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By Rodney A. Cooper

The Mary River iron ore deposits were discovered in the 1960?s. The high quality of the deposits was immediately evident, and drilling programs were successful in defining a resource adequate for supporting a feasibility study. Through a combination of ownership, market and political forces, the deposits were not developed. Having missed the window of opportunity, the project remained dormant for over three decades. Baffinland Iron Mines Corporation, with its 100% ownership of the Mary River deposits, began trading publicly in 2004. Modern exploration and metallurgical test work began in 2004 and has continued in 2005 and 2006, resulting in total expenditures during this period of almost C$60 million. In May 2006, an engineering team lead by Aker Kvaerner E&C, a division of Aker Kvaerner Canada Inc., completed a scoping study based on the first of five identified deposits. Highlights of that study include direct shipping of high quality lump ore to Europe over a 34 year mine life at a production rate of 10 million tonnes per annum, based on an indicated resource of 309 million tonnes at 66.1% Fe and an inferred resource of 28 million tonnes at 65.9% Fe. Capital costs were estimated at C$1.5 billion. Using iron ore prices approximately 36% below that of the 2006 market, a pre-tax internal rate of return of 15% was estimated assuming equity financing. Payback on initial capital was 5.9 years. The pre-tax life-of-mine cash flow was estimated to be C$6.3 billion. As a result of this study, Baffinland initiated a Definitive Feasibility Study, under the management of Aker Kvaerner, which is scheduled for completion in December 2007. This paper touches on the geology of the deposits, the current resource and the outlook for expansion. Project permitting, construction planning, logistical challenges and ocean shipping considerations are discussed, providing a current perspective on the project scale, scope and timeline for commercial production. In addition, an overview of the Company?s bulk sampling program will be provided.

May 1, 2007

By Thom Sedun

No sector of the mining industry is more closely tied to local communities than aggregates. Noise, dust, traffic, visuals aesthetics and environmental impacts all fall under the purview of neighbours, local governments and nongovernment organizations. It is no surprise that aggregate operations may not be welcome neighbors in many communities. In British Columbia (BC), the regulatory environment for aggregate operations includes a local component of municipal bylaws and land use-planning in addition to the usual suite of federal and provincial statutes that apply to its sister mining sectors. Additionally, under common law aggregate extraction is not considered to be a land use subject to land use zoning, and some aggregate processing activities can be regulated by zoning. Often traversing multiple local government jurisdictions, aggregate producers find themselves negotiating not only local traffic, but also a mosaic of regulatory environments. There is an opportunity in this present situation to facilitate the application of current technology and practices in the mitigation of many community and environmental concerns associated with aggregate operations. Moving a bulk commodity is a volume-based business, and operators often don?t have time for matters that don?t directly or obviously affect the bottom line. Regulatory agencies often play multiple and complex roles with respect to their industry, not the least of which is the fiduciary role. Balancing how and when to assist an industry is often a difficult decision. For the aggregate industry in BC, the Ministry of Energy and Mines saw an opportunity to assist not only aggregate operators, but also regulatory agencies, local governments, and the general public. Through investing in the Aggregate Operators Best Management Practices Handbook (handbook) project, the Ministry of Energy and Mines (MEM) believes that it will realize a return of upheld community values, enhanced environmental protection, improved regulatory compliance, reduce disputes and a stronger provincial aggregate industry. It is the intent to publish the handbook electronically through the MEM website later this year.

May 1, 2002

By E. Burdukova

Rheological measurements have found a wide array of applications in mineral processing research. Rheological properties of mineral suspensions are highly dependent on the mineral surface properties as described by DLVO theory, and the relationship between these properties and inter-particle interactions is well established. In this paper, rheological properties of mineral suspensions are used to study the differences in behaviour of isotropic talc and anisotropic zirconia minerals as a function of varying properties of the suspension medium, such as pH and polymer dosage, specifically carboxymethyl cellulose (CMC). It was found that the rheological tests when carried out in parallel with electrophoretic or point of zero charge measurements, clearly reveal differences between behaviour of the suspensions of isotropic and anisotropic minerals. These differences are further accentuated with the addition of carboxymethyl cellulose (CMC).

