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In this paper, the use of electrochemical AC impedance spectroscopy (EIS) for in-situ diagnosis of high temperature PEM fuel cells is described. EIS was performed on single cell hardware, built in-house, using a fuel cell test station modified to operate up to 120°C and 30 psig. Electrode kinetics, membrane resistance, porous-layer and mass transport impedance of MEAs, assembled in-house, were measured at various current densities for the purpose of validating the test station and cell hardware, and for optimizing MEA and flow-field designs. The effect of temperature and humidity on the various impedances was investigated. Impedances obtained at lower and higher temperatures were compared to obtain insight into the issue of water management in operating fuel cells.

Jan 1, 2005

By R. W. Thompkins

The two largest contributors to silicosis in machine men are dust from drilling and dust from blasting. With the advent of the shatter-cut method of blasting, the evils of blasting dust were greatly reduced. The problem of dust from drilling has been attacked from two different angles: (1) The adoption of dustless frontheads or enlarged water tubes, both of which have proved capable of reducing dust concentrations; and (2) The adoption of better ventilation. Many operators are loath to adopt dustless frontheads or enlarged water tubes on Leyner drills because of the increased repair costs on drills, and also because it has been found difficult to enforce 'the proper usage of dustless machines: for example, workmen sometimes plug the vents in the fronthead.

Jan 1, 1943

Several inorganic reagents and organic polymers were tested as depressants in the single mineral flotation of ultrafine iron oxide and hydroxylapatite with Dowfroth 250 as a frother. It was observed that the inorganic reagents and the low molecular weight polymers generally caused dispersion of the ultrafine particles, and consequently their recovery into froth products more or less equaled the recovery of water. On the other hand, the high molecular weight polymers caused different degrees of flocculation of the ultrafine particles, and their recoveries were much lower than the recovery of water. These observations pointed to a need to re-define flotation depressants in fine particle flotation. The traditional definition of a flotation depressant, i.e., to make particle surfaces hydrophilic by forming a hydrophilic film and/or by removing collector and activator coatings, is sufficient for relatively coarse particles. However, to prevent fine and ultrafine particles from floating, a successful depressant should not only make the particles hydrophilic, but also enlarge the particle sizes so that they do not enter the froth product by mechanical entrainment. Polymeric depressants are ideal for these purposes. The different schemes to use polymeric depressants in the selective flotation of fine and ultrafine particles were discussed These schemes involve the integration of the polymeric depressants into other size enlargement processes such as shear flocculation, oil agglomeration, etc., for hydrophobic particles.

Jan 1, 2004

By Michael Harley, E. Guy Charleworth

"Bedding-parallel thrust-hosted gold veins are developed in the Sabie-Pilgrim's Rest goldfield, eastern Transvaal, South Africa. The reefs display a complex history characterized by temporally and spatially overlapping events of similar mineralization and deformation. Recognition of the episodic reactivation of these low angle (5° to 10°) thrust faults implicates high fluid pressures (equalling or exceeding lithostatic pressures). Geochemical constraints limit the amount of fluid-rock interaction and the occurrence of transgressive mineralization within the Archaean granitoid basement suggests that the high pressure fluids originated at depth beneath the Transvaal Basin.Similarities exist between gold deposits of Sabie-Pilgrim's Rest and Telfer, Western Australia as well as Passagem de Mariana, Minas Gerais, Brazil. All deposits are sub-parallel to the enclosing bedding which is shallowly inclined. Furthermore, they are also hosted by contractional deformational structures and are clearly epigenetic in origin."

