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By Asanga S. Nanayakkara

The surface deformations induced by reservoir dilations can be measured using tiltmeters and these measurements can be used to infer reservoir level volume changes by solving an inverse problem. Preferred approach to solve such an inverse problem is to consider more tiltmeter measurements than the number of unknown variables considered in the inverse problem. However, sufficient number of measurement points is not always available due to economical and practical issues. This paper proposes a new approach to circumvent this problem. The new approach entails generation of pseudo surface deformation data by curve fitting tiltmeter measurements using a mathematical function, which delineates three-dimensional characteristics of surface deformation profiles. Then a three-dimensional inverse problem is solved using pseudo surface deformation data. This method is useful in inferring reservoir volume changes with high areal resolution when the number of available measurements is not sufficient to acquire the desired areal resolution.

Jun 1, 2012

By H. Ishimoto

It always has been a serious issue to improve safety in mine sites, demolition work sites, and civil engineering work sites. Especially, collision accidents caused by construction equipment damage not only the productivity of operations but also the health and life of workers in those work sites. To solve this problem, a variety of worker auto-detection means are developed so far, but they have not still become widely used in actual worksites. There have been two controversial points in the prior methods. One is that they were not enough in respect of the detection accuracy and certainty, and the other one is that the information of the detection results was not comprehensible to the operator of equipment. In this paper, the functional requirements of the obstacle detection system in earth moving work site is redefined at first, and then, it is proposed to apply a stereo vision to the obstacle detection system for an excavator. The system consists of horizontally arrayed two digital cameras with low distortion lens, an image processing controller, and a monitor for an operator in the cab. Stereo vision calculates the depth image from images of two cameras and detects the presence of obstacles, its distance, direction, and dimensions. Sensed obstacles are informed to the operator in the monitor image. Preliminary experiments are conducted with a stereo vision system mounted on a real equipment in a demonstration site. The result shows that two controversial points of the conventional technologies are improved, and that the applicability of this system is validated.

Aug 1, 2013

By A. Chamanara

The gross vehicle weight (GVW) of an ultra-class mining truck comprises the unsuspended weight below the struts plus the suspended empty vehicle weight, plus the payload. Theoretically, one third of the suspended total weight is supported by two front struts and two thirds by two rear struts. However, since the payload position is not fixed when placed in the truck body and varies from load to load, compounded by uneven haul road profiles, the truck structure experiences higher than normal stresses, which manifest in the reduction of the life of the truck via structural fatigue. The downstream effects are a decrease in production and increase in operational and maintenance costs. In order to control the dynamic forces causing the high stresses on the truck structure, both the haul road conditions and the load distribution in the truck body need to be investigated. The latter aspect is the prime focus of this paper. A field test has been conducted in an oil sands mine where the Caterpillar 797B trucks are loaded by a Bucyrus 495 shovel. The strut pressure readings are collected using the data-loggers on the trucks as well as the truck velocity associated with each reading. Rack, roll and pitch are the main key performance indicators (KPIs) that are calculated to study the adverse effect of an unbalanced payload and consequently the truck structure. Finally, the shovel bucket load passes within the truck body are simulated and a new method is suggested to improve the truck payload balance.

Aug 1, 2013

By Shuai-Jun Li, Xia-Ting Feng, Xian-Jie Hao

"The anisotropy of rock is of great importance to the rock engineering. To investigate the anisotropic character of slate, the rock samples of slate under different confining pressures and bedding plane angles was conducted on the MTS. The results indicated that the relationship between bedding plane angle and elasticity modulus, friction angle, cohesion and strength was shown as U pattern. The minimum value of them is located from 30°to 45°.In addition, the elasticity modulus and Poisson's ratio increase with the increasing confining pressure. The slate behaves brittle failure both in the uniaxial and triaxial compression. The failure pattern of uniaxial compression is generally tension failure, and triaxial test usually shows shear failure. The failure angle decrease with the increasing of confining pressure.INTRODUCTIONThe anisotropy of rock is that loading in different orientations the rock has different mechanical properties. The anisotropic property of rock is always an important problem in rock engineering (Hoek E. & Brown E. T., 1980). J. C. Jaeger (1960) first presented that transverse strength criterion for sliding fracture on joint surface. Later he revised rock parameters to anisotropy empirically for isotropic Mohr- Coulomb criterion. His main idea is revising cohesion according to loading direction (J. C. Jaeger, 1971). Then, many scholars study a lot on transverse strength criterion. E. Z. Lajtai (1969) considered the influence of connecting rate in all directions in joint groups for shear strength in intact rock; R. Mclamore and K. E. Gray (1967) referenced the theory of J. C. Jaeger. They not only revised cohesion also revised friction coefficient. Y. M. Tien (2000, 2001) made further study on the influence of connecting rate in joint group to transverse strength. R. Nova (1980) studied on the variation of strength when rock specimens in triaxial pressure and complex stress paths. O. Cazacu(1998) put forwards a new anisotropic strength criterion for analyzing rock strength. S. Pietruszczak(2000) introduced fabric tensor for characterizing inner seismic structure and he built an anisotropic strength criterion containing the invariants of stress tensor and seismic fabric tensor."

