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By S. Balideh

A good understanding of the behavior of rock helps us to make more informed decisions regarding geo-structures. Engineers need accurate equations to calculate the strength and deformation of rock before and after failure. Previous studies explain the failure of rock to ultimate strength, and laboratory tests adequately determine the ultimate strength and deformation modulus of rock. However, there are few comprehensive equations to determine the post-failure strength and deformation of rock. Previous work shows that the post-failure behavior of rock depends on the behavior of the broken rock particles after failure. The following question is then posed: How can the post-failure behavior of rock be determined by the behavior of broken rock particles? In order to answer the question, this study pursues three objectives: (i) to explain the behavior of broken rock at low confining pressure; (ii) to estimate the behavior of broken rock via the extrapolation of scaled laboratory testing; and to suggest a procedure (iii) to outline the post-failure behavior of a rock mass at low confining pressure commensurate with the behavior of broken rock in a rock mass.

Aug 1, 2013

By Z. Zhang

Aluminum boron carbide particulate reinforced composites have found new applications in nuclear industry due to their special capability to capture neutrons, Recently, Alcan successfully developed a liquid metal mixing process to fabricate Al¬B4C metal matrix composite instead of powder metallurgical technology. In the process, titanium is added into the composites to control interactions between boron carbide particulates and aluminum matrix, To understand the effects of titanium on the composites, the solidification microstructure of Al-16%B4C without or with titanium was examined by optical and electron microscopes. The results show that titanium can improve the uniformity of the particulate distribution within aluminum matrix if the titanium content in the composites is more than 0,5%, Furthermore, it is found that the layer with rich titanium on the surface of the particulates can limit the formation of AlB2 type compounds, which may greatly deteriorate the fluidity of the composites, In addition, it is also found that the amount of the reaction products in the composites increases with the increase of holding time. However, the rate of the increase is mitigated by the increase of the content of titanium in the composites. Besides, a procedure was proposed and implemented for the evaluation of uniformity of particulate distribution within aluminum matrix.

Jan 1, 2005

By C. Tissot, R. Palmer

"Due to the low concentrations of gold, direct measurement of gold concentration in ore on belt has not been seriously considered to now. Pre-concentration or sorting strategies have largely consisted of particle sorting based on secondary characteristics such as colour, which can be successful in select cases. CSIRO has produced sample measurement results using gamma activation analysis of ~300 gm samples with accuracies of around 30 ppb at best. With this encouragement, a feasibility study into gold ore measurement on belt for the purpose of sorting pods of gold ore has been undertaken. The study described here included, prototype design options with existing industrial Linacs, extensive Monte Carlo modelling of measurement sensitivity and shielding, further sample measurement, a study of the interaction of target measurement accuracy and sorting efficiency, and a rough estimation of potential economic benefit. The projected model sensitivity of around 0.1-0.15 ppm (1 standard deviation) in 10 seconds for 1 ppm average feed result in good bulk sorting performance and intriguing economic potential.INTRODUCTION Pre-concentration or sorting strategies for gold ores have largely consisted of particle sorting based on secondary characteristics such as colour or density, which can be successful in select cases (Klein, 2010). No method is available to measure gold content for sorting in particles or even in bulk on belt, principally due to the low concentrations of gold present. In fact, in many cases it is difficult to do rapid bulk grade measurements of base metal ores with concentrations many orders of magnitude higher. By a fortunate quirk of nature gold is particularly amenable to gamma activation analysis (GAA). CSIRO has performed extensive work in GAA of samples of crushed ore (Tickner, 2017). This has resulted in the Photon AssayTM technique that is currently being commercialised through the CSIRO spinoff company Chrysos. The technique relies on the recent availability of industrial high intensity X-ray sources such as Linacs which are currently being used in industry for security, medical and sterilisation applications. This development has led to CRC ORE funding a feasibility study to determine whether on-belt measurement of gold concentration is possible at a rate and accuracy sufficient to be useful for bulk sorting, where pods of ore are diverted rather than individual rocks. The study in the first instance is based on Monte Carlo modelling that has successfully predicted the performance of the sample based gold measurements. As well as the measurement feasibility consideration was also given to the likely heterogeneity of gold ores and hence the degree to which useful separation could be achieved. This is then tied to a back of the envelope evaluation of the order of magnitude economics of bulk sorting in an example deposit."

