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By R. Darlington, S. Ji

"High pressure die casting is a promising process to make thin-wall components with high dimensional accuracy and excellent surface quality. However, the non-uniformity is one of the important features in castings. The inhomogeneity in tensile properties and microstructural characteristics were studied for the castings with different thicknesses made by high pressure die-cast Al-Mg-Si alloys. For the local mechanical properties in the die-castings, the casting skin provided the highest, whereas the casting centre provided the lowest yield strength, UTS and elongation. The yield strength, UTS and elongation were significantly decreased towards the casting centre. The microstructural inhomogeneity is characterised by the segregation of coarse fragmented dendrites, the reduction of solute concentrations of Mg and Si, and the increase of porosity level from the surface to the centre of castings. The growth velocities of eutectic a-Al phase estimated using the Jackson-Hunt model confirm that the growth variation is larger in the thin castings than that in thick castings.INTRODUCTION Inhomogeneity is an inherent characteristic in as-cast microstructures of a variety of alloys because of their non-uniform chemistry, microstructure, defects, topology and the resultant mechanical properties in the different ranges of localization (Campbell, 2003). Generally, three types of inhomogeneities characterise casting microstructures, which include (a) the casting defects of shrinkage and gas porosity, misruns, cold shuts, inclusions, hot tears and hot spots; (b) the non-uniform microstructure from the surface to the centre of castings; and (c) the non-uniform microstructure from the dendrites grown from primary solidification and the structure formed during the subsequent eutectic solidification in inter-dendritic regions. The chemical composition and the morphology between the primary dendrites and the inter-dendritic eutectics also differ in the as-cast microstructure. Obviously, the inhomogeneity is different in the castings obtained from different casting processes."

Jan 1, 2018

By David S. Robertson, Richard F. Douglas

"Uranium is a lithophile element of relatively low natural abundance. Concentrations of uranium form through processes of erosion and sedimentation, and over 90 per cent of the western world's uranium ore reserves are in sedimentary rocks.Proterozoic quartz-pebble conglomerates contain about 60 per cent of the known uranium reserves. These are all similar in appearance, in mode of distribution and in manner of origin. They carry uranium minerals and/or gold and abundant pyrite. Their unique distribution in Huronian time required a pre-existing crust well enough evolved to have plentiful quartz and abundant gold, uranium and pyrite. The materials of value were deposited as detrital heavy minerals prior to the appearance of an oxidizing atmosphere in late Proterozoic time.Epigenetic uranium deposits occur in arkosic sedimentary rocks through the entire geological column. About 30 per cent of the western world's known ore reserves are in _these rocks. This type of deposit is particularly prominent in semi-arid parts of the United States, having yielded most of the uranium ore produced and containing nearly all of the known reserves.The Western States type"" of deposits occur in lenticular, permeable stream-laid sedimentary rocks. The de-posits are believed to have been precipitated from moving ground water at locations where plant debris or other organic matter had accumulated. The uranium may be derived from volcanic sediments, which are commonly associated with the units containing the ore, or it may be leached from exposed granite surfaces or from granitic debris which forms the sediments.A significant part of the world's uranium resources are in black shales and lignitic rocks. The lignites that contain uranium are virtually valueless as potential sources of heat. Uranium concentrations at levels such as to be potential sources of by-product uranium occur in many phosphorites.Reworked sediments may provide uranium in pegmatites and vein-like deposits."