Jan 1, 2006

By Roger J. Higgins

Papua New Guinea is a country on the cusp of development, struggling to find a balance between the demands of national and regional growth, landowner expectations and the maintenance of cultural identity. Ok Tedi Mining Limited is the single largest contributor to PNG?s economy, representing about 10 percent of the country?s GDP. OTML is demonstrating that business and country risk can be managed through effective, respectful partnerships with local communities. OTML?s relationships with the communities of PNG?s Western Province are multifaceted. Communities have borne the brunt of the mine?s environmental impact, yet have benefited enormously from the development that the mine has brought. Importantly, the PNG economy is now the ultimate beneficiary of more than four-fifths of the dividends from the mine, the majority of which are held in trust for long-term sustainable development projects. The paper describes how OTML works with the Western Province communities to create a secure operating environment that recognizes the people?s aspirations for development and self-determination.

May 1, 2002

By T. Liu, C. Shi, T. Fu, M. Zhong

Water inrush in coal mines is induced by the imbalance of the groundwater flow field and the engineering geo-mechanics field. Therefore, to prevent water inrush it is important to predict the critical hydraulic pressure of water inrush in coal seam floors. This paper will investigate a method for conducting theoretical forecasting of the critical hydraulic pressure of water inrush in coal seam floors by adopting the combination method of a genetic algorithm-neural network. First, the topology structure of a neural network (NN) based on genetic algorithms (GA) will be determined and then the critical pressure of water inrush in a coal seam floor using the chosen NN will be predicted. Finally, theoretical forecasting results will be compared with actual measurement results to determine the feasibility and applicability of this method.

Jan 1, 2008

By H. Henao, F. Canales

The present work evaluated the use of copper ore flotation tails as flux in the process of smelting copper concentrates. For this purpose, experimental and simulated liquidus lines were obtained at different ratios of tail/flux. Experimental variables included temperature, partial pressure of oxygen and sulfur dioxide and the conditions of tridymite or spinel saturation. The results indicate the feasibility of replacing the flux by increasing the temperature of the smelting process by 20°C. Results of simulation using FactSage and HSC confirm that the required increase in temperature can be achieved by increasing the flow of concentrate, enrichment of oxygen or increasing the matte grade. INTRODUCTION In the pyro-metallurgical process of copper production, the smelting stage produces two liquid phases, a sulphide phase rich in copper and another composed mainly of oxides called slag. The slag phase is the product of oxidation of the iron contained in the flotation concentrate. The smelting process which is carried out at temperatures of 1250°C, require the addition of silica as a flux and the injection of air enriched in oxygen (Schlesinger 2011). Currently, one of the most important aspects of the mining industry is the minimization of costs, the optimization of the use of available resources and the reduction of environmental impact. Under this context, the use of flotation tails from as a flux in the copper smelting process has the potential of reduced production costs and generate an environmental benefit by reduce the disposal amount of this waste material Regarding the use of copper tails as flux in the copper smelting process, a thermodynamic simulation study using the FactSage software had been reported in the literature (Parra et al., 2011). The results indicated an increase of 35°C in the temperature the liquidus for the equilibrium matte/spinel and a subsequent requirement of energy in the process of approximately 350 [MJ/ton slag]. Given that the calculated viscosity remains in the same order of magnitude, the melting temperature is a more relevant parameter for the evaluation of the use of tailings as flux.

