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By R. M. Graves, C. B. McKenzie, D. Barbour, D. W. Desnoyers

"Abstract -The prospective Tulks volcanic belt hosts five significant massive sulfide deposits, Tulks Prospect, Tulks East, Jack's Pond, Daniel's Pond and Victoria Mine, as well as numerous showings and indications throughout its 70 km outcrop length. Regionally, the 498 Ma sequence consists dominantly of felsic pyroclastic rocks and flows with interbedded mafic volcanic units and fine­ grained sediments, commonly graphitic. Contemporaneous granitoid rocks occur in the south half of the belt. Rocks usually display a strong NE-SW, steeply dipping, penetrative foliation and other shear-related high-strain fabrics. Facing directions are normally northwest, although there is local evidence of folding. Sulfide bodies and their alteration systems are deformed and shape-modified in the style of ambient strain.The Tulks, Tulks East and Jack's Pond prospects appear to occupy a similar stratigraphic level, on or near the contact between a thick felsic pile and an overlying broad, conductive package of graphitic sedimentary rocks. AU are pyritic deposits with well-developed footwall alteration systems. The Tulks prospect comprises four polymetallic lenses totalling 750 000 t. Three lenses constituting more than 6 000 000 t of sulfide mineralization are indicated at Tulks East but only the 210 000 t ""B"" lens contains significant base metals. Jack's Pond consists of a very extensive, zoned alteration complex in which four lenses of massive to semi-rnassive pyrite + chalcopyrite are known.The central part of the system, characterized by Mg chlorite and carbonate, is enveloped by pervasive sericitization and capped by intensely silicified and pyritized volcanics. The sulfide lenses are interpreted as part of the footwall zone and are beneath that part of the system most likely to host polymetallic massive sulfides.Daniel's Pond differs from the other prospects in such fundamental ways as metal content, associated alteration and structural setting. The deposit comprises strongly tectonized, Ag-rich, Zn-Pb mineralization distinguished by a pronounced Ba-As-Sb signature. Mineralization is confined to a narrow, north-south high-strain zone which separates unstrained mafic volcanic rocks to the east from well-foliated felsic rocks. The deposit Jacks an extensive alteration halo and at its north end is associated with a lens of barren, undeformed massive pyrite.The Victoria Mine deposit, the most cupriferous of the five, is related to a moderately dipping structure that separates well-foliated Tulks volcanic rocks from an overlying, Jess deformed volcanic­ sedimentary sequence that may be as young as 462 Ma. The structure is also the locus of black chlorite, dolomite and quartz alteration. Structurally remobilized precursor sulfide mineralization is one possible source for the deposit."