Jan 1, 2015

By E. Michelotti, M. Cardu

This paper presents the results of a new method that has been tested to recover metallic cobalt lost by diamond beads from rock cuttings. When dimension stones are cut using diamond wire saws, the beads become worn and, before the end of their cycle life, lose a certain amount of material; this material is prevalently made up of sintered metal and diamonds. The material is then washed away, together with rock debris, in a dilute pulp. In effect, this process involves the dispersion of economically valuable, but potentially polluting, materials (such as cobalt) that are used to confer indispensable technological features to the beads. This current research aims to develop a waste-processing pilot plant (High-gradient Magnetic Separator or HGMS) to recover metallic components from the pulp by means of a suitable separation. The research\u2019s purposes are two-fold: a. to remove the polluting components from the rock debris before their disposal and b. to start a recycling process of the valuable metals.

Jan 1, 2010

By Heribert F. Broicher

By the very nature of mineral deposits the quality of the raw material generally fluctuates and should be known for optimum processing. Early classification, for example, of limestone into road-metal grade or lime grade or of run-of-mine ores into high grade, low grade and waste as well as information for blending or for dosage of reagents are prerequisite for economic processing. Non-contact, real-time and on-line rock identification or assessment of quality parameters can be realised by introducing the analysis of laser-induced fluorescence (LIF) into the mining industry. LIF analysis is an optical method evaluating the basically known photoluminescence properties of matter, however, extending the application into hitherto unimagined fields by use of high-energy pulsed lasers and time-resolved analysis of fluorescence in the ultra-violet, the visible and near-infrared domains of light. LIF analysers and test work in a limestone quarry and a cement plant in Germany as well as in an iron ore mine in Sweden are described. First results of test work are available and proof this technology to be promissing.

May 1, 2002

By Gordon E. Forward

Sustainable development in the mining and metallurgical industrial sectors can be implemented by two distinct groups: 1. The managers and operators of existing facilities ? working with industrial processes and systems that have been operating for many years, in some cases several decades 2. Those who are engineering and building new facilities or upgrades of existing plants. The focus of this paper is to look at approaches and tools available to bring sustainable development thinking and action to these two distinct areas. The paper will discuss: 1. The concept of working with existing facilities and processes to minimize waste and maximize product from a regional raw material/resource consumption perspective using By-product Synergy. The BPS concept has been carried out in Texas (TXI-Chaparral?s STAR Example), in Calgary, Alberta with Suncor assistance, in Montreal, Quebec with Noranda as project leader and currently in Ontario with Dofasco as industry champion. Successful outcomes are presented. 2. A new approach to designing greenfield facilities or upgrades to existing plants using a sustainable development review process. Undertaking the review early in every project can institutionalize the concept of discussing and implementing waste elimination, design for environment, eco-efficiency, risk minimization and community awareness and involvement in the future capital stock. The review process has been developed as an excellent tool for measuring and reporting on a corporation?s sustainable development progress. Examples of how this approach has been adopted in the mining and metallurgical industry, and the resultant outcomes are given.

