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By Erwin L. Zodrow

"For 25 chemical elements in electrostatically precipitated fly ash (Lingan coal-fired power station), concentration changes are studied as a function of increasing proportions of fines (ash particle diameter less than 45 micrometres). Elements that are involved when concentrations increase as the proportions of fines increase are likely to escape into the atmosphere. These are Th, U, As, S, P, Sb, Na, Ag, Zn, Pb, Ni, Ba, Sc, AI, Mo (and Bi, Ge, Ga, F and Li), i.e., more or less highly volatilized elements. Of the less volatilized metals such as Fe, Ca, Cu, Ti, K, Co, Mn (and lanthanides), certain portions presumably also escape as stack emissions. Diadochy and spinel formation in bottom slag is presented as an emission-reducing agent for certain metals.IntroductionThe Lingan coal-fired power generation plant, owned and operated by the Nova Scotia Power Corporation, produces annually about 140,000 metric tons of ash (the residual mineral content after burning coal). The tonnage is based on a 15 per cent average ash content of Cape Breton coal.For purposes of this report, samples of the hard, fused slag (bottom slag) that is accumulated at bottoms of boilers, and electrostatically precipitated fly ash (ep ash), were collected and investigated. Bottom slag is a minor component of the produced ashes.The ashes were surveyed and the presence of over 75 major, minor and trace elements is reported. From this survey, 25 elements were selected to establish elemental enrichment/depletion trends when the proportions of the less than 45 micrometre <45µm) fractions in ep ashes increase. The results are significant in that, taking the case of elemental enrichment, the elements involved are likely to escape into the atmosphere, i.e, highly volatilized elements. Depletion trends for elements are presumably associated with less volatilized elements during coal-firing. Quantification of the emission of atmospheric pollutants is not considered part of this work. ""Igneous"" minerals generated during coal combustion include spinels (found mainly in the bottom slag), quartz, glass and mullite."

Jan 1, 1982

By Fernand Dubuc

"The New Pascalis property is situated in Louvicourt and Pascalis townships, about 200 km east of Val d&apos;Or, Quebec. It is made up of 38 claims under option to SOQUEM since August I, 1981 during which time SOQUEM has earned a 60% interest. The property is underlain by archean basaltic volcanics that have been intruded along the west boundary by the Bourlamaque batholith, and by north -trending dykes.The 1982 disco very is related to the re-evaluation of a 1931-gold showing located in the southeastern part of the property, a combination of the presence of a weak IP anomaly at the eastern end of the showing and overburden stripping at that location, resulted in the discovery of a mineralized diorite dyke.The dyke, which strikes N 20 ° Wand dips vertically , has intruded E-W striking agglomerates. The dyke contains south dipping, gold-hearing quart z-tourmaline-pyrite veins that are distributed in a ladder-type arrangement. Visible gold may he observed in drill core, and is generally associated with pyrite porphyroblasts.Diamond drilling has outlined th e dyke for a strike length of 300 11/ and a width of about 10 m, Result s of this drilling indicate, to a depth of 155 m, reserves of 834 000 metric tonnes grading 8.25 g Au/t un cut or 5.38 g Au/t cut to on e ounce. However, four deeper holes have added depth extension to 400m. Also, west of the dyke and within 150 m, other promising gold values have been intersected within quartz-tourmaline veins associated with other parallel dykes."

Jan 1, 1985

By Robert B. Parsons

"Recent amendments to the so-called ""flow-through share"" rules in our income tax legislation have given a new lease on life to this once popular investment vehicle.The original ""Dome funds"" for exploration in the Beaufort sea recognized the usefulness of flow-through share arrangements, but, by and large, flow-through shares have until recently not been able to compete effectively with other tax shelter instruments-mainly , limited partnership interests.This month, Tax Notes examines the new tax rules for investing in flow-through shares.IntroductionRecent income tax amendments have helped to rekindle investor and industry interest in so-called ""flow-through shares"" as a mechanism for mobilizing funds toward mineral exploration and development activities. In competing for investment funds, flow-through shares have historically placed a distant second in terms of investor popularity, being unable to compete with the more attractive features of limited partnership arrangements. However, primarily as a result of favourable changes to the income tax law, flow-through shares may be well poised for a comeback.This article examines the income tax considerations pertaining to issuing and investing in flow-through shares, and compares the former and the new income tax rules relating thereto. Of course, inasmuch as a flow-through share issue can involve various contractual arrangements between the investor and the issuer, there is a wide range of legal and business factors that generally have to be taken into account. A discussion of these matter s is beyond the scope of this paper, which is restricted to a summary of the special income tax factors attributable to flow-through shares."