Jan 1, 2017

By R. G. Rosehart, S. Y. Lee

"The current investigation concerns the removal of arsenic from waste waters using ion-exchange resin and activated carbon as sorption media. Use of certain weak and strong base anion exchange resins permits the removal of arsenic. Arsenic may be loaded on the weak base resin in the pH range of 2 to 3 and on the strong base resin above pH 5. The elution of arsenic is successfully achieved using 0.5 M NaCl or a mixture of NaCl and NaOH. The activated carbon investigated was less effective on loading arsenic, but the arsenic loaded was easily eluted by simple pH adjustments."

Jan 1, 1972

"Coupon testing has been used to investigate stress corrosion cracking (SCC) of rockbolts in a laboratory based experimental program. This program has focused on the use of ASTM G39 three- and four-point bent beam coupon specimens, immersed in an acidified sodium chloride test solution containing hydrogen sulfide. The specimens were loaded to a range of stresses from zero, to just above the materials yield strength. It was found that only specimens above an applied stress of 580MPa failed by means of SCC, showing that rockbolts loaded to near their yield strength may be susceptible to SCC in-situ.INTRODUCTIONStress corrosion cracking (SCC) is a failure mechanism that affects material through the growth of hairline cracks when exposed to a corrosive medium while under stress (Jones and Ricker, 1999). SCC has been found to affect rockbolts in the Australian underground coal mining industry and has the capacity to cause the catastrophic failure of ground support systems, potentially leading to falls of ground in underground excavations, injury or death to mine personnel, damage or loss of equipment, and loss of productivity through the loss of roadway access (Crosky et al, 2002).Coupon testing utilises small scale samples that are intended to be indicative of the behaviour exhibited by a material in-situ (ASTM G39). The small scale, and usually high surface area to volume ratio of coupon specimens mean that they corrode at faster rate proportional to their mass, greatly reducing testing times. The small scale of the specimens allows them to be more easily prepared and handled, loaning them to mass manufacturing techniques.A previous study conducted by Vandermaat et al (2012b) into the use of three- and four-point coupon testing in-situ in an underground coal mine failed to result in SCC of the specimens. This paper serves as a follow up laboratory investigation in order to understand why these specimens did not fail. Previous studies into the SCC in rockbolts carried out by Gamboa and Atrens (2003) determined that rockbolt steel has a critical stress threshold of approximately 90% of the material ultimate tensile strength (800-900MPa). This study will focus on this critical stress threshold as a possible explanation for the lack of failure in the in-situ specimens (Vandermaat, 2012b)."

Jan 1, 2015

By Seungyeol Lee

Currently, a new construction method using a robotic system is widely spreading in construction sites. This study is related to the design of glazing robot?s teach pendant which can improve convenience of handling and hence improve the productivity through the efficient interaction between an operator and a robot while doing glazing works, e.g., curtain wall installing. The suitability of selection and arrangement of control switches was assessed according to mechanical motions of a glazing robot, and design guidelines for improving convenience and productivity were drawn up through questionnaires carried out by site operators. To verify the proposed design guidelines, working time comparison of the proposed teach pendant and the existing teach pendant was executed.

Aug 1, 2013

By J. Bednar, R. R. Rogers, W. Dingley

"Zinc is by far the most important metal used for protecting steel from the ravages of corrosion, and cadmium is also used extensively for this purpose. These metals are applied by electrodeposition in cyanide baths when a particularly good appearance and high throwing power are required. One great disadvantage in using these baths has been the decrease in cyanide concentration and the increase in carbonate concentration that takes place during the plating. Another disadvantage has been the development of serious embrittlement in high-strength steels. The present authors have developed new cyanide baths for electroplating both zinc and cadmium on steel. These baths are stable in composition during plating, they have not produced appreciable embrittlement in the high-strength steels that have been investigated up to the present time, and they permit the use of considerably higher plating current densities. In addition, they produce extremely fine grained coatings that are attractive and have excellent adherence and covering properties. Brighteners can be used in the plating baths if bright finishes are required."

