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"The McArthur River uranium deposit is the single richest uranium ore body developed in the world to date. The ore body’s average grade is 15% U3O8. Proven reserves are in excess of 450 million pounds. The grinding circuit is located underground. The ground ore is pumped to a surface facility where the slurry is thickened and loaded into containers for shipping to the Key Lake mill 78 kilometers to the south.The paper will briefly describe the mining method employed. The underground ore handling and grinding circuit, and surface facilities including slurry load out, wastewater treatment and the freeze plant will be described in detail. The paper will emphasize radiation and safety procedures that are followed to minimize operator exposure to radiation risks.LOCATIONThe McArthur River mine is located 78 kilometres north of the Key Lake mill. It is located at latitude 57’ N in northern Saskatchewan, within the southern boundary of the Athabasca formation. The nearest town is Pinehouse, located 320 kilometres to the south. Access to the mine is by an all weather road and by a private airstrip.HISTORYThe McArthur River Operation is jointly owned by Cameco Corporation (69.805%) and Cogema Resources Inc. (30.195%). Exploration for uranium in the McArthur River area started in 1980 by the Saskatchewan Mining Development Corporation, a predecessor company of Cameco.In 1984, a 12-kilometre long basement conductor was identified at a depth exceeding 500 metres. Systematic exploration drilling of this conductor resulted in the discovery of the P2 North deposit. Subsequent surface drilling programs from 1989 to 1992 delineated a narrow ore zone over a strike length of 1700 meters at a depth of 500 to 600 metres. At this time, geological reserves for the deposit were estimated to be 2.4 million tonnes at a grade of 5.0% U3O8 for a uranium content of 260 million pounds U308"

Jan 1, 2001

By W. W. Heywood

"IntroductionCIRCULAR structures on the Arctic islands were first noticed early after World War II. During the indexing of the 1950 Royal Canadian Air Force photographs their occurrence was brought to the attention of the Geological Survey of Canada by Mr. W. B. Waugh, Surveyor General. As a result, I. C. Brown ( 195l) of the Geological Survey of Canada studied the air photographs of these structures and discussed theories that might explain their origin. The author, as a member of the Geological Survey of Canada, spent several months in 1952 and 1953 in reconnaissance study of the geology of Ellef Ringnes island, using the Isachsen meteorological station as a base. Twelve days in the summer of 1953 were spent mapping the Isachsen dome and adjacent areas. The Isachsen dome, one of several similar structures occurring on Ellef Ringnes island, is situated 35 miles southeast of the meteorological station.PhysiographyEllef Ringnes island is a mature, stream dissected plain having an average elevation of about 400 feet. The surface of the plain is undulating with a relief of about 150 feet; only a few of the numerous streams that form a dendritic drainage pattern have eroded valleys this deep. Long, low, cuesta escarpments cross' the plain, which is underlain by sedimentary rocks of Lower Cretaceous and possibly younger age. The sedimentary strata have a low regional dip to the southeast; exceptions are found in the vicinity of the domes, where the strata are up-turned, and in the plateau region, northeast of Deer bay, where they are flat lying. The plateau, which is underlain in large part by basalt, is deeply dissected and has an average elevation of 1,000 feet."

Jan 1, 1955

We report the studies of Proton-Exchange Membrane Fuel Cells (PEM FC) and hydrogen storage materials at McMaster University for the last 14 years. From the initial investigation of ionic conduction mechanism to the revelation of the origin of non-Arrhenius temperature dependence, as well as the synthesis and characterization of high temperature polymer electrolytes, both experimental and theoretical works have been compiled for the fuel cell membranes. In addition to the discovery of suppressed ionic conduction in Electrode-Membrane Assembly (EMA) and novel hydrocarbon PEMs based on micro-emulsion, the first evidence of hydrogen adsorption saturation by carbon nano-tubes was also achieved, which has been the bottleneck for the application of PEM FC. Prior to our study, a number of controversial publications have claimed the hydrogen capacity of these materials to be between 0.1 to 10.0 wt.%, and none demonstrated a plateau of adsorption with pressure that is consistent with monolayer saturation. Others suggested that the tube bundle structure is opened under high pressure to enable higher adsorption on newly uncovered surfaces, but received no confirmation. Using our home made high-pressure instrument with in-situ electrical probes, we found that a plateau is nearly achieved at about 300 atm in the room temperature isotherm, and that nanotube bundles actually compress with pressure instead of splitting, using in-situ electrical measurements.

