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By S. J. Buckler

Many metallurgical processes use submerged gas injection to increase the contact area between gas and liquid phases in order to promote faster overall reaction rates. The work presented in this paper is part of an experimental investigation to measure the gas-liquid interfacial area available in bubble plumes within molten metal baths. Measurements of the nitrogen absorption rate during submerged injection into molten iron baths have been used to estimate the interfacial areas of the bubble plumes. A theoretical model was used to predict the superficial nitrogen transfer rate under mixed liquid phase mass transfer -interfacial reaction control. The interfacial area was calculated by dividing the overall nitrogen absorption rate by the superficial rate. Reasonable agreement was obtained between the interfacial areas measured in our laboratory with data from a comparable system reported in the literature. The experimental results were compared with the predictions of three theoretical models and one empirical correlation. The models of Turkdogan (3) and Zhao and Themelis (5) gave the best agreement with our data.

Jan 1, 2004

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012

By D Maschemeyer

The cobalt production of the Chemical Metallurgical Division of Sherritt Gordon Mines Limited was supplemented, from May, 1962, to June, 1964, by processing 3,500 tons of a calcined cobalt-nickel concentrate. This paper describes the reduction roast -aqueous sulphuric acid leach process and the operating practices employed in recovering cobalt, nickel and copper from this oxidized by-product of a lead-copper operation. Incorporated in this paper is a description of how this process was integrated with the existing ammonia leach -hydrogen reduction process for the recovery of nickel and with the soluble cobaltic ammine process for the recovery of cobalt. Introduction T HE Chemical Metallurgical Division of Sherritt Gordon Mines Limited at Fort Saskatchewan, Alberta, has recently completed ten years of operation utilizing the ammonia leach process for the recovery of nickel, cobalt and copper from sulphide concentrates, matte and other materials amenable to this process. A continuing development program, along with the expansion of certain facilities, has enabled the refinery to attain a production rate of 31, 000,-000 pounds of nickel per year by hydrogen reduction. This represents an increase of approximately 85 per cent over the original design capacity of the plant.

Jan 1, 1965

By Caroline B. Chapleau, Mélanie Proulx, Claude Bazin, Gaétan Lavoie

"Quebec Cartier Mining operates a pelletizing plant in Port-Cartier, QC. Grinding, agglomeration and pellets induration are the three main steps in the preparation of iron oxide pellets. In 1998, following different recommendations, the company increased the speed of one of its ball mill in order to increase the grinding efficiency of the machine. As expected, the increased speed lead to an increase of the power draught, which did not produce the expected increase of fineness of grind, neither its allows to increase the mill throughput. The change of behaviour of the mill could hardly be understood by comparison of discharge size distribution at initial and modified mill rotation speed. On the other hand, the use of the selection function from a population balance model provides an insight of the changes that occurred in the mill. This paper reviews the various steps required for the estimation of a grinding mill selection function. Results of the calibration to Quebec Cartier grinding mills show that the increase in the mill speed leads to higher rate of breakage of coarse particles, at the expenses of less efficient breakage of medium and fine size particles. In the case of the studied mill, breakage of coarse particles was probably not the critical step of the mill operation. INTRODUCTIONOre size reduction is the major energy consumption step in any mineral processing operations (Austin et al., 1984). Size reduction is required to either liberate valuable minerals from the gangue minerals in which they are imbedded, or to increase the specific surface of the ground material. Plant engineers continuously face the challenge to find grinding machines, operating conditions or grinding circuit flowsheet configurations that could improve the size reduction process at lower energy or m6dia consumption."