Jan 1, 1993

By Chuan-Jian Zhong

Gold-based nanoparticles in the size range of a few nm have attracted increasing interests in catalysis, sensors and biomedical applications. The study of the unique catalytic properties of nanosized gold was inspired by the pioneering work of Haruta on the nanogold-catalyzed CO oxidation (1-4). There have been a number of excellent reports discussing both fundamental and application aspects of gold nanoparticles in catalysis (3-8). Our work reported herein is aimed at investigating the preparation and application of gold and its alloy nanoparticles for potential applications in fuel cell catalysis. Fuel cells operating by electrochemical oxidation of hydrogen or methanol fuels at the anode and reduction of oxygen at the cathode are attractive power sources due to their high conversion efficiencies, low pollution, lightweight and high power density. While methanol offers the advantage of easy storage and transportation in comparison with hydrogen fuel cell, its energy density (~2000 Wh/kg) and operating cell voltage (0.4 V) are much lower than the theoretical energy density (~6000 Wh/kg) and the thermodynamic potential (~1.2 V). The poor activity of the anode catalysts and inefficient activity or issue related to "methanol cross-over" at the cathode electrode are associated with the loss of about one-third of the available energy at the cathode and the other one-third at the anode. Extensive studies have been focused on Pt-group metals (Pt+Pd+Rh+Ru+Ir (PGM)) for both anode and cathode catalysts. A major problem is the poisoning of Pt by COlike intermediate species (9,10). Recently, oxide-supported gold nanoparticles in the <10 nm size range have emerged as one of the best catalysts for CO oxidation (1-3,11), and for water gas shift reaction in reforming stage using 5 nm Au on Fe2O3 (6). Gold and its alloy with other metals in the nanosize range present new alternatives (2,12). Whether the unique properties of gold nanoparticles can be exploited for addressing these problems is a focus area of our work. The ability to harness the large surface area-to-volume ratios and the unique surface sites of nanoparticles in <10 nm size range, especially in heterogeneous catalysis, constitutes a major driving force in fundamental research and practical applications of nanoparticle catalysts. It is this size range over which the metal particles undergo a transition from atomic to metallic properties. The understanding of factors controlling the morphological and surface reconstitution associated with such a size range is of fundamental importance to the ultimate exploration of nanostructured catalysts. We have been investigating the interfacial structures and properties of core-shell types of nanoparticles consisting of gold or alloy nanocrystal cores and organic monolayer shells that were prepared by twophase synthesis (13) and processing (14) protocols. Important attributes of such nanoparticles include controllable size monodispersity, processibility, and stability towards size- and composition-tunable catalysis (15-21). Some of these attributes were studied for understanding their electrocatalytic properties in the oxidation of methanol and reduction of oxygen, which are of fundamental interest to fuel cell technology.

Oct 1, 2003

By A. Hayatdavoudi, D. Chitila, F. Boukadi

"Shale oil and gas have provided a tremendous boost to energy production in the United States even though the characteristics and behavior of shale are yet to be fully understood. Hydraulic fracturing is often applied to horizontal shale wells to stimulate production. This experiment seeks to determine effects of cyclic variable temperature, water vapor and exposure time on shale micro fracture propagation. We used 22 small Pierre shale specimens and subjected them to aforementioned conditions. Fractures developed in 19 specimens. Combination of high temperature and high water vapor generated the largest number of micro fractures on the specimen surfaces.INTRODUCTIONShale oil and gas have contributed immensely to energy independence in the United States. Most if not all shales depending on their total organic content (TOC) and their clay content bear the promise of being a source rock. For example, the Eagle Ford shale play, located in south Texas, is one of the key contributors to the recent rise in oil and gas production in the United States. Data from the U.S. Energy Information Administration (EIA), published in 2014, states that monthly oil production from Eagle Ford wells increased from 340 barrels per day (bbl/d) in January 2009 to nearly 1 million bbl/d in June 2013. Natural gas production has also increased at a similar rate over the same period, from 5.8 million cubic feet per day (MMcf/d) to nearly 4,000 MMcf/d (EIA, 2014).According to the railroad commission of Texas (RRC) 2014 published information, the Eagle Ford shale play is an important play because it produces gas and more oil than other shale plays in the United States. It is an organic-rich play with carbonate shale percentage in the 70% range in south Texas and the shale content increases moving to the northwest. High carbonate proportion renders this play brittle and suitable for hydraulic fracturing treatments."

Jan 1, 2015

By Peter Hayes, Evgueni Jak, Taufiq Hidayat, Gary O’Connell, Denis Shishin, Jeff Chen, Francis Letarte