Jan 1, 1994

By George Meadows

Consultation and Accommodation Introductions Consultation -Best Practices The Role of Negotiations The HVC Experience Summary / Conclusions The Challenge Meeting legal and policy obligations to consult while adhering to project priorities, timelines and budgets Defining who needs to be consulted, by whom, and ?how much?? Accommodation ?who is responsible and what is the appropriate scope? Social License -establishing positive working relationships with First Nations involved in project review / approvals / implementation in a manner that advances the interests of all parties

May 1, 2010

By E. Asselin

Electrochemical polarization experiments were conducted on alloy 625 in ammonia solution between 25 and 225°C and the results were compared with those of an oxygen solubility model. Results confirm that corrosion is under oxygen control, Normalized corrosion rates are determined based on the rate of oxygen diffusion to the corroding surface, and the corrosion rate at 200°C (-9.7 µA.cm-2) is roughly 24 times higher than the corrosion rate at 25°C (0.4 nA,cm-2), An oxygen-solubility model for Supercritical Water Oxidation (SCWO) conditions was generated using the Redlich¬Kwong-Soave (RKS) equation of state, Results of the model confirm many of the experimental observations from SCWO reactors which suggest that corrosion is at a maximum at temperatures just short of the critical point, The RKS/oxygen diffusion model predicts that the corrosion rate at 365° C is ?85 times higher than the corrosion rate at 25' C. Given that a normalized corrosion rate is obtained, this type of model could be useful for selection of SCWO reactor materials.

Jan 1, 2005

By R. H. Pemberton

"THE Mattagami district of Quebec has, during the past few years, experienced intense exploration by virtually every mining company operating in Canada. As a result of this activity, a number of well-mineralized zinc-copper bearing bodies have been found, some of which will almost certainly go into production. Much of the area has undergone what is now termed ""Saturation Prospecting"" or intense and detailed geological and geophysical surveying, followed by the drilling of nearly all possible bets. Considering only the airborne geophysical surveying, some blocks of ground have been flown by virtually every geophysical instrument which has to date been installed in an aircraft. A list of these different geophysical instruments would include: l. Fluxgate-type total field magnetometers 2. Vertical field magnetometer ,3. Nuclear-precession magnetometers 4. Single-frequency out-of-phase electromagnetometers 5. Dual-frequency out-of-phase electromagnetometers 6. Horizontal component measuring electromagnetometers 7. In-phase and out-of-phase electromagnetometers8. Dip-angle measuring electromagnetometers."

Jan 1, 1961

By S. J. van Rensburg

Competition for resources, including water and arable land, refocused attention on water and gold tailings management with respect to quantity and quality. MINTEK established and validated an "Advanced Leach Facility" to record kinetic leach information aimed at gold refractory sulphide ores. This facility was developed because of the need for additional leach process information to enable proactive decision making. Instead of focussing on optimised gold recovery only, the impacts of pre-oxidation methodologies were evaluated by considering key parameters, including cyanide speciation, reagent consumption, thiocyanate, arsenic, heavy metals, salt loads, water quality and residue stability. Results from oxidative leaching of a refractory gold ore employing oxygen, ozone, ultra-fine grinding, high shear and pressure oxidation are discussed. The relative cyanide and lime costs and environmental and sustainability effects associated with these technologies are briefly outlined.

Jan 1, 2011

By Walker. P. W. A.

Abstract -The Riviera tungsten occurrence in the Cape Province of South Africa was discovered in October 1979 as a result of stream-sediment panned concentrate sampling. The Cape age granite and late Precambrian Malmesbury Group carbonates and chlorite schists which it intrudes and which host the mineralization are covered by between 10 m and 30 m of Tertiary/Recent alluvium and clay. The scheelite/powellite and molybdenite mineralization occurs in a greisenized granite cupola with an overprint of porphyry-type alteration as well as in minor skarns. The ore reserve is estimated to be 46 million tonnes at an average grade of 0.2160Jo W03 and 0.020% Mo. The deposit is uneconomic at current tungsten prices.

