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By A. Hashempour, D. Javani

"Selection of an optimal bit is a critical issue in drilling engineering. Specific energy (SE) and Cost per Foot (CPF) are the most common methods for evaluation of bit efficiency and optimal bit selection. The major shortfall of both methods is that they do not directly account for geological and geomechanical parameters of formations being drilling. In this paper, results of using the two foregoing methods are compared using Formation Drillability (FD) method, which directly accounts for geological and geomechanical parameters of a formation. This method combines various geological and geomechanical parameters and yields a dimensionless parameter indicating the formation drilling hardness (drillability). Results of this study show that the amount of energy, cost and time spent for drilling a unit volume / length of an identical formation may vary in different wells. This is due to the fact that geological and geomechanical characteristics of a formation may vary among wells and even within short intervals of a single well. Therefore, an optimal bit may not be appropriately selected, if drilling and economical parameters are the only factors considered and the formation geological and geomechanical specifications are ignored.INTRODUCTIONMany authors such as Bilgesu, Al-Rashidi, Aminian, and Ameri (2000) and Clegg (2006) conducted research in the evaluation of bit performance and optimum bit selection. Almost all of them tried to establish a good relationship based on geomechanical parameters. Primary examples are the research done by Ubaldi (1999), Macini, Magagni, Da Dalt, and Valente (2007)."

Jan 1, 2015

By Rayleen Riske

Why do we look for better reconciliation when times get tough? Why wait? Mine reconciliation should be a priority throughout the good times too. In fact, with good reconciliation, those good times are going to be even better and will help pave the way to success through those preventable bad times. Reconciliation throughout the entire mining value chain requires the capture, validation, and analysis of copious amounts of data. This task can be daunting for a team in a small mine, let alone reconciling across a suite of large mines. This paper will outline the different ways we can reconcile across the value chain, why we should reconcile over differing periods of time and how Snowden?s solution to proving reconciliation can be a simpler, reliable and transparent process. Snowden?s Reconcilor is proving to be a valuable tool on any mining scale, by capturing, validating, sorting and reporting data for timely decision making by the site geologist through to corporate management. By instigating vigorous reconciliation, you are setting your mine up for the future. Not only will you have the means to analyse your current processes and measures, but you will have the opportunity to identify and improve your mine?s performance from the resource model through to the final product.

May 1, 2010

By S. Qian

Galvanic corrosion is a potentially major concern associated with the application of stainless steel reinforcement which is in direct (electrical) contact with carbon steel reinforcement in concrete structures. Judicious use of stainless steel rebar in both new construction and rehabilitation of older structures is a viable, cost-effective option for extending service life and reducing maintenance costs. Questions, however, had arisen about the possibility of increased corrosion due to galvanic effects. This paper investigates the galvanic-coupling behaviours of three different types of stainless steel and carbon steel. Tests were performed both in electrochemical cells and with specimens in concrete inside an environmental chamber. The results show that oxygen reduction on stainless steel is the rate-determining factor for galvanic coupling of these two metals. It is much lower than that of passive carbon steel. As a result, the galvanic coupling of stainless steel with carbon steel will not increase the risk of corrosion of carbon steel reinforcement.

Jan 1, 2005

By Cesar H. Oboni

The development of specific risk-based methodologies to guide and prioritize clearing decisions in countries contaminated by Unexploded Ordnance and Land Mines (generically defined as Explosive Remnants of War: ERW) either at country-wide scale or road-network-scale was used in an unexpected way when a large mining company asked Riskope (www.riskope.com) to develop a multi-modal transportation network risk assessment plan, which included ocean going vessels, ports, wharves, railroad, trucking and other modes of transportation. What had been a first-in-the-world attempt in the humanitarian landmine clearing industry turned out to be extremely useful and equally innovative in the extractive corporate world. Instead of a country contaminated by man-made hazards such as Explosive Remnants of War (ERW) we were now dealing with a very complex multi-modal transportation system afflicted by all sorts of potential hazards from quakes to climate change, sabotage to labour strikes, and vulnerable infrastructures to potential energy crises. Interestingly enough the method developed to deal with ERW risk based clearing was also capable of solving the transportation risk evaluation problem, after necessary customization. This paper shows how ?out of the box? thinking and industry cross dissemination can bring significant evolution and a competitive edge even to unexpected areas of the world-wide mining industry. The results of the logistic system risk assessment shed new light on the management of the system, changed the way insurance coverage was purchased, and led to significant potential cost reductions in a period of global recession.