Jan 1, 2019

By I. Paredes, R. Díaz, H. Henao

Smelting of copper concentrate generates a significant amount of dusts which are collected in electrostatic precipitators. This material, which is a complex oxide of Cu, Fe, S, As, Sb, Bi and others, is difficult to recirculate into the smelting process due to the reported high concentration of arsenic. However, the dust also has concentration of copper above 10wt %, aside from reported contents of silver corresponding as much as 25wt% of the total inventories of this element in the smelters. Thus, it is of economic and environmental interest the development of a process able to reduce the concentration of arsenic in the dust and produce a material suitable to be recirculated into the smelting process. The present experimental work shows the results of a process of dust sulfidization-oxidition able to remove more than 65wt% of the arsenic present. INTRODUCTION Copper sulfide deposits worldwide exhibit increasing concentrations of arsenic. One case of interest would be the copper ores from the northern zone of Chile, which report high concentrations of enargite (Cu3AsS4) (Revista química, 2015) (Latinominería, 2014). The obtained concentrate from this ore is treated in a Fluidized Bed Roaster, producing calcines with low concentration of arsenic (<0.5 wt% As). This material is suitable to be treated in a Flash Furnace. At the roasting process, the arsenic is volatilized and then precipitated as fine particles of complex oxides. Most of this particulate material is removed from the gas stream through a device called Electrostatic Precipitator (Minería chilena, 2014). The experimental results reported in the literature indicate that arsenic present in these particulate materials (or dusts) cannot be eliminated in oxidizing atmospheres (air) or with inert gases (N2) in a Fluidized Bed Roaster even at temperatures as high as 700°C. There is also information that even the recovery of valuable metals from the dust is difficult through hydrometallurgical processes (private communication). This is how in some foundries these dusts are considered environmental liabilities. Regarding the decomposition of enargite (Cu3AsS4) in neutral atmosphere, it is reported in the literature (Padilla, 2001) that the main chemical reactions are:

Jan 1, 2019

By L. J. Surges, C. Bazin, D. Hodouin

"A kinetic model was developed for the conditioning and flotation processes of an industrial lead concentrate dezincing circuit. The models were incorporated into a flowsheet simulator. Simulation results demonstrate the advantages of split conditioning of coarse and fine particles and the potential of this approach for the production of the heuristics required for the development of intelligent control strategies.The conditioning model relates the proportions of activated and hydrophobic surfaces and residual reagent concentrations to activator and collector reagent flowrates. The model accounts for the solids and water flowrates, and for the solids grade and size distribution. The flotation model uses the predicted proportion of hydrophobic mineral surface, the aeration rate and the froth depth to estimate cell, bank and circuit performances. IntroductionFlotation has been the object of modelling and simulation studies for more than two decades. The process is usually modelled as a kinetic one in which the particle flotation rate constants are key parameters. Rate constants are related to the operating variables (pH, reagent flowrates, aeration rate, etc), however these relationships are seldom established in the literature.In spite of the large amount of literature on flotation modelling and simulation, few papers deal with the interaction between flotation rate constants and operating variables. This important gap, which was identified in the early seventies by Woodburn (l970), still exists. One of the first attempts to include operating conditions in a flotation simulator was made by King (l973), who explicitly introduced the aeration rate into an air bubble loading model. Lynch et al. (1981) used an empirical model to relate the proportion of slow floating particles to the ratio of collector per ton of ore. Such empirical relationships are difficult to calibrate and cumbersome to use when an activator and a collector are added to slurries in which particle size distribution and surface characteristics are changing. Eascur and Herbst (l982) relate in a fundamental way the mineral flotation rate constants to the aeration rate, froth depth, agitation and frother concentration, however the model does not account for reagent flowrates. Niemi et al. (1982) have proposed a model for the conditioning of minerals and included it into a conventional flotation simulator."