"Knowledge of slag properties is required for the optimisation of smelting operations. The phase equilibria and viscosities of the Al2O3-CaO-FeO-Fe2O3-MgO-MnO-NiO-Cr2O3-SiO2 slags at conditions of interest to Koniambo Ni-laterite smelting operations have been investigated. High-temperature re-equilibration phase equilibrium experiments of industrial slags followed by rapid quenching and direct measurement of phase compositions using electron probe X-ray microanalysis (EPMA) have been undertaken in the olivine and pyroxene primary phase fields at temperatures between 1475 and 1600°C and SiO2/MgO weight ratios between 1.57 and 2.09. Phase equilibria predictions were performed using FactSage thermodynamic software. A slag viscosity model available in the FactSage thermodynamic package has been used to calculate the viscosities of the liquid slags. The Einstein-Roscoe equation combined with the predicted phase equilibria data have been used to estimate the viscosities of the slag slurries (slag + solids). The information provided can be used to assist in the evaluation of the furnace performance, to assess further optimisation of slag composition and to explore possibilities of targeted feed changes.INTRODUCTION One of the key steps in the production of ferronickel from nickel laterite ore at Koniambo Nickel SAS involves reduction and smelting of pre-dried nickel-bearing saprolitic ore (high Mg and Si) in an electric furnace at temperatures up to 1650°C. The characterisation of the slag properties as functions of key operational parameters, such as, temperature and composition, including liquidus, the proportions of solids and viscosity, is essential for improving control and optimisation of the operations. The slag produced in the smelting process is a complex oxide system with the major chemical components including Al2O3, CaO, Cr2O3, “FeO”, MgO, “MnO”, “NiO” and SiO2. Characterisation of these multi-component systems using a solely experimental approach becomes increasingly complex as the number of components is increased."

Jan 1, 2017

By S. Kahraman, K. Develi, E. Yasar

Four hydraulic top hammers, one pneumatic top hammer, and three down-the-hole drills were observed in several rock types at quarries and highway construction sites to measure the performance data. At the same time, drill cuttings from each drill hole were collected for the determination of the coarseness index (CI), which is the sum of cumulative weight percentages of a particular size-graded sample of debris, and for the determination of median particle size (MPS), which is defined as the particle for which the quantity of particles equals 50% of the total of the cumulative distribution. After the sieve analysis was carried out on the drill cuttings in the laboratory, CI values were calculated and MPS values were obtained from the plots of cumulative undersize vs particle size. The performance data of the drills, CI values, and MPS values were analyzed using the least square regression method. It was seen that strong linear relationships usually exist between penetration rates and CI values, and penetration rates and MPS values for both top hammer drills and down-the-hole drills. Penetration rates increase linearly when increasing the CI and MPS values.

Jan 1, 2004

By R. E. Michelutti

"The Sudbury area environment became drastically altered commencing in 1871 with lumbering, repeated fires and early open roasting operations from 1887 to 1929. These combined factors had such a pronounced effect that approximately 24 square miles were totally denuded of any vegetation and 87 square miles were semi-barren to somewhat stressed.The two nickel producing companies in the area have reduced the sulphur dioxide emissions considerably over the years. Falconbridge Limited, alone, reduced sulphur dioxide emissions by 77% from 1971 to 1984.These reductions have resulted in improvements to the air, soil, lake and vegetation quality in the Sudbury area.INTRODUCTIONThe Sudbury area environment became drastically altered commencing in the 1870's with lumbering, repeated fires and early open roasting operations from 1888 to 1929. These combined factors had such a pronounced effect on the Sudbury environment that approximately 24 square miles (64 sq. km.) were totally denuded of any vegetation and 87 square miles (225 sq. km.) were semi-barren.Over the years, the Sudbury area environment has improved considerably. This has been due to emission cutbacks by both Inco Metals and Falconbridge Limited, coupled with industry, government and community reclamation programs. Before the improvements are discussed, a better understanding of the historical degradation is required."

Jan 1, 1986

By T. Salman

Most authorities agree that the dissolution of gold from an ore takes place according to the Elsner equation first stated in 1846. The main requirements for the dissolution reaction to proceed are:(1) that the gold be clean.(2) that the gold be exposed to the solution.(3) that the cyanide solution be active, i.e., not over loaded with impurities which could retard or inhibit the reaction.(4) that an adequate supply of oxygen be available (from air).When the above conditions are met, cyanidation becomes basically a mechanical operation.Minerals such as quartz, calcium carbonate are relatively inert to cyanide though they may give rise to mechanical troubles. Most ores present an assortment of chemical problems, depending upon the constituent present, which react to the solution to varying degrees. It should be borne in mind that minerals which are disturbing to the operation, though present in small amounts, usually exceed the weight of the gold by several hundred times. In addition, the application of flotation and other forms of concentration to gold ores, previous to cyanidation, concentrates not only the gold, but also the other heavy minerals and these complicate the chemistry of the process.