May 1, 2010

By M. I. Kalashnikova, Y. M. Shneerson, E. E. Zhmarin, Y. V. Degtiarev, E. M. Vigdorchik

Separation of a magnetic fraction from nickel concentrate following matte flotation, and its treatment in a separate circuit enable reduces precious metals losses. The magnetic fraction is treated in two stages of oxidative leaching: atmospheric and pressure leaching. A study of the atmospheric stage, using mathematical modelling, is described in this paper. The mathematical model and experimental data were used to carry out industrial process calculations. The model enabled extrapolation of the results of batch laboratory test to industrial-scale continuous processing and the selection of optimal process conditions and large-scale equipment. In December 2004, commercial oxidative leaching tests were performed on the magnetic fraction at the Severonickel Plant (Monchegorsk, Russia). A comparative analysis of the mathematical modelling results and the actual process parameters is presented.

Jan 1, 2005

By Yasser Mohamed

Daily field management of earthmoving operations requires quick and regular decisions for allocating available equipment to different jobs on a project. A general foreman?s day starts with matching several activities with a suitable set of available equipment to achieve the highest productivity and lowest unit cost. Usually, this decision-making process needs to be quick, and depends to a great extent on the foreman?s experience, which varies from one individual to another. Many analytical solutions with various degrees of sophistication and optimization exist to address such decisions. However, adopting any of these solutions is contingent on how accessible and easy-to-use the solution is. This paper discusses the development process of a webaccessible solution for evaluating earthmoving fleet composition and allocation scenarios. The solution relies on discrete event simulation and an optimization backend engine, but introduces the user with a simplified and easy-to-use interface that is accessible from any mobile device, and is customized to specific user?s needs. The developed system gathers most equipment and site-related input data from a company?s information systems to minimize user input. The user mainly needs to formulate equipment and job combinations and allocation scenarios (e.g. soil type, quantity, and hauling distance), according to equipment availability each day. Then the system will evaluate the productivity and unit cost estimates for each scenario, allowing the user to choose the most suitable one. It may also be used to automatically recommend the optimum solution given an available list of equipment. The paper presents the process followed in prototyping the proposed system in collaboration with a major Canadian earthmoving contractor, and customizing it to the user needs within the company. It also describes the overall structure of the developed system and its core simulation model.

Aug 1, 2013

By K. S. Raja, B. McNall, B. Pesic

"High-level radioactive wastes are stored in large underground storage tanks made of low-carbon steel. The wastes consist of concentrated solutions of sodium nitrate (NaNO3) and sodium hydroxide (NaOH), and the radionuclides 137Cs, 99Tc, and 90Sr. The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV), which in turn modifies the kinetics of corrosion of the storage tank. To understand the influence of technetate ions on the corrosion of steel, electrochemical polarization studies of A 537 steel samples were carried out in 1 M NaNO3 + 0 .05 M S r(NO3)2 + 0.1 M NaOH with and without addition of HReO4 at different temperatures (24 – 85 °C). The concentration of HReO4 was varied from 0.014 – 0.04 M.INTRODUCTIONAqueous processing of spent nuclear materials generates a large amount of high-level radioactive wastes. The wastes are primarily salt solutions of sodium hydroxide and sodium nitrate which also contain fission products such as 137Cs, 99Tc, and 90Sr. Among the high level radioactive fission products, Tc-99 is of great importance because of its high concentration, long half-life (2.1 x 105 years), high solubility in geologic waters as technetate, and rapid diffusivity through the geologic systems. The solubility of technetate ions varies depending on the oxidizing conditions prevailing in the storage containers. High level radioactive wastes are stored in single shell or double shell tanks made of low carbon steels such as ASTM type A15, A516-70 and A537. Most of the available literature on corrosion of steel in simulated radio active waste environments pertains to nitrate induced stress corrosion cracking (Subramanian & Mickalonis, 2005). The corroding steel microenvironment may produce localized reducing or oxidizing conditions that affect the solubilities of the species such as Tc(VII) and Tc(IV). Corrosion of steel and formation of Fe(II) and Fe(III) will affect adsorption and reduction of Tc species. The radioactive species can irreversibly be sorbed on the steel surface by oxidation of Fe(II) to more stable Fe(III) and fixed as less soluble Tc(IV)/Fe(III). The solubility of Tc species is also affected by other factors such as dissolved oxygen, local pH, temperature etc. How the corrosion behavior of steel will be affected in the presence of Tc species is not clearly understood.Cartledge (Cartledge, 1960) demonstrated that passivation of iron can be achieved in the presence of oxygen along with suitable inhibitor ions/molecules of the general formula XO4 n-, such as pertechnetate (TcO4 -). The pertechnetate ion is univalent. Since it is derived from a strong acid, no buffering action can be expected from this ion. The redox potential of the reaction (1) is 0.738 VSHE (Pourbaix, 1974)."