Jan 1, 1988

By I. Silin, M. Stapelmann, H. Wotruba, K. M. Hahn, C. Gerold, J. Katzmarzyk

New deposits are often characterized as low-grade and complex ore bodies. To date, processing of fine grained ore deposits implies complex processing routes with high energy consumption. For that reason, the investigation of dry grinding, e.g. with vertical roller mills (VRM), is an approach to save energy reserves. It is already proven that dry grinding can influence subsequent processing steps. In terms of flotation, the surface characteristics of the minerals are crucial for a successful flotation process, e.g. the sufficient adhesion of mineral particles and air bubbles. Wet grinding results in different surface properties of the product entering the conditioning stage than dry grinding, which has direct influences on the subsequent flotation process. To investigate the consequences for flotation, processing of a copper sulfide ore containing chalcopyrite and bornite was investigated, including grinding and rougher flotation. The effects of wet tumbling mill and dry VRM grinding on the degree of liberation of valuable minerals are characterized using mineral liberation analysis by scanning electron microscopy. The obtained flotation results, as well as the recorded flotation parameters such as dissolved oxygen, oxidation reduction potential and conductivity are presented and discussed. INTRODUCTION Copper production is mainly connected to porphyry copper deposits as main source for copper sulfides such as chalcopyrite and bornite. State-of-the-art processing of these deposits is already established worldwide for decades, combining crushing, fine grinding and subsequent flotation with rougher, cleaner and scavenger stages (del Villar, Desbiens, & Maldonado, Bouchard, 2010). While the demand for copper is increasing, copper grades of the deposits are decreasing and the remaining ore bodies have more complex mineralogy and finer particle size distribution. This implies processing routes with high water and – due to the liberation of fine grained valuable minerals – high energy consumption by fine grinding. One of the main energy consumers in processing plants is the grinding section, which accounts for more than 50% of the energy consumption in processing plants and even 4% of the worldwide energy consumption (Jeswiet, & Szekeres, 2016). Therefore, dry fine grinding alternatives are applied to enhance the overall energy consumption of mineral processing plants: high pressure grinding rolls (HPGR) and vertical roller mills (VRM).

Jan 1, 2019

By A. J. Rigby

The wear mechanisms of the tuyere lines of Peirce-Smith and Hoboken converters are a subject of endless debate and speculation. However, there has been an indication that one of the primary factors in the deterioration of tuyere lines is due to the batch operation of the converting process. The cooling of the brick in the tuyere line during out-of-stack times leads to shrinkage of the brick and resultant opening of the joints. Subsequently, on re-entry of the tuyere line into the bath, the joints become penetrated with matte and re- expansion of the brick is prevented. It is thought that this regular cycle of exiting the batch for slag skimming and replenishment of matte and re-entering for further blowing leads to a gradual “ratcheting” of the tuyere brick lining. If no expansion allowance is furnished between the endplate and the endwall of the lining, then the generation of damaging compressive stress is unavoidable. INTRODUCTION It is generally accepted industry-wide that the integrity of a refractory lined vessel is determined by an inextricable combination of refractory brick quality, the caliber of the lining design and installation, and the severity of the process inflicted upon the high wear areas of the vessel lining. Rigby has summarized the concentrated attempt, over the past several years, to optimize the microstructural, chemical, and fracture properties of the refractories used in non-ferrous pyrometallurgical vessels. Furthermore, lining design concepts involving larger and longer brick and the extent and positioning of expansion allowance in the joints have been extensively trialed. All these efforts have provided some, but not startling, improvements. The simple fact is that a vessel lining composed of bricks with an optimized microstructure and chemical inertness must installed with a well-conceived design to decompress the lining stresses that are generated by the batch operation of copper converters. REFRACTORY QUALITY Converting is conducted by injecting air into the molten matte and white metal for the very purpose of generating iron and copper oxide slags. These slags must be contained by a refractory which, by its mineralogical formulation, is optimized for chemical inertness.