Jan 1, 2005

By J. E. Hawley, R. C. Hart

"The Preston East Dome gold mine is in the southeastern part of Porcupine district, Ontario, 5 miles southeast of Timmins, and immediately south of the property of Dome Mines, Limited.The claims now owned by this Company were originally staked in 1909. After the property had remained dormant for many years, the present Company was organized in 1936 to resume development operations. Two shafts had been sunk: at the time of the early work on the claims, but lateral work from these failed to reach the ore deposits. A successful diamond drilling campaign undertaken under the direction of D. G. H. Wright, however, was followed by the sinking of a five-compartment shaft arid the erection of a mill. From the start of operations to the end of 1944, 1,292,000 tons of ore averaging $11.60 in gold a ton have been mined.An outstanding feature in this mine is the occurrence of the major gold deposits in quartz porphyry intrusives, though minor deposits are also found in the adjacent Keewatin volcanics. Most of the ore occurs in fractures, but the filling was accompanied by varying degrees of replacement of schistose wall-rocks. The ore deposits may be classified as:"

Jan 1, 1954

By Amauri Garcia, Rodrigo Valenzuela Reyes, Noé Cheung, José Eduardo Spinelli, Leonardo Fernandes Gomes, Rafael Kakitani

"The present research work deals with directional solidification (DS) of both Al-15wt.%Si and Al-15wt.%Si-1.5wt.%Mg alloys and further characterization of the related microstructures. The growth of refined primary Si and refined eutectic is well-known as positive in order to improve mechanical properties of the Al-Si based alloys. Alloying is also an effective method to strengthen the Al-Si based alloys, in which Mg is considered an important alloying element. However, lack of investigation regarding the effects of Mg on microstructure of these alloys is noted. So, in the present research work emphasis is given on both dendritic and eutectic growth being affected by solidification kinetics (V-growth rate and G-thermal gradient) during transient directional solidification. Experimental evolutions of microstructural spacing of both alloys have been determined which becomes possible to understand the effects of Mg coupled with the effects of growth rate on the final microstructural arrangements. A direct comparison of the tensile mechanical properties obtained for the alloys is also performed. It is shown by these correlations that the addition of Mg generally improves the tensile mechanical resistance with a minor decrease in ductility. Furthermore, the Scheil solidification path of the ternary Al-Si-Mg alloy was determined using the computational thermodynamics software Thermo-Calc, resulting in the following sequence of precipitation: Liquid-Si-a (Al)+Si- a(Al)+Si+Mg2Si. This sequence is compared with the experimental microstructure findings.INTRODUCTION Al-Si alloys containing from 4wt.% to 22wt.% Si comprise more than 90% of all Al-based castings. Parts manufactured with these alloys have a wide range of industrial applications due to their excellent castability, crack resistance, good corrosion resistance, good weldability, low density and high strength (Bray, 1976; Zolotorevsky, 2007; Reyes, 2017). Hypereutectic Al-Si alloys are widely used and researched in the automotive and aerospace sectors due to the low coefficient of thermal expansion, resistance at high temperatures, good wear resistance and high strength (Reyes, 2017; Tebib, 2013). Above the equilibrium eutectic composition (~12.5wt.%Si) the amount of primary Si particles becomes significant (Lasa, 2003). In the place of conventional hypoeutectic Al–Si, there is growing interest in hypereutectic Al–Si alloys as a candidate material for the high-quality engines because a higher volume fraction of silicon may bring about superior properties (Matsuura, 2003)"

Jan 1, 2017

By G. H. Gale, M. A. F. Fedikow, L. B. Dabek

Rare earth element (REE) data are reported for ores, sul?de-bearing rocks and host rocks from massive sul?de deposits and barren sul?de facies iron formations in Proterozoic volcanic rocks of the Flin Flon-Snow Lake area, Manitoba. Some of the rare earth elements (e.g., Eu), are selectively leached in zones of intense alteration and redeposited together with the sul?des and silicatesin the uppermost parts of the alteration zones and at the rock-water interface. Chondrite normalized REE pro?les of layered sul?de ores and exhalites proximal to the deposits typically have positive europium anomalies and are enriched in light REE. In contrast, barren sul?de facies iron formations exhibit negative or ‘normal’ Eu pro?les. REE data are useful to explorationists in determining the presence of ‘off-hole’ metal-bearing sul?de zones, in distinguishing metal-poor sul?dic layers related to ‘economic’ hydrothermal activity from barren sul?de facies iron formation and in some instances as a means of establishing ‘ore-equivalent’ strata.