Jan 1, 1975

By Laszlo Imreh, Pierre Trudel, André C. Tessier

"The Siscoe gold mine is ranked as the fourth largest mine in the history of the Val d' Or mining district with a total production of 27.4 tAufrom1929 to 1949. Most of the gold mineralization occurred in quartz veins, hosted in a small (.69 km2) intrusion of altered quartz gabbro known as the Siscoe stock. The southern contact of the Siscoe stock is crosscut by a major shear zone (the ""K"" zone) trending 295/80 NE and from which gold mineralization was also exploited within the limits of the stock. Field and petrographic observations of the Siscoe stock combined with chemical analyses of major, trace and rare earth elements of the stock and its volcanic host rocks (Dubuisson Formation) suggest that:The Siscoe stock comprises four alteration facies formed from a homogeneous precursor: 1) the actinolite - Mg-chlorite facies, characterized by low FeOt,Na2O andTiO2 , and highAlp3 and MgO; 2) the albite- Fe-chlorite facies, containing high concentrations of FeOt and Nap; 3) the Mg + Fe-chloritefacies, which is transitional between the actinolite- Mg-chlorite and albite- Fe-chloritefacies; 4) the carbonate-chlorite facies, which consists of rocks that were subjected to extreme hydrothermal alteration, is spatially associated with mineralized veins and part of the K-zone. The first three facies are depleted in SiO 2, CaO and Au, and enriched in MgO, relative to fresh rocks of the Siscoe stock and the equivalent rocks of the Dubuisson Formation.Hydrothermal fluids introduced mainly along the K-zone ""channelway"" induced three types of element remobilization, resulting in the various alteration facies: 1) redistribution of elements within the stock from one facies to another (e .g., FeOt, Nap, Ti02 migrated from the actinolite- Mg-chlorite facies to the albite- F e-chlorite and Mg + Fe-chlorite facies); 2) remobilization of elements from the intrusive rocks into veins (e.g ., SiO 2 and CaO ); 3) introduction of elements by hydrothermal fluids in rocks of the Siscoe stock (e .g., Al2O3, MgO, H2O, CO2 and FeOt).The Siscoe stock and the Dubuisson Formation form part of the same tholeiitic suite. Similarly, the Bourlamaque batholith and the Val d'Or Formation belong to a single calc-alkaline suite. In view of this relationship, dissimilarities between the petrochemistry of the Siscoe stock and the Bourlamaque batholith suggest that the two intrusions are not co-magmatic.Finally, gold may have been leached from rocks of the Siscoe stock and remobilized into the quartz-carbonate mineralized veins. In order to account for the total production at the Siscoe mine, approximately 1.2 km3 of the Siscoe stock is thought to have been partially leached of its gold."

Jan 1, 1990

By Mark G. Lafontaine

Underground 802.11 wireless communications has become widely adopted for automation and communication purposes but maximizing the wireless signal presents many obstacles given the harsh environment as well as the presence of materials and conditions that can reduce signal propagation. Changes in elevations and curvatures in ramp to drift transitions also affect the wireless signal. Based on the requirements of wireless applications such as voice, data, or location tracking, the wireless site survey is the key tool for measuring and predicting signal strength and signal-to-noise ratio. These readings help determine the maximum distance between access points in order to sustain an overlapping wireless signal where required. This paper describes the methodology and tools used for measuring 802.11 wireless signal strength in an underground mine environment in Northern Ontario. The physical characteristics of the mine and the actual recorded wireless signal data will be presented in order for the audience to gain an understanding of the factors that affect signal throughput. Antenna selection used for the site survey will also be discussed as it played a key role in propagating the wireless signal.

