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By Fazel G. Jahromi, Ahmad Ghahremaninezhad

Enargite (Cu3AsS4) is a major complex copper mineral and often is a carrier of invisible gold particles. Pyrometallurgical treatment of enargite is challenging due to the arsenic release to the environment. Hydrometallurgical treatment, on the other hand, appears to be a promising alternative for enargite processing. In an atmospheric enargite leaching process both the copper and arsenic from the mineral can be leached into a sulphuric acid solution and the arsenic can be simultaneously precipitated as ferric arsenate. The unlocked gold in the residue then can be recovered in a subsequent cyanidation circuit. The downside of the atmospheric enargite leaching in sulphate solutions is the slow leaching kinetics. In this study the effective parameters of the atmospheric enargite leaching process in ferric chloride media were investigated. All the experiments were carried out at temperatures below 100 °C. The process parameters that were investigated in this study included ferric, chloride, sulphate and cuprous concentrations, temperature, mixing rate and leaching slurry pulp density. It was found that the copper recovery rate increases with the addition of cupric chloride and also with raising the temperature. The highest leaching kinetics and the highest overall copper recoveries were achieved when cupric was initially added to the leach solution and at 90 ºC.

Jan 1, 2015

By J. A. Abols, P. M. Grady

Recovery via gravity is one of the oldest mineral processing methods available. Unfortunately, the use of gravity techniques for gold recovery has been in decline for the past century as more effective chemical processes such as flotation and leach/CIP have been developed. Recently, with the push towards more sustainable environmental outcomes, the benefits of gravity separation have become more apparent. While gravity as a unit process is not usually capable of achieving as high a recovery as flotation or whole ore cyanidation, a combination of gravity devices alone or in conjunction with these processes can offer significant advantages to the operator. This paper reviews the range of gravity devices available, their application and the results that can be achieved by maximizing gravity through the use of a combination of gravity recovery devices. Three case studies are provided.

Jan 1, 2005

By P. S. Capper

"Generally speaking, the most intensive efforts at dust control in the mining industry have, in the past, been concerned with underground operations and where uranium ore or high silica material is processed. In the past several years, Stoop Rock has made Intensive efforts to reduce dust levels in it's Iron ore pelletizing complex. There have been no great engineering break-throughs with regard to dust control in such plants, and certainly no new engineering techniques have had to be applied at Steep Rock. This paper deals with how significant improvements in dust levels have been achieved through minor modification to dust collectors and ventilation units, improvements in operating practices, and education of supervisors and hourly personnel.PROCESS DESCRIPTIONSteep Rock Iron Mines is located 120 miles west of Thunder Bay near Atikokan. (fig. 1) Run-of-mine ore is pelletized along with some -1"" concentrate that has been processed in the concentrator (a summer operation only), which utilizes gravity separation to upgrade a mechanical mixture of ore and waste."

Jan 1, 1976

By D. Bronkhorst, J. Rheault

"Backfill practices at the Williams mine have evolved significantly since underground mining began in 1986. The use of conveyors as a means of transporting fill material to stopes has been discontinued in favour of load-haul-dump equipment. The method of adding binder to the fill product has been refined along with the placement technique. Slurry preparation has been fully automated and flyash is now included as a binding agent. Surface preparation of the fill product has evolved substantially with the quarry operation coming into full operation and the construction of pennanent crushing, screening, and storage facilities. Company personnel have replaced all contracted labour involved in backfill operations. Some changes have been made to achieve a higher standard of quality control while others were implemented as a matter of cost reduction. BackgroundThe Williams mine is one of three mines operating at the Hernlo gold deposit, located 40 km east of Marathon, Ontario, along the north shore of Lake Superior. Daily production at the mine is 6000 Ud yielding an annual gold production of approximately 500 000 oz. The orebody extends from surface to a depth of 1300 m dipping north at 70 degrees. The average orebody width is 25 m, but varies from 45 m on the eastern boundary to about 10 m at the western probable limit and at depth. Proven and probable reserves currently stand at 32 million tonnes grading 6 g/t.The Williams orebody has been divided into four separate mining zones: the A-zone, the West-of-Dyke zone, the B-zone, and the C-zone (Fig 1). Ore production originally was from the A-zone open pit operation while the A-zone and B-zone underground workings were being developed. The mining method employed underground is blasthole open stoping with delayed rockfill. Mining block dimensions are nominally 20 m along strike by 25 m high. Stope extraction is sequenced to achieve a relatively short pillar life and 100010 ore recovery. Pillars are extracted as soon as the adjacent primary stopes are two cycles ahead. Primary stopes are filled with consolidated rock fill after mining. This allows pillars to be blasted right against the consolidated fill, but also requires that the fill be self supporting to a height of 30 m.The Williams mine places approximately 1.4 million tonnes of rockfill and 50 000 tonnes of binding agents each year, with about three quarters of the fill placed being consolidated. The consolidated fill placed at the Williams mine contains Portland cement and flyash as binding agents."