Jan 1, 1970

By L. Shang

In conventional continuous hot rolling processes, metals are usually reheated to a temperature such that the workpiece will maintain appropriate hot working characteristics as it proceeds through the rolling mill, assuming that the temperature is continually decreasing. Metallurgically, reheating will reduce micro-segregation in the as-cast material, may increase the as-cast grain size and will affect any second phase particles present in the as-cast structure. All these changes can affect the hot working characteristics, and the final as-hot rolled microstructure. In order to study the effect of reheating on AZ31 magnesium alloy, a plate sample was cast in a water cooled copper mould and a series of compression tests was performed at a temperature of 350 °C, strain rate 0.01 5-1, and strains from 0.2 to 1.0, after different reheating schedules. It was found that there is no significant difference in flow behavior between the as-cast sample and all but one of the reheated ones. The reheat treatment of the 'anomalous' sample was a two stage heat treatment; it was first reheated to 450 °C, cooled to room temperature, then reheated to 350 °C. The effect on the flow curve was to increase the flow stress. This result may be related to changes in second phase particle characteristics.

Jan 1, 2006

By E. S. Yan, R. Graley

"The StackCell was developed to overcome the engineering and design challenges that are commonly associated with existing flotation technology such as pneumatic, self-aspirating cells, mechanical cells, and flotation columns. These challenges include high energy consumption, large floorspace requirements, and size. They are most evident when designing systems to process streams containing a high volumetric flow rate coupled with a significant float yield. Unlike many metalliferous and industrial mineral applications, fine coal flotation circuits are typically characterized by feed streams containing a low solids content (<5%, by weight) where up to 85% of the feed can report to the product launder. With input from major engineering houses and end-users, the Eriez Flotation Division (EFD) developed the StackCell technology with the goal of providing an additional flotation option for end-users. This technology was designed specifically to overcome these challenges by providing an efficient method of separation in terms of metallurgy, but also with respect to equipment size, energy consumption, and installed costs. Besides being placed in tandem with existing cells to provide cost-effective supplemental capacity, this technology can be installed in a stand-alone arrangement as recently demonstrated at Patriot Coal’s Kanawha Eagle preparation plant. This manuscript provides an understanding of the underlying fundamentals of this new technology and presents data from Kanawha Eagle in addition to other industrialscale installations.INTRODUCTIONOver the past decade, column flotation has continued to gain acceptance as an alternative method for recovering fine coal due to superior metallurgical performance as compared to mechanical flotation cells. This point has been proven on numerous occasions by comparison of plant flotation data with the release analysis separation curve (Dell et al., 1972). Data from a release analysis test approximates the ultimate flotation response of a coal sample. In North America, a number of investigations have been published that document bottom-line improvements achieved using column cells (Luttrell et al., 1999; Kohmuench et al., 2004; Baumgarth et al., 2005). According to these reports, the benefits are derived from an overall increase in plant yield that can be achieved due to the improved product grade in the flotation circuit. In particular, the application of wash water to a deep froth utilized in column flotation minimizes the nonselective recovery of high-ash ultrafines that are hydraulically entrained in the froth by conventional flotation machines."

Jan 1, 2013

By L. Vollert

In August 2018, the first full-scale HydroFloatTM cells for the recovery of coarse composited copper and gold were commissioned at Newcrest’s Cadia Valley operation in New South Wales, Australia. The primary objective of the installation is to recover coarse value-bearing composites that are lost to conventional flotation tailings, without the need for additional power input for particle size reduction to improve mineral liberation. This paper examines the application of Eriez HydroFloatTM technology for the recovery of coarse, poorly liberated copper sulphide particles drawing on recent experience from lab scale testwork through circuit design and commissioning of the full-scale installation at Cadia Valley. INTRODUCTION In the face of declining copper head grades and a tightening regulatory environment around the use of wet tailings dams, the processing of copper ores at coarser particle sizes has become a focal point for the industry. Sulphide flotation using the Eriez HydroFloatTM is one of the emergent technologies that sits under this umbrella of coarse pre-concentration. It has been demonstrated through numerous lab and pilot scale testwork programs carried out by Newcrest and others (Awatey, Kohmuench, Thanasekaran, Skinner & Zanin, 2013), to improve the flotation recovery of sulphide-rock composite particles with low surface liberation, relative to conventional flotation technology. The HydroFloatTM technology has been used widely for the recovery of coarse potash, phosphate, coal, vermiculite, spodumene and diamonds but has never been applied at full scale in either gold or sulphide flotation. In August 2018, the first full-scale 3.4 m diameter HydroFloatTM cells for the recovery of coarse composite copper and gold were commissioned at Newcrest’s Cadia Valley operation in New South Wales. The primary objective of the installation is to recover coarse value-bearing composite particles that are lost to conventional flotation tailings, without the need for additional upfront power input for particle size reduction to improve mineral liberation.