Jan 1, 2019

By J. W. Smith, J. Van Dusen, A. Papachristodoulou

"As part of a study to evaluate factors affecting tankroom air quality, the mechanism of aerosol generation from bursting bubbles in electrowinning operations has been investigated. Typically 2 to 3 mg/m2.s are produced in zinc tankrooms. Analysis shows that the rate of production of film drops (geometric mean diameter - 2 urn] increases with decreasing bubble size, and that jet droplets (geometric mean diameter - 20 um) are not produced with gas bubble larger than - 4 mm. Both mechanisms of drop formation and current efficiency are affected by surface active agents, with an over-all reduction in emission of up to 60% to 70% being achievable. A source control system which does not adversely affect electrolyte properties is always preferred, and coalescence of all gas bubbles in to a continuous stream of gas at a single point on the electrolyte surface would eliminate aerosol emissions. This objective was the basis for design of a coalescence device which, in laboratory tests, reduced the emission rate by over 95%.The control device fit s over the electrodes in the electrowinning cell and is partially immersed in the electrolyte. A number of changes in the design which resulted in significant improvement in the performance of the device are reported.Field tests have shown that only about 75% of the aerosol below 10 um can be eliminated by coalescence. The remainder (up to 95% of the total) is controlled by coalescence of droplets, by impaction on the exposed collector surface and gravitational settling.The device does not interfere with operation of the tankroom, handles the effect of surges in power during harvesting, and is simple and inexpensive to maintain. IntroductionDuring the electrowinning of metals (such as zinc and copper) gases are evolved along the electrode surface forming small bubbles. The bubbles travel upwards and burst on the electrolyte free surface generating, in this way, small droplets. Because the electrolyte is often highly acidic or contains toxic materials, the whole process can result in the formation of an aerosol in the atmosphere above the electrowinning cells which poses a serious health hazard to workers in the area, and corrodes equipment."

Jan 1, 1988

By L. Tong, D. Robinson

"The stirred milling of nickel laterites offers possibilities for improving liberation and selective size reduction of soft nickel-bearing minerals in laterites. Batch grinding tests were performed in a netzsch™ lME4 stirred mill on siliceous goethitic, goethitic, and saprolitic nickel laterites. Tests on the -2,000 µm sample displayed the effects of selective comminution. The -38 µm product of grinding the -2,000/+38 µm feed confirmed the effects of selective grinding and nickel upgrading. Size classification followed by stirred milling is recommended for nickel upgrading. The energy requirement in the stirred milling was also investigated.RÉSUMÉ le broyage par billes de latérites comportant du nickel offre des possibilités d’amélioration de la libération et de la réduction sélective de la taille des minéraux nickélifères tendres dans les latérites. Des essais de broyage en vrac ont été effectués dans un broyeur à billes netzschMD lME4 sur des latérites nickélifères à goethite siliceuse, à goethite et saprolitiques. Des essais sur l’échantillon -2000 µm présentaient des effets d’une comminution sélective. le produit -38 µm de l’alimentation -2000/+38 µm confirme les effets d’un broyage sélectif et du rehaussement de la teneur en nickel. Pour améliorer la teneur en nickel, il est recommandé de classifier le minerai en fonction de sa granulométrie, puis d’effectuer un broyage à billes. l’énergie requise pour le broyage à billes a aussi été étudié."

Jan 1, 2015

By Maureen E. Lipkewich

Education builds long term awareness, acceptance and support for responsible mineral resource development. The MABC Education Program is an award winning education partnership with British Columbia classroom teachers that has helped over 5400 teachers with resources and other learning opportunities. Each year, thousands of students begin, and continue, to learn about our modern mineral industry as a result of this teacher-written program. The CIM network has an integral role in the future of mineral education in today?s classrooms in Canada and programs of this caliber are vital to our future. The industry needs help in raising awareness of the benefits of modern mining and teachers need help in acquiring that information.

May 1, 2002

By Baki Özüm

Early evaluations of Pasquia Hills kerogen shale deposits by Geological Survey of Canada, Saskatchewan Geological Survey, Manitoba Energy and Mines and Sun Oil Company, using modified Fischer Assay, Rock-Eval and other techniques, estimated recoverable reserves of about 2.6x109 barrels of oil in areas favorable for strip-mining; each metric ton of ore was determined to yield about 30 L to 50 L of shale oil remarkably high in aromatic compounds. Western Petrochemical Corp. (WPC) is holding two Oil Shale Exploration Permits covering about 76,635 hectares in the Pasquia Hills Region of eastern Saskatchewan and conducting a 15-corehole drilling program to determine stratigraphic correlation on both first and second white specks kerogen shale. In this program, correlation will be established between oil yield and oil quality, using different retort techniques, including modified Fischer Assay, steam retort and Rock-Eval. Results will lead to further resource evaluation and to a preliminary engineering design for a shale processing plant, including selection of retort process, upgrading of shale oil to petrochemical feedstock, hydrogen management, energy balance and evaluation of environmental impact.