Jan 1, 1983

By Fritz F. Prugger

In August, 1970, during routine shaft grouting, a major water source was intersected. Water and quicksand under very high pressure entered the shaft at a rate of 65 m3 per minute. The mine and both shafts were flooded. The breach was sealed simultaneously from within the shaft and through a relief hole drilled from surface. The mine was dewatered, rehabilitated and the equipment was restored. Production resumed two years after the accident.

Jan 1, 1979

By N. W. D. Davis

"As I have recently carried out some further research on the Navan lead-zinc deposit data while working in Michel David's research team, I should like to add a few comments on the paper- ""Universal Kriging for Ore-Reserve Estimation- Conceptual Background and Application to the Navan Deposit"", by M. Dagbert and M. David (CIM Bulletin, pp. 80-92, February 1976). The first comment is that since this research has been carried out, important new theoretical advances have been made which make for an easier application of geostatistics to the non-stationary case (see Matheron0l). This is the theory of intrinsic random functions of order k. With the aid of this theory, it has been possible to write computer programs which can carry out automatically universal kriging, although so far such applications have been largely confined to automatic contouring and not to mining problems. However, if approached with care there is no reason why these methods should not be applied to mining problems and, in this case, an automatic study has been done on this data."

Jan 1, 1976

"This paper describes an alternative method of vehicle control which uses a micro-processor to control the field current and armature voltage concurrently. The field tests carried out and the conclusions drawn from the basis of the paper.IntroductionIt is generally accepted that the main obstacle to a greater use of electric vehicles is the relatively poor range and performance when compared to alternatives such as diesel and petrol-engine vehicles. Much effort has been applied to the problem of increasing the energy storage density of batteries and considerable improvements are now being reported.Improvements in the efficient use of the stored energy, although unlikely to achieve the necessary increase in range and performance for a widespread acceptance of electric vehicles, can nevertheless make a useful contribution. Because the improvement in efficiency is achieved by a reduction in losses, it follows that the temperature rise in drive-train components is reduced. These advantages, coupled with the increasing cost of energy, make improvements in the efficient use of the stored energy desirable, if not absolutely necessary. To achieve this with the large and rapidly varying loads encountered during the operational use of a vehicle will require a more flexible system of control than that provided by the current limit. This paper describes an alternative method of control which uses a micro-processor to control the field current and armature voltage concurrently.The value of these parameters is selected to supply the power demand at the motor shaft, with the minimum losses in electrical transmission, thus increasing the efficiency with which the stored energy is used."

Jan 1, 1982

An Attractive Investment ?Near term low cost and secure PGM producer ?restricted supply legislated demand ?strong pipeline of resource development ?Building Canada?s largest undeveloped PGM-Cu resource ?All work (resource, reserves, DFS, EA) is NI43-101 compliant ?Strong balance sheet: over $8 m in cash with no debt

May 1, 2010

By W. G. Jeffery

"The mining and mineral industries have been, and remain, a major component of the Canadian economy. There are approximately 560 producing mining establishments of which there are some 130 metal mines and an equal number of non-metal mines, the balance being quarries for stone, sand and gravel. For 17 metals and minerals, Canada ranks within the top five as a world producer. There are 29 metallurgical plants. Employment in mining, smelting and refining was about 150000 in 1990. Mineral production, including coal, is about $20 billion. Exports up to the metal stage amount to $15 billion providing a positive trade balance of some $10 billion.The producing industry has a wide diversity of products. The companies range from small single mining operations to large multinationals. In terms of technology the industry has always been in the forefront of cost-effective practice, either using home-grown innovation or freely importing technology from around the world,The Mining Industry Technology Council (MITEC) makes an annual survey of the exploration and R&D expenditures of the senior mining industry that is the mining companies that are involved in mineral production from their existing mines. It does not include those companies solely involved in exploration using funds raised through equity sales.Table 1 shows the actual R&D and exploration expenditures as a per cent of sales. R&D shows a rising trend since 1988although the drop in value of output due to lower prices must be recognized as contributing to the increase. The point about this compilation is that the mining industry re-invests some 4070 of its sales in both exploration and R&D in order to sustain itself. Exploration for the renewal of metal inventories for future mining is a process unique to mining. It is not classified as R&D, and the necessity for this investment goes unrecognized by those who state that the industry does not do enough R&D."