Jan 1, 2019

By D. B. Dreisinger, A. A. Gunaratnam

A pressure oxidation (POX)-hot cure (HC)-lime boil (LB) process is used in industry to recover silver from refractory gold sulfide ores containing minerals such as pyrite and arsenopyrite. Pressure oxidation is used to oxidize minerals and liberate occluded gold particles. As such, iron goes into solution and under acidic and high temperature conditions often precipitates as basic iron sulfate (BFS). BFS consumes excess lime during neutralization prior to cyanidation. Therefore, a hot cure stage is required to re-dissolve BFS back into solution. BFS re-dissolution consumes acid and produces ferric sulfate. In the presence of silver, these conditions favor the slow formation of silver jarosite. Silver jarosite is refractory to cyanidation, and must be broken down prior to cyanidation. This is done in the lime boil to produce a cyanide-soluble silver hydroxide. A study was conducted to investigate parameters that affect the precipitates that form in each stage of the POX-HC-LB process.

Jan 1, 2017

By D. Letzig

Wrought magnesium alloys are of special interest as lightweight structural components as a result of their more homogeneous microstructures and improved mechanical properties compared to cast components. Extrusion as a shaping technology offers the possibility to produce a wide variety of magnesium alloy profiles. In this contribution we describe the role of extrusion parameters such as extrusion speed, ratio and temperature as well as the type of extrusion process on the microstructural development of AZ-series magnesium alloys and the resulting mechanical properties. The effect of microstructure on the tensile/compression deformation behavior of the alloys has also been investigated. Aspects of process optimization designed to overcome technical and economic limitations and thus establish magnesium alloy profiles for industrial applications will also be discussed.

Jan 1, 2006

By Suzie Poulin, N. Geoffroy, G. P. Demopoulos

Most metallurgical industries generate toxic waste that must be treated prior to being released to the environment. However, in a lot of cases, the waste materials are poorly characterized or the analytical results are not well interpreted. These shortcomings often result in the development of inefficient industrial procedures, thus causing economic waste and difficulty meeting environmental regulations. Fortunately, a wide range of analytical techniques are available to guide researchers and engineers into making sound process development decisions. In this work, an industrial selenium and mercury removal process is used as an example to illustrate the application of X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM) coupled with Energy-dispersive X-ray spectroscopy (EDX) and powder X-ray diffraction (PXRD) on solid waste. Furthermore, samples of analytical results are presented and interpreted and the modifications to the industrial process that resulted are explained. Finally, a brief description of the advantages and limitations of the aforementioned analytical techniques is given with an emphasis on industrial solid waste material.

Jan 1, 2011

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003

By Richard Jundis

At the Vale Inco Ontario Operations, the working environment is rapidly evolving with organizational changes, new business systems and software tools. These changes are required in order to meet today?s challenging business environment. Mining professionals are focusing on the development of safe and achievable mine plans to maximize mining value while reducing the potential of project delays and production shortfalls. This paper explores how new design tools, techniques and system designs in mine planning are being developed to optimize the value of every ton of ore mined and processed. To differentiate from other papers on long-term planning, this paper focuses on the concept of business planning at the mines. Business planning is the understanding and optimization of the relationship between mine plans and the value it adds in the overall process. The management and key stakeholders of Vale Inco have recognized that the development of a robust mine planning system and programs are essential for the long-term sustainability of the operations.