May 1, 2002

Today?s Topics ? Data to decision value chain ? Practical Considerations ? Example ? Before / After DSS ? Quick Decision Support Demo Practical Considerations ? More data is not necessarily better ? Organization and process silos ? Good vs. ?optimal?, but impractical Solutions

May 1, 2008

By C. W. Chao, M. Melashvili, F. Hilário

The processing of a bulk concentrate containing copper as chalcocite, enargite, bornite and chalcopyrite along with pyrite and precious metals of silver and gold was studied. A leaching study was undertaken to examine the application of the atmospheric acid leaching process to a bulk copper concentrate for copper recovery followed by cyanidation or thiosulfate leaching for gold and silver recovery. The extraction of copper exceeded 90% under some conditions and the recovery of gold and silver reached a maximum of 44 and 45%, respectively. A sample of bulk concentrate was roasted in air to oxidize the sulfides with release of sulfur dioxide followed by acid leaching of the roaster calcine and cyanidation of the acid leach solution. The copper extraction reached over 92% and the gold extraction exceeded 88%. The sulfur dioxide may be captured for acid production. INTRODUCTION The processing of a large primary copper deposit in Indonesia is under investigation. One of the possible routes for processing involves flotation of a bulk copper-gold concentrate followed by treatment by an atmospheric leach/SX-EW process for copper recovery. The atmospheric leach residue would then be leached for recovery of gold and silver. A second route involves roasting of the concentrate followed by acid leaching and SX-EW for copper recovery. The leach residue from the roaster calcine would then be leached for recovery of gold and silver. The roaster off-gases could be used for sulfuric acid manufacture, enabling the production of a valuable by-product. The Cobre Las Cruces (CLC) process (Munoz, Garcia, & Delgado, 2017) was designed to treat a resource of copper discovered close to Seville, Spain. The process was developed by Outotec with MK Gold (original project owner). INMET Mining subsequently purchased the deposit from MK Gold and built the copper processing facility. The CLC process is similar to the Mt. Gordon Copper process; except that OKTOP reactors have been installed instead of a low temperature, low pressure autoclave process. The plant was designed to treat 1.3 mtpa of ore at a grade of 6.2% Cu to produce 72,000 tpa of cathode copper over a 15 year project life. The main gangue mineral at Cobre Las Cruces was pyrite. The Cobre Las Cruces ore is therefore similar to a rougher flotation concentrate containing copper minerals and pyrite. The roasting of a rougher flotation concentrate can be designed to produce hematite, basic copper oxides and sulfur dioxide off gas. The acid leaching of the basic copper oxides may produce soluble copper for SX-EW recovery of copper. The sulfur dioxide off-gas may be used to make sulfuric acid.

Jan 1, 2019

By P. Au, R. Kearsey, D. Y. Seo, Patnaik. P. C.