Jan 1, 2000

By Leslie Gertsch

Outline First progress report ? ?Introduction ?Non-terrestrial mining ?Near-term targets ?Stages of mining ?Study procedure Capabilities needed for non-terrestrial mining ?Mining methods ?Mining unit operations ?Typical surface mine operations sequence ?Results to date General effects of gravity ?On fragmentation ?On excavation ?On transport ?Conclusions / Recommendations

May 1, 2013

By W M. Gilchrist

This paper gives an estimation of the future requirements of the western world in relation to energy re-sources. It then goes on to outline the role that atomic power -with its basic raw material, uranium -will play in supplying these energy requirements. Canada's position in this picture is covered, and some interesting forecasts are made. Introduction I T is possible that the following remarks will appear to have more to do with power than uranium. However, to fully comprehend what is in store for the Canadian uranium mining industry, we must be able to estimate the potential requirement, and, to do this satisfactorily, a thorough understanding of the circumstances that will give rise to that demand is necessary. The growing need for electrical energy will play by far the major role, as large tonnages of uranium will be required for its generation. The nuclear weapon has, up to the present, comprised the major market for uranium.

Jan 1, 1964

By Douglas C. Fraser

A DIGHEM survey was flown in the Belford-Montcalm Township area of Ontario in November 1975. This 600-linemile survey resulted in the detection of 134 EM anomalies. The Montcalm Township copper-nickel discovery yielded a single-line anomaly having a conductance of 154 mhos. This anomaly was highly visible because (a) it had the highest conductance in the survey area, (b) it correlated with a 175-gamma thumbprint-shaped magnetic anomaly and (c) it was isolated from long conductive bands. The deposit is a copper-nickel pyrrhotite body which occurs in gabbro and strikes north-south, parallel to the flight lines. The DIGHEM survey was flown north-south, because the exploration program was primarily concerned with locating copper-zinc sulphides in the east-west-striking felsic volcanics. The flight line passed close to the deposit and yielded a 9-ppm anomaly on the chart record. The computer analysis showed that a deposit of exceptionally high conductance (154 mhos) caused the relatively weak (9 ppm) anomaly. The ground follow-up program of magnetics and EM led quickly to the discovery drill hole, which penetrated the orebody in September 1976. Subsequent geophysical surveys consisted of horizontal-loop EM, pulse EM, magnetic and induced polarization surveys over an area of about 8 claims. In addition, a detailed DIGHEM" airborne survey was flown at a line spacing of 100 m to evaluate the entire property of 620 claims. This detailed survey yielded EM conductor maps and contour maps of resistivity, magnetics and enhanced magnetics.

Jan 1, 1978

By Theodore H. Boggs

The battle of the gold standard is not limited to one country alone, or even to a single group of countries. It is being waged merrily in many important commercial and industrial quarters. Though it is not always a practical issue calling for immediate attention, it is none the less, quite widely, engaging the thought of bankers and other students of finance. The controversy arises, in the last analysis, because of the desire of men to secure a stable currency. There are two ways of restoring a reasonably stable currency system: (1) the re-establishment of the gold standard, or (2) the deliberate and artificial management of a paper currency. Both systems are well known. The gold standard was in use prior to the war in the principal commercial countries. A currency of inconvertible paper has been at times employed in the past in various countries; for example in Britain from 1797 to 1821, and in the United States from 1862 to 1879. The gold standard, as all are aware, implies the selection of gold as the standard of value. The unit of value is a fixed weight of gold and, so long as the standard remains unimpaired, all other means of payment are maintained at a parity with standard gold coins. And gold coins alone constitute the standard money, inasmuch as their value as bullion equals their value as coins. Under the gold standard this would not be true of any other form of money, although all other varieties of money, including bank notes, government notes and silver coins would be freely convertible into gold money. Strictly speaking, the gold standard also implies that the gold money in turn shall itself be freely convertible, through melting, into gold bullion and freely exportable.