Jan 1, 1993

By F. Goodarzi

"The nature and distribution of the inorganic components and the concentration of certain environmentally sensitive elements, such as, As, Sb, B, Hr, Cd, CI, F, Mo, Pb, S, and Se, or elements detrimental to the utilization by industry such as B, Na, P and S are very important in determining coal quality. The concentration of elements in coal is controlled by the following factors: (1) frequency of occurrence of partings; (2) nature and habit of occurrence of minerals in coal; (3) environment of coal deposition; (4)rank; (5) geological setting; and (6) weathering.Selective mining of coal can reduce the input of undesirable elements such as As and S by eliminating the part of the seam which is enriched in these elements. IntroductionCoal is a sedimentary rock of plant origin and consists of two components: an inorganic component (minerals) which is formed by influx of clastic sediments into the coal-forming environment and also by activities of groundwater, and an organic component (macerals) which is formed from plant debris deposited in the original coal-forming environment. However, coal is a generic term with a broad range of utilization characteristics. A coal that is attractive for use in one market - such as generation of electricity (combustion) - may not necessarily be acceptable for use in another, such as for production of coke (Davis, 1978).The elements in coal are associated with both macerals and minerals. The elements associated with coal macerals, such as C, H and N are termed elements with organic affInities. The concentration of elements with organic affmities (including B, Br, CI, F, I, S, and Mg) often decrease with increasing ash content of coal (Nicholls, 1968; and Finkehnan,1982). FIgure 1 shows such a trend for chlorine. Some of these elements may also be incorporated in coal maceral as very fine mineral grains (Finkelman, 1982). The elements with organic affmities are often volatilized during combustion and carbonization of coal and emitted in the vapour phase. Emission of some of these elements (C, 0, Br, N and S) is of major environmental concern (Lim, 1979)."

Jan 1, 1994

By P. H. Riordon

ONE OF the major sources of the world's supply of asbestos lies in a belt of ultrabasic rocks stretching through the Eastern Townships of Quebec where chrysotile asbestos has been mined continuously since 1878. The productive portion of the belt extends from the town of Asbestos in Shipton town-ship northeastward some 60 miles to the eastern edge of Broughton town-ship. (See map). Twelve mines, currently treating an aggregate of over 60,000 tons of rock daily, produce more than one million tons of asbestos :annually. An equal number of mines are now dormant, having for the most part exhausted their reserves. It is evident from the past and present activity, in this belt that it can look forward to at least half a century or more of large scale production. The host rock to the asbestos de-posits is essentially a peridotite which originally contained I 0 to 15 per •cent pyroxene. The peridotite, associated with dunite, pyroxenite

Jan 1, 1962

By J. G. Whellock, J. W. Matousek

"In spite of their importance to the economics of many metallurgical projects, the values and technical aspects of precious metals losses in smelting operations are relatively undeveloped subjects. This paper attempts to provide a condensed overview of precious metals losses in pyrometallurgy, using some of the limited production and experimental data available. It is intended for three general groups of metallurgists - operators attempting to improve recoveries, cost-accounting engineers making estimates of metal losses in new or modified smelting plants, and research engineers and students.Distribution coefficients of precious metals, the ratios of metal or matte assays to slag assays, are convenient means of comparing smelting processes and the tendencies of the different metals to enter the slag. For silver in lead blast furnaces this ratio is approximately 250;for gold and the platinum group metals in submerged-arc, electric furnaces it is 900. The ratio for gold and PGMs in converters varies with the degree of oxidation of the charge. The over-all cycle-average for industrial installations is tentatively estimated to be 35.IntroductionThe magnitude of precious metal s losses in pyrometallurgical operation s is difficult to assess. The primary producers are generally reluctant to discuss the subject. The by-product producers (the large sulphide smelters o f copper , nickel, and lead) might be more willing to disclose information, but these have precious metals in their feeds in such dilute quantities that accurate accounting is extremely difficult. It is not until numerous processing steps have been taken t hat the precious metals become sufficiently concentrated to permit acceptably accurate sampling and analytical procedures to be followed. Thus, knowledge of the precious metals contents o f the intermediate mattes and slags may simply be unavailable."