Three nickel based superalloys (7.5%Cr+5%Co+2%Mo+1%Ti+5%Al and Ni balance (wt%)) containing different amounts of W and Re were produced in the single crystal (SX) condition utilizing the Bridgman casting process. First, the effect of different levels of Re, and W on chemical microsegregation were investigated by EPMA quantitative analysis, and eutectic phase fraction analysis. Second, in order to investigate the effect of these refractory elements addition on oxidation behaviour, isothermal oxidation testing of the SX nickel based superalloys was conducted at 1000°C for 277 hours under 3 ppm moisture content of air in a thermogravimetric analyzer (TGA). All three SX nickel based superalloys revealed an excellent SX solidification structure with a common primary dendrite arm spacing of -250 µm and a large fraction of ?/?&apos; eutectic located between the secondary dendrite arms. From the average EPMA compositional results, with the exception of Ni, elements such as Cr, Co, Re, Mo, and W all tended to segregate towards the dendrite core during solidification, while Al, Ti, and Ta were present in greater quantity in the last liquid phase to solidify, which resulted in large eutectic ?/? &apos; phases to form within the interdendritic regions. As the nominal level of Re increased, microsegreagation of Re, W, Cr and Mo increased, indicating that Re had a much greater influence on partitioning behavior compared to W. Figure la shows the specific mass gain as a function of exposure time for each alloy. An alloy with 2wt% of W and Re (Alloy B) exhibited less weight gain compared to two other alloys with either higher content of W or Re (Alloy A and C). Microstructural and compositional analyses of oxidized samples were conducted using SEM and EDS. Figure lb shows the typical surface morphologies of the oxidized Alloys A and B. It is evident that more oxide nodules (indicated by arrows in the figure) were presented in Alloy A. It is speculated that the amount of these nodules was responsible for more mass gain in Alloy A compared to the two other alloys. From the examination of the longitudinal section of the oxidized samples as shown in Figure 2, for Alloy A, nodules actually penetrated deep into the material. For Alloy B, however, a relatively uniform and continuous oxide layer was developed and deeply attacked areas were not observed. It was also found that preferential oxidized regions were located at the area between the ?/?&apos; eutectic phase and the dendrite arms where the concentration of refractory elements was relatively high. Therefore, it is plausible that the oxidation kinetics of these alloys is related to the extent of microsegregation.

Jan 1, 2004

By Daniel Hodouin, Mélanie Proulx, Claude Bazin

"Collector and frother are commonly used to induce the floatability of valuable minerals in flotation plants. These reagents are usually distributed down a flotation bank or sometimes added in a single location at the top of the bank. A review of the literature and some experimental results obtained from laboratory and full scale trials indicate that the way flotation reagents are distributed down a flotation bank may influence the flotation response of coarse particles. The paper summarizes these observations which show that the distribution of reagents is a potential tuning variable for process optimization.IntroductionFlotation is in many cases the only way to concentrate sulphide and some oxide minerals. Flotation is a concentration process that uses particle surface composition to induce the selectivity by mean of hydrophobic reagents. The influence of particle size on flotation was firstly analyzed in the 50's1·2 and intensively investigated in the 70's, early 80's and 90's3-18. Most of the observed results show the existence of an optimum flotation size range9 whose recovery is not significantly influenced by a reduction of collector dosage""18. This result brought the idea of using a small portion of the total collector dosage at the top of a rougher bank and to distribute the remaining through the end of the bank to ensure sufficient collection of the coarse particles that need more hydrophobic coverage to attach to air bubbles and be lifted to the surface.This paper discusses the idea of using the distribution of reagents down a flotation bank to tune the operation of the process. Unlike the literature on the effect of reagents (collectors, frother...) dosage that is dense, little attention has been put on the distribution of reagents in a flotation bank. Although research on this subject has not been pushed very far, some operators have recognized the potential of a strategic addition of reagents down a flotation bank19. Except for a few exceptions, the proportions of the reagents to be distributed down a flotation bank are decided according to operator's experience instead of process analysis in relationships with particle size. This paper recalls observations made by different researchers that lead to the idea of using the distribution of reagents as a tuning variable for the flotation process. The paper does not present a detailed analysis or optimization scheme for tuning the distribution of reagents, but analyzes some plant and laboratory results with a view toward the development of a testing methodology and ultimately a validation or rejection of the idea."