Jan 1, 1994

By Khosrow Ebrahimi

We document the occurrence, mineralogy and firing properties of magnesite from hydrothermal deposits in the upper Cretaceous ophiolites of Eastern Iran. These deposits occur as thin veins of nearly pure cryptocrystalline magnesite with only trace amounts of quartz, calcite, and dolomite. Ratios of CaO/SiO2 in the bulk ore are variable. The composition of dead-burned magnesite from these deposits, calcined at different temperatures and durations, is predictable from phase equilibria. Textures of the calcined magnesite were studied by SEM; results show that the principal impurites produced during calcination are forsterite, monticellite, merwinite, dicalcium and tricalcium silicates, and that these are located principally at triple junctions of the periclase crystals. The size of periclase crystals increased with temperature and duration of calcination and the amount of periclase-periclase grain contacts was reduced by increasing the concentration of impurities in the starting products. EPMA show: 1) that CaO and FeO contents in periclase increase steadily with an increase in the CaO/SiO2 ratio and the FeO content of the bulk ore, respectively, and 2) that limited solid solution exists between impurites. This study demonstrates that high quality dead-burned magnesia refractories can be produced from the Iranian magnesite with low CaO, SiO2 and FeO contents.

May 1, 2004

By J. H. McKibbon

This paper outlines the basic steps in the sizing of electrostatic precipitators according to the Deutsch equation. Design parameters that do not appear in the equation are also described.

Jan 1, 1971

By M. N. Bassim, W. W. Tennese

"Concepts of linear elastic fracture mechanics were applied to study two cases of failure, namely an equalizing beam from a tandem rear axle of a highway tractor unit and the main beam of a flat bed trailer. In the first case, the presence of a crack, initiated by stress corrosion cracking followed by significant fatigue crack propagation produced a state of stress which was sufficient to produce brittle failure. Calculation of the fatigue life agreed with the number of cycles that the structure experienced before final fracture. In the second case, it was demonstrated that a combination of low temperature and high loading rate was sufficient to cause brittle fracture.IntroductionFailure analysis of engineering components has generally been carried out without the benefit of fracture mechanics. It is generally understood that real structures inevitably contain internal or surface flaws which under an applied load, may propagate to fracture. Fracture mechanics relates the applied stresses to the crack size in specified geometries. Since its introduction approximately thirty years ago, fracture mechanics has evolved as a design philosophy which can be used to develop fracture-safe designs. It can be also applied in analysis of failures, to ascertain if sound design and fabrication methods have been used."