Jan 1, 1994

By G. Morin, G. Marin, M. C. Parr, J. Carignan

"Investment casting offers many advantages for the near net shape production of complex geometries, however, molten titanium reacts with most of the refractories used in investment casting shelling systems, which leads to the formation of an oxygen contaminated surface layer. This layer, called alpha case, is 0.1 to 0.6 millimeters in thickness according to the casting section size and must be removed either by mechanical or chemical milling processes. Alpha case removal processes affect casting tolerances and may contaminate the part intended for medical applications (e.g. embedding of abrasive grit media in the alloy). A shelling system based on an yttria prime slurry has been developed and was found to almost suppress the mold metal reaction. Yttria is an expensive refractory, but slurry life was found acceptable for small castings using a closed container and flow coating process instead of conventional pattern dipping. Alpha case depth has been determined for Ti6Al4V by metallographic techniques and microhardness measurements on different step block casting cross sections. Alumina and yttria second prime stuccos were evaluated in this study. The shelling system minimizes finishing operations in the production of casting for medical applications.INTRODUCTIONTitanium investment castings have been in the commercial market since the beginning of the titanium era in the mid 50’s. Investment casting is a cost effective way to produce complex parts for medical, aerospace and chemical processes applications. Investment casting of titanium is difficult due to the high reactivity of titanium with air and refractories used for shell mold building especially for the face coat. Melting is done under vacuum and no shelling system has been proven effective to suppress the mold-metal reaction yet. The main issue with the mold-metal reaction is the formation of an oxygen enriched zone at the surface of the castings named alpha case (Frueh et al., 1997; Kim, 2002; Saha, 1986). The alpha case is brittle, reduce the fatigue life in service of the parts and must be removed by chemical milling.For industrial purposes, calcia partially stabilized zirconia based slurries have become widely used in titanium investment casting for primary coats due to a combination of limited metal shell reaction. Calcia stabilized zirconia slurries have an acceptable shelf life and offer an interesting production window. Our experience shows that a resulting alpha case depth is 280 micrometers for a casting section of 6.35 mm in thickness is typical with such a shelling system (Morin, 2013)."

Jan 1, 2016

By M. Pawlik, E. Arinaitwe, V. Ferrera

A series of flocculation tests were performed on dilute quartz suspensions with the use of five polyacrylamide-based flocculants of similar molecular weights but of different degrees of anionicity. The tests were performed as a function of ionic strength and pH. The macromolecular conformation of flocculants in solution was assessed through intrinsic viscosity measurements under the same physicochemical conditions as those of the flocculation tests. It was generally found that the flocculating efficiency of the polyacrylamides correlated with their ability to coil or stretch in solution. Polyacrylamides with the degrees of anionicity on the order of 10-18% showed the highest flocculating efficiency in terms of the settling rates of the flocculated solids and the residual turbidity of the resulting supernatant. At the same time, these most effective flocculants were also found to exhibit the greatest tendency to coil and stretch in solution. This result suggests that the flocculating power of a flocculant is determined not only by its ability to adsorb onto (and bridge) fine particles but also on its ability to conform to the size of the resulting floes.

Jan 1, 2009

By Dennis Hoffmann

"Abstract - Banded iron formation rocks associated with massive sulfide lenses in the Broken Hill Pb-Zn-Cu-Ag deposit in the Namaqualand Metamorphic Complex, South Africa , were investigated with respect to the geochemistry of manganiferous silicate-rich bands. Two common varieties of these are: amphibole- and garnet-rich iron formation bands. The results reveal that the former are enriched in Fe, Mg, Cu, Co and S. The garnet-rich bands are enriched in Mn, Ca, P, Pb and Ba with significant detrital contamination of Ti, Al, Zr, Cr, Y, V, Ni and Nd.The silicate-rich bands have compositions, in terms of, Si/Al, Si/Fe, Fe/Mn, La/Ce and Co/Zn, comparable to submarine chemical sediments which precipitated from hydrothermal fluids. The garnet­ and amphibole-rich bands are interpreted as ""evolved"" and ""immature"" hydrothermal sediments, respectively. The latter resulted from rapid precipitation after exhalation, whereas the former had a longer residence within sea water. The silicate-rich bands both exhibit increasing Mn/(Mn+ Fe) fractions, which are consistent with a variation expected from proximal to distal depositional settings. The prevalence of garnet-rich bands over amphibole-rich bands is interpreted as the result of injection of hydrothermal fluids from a single vent situated along the northwest margin of the Broken Hill deposit."