May 1, 2009

By R H. Hallam

The Mattagami mining district encompasses a favour-?able belt of folded Keewatin-type rocks, with intercalated sediments and intrusives of late Keewatin age. This environment has been subjected to periods of basic and acidic intrusion. The orebodies lie within the fold structure and are associated with faulting and shearing of considerable magnitude. The No. 1 orebody contains 60 to 70 per cent massive sulphides. The minerals, in their order of abundance, are generally: pyrite, sphalerite, pyrrhotite, magnetite and chalcopyrite. It is evident that the broad geological structure of the district is amenable to ore deposition. There are two ? prominent linear expressions which comprise this broad structure. Both strike directions lie at the edge of, or are related to, a complex gabbro-anorthosite-peridotite zone. The fact that eleven of the ore zones discovered to date coincide with the broad structure indicates its over-all importance. It is estimated that the production from Mattagami Lake Mines will be in the range of 600 to 700 tons of zinc concentrate and 70 tons of copper concentrate per day.

Jan 1, 1964

By E. L. Bruce

Red lake is a body of water some thirty miles in length lying about forty miles northwest of the outlet of Lac Seul. It forms one of several large lake expansions on a river which enters the English river from the north, twenty miles below Lac Seul. Before the construction of the National Transcontinental railway a long canoe journey was necessary to reach that part of the English river, and Red lake, two days travel beyond, was one of the furthest outposts of the trading companies in that difficultly accessible triangle of country between Lake Winnipeg, James Bay and the English and Albany rivers. The Hudson&apos;s Bay Company post at Red lake is said to be one of the earliest established in the district but there are no records at the post, and as the English and Albany rivers never were used to any great extent as travel routes there is no mention of the place in the diaries of any of the early explorers. Dr. Bell passed through Red lake on his excursion to the Berens river country in 1883, and a brief note mentions that Huronian rocks were seen. To Dr. Dowling, however, belongs the credit for the first thorough description of this basin of sediments and basic volcanics. In 1893 he followed the course of Dr. Bell&apos;s trip, of ten years previous, through Red lake to the upper part of the Berens river.

Jan 1, 1926

By Chuck Edwards

Whatever your opinion of the validity of the scientific case for global warming, or of the wisdom of the Kyoto Protocol, it would seem judicious to err on the side of caution and try to sensibly minimize global climate change. To this end, we should take prudent steps to minimize our emission of greenhouse gases. Cameco is the world's leading supplier of uranium for use as fuel in nuclear power plants. Cameco’s uranium production fuels nuclear power plants in 16 countries. Nuclear power plants generate clean electricity without greenhouse gas emissions. This presentation describes the role that uranium and nuclear power can have in meeting the growing demand for electricity and at the same time combating global climate change.

Jan 1, 2004

By Anil K. Beersing

Effective drainage systems are required for reclamation of mine-disturbed areas to control surface water runoff and avoid excessive erosion. For the conventional structural design approach, armouring material necessary to satisfy the design criteria should not move during the design flood event since displacement would uncover the erodible underlying materials. This paper discusses an alternative geomorphic approach for designing drainage channels and watershed landscape. The approach is based on quantitative studies of geomorphic processes operating in a watershed. A design based on the geomorphic approach replicates the configuration, channel regime, sediment volume and hydrology of natural and mature drainage systems. Movement of some armouring material is acceptable in such an approach because the channels are allowed to mature by natural degradation and aggradation, with erosion rates comparable to the natural environment. The key advantages of a geomorphic approach over a purely structural approach include reduced sizes of armouring material, geomorphologically sustainable landscapes, ?walk-away? or maintenance-free design and reduced liability in the future. The geomorphic approach is illustrated using the example of a coal mining operation in northwest U.S.A. The paper discusses field data collection, design criteria, typical design details, and construction methods.