Jan 1, 1925

By H. M. Kim, J. Rutqvist, D. W. Ryu

"Demand of high pressurized gas storage in underground rock caverns is increasing. Compressed natural gas (CNG) and compressed air energy storage (CAES) are one of the promising examples after since lined rock cavern (LRC) concept has been verified through in-situ pilot tests. Two key essential concerns of high pressured gas storage in underground rock caverns are mechanical stability of the cavern against high inner storage pressure and the risk of gas leakage from the caverns.In this study, we introduce our results of numerical simulations so as to investigate the potential of monitoring for gas leakage at a pilot facility for CAES in underground LRCs. The pilot facility was constructed at a comparatively shallow depth of 100 m, compared to the previous cases with several hundreds of meters, aiming at validating the feasibility of the LRC storage concept in which inner sealing liners, consisting of steel plate and concrete linings, are installed inside the excavated rock caverns (KIGAM, 2011). Compressed air may leak through either initial defects of inner containment liners such as imperfect welding regions and in-situ construction joints of the liners, or through structurally damaged points of the liners during the CAES operation where compression and decompression of the caverns are necessarily repeated and their structural robustness can be deteriorated.For this perspective, we carried out a coupled thermodynamic and geomechanical deformation analysis using TOUGH-FLAC simulator, and investigated the effectiveness of strain monitoring method in detecting mechanical failure of liners which may provide major pathways of air leakage. We therefore used an equivalent continuum model to relate the localized tangential strain to fracture permeability changes, which was developed in our early work (Rutqvist et al, 2012). In detecting and characterizing the leakage location, we tested a cross correlation technique using the synthetic pressure responses monitored in case of the failure of the inner liners. From the investigations, we showed that tangential strain, rather than radial, monitoring especially at the inner face of the sealing liners can be more effective in detecting the mechanical failure of the liners.In localizing the leakage point, we noted that the interface between the inner liners and surrounding rock may not be perfectly bonded so as to increase permeability through which any leaking air pressure may migrate more dominantly. We also demonstrated that the cross correlation of the time histories of pressure measurement especially at these interfaces can be useful in identifying the leakage point. These results may provide useful information in overall design of monitoring and alarming system of our upcoming CAES pilot facilities."

Jan 1, 2015

By D. G. Minnes

Many non-metallic minerals and structural materials are produced in Ontario to serve the needs of domestic manufacturers and export markets. In 1982 production was estimated to have a value of $765 million. Approximately 81 per cent of this was represented by structural materials, nearly 12.8 per cent by salt, and the remainder was other industrial minerals. Total mineral production in Ontario in 1982 was estimated at $3 .16 billion, down nearly $1.5 billion from 1980's high of $4.58 billion.

Jan 1, 1984

By Edward I. Renouard

"THE mineral industry is constantly undergoing changes and facing challenges, and today we are in the midst of another serious one -namely, manpower requirement at every level in the mines, shops and plants. In the not too distant past we had a situation where labour was plentiful, although the equipment, by present-day standards, was quite inadequate, and that's easily understandable when you look back at the primitive methods by which our Western mines were first developed and operated, and then improved by the inventiveness and ingenuity of man.I'd like to show you a few slides from drawings made by Buck O'-Donnell which illustrate some of yesterday's methods of mining. Some of you probably had first-hand experience with some of these so you know they were tedious, time-consuming and involved a lot of heavy labour.Taking the Anaconda Company operations at Butte as an example, we can see what has happened in just the past ten years. In August of 1956, the Butte mines had 5,516 day's-pay employees and 976 salaried employees, for a total payroll of 6,492. In August of this year, there were 3,645 day's-pay employees and 605 on the salaried roll, for a total of 4,250. The number of contract miners had gone from 1,347 in 1956 to 606 in 1966 and that of other underground miners from 2,893 ten years ago to 1,149 this year. Along with these changes, however, another change of special significance has taken place, and that is in the number of skilled craftsmen, surface engineers and so on required for our operations. In 1966, we had 1,890 of these people, 600 more than in 1956 and nearly three times as many as just twenty years ago."

Jan 1, 1967

By W. P. Campbell

Foreword At the outset, it should be stated that this paper does not pretend to present a panacea for the ills that 'frozen' wells are heir to, but rather is an attempt to bring to the attention of those whose special concern it is, a little theory and some facts, which have been brought to light recently, in connection with the problem of 'freezing' as it applies to naphtha-producing wells in the Turner Valley field, and to draw some conclusions that follow from the facts discovered. It should also be stated that the investigation is not to be regarded as in any sense complete, but in progress. Doubtless new facts will be brought to light from time to time which may modify present ideas on the subject, but whether favourable or contrary, these will be welcomed, as the purpose of the Department is to secure as complete information as possible of the factors contributing to 'freezing', since this must be the first step to an intelligent attempt to remedy or prevent its occurrence, if such can be done. It is possible, too, that the cause or causes of freezing may not be the same in all cases, but whether this be so or not will have to be determined later as new information comes to hand. Introduction One of the worries which must constantly confront the operators of gas-naphtha producing wells in Turner Valley-although all, fortunately, have not met with it-is the possibility of the occurrence of what is commonly called 'freezing' (going off production).