May 1, 2013

By A. Shakoor, T. P. Gautam

The long-term slaking behavior of clay-bearing rocks in the field can be quite different than the short-term slaking behavior in the laboratory. To assess this difference, 12 replicate samples of each of 20 clay-bearing rocks, including 5 claystones, 5 mudstones, 5 siltstones, and 5 shales, were exposed to natural climatic conditions for 12 months. After each month of exposure, one replicate sample of each rock was removed from natural exposure and its grain size distribution was determined. Disintegration ratio (DR), defined as the ratio of the area under the grain size distribution curve of the slaked material for a given rock to the total area encompassing all grain size distribution curves of the tested samples, was used to quantify the amount of disintegration under natural climatic conditions. DR values of naturally exposed samples were then compared with the corresponding values of second-cycle slake durability index (Id2) determined in the laboratory. The relationship between Id2 and DR after, 1 month of exposure, exhibits an R2 value of 0.65 but the relationship deteriorates when DR values for 6 and 12 months of exposure are used, with R2 values of 0.63 and 0.25, respectively. However, when DR values for laboratory samples, computed from grain size distributions of slaked material after second cycle, are compared with DR values of naturally exposed samples for the three periods of exposure, the relationship improves with the corresponding R2 values being 0.61, 0.71, and 0.41. These results suggest that DR may be a better parameter for assessing the long-term disintegration behavior of clay-bearing rocks than Id2.

Jan 1, 2015

By B. D. Pandey, D. Bagchi, Premchand

During the separation and recovery of metals from the ammoniacal leach liquor of Indian Ocean nodules by solvent extraction-electrowinning (SX-EW) in close-loop operation, the copper electrolyte containing ~40g/L Cu, 20 g/L Ni and 180 g/L sulphuric acid is bled-off to control the impurities. The recovery of copper and nickel as powders has been examined from the copper bleed solution following partial decopperisation, crystallization of mixed sulphate of the two metals and aqueous hydrogen reduction. From the dissolved sulphate solution containing 17.68 g/L Cu, 18.83 g/L Ni and 0.03 g/L Fe, the copper powder was precipitated at initial hydrogen pressure of 26 bar in an autoclave in 90 min at 140 °C. The residual copper from the spent solution was removed as sulphide and nickel powder was then recovered (99%) in two stages from a solution of pH 4.5 at 40 bar pressure and 190 °C. However, 98% nickel recovery in one stage was achieved when hydrogen reduction was carried out from an ammoniacal solution in the pH range 9-11. Copper and nickel powders were produced from the bleed solution with acceptable purity and specifications suitable for P/M applications.

Jan 1, 2004

By S. Demetrio

China has a traditional segment of Copper Smelters with its own Chinese technology, typically small in size from 20.000 to 50.000 tCu/a, and they are responsible for the processing and production of more than 600,000 tonnes of blister copper per year. For occidental experts, like one of the authors, it is not so easy to believe that they are profitable, because the size and the use of old Blast Furnaces, but they are with simple and effective production lines. The authors are convinced that China has a good alternative to improve theses old copper production lines with small innovative changes in its process arrangement, jumping to higher level technology, more efficient in production, productivity and cost, assuring copper as a raw material for the country and its high speed development. The key to improve that the traditional Chinese Copper Smelter is white metal as an extra raw material as a first step doubling the copper production from raw materials and the complete replacement of concentrates by white metal (WM) in a second step increasing it four times or more as the final goal. It is not so difficult nor expensive to make it happen, but there are a couple of questions for implementing this innovation in the copper smelter industry: 1 - Will the old fashioned mentality be open to this new direction for China being the biggest copper consumer on one side, and the biggest copper Primary Producers on the other hand? and 2 - Will they be open to follow this "win-win" strategic way for both ends of the copper market? We don&apos;t know if anybody will take up the challenge to improve it but our responsibility as a consulting expert and a university professor is to put the alternative on table for others to decide whether to implement it.