Jan 1, 1990

By Clyde Williams

If you would allow me some liberties, I would re-state the title of this talk as Scientific Research, Our Greatest Resource, because that title would represent more clearly a present-day conception of the metals and minerals situation. It is a subject worthy of careful consideration. Canada and the United States are so similar and interdependent in their national economies that, in the following discussion, examples of conditions in the United States may? be interpreted to apply to Canada as well. Moreover, it is a striking fact that the per capita value of mineral production in Canada and the United States in 1940 was almost the same. Therefore, in the consideration of this subject, I have made no attempt to differentiate between the two countries. The consumption of the world&apos;s mineral resources in the last few decades, and particularly during World War II, has been so enormous as to require some form of magic to ensure the continued progress of civilization in the face of a diminishing supply of these resources which are so critically essential. As Dr. C. K. Leith pointed out in 1941, industrial expansion has been so great that, during the first forty years of this century, the world used more of its mineral recourses than in all preceding history. And this did not include the all-out consumption during the succeeding five years of war.

Jan 1, 1947

By Nehad Elsafty

It is always necessary to expand existing buildings, so that they could meet the growing societal needs. Compared with demolishing them and then constructing new ones, the expansion of existing buildings could not only reduce project cost, but also save the use of energy and raw materials in projects. Therefore, it is widely adopted in most under-developed countries. However, the expansion of existing buildings is not an easy task. It has been involved with a lot of issues in defining the scope of work, planning landscape, managing construction activities, etc. This paper investigates the potential challenges in expanding existing buildings. The project of expanding the Al-Agoza Hospital, one of the biggest and oldest hospitals in Cairo, Egypt, is selected as a case study. In the case study, the project documents have been carefully reviewed. The project engineers and the health-care professionals working in the hospital have been interviewed. This way, the point of views from the owner, the architect/engineer, and the contractor have been taken into account. Several lessons are learned through the discussion with these people. The results from this paper are expected to provide pieces of useful advice and suggestion for the expansion of existing buildings in the future.

Aug 1, 2013

By Yulin Zhou, WenFeng Li, Wen Chen

"In this article, with the help of the X-ray photoelectron Spectroscopy (XPS), a modern test method, all the characteristics of the chlorite,and adsorption collector A6 on the surface of chlorite have been studied. There exist abundant carboxylic C-O and C=O structures in the Carbon XPS atlas with strong adhesive ability after the reaction between new collector A6 and chlorite, which indicates that the ring structure and ether-base functional groups can strengthen the reaction between collector A6 molecule and chlorite surface. The results of XPS analysis indicate that the photoelectron spectroscopy peaks of Mg2p and Al2p moved towards low energy after collector A6 absorbed on chlorite surface, which indicates that chemical bonding through electron cloud transfer happened between collector A6 and Mg, Al ions of chlorite surface. The chemical reaction promoted the adsorption of A6 on chlorite surface and eventually improved the ability of A6 to float and collect chlorite.INTRODUCTIONThere are a large amount of iron-bearing silicate minerals such as chlorite in different types of gangue minerals in iron ore from different areas besides quartz (Yingyong et al, 2012; Qiang et al, 2009). There always exist Mg2+, Al3+ Fe3+ and other metallic ions due the isomorphic replacement among the irons of this kind of minerals. The dissolution often occurs on the surface of minerals with abundant metallic ions during grinding process, and some ions are exposed on the surface, such as Mg2+, Fe3+, Al3+, Si4+, which can increase the surface electrical behaviour of iron-bearing silicate minerals (Wanzhong & Chuanyao, 2002; Yuping et al., 2007), making it easy for the surface to react preferentially with the depressants such as causticizing starch which making it impossible for the surface to reach with conventional anionic fatty acid collector (Mowla et al, 2008). Thus, the beneficiation efficiency is dramatically decreased and the improvement of concentrate grade becomes very difficult. The conventional aliphatic acid collector has some defects such as poor selectivity, poor low temperature resistance, sensitive to water hardness, etc. Thus, the addition of synergist (Liu, & Yu, 2015) or other compound reagents (Zhou et al, 2015) can promote the adsorption of reagents to mineral surface, and improve the collecting capacity and selectivity of aliphatic acid collector to minerals. The addition of polar group to nonpolar group in aliphatic acid can improve the water solubility, dispensability and hard water resistance (Tian et al, 2013). The nitrogen atoms in amid ate aliphatic acid collector can adsorb on mineral surface by itself and supply coordinate electron which can form chelating keys to improve the collecting capacity of collector. There exist coordinate electron in oxygen atoms of ether acid collector, which, along with the oxygen on carboxyl compose chelate with metal (Luo et al, 2015). There are also exist some opinions that the ether acid can arrange into similar crown ether structure which can absorb on mineral surface. A new alicyclic unsaturated ether acid compounds collector A6 is adopted in this paper, the structural formula is listed in Figure 1. The A6 has a strong collecting ability to chlorite with strong water solubility and low temperature resistance."

