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By D. Allan Coutts

Demonstration projects using hydrogen as a fuel are becoming very common. Often these projects rely on project-specific risk evaluations to support project safety decisions. This is necessary because regulations, codes, and standards (hereafter referred to as standards) are just being developed. This paper will review some of the approaches being used in these evolving standards, and techniques which demonstration projects can implement to bridge the gap between current requirements and stakeholder desires. Many of the evolving standards for hydrogen-fuel use performance-based language, which establishes minimum performance and safety objectives, as compared with prescriptive-based language that prescribes specific design solutions. This is being done for several reasons including: (1) concern that establishing specific design solutions too early will stifle invention, (2) sparse performance data necessary to support selection of design approaches, and (3) a risk-adverse public which is unwilling to accept losses that were incurred in developing previous prescriptive design standards. The evolving standards often contain words such as: ?The manufacturer shall implement the measures and provide the information necessary to minimize the risk of endangering a person?s safety or health.? This typically implies that the manufacturer or project manager must produce and document an acceptable level of risk. If accomplished using comprehensive and systematic process the demonstration project risk assessment can ease the transition to widespread commercialization. An approach to adequately evaluate and document the safety risk will be presented.

May 1, 2007

By Jesús L. Valenzuela, José R. Parga, Salvador Aguayo, Héctor Moreno

The Merrill Crowe zinc-precipitation process has been applied worldwide on a large number of operations for the recovery of gold and silver resulting in a higher consumption of zinc dust from cyanide solutions. However, in some of plants this precipitate is of low quality, because lead, cadmium and especially copper are precipitated along with gold and silver. The low quality precipitate also requires more fluxes in smelting and shortens crucible life. In this study, a process is introduced to remove copper, silver, lead and cadmium from barren solutions following the Merrill-Crowe process. Copper and silver are removed by precipitation in a serpentine reactor, using sodium sulfide as the precipitator, and sulfuric acid for pH control. The recovery of lead and cadmium ions with natural hydroxyapatite using cow bone powder (CBP) as a new adsorbent material, is introduced. CBP is capable of removing lead and cadmium ions from aqueous cyanide solutions with 99% efficiency. It has the ability to compete with other existing commercial adsorbents for the removal of lead and cadmium. Results show that pH value has a significant effect on copper cyanide removal efficiency, and it was determined the optimal pH range to be 2 - 3. At this pH value, the copper cyanide removal efficiency achieved was up to 99 %; and for the cyanide associated with copper cyanide complexes, the recovery was 90%. Finally, the precipitate quality was improved 400% .This procedure was successfully run at three mines in México.

Jan 1, 2014

"Adopted in 2003, theses guidelines are intended to assist the Qualified Person(s) in the planning, supervision, preparation and reporting of mineral resources and mineral reserve estimates. The report is divided into two broad sections “General Guidelines” appropriate for most metals and “Guidelines Specific to Particular Commodities” for potash, industrial minerals, uranium and coal. “These guidelines are reference in the Companion Policy of NI 43-101 with a statement that a qualified person classifying a mineral deposit as a mineral resource or mineral reserve should follow them.”Executive SummaryThe following is a summary, in table format, of the main elements of the Estimation Best Practice Committee's report ""Estimation of Mineral Resource and Mineral Reserve Best Practice Guidelines"". While the summary table is provided for convenience, the Committee recommends that the report be read in its entirety and the table summary not be used as a stand alone document. These guidelines are not intended to be either prescriptive or exhaustive. They do not preclude innovation. Preamble: These guidelines have been prepared by the Canadian Institute of Mining and Metallurgy and Petroleum (CIM) led Estimation Best Practices Committee. They are intended to assist the Qualified Person(s) (QP) in the planning, supervision, preparation and reporting of Mineral Resource and Mineral Reserve (MRMR) estimates. All MRMR estimation work from which public reporting will ensue must be designed and carried out under the direction of a QP in accordance with National Instrument 43-101 (NI 43-101) and related forms. A QP is defined in NI 43-101 as ""an individual who is an engineer or geoscientist with at least five (5) years of experience in mineral exploration, mine development, mine operation, project assessment or any combination of these; has experience relevant to the subject matter of the mineral project and technical report; and is a member in good standing of a professional association"". Disclosure of MRMR estimates is to be made in accordance with industry standard definitions approved by the CIM (the CIM Standards adopted by the CIM Council in August 2002) which have been incorporated by reference into NI 43-101."