Jan 1, 2007

By F. J. Hrach, S. A. Gasiorowski, J. D. Bittner

"Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (500 µm) materials with very high throughputs.. The technology has been also successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, and potash. TECHNOLOGY OVERVIEWThe ST separator utilizes electrical charge differences between materials produced by surface contact or triboelectric charging. When two materials are in contact, material with a higher affinity for electrons gains electrons and thus charges negative, while material with lower electron affinity charges positive. This contact exchange of charge is universally observed for all materials, at times causing electrostatic nuisances that are a problem in some industries. Electron affinity is dependent on the chemical composition of the particle surface and will result in substantial differential charging of materials in a mixture of discrete particles of different composition.In the ST separator (Figures 1 and 2), material is fed into the thin gap 0.9 – 1.5 cm (0.35 -0.6 in.) between two parallel planar electrodes. The particles are triboelectrically charged by interparticle contact. For example, in the case of coal combustion fly ash, a mixture of carbon particles and mineral particles, the positively charged carbon and the negatively charged mineral are attracted to opposite electrodes. The particles are then swept up by a continuous moving open-mesh belt and conveyed in opposite directions. The belt moves the particles adjacent to each electrode toward opposite ends of the separator. The electric field need only move the particles a tiny fraction of a centimeter to move a particle from a left-moving to a right-moving stream. The counter current flow of the separating particles and continual triboelectric charging by carbon-mineral collisions provides for a multistage separation and results in excellent purity and recovery in a single-pass unit. The high belt speed also enables very high throughputs, up to 40 tonnes per hour on a single separator. By controlling various process parameters, such as belt speed, feed point, electrode gap and feed rate, the ST process produces low carbon fly ash at carbon contents of 2 % ± 0.5% from feed fly ashes ranging in carbon from 4% to over 30%."

Jan 1, 2012

By H. Higuchi

The Sumitomo Metal Mining Company Ltd. (SMM) started to produce electrolytic nickel at the Niihama Nickel Refinery in 1939. In 1992, the conventional matte electrorefining process was converted to the matte chlorine leach electrowinning (MCLE) process, which is currently in practice. SMM has mainly used two kinds of nickel matte as the raw material for the MCLE process. Treatment of new raw materials, which have different impurity contents from the original nickel matte, has become mandatory because of changes in the market. Therefore, the MCLE process has been required to increase its flexibility to treat the different impurity contents in the new raw materials. An increase in the capacity for iron removal is included in such requirements. A new iron removal circuit in the MCLE process, based on a process development study, was recently installed. The iron removal circuit is in operation, and efforts are currently underway to optimize the performance of the circuit by changing the present operating parameters. In addition to the removal of the iron, the application is also expected to improve the nickel recovery. The outline of the new circuit and the current iron balance in the MCLE process are described in this paper, together with the effect of the circuit on iron treatment capacity.

Jan 1, 2006

By Margarete Kalin

"Biotechnological approaches to decommissioning of mine waste management areas are presented in the context of sustainable environmental management. Improved design of waste sites and environmental management paves the way for the application of new technological approaches. Mining wastes are better confined, effluent quantity is reduced and the quality is expected to improve in the future. The biologically mediated treatments focus on the creation of conditions inside the waste management area which lead to the confinement of the contaminants in the inactive tailings ponds and seepage collection ponds, as well as pits or other disturbed areas which were part of the operating conditions.Biogeochemical reactions lead to three fundamental water treatment steps mediated biogeochemically , alterations in chemistry which lead to formation of particles, which then have to flocculate and be assisted to collect in the bottom of the ponds. Microbially active sediments are installed to assist particulate formation and serve as sinks for metals. In deeper sediment strata, stable forms of metals are created. Biological polishing is used to collect the particulates and relegate them to the sediment. Examples will be given of the application of these processes, to waste rock piles, open pits and tailings ponds. This paper attempts to show that, through the integration of applied biotechnological advances and the application of new approaches to decommissioning, reductions of environmental impacts by mining are possible. * Note: this paper has been presented at the 13th Annual Meeting of BIOMINETIntroductionThe role of biotechnology in decommissioning of mining waste management areas should be placed in the context of sustainable development. The concept of sustainable development as defined by the Brundtland Commission (1987) for the restoration/ reclamation of mining operations could be translated as follows: The increasing demand for the resources by the world population must be met in a manner which does not compromise the earth's environment over the long term (Brooks et al., 1995)."