Jan 1, 2012

By Rodney R. Koch

The phys ica l properties of gold should faci li tate its detection. However, the average concentration of gold in the ea rth's cru st precl udes the ability of geophys ical methods to detect the metal directly. In order to effectively pursue geophys ical detection and location of gold mineralization there must also be geological input - i.e. a model. This will lead to the selection of the appropriate geophy ical techn ique(s) in the fo llow-up programs. Interpretation of the fie ld survey data is of con iderable importance in expl oration geophys ics. Analytical techniques such as cont inuation, fi ltering, and spectral analys is, are now routinely empl oyed in the analys is of survey data to aid the interpretation process. The uccessful application of geophysical methods and the use processing techniques is demonstrated by two recent Saskatchewan discoveries. The first, the Star Lake 21 Zone, with reserves of 230,000 tons grading bener than 17.14 git Au associated with a disseminated sulphide quartz-bearing shear zone yielded geophysical anomalies that were distinctive, obvious, and would have lead directly to its discovery. The econd , the Laurel Lake Prospect, with ore grade intersections of 28.0I git Au and 52 .46 git Ag· over 5.49 m, resulted in numerous geophysical anomalies. However, none of these anomalies demonstrated association with the mineralization until processed results indicated that structural features crosscuning regional trends were important cont rol mechanisms for the mineral ization.

Jan 1, 1986

By J. Desrosiers

"Minnova Inc. has five operating divisions thoughout Canada. One of them is Lac Dufault which was established in 1964.Lac Dufault is located 15 km north of Rouyn-Noranda, in what is known as Noranda volcanic centre, in northwestern Quebec. For more than 25 years, Lac Dufault has produced copper, zinc, gold and silver from four different mines: Norbec, Millenbach, Corbet and now Ansil.Ansil, officially in production since July 1989, is one of the deepest mines presently in production in Quebec. This high-grade copper, gold, zinc and silver orebody is being mined at a rate of 1200 tonnes per day with a total workforce of 200 employees.Of particular interest are the high mechanization level of the underground mine, technical innovations also underground, and computer applications throughout the division.IntroductionMinnova Inc. was formerly known as Corporation Falconbridge Copper until 50% of its shares were bought by Kerr Addison Mines Ltd . in 1986 and it became a member of Noranda Group of Companies.Minnova stands for mining innovation. It means Minnovaaims to use state-of-the-art technologies in mining and exploration to achieve maximum efficiency and cost effectiveness. It also means that they aim to use both proven and innovative management principles to the optimum benefit of their employees and shareholders. Minnova has operations across Canada. Presently four mining divisions produce copper, zinc, gold, silver and lead. Two are situated in Quebec: Lac Dufault (established in 1964) and Lac Shortt (established in 1985); one in Ontario; Winston Lake (established in 1988); and one in British Columbia; Samatosum (established in 1989).Minnova has an annual exploration budget of $15 million divided 60/40 between base metals and precious metals. Most of Minnova's exploration efforts are concentrated around their existing mines. Exploration is carried out from six regional offices located at Rouyn-Noranda and Chapais in Quebec; Thunder Bay in Ontario, Vancouver in British Columbia, Reno, Nevada in the United State and Panama City Panama. Each of the Canadian offices maintains close liaison with nearby operations.Lac Dufault Division is located in the Noranda mining camp, approximately 15 km north of the city of Rouyn-Noranda, in northwestern Quebec (Fig . 1)."