Jan 1, 1985

By Robert E. McIvor

"“Classification System Efficiency (CSE)” is a powerful, emerging tool that can be used to increase grinding circuit efficiency. It is defined as the percentage of the ball mill energy being used to grind target, oversize particles. The discovery, validation and current use of CSE, including how it was manipulated, are described through seven plant case studies. These resulted in efficiency improvements ranging from 3 to 30 percent, along with major reductions in over-grinding. The achievable CSE for any given circuit is described. This paper demonstrates both how, and how much, every plant can benefit from increasing grinding circuit CSE.DEFINITIONS: BALL MILL CIRCUIT “CLASSIFICATION SYSTEM EFFICIENCY (CSE)”, “EFFECTIVE MILL GRINDING POWER”: “WASTED/OVER-GRINDING MILL POWER”The closed ball mill circuit is shown in Figure 1. The extreme importance of the circulating load ratio in determining circuit productivity was demonstrated by Davis (1925) and re-published by Guadin (1939), as shown in Figure 2. The circuit production rate increases with increased circulating load ratio, rapidly so at first and continuing to increase more gradually with higher and higher values of circulating load ratio.The underlying cause of this relationship was seen when comparing the ball mill feed and product size distributions from two different ball mill circuits, one with a low circulating load ratio, and one with a high circulating load ratio (Figure 3). While the F80’s and P80’s of these two circuits were close to the same, the mill feed and discharge size distributions were quite different. The ball mill in the circuit with the higher circulating load ratio contained a substantially greater fraction of material coarser than the target P80, as indicated by the respective mill feed and discharge size distributions. This fraction represents the fraction of the mill power being expended on “coarse” (in this case, plus P80 size) material, or the circuit “classification system efficiency.” The “effective mill grinding power” is the total mill power multiplied by the CSE. The compliment of CSE, the remaining fraction of “fines” in the mill, is the fraction of the mill power being wasted, and spent on over-grinding of material already finer than the circuit target product size. This is the “wasted/over-grinding mill power”"

Jan 1, 2013

By John A. Dresser

Seventy years ago a period of prospecting and mining activity began in the Eastern Townships of Quebec that seems to have been quite equal to that of recent years in the Rouyn field. In the following six or seven years a large amount of work was done over a widespread area. About fifty deposits gave some shipment of ore, from a few tons upwards, and as many as five hundred occurrences of copper were made known in the district by official records. Comparing the scale of commercial undertakings of that time and of the present day, these developments must have occupied quite as large a share of the capital and man-power of the Province as northern Quebec employs today. Working conditions at that time were not very favourable. The country was then only newly opened for settlement, and colonists were few and widely separated. Roads of the class built today were unknown. A single line of railway, the Grand Trunk, crossed the district from east to west. Colonization companies controlled large blocks of land on which they owned mining rights and usually reserved these rights in whole, or in part, when selling the lands. Then, as now, the precious metals belonged to the Crown. Yet the work was not without its successes. One of the first deposits discovered, the Acton, was, for a few years, one of the most profitable producing copper mines of its time. Another, the Eustis mine, has been in almost constant operation ever since, and is now vigorously pushing further development. At least two others, now quiescent, proved profitable operations, and several made considerable production. The manufacture of sulphuric acid in Canada was begun by the founder of the Nichols Company at Capelton, on a deposit that is now being re-developed, after a long and creditable career.

Jan 1, 1928

By Henri-Louis Jacob

Le Québec dispose de ressources en silice abondantes et diversifiées, pouvant convenir dans l'ensemble à la plupart des usages industriels. Dans les terrains Paléozoïques des BassesTerres du Saint-Laurent et des Appalaches, les ressources identifiées comprennent les grès quartzitiques purs du Croupe de Potsdam (Cambrien), exploités notamment à Saint Canut au nord de Montréal comme source de sable de silice pour l'industrie du verre; les arénites quartzitiques des Formations de Val-Brillant (Silurien moyen) et de Kamouraska (Ordovocien inférieur) exploitées dans l'est du Québec comme source de fondant métallurgique; les grès friables de la Formation de Guigues (Ordovicien) au Témiscamingue, à partir desquels on produit des sables de silice utilisés notamment en fonderie et en filtration. Dans la province structurale du Grenville, au nord du fleuve Saint-Laurent, les métaquartzites purs du Supergroupe de Grenville représentent une source importante de silice pour la production de silicium, de ferro-silicium et de carbure de silicium. Des veines et amas de quartz ont aussi été exploités un peu partout au Québec comme source de fondant métallurgique ou de silice ultra-pure pour la production de silicium métal. Quelques dépôts de sables naturels, généralement d'origine marine ou deltaïque sont finalement exploités dans la région de Montréal comme source de sable pour des usages n'exigeant pas un produit de haute pureté.