Jan 1, 1997

By A. B. Irwin

Abstract The techniques used in recognizing, recording, and interpreting structures in the Slocan sedimentary ceries in the West Kootenay district of B.C. are presented here in the hope that they will be of use to others working in complexly folded areas. The general pattern of folding in the Central Slocan area is obscured by lack of outcrop over a large part of the country, lack of marker horizons, local complexities of folding, and several systems of faulting. 1t was found necessary to observe and record in great detail all primary and secondary structural features and to analyse those observations on a statistical basis. The determination of bedding tops as well as bedding attitudes proved to be of fundamental importance in determining the pattern of folding. The interpretation of secondary linear and planar structures confirm:; this pattern. Accordingly, the thickness of the Slocan sedimentary series is computed to be several times that formerly postulated. Introduction The data upon which this paper is based were collected largely during the field seasons of 1947 and 1948 when the writer was employed by the British Columbia Department of Mines on detailed mapping in the Slocan mining camp. Additional observations were made by the writer during 1950 when engaged in property examinations for the Geological Survey of Canada. This presentation is largely a condensation of part of a more comprehensive thesis (5) and is restricted to observations and conclusions pertaining to the mapping of complex folds, stripped of any hypothetical discussion. Except for some unique occurrences of primary structures, there are no features or techniques described here which are not presented in standard textbooks on structural geology. It is felt that the major contribution of this paper is the method used in applying these standard techniques to a specific field problem and in interpreting the results.

Jan 1, 1951

By W. G. Mine

In September, 1953, seismographs were installed in the Crowsnest Pass area of Alberta and British Columbia to study the 'bumps' which were occurring in the coal mines at Fernie and Coleman, and to investigate the possibility that they might be related to minor earthquakes in the area. During the initial phase of the work, three seismographs were operated at widely separated stations, two in the region of coal mines at Coal Creek and Coleman and one at Turner Valley, distant from any mining operations. Some earthquakes were recorded at all three stations and, in addition, many small disturbances were recorded by the seismographs located near the mines, especially -by the instrument at Goal Greek. A closer network of radio-linked seismographs was then in-stalled near Fernie, the records of which definitely established that the small disturbances were occurring in the mine workings, both active and inactive. No relationship was established between bumps and local earth-quakes in the area. This work was initiated as a -co-operative effort with the Fuels Di-vision of the Mines Branch, Department of Mines and Technical Surveys, which has undertaken a study into the phenomena of ground stress relief in underground mine workings.

Jan 1, 1958

By Alan E. Cameron

WE assemble again today in this comfortable, hospitable Inn to begin this, the 58th, Meeting of our Society. It is just a year ago when last we met but that year was, probably, the most portentious year in the whole history of mankind. In that year, the German 'Atlantic Wall' was broached, the Rhine was crossed, and Germany, as a Nation, has ceased to be. The agony of Europe is over; convalescence may be, probably will be, slow. But blood no longer flows in Europe. Time will heal the sores, cover the scars, regenerate the industries, rebuild the cities, and re-establish the people. True, the war of all wars is not yet over. True, a bloody conflict remains . But, the power of the United Nations now converges on one target. The rain of blood will be heavy. We can hope the storm will be short. The sun is on the horizon. The light of peace 1s in the sky. What of that Peace? Are we ready for it? Have we a 'sure foundation ' for our future world? Are the footings under that foundation broad and substantial? Can we look forward with confidence to a lasting peace and a fruitful life? The United Nations, even as this is being written, are in conference in San Francisco, placing the footings, rearing the foundations for a world edifice. There are bickerings; there are jealousies. The world is tired, and a tired family always squabbles. We can, we must, believe that the decisions they make, the edifices they rear, will be better than anything we each could effect separately. It will be a compromise, probably; it will carry things that will hurt us, just as it will carry things that will hurt others. We can, we must, believe that the good of the whole is a greater good than the good of the part. Each Nation within the United Nations must sacrifice something, each part of each Nation must sacrifice something, each individual within each part of each nation must contribute something, if the whole is to be wholesome. Sacrifice and contribution must be the order of the day if the New World we are about to build is to be worth while. What of Nova Scotia? The world has travelled far in the last year; how far has Nova Scotia gone? Canada has preparations for the Peace under way; what has Nova Scotia done? Is Nova Scotia preparing counter measures for the sacrifices it must make? Is each of us ready to contribute his share?