Jan 1, 2003

By J. L. Jambor, R. W. Boyle

"The Magnet Cove barite-sulphide deposit is a raking pipe-like body that replaced and partly filled a large brecciated zone at the junction of two faults at the contact between sedimentary rocks of the Horton and Windsor Groups of Mississippian age. The principal minerals in the deposit are siderite, barite, hematite, pyrite, marcasite, galena, sphalerite, chalcopyrite, tennantite, proustite, pearceite, acanthite and stromeyerite. The mineral assemblage and textural relationships indicate that the minerals were deposited from low-temperature solutions. The source of the elements in the deposit is believed to be the enclosing sedimentary rocks, with connate or ground waters as the transporting medium, and solubility products as the governing factor controlling the abundance and order of deposition of the minerals."

Jan 1, 1966

By Z. Luo, China University of Mining & Technology, C. Duan

"The magnetic separation removal rate of pyrite could be improved effectively by increasing the susceptibility of pyrite. The electromagnetic characteristics and absorption response performance of high-sulfur fine coal were studied in strengthening the susceptibility of pyrite. In the process of treating the sample through the microwave, electromagnetic energy could be converted into heat energy due to dielectric loss and magnetic loss. The RL(dB) was evaluate the performance of absorption response of coal. The microwave improved the susceptibility was in ultra-high frequency region, which is the most natural resonance. The absorption fine coal to microwave was strengthened and microwave energy was improved by adding the magnetite powder with double loss characteristics as the microwave absorber. The dielectric properties and permeability characteristics of the fine coal trend were investigated by maxing magnetite powder. The microwave absorption in different coal thickness was surveyed through the reflection of energy loss.INTRODUCTIONMicrowave desulfurization is one of the most important research directions (Haque, 1999; Makul, Rattanadecho, & Agrawal, 2014; Su, Tang, Zhang, Jing, & Bai, 2014). The working principle of microwave absorption response can be briefly described as the interaction of the sample with microwave energy, which will result in the microwave energy converting into heat energy loss (Keangin & Rattanadecho, 2013). For specific samples, the polarization effect includes multiple polarization mechanisms(Meikap, Purohit, & Mahadevan, 2005). Different polarization mechanisms have different occurrence time and dominant mechanisms. Meantime, energy consumption will be occurred during the process of polarization effect (Chelgani & Jorjani, 2011; Rowson & Rice, 1990) . The absorption of microwave energy in the fine coal is a process of electromagnetic response (Znamenácková, Lovás, Mockovciaková, Jakabský, & Briancin, 2005). Microwave transfers the electromagnetic waves into the heat energy by microwave dielectric loss and magnetic loss for achieving the absorption of microwave energy in the treatment of samples (Lee, Kim, Kim, Chung, & Kim, 2004). The additive magnetic medium is Fe3O4 belonging to microwave energy absorber of double loss medium (Uslu, Atalay, & Arol, 2003)."