Jan 1, 1991

By Magella Pelletier

"IntroductionDepuis une vingtaine d'année, les nombreux travaux de géochimie effectués par l'industrie privée et les milieux gouvemementaux ont permis:• de découvrir de nombreuses zones minéralisées a valeur économique;• d'identifier et de vérifier certains patrons de dispersion géochimique au-dessu s de secteurs minéralises déjà connus;• de favoriser le développernent des techniques analytiques;• de forcer le développement d'une mise en carte des résultats d'analyse, qui soit plus adéquat afin de permettre une meilleure interprétation géochimique.L'une de ces cartes géochimiques qui permet le mieux de mettre en valeur les données analytiques et qui fut instaurée au debut des années 80, est la carte d'interprétation géochimique par pondération.Cette carte numérique semi-quantitative, qui est construite à partir des données de base et de l'importance des éléments indicateurs pour une substance donnée, permet d'identifier et de définir des zones possédants de fortes probabilités pour la recherché de sources minéralisées."

Jan 1, 1987

By Joo Hyun Park, Hyun-Sik Park

"Gold is one of the most valuable and precious metals. But, the extraction efficiency of gold from natural resources is very low and labor-intensive due to very low concentration of gold, i.e.,1–5 ppm, which means that gold extraction processes produce extensive amounts of tailings. The gold content in printed circuit boards (PCB) from waste mobile phones is about 100 to 400 ppm, which is enormously greater than the concentration found in natural ores. Consequently, processes for recycling waste PCB and gold mine tailings become of increasing importance to maintain a sustainable society. As processing these waste materials by pyrometallurgical methods has become more economically attractive, understanding the thermodynamic behavior of gold in smelting slags under oxidizing and reducing conditions has become increasingly important. Therefore, in this study, the effects of slag chemistry, oxygen potential and temperature on gold solubility in smelting slags are discussed. From the results presented, the predominant species of gold is strongly dependent on the basicity of slag. Furthermore, more basic slags showed higher solubility of gold at a given oxygen partial pressure, and more oxidizing atmospheres enhanced the dissolution of gold to the molten slag phase. As a consequence, careful control of the slag composition during pyro-processing of gold-containing waste materials is required to maximize gold recovery. INTRODUCTIONGold has good physicochemical properties. Thus, it plays an increasingly important role in industrial applications. For example, over 300 tons of gold are used annually in electronic components (Hageluken &Corti, 2010).However, 75% of all gold ever produced has been extracted since 1910 and gold reserves in the world are becoming rapidly depleted (Louis & Pluchery, 2012).The cost of gold production and its price in the market have increased rapidly during last 20 years as shown in Figure 1, and interest in the recycling of gold-containing materials has naturally increased.The wastes from electronic equipment (e-wastes) contain large amounts of precious metals compared to their own respective ores, and therefore such wastes may be considered as a secondary source of valuable metals. For instance, the concentration of gold in natural ore is commonly 0.5–15 g/ton-ore (0.5–15 ppm), while its concentration in electronic circuit boards is over 10 times higher, typically being about 150 ppm in expansion cards and over 10,000 ppm in central processing units(Barbieri et al., 2010).Also, gold mine tailings are discharged after the flotation process as slurry form then stored near the operating plants (approx. 100 ton per day in one Korean gold mine). Gold mine tailings contain gold at about 1–2 g/ton. This is the reason why Au-containing materials such as e-wastes and mining wastes are highly important sources of gold (Yamasue et al., 2009)."

Jan 1, 2017

By K. Torigoe, S. Owad, C. Tokoro, Y Tsunazawa

The mechanism of an abrasion process to recover metal values by removing components from printed circuit boards (PCBs) is modeled using a discrete element method (DEM) simulation. To simulate the abrasion process, a model PCB geometry was constructed consisting of bonded particulates. The simulation allowed connections between particles to be broken if the bonding force calculated from DEM exceeded a threshold level. Simulation results were compared with experimental comminution data using an agitation mill with test PCBs on which nine capacitors were surface solder-mounted. Simulation results obtained from the DEM with the anchoring model corresponded to experimental observations.