May 1, 2002

By Lin-fang Shen, Shao-jun Li, Zhi-liang Wang

"The meso-structure of real soil consists of numerous particles with different sizes, while the traditional reconstruction method of quartet structure generation set (QSGS) produce relatively uniform soil particles resulting in significant discrepancy between the actual structure and reconfiguration model. In order to remedy the deficiency, the QSGS is improved by considering the influence of porosity and autocorrelative function of soil, which make the models closer to the real soil. Based on the reconfiguration model, Lattice Boltzmann method is combined in the algorithm to conduct further simulation of fluid flow in soil pores. The D2Q9 model is applied to construct the two dimensional model for simulating mesoscopic seepage field of saturated soil by setting the non-equilibrium extrapolation scheme at the inlet and outlet boundary, and the bounce-back scheme at the soil particles boundary as well as the left and right boundary. According to the case study, the proposed program is realized to simulate mesoscopic seepage field of reconstructed soil with constant inlet seepage velocity. The results show that the seepage direction of soil is along the passage with good connectivity, therefore the permeability is controlled by these passages. The seepage velocity in such channels is faster than in bad connectivity channels. Even if the channel has larger pores, the seepage velocity is still small. INTRODUCTIONUnderstanding the seepage mechanism in porous materials is significant in both theoretical and engineering problems. As a typical porous media, soil consists of solid particles and voids, which form connected channels allowing water to flow through. Such seepage in soil exists widely among geotechnical project of slope, foundation pit, and tunnel, etc. Meanwhile, a number of engineering accidents are caused by limited knowledge of seepage characters in soil (Huang, 2006; Liu, 2013). The conventional method in describing seepage features mostly based on the parameter of permeability, which is a macro statistic mean evaluating the whole connectivity of soil. Obviously, this parameter cannot exactly reflect the details of how water flows through the inner soil structure, especially the flow velocity in local mesoscopic area, hence is unable to represent the actual seepage properties. Therefore, it is necessary to develop mesoscopic approaches to fully study the seepage mechanisms."

Jan 1, 2015

By Philippe V. Scheers

Polycrystalline gold, glassy carbon and gold-activated glassy carbon electrodes were compared for the production of hydrogen peroxide by the cathodic reduction of dissolved oxygen. Gold was deposited on glassy carbon by sputtering with a sputter coater and by electrodeposition from a diluted KAuCl4 solution using short potential steps. The sputtered gold particles were not adherent enough, but there were no adhesion problems with the electrodeposited gold particles. The gold coverage of the glassy carbon surface could be varied by applying a different number of potential steps. The overpotential for the electroreduction of oxygen to hydrogen peroxide decreases with increasing gold coverage of the glassy carbon surface, and for gold coverages exceeding about 16 %, the overpotential is close to that observed on polycrystalline gold.

Oct 1, 2003

By S. J. Cook

Outstanding advances among the metals, marked the mineral production records for Canada during the first half of 1925. Production of metals and non-metals reached a total value of $90,347,698. as compared with $84,307,385. in the first half of 1924, an increase of 7.16 per cent. Metals and non-metals produced during the calendar year 1924 were valued at $17 4,202,537.; production during the first half of 1925 showed a sum equal to 51.86 per cent of this total. Advances among the metals were general. Gold rose to a new record. Lead advanced 62.41 per cent over the high mark attained in the first half of 1924. Nickel production was well maintained. Copper was up a million pounds. Silver showed increased values. Zinc followed the trend in lead to almost double the output recorded in the first half of 1924. Cobalt production continued to improve. Despite the loss due to the protracted strike in the Nova Scotia coal mines which reduced the output of coal in that province; during the six months ending June, to less than half the tonnage reported in the first six months of 1924, improved conditions throughout the rest of the non-metal mining field resulted in the production of non-metals during the half-year reaching a total value of $31,199,233. as compared with $36,844,286. in the first half of 1924; the loss in the value of coal output al one amounted to $5,723,873, while the decrease in the aggregate value of non-metals amounted to only $5,645,053.