Jan 1, 2001

By Jess Harding

Oyu Tolgoi investment agreement now in full, legal effect Successful completion of a series of conditions to 2009 Investment Agreement was announced March 31, 2010. Full-scale construction now set to begin. First copper-gold commercial production from Oyu Tolgoi expected in 2013. 34% of holding company Oyu Tolgoi LL Cacquired by Erdenes MGL, a Mongolian state-owned resources company. Remaining 66% will continue to be owned by Ivanhoe Mines. ?After 9 years of discoveries at Oyu Tolgoi, a big piece of the future of copper and gold in Asia is poised to become a reality.?

May 1, 2010

By P. A. Mingione

"AEROPHINE@ 3418A is a unique sulfide mineral promoter produced by Cyanamid, based on phosphine (PH3) chemistry. It has proven effective as a collector for the sulfide minerals of copper and particularly lead (galena), as well as for secondary gold and silver values. AEROPHINE 3418A has widest application as a Cu and/or Pb collector for complex ores of Cu-Zn and Pb-Zn, which frequently have significant quantities of associated precious metal values. Advantages shown in the use of AEROPHINE 3418A are improved selectivities against Zn- and Fe-sulfides, increased precious metals recoveries, reduced total collector consumptions for Cu and/or Pb flotation, and increased flotation kinetics leading to higher recoveries of these values. Operating plant, pilot plant and laboratory test data from treating different ores are presented, demonstrating the advantages in use and preferred application of AEROPHINE 3418A.INTRODUCTIONCyanamid operates the only phosphine and phosphine derivatives plant in North America, located in Niagara Falls, Ontario. Specialty chemicals manufactured at this facility are used in many diverse applications, including solvent extraction reagents and textile flame retardants. A unique phosphine-based sulfide mineral promoter, AEROPHINE 3418A, is also produced. The origins of AEROPHINE 3418A promoter date back to the 1960's, when it was established that sulfide mineral collectors based on phosphine chemistry demonstrated efficacy. This new collector chemistry was found to provide flotation performance differing significantly from those of more traditional thiol collector chemistries such as xanthates, dithiophosphates, mercaptobenzothiazoles, thionocarbamates and those with xanthogen groups. Some of the advantages ultimately demonstrated by AEROPHINE 3418A promoter compared to these traditional collectors include:"

Jan 1, 1990

By Charle Pelley, Kosta Fytas, Peter Calder

"A computer model has been developed which is capable of evaluating alternative production schedules (long- and short range) of an open pit mine once the ultimate pit limits have been defined. The model user can choose the best alternative according to cash flow considerations and the particular mining conditions. The model involves a combination of simulation for long range production scheduling and linear programming for short range scheduling. IntroductionMining of mineral deposits in such a fashion so that, at depletion the maximum possible profit is realized, has been a very old problem of the mineral industry. In the past, when high-grade ore reserves were readily available and profits were very high, no question of optimum profitability was raised.However, recently the complexity of both open pit and underground mining has been increased tremendously. The additional problems of continuously rising production costs on one hand and of depressed metal prices worldwide on the other, have been demanding optimum profitabiliy from every mining venture .Particularly in the area of open pit mining, the sequence of ore and waste extraction has now become very important since the size of the pits and of the mining equipment has increased enormously. The process of open pit mining involves a continuous change of the open pit surface and there are many feasible plans of extraction which lead to the same final pit shape (ultimate pit limits). Each of these feasible plans generates a production schedule over the entire mine life, which mayor may not be optimal."