Apr 1, 2005

By Costa

The fly-in-fly-out (FIFO) mining model has significant implications for the industry as it plays an important role in fulfilling the economic, social and workforce needs of the contemporary mining industry. It has increasingly been adopted in countries such as Canada and Australia, but is the current nature of the FIFO model challenging the place women have achieved in the mining workforce? Research in the mining and oil and gas industries reveals that major sources of stress for fly-in-fly-out mining workers are the times of parting and of reunion, the challenges in defining roles within the family, parenting, and conflict between spouses over the use of the leave time and money. So how are women in the industry coping with the FIFO schedules and consequent intermittent relationship with families and partners? How is the mining industry adapting to recruit and maintain female employees in FIFO operations? This paper describes an exploratory study conducted in Canada, which intended to provide some initial insights that might help us answer the questions above. There are several inferences made from this exploratory study. It is clear that FIFO poses significant challenges for both female and male workers. It is largely seen as rigid, extremely challenging for employees with young families and workers who are single mothers, and it is generally incompatible with starting a family and caring for small children. FIFO creates severe stress on relationships and on workers psychological well-being. It seems to be indeed harder for women, since they are often in lower paying positions and therefore have less financial reward for the FIFO lifestyle. On the other hand, FIFO creates the opportunity for young women, including Aboriginal women, to jump-start their careers, as well as opportunities for mature women to work while pursuing other personal interests during their time off. This paper concludes with recommendations to improve the FIFO system in order to increase the ability of mining companies to hire and retain women

May 1, 2006

By G. Belzil, F. Robichaud, M. Fullam

"The Goldex mining and milling complex is operated by Agnico-Eagle Mines Ltd. and is located in the Abitibi greenstone belt of Northwest Quebec, Canada. The mill operates presently at a throughput of 8,250 tpd with gold grade varying between 1.8 and 2.2 g/t. The ore is very high in gravity recoverable gold (GRG) at about 92% and as such a significant emphasis was placed on the gravity circuit. Commercial production started in 2008. Average gold recovery is 93.5% with about 68% of gold recovery coming from the gravity circuit. Over the course of the first several years of production, several gravity audits were carried out. In 2009, a complete gravity audit was completed, including ore, classification, Knelson Concentrators, and the gold room. In 2011, an audit was undertaken of the flotation circuit to determine the efficiency by which GRG is floated. Large samples of flotation feed and tails were collected and process for GRG content. This allowed a link between gravity and overall recovery to be made. This paper presents results of the audits and the development of a model linking gravity and overall gold"

Jan 1, 2012

By Stephen C. Tadolini

"The use of a torque wrench to establish the amount of actual load developed on an expansion anchor bofting system dates back to work completed in the early 1950s. The advent of ultrasonic measurement systems and hydraulic torque wrenches has made it possible for the U.S. Bureau of Mines to perform torque-tension measurements in the laboratory and the field much more accurately. The results indicate that the amount of initial boft preload may be overestimated by amounts in excess of 45% of the expected load using torque wrenches. This inaccuracy is primarily due to the friction that occurs between the bearing plate and the head of the boft. These parameters become extremely important when the support system is being used to prevent joint members from slipping relative to each other or when the boft acts as a heavy spring to clamp two or more sections together. Methods to overcome the frictional losses are presented in conjunction with a laboratory method to determine the actual torque-tension ratios for expansion anchor and combination bolting systems.IntroductionMechanically anchored roof bolts have been widely used in the mining industry since their introduction in 1947. Estimates made in 1989 indicate that out of 85 million fixtures, approximately 49 million bolting fixtures still use applied tension to complete the reinforcement necessary to maintain stable openings. Nearly 85 million bolts are used yearly. The most widely used bolt is the resin-anchored headed rebar, followed by standard mechanical roof bolts, specialty bolts (mechanically anchored, resin enhanced fixtures) , and combination bolts . Po st-tensioned resin rebars, combination systems, and friction stabilizers make up the remaining 10% of the units used (Fig. I).For mechanical, combination, and tension rebar bolts, the bolt tension is the primary means of reinforcing the roof, but in many cases, because of poor installation procedures, the bolts are ineffective. Mine operators recognize the importance of proper installation procedures. Long-term bolt tension measurements are required in the Code of Federal Regulations (CFR)In each bolting cycle, the actual torque or tension of the first tensioned bolt installed with each drill head shall be measured immediately after it is installed. Thereafter, for each drill head used, at least one roof bolt out of every four installed shall be measured for actual torque or tension. If the actual torque or tension of any roof bolts measured is not within the range specified in the roof control plan, corrective action shall be taken."