Jan 1, 1925

By P. Nayak

"Comminution is an energy intensive and expensive process consuming approximately 40-50% of the total processing costs in a mining operation. This process poses an even greater challenge with gold ores due to their low elemental concentration and small particle size. Over 99.9% of the ore fed to the mill is waste which must be removed during the ore processing stage. Preconcentrating the Run of Mine (ROM) ore before feeding the mill will result in significant cost savings. In partnership with Sacré-Davey Engineering, Agnico Eagle Mines Limited identified this opportunity and is currently evaluating the implementation of sorting technology to preconcentrate the ore or upgrade the waste material at its operations. This paper will discuss the steps adopted by Agnico Eagle in the evaluation and installation of sorting technology at its operations. Since the Company has a large portfolio of operations, the first step in the project was to shortlist the operations that had the highest probability for successful application of the technology. Following this, the top three operations were selected for bench scale evaluation. The projects which showed the most economic potential were then considered for detailed evaluation and pilot plant installations. This paper provides an insight into the methodology followed by Agnico Eagle and Sacré-Davey in the evaluation of the technology.INTRODUCTION The benefits of ore sorting technology are being increasingly understood by the mining industry today. The application of ore sorting in gold mining is attractive due to the nature of the mineral distribution. The presence of high value minerals distributed in an extremely small mass of the ROM ore creates a tremendous opportunity for preconcentration with ore sorting. Since Agnico Eagle currently has a portfolio of eight operating mines and numerous development projects and exploration properties, the challenge was to identify the deposits which had the most favourable mineralogy and grade distribution for successful ore sorting. The success of ore sorting is mostly based on the minerals present in the deposit and the grade distribution. The minerals signify the amenability of the deposit for ore sorting and the kind of sensing technology to be used. On the other hand, the grade distribution demonstrates the amount of material that can be rejected without losing value. In order to understand a deposit’s characteristics, it is important to examine the sample’s behaviour with various sensors and then assay it to know its actual value. It is a common practice in the mining industry to document assay value of drill cores and/or material feeding in and out of the mill. However, those VALUES (are insufficient to understand the grade variability on a granular basis. To capture the ore variability in very high resolution and significantly improve the selectivity of the material feeding the mill, it is vital to assay the samples on a rock-by-rock basis, as this is the level of resolution which will be examined by the ore sorter during sorting. A careful and elaborate procedure was followed in evaluating the technology at Agnico Eagle’s operations which is discussed in this paper."

Jan 1, 2019

By L. Bichler

Lightweight magnesium alloys are gaining in popularity for applications in the automotive and aerospace industries, Their use, however, remains limited due to their relatively low strength and creep properties. Lost Foam Casting (LFC) is a new casting process and the strength of foam cast magnesium alloys has not been investigated in great detail thus far, In this research, magnesium alloy AZ91 E and three new alloys were cast by the LFC process to study the effect of varying aluminum and manganese content on the alloy's tensile properties, The study reveals, that the tensile strength of the magnesium alloy is closely related to the relative amount of aluminum in the system. Formation of ß-Mg17Al12 phase was seen to significantly affect the yield strength and ductility of the alloy, Furthermore, formation of manganese intermetallic compounds was seen to effectively increase yield strength of the base alloy, Individual alloy morphologies were analyzed via optical and SEM techniques.

Jan 1, 2004

By C. Prévost, V. Leclerc, R. Pinto, M. Ruel

"A buffer’s ability to dampen production variations is directly related to its size. Small buffers cannot handle large variations in production, resulting in production losses when their inventory is depleted or saturated. This paper presents a predictive control algorithm used to regulate the inventory in a buffer of limited size, subject to large production variations caused by an upstream batch process. The algorithm was designed to manage the acid flow rates in an acid regeneration process, servicing batch leach reactors at Rio Tinto Fer et Titane, in Sorel-Tracy, Québec. The objective was to increase production by reducing equipment downtime caused by imbalances in the acid tanks servicing the leach reactors. The controller attempts to maintain acceptable acid tank volumes by optimizing the leach reactors acid/slag ratio and reaction time as a function of anticipated acid needs, all while maintaining product quality.INTRODUCTION Some beneficiation processes in extractive metallurgy require processing bulk material in batches. Typical examples of metallurgical beneficiation batch processes are smelting, leaching, electrowinning, elution and carbon-in-pulp. These processes are often situated midstream in an ore beneficiation flow sheet and either receive or transfer ore to continuous processes. Batch processes, by their very nature, introduce large variability in the flow sheet, because they process large finite quantities of material at nearly periodic time intervals. In order to dampen variations in production, various buffers–tanks and stockpiles–are utilized to accumulate ore upstream and downstream of batch processes. A buffer’s ability to dampen production variations is directly related to its size (Phillis & Gumede, 2011). Small buffers cannot handle large production variations, resulting in equipment downtime when their inventory is depleted or saturated (Everett, 2010, Berton et al., 2013). Consequently, the batch equipment production rates must be adequately managed to minimize production losses, attributed to depleted or saturated inventories, while maintaining product quality. Algorithms that anticipate or predict future production variations are often utilized to regulate buffer inventories, subject to large flow rate variations (Salvo et al., 2002; Bonvin, 2013). This paper presents a predictive control algorithm used to maintain an acceptable volume in a spent acid tank servicing several batch leach reactors. The algorithm is implemented at the acid leach plant of Rio Tinto Fer et Titane, in Sorel-Tracy, Québec."