Jan 1, 1994

By Tuula Mäkinen, Lauri Pesonen, Peter Björklund, Jouni Pihlasalo, Mikko Korpi

Outotec Direct Blister Flash Smelting technology has proved to be an efficient and environmentally friendly way to treat copper concentrates from the Zambian Copperbelt at Konkola Copper Mines' (KCM) Nchanga smelter in Zambia. The modeling of slag chemistry and thermodynamics with MTDATA software played a central role in deciding the operation parameters for the smelter. Outotec FSF Online Process Advisor is used to calculate the process parameters and to give valuable information of the process state for the operating personnel. The pre-calculated slag liquidus graphs are also integrated to the Online Advisor.

Jan 1, 2011

By D. D. Liu

This paper proposes a charge induction dust measurement method based on detrended fluctuation analysis (DFA) for use in coal mine environments, based upon electrostatic interference, dust properties, wind speed, particle size, moisture content and other factors. In this methods, sequence x(t) is first obtained through a dust concentration sensing probe, and then the cumulative deviation y(t) is calculated, and y(t) is divided into same lengths. Secondly, a first-order linear fit is used for data of each interval, and mean-square deviation filtered DFA was calculated for each interval. Finally, the dust mass concentration of the corresponding time is obtain by supplemented calibration coefficient and fitted the data point which is the mean and square root for all lengths of interval. Simulation and verification experiments showed that the charge induction dust measurement method based on DFA can reduce coal mine electrostatic interference effects with high accuracy. The design has been successfully applied to select areas.

Aug 1, 2013

By K. J. Palmer, D. A. Silva

"Evaluating resources and reserves requires the reliable modelling of geological domains and their grades. “Multiple point statistics” simulation is a relatively new geostatistical method to generate complex, high-resolution geological models by extracting high-order spatial relations from training images. A method based on combining multiple training images is developed to obtain the correct amount of large-scale continuity and short-scale variability. A calibration process matches the geological spatial variability between the final realizations and the drillhole dataset. A case study with data from the Red Dog mine, Alaska, United States, shows an appropriate reproduction of short-scale variability along boundaries between geological units.RÉSUMÉ L’évaluation des ressources et des réserves exige une modélisation fiable des domaines géologiques et de leur teneur. La simulation par « statistique multipoint » est une méthode géostatistique relativement nouvelle pour générer des modèles géologiques complexes à haute résolution par l’extraction de relations spatiales d’ordre supérieur à partir d’images d’entraînement. Une méthode basée sur la combinaison de multiples images d’entraînement est développée afin d’obtenir la bonne quantité de continuité à grande échelle et de variabilité à petite échelle. Un processus d’étalonnage fait correspondre la variabilité géologique spatiale entre les réalisations finales et l’ensemble des données de forage. Une étude de cas avec des données de la mine Red Dog, Alaska, États-Unis, montre une reproduction adéquate de la variabilité à petite échelle le long des limites entre les unités géologiques."

Jan 1, 2015

By Denis Yaychuk, Gary Billingsley

The economic eva luation of a mineral property or mining venture should include the quantification of ri k as part of the analy is. The re ults of such an analysis provide the decision-makers not only with the most likely financial outcome and the probability of achieving that or any other outcome. but al o with a ranki ng of the relative impact of all the ri sk factors. These type of resu lts offer more complete information for investment and technical deci ions than the traditional cash flow/ ensitivity analysis. In addi tion. by attempting to quantify ri sk. the personnel providing the va ri able input are forced to take a much clo e r look at the data involved, and are fo rced to work together. the reby increa ing substantially the awa reness of the impact their work and others· work has on th e outcome of the analysis.

Jan 1, 1986

By A. McLean, L. Gao, Z. Shi, Y. D. Yang, K. Chattopadhyay, G. F. Zhang

Levitation melting of metals is one of the emerging applications of magnetic and electric fields in liquid metal refining. The varying magnetic field generates induced current inside the metal droplet and leads to the Joule heating effect and Lorentz force against gravity. This contactless process can avoid contamination from the crucible and can be used to produce high-purity materials. Visualization of the levitation melting process is difficult, and thus generally investigated by mathematical modeling. In the present study, a three-dimensional mathematical model of metal levitation was developed using finite element method for proper understanding of the levitation process. The effects of harmonic magnetic field frequency, coils power input, and sample size on levitation nickel droplet were investigated. Temporal evolution of temperature fields were predicted directly though the model. Levitation and balance condition of the droplet were investigated as well.