Jan 1, 1987

By Marcel M. Djivre

The paper will outline the methods and test procedures including the evaluation criteria currently used at the Materials Testing Laboratory (MTL), Sudbury, Ontario, Canada, a laboratory approved by the Ontario Minister of Labour for the purpose of testing or examining mine shaft ropes or other hoisting appliances. Also for Canadian mines the paper will suggest proposed criteria to be used at MTL for the evaluation of ropes used in "ultra-deep" single-lift shafts. Most of the methods and test procedures currently used at MTL were adopted during the revision of the CSA Standard G4, Steel Wire Rope for General Purpose and for Mine Hoisting and Mine Haulage to be published most likely in year 2001. In this latest or sixth edition of CSA Standard G4, a new Clause 14 has been added outlining the requirements for in-service destructive testing of steel wire ropes for mine hoisting applications. The existing fifth edition of CSA Standard CAN/CSA -G4-92, which is intended for the manufacturing of new ropes, includes requirements for raw materials and construction features for round strand and flattened strand rope, and locked coil rope in bright and galvanized finish.

May 1, 2001

By Steve Wilkinson

"""Techniques for coarse-particle beneficiation of some gold ores and methods for determining potential for sorting any gold ore deposit.""With the advent of high speed computers, laser technology end different types of electronic sensing devices, ore sorting machinery has been developed, capable of handling significant tonnage rates while maintaining high level efficiency. Gold ores may be amenable to coarse-particle beneficiation where there exist measurable criteria upon which there can be recognition of auriferous versus barren lumps in the run of mine. Three types of criteria are suitable for sorting and are:i) Photometric - optical variance between ore and waste such as vein ores hosted by barren country rock;ii) Conductivity/Magnetic - based upon the metallic mineral content of ore end waste, and its association with Au, such as found in sulphide/arsenide Au ores,iii) Radtometric - detection of natural gamma activity occurring with uranium-bearirig gold ores.The method for determining the sortability of an ore depositconsists of, at least, three stages:i) Initial stage identification of ore and waste types,mineralogical/petrographical associations,amount of dilution in P.O.M.establishment of any sorting criteria]"

Jan 1, 1985

By Jim Sadowski, Steve Stewart, Bob McMurdy, Martin Nevens

"Mohawk Garnet has been operating a small pilot plant near Sudbury, Ontario for several years attempting to produce commercially viable garnet. The challenges of operating a pilot scale mining, processing, and product handling operation as a full time plant have led Mohawk Garnet to seek a better way. In co-operation with Mohawk Garnet, Outotec (USA) Inc. has taken on the technical and design challenges of increasing garnet product from twenty tonnes per day to two hundred tonnes per day.Outotec performed a comprehensive test and flowsheet development program applying Outotec’s density separators, spirals, flotation, and other technologies to design a successful process for the separation and recovery of the valuable garnet for Mohawk.This paper explores the test program, the process flowsheet development work, plant design and preliminary engineering of a new garnet processing. The various technical challenges, process technologies involved, and design concepts will be discussed.INTRODUCTIONMohawk garnet has been operating a small-scale garnet mine and process plant in Wahnapitae, Ontario near Sudbury.The current operation was intended to be a pilot plant and so only produces 20-25 tonnes of garnet concentrate per day. The garnet is bagged and sold for use as abrasive. The process is inefficient with low yields, poor material handling and very high cost per tonne. Mohawk garnet approached Outotec to help them improve their garnet process and transform themselves into a larger scale and more efficient operation."

Jan 1, 2010

By V. N. Rampton, C. F. Gleeson

"Exploration results over three overburden drilling anomalies defined by the Ontario Geological Survey in 1981 in the Kirkland Lake area, Ontario are presented. The anomalies come from lowland areas where overburden is thickest. By mapping the bedrock and surficial geology, by prospecting, humus sampling and shallow till sampling over the surrounding upland surfaces, one can initially evaluate such overburden drill anomalies without costly reverse circulation drilling. The drilling should follow, if necessary, only after surficial base data has been obtained. Preliminary work on these three properties has defined the presence of at least two styles of gold mineralization. One occurs in silicified zones in intermediate volcanics closely associated with northwesterly trending faults and shear zones. The second occurs in quartz-carbonate alternation zones in volcanics intruded by quartz-feldspar porphyry dykes. IntroductionThe three examples presented in this paper present first-hand information on an approach to the follow up of several geochemical anomalies that were found by the Ontario Geological Survey when they carried out reverse circulation overburden drilling as part of the Kirkland Lake Initiative Program (KLIP) in 1980 (Routledge et al., 1981). The initial approach is relatively simple, systematic, and cost and technically effective. It readies the properties for further exploration, or conversely, it could downgrade the properties as viable gold targets."