Jan 1, 2011

By Phil Keele

"Manalta Coal Ltd. 's Vesta Mine will supply Alberta Power Limited's 740 MW Battle River Generating Station with 1 128 000 tonnes of sub-bituminous ""C"" coal in 1983. Mana/ta Coal Ltd. and Alberta Power Limited are in their seventh year of a 31-year coal supply agreement. With the exception of localized topographic highs where three coal seams are mined, the Vesta Mine is primarily a single-seam mining operation. Vesta's comprehensive programs of mine planning, preventative maintenance, reclamation, and employee relations make it an efficient and a well run operation. Introduction The Vesta Mine, located in east-central Alberta approximately 300 km northeast of Calgary, supplies sub-bituminous ""C"" coal to Alberta Power Limited's 740 MW Battle River Generating Station. The coal reserves and principal stripping equipment are owned by Alberta Power Limited. Manalta Coal Ltd. owns and operates the additional mining equipment and support facilities. Coal production is from a single pit, 3.5 km in length. Both single and multi-seam operations are encountered in the active pit. In 1983, production is anticipated to increase to I 128 000 tonnes from 906 000 tonnes in 1982. The additional tonnage will be achieved by operating 24 hours per day, 5 days per week. The following sections briefly highlight historical, geological and mining/reclamation aspects of the Vesta Mine. Figure I illustrates the location of the Vesta Mine in relation to the cities of Calgary and Edmonton. History Coal mining for domestic use began near the turn of the century in the Vesta Mine area. Initially, small underground room-and-pillar operations were dominant. As equipment technology advanced, surface strip mining replaced the underground methods."

Jan 1, 1985

Proper water and thermal management is essential for obtaining high performance of Proton Exchange Membrane Fuel Cells (PEMFCs). A steady, two-dimensional water and thermal management model was developed, aiming at considering pressure drop, open circuit voltage variation with stack temperature, water vapor effects on membrane conductivity, which made the model physically more reasonable and more suitable for various operating conditions. The model could predict the distributions of a series of important parameters along the flow channel, and thus the effects of various operating and design parameters on the fuel cell performance could be investigated easily by numerical trial-and-error method. The modeling results compared well with the available experimental results from the literatures. The results also showed that the humidification is crucial for the performance of PEMFCs. The model could be a very useful engineering tool for the optimization of PEMFCs.

Jan 1, 2005

By Michael McClintock, Bern Klein

"The high pressure grinding roll (HPGR) is a relatively new comminution technology that is gaining popularity for providing energy efficient solution to hard rock mining operations. A significant barrier to increased adoption of HPGRs is the present requirement for large amounts (excess of 2 tonnes) of sample for pilot testing, which may not be possible for most early stage projects. Three methodologies have been developed at NBK Institute of Mining Engineering at the University of British Columbia that may be used for sizing design optimization of HPGR circuits. All three methodologies use a MTS pistonpress to simulate HPGR comminution. These tests are capable of providing information regarding energy consumption, energy breakage relationship, reduction ratio, and product size distributions. In a period of slow economic development, these methodologies are critical to allow the industry to cost effectively understand the operational benefits of HPGR implementation. This paper examines previous test work done at UBC, as well as the development of an HPGR and piston press database for use in sizing and budgeting of HPGR circuits.INTRODUCTIONCurrently, the mining industry faces several challenges due to falling commodity prices and escalating costs. This has applied pressure for operations and projects to reduce costs and improve project economics. In addition engineering and metallurgical budgets have shrunk as companies try to conserve cash. Improvements and optimization of milling and comminution circuits is one area project economics may be significantly improved. By considering alternative comminution technologies such as the high pressure grinding roll (HPGR), energy operating costs may be greatly lowered. Many have begun to implement HPGR crushing as an alternative to semi-autogenous grinding (SAG) mills, including KGHM and, Sierra Gorda, and Freeport Mc-MoRan’s Cerro Verde operation. However, implementing new technology for companies with little or no HPGR experience may not be practical. An operator must consider both feasibility and economics of a circuit. Currently, consideration of the HPGR requires expensive pilot scale testing for which large sample sizes are needed. In addition, few laboratories are equipped for running pilot scale HPGR test programs. Furthermore, the results of pilot HPGR testing are dependent on the quality of the sample, which cannot represent variations across a deposit. In contrast, ball mills and SAG mills can be sized using the Bond Mill Work Indexes that require a small amount of sample which enable a number of different geological blocks to be tested to allow engineers to have a complete understanding of how the comminution circuit will perform for the life of mine."