Jan 1, 2016

By Norman O. Lotter, Simon Yu, Tony Deng, Antonio Di Feo

"Xstrata Nickel’s Raglan operation, northern Québec, achieved paymetal recovery gains in 2007 by switching the collector from potassium amyl xanthate to sodium isobutyl xanthate. To follow on from that position, Xstrata Process Support (XPS) and A. Di Feo of Raglan proposed that a mixed xanthate system be formulated and tested towards further performance gains. This work selected ethyl and isobutyl xanthates as the candidates. An optimized ratio of these was to be determined by a designed experiment. This suggestion was based on an abundance of published literature that reported mixed collector systems outperformed single ones. A partial factorial design was used to configure four test conditions and a mid-square for the flotation work. The testwork was conducted using High Confidence Flotation Testing. The raw data were analyzed and modelled by Design-Expert software. An optimum ratio of 1.6:1.0 by mass (1.32:1.0 in molar terms) of isobutyl:ethyl xanthate was determined. Without this modelling, the optimum ratio would have been missed. Results obtained with the new baseline flotation test using this optimized mixture showed a 3.3% Ni recovery gain in the bypass concentrate and more than 1% recovery gain for PGM over the single PIBX system. This system has been proposed for and accepted as a plant scale trial in the first half of 2010.INTRODUCTIONConcentrator OperationsMilling and flotation of sulphide ores ahead of smelting and refining is a common practice. This choice results in the larger and more variable paymetal loss in the production of saleable metal [Cramer, 2001]. For this reason, it is common to see an ongoing performance improvement programme at the operations level. When successfully performed, these e"

Jan 1, 2010

By Alan Galley, Tom Hynes, Michel Plouffe

"Mining in Canada’s economy• Employs 320,000+ workers; Wages 30-60% above other sectors• Operates 220 producing mines, 33 smelters and refineries• Paid $8.4B in taxes and royalties to governments in 2010• Invests about $30B in capital projects annually • Largest private employer of Aboriginal Canadians 2• Core supplier to clean-technology sectors• Attracted 18% of world exploration spending in 2010• Efficient TSX processes - 1400 mining companies listed, ~50% of mineral projects are outside Canada• Estimated 1000 Canadian companies in 100 countries• Minerals account for 21% by value of Canada’s goods exports• Top 5 World Producer in uranium, potash, nickel, platinum, aluminum, diamonds, zinc, met coal"

Jan 1, 2012

By K. H. March

In the present very highly competitive condition of the bituminous coal business, it is becoming increasingly apparent that coal mines which do not lend themselves to efficient mechanization cannot long survive. It would seem that those mining operations best fitted to survive the struggle for existence are burdened with the considerable capital and maintenance cast of carefully selected mechanical and electrical mining equipment. The ever changing conditions of coal mine operations require equipment which is adaptable to a variety of uses; and investigation of the mechanical and electrical equipment in most mines will show that the operating duty of much of this equipment is considerably different from that duty for which it was originally selected. And it would appear that one of the essential qualifications for a successful mine management is a marked ability to get satisfactory operating results from equipment which has been transferred from some other operation, rebuilt, rearranged, or in some way adapted to the job at hand. As a striking example of such mechanical ingenuity, many of us recall that the first longwall jigging conveyor used in Nova Scotia was built in Sydney Mines from odds and ends in the scrap pile at a total cost of less than $50.

Jan 1, 1930

By M. E. Holter

"Five main lignite seams occur in the Tertiary Ravenscrag Formation in the Eastevan area, at depths of 100 feet or less. They are named, in ascending order: the Boundary, Estevan, Souris, Roche Percee and Short Creek seams. A total sequence of approximately 250 feet is represented by the coal beds and interstratified clays, silts and sands. Strata dip to the southeast at 25 feet per mile or less and trike northeast. Large areas underlain by coal seams at shallow depths are delineated. Reserve calculations are dependent on detailed information on seam thicknesses and feasible stripmining depths. The stratigraphically higher seams are thinner on the average than lower seams and this, together with the increase in elastic size fractions in higher strata, suggests a retreat of a Tertiary marine margin to the south during the closing depositional history of coal seams and associated strata."

Jan 1, 1972

By F. E. Lee

The following outline gives a brief account of some of the ways in which microscopy is applied to the problems arising from the various operations of the Tadanac reduction works, at Trail, B. C. The Sullivan ore is a very fine-grained mixture of galena, marmatite, pyrite and pyrrhotite. The separation of minerals associated so intimately is a difficult task and requires careful control. Various oils and reagents are used in the process as developed, and it is essential that the operators have a means of control which shall be rapid, and at the same time, approximately correct. This result is obtained by microscopic analysis in the following manner: The operator places a quantity of the material upon a slide, a drop of water is added, and it is covered with a cover glass. Upon examination with transmitted light, the zinc mineral particles appear reddish, the ordinary gangue colorless, the lead and iron sulphides opaque. This method has proved of great assistance both in the development and in the operation of the present method for concentrating Sullivan ore. The miscroscope has thus become as much a part of the metallurgical equipment as the balance and burette. The microscope used in the laboratory is a Fuess "petrographic" with a specially-made vertical "illuminator" by Bausch & Lomb, with the usual accessories.