Jan 1, 1945

By J. A. Finch

Solvent-coated air bubbles in the Air-Assisted Solvent Extraction (AASX) process achieve the dual role of high solvent specific surface area and ease of phase separation. The thickness of the solvent film is of fundamental interest but difficult to measure directly in the process itself. As an approach interferometry (in the UV-vis region) was used to measure the time dependent thickness of a film formed by blowing an air bubble in kerosene-based solvents. The film was stabilized by the presence of 1.5 ppm silicone oil, as employed in AASX. The film appears to comprise two layers; an outer "free" layer of almost constant thickness and an inner "bound" layer which decreased in thickness with time. The bound layer is considered relevant to AASX. For a 20 mm diameter bubble blown in LIX/kerosene solvent the initial thickness was ~ 3 um which decreased over 10 minutes to a final rupture thickness of 500 nm. The bound layer thickness and time to rupture decreased with decreasing bubble size. Correspondence to prior indirect estimates of solvent layer thickness is examined.

Jan 1, 2006

By David C. Cook

The milling complex, situated just east of the Cassiar townsite, receives raw ore from the tramline and processes it into 105,000 tons per year of milled asbestos fibre. The ore is passed through a concentrator, where a barren rock fraction is removed. The concentrated ore, representing 70% of the feed, is dried, stored and then milled into nine separate fibre classifications. The finished product is packaged into 100-lb bags and loaded into trucks in one-ton units. New air-handling facilities were added in 1977to provide additional air for environmental control.

Jan 1, 1978

By Peter Broad

"Extracting any metal, especially specialty metals and rare earth elements, requires an in-depth analysis of the costs and potential revenue as well as a due diligence study of other stakeholder interests. Rare earth projects are generally in the billion dollar US range or above, and thus failure to accurately predict any loss of revenue caused by impurities within the product or additional effluent treatment costs can destroy an otherwise viable study. Two prime sources of input impurity are considered: impurities in the material feed and from reagents. The effect of these impurities factor on both the product (in reduced revenue) and on residual “tailings” that may incur additional unforeseen costs.INTRODUCTION“Truth passes through three stages. First, it is ridiculed. Second, it is violently opposed. Third, it is accepted as being self-evident” – Arthur SchopenhauerThe era of unscoped, unbudgeted construction ended about 150 years ago. Today’s engineer must design with confidence; but do so amidst proprietary secrets and unfamiliar pollutants, which present a myriad of interesting challenges. Is it possible to build a viable rare earth plant to a realistic budget, without destroying that which we cherish? Some see this as contradictory but in reality it is the only viable option.WHEN GOOD PROJECTS FAILWithout rare earths the Copenhagen agreement might be null and void. Running a wind turbine with a 30 tonne conventional magnet requires some hefty engineering and prohibitive investment. Despite their ‘Green metal’ applications, production of rare earths have created environmental nightmares, as Folger stated in 2011 when visiting Baotou, or has Jaing Mainheng who has been quoted by Ambrose Evans-Pritchard 6 Jan 2013. This comment is not a criticism of China; the details are from a 2012 white paper published by the Chinese Government that initiated a $6 billion environmental clean-up. Nor is China unique; other plants have had problems as well. There were toxic leaks in the 1990s from Mountain Pass, and the Mitsubishi Bukit Merah Plant (built in Malaysia in 1958) required a $100 million clean-up."

Jan 1, 2016

By M. Noaparast, N. Nickoletopoulos, André R. Laplante

"This paper presents an application of the use of synthetic ores to study gold recovery by gravity. Three case studies are presented: the first focuses on the use of tungsten to study applications of Knelson Concentrators for upgrading gravity concentrates; the second on tungsten again, in this case to study the performance of a 86 Falcon Concentrator; and the third on lead to mimic gold's grinding behaviour.It is shown that the use of synthetic ores with metallic substitute for gold is not only expedient, but it can also lead to an increased understanding of separation and grinding mechanisms, because of the more accurate results and controlled particle shapes. The case studies highlight the problems associated with gold particle flakiness and gangue density. The grinding behaviour of malleable materials is shown to be complex, as particles can migrate to coarser size classes by flattening and cold welding, and to finer size classes by folding and actual breakage.IntroductionThe title of this contribution is not entirely misleading. Mineral processing has much to do with philosophy, rather Philosophy, as described by Georgius Agricola:""Furthermore, there are many arts and sciences of which the miner should not be ignorant. First there is Philosophy, that he may discern the origin, cause, and nature of subterranean things; for then he will be able to dig out the veins easily and advantageously, and to obtain more abundant results from his mining. ""1"