Jan 1, 2017

By S. Maleksaeedi

On-site evaluation of strength using hardness is common for different materials. The lack of such relation for aluminum alloys has always been felt. In this work, a finite element analysis of plastic deformation and its distribution in Brinell hardness testing is presented. The analysis has been performed for different strength levels of aluminum alloys. By utilizing the Von Mises equivalent strain in hardness, it is tried to derive a correlation between hardness and strength values for the alloys under consideration. The derived correlation is verified using the experimental values available in literature.

Jan 1, 2004

By B. K. Mishra, Avijit Biswal, B. C. Tripathy, Abhijeet Singh, K. Sanjay, T. Subbaiah

We studied theeffect of anode substrates such as pure lead (Pb), lead antimony (Pb-Sb), and lead-silver (Pb-Ag) on the structural and electrochemical properties of electrolytic manganese dioxide (EMD). X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), and chemical analyses were used to determine the structural and chemical characteristics of the EMD samples. The charge-discharge profile was studied in 9 M KOH using a galvanostatic charge-discharge unit. In all the substrates the current efficiencies were more than 99% except with Pb-Sb where it was 90%. Results revealed the nature of the substrate strongly affected the morphology of the deposited material which in turn affected the electrochemical properties of the EMD samples. XRD analyses revealed that the nature of the anode did not affect the crystal structure of the deposited EMD and all the samples were predominantly ?-MnO2, which is electrochemically active for energy storage applications. The EMD deposited on lead substrate showed superior discharge capacity of 245 mAhg-1 when compared with other substrates.

Jan 1, 2014

By Q. G. Reynolds, R. T. Jones

"Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. A mathematical description is presented for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are shown to have a significant effect on the residence time distribution.INTRODUCTIONThere are some processes in which the time spent by the feed material in a smelting furnace plays a significant role in determining the extent of the reactions between metal and slag and influences the degree of settling of metal droplets from a molten slag.Residence time distributions are well defined for batch and continuously stirred reactors. However, there exist many smelting furnaces that do not fit either of these classifications. Here we will focus on producing a mathematical description for the case of a furnace that is fed continuously, but where the liquid slag and metallic products are tapped intermittently. The effects of slag and metal tapping intervals and the fraction of liquid retained in the furnace, are studied.Previous work (Jones, la Grange and Assis, 1997) has studied the effect of retention time on the degree of cobalt recovery achieved in a slag reduction process. In that work, a method was proposed for the calculation of the mean residence time of the contents of a pilot-plant furnace. That approach is to be extended here for the purposes of providing a more general design or scale-up tool.The maximum allowable depth of molten material in a given furnace is affected by such factors as the desired batch size (or the size of the ladles) and the pressure of the molten material that the tap-hole and surrounding system can withstand. Within these constraints, there might be some scope for choice of taphole position. The effects of this choice need to be understood mathematically."

Jan 1, 2012

By J. Keith Haddock

"Introduction The Luscar company, Forestburg Collieries Ltd., operates the Diplomat Mine located 14 km south of Forestburg, Alberta. Production is now at a declining rate from the 1 million tonnes achieved in 1978 as the reserves are being depleted. Three pits are operated at this prairie strip mine utilizing draglines and stripping shovels to uncover the coal. The coal is hauled to a tipple on site for shipment by rail or highway vehicles or is hauled directly to the adjacent Battle River Generating Station. Geology The mine is currently extracting the Battle River seam on the north side of the Battle River. This is the lower-most seam in the Horseshoe Canyon Formation and is the only one present in the area, the upper seams having been eroded by glaciation. The seam lies generally flat and varies from 2.0 to 5.0 metres thick. It lies under glacial till overburden varying in depth from 5.0 to 12.0 metres. The mineable coal extends from the side of the Battle River valley where it outcrops, to approximately 2.5 kilometres to the north. The mine is spread out over a distance of 8.0 kilometres in an east-west direction. Reserves and Coal Quality After over 30 years of mining at Diplomat, there are now less than 1 million tonnes of mineable reserves remaining on the property. With the commencement of coal production from the Paintearth Mine in 1981, supply to the Battle River Generating Station, formerly Diplomat's biggest customer, is being transferred to Paintearth. Rail shipments and domestic supply will continue until reserves are depleted. The coal has the following specifications:"