Jan 1, 2016

By Jinsuo Zhang

Investment in coal resource development is affected by a variety of uncertain factors. Investors can make a flexible, strategic decision to achieve the value of risk implicated in those uncertain factors. Therefore, based on real-option theory, we identified key uncertain factors that affect a coal resource investment project, and revealed the formation mechanism of option value in coal resource developing investment project. Then, a multi-factor decision making model was established for a coal resource development investment project with random changes of coal price, interest rate, convenience yield and production cost. Finally, we tested the model and analyzed relevant parameters by applying living data. Our results indicate this model reflects the value of risk implicated in uncertain factors for coal resource development investment, and is able to determine a critical point of decision making change when coal price and production cost varym respectively. By means of parameters analysis, the convenience yield has a positive effect on the project value. The interest rate has a negative effect.

Aug 1, 2013

By H. Stutchbury

Alberta is labouring, and has laboured, under serious difficulties in the marketing of ?her coals, due to a number of conditions which now obtain, but all of which appear capable of solution, and their elimination would insure a very largely increased market for the vast coal resources of that province. It is perhaps necessary to again mention the fact that 15 per cent of the world&apos;s coal resources are to be found in Alberta; 21 per cent of that of North America; 72 per cent of that of the British Empire, and 87 per cent of that of all Canada. While we talk largely of the great wealth of Canada, the immensity of her vast natural resources, it is axiomatic that the mere presence of any natural product in a country does not in itself constitute wealth for that country, unless these raw materials can find a market, either in their raw state, or by the process of manufacture. There are many factors, however, which enter into the marketing of any commodity. The chief of these, in my opinion, is price competition. High costs of production materially reduce the radius in which any product can be marketed, and this applies particularly to coal. Mining costs in the province of Alberta are necessarily high at the present time, due in a large measure to the ease with which the &apos;gopher hole&apos; mine can be opened with small capital.

Jan 1, 1925

By R. Kumar, A. K. Verma

"In this paper, an anisotropic shear behavior of rock joints is investigated under constant normal load condition (CNL). The natural rock joint roughness is transferred to artificial rock samples using room temperature vulcanizing (RTV) silicon rubber. Artificial cylindrical rock joint samples (90 mm diameter and 50 mm height) are made by mixture of cement, sand, and water in the ratio of 1:1.5:0.45 (by weight). Direct shear tests are conducted on these samples in twelve directions at 30º apart at four different normal stresses (250kPa, 500kPa, 1000kPa, and 1500kPa). Thus, 48 samples are tested in laboratory. Test results shows that the peak shear strength (?) of rock joints is anisotropic in nature due to change in morphological features in particular shearing direction. Joint roughness coefficient (JRC) is determined in each shearing direction by trial and error method using Barton’s model (1973). Further, cohesion ( c) and angle of friction ( ? )of joint surface in each direction is determined. Finally, a relationship between angle of friction ( ? ) and joint roughness coefficient (JRC) is developed. Experimental shear strength and Barton’s shear strength is compared and it is found that effect of anisotropic decreases with increasing normal stress. INTRODUCTIONRock mass is generally composed of discontinuity which refers collectively to joints, faults, bedding plane and folds etc. ISRM (1978) defined joint as a line of break of geological origin along which there is no visible displacement. Joint is three dimensional discontinuity which composed of two matched/mismatched surfaces. The presence of joints in rock mass plays an important role to define its overall shear strength, deformability behavior, in-situ stresses and hydro-geological properties. The shear strength of rock joints is important in the design of near surface/ deep geotechnical works (mining excavation, dam foundation, power plants, underground caverns, and slopes).In last 40 years, many constitutive models are developed to predict shear strength of rock joints under CNL conditions (Patton 1966; Landanyi and Archambault 1969; Barton 1973; Goodman 1976; Barton and Choubey 1977; Plesha 1987; Desai ad Fishman 1991; Amadei and Saeb 1992; Maksimovic 1992; Wibowo et al. 1993; Huang et al. 1993; Amadei et al. 1998; Indraratna 2000; Homand et al. 2001; Wang et. al. 2003; Samadhiya et. al. 2008; Asadollahi and Tonon 2010; Ghazvinian et al. 2012). These constitutive models have limitations to predict shear strength of rock joints in one direction. Till date, among all constitutive models, Barton (1973) model is widely used in practice due its simplicity. It includes parameters such as joint roughness and joint compressive strength (JCS) to quantify joint surfaces."