Jan 1, 1924

By B. Krysa, A. Mitsui, T. L. Koehler

The presence of arsenic, even at trace levels, in copper processing leads to the risk of arsine gas where reducing conditions exist that can reduce any soluble arsenic present to its minus 3 valance state and generate hydrogen gas from the solutions. This risk is understood to be significant within the industry, particularly in the case of liberator cells where copper concentrations in solution are drawn down to remove the copper and impurities from the bleed stream. However, there are numerous other potential areas where the arsine gas risk exists including contact between active metal such as iron, zinc or aluminum and arsenic bearing solutions in pyrometallurgical dust treatment, refining and acid plant operations. In turn this breaks down to different mitigating strategies dependent on the risk scenarios considered; for example, how this risk interacts with Change Management, Confined Space Entry or Contractor Training. The ISO 45001 is an emerging standard meant to improve employee safety, reduce workplace risks and create safer working conditions all over the world. The paper shows a case study of how a framework consistent with the tenets of ISO 45001 has been used to provide a consistent assessment of this risk for a wide variety of copper operations and the expectations of how this may be used to effectively improve the effectiveness of barriers against future incidents. INTRODUCTION Arsine gas (AsH3), first identified in 1775, is a highly poisonous, colorless, non-irritating gas with a mild garlic odor that is heavier than air. Arsine gas is generated when reducing conditions are generated in the presence of hydrogen ions and arsenic compounds. Present permissible occupational exposure limit as defined by Occupational Safety and Health Administration (OSHA) as an 8-hour time-weighted average is ppm (0.2 mg/m3). Further increasing the risk, conventional respiratory protection utilizing half or full masks with gas filtering cartridges provide minimal protection against arsine. In copper processing plants, the risk of arsine generation is well understood in liberator cells, which are part of the electrolysis process. In this process, solutions containing copper are reduced in copper concentration removing not only the copper, but also arsenic, antimony and bismuth. The residual solution can be bled to control impurity build-up in the refinery. In this process, if the copper concentration is reduced to the point where As3- can form, arsine gas is generated via reaction with hydrogen ions generated during the plating process. The copper concentration at which arsine gas is generated depends on copper concentration at the cathode surface, the temperature and the acidity. As a result, there is always a risk of arsine gas generation in the liberator cell. Process measures to minimize or mitigate arsine evolution are tight control on final copper concentration, warm temperatures, fresh feed distribution and internal acid recirculation rates. Operator exposure protection measures are hooding, ventilation, arsine detection systems, restricted personnel access, automated shutdown controls and pre-defined evacuation plans.

Jan 1, 2019

By C. Blais, G. L’Espérance

Characterization of second phase particles is important with regard to their influence on mechanical properties of materials. Analytical electron microscopy offers the possibility to achieve complete characterization of inclusions. Complete characterization of inclusions means quantitative evaluation of their chemistry and the stereological parameters. A characterization technique based on integrated microscopy and involving scanning electron microscopy, image analysis and energy dispersive X-ray spectrometry is presented. A discussion of the use of transmission electron microscopy and electron energy loss spectroscopy is also presented for the characterization of very small particles and compounds (>100 nm).

Jan 1, 1998

By Andrea Lisjak

The mechanical behaviour of Opalinus Clay, an indurated over-consolidated argillaceous rock, is heavily influenced by the presence of preferably oriented bedding planes. The objective of this study is to illustrate a new modeling approach aimed at capturing the bedding-induced anisotropy of Opalinus Clay as observed in the laboratory and in situ. The combined finite-discrete element method (FEM/DEM) is employed as the main simulation tool. FEM/DEM is a numerical method that models material damage processes by explicitly considering fracture nucleation and propagation. A transversely isotropic elastic constitutive law is used to account for different elastic property values in the direction parallel and perpendicular to the layering, while strength anisotropy is captured using a directional cohesive fracture model. Quantitative calibration and validation of the model is based on laboratory results of indirect tensile tests and uniaxial compression tests. Emergent strength and deformation properties, together with the simulated damage mechanisms, are shown to be in good agreement with experimental observations. Preliminary results relative to the analysis of a circular tunnel show that the approach is able to reproduce the main Excavation Damaged Zone (EDZ) formation mechanisms as observed in the field.