Jan 1, 1985

By R. C. Wallace

It was to be expected that the convening of the first Empire Mining Congress in June, 1924 in the city of London would turn men's thoughts very definitely to the question of exploring the mineral resources within the British Empire, the examining of her strength and her weakness in mineral material, and the consideration of steps that might advisedly be taken to strengthen her trade in minerals. That expectation was in part realized, though in the British way of presenting the case, and permitting the inferences to be drawn by implication. The opening address by the President of the Congress, to whom the Empire meant so much, gave a résumé of the contributions to the mining industry which were being made by the constituent parts of the Empire. The papers from the Institutes in Australasia, South Africa and Canada provided the details of resources and practice: while the individual contributions to the proceedings dealt with those phases of the mineral industry which are fundamental to the economic strength of British people, or to the health and well-being of the workers. While the subject matter thus presented was British mineral resources, and while the first consideration was the co-ordination and co-operation of British enterprise throughout the world, there emerged very clearly the wider viewpoint that the discussions had to do with a world industry, and with the contributions that that industry was making, and could further make, to the advancement of civilization irrespective of national boundaries, the world over. The invitations to representatives of the mining industry from the United States to participate in the Congress, and the warmth of approval which that participation evoked, were indications that such a congress cannot to-day be merely national in scope, and that trade in minerals, as in other natural resources, cannot be confined within national boundaries, but will seek its channels, unless artificial obstructions are too great, where the natural channels already exist.

Jan 1, 1925

By J. Jara

Oxygen, ozone and air were evaluated in the oxidation of ferrous iron in the presence of hydrochloric acid ranging from 0.1 to 4 M HC1. Stoichiometric coefficients were determined through mass balances of gases and ferrous titration. The molar ratio ferrous to ozone increases from two at 0.1 M HC1 concentration to six at 4 M HC1. For oxygen the same ratio is constant and equal to 2 and it is in agreement with other works. The stoichiometric coefficient of hydrogen ion was not defined due to the effect of hydrolysis of ferrous and in particular ferric ion on measuring acid concentration by titration with sodium hydroxide. Agitation, gas flow and pressure contribute in the utilization of gas. A technique to compare the gas efficiency at several conditions is discussed and it is based on the relationship between oxygen and ferric during time. There is a strong compromise between gas efficiency and ferrous conversion. Oxygen efficiency decreased with time due to ferrous depletion. The gas efficiency ranged from 3 % (low level of agitation) producing 25 g Fe(III)/h to 12 % at 1000 rpm with 60 g Fe(III)/h converted. At 405 kPa absolute the oxygen efficiency was in the range of 80 % producing 300 g Fe(III)/h. The replacement of chlorine with oxygen to enrich molybdenite concentrates by reducing copper to less than 0.2 % was evaluated. Oxygen can be employed in batch or continuous operation and it can treat molybdenite concentrates with high variation of copper content. The dissolution rate is mainly controlled by oxygen addition in which utilization of oxygen plays an important role. Improvement on safety and environmental conditions is feasible by using oxygen instead of chlorine gas. The economics indicate good opportunities to implement oxygen without significant modifications to the actual circuit and enough benefit when oxygen is well used.

Jan 1, 2007

By J. C. Ingles

"A survey of possible methods for controlling cyanide concentration indicated that the simplest method would involve the use of a potentiometric technique. Such a method was suggested by a paper from the laboratory of Mines Safety Appliances, which described a method for determining hydrogen cyanide in air. In this application, the cyanide was absorbed in caustic and a silver electrode immersed in the caustic solution provided a measure of the cyanide concentration. However, our attempts to use the silver electrode in this simple manner to measure the cyanide concentration of solutions were not very successful. A study of the mechanism by which a silver electrode responds to cyanide concentration made it evident why this simple procedure is not satisfactory.Basically, the silver electrode provides an indication of the free silver ion concentration of a solution, and generally speaking, ignores the other ions' present. It can be used to measure an anion if this anion complexes silver. This technique has been used in complexing studies to determine the activities of such anions as acetate, citrate, oxalate and chloride. To do this, the electrode has to be placed in a solution which initially contains a known concentration of free silver ions. Addition of the complexing anion causes a drop in the free silver ion concentration and hence a change in the potential of the silver electrode. The change in potential can be expressed in terms of the concentration of the complexing anion, and used to indicate its concentration in the solution being analysed. The determination of chloride-ion by a silver-silver chloride electrode is an example of an application of this technique. The solubility of the silver chloride with which the electrode is coated provides the initial free silver-ion concentration. Depression of this free silver-ion concentration by the presence of the excess chloride ion of the sample solution results in a change in the potential of the electrode which is proportional to the chloride-ion concentration."

Jan 1, 1965