Jan 1, 2015

By R. J. Enkin

Modern mineral exploration depends on multidisciplinary 3-dimensional integration of geological and geophysical data. Identification of the geological sources of geophysical anomalies requires knowledge of the physical properties fingerprint of rock types, formations and their alteration products. Understanding how and why rock physical properties vary within the Earth&apos;s subsurface ensures that appropriate geophysical exploration methods can be chosen, and allows for more efficient and effective surveys to be designed. Physical properties knowledge is integral to geophysical modeling - measured data or values estimated based on geological understanding are used to produce realistic forward calculations and to constrain inversion models. Mira Geoscience and the Geological Survey of Canada, in collaboration with industry and academia, are building a Rock Properties Database System (rpds.mirageoscience.com). It compiles the most valuable physical properties for mineral exploration (density, porosity, magnetic susceptibility and remanence, electrical resistivity and chargeability) linked with location and lithological metadata. A critical knowledge gap, addressed in this study, concerns the dependence of physical properties on alteration and mineralization processes. We report on the results of a collaborative University of British Columbia - Geoscience British Columbia project, ?Integrated Geological & Geophysical Porphyry Models: Adding Value to Geoscience BC Geophysical Data?. As part of the QUEST and QUEST-West geophysical initiatives, Geoscience BC focused detailed geophysical surveys on a suite of six known porphyry deposits: Mount Milligan, Endako, Huckleberry, Bell, Granisle, and Morrison. Physical properties for a set of 269 samples of characteristic host rocks and their altered equivalents were measured. The causes of physical properties variations were investigated through their correlations with ore and alteration mineralogy determined from thin-section observations and X-ray diffraction analyses. Physical properties of variably altered host-rocks and intrusive rocks vary significantly between different BC porphyry deposits. No specific unifying geophysical model exists that can be uniformly applied during exploration. Knowledge of local background geology and local physical properties variations is necessary as host-rocks and intrusive rock compositions vary depending on magmatic affinities, and alteration styles will vary reflecting host-rock compositions, crustal depth and influence of meteoric water. A district-scale exploration strategy requires location of intrusive bodies, which are commonly magnetic, resistive and low in density. Correlations should not be expected between density and magnetic susceptibility, because alteration may lead to magnetite destruction or to secondary magnetite development. Deposit-scale ground geophysics might image potassic alteration zones that can be magnetic in both alkalic and calcalkalic systems. Low magnetic susceptibilities, resistivities and densities might aid in locating the typically more porous phyllic and argillic zones. All geophysical data must be interpreted with background knowledge of local rock types and in light of the expected deposit model and associated magmatic and hydrothermal processes. The most effective means to building physical properties knowledge prior to geophysical investigation remains collecting rock physical properties measurements. The cost of rock properties data collection is low, relative to the overall costs of running a mineral exploration program, and can provide an important framework for design of geophysical surveys, survey method selection, geophysical modelling, and data interpretation.