Jan 1, 1991

By M. P. Rennick, D. M. Burton

Abstract -The Murray Brook massive sulfide deposit, which was the first geochemical discovery in the Bathurst camp, is one of the largest sulfide deposits in the area. The massive sulfides are hosted by quartzose metasedimentary rocks in the lower part of the Ordovician Tetagouche Group. This thick succession of sedimentary rocks is overlain conformably by felsic volcanic rocks, and is structurally overlain by mafic volcanic rocks. The massive-sulfide body is polydeformed, but primary metal zoning is still discernable and may permit future exploitation of discrete lead-zinc and copper zones. Although it was discovered in 1956, the deposit was not developed unti11989, when Murray Brook Resources commenced processing of gossan containing precious metals. Recovery of gold, silver, and mercury is accomplished by indoor vat leaching on a year-round basis.

Jan 1, 1992

By D. B. Dreisinger, M. Rasouli

"Developing technology to address the environmental hazards associated with selenium in mine-impacted waters has been a serious challenge. Ion exchange (IX) has been identified as a potential treatment technology. This paper begins with a review on selenium adsorption with commercially-available basic anionic exchangers (BAS). It then looks at the use of resins for selenium removal via modification with the addition of -O, -N, or -S-containing chelating ligands and chelating polymeric ion exchangers pre-loaded with immobilized metal cations. The synthesis of chelating exchangers requires a final product with a highly stable metal in the ligand-metal complex. The nature, oxidation state, size, and affinity of the metal for the target oxyanions and the size, degree of protonation and space configuration of the oxyanion are among critical factors affecting the oxyanion uptake. There is a limited number of studies on the critical parameters affecting the selenium affinity for chelating exchangers. Such a study could fill in the gaps of our understanding of selenium-metal-chelating ligand interactions and assist in developing a new ion exchanger. In addition to commercial IX resins, layered double hydroxide materials (LDH) have received attention for oxyanion removal from waste water. The adsorption capacity of the LDHs are affected by the crystallinity of LDH, the nature of metal components, the ratio of metals, charge and type of anion, and the space between the layers. In particular, the Friedel phase (FP), a member of the LDH family, showed high adsorption capacity for selenate removal from synthetic solution. A study is currently underway at the University of British Columbia to investigate the effect of different synthesis methods and aging on the suitability of FP for selenium removal from mine waste water."

Jan 1, 2017

By G. Viramontes-Gamboa, A. Encinas-Oropesa, S. Velázquez-Roque, L. A. Ibarra-Bracamontes

Some industrially relevant applications for pyrite nano/micro-particles have been proposed in the literature, such as the catalysis of chalcopyrite leaching, the removal of As(III), As(V) and Cr(VI) from solution, as photovoltaic devices, and others. Even though pyrite can be recovered from solution by flotation, for some applications it may be beneficial to provide pyrite with magnetic properties. In this work, a methodology to synthesize magnetic shell/core composites made of pyrite as the shell and either natural or synthetic magnetite as the core is presented. The size of the magnetic composite may range from tenths to hundreds of microns. The synthesis is basically made by stoichiometrically mixing iron nano/micro-particles with sulfur microparticles with magnetite particles, and bringing the mixture in an oxygen free atmosphere from 200 to 300 °C for 4 h. The composites were characterized by optical microscopy, Scanning Electron Microscopy and X-Ray diffraction.

Jan 1, 2014