cu) and A356 (Al-Si-Mg) is presented in this paper. Specifically, the predicted pore size and pore fraction distribution of these two alloys resulting from directional solidification and identical hydrogen concentration are investigated numerically based on a model proposed by Yao et al. (2011. Met. & Mat. Tran. A. 42A, 4137–4148). This model takes into consideration the initial hydrogen content in the melt, the cooling rate, the partitioning of hydrogen between the solid and liquid phases, and the evolution in solid fraction with temperature. Due to different alloy chemistries, the activity of hydrogen in B206 and A356 are quite different, as are the solidification range and the resulting solidification microstructure. Being a primary alloy, B206 has dendritic microstructure and solidifies over nearly 135°C (505–641°C), whereas A356 contains fifty percent eutectic microstructure, and solidifies over 80°C (533–613°C). This allows a very different behaviour of micropores i.e. the effective pore radius in B206 is quite a bit lower as compared to A356, as is the pore number density. The evolution of local hydrogen concentration in liquid metal is analysed and compared for both the alloys.INTRODUCTION Over the past decades, the demand for materials with enhanced strength-to-weight ratios has significantly increased in the aerospace and automobile industries in order to improved fuel efficiency. For many automotive components, particularly shape castings, the trend is towards replacing ferrous alloys with aluminium alloys. The increase in the use of Al is primarily due to its low density, about one-third that of steel, and its relatively good strength that allows for weight reduction without reducing performance. Presently, Al-Si based alloys (e.g. A356) are the most prevalent due to their good mechanical performance in strength-to-weight ratio and excellent castability (Atwood et.al., 2000). However, superior mechanical properties can be achieved using Al-Cu alloys. For example, the alloy B206 offers a higher strength while retaining excellent ductility (Poirier et.al., 1987)."

Jan 1, 2017

By J. L. Jambor, E. J. Reardon, E. C. Appleyard, J. A. Cherry

Abstract- Since the 1957 initiation of deposition of mill tailings at the Heath Steele mine, New Brunswick, periodic detailed studies of the tailings geochemistry and mineralogy have been con­ ducted, thereby providing a unique opportunity to examine the geochernical evolution of a sulfide- rich mine-tailings impoundment. When deposited, the tailings contained about 85 wt% sulfide minerals, 1 wt% to 3 wt% carbonate minerals, and 12 wt% to 14 wt% aluminosilicate minerals. Mineralogical examination of samples of the tailings from deep in the impoundment indicates that little oxidation occurred prior to tailings deposition. The mill process-water deposited with the tailings was neutral to slightly basic and contained low concentrations of Cu, Pb, Zn and As. Sampling of the tailings five years after deposition indicated that sulfide-oxidation reactions, occurring near the tailings surface, had decreased the tailings-water pH and increased the concentrations of Fe, SOi-, Cu, Zn and Pb (up to 10 000 mg/L, 25 000 mg/L, 2.5 mg/L, 200 mg/L, and 4.5 mg/L, respectively) . In 1975, ten years after decommissioning, the tailings could be divided into three zones: an upper oxidation zone in which sulfide oxidation is actively occurring, a hardpan layer, 15 cm to 20 cm thick, composed of tailings cemented by secondary Fe minerals, and an underlying reduction zone in which the tailings are relatively tinoxidized (Boorman and Watson, 1976). Chemical analyses indicated the presence of low-pH waters containing very high concentrations of SO42- , Fe, and other metals (up to 63 600 mg/L SO42-, 28 600 mg/L Fe, 10 mg/L Pb, 600 mg/L Cu and 4000 mg/L Zn), suggesting that there was a period of intense sulfide oxidation between five and ten years after tailings deposition. More recent sampling, conducted some 20 years after the end of tailings deposition, indicates that relatively little change has occurred in the last ten years, thereby suggesting that the hardpan layer has provided an impediment to the downward movement of dissolved constituents . Analyses of the tailings solids show increased accumulations of many metals at or near the depth of the hardpan layer. Evaluations of the long-term evolution of the tailings can be enhanced by comparison of descriptions of the tailings with descriptions of the gossan that overlay the massive­ sulfide orebody prior to mining. At Heath Steele, this comparison suggests that many of the mechanisms controlling the distribution of metals in the tailings will probably persist over geologic time.

Jan 1, 1992