Jan 1, 1967

By O. G. Olvera, E. Asselin, D. Rival

Particle concentration distributions in a leaching tank have been estimated using a novel experimental approach that takes advantage of the galvanic interactions that occur between pyrite (FeS2) particles and a Pt electrode. The collision of FeS2 particles with Pt changes the open circuit potential measured with the electrode due to galvanic interactions. To discern particle collisions with the Pt electrode from experimental noise a simple analytical procedure was first adopted although the use of techniques involving frequency domain analysis is also briefly presented and discussed. Although this method is still under development, it is simple to implement and can yield valuable information regarding the hydrodynamic behavior of solid particles in stirred tanks in very short times. Finally, the advantages and drawbacks of the technique are discussed.

Jan 1, 2014

By V. Estrada, G. Aguilera

"Since the most of mineral processing are wet, and for more specific applications where it is necessary to increase the purity through leaching and / or concentration, the proper dispersion is the first, and perhaps more crucial stage in the whole chain of processing. This specific process is based on the formation of a dispersion or suspension of mineral, trying to make the mixture as homogeneous as possible, and with specific rheological conditions. Sometimes it is not enough agitation to make it happen, so that chemical additives are used as an aid. However, the addition of chemicals strongly alters the viscosity and other rheological properties of the suspension factor to consider for subsequent steps to ore beneficiation. In other hand, in a process where no chemicals used often employ large quantities of water to achieve dispersion. But if an efficient chemical agent, which optimizes said dispersion through a specific physicochemical effect on the particle surface is used, also it can generate rheological advantages, besides achieving rational use of water and increase the recoveries of the product main about also optimal costs. The aim of this work is to find the optimal rheological conditions for a dispersion of kaolin as study case, looking for stability, best disaggregation, viscosity and pseudoplasticity.To find the optimal additive, the evaluation parameters were: 1) Best degree of dispersion of the suspensions according to the analysis of the flow curve; 2) Best level of disaggregation of particle chemical analysis delaminated by Particle Size Distribution; and 3) Best thixotropic rheological parameters and pseudoplasticity. Finally the optimum additive as one that meets the best combination of parameters is proposed.INTRODUCTIONKaolin is a clay material formed by altering of feldspar composed mainly for kaolinite. Depending on the application, the kaolin as raw material must be refined and processed because the ores of clays contain usually a lot of impurities derived of its sedimentary source, such as feldspar, mica and quartz (Torres, et. al., 2011). According to the experience on the plant floor and the publication of several scientific papers, it is known that the dispersion is a crucial stage in mineral processing (Greene, Duke, & Hunter, 1965) (Raghavan, et. al., 2004), not only because of the disaggregation of particles, besides because of the humectation of them. Is clear that disaggregation of particles give to the suspensions rheological stability, and the humectation improves the effect of further processes like grinding or chemical treatment. The dispersion process involves making a suspension of the mineral with a solvent which is usually water, to obtain a homogeneous dispersion, with the aid of energy of stirring. Sometimes is not enough the agitation (even with high energy) for this to occur, so is necessary the use of dispersing substances which introduce ions and molecules as modifiers of chemical potential, forcing the molecules of the material to disperse. Sometimes their use even could affect the pH of the suspension in a non-desirable condition. (Flores, 2013)."