Jun 1, 2012

By John Knox

The object of this paper is to present an analysis of the major problems encountered both in the design and application of downhole drills. Particular reference is made to design features governed by: physical size limitations; metallurgical material standards; physical operating environment; range of commercial materials to be drilled; high power output required, coupled with simplicity from the operating and maintenance viewpoint; and bit design. The history of attempts to develop downhole drills is discussed, and representative mechanical configurations are illustrated. The general design and application aspects of the different types are commented on. The application of this drill type in various commercial fields, such as (a) oil-well drilling, (b) open-pit mining and (c) underground mining, is discussed, along with the limitations presently imposed by the commercial state of the art in the manufacture of accessory equipment; e.g., drill rods, air compressors, mountings, etc. Suggestions on the possible future direction of the development and application of this tool are put forth.

Jan 1, 1965

By Moe Momayez

Shotcrete is a practical and economical support system in many Canadian underground mines. Although shotcrete technology has gained acceptance in the mining industry, there are some problems that have emerged with respect to quality assessment and thickness measurement of the liner. This paper presents recent tests performed with a miniature seismic reflection device developed primarily for thickness measurement of this heterogeneous liner. Work was performed on site in an underground mine in Ontario, Canada. This paper also presents the results from laboratory tests performed on fibre reinforced and non-reinforced shotcrete panels that were used to assess the P-wave velocity in both materials. The results of these tests were used in a second on site investigation. The NDT thickness measurements showed good agreement with direct thickness measurement such as coring.

May 1, 2001

By A. D. Misener

Introduction Temperature gradients have been determined for numerous locations in the Canadian Shield in connection with mining operations (1, 2, 12, 13, 14, 15). As part of a programme of geophysical studies of this region, some of these gradients were re-determined by the writer at locations where other thermal properties, specific heat, thermal conductivity, radioactivity, etc., were also to be measured. The ultimate object was to determine the heat flow to the surface at these locations. It was felt that the practice of determining heat flow from the temperatures and conductivities obtained in a single vertical bore hole (3, 4, 5, 6, 7, 8, 9) might give results which were appreciably divergent from the average for a considerable area. Particularly, it was thought that temperature gradients, whether obtained in a single vertical hole or from a number of random locations at various depths in a mine, might be subject to local variations and anomalies serious enough to render unsure any discussions based on them. The procedure followed in this investigation was to select a location where mine workings extended to considerable depth over a reasonably wide area. At selected depths below surface, horizontal drill holes extending into regions of undisturbed rock were located and resistance thermometers were inserted into these holes far enough to record the true rock temperature. An attempt was made to obtain a sufficient number of readings at or near any one level to give a representative coverage of the area selected. This ideal could not always be attained, but the large number of readings obtained for each are a does give a reasonably representative picture of the temperature conditions. These readings required much rime and movement of men and equipment underground . They could not have been obtained without the wholehearted co-operation of the management and considerable assistance from the personnel of the mines concerned.

Jan 1, 1949

By J. Kang

Large-scale land reclamation has been undertaken in Singapore since the 1960s. In the early years, the fill materials excavated from the hills. In recent years, sea sand is the main source of the fill materials. The contractors used to import the sea sand from the neighbouring countries such as Indonesia. However, in early 2000, the sea sand import from Indonesia and Malaysia was banned. Cambodia, Myanmar, and Philippine therefore became the alternative sources for sea sand. Distance between the jobsite and these countries is over 1,200 km, and transporting sea sand from these areas became a critical issue that could affect the contractor?s performance. Figuring out the right combination of transportation means for a longdistance sand transportation would be challenging because of uncertain situations. We developed a stochastic simulation model, using ARENA, to figure out the right quantity of small-size barges, bulk carriers, and loading/unloading equipment, which could help project managers yield the most production for sand transportation. This paper presents how we developed the simulation model, how it was applied to figure out the optimum combination among various size barges, different bulk carriers, and various types of loading/unloading equipment, for the sand transportation project in Singapore.