Jan 1, 1987

By K. Szafran, R. E. L. Seal, M. Tansey

Conversion of hydraulic equipment to fire resistant fluids has been hampered by less than satisfactory component performance and in some cases, catastrophic equipment failure. Concern over identifying possible causes to these problems led to a joint research project between the Potash Corporation of Saskatchewan Mining Limited and the University of Saskatchewan. This paper summarizes some of the results and conclusions derived from this joint project. In this study, the research was limited to evaluating the effects of potash contamination on the performance of hydraulic equipment. Two separate types of tests were conducted in order to provide a basis upon which trends could be established. This study concluded that the presence of potash dust in the hydraulic fluid can induce severe wear over relatively short periods of time. It was also deduced that a contaminant free fluid combined with proper fluid maintenance could extend the performance of hydraulic components using fire resistant fluids even under very severe operating conditions, such as elevated pressures and temperatures. Recommendations as to how to achieve this goal and the practicality of doing so are presented.

Jan 1, 1988

By Ronald Molnar

"High demand for metals is driving the exploitation of lower grade and more complex orebodies. These projects are often the initiatives of junior mining companies with limited financial resources. In addition, existing operations seek to enhance revenue from their existing metal recovery operations, through the production of value-added by-product metals and chemicals. Typically, hydrometallurgical circuits, often with novel chemistry, are required to exploit these new ores, to produce the multiplicity of products that will make a marginal project economical, or to increase the product range of an existing operation. Often, the mineral processing engineer is given the task of coordinating the development of a back-end hydrometallurgical flowsheet for their mineral processing project. This paper discusses the objectives that companies have when they commission the operation of a hydrometallurgical pilot plant. The paper goes on to enumerate some of the principal differences between mineral processing and hydrometallurgical pilot plants and the effect these have on the design, operability and potential pilot plant outcomes. Important factors include working with chemically reactive solutions and pulps, elevated temperatures operation, changing rheological properties of slurries, the complexity of integrated circuit flowsheets with long hold-up times and multiple recycle streams, and the need in some cases for extreme attention to purity and cleanliness. Examples will be drawn from the extensive experience base of SGS Minerals Services at the Lakefield site, in piloting both mineral processing and hydrometallurgical process flowsheets.INTRODUCTIONWe are currently experiencing a period of strong growth in the demand for metals. This in turn is turning the spotlight on a great many smaller mining companies and mining promotion ventures trying to tap into the rising metal demand. Some of these companies want to develop their properties and recover metals while others want to develop to the point that a major company will take an interest, or in some cases buy them out completely.With the heightened interest in metals, many orebodies that have been known about for years are being reconsidered for exploitation. Often, the reason they have not been developed to date is because of difficult metallurgy and marginal grades leading to marginal economic viability. In both cases the key that unlocks the resources is often the application of a novel metallurgical flowsheet, often a hydrometallurgical flowsheet."

Jan 1, 2006

By Yongqiang Liu

Background For refractory gold ores with high carbonate contents ! Acid pressure oxidation ! High acid consumption (if low sulfur content) ! Low oxidation efficiency due to CO2 in autoclave ! Problems with slimy precipitates (gypsum, etc.) ! Alkaline pressure oxidation ! Difficulty in fixing arsenic ! Low gold dissolution due to iron hydroxides/oxides coating ! High reagent costs Summary ! Carbonate and sulfide minerals had similar floatability across the pH range tested (5 - 12) using sodium oleate as a collector; ! Thioglycollic acid or citric acid depressed the flotation of pyrite but could not depress chalcopyrite when used alone; ! Combination of thioglycollic acid and citric acid had a much stronger depressive effect, and the mixture depressed chalcopyrite as well as pyrite between pH 8 and 11 without affecting the flotation of calcite and dolomite; ! Calcite could be separated from chalcopyrite and pyrite; dolomite could be separated from pyrite but not from chalcopyrite under the tested conditions.

Apr 1, 2005