Jan 1, 2016

By Mauro Torres, Gabriel Zarate

"AngloAmerican used the extractant M5640 at Mantos Blancos and Mantoverde and uses PT5050MD at Los Bronces Division, which are aldoxime and modifier blends. In the first case, the modifier is the esther TXIB, while in the second case is the tridecanol TDA. It is a well-known fact that the extractant degrades while the modifier does not and with time the oxime/modifier ratio can change significantly, depending on the operating conditions of each plant.In order to evaluate the effect of this varying modifier content in the plant organic, especially in the organic losses, a complete metallurgical test work program was conducted at laboratory and pilot plant scale by Flomin SNF, a new extractant supplier. Results showed that the addition of an aldoxime without the modifier did not affect the chemical performance of the extractant, but there was a significant decrease in the viscosity and density of the organic.Based on the results obtained in the metallurgical program, it was decided to run plant scale tests at the SX plants of Mantos Blancos and Mantoverde. In these tests, instead of adding extractant to maintain the organic inventory, CuPROMEX 3406 which is an unmodified aldoxime was added until the original oxime/modifier ratio was reached. This was obtained after 6 months of operation and since then both plants are running with the extractant CuPROMEX 3302 both supplied by Flomin SNF.In the case of Los Bronces, the pilot plant work was completed and it is programmed to run similar plant scale tests. In this case, the oxime/modifier ratio increased and TDA will be added until reaching the original ratio.The plant results obtained at Mantoverde and Mantos Blancos, together with the pilot plant test results obtained at Los Bronces, are discussed in this paper."

Jan 1, 2016

By Mariam Melashvili, Chris Fleming, Rene Jackman

"A study was undertaken to develop a flowsheet for treating a high grade silver/gold ore body by cyanidation, CCD and Merrill Crowe precipitation, with tailings detoxification to meet stringent limits for cyanide and thiocyanate concentrations in the final discharge. In one of the flowsheets examined, free cyanide in the final leach liquor was recycled to the mill where it was hoped that it might react beneficially with fresh ore to reduce the cyanide makeup by an equivalent amount. However, laboratory results suggested that most of the cyanide recycled to the mill reacted with iron forming a soluble ferrocyanide complex. This would have had a negative impact on cost, not only because the cyanide recycled to the mill could not be claimed as a credit, but also because the presence of ferrocyanide in the final tailings meant copper sulphate had to be added to the SO2/air cyanide detoxification process to precipitate the iron cyanide. In an alternative flowsheet that was examined, recycling of cyanide to the mill was abandoned, and this allowed the milled slurry to be pre-aerated in a single mixing tank before cyanidation. During alkaline pre-aeration, any ferrous ions that are generated in the mill are oxidized to ferric ions, which, unlike ferrous ions, are inert in cyanide solution. This significantly reduced cyanide consumption and lowered costs in the detoxification of the tailings. In this paper, the cost implication of these two circuits is compared.INTRODUCTIONMost of the gold that is produced by hydrometallurgical processes is recovered by cyanide leaching. The reason for that lies in the superior thermodynamic stability of the gold cyanide complex and the favorable economics this confers on the process (Fleming, 2014). However, the gold in most of the gold-bearing ores processed is a very minor component, and therefore, the leaching response is often dominated by that of the host minerals.Many gold ores treated by the cyanidation process contain iron minerals. Cyanide reacts readily with some iron minerals forming ferrocyanide as one of the compounds. Ferrocyanide is stable when solutions are exposed to air and does not retard the dissolution of gold. In fact, it has been claimed that potassium ferrocyanide in the presence of oxygen is a weak solvent for gold (Hedley & Tabachnick, 1958). The main problem with the formation of this compound is the consumption of cyanide. Ferrocyanide contains six molecules of cyanide for each atom of iron {Fe(CN)64-} so the wasteful consumption of cyanide is greatly increased by its presence. Thiocyanate is also often produced during the reaction of certain iron sulphide minerals with cyanide, and contributes to the wasteful consumption of cyanide. In addition, environmental regulations in certain countries demand that thiocyanate be removed from the tailings, and this adds significantly to the cost of tailings treatment."