Jan 1, 2016

By D. Bronkhorst, J. Rheault

"Backfill practices at the Williams mine have evolved significantly since underground mining began in 1986. The use of conveyors as a means of transporting fill material to stopes has been discontinued in favour of load-haul-dump equipment. The method of adding binder to the fill product has been refined along with the placement technique. Slurry preparation has been fully automated and flyash is now included as a binding agent. Surface preparation of the fill product has evolved substantially with the quarry operation coming into full operation and the construction of pennanent crushing, screening, and storage facilities. Company personnel have replaced all contracted labour involved in backfill operations. Some changes have been made to achieve a higher standard of quality control while others were implemented as a matter of cost reduction. BackgroundThe Williams mine is one of three mines operating at the Hernlo gold deposit, located 40 km east of Marathon, Ontario, along the north shore of Lake Superior. Daily production at the mine is 6000 Ud yielding an annual gold production of approximately 500 000 oz. The orebody extends from surface to a depth of 1300 m dipping north at 70 degrees. The average orebody width is 25 m, but varies from 45 m on the eastern boundary to about 10 m at the western probable limit and at depth. Proven and probable reserves currently stand at 32 million tonnes grading 6 g/t.The Williams orebody has been divided into four separate mining zones: the A-zone, the West-of-Dyke zone, the B-zone, and the C-zone (Fig 1). Ore production originally was from the A-zone open pit operation while the A-zone and B-zone underground workings were being developed. The mining method employed underground is blasthole open stoping with delayed rockfill. Mining block dimensions are nominally 20 m along strike by 25 m high. Stope extraction is sequenced to achieve a relatively short pillar life and 100010 ore recovery. Pillars are extracted as soon as the adjacent primary stopes are two cycles ahead. Primary stopes are filled with consolidated rock fill after mining. This allows pillars to be blasted right against the consolidated fill, but also requires that the fill be self supporting to a height of 30 m.The Williams mine places approximately 1.4 million tonnes of rockfill and 50 000 tonnes of binding agents each year, with about three quarters of the fill placed being consolidated. The consolidated fill placed at the Williams mine contains Portland cement and flyash as binding agents."

Jan 1, 1994

By Habib Zughbi, Paul Zulli

"A key step towards sustainability in iron and steelmaking is to optimise the use of raw materials and energy consumption, and consequently minimise CO2 emissions. Models based on a Process Integration (PI) approach play a key role in evaluating various scenarios and the impact of introducing changes in raw materials and operational conditions on the overall energy consumption and CO2 emissions. BlueScope uses a PI based comprehensive model for its Port Kembla Steelworks (PKSW), called the Integrated Steelworks Energy and Emissions Model (ISEEM). ISEEM is tightly coupled to the configuration of PKSW. It is based on mass and energy balances as well as thermodynamic relationships. ISEEM is a steady-state model and is used to predict overall and detailed unit-by-unit energy consumptions and CO2 emissions. It is also used for plant-based scenario modelling. This paper investigates the impact of major changes to PKSW configuration, including the shutting down of a blast furnace and cokemaking battery, on the energy consumption and CO2 emissions of the plant. It discusses some of the issues involved in updating the model and some identified opportunities."

Jan 1, 2015

By K. Forsberg, A. Rasmuson, R. Rodriguez Varela, J. Martinez De La Cruz

"This study analyzes the separation of rare earth elements by means of a supported liquid membrane (SLM) with the final objective of recovering REE from an apatite concentrate (Alemrajabi, Forsberg, & Rasmuson, 2015; Mohammadi, Forsberg, Martinez de la Cruz, & Rasmuson, 2015). In this study, the feed phase consists of an aqueous phase containing REE, the membrane phase contains the organic solvent and carrier (D2EHPA and EHEHPA), and the stripping phase is a hydrochloric acid solution. An evaluation of mass fluxes, separation efficiency, and membrane performance is conducted. In order to analyze the suitability of liquid membranes in the extraction of REE, a deeper insight into the mechanisms causing instability is needed. In this study, surface tension is considered as the key factor of Marangoni instabilities and spontaneous emulsification.INTRODUCTIONThe demand of REE and their compounds has increased considerably due to their special physicochemical features that make them crucial elements for numerous high-tech applications, including wind turbines, hybrid cars, mobile phones, and defense technologies. They are also extensively utilized in traditional industries such as nuclear energy, petroleum, metallurgy, agriculture, and textiles (Xie, Zhang, Dreisinger, & Dyole, 2014; Zhang, Wu, Bian, & Zeng, 2014).Solvent extraction is widely used for the separation of REE (Xie et al., 2014; Zhao, Huo, Pan, Li, & Liu, 2014). Di-(2-ethylhexyl)-phosphoric acid (D2EHPA) and 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (EHEHPA) are two of the most effective extractants for the separation of rare earth elements among organophosphorus extractants (Gupta & Krishnamurthy, 2005). However, the difficulty in stripping loaded D2EHPA extractant, especially for heavy REE, has limited its utilization. Yttrium can be stripped at lower acidities in EHEHPA systems compared to D2EHPA systems (Gupta et al., 2005), but the extraction efficiency is lower. Conventional solvent extraction by mixer-settlers is restricted by its large solvent inventory and loading limits, and suffers from phase disengagement, emulsification, loss of solvent, and flooding problems (Swain, Jeong, Lee, & Lee, 2007). In this context, supported liquid membranes (SLMs) present a potential alternative due to their advantages, being low solvent inventory, process simplicity, low energy and operational costs, great enrichment ratio, and combination of extraction and stripping into one single step. A SLM is a system in which two aqueous phases are separated by an organic liquid membrane suspended in the pores of a porous support by capillary forces. One of the aqueous phases is the feed solution with the solute and the other is the stripping or receiving solution. The solute diffuses through the liquid membrane and then is extracted into the stripping solution (Kislik, 2010)."