Jan 1, 1995

By H. L. Noblitt, Pauline Moyd, Louis Moyd

The deposit, which forms a ridge -adjacent to the York river, in Mont-eagle township, is held by Monteagle Minerals Limited, of Toronto. The ore is in a Precambrian gneiss which is composed of nepheline, scapolite, andesine and microcline feldspars, muscovite and biotite micas, and -corundum. The major orebody is tabular and is exposed for 1,200 feet along the crest of the ridge. It aver-ages about 90 feet in thickness, dips at about 70°, and was intersected by drilling at a vertical depth of 600 feet. The deposit was prospected for corundum in the early 1900's. Recent exploration was undertaken to deter-mine its potential as a source of high-alumina ceramic material, with by-product corundum and white mica. The program included prospecting, mapping, trenching, diamond drilling, bulk sampling, beneficiation research, a large-scale beneficiation test, product evaluation, market investigations, and plant design. Reserves, to a depth of about 300 feet, are estimated at about 3 million tons.

Jan 1, 1962

By Gordon A. Gross

During the last half century major steel industries of the world have become dependent on iron and manganese resources derived from siliceous ironformation sediments. More than two billion years ago vast amounts of iron and manganese were deposited in ironformation sediments on all continents and until recent years their genesis was considered to be a uniquely Precambrian phenomenon. Research work has demonstrated that the origin of the banded ironformations was related to major tectonic features and associated volcanogenic processes that were active throughout geological history. Similar sedimentary-tectonic environments are being explored on the seafloor where metalliferous sediments are forming today. Ironformations are now considered to be a major part of the stratafer group of stratiform metalliferous deposits. They developed in sedimentary basins in areas where deep tectonic fracturing intersected high thermal gradients in the earth?s crust and gave rise to profuse volcanism and the hydrothermal effusive discharge of metals in the vicinity of the volcanic centres. Concepts for the genesis and metamorphism of stratafer deposits as revised in the last half century have had a profound impact in the development of iron ore resources and have had a dramatic impact in the use of metallogenetic concepts for guiding exploration for other mineral resources. They are based on the tectonic history and stratigraphy in the sedimentary basins, the role of hydrothermal volcanogenic processes , as well as environmental and sedimentation factors which influence the deposition of silica, iron , and other metals that were emphasized in the past. Topics of special interest in the genesis of ironformation and stratafer deposits and for guiding mineral exploration are: biomediation in their sedimentation and genesis, the significance of metamorphism in the processing and beneficiation of iron ore and in the genesis of iron ore by natural enrichment processes, syngenetic concentrations of Mn, Ti, Cu. Zn, Pb, Ni, Co, REE, F, Ba, B, As, Hg, W and Au in ironformations and stratafer lithofacies, and the mobilization of gold and other elements by alkaline solutions during diagenesis of ironformation and other stratafer metalliferous sediments.

May 1, 2003

By C. M. Clapperton, K. E. Darke, A. J. Boyce, C. M. Rice, S. D. Redwood

"The Kori Kollo gold deposit is hosted by a c.15 Ma sericitized dacite stock in the LaJoya district on the Bolivian Altiplano. The mineralization is of the Bolivian polymetallic vein(BPV) type, with a signi?cant amount of the gold reserves contained in the oxide cap.Field and microscopic studies, K-Ar dating, ??34S values of pyrite, alunite and jarosite, and ??18O values of alunite and jarosite demonstrate that some of this gold is supergene. Two types of supergene gold are present: minute gold grains, 1 to 10 microns across, of high fineness and associated with jarosite and iron oxy-hydroxides; and ‘invisible’ gold, which is probably sorbed onto minerals such as jarosite and iron oxy-hydroxides.Pyrite ??34S values fall in the limited range -3.5 ± 0.6‰, consistent with a magmatic origin. Sulfate ??34S values are homogeneous and overlap closely with those of pyrite (-1.2 ± 2.1‰), which supports petrographic evidence that sulfates replaced pyrite. By contrast, sulfate ??18O values are inhomogeneous with a large range (alunite +2 to 26‰, jarosite -5 to +18‰). These data are interpreted as reflecting kinetically controlled reactions involving various proportions of atmospheric oxygen and local meteoric water. This is typical of supergene alteration and is due to the seasonally dry climate of the Altiplano.The oxide-zone mineralogy is dominated by sulfates and iron oxy-hydroxide minerals with some phosphates and halides, which indicates that the groundwaters were acidic, oxidizing and relatively saline. Under these conditions the most likely complexes responsible for gold mobilization are halides.Geological data and K-Ar ages indicate that oxidation of the BPV deposits began at least around 11 Ma and possibly up to 15 Ma ago, and that supergene alteration lasted until around 4 Ma. During this period, erosion was minimal. Although supergene processes have been active on the Bolivian Altiplano since the Middle Miocene, in contrast to Northern Chile, enrichment of gold has not occurred."