Jan 1, 2016

By Leiting Yue, Peng Ren, Yu Shen, Zhihong Liu, Haibao Shao, Longgong Xia, Feng Yu

The Kennecott-Outotec Flash Converting technology has been proven as an advanced and mature process in 5 individual plants during the past 2 decades. High grade copper matte (65–72%) produced in the flash smelting, or other smelting technologies is granulated to 3-5mm granules in a water torrent, and further crushed to fine powder (≈50µm) and dried to contain less than 0.3% H2O. Oxygen enriched air, together with fine copper matte powder and lime flux are injected into the reaction shaft by a matte burner. The copper making and slag making reactions will happen in very short time and distance during the particle falling and settling. However, industrial practice has found negative effects caused by sodium contamination. Na is introduced in the copper matte granulating process, and appears as Na2SO4 on particle surface. When Na content was high, scaling problems in the boiler will be worse, and the processing air will be blocked by the growing accretion around the matte burner, and as-produced blister copper is always high in S and O. In this present study, an industrial matte sample was used in the experimental work. Na was introduced into the matte powder by Na2SO4 solution soaking. The burning behaviour of the doped copper matte powder has been investigated as a function of the impurity concentration and processing temperature. Morphology and composition of these samples explained how Na2SO4 converts and reacts in the oxidizing atmosphere, and how they or their converting species influence the burning behaviour of matte particles. Cross-sections of as-prepared samples were analyzed with SEM-EDS, and the reaction mechanism has been carefully interpreted. Results from the present study can benefit both academic and industrial people. INTRODUCTION "Flash Converting" technology was developed jointly by Kennecott Utah Copper Smelter and Outotec (Finland) OY in 1992. The first industrialization of the technology was in Utah Smelter in 1995. Since 2006, it has been successfully applied in Xiangguang Copper, Tongling Jinguan Copper Branch, Fangchengang Jinchuan Copper, and Ningde Southeast Copper. The technology has also been further developed in those smelters. At present, roughly 2 million tons blister copper is produced annually through the Kennecott-Outotec Flash Converting technology, accounting for more than 10% of global primary copper production. The technology has advantages of high efficiency, high sulfur capture rate, good in environmental issues, mature equipment supporting, high automatic control level, low comprehensive energy consumption and flexible connection with the smelting unit, which make the technology to be one of the best choices in investing a new large-scale copper smelter or updating an old copper project in the world.

Jan 1, 2019

By C. E. Rodgers

WHEN I was asked to prepare, for presentation at the 1938 Annual Meeting of the Institute, some data concerning low-discharge grinding at the Sylvanite mill, it seemed entirely reasonable to expect to have at my disposal the results of at least four full months' operation after the last unit, as then proposed, was installed. Delays in delivery of equipment, nevertheless, shortened the interval, as will be shown herein. In submitting the data contained in this discussion, I wish distinctly to state that the intention is not to claim that final conclusions can be reached at this time concerning our operation. Test periods, in certain instances at least, have been too short for this purpose, although some, where so stated, have been extended through March and April. It is hoped, however, that an advantageous trend in practice can be shown and that the experience related may be of interest to others who are now operating, or who are considering the operation of, low-discharge grinding mills. In the plant under review, four mills are in use: one primary and three secondary. Present mill capacity (grinding, as shown by screen test, about 99 per cent through-200-mesh and approximately 88 to 89 per cent minus-325-mesh with infrasizer giving about 90 per cent of the latter) averages about 525 tons per day. A brief description of each unit will be given and comments will also be made relating to operation. This will be followed by certain test data from which, in conclusion, operating results are summarized.