Jan 1, 1930

By H. Staton, XPS Consulting & Testwork Services, T. Deng, M. Kelvin

"Lundin Mining’s Eagle Operation, located in Marquette County, northern Michigan consists of a mine and concentrator that processes a Ni-Cu-(PGE) ore. Mine production began in 2014 and is expected to achieve production of approximately 23,000 tonnes of Ni and 20,000 tonnes of Cu per year. The ore is trucked to the Humboldt Mill, where both a Ni and Cu concentrate is produced.XPS Consulting & Testwork Services (XPS) has assisted the team at Eagle since 2013. Prior to start up, the ore was piloted at the XPS lab in Sudbury, Ontario to demonstrate the concentrator flowsheet and establish flotation operating strategy. XPS consulting metallurgists worked closely with the Eagle team during the commissioning of the plant providing troubleshooting, sampling, metal balancing expertise and support. Finally, a series of monthly composites over a 6 month period was submitted for mineralogical characterization to assess plant performance, identify opportunities for improvement and to provide a baseline for the future operation.Lundin’s investment to test the ores ahead of mining and to team with XPS’s experienced mineral processing engineers to help commission the plant has led to the plant achieving concentrator production targets shortly after startup. The commitment to training and implementation of best practices, and a culture where ongoing testing is the norm, puts the Eagle Operation on sound footing for future operation.INTRODUCTIONLundin’s Eagle Mine is a subsidiary of Lundin Mining located in the upper peninsula of Michigan. The mine itself is an underground operation and the ore is trucked from the Eagle mine site 2 hours to the Humboldt mill.The ore is an ultramafic hosted high grade Cu Ni deposit and exists as either massive or semi massive sulphides. The high resource grade of Cu (2.49%) and Ni (2.93%) make this a valuable ore source. (Owen & Meyer, 2013) A metallurgical team was put together by Lundin to ensure the mill was designed and commissioned to optimize metallurgy in the shortest time from this valuable deposit. The commissioning plan targeted commercial production by Q1 2015."

Jan 1, 2016

By N. V. Mel'nikov

This paper discusses the reserves of oil, natural gas and coal in the USSR, with particular attention to the future role to be played by coal in supplying the energy fuel resources of the country.

Jan 1, 1972

By Paul Graham

Presentation Focus ? What is LTUG / What do we do? ? History of LTUG ? Examples of Benefits from LTUG Participation ? Encourage Participation What is LTUG? ? An informal gathering of surface mining companies to discuss and work issues of common interest and to share information and best practices around large tires.

May 1, 2008

By T. Majcherczyk

Shaft lining reinforcing analysis of two shafts under construction has been presented in this study. The first shaft was driven from the surface, while the second was deepened. Mining and geological conditions have been studied with respect to the lining capacity. The improvement of shaft stability comprised two elements, i.e. reinforcement of the shaft lining capacity and improvement of the strength properties of the rock mass. In both tested cases, the particular hazard was connected with non uniform loadings of the lining, which could generate shearing stresses within lining structure. Thus such elements as armored concrete with high strength properties, bolting and injection sealing of the rock mass, and the use of special ring reinforcing the shaft lining have been used in order to reinforce the shaft-rock mass system. Practical conclusions related with new technological solutions, allowing the rock mass and shaft lining reinforcement, have been included for the present study. Practical conclusions related with new technological solutions, allowing for rock mass and shaft lining reinforcement, have been also included to the present study.