Aug 1, 2013

By H. C. M. Gordon

MR. A. D. BADOUX: I have listened to Mr. Gordon's excellent paper with great interest, as I personally have gone through some of the experi­ences he has so clearly depicted. In particular, there were a good many times when we were greatly exercised in our minds as to whether we were justified or not in closing-off certain sections in the Allan mine. The difficulty in these cases arose from the fact that a peculiar smell could be detected in these sections but at the same ti me there was no positive evidence of spontaneous combustion either from heat being apparent or from the possible indications of fire getting any worse. It was suspected that the small percentage of -carbon monoxide that could be obtained by analysis in the air in these sections, and also the peculiar odour, were emanating from the coal itself, and, in order to verify this, bore-holes were drilled in the coal and the gases released from these bore-holes were analyzed. They were found to contain carbon monoxide. After quite a considerable length of time this contained carbon monoxide gradually diminished and finally could not be detected when analyzing such samples of gas. It was our intention to follow this matter up further, as such an occurrence of carbon monoxide is practically unknown, but the sections in which these occurrences were found had to be abandoned. Mr. Gordon referred t0 a case of spontaneous combustion in the Allan . mine, and I may say that, although the section in which that occurrence took place was travelled and carefully examined every day by the colliery officials, yet nothing unusual was noticed until the fire actually took place. This tire was the cause of a slight explosion.

Jan 1, 1938

By V. “Ram” Ramachandran

"In view of the increasing number of environmental regulations that have been promulgated all over the world in the last thirty years, non-ferrous smelters and refineries have had to learn and adapt to treating process bleed waste streams containing heavy metals. The result of such treatment invariably yields a gypsum-saturated solution containing salts such as alkali metal sulfates, chlorides and fluorides. Presence of anions such as sulfates, chlorides and fluorides in the discharge streams – presently not a major problem- are coming under increasing scrutiny and will have to be addressed in the near future. It is envisaged that discharge limits for sulfate ions will be in place in the near future. Treatment of brackish water to produce drinking water also results in brine streams containing alkali salts that have to be addressed for proper disposal. This paper reviews treatment options for such streams containing high levels of total dissolved solids with emphasis on sulfate removal. Areas covered would be: a) chemical treatment for removal of various constituents that make up the total dissolved solids b) processes for sulfate removal processes –thermal and non-thermal-to recover and reuse of treated water and c) brine use and treatment options.INTRODUCTIONThe rising cost of water and meeting the ever-changing stringent environmental discharge regulations make water recycling and reuse essential. The metallurgical industry has used water as a medium for dissolving and/or rejecting metals and chemicals in addition to removing thermal energy. Any excess process effluent is collected and sent to end-of-pipeline treatment and ultimately discharged to surface water for disposal under a permit. The conventional- and probably the cheapest way -of treating metal-bearing process effluent streams is lime neutralization followed by sulfide polishing for elimination of heavy metals to produce a stream that meets NPDES discharge limits. This results in a stream containing dissolved solids.These dissolved solids normally comprises of inorganic salts. The possible constituents are cations calcium, magnesium, sodium and potassium. The anions are sulfate, chloride, fluoride, nitrate, carbonate and bicarbonate. In addition to these constituents, the treated effluent streams contain very small amounts of heavy metals, oxyanions such as arsenites, arsenates, selenites and selenates. Process streams from gold operations contain residual cyanide. Small amounts of ammonium ions are also present in these streams based on the pH of the solution."

Jan 1, 2012

By P. J. Finnis

This paper describes the use of wire rope on open-pit mining equipment, giving specifications and examples of the performance achieved. Installation methods are also discussed, making the paper of considerable practical use to mine operators.

Jan 1, 1973