Jan 1, 1938

By Yvon T. Maurice

Under the auspices of the Federal-Provincial Uranium Reconnaissance Program, a geochemical orientation survey was undertaken in an area of uraniferous Lower Proterozoic (Aphebian) rocks near Cape Dorset in southwest Baffin Island. The main objective of this study was to establish a methodology for a future reconnaissance geochemical program using lake samples over a 300-mile Lower Proterozoic rock belt that occurs along the southern coast of Baffin Island. Mineralogical and chemical studies of known radioactive occurrences, combined with detailed sampling of secondary environment media in the vicinity of the showings. indicate that uranium is the most significant pathfinder, despite considerable enrichment of other metals in the uraniferous rocks, Significant geochemical patterns produced by uranium in lake waters and uranium in lake sediments have been obtained, but their relative usefulness depends on the distribution of carbonate bedrock, which in turn affect the bicarbonate content of lake waters. In southern Baffin Island, because of erratic variation in lake-water alkalinity, it is recommended that both water s and sediments be sampled on a routine basis. The need for lake-water acidification to prevent depletion of soluble metal ions in samples resulting from adsorption on the walls of the containers and/or suspended solid matter is discussed briefly. The base metal potential of the area was examined in some detail and found to be significant, particularly for a Lower Proterozoic gossanous formation that occurs throughout southern Baffin Island.

Jan 1, 1977

By K. G. Chipman

THE discussion on Dr. Chipman's paper, Mapping by the Topographical Survey, centred mainly on the urgent need for aerial photographic reconnaissance of unmapped portions of the country as an initial phase in the provision of suitable topographical maps for use as a guide in geological mapping, prospecting, exploration, and development work in the areas concerned. This, ir was pointed out, would necessitate an expansion of the topographical work of the Bureau of Topography to keep pace with the photographid work and to meet the demand for maps for use by geologists of the Bureau of Geology and others. A resolution requesting Institute Council to make representations to the proper authorities, urging that aerial photography and topographic map-ping be greatly expanded to meet the pressing needs of the situation, was moved by DR. W. F. JAMES and seconded by MR. L. G. SMITH, and carried unanimously. The full text of the resolution appeared on page 221 of the May BULLETIN. Others who spoke in support of the resolution were MESSRS. E. S. MOORE, L. B. ROCHESTER, F. D. SHEPHERD, and W. J. WRIGHT. Dr. Hansen then presented his paper, Mapping by the Geological Survey, discussion on which is summarized below. MR. FRANK EBBUTT(l) spoke of the very valuable service the Geological Survey bas rendered the mineral industry, and indeed the whole nation, in its century of existence, despite the very inadequate financial support it has received. Now, more than ever before, a strong and expanded Geological Survey is essential if the Industry is to continue to prosper. Our known ore reserves are being depleted very rapidly, and we are finding no new orebodies to take their place. As an aid in prospecting and exploration, and also in the development of orebodies when they have been found, we must have geological maps of the vast sections of the country which at present are unmapped or inadequately mapped. The Institute should make every endeavour to have the Geological Survey strengthened so that such maps may be made available as soon as possible.

Jan 1, 1944

By V. Panayotov, M. Panayotova, R. Villas-Bôas

The "United Nations Framework Classification (UNFC-2009) for Fossil Energy and Mineral Resources 2009” is the international system designed to meet (to the extent possible) the needs and to support the decision making and resources management of private industry investment, governments, policymakers, bank investment, scientists. There are different international and national systems classifying commodities (resources, reserves, possibility and feasibility to extract them, etc.) with their own definitions and reporting terminology which often do not overlap entirely or even differ significantly - thus creating difficulties and problems among stakeholders to understand each other. The UNFC-2009 is developed to allow “speaking in one language”. The paper presents briefly the UNFC-2009. The UNFC-2009 applies simultaneously three fundamental criteria to classify projects: economic and social viability, field project status and feasibility, and geological knowledge (so called E, F and G axes), thus creating a visualized, easily understandable three dimensional system. The E, F and G axis categories are divided to subcategories, using additional criteria. The UNFC-2009 is already applicable to solid minerals, nuclear fuel resources, petroleum. The amounts of solid waste generated by metals production from ores (mining, minerals beneficiation, extraction metallurgy) and its metals content are discussed from the viewpoint of using the waste as resource. An attempt is made to apply the UNFC-2009 to technogenic waste from metals production from ores - both to old engineering constructions (historic mining dumps and reclaimed beneficiation tailings ponds) and new (currently in use) dumps and ponds.