Jan 1, 2016

By J. -P. Lempainen, K. Haavanlammi, K. Valkama

The Outotec nickel matte chloride leaching process is especially suitable for small capacity standalone nickel refineries. The matte is leached with hydrochloric acid and oxygen in multiple steps in atmospheric OKTOP® reactors. Oxygen feed prevents reductive conditions and hydrogen formation in the leaching process. A sufficiently high acid concentration keeps the iron dissolved in the solution. The iron is removed after leaching by precipitation and the pregnant leach solution continues to metals recovery. The metals recovery from the chloride solution is done by solvent extractions, where ammonia is used for pH control. Copper and nickel are stripped from the organic phases into sulphate solutions. Metals can be recovered from the purified solution by conventional electrowinning. Other alternatives are precipitation or hydrogen reduction processes. The ammonium chloride in the solvent extraction raffinate is regenerated into ammonia. The calcium chloride solution from ammonia regeneration is routed to acid regeneration where sulphuric acid is added and ultra-pure gypsum is precipitated. The hydrochloric acid solution from this step is recycled back to leaching. The process yields good overall metal recoveries and expensive

Jan 1, 2014

By Ross Gilders, Leo Cheung, C. David Desjardins

"For the past twenty years significant progress has been made in bacterial leaching. In fact, a recent article in the Northern Miner has cited that nearly all new copper production is based on bioleaching. The bacteria that play the predominant role in bioleaching is an obligate chemolithoautotroph called thiobacillus ferrooxidans. These bacteria thrive in areas rich in sulphide and prefer low acid media. In the simplest sense, they metabolize sulphide converting it to sulphate either as acid or as soluble metal sulphates. This process is well known because these bacteria generate acid mine water. Over the last five( 5) years, we have been carrying out development work on creating optimum bioleach conditions for the extraction of metals from sulphide rich ores and concentrates. Recently, a study was carried out on a byproduct sulphide concentrate produced in a tin flowsheet developed for the Mt. Pleasant Mine of ADEX Mining Corp. The objective was to determine whether a bioleach process might successfully leach this sulphide material which contains copper, zinc, iron and, what is more important, trace metals such as Indium, Gallium, and Bismuth. The current work describes the successful recovery of these metals achieving extractions of more than 80% by applying bioleaching techniques. An overview of this technical program forms the basis of this paper.IntroductionBio-Oxidation of metal sulphides has emerged to be one of the leading edge hydrometallurgical processes for the economic extraction of metals from ore and concentrates. The fundamental process involves the bacterial assisted oxidation of sulphide to sulphate yielding metal sulphates which can be subsequently leached by conventional means. The bacteria that play the predominate role is an obligate chemolithoautotroph named thiobacillus ferrooxidans (TF). These bacteria thrive in areas rich in sulphide and occur naturally worldwide. In fact, TF is responsible for generating acid in water (acid mine water) from exposed sulphide surfaces primarily through the oxidation of pyrite. TF bacteria thrive under the proper conditions of temperature and oxygen supply in the presence of sulphides and populations in excess of a million per millilitre (ml) of solution are achievable. Typically, at room temperature, the bacteria will bio-oxidize in a pH range of 1.0 to 3.0. Today, bio-oxidation has been applied commercially with great success for the extraction of uranium, copper, and gold."

Jan 1, 1996