Aug 1, 2013

By A. Hayatdavoudi, K. G. Sawant, F. Boukadi

"In this work, we found that contact between shale and water results in development of micro fractures. Based on results of experiments on Pierre shale, we conclude that appearance of micro fractures begin with saturation of capillaries, ionic and diffusive transport of water into the shale clays and once capillaries are saturated, the cause of micro fracture propagation is the conversion of ionic activity/exchange to excess pressure that did not exist before fracking. Based on these findings, the spread of micro fractures appear to be a time-dependent phenomenon which has not been addressed in the existing macro/micro fracture models.INTRODUCTIONShale has often been involved as a hazard in drilling operations. This hazard can be defined as “destabilization” of shale. When contacted with water-based drilling fluids, some shales readily swell and sometimes, cause the wellbore to cave-in, slough, wash-out, close, and pack-off, impeding the drilling by sticking the drill-pipe. However, once drilling reaches the desired depth or length, the casing is set, cemented, and perforated, and then actually we wish to initiate fractures and destabilize the shale formation, using hydraulic fracturing.Clays constitute a major portion of minerals in shale. These clays contain a large amount of free energy which is the main factor for “slick” water adsorption/absorption. In fact, the reason for using “surfactants” in hydraulic fracturing fluids is to make the penetration of the fluid into the capillaries much easier, thus water meets with less resistance to enter the small capillaries. Also, the result of high capillary suction pressure is due to small Angstrom size capillaries, smaller pores and presence of ions and hydrateable metal atoms. The free energy is thus, related to all the above mentioned and other affects. Capillary pressure, osmotic pressure and other pressures are responsible for creating the micro-fractures in shale, thus, increasing the network of micro-fractures which leads to more gas production. The objective of this study is to evaluate the pressures of the individual ions which are released by the diffusing “slick” water into shale. These pressures would be added to the above mentioned capillary pressure, osmotic pressure, bacterially-induced pressures, chemically-induced reaction pressure, pressure due to exchangeable ion-transport, pressure due to release of free energy of solvation and eventually to the pore pressure as suggested by Terzaghi’s equation."

Jan 1, 2015

By D. Warkentin, M. Tomlinson, A. Nacu

"This study focuses on comparing the “blinding” effectiveness of various organic additives as part of a general review of using organic additives to mitigate preg-robbing and improve gold recovery during cyanide leaching of carbonaceous gold ores. The laboratory results compared the impact of various organic additives on the prevention of gold adsorption using both activated carbon and ore samples containing carbonaceous matter, generally referred to as total carbonaceous matter (TCM). Although several organic reagents were found to have a significant blinding effect on activated carbon, these results did not translate into increased gold leaching efficiencies with actual ore samples.INTRODUCTION Preg-robbing refractory ores, which contain carbonaceous matter, have been problematic in cyanide plants for many years. In industry, preg-robbing by carbonaceous matter may be mitigated using various techniques including flotation, to remove the carbonaceous matter; addition of blinding agents, to passivate the carbon surface and prevent adsorption of gold cyanide complex; roasting, to partially or fully destroy the carbonaceous matter; chemical oxidation (Abotsi & Osseo-Asare, 1986); pressure oxidation; or microbial deactivation (Dunne, Staunton, & Afewu, 2013). Carbon-in-Leach and Resin-in-Leach are also used as process alternatives in which activated carbon or resins are used to compete with the carbonaceous matter for gold cyanide adsorption. For highly preg-robbing ores, thiosulphate leaching may be considered as an alternative to conventional cyanide chemistry (Baláz, et al., 2000). Natural carbonaceous matter is composed mainly of hydrocarbons, organic acids, and graphitic/amorphous elemental carbon. Natural elemental carbon that behaves as activated carbon is considered to be the main reason for preg-robbing, although the true nature of this phenomenon is not fully understood (Tan, Feng, Lukey, & van Deventer, 2005). In general, the hydrocarbon fraction is assumed to have negligible interaction with gold, while organic acids, such as humic acids, may form complexes with gold, inhibiting its extraction in cyanide solutions. Organic reagents have been used for blinding carbonaceous matter in gold ores prior to cyanidation. Abotsi & Osseo-Asare (1987) tested various organic compounds, with two possible effects in mind. First, the organic compounds were expected to adsorb onto the surface of the solids as anionic/cationic species; the resulting electrostatic interactions between the Au(CN)2- anion and the negatively/positively charged surface would inhibit/enhance the gold uptake. Second, the organic reagents were expected to coat the surface of the carbonaceous component in the ore, limiting the available adsorption sites and reducing gold losses. Optimal reagent dosage depends on ore mineralogy, maturity and surface area of the carbo"

Jan 1, 2019