Jan 1, 2015

By E. Goodwin

The mechanics of formation of wear-metal suspensions in lubricants is discussed, along with the relationship of the concentration of the metals and other particles to the wear of lubricated machinery parts. The importance of particle and suspension analysis of used lubricants in a preventative maintenance program is stressed, in particular with regard to mobile equipment in a mining operation.

Jan 1, 1978

By Simon C. Dominy, Ian M. Platten, Garry F. Johansen, Alwyn E. Annels, Brian W. Cuffley

Abstract - Coarse gold-bearing veins are characterized by high grades that are localized and erratic. Effective sampling of coarse gold-bearing veins is difficult because of the low concentration and erratic nature of the gold particles. Diamond drilling is an effective measure of geological continuity, however, grade distribution can only be reliably obtained from underground development (including close-spaced sampling, bulk sampling, and trial mining). Comparison between surface and underground drilling, underground linear/panel and bulk sampling indicate that drilling and linear/ panel samples generally understate bulk sample grades. Bulk samples are likely to be the closest estimators of true grade. It is unlikely that anything above an Inferred Resource category can be estimated from surface drilling alone, and at best the grade will only be a global estimate. Underground development, in-fill drilling and bulk sampling/trial mining will be required to delineate Indicated and Measured Resources. Closely spaced development and bulk sampling is likely to be the only way to determine Reserves. The resource estimation process must driven by a clear geological model that should attempt to understand both geological and grade continuity. Traditionally, grade interpolation has been undertaken using classical methods, though more recently, computer-based block modelling techniques have been used with some success. Three case histories are presented, documenting the problems of estimating resources in coarse gold-bearing veins and the practical ways in which they were approached.

Jan 1, 2000

By C. M. Campbell

IN 1902, a famous Canadian geologist made the following statement : ?'From what we know row of the iron-ore fields of the Province, we may feel that Ontario is assured of a great future as an iron-ore producing country. Judging from the extent of the territory over which the newly discovered ranges have been found, Ontario should in the not far distant future take her place as one of the chief iron producers in the world". In 1905, an official of the Department of Mines said: "In ten years Canada will have b:ecome a great metallurgical country. You will see an iron industry in this Dominion larger than in any country in the world. Canada will yet furnish the world with its iron supply. It will be the same with iron as with wheat. A decade from now Canada will outstrip all other countries in wheat growing. The production of iron at a cheaper rate than it can be made elsewhere will cause Canada to take a similar position as far as iron is concerned". In 1924, a former President of the Institute, in arguing his claim for inconceivable mineral wealth in this country, stated as a "certainty" that iron-ore deposits on the scale of the ones in Minnesota would be found "again and again" in the Canadian Precambrian. In 1930, a Minister of Mines announced that "The country surrounding Churchill holds large deposits of valuable iron and coal", and he stated that, at that place, 'We will have an industry in iron that will compare with Pittsburgh". These statements are definite promises, just as definite and important as the statement "I promise to pay" on a note, and they are not fulfilled by casually stating, as is the habit, that someday we will work our low-grade iron ores. Nor are they fulfilled by stating, as is often done, "Oh, So-and-So did not mean that ' . Due to their importance and to the prominent positions held by the men who made these statements, they were widely circulated throughout Canada. They were taken at their face value, and on the strength of them and many more of the same kind in regard to our other resources we have planned and built, at huge expense, provinces, governments, civil services, railways, and other equipment. The reserves that were to justify these expenditures have not appeared. There has not been a ton of iron ore mined in Canada for many years, and important commercial reserves are unknown. We have built the mill, but adequate ore is lacking.

Jan 1, 1937