Jan 1, 1998

By Minerals Refining Company, Gerald Luttrell, Biao Li, Robert Bratton, Roe-Hoan Yoon, Stan Suboleski, Nikhil Gupta

Flotation is regarded as the best available method of upgrading coal and mineral fines in the mining industry. However, its efficiency deteriorates rapidly with decreasing particle size. Furthermore, ultrafine concentrates are difficult to be dewatered economically. Due to these technological problems, some operators are forced to discard at least part of the ultrafine materials to tailings (or refuse) ponds, causing significant losses of valuable resources and creating environmental concerns. To address these technological issues, a new separation process named hydrophobic-hydrophilic separation has been developed on the basis of the recent advances in the science of hydrophobic interactions. The results obtained to date show that the process can recover and dewater ultrafine particles simultaneously with high separation efficiencies. Following a series of extensive laboratory tests, the process has been scaled up to proof-of-concept and pilot-scale continuous tests. The results obtained with desliming cyclone overflows, screenbowl effluents, and by-zero coal flotation feeds can be cleaned to less than 4% ash and moisture with over 97% organic matter (or coal) recoveries. The results obtained with mineral fines also showed encouraging results.

Jan 1, 2016

By H. Sato, Y. Sato, T. Ooishi, K. Sakamoto

"Sumitomo Metal Mining Co., Ltd.(SMM)'s Niihama Nickel Refinery(NNR) produces high quality Nickel cathode, Cobaltcathode and other by-products using hydrometallurgical refining process called “MCLE”(Matte Chlorine Leach and Electro-Winning). In 2005,NNR started to use nickel and cobalt mixed sulfide (MS) produced by one of the SMM’s subsidiaries Coral Bay Nickel Corporation(CBNC)’s HPAL plant in Philippines, although its main and the only raw material until then was nickel matte. With start-up of the second HPAL plant at Taganito in 2013, NNR expanded its production capacity of nickel cathode from 41,000 to 65,000 tpa and finally achieved its target in 2015 by producing 65,980 tpa. SMM developed the technologies to improve poor reactivity of MS and installed new facilities to cope with increased Cobalt and Sulfur production at that time. This paper describes the technical approach to increase MS treatment with high efficiency.INTRODUCTIONThe Sumitomo Metal Mining Co., Ltd.(SMM)Niihama Nickel Refinery(NNR) produces Nickel cathode, Cobalt cathode and other by-products using Matte Chlorine Leach and Electro-Winning (MCLE) process technology. SMM uses nickel matte and nickel & cobalt mixed sulfide (MS) as raw materials for the MCLE process. Table 1 shows typical composition of these raw materials. Nickel matte had been only raw material until 2005, and with start-up of Coral Bay Nickel Corporation (CBNC) operation in the Republic of the Philippines, MS became major part of it. In 2009, when CBNC doubled its production capacity, NNR also expanded its plant capacity of electrolytic nickel from 36ktpa to 41ktpa, keeping an eye on the possibility of 65ktpa with oncoming SMM’s second HPAL in Philippines. Poor reactivity of MS was the prime concern at that time because our intention was to increase production with MS. Nickel extraction rate deteriorated with increasing usage ratio of MS in raw materials. To keep high nickel extraction rate under high ratio of MS, NNR developed a new leaching technology. Another concern arising from treatment of MS was Cobalt and Sulfur contents that are much more than those of nickel matte as shown in Table 1.NNR introduced new technology of solvent extraction process as to Co/Ni separation process in order to keep cost competitiveness instead of the conventional cobalt oxidation–neutralizing method. As to sulfur products, new sulfur productive facility was installed to improve the exposure to sulfur dust and the hot working conditions for workers. As a result of process development and installation of new facilities against the problem with MSusage,65 ktpa production was achieved in 2015."