Jan 1, 1997

By O. Babak, J. G. Manchuk

ABSTRACT A significant factor in evaluating bitumen recovery from an oil sands mine is the particle size distribution (PSD). Increased understanding of mined ore quality and improvement in predictions of recovery can be achieved through PSD modeling. This paper addresses PSD modeling using geostatistics. PSDs may be described using many discrete particle sizes, making this a challenge. The approach parameterizes PSDs with a few statistics. A lookup table is used to reconstruct the PSDs based on models of the statistics. The workflow is applied to Total E&P Canada’s Joslyn Lease and yields good results that reproduce input statistics without introducing artifacts.

Jan 1, 2013

By G. H. Long, D. H. Magnusson

THE DEFINITION of the continental margin, as considered in this paper, is in the broad sense: " ... those provinces of the continents and of the oceans which are associated with the boundary between these two first-order features of the earth" (Heezen et aL, 1959, p. 17). The provinces in the area under con-sideration are: the Continental Shelf, the Continental Slope and the Continental Rise. The Continental Shelf extends from the shoreline to the shelf break, which lies at approximately the 200-meter isobath through-out the region (except north of the Grand Banks, where the break may be defined more properly by the 400-meter isobath). The Continental Slope and Rise occur between the shelf break and the 4,000-meter isobath. (The last figure was somewhat arbitrarily selected for the purpose of this paper.) The Atlantic Continental Margin as thus defined extends along the eastern coast of Canada from the International Boundary in the Gulf of Maine northward to approximately the 60°N latitude off the coast of Labrador. The area of study amounts to at }east 500,000 square miles -an area roughly equivalent to 13 per cent of Canada's total land surface.

Jan 1, 1970

By W. L. Hunter

The preparation of coal for the commercial market is a study both varied and wide, and can be viewed from many angles and in different ways. This short paper can but touch upon the subject and is intended to discuss briefly preparation plants which in some cases would seem to be quite inadequate. The conditions confronting most operators are similar, inasmuch as the existing plants were not built specifically to prepare a product for the market of today, but rather of yesterday. The tremendous strides made in the field of combustion in recent years require that the product be of the highest grade procurable, and in a glutted and somewhat restricted market the buyer may be more pernickety than otherwise. These would appear to be the conditions of today. Where a mine is operated individually, better all-round results seem more readily procurable than in a consolidated effort where so many different conditions are sure to arise demanding cognizance, and in many cases requiring to be incorporated in the scheme of things. In the case of a number of mines being administered to form a central source, that source not having had anything to do with the bringing into being of the institutions over which it presides, we find some of the mines well equipped with facilities to properly screen and load the coal, while in others the facilities are not so good, but are doing their share towards delivering a product that will pass muster and in such quantities that they can be counted on.

Jan 1, 1930

By A. Anderko, R. D. Springer, R. D. Young

A thermodynamic model has been developed for calculating phase equilibria and other properties of multicomponent electrolyte systems. The model has been designed to reproduce the properties of both aqueous and mixed-solvent electrolyte systems ranging from infinite dilution to solid saturation or pure solute limit. The model incorporates formulations for the excess Gibbs energy and standard-state properties coupled with an algorithm for detailed speciation calculations. The excess Gibbs energy model consists of a long-range interaction contribution represented by the Pitzer-Debye-Hiickel expression, a second virial coefficient-type term for specific ionic interactions and a short-range interaction term expressed by the UNIQUAC equation. The accuracy of the model has been demonstrated for common acids and bases and for multicomponent systems containing aluminum species in various environments.

Jan 1, 2005