Jan 1, 2016

By A. G. Pentland

PROSPECTING is popularly supposed to be surrounded with an air of romance and adventure. The word 'prospecting' brings to mind high mountains, northern lakes, and aeroplanes. A note of urgency has been added to this by the war, particularly in the case of strategic, minerals. Prospecting for strategic minerals in a modern mine in full production, although it may Jack the romance of travel in little-known places, has the advantage of having all the necessary machinery at hand and ready to go into action at a moment's notice. HISTORY Tin was discovered in the Sullivan ore in 1925, when a white streak was noticed on a pilot table which was being used to check the amount of galena in the tailing. The mineral which made up this streak was identified as cassiterite. The amount of tin in the ore is so small that, while of scientific interest, it was considered to be of very little economic importance. Nevertheless, several attempts were made to learn something of the occurrence during times when other work was nor pressing. These studies were dropped when anything came up that seemed more important.

Jan 1, 1943

By G. P. Cooper

A comprehensive computational heap leach model was used to evaluate options for operating a chalcocite-ore heap leach process. The stockpile leach model is based on the computational fluid dynamic software framework PHYSICA+ and incorporates various physical and chemical phenomena to simulate fluid transport, mineral reaction kinetics, bacterial effects, and heat, energy and acid balances for the overall leach process. The leach model is calibrated against small-scale column leach tests, and simulation results are validated against closely controlled column pilot-scale tests. For a given set of ore conditions, the effects of raffinate irrigation rate are examined. Several options for pulse leaching were investigated, and the effects on copper recovery and pregnant leach solution (PLS) grade are described. Model simulations indicated that pulse leaching could be used to control copper grade of the PLS. Finally, an analysis of inventory issues is presented for various lift heights including multi-lift simulations to examine potential operating options. U sing irrigation rate, raffinate copper grade, and lift height as variables in a factorial design of experiments, the simulations showed that raffinate copper grade is the main factor that affects the soluble copper inventory grade.

Jan 1, 2007

By D. P. Fenton

The Phelps Dodge El Paso Rod Mill produces approximately 2.4 million pounds per day of copper rod from a casting and rolling operation. The newly formed rod is treated to remove mill scale and oxides using a sulfuric acid and hydrogen peroxide solution which is bled periodically when the copper concentration reaches 30-35 g/L. The bleed solution is heated to 75° C to destroy the residual peroxide. Copper is then recovered in a 270 cell EMEW electrowinning plant. Clean acid is also regenerated in the EMEW plant and is returned to the rod cleaning circuit. The EMEW plant commissioned in January 2006, has two operators and replaces a copper sulfate plant with fourteen operators. The EMEW plant has a capacity of 1700 kg/day of cathode copper at 2.1 kWh/kg copper deposited. The electrowinning plant operates in closed circuit with the rod mill returning up to 2600 kg/day of sulfuric acid resulting in zero discharge. Use of dimensionally stable anodes (DSA®) ensures that the acid quality is maintained in the closed loop operation. The operating conditions, performance and plant experience of the EMEW copper and acid recovery plant are discussed.

Jan 1, 2007

By N. Haghdadi, D. M. Maijer, A. B. Phillion

B206 is a recently-developed high-strength Al-Cu casting alloy with reduced Ti and Fe, as compared to the well-known AA 206 alloy, for improved hot tearing resistance. In the current study, the solidification kinetics of this alloy as a function of cooling rate from 1 to 15 K/min were studied using differential scanning calorimetry (DSC) and microscopy. Specifically, the evolution in fraction solid, grain size, and secondary dendrite arm spacing have been characterized. The DSC results show the occurrence of three peaks during cooling from the liquid state, which are related to the formation of primary aluminum, a pre-eutectic intermetallic, and the eutectic phases. Thermal analysis also indicates that while the liquidus temperature is not sensitive to the cooling rate, the temperatures at which the pre-eutectic and eutectic phases form are strongly coupled to the rate of heat extraction. A decrease in the latter temperatures was observed when the rate of solidification was increased, leading to a lengthening of the freezing range of the primary phase. The results will be useful for improving B206 casting processes, specifically through modification of mould cooling conditions.

Jan 1, 2014