Jan 1, 2017

By D. Bois, P. Poirier, B. Bussière

Environmental desulphurization is an attractive alternative for the management of acid generating tailings. Bulk sulphide flotation is the most commonly used method to produce desulphurized tailings, as shown from many previous works. This process can reduce the volume of problematic tailings to manage by making a sulphide fraction concentrate. The desulphurized tailings can then be used as construction material for an engineered cover to prevent acid mine drainage. In this paper, the results from different laboratory and pilot scale flotation tests are presented. These results confirm that low sulphide non-acid generating tailings can be produced by froth flotation. It is also demonstrated that sulphide concentrates obtained from desulphurization mixed with the appropriate binders can be used as feed material for paste backfill. From previous work on the evaluation of operating and capital costs of the desulphurization process for different ore types, the use of desulphurization as a tailings management approach was studied for several scenarios. The desulphurization process was then compared with other technologies (underwater disposal, engineered soil cover) currently used to prevent acidic drainage (AD) for a new mining operation. Results show that partial or total desulphurization are technically and economically viable options to manage tailings during mine operation. Mine waste managers should consider desulphurization as an efficient technology.

Jan 1, 2005

By Q. H. Bui

The elastoplastic self-consistent model is one of the effective models to study the initial microstructure effect on the mechanical behavior of bulk materials. However, the use of this micromechanics-based model which takes into account only the Hall-Petch relationship at grain level for predicting the grain sized effects on the strength of the deformed materials is not accurate yet because of the fact that the dislocation density contributes also to the strengthening of this kind of materials. In this study, a modification made to the Hill-Hutchinson elastoplastic self-consistent model was proposed for investigating the microstructure dependence of the mechanical behavior of cold-drawn 6063 aluminium tubes. Because of the novel modification, an estimation procedure with two steps was required to identify the parameters of this micromechanical model. An acceptable agreement between experimental and theoretical stress-strain curves was achieved.

Jan 1, 2011

By E. Ghali, N. Sorour, G. Houlachi

"The binary Fe53Mo47 and ternary Fe54Mo30P16 coatings have been electrodeposited from citrate-based electrolyte on mild steel (MS) substrates. The electrodeposition has been conducted for 6 hours at 20 mA cm-2 and 30°C. The electrochemical tests were carried out in chlorate solutions containing 300 g L-1 NaCl and 4 g L-1 K2Cr2O7 at pH 6.4 and 80°C. A number of surface characterization techniques such as SEM-EDS, XRD and EMP were used to study the microstructure of the alloys. The electrocatalytic activity of these coatings was investigated using steady-state polarization and galvanostatic technique. This study revealed that the Fe-Mo-P coating could be considered as a promising cathode material for the hydrogen evolution reaction (HER). The results showed an important decrease of hydrogen overpotential for Fe-Mo-P alloy as compared to that of Fe-Mo and especially MS which is a traditional cathode in chlorate industry. The HER overpotential for Fe54Mo30P16 at current density of 250 mA cm-2 was decreased by 30% in comparison to that of MS (1029 mV), and by 16.5% to that of Fe53Mo47 coating (857 mV).INTRODUCTIONSodium chlorate is used for manufacturing of several daily consumption products. This chemical is mainly employed for the production of chlorine dioxide (ClO2) that is a bleaching agent used in the pulp and paper industry. The ClO2 is also consumed for generation of perchlorates, chlorites and other chlorates, as an herbicide and in uranium processing (Cornell, 2002). Sodium chlorate is produced industrially via following overall formula in un-divided electrochemical cell (Nylén & Cornell, 2009):"

Jan 1, 2016