Aug 1, 2013

By Eiichiro Mizushima

Catalyst systems comprising (Ph3P)AuCH3 and acid co-catalysts were found to be highly efficient for hydration of alkynes to give ketones. Methanol was the best choice of solvents. Introduction Hydration of carbon-carbon unsaturated bonds is one of the environmentally benign routes to the carbon-oxygen bond formation. Hydration of alkynes forming carbonyl compounds, an important variation in this category, is a well known reaction which has been extensively studied. The reaction by acid-catalysis is the most conventional method, while it is applicable only to electron rich acetylenes to obtain satisfactory yields (1,2). The hydration of simple alkynes usually requires another catalyst (co-catalyst), typically a mercury(II) salt (3), which is inconsistent with the guiding principle of Green Chemistry (4).

Oct 1, 2003

By R. J. Mitchell

"A lest apparatus has been developed for obtaining the relations among confining stress, porosity and percolation rate for hydraulic sand backfills. The apparatus can also be used to evaluate internal drainage characteristics and the effects of partial saturation on percolation rates. The test apparatus, test procedures and typical test data are presented in this paper.IntroductionAlthough the standard percolation test has become an accepted method of evaluating the drainage characteristics of hydraulically placed tailings backfill, it is recognized that the test results require considerable interpretation due to the following factors: (I) The results can be markedly influenced by varying sample preparation procedures, which vary the amount of material segregation in the sample . In particular, a thin layer of slimes on the top of a sample can control the flow of water into the sample. Wall edge effects can also affect the test results. (2) The in-place porosity of the backfill is not duplicated in the test sample and empirical formulae must be used to estimate the variation of percolation rate with porosity. (3) Internal drainage characteristics and the percolation rate of partly saturated fill cannot be evaluated in the standard percolation test.In addition to eliminating these problems, the compression percolation test apparatus also provides additional data on the mechanical properties of the backfill. Compressibility (or bulk modulus) is measured at different stress levels during the course of a test and this information can be used in evaluating the usefulness of the fill in providing ground control and in limiting ground subsidence. The engineering design of mine backfill is becoming an important part of the over all design of underground mine operations. The design problems are sufficently different from conventional civil engineering soil mechanics problems that new test methods and design procedures are required."

Jan 1, 1981

By A. McLean, A. Hue, K. Le, Y. D. Yang, P. Wu

While the treatment of relatively inexpensive ferrosilicon alloys is a potential refining route in order to generate solar grade silicon, phosphorus is one of the more difficult impurities to remove by conventional processing. In this project, the use of an electromagnetic levitation technique was used to investigate the dephosphorization of ferrosilicon alloy droplets exposed for various times and temperatures to a hydrogen-argon gas mixture. It was found that approximately 40% of the phosphorus was removed from an 85%Si-15%Fe alloy after 20 minutes exposure at approximately 1673K, to a gas mixture containing 48.5% hydrogen. Further dephosphorization is expected with longer reaction times. The effect of increasing temperature was found to be insignificant, although processing at lower temperatures is not only economically advantageous, it also decreases evaporative silicon losses, thus resulting in a more efficient process.

Jan 1, 2015

By H. Wilton Clark

"IntroductionTHE CANADIAN use of short-period delay-action detonators in coal shooting has been carried on for about two years, mostly in British Columbia, and this is a preliminary report on progress to date. Entire coal faces are being shot successfully with one application of electric current.The electric blasting cap came into use about the beginning of the century. The low-tension electric cap, the type most commonly used, consists essentially of a metal tube containing an initiating explosive. Two wires lead into the end of the cap and are connected inside the cap with a short 'bridge wire .of very high resistance. This •bridge wire is buried in a match-head of a readily ignitable powder composition. When current goes through the lead wires, the bridge wire becomes extremely hot and sets• off the match-head which, in turn, ignites the powder just below it in the tube. This explosion sets off the main charge of explosive. Thus, by connecting a group of caps to a source of electric .current, a number of charges could be exploded simultaneously. This immediately became of great value to mine and quarry operators. Explosives could now be used to break up large masses of material at one time, as against the older, slow method .of blasting small amounts with single charges.The next step was to develop a delay detonator which would allow charges of explosive to fire one after the other, one or two seconds apart. Such detonators allowed first blasts to relieve some rock burden before the next charge fired, giving the second charge an easier task in forcing out more rock, and so on for the rest of the series of charges."

Jan 1, 1953