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By G. M. Ritcey, B. H. Lucas

In the conventional alkaline leaching of concentrate containing nickel, copper and cobalt, copper is usually removed from the system, prior to nickel reduction, by sulphide precipitation. A new process is described for the selective extraction of copper and separation from cobalt and nickel, using liquid-liquid extraction. General Mills LIX-63 dissolved in a kerosene diluent is the extractant. Trace amounts of co-extracted cobalt and nickel are easily removed by a scrub treatment, and copper is recovered from the extract by sulphuric acid stripping, thus providing a solution amenable to the oroduction of electrolytic copper. Estimated processing costs are included together with a proposed flowsheet.

Jan 1, 1972

By G H. Reavely, The University of Western Ontario Department of Geology

The lower Middle Devonian Sylvania Sandstone occurs in the sub-surface in the western part of Mal-den township, Essex county, Ontario. The formation is composed of well rounded, frosted quartz grains with a silica content varying from 42 to 93 per cent and the grains are cemented by carbonate, constituting up to 57 per cent of the rock. This sand-stone is not a homogeneous bed but is divided by strata rich in carbon-ate cement. The thickness of the Sylvania in Malden township varies up to a known maximum thickness of 88 feet. The lower contact with the chert-bearing Bois Blanc formation is sharp but the upper contact with the Amherstburg formation (Detroit River group) exists as a transition by a gradual downward increase in quartz grains. The Sylvania would seem to outcrop in the lake bottom near the mouth of the Detroit River dipping to the north along a broad anticline the axis of which follows the Detroit River. Just south of Amherstburg, a local east-west trending

Jan 1, 1961

By H. Warren Newcomen, Dennis C. Martin

"This paper describes the investigation of a large, progressive slope failure on the southeast wall of the east pit at Highmont Mine, British Columbia Geotechnical investigation s consisted of geological and structural mapping, assessment of blasthole drilling records, review of rock core information, slope movement monitoring and back analysis of various possible failure modes. Climate records and mining history were also assessed to determine their relationship to slope movement .Analysis of movement monitoring records and geotechnical information indicates that the failure is deep seated. The upper portion of the failure surf ace occurs along clay filled discontinuities. The lower portion of the failure surf ace appears to occur through the highly altered rock mass. High groundwater pressures and mining at the toe of the slope are documented to have had a major influence on stability at various times during the failure. Stability analyses results are presented and possible remedial measures are discussed.IntroductionHighmont Mine is located near Logan Lake in the Highland Valley approximately 50 km southwest of Karnloops, British Columbia (Fig. I). Mining of the porphyry copper and molydenum ore bodies began in 1980. In May, 1983, when mining in the east pit had progressed to a depth of about 60 m (200 feet) , a failure (designated the Southeast Failure) began to develop in the southeast corner of the east pit. Subsequent mining to a depth of 110m (360 feet) was accompanied by frequent and substantial slope movements involving between 500000 and I 000 000 m3 of rock . The slope was monitored extensively to assess short-term movement trends for operational safety. Geological mapping, core logging and rock mechanics testing were used in conjunction with the long-term monitoring information to determine the failure mechanism, conduct stability analyses, assess the effects of instability on pit design and enable design and installation of remedial measures."

Jan 1, 1988

By Lifeng Yang, Xiang Zhang, Liang Yuan, Yonghui Wang, Bing Hou, Mian Chen, Rixing Zhang

Large-scale hydraulic fracturing technique has been widely applied to the development of shale gas reservoirs, where the interaction between natural fractures and critical fracture zones has substantial impact on the propagation of hydraulic fractures. Therefore, it is of significant importance to understand and experimentally verify such mechanism. To reach this end, tri-axial fracturing tests were implemented on 400mm×400mm×400mm block samples collected from Longmaxi shale outcrops. The interplay between hydraulic and natural fractures was investigated during the tests, factoring in the role of pump rate in affecting the created fracture network. Based on the experimental results, the critical fracture zone, defined as the weak formation zone nearby the wellbore created by staged pressure implementation that is observed rapid fracture propagation upon next stage of pressure increase, was thoroughly investigated. The analysis illustrates that given the high brittleness of the shale formation, abundant critical fracture zones are generated around natural fractures with pressure building up at a relatively low pump rate. As the pump rate increases, hydraulic fractures initiate and come into play with critical fracture zones, implying emergence of a large number of micro-cracks. A changing pump rate modifies the way of interaction between hydraulic and natural fractures and the subsequent formation of fracture network. Long term fracturing fluid injection with relatively low pump rate below the activation of critical zones is suggested. Also proposed is appropriate timing when applying a specific pump rate that will contribute to the improvement of hydraulic fracture propagation.

Jan 1, 2015

By G. E. Peacock

SIGMA MINES is situated in the township of Bourlamaque, Abitibi County, Quebec. It is a gold producer, and presently treats an average of 1,200 tons of ore per day, at a grade of approximately 0.18 oz. per ton recovered. The mill started operations in March, I937, at a rate of 300 tons per day. This was increased to 800 tons in I940, and to 1,000 tons by I943. The rate was cut back during the war years, but was brought back up to capacity by I948. The mill tonnage was in-creased to the present 1,200 tons per day in I960. The underground workings are serviced through No. 2 Shaft (Figure 1), which, with 24 operating levels, extends from surface to a depth of 3,317 feet. When depth exploration was decided upon, two possibilities were considered: (a) deepen the main shaft by1,000 feet; (b) put down a winze for the same distance.

Jan 1, 1962

By Y. Faitakis

In the mining industry, maintenance is a key priority and a major expense. As mining equipment is large in scale, high in cost, and difficult to tow, it is key to maintain equipment on a timely basis. Breakdown in -40°C or away from a maintenance station can cause great costs in repair as well as lost production. It has often been quoted that about 5% of the North American production is lost every year due to unscheduled downtime. About one-third of the downtime is attributable to equipment failures. From this fact alone, it is evident that proper equipment maintenance can add tremendous value to the bottom line. As organizations and equipment become more sophisticated, maintenance expectations begin to evolve. This evolution can be traced through three generations: The first generation (1940?1950): A ?fix it when it broke? attitude prevailed during that time, mostly because the industry was not highly automated. The second generation (1950?1980): Automation and mechanization of the industry increased. The industry now was dependent on machines performing the majority of the work. Preventive maintenance (overhauls at fixed intervals) appeared as the first maintenance practice. Maintenance costs started to rise rapidly. The third generation (1980?): Assets become more complex. Failure modes are better understood and computerized maintenance methods are becoming mainstream. Condition-based maintenance (CBM) starts to gain ground as a cost-effective alternative, replacing the fixed interval overhauls. As corporations amalgamate and market places are becoming more complex, multi-functional teams become responsible for maintenance. At the beginning of the third generation, maintenance organizations began embracing technology to provide efficiencies in maintenance management. A strong push was made to transition from reactive maintenance to proactive maintenance. At the forefront of this push is condition-based maintenance.

Jan 1, 2004

By Y. Faitakis, G. J. Powley, C. Mackenzie

"In the mining industry, maintenance is a key priority and a major expense. As mining equipment is large in scale, high in cost, and difficult to tow, it is key to maintain equipment on a timely basis. Breakdown in -40°C or away from a maintenance station can cause great costs in repair as well as lost production.It has often been quoted that about 5% of the North American production is lost every year due to unscheduled downtime. About onethird of the downtime is attributable to equipment failures