Jan 1, 1998

By Dan Zou, Ji Chen, Deqian Li

"Bayan Obo mixed RE concentrate is the largest RE source in the world. RE elements occur dominantly in bastnaesite and monazite. This paper describes a clean and green technique for processing Bayan Obo mixed rare earth (RE) concentrate. A two-step oxidation method can lead to the effective recovery of REs, thorium (Th), fluorine (F) and phosphorus (P). Ce has a property of valency change, enabling the separation of it from other RE(III) elements. Making use of the interactions of cerium (IV) (Ce(IV)), F and P, a new extraction system was created to separate Ce(IV) effectively from other RE(III) while recovering F, P and Th by complexing F and P following the oxidation of Ce(III) to Ce(IV). The method includes two parts. Firstly, bastnaesite is oxidized by air roasting and sulfuric acid leaching. And then a first leach liquor containing Ce(IV), F and P is obtained. Secondly, monazite was converted into REhydroxide through alkaline attack and then Ce(III) in the RE-hydroxide was oxidized into Ce(IV) by wetair oxidation. After sulfuric acid leaching the oxidized RE-hydroxide, a second leach liquor is obtained. The two parts of leach liquor containing Ce(IV), F and P are then extracted by Cyanex923 to obtain CeO2, CeF3 and CePO4 based on the complex of Ce(IV) with F and P. The raffinate was further extracted by the primary amine N1923, and Th-product was recovered as ThO2. The RE elements recovery yield during the whole process is greater than 92%. The new technique not only provides a new way for Bayan Obo RE ore utilization, but also avoids resource waste and environment pollution.INTRODUCTIONRare Earths (REs) refer to lanthanides, including scandium and yttrium. Owing to the similar structure and property of RE(III), it is difficult to separate them from each other, especially for the adjacent elements. According to the United States Geological Survey, in 2010, the whole world has about 142 million tonnes of rare earth reserves. In that, China ranks the second with 22% following Brazil which ranks first with 32% (Cheng, 2011). There are three main RE ore types in China with about 80% mixed ores in Bayan Obo, 10% bastnaesite ores in SiChuan and ShanDong province and 2.9% ion adsorption ores in Southern China. Bayan Obo mixed RE concentrate consists of bastnaesite and monazite. The concentrate contains CeO2/_REO of 50% and there are 7–8% F, 4-6% P and 0.2–0.3% Th."

Jan 1, 2016

By Ralph Harris, Javier Jara

"Oxygen is essential in gold cyanidation. It is supplied to the leaching media by sparging oxygen or compressed air into the cyanidation tank. The rate of oxygen transfer is critical to achieve the desired oxygen concentration in solution.The performance of a novel device for gas sparging recently developed at McGill University is compared to the mass transfer characteristics of the two spargers most used in the gold industry: the four lance configuration and the inverted cone. The distribution of gas and the kinetics of oxygen desorption of the three types of spargers was studied in a 140 litre tank. The oxygen dissolution of the new device is three to five times faster than the other spargers. This could increase the leaching rate and/or decrease the cyanide and oxygen consumption.IntroductionIn hydrometallurgical processing, it is often necessary to bubble gas through a pulp to carry out the wanted reactions. The gas can act to agitate the pulp and it can also supply reactant. The rates of the reactions which require a reactant supplied by the gas are often dependent on the rates of mass transfer from the gas to the solution.A common example of this is gold cyanidation which requires oxygen for gold dissolution. Since the gold containing slurry is rich in other oxygen consuming substances (sulphide like pyrrhotite), it is important to provide enough oxygen to allow complete gold dissolution within the residence time of the cyanidation reactors. It has been demonstrated that the rate of gold dissolution is directly proportional to the dissolved oxygen concentration of the pulp which in turn is proportional to the oxygen partial pressure in the bubble 1 2 3. Improving the rate of mass transfer of oxygen increases the dissolved oxygen concentration of the slurry and therefore improves the rate of the reaction.The rate of mass transfer from a bubble to its surrounding solution increases with decreasing bubble size and increasing gas bubble residence time which in turn increases with decreasing bubble size. The generation and dispersion of small bubbles is thus critical to achieving high rates of mass transfer. Different configurations and devices used to inject gas have different effects on the bubble size and the residence time, influencing the overall rate of mass transfer. Therefore better mass transfer can be achieved by adopting a more efficient method.The methods tested in this report are the four lance configuration (wall spargers), the inverted cone and a new device, designated HCD. The wall spargers and the inverted cone are used widely in the industry today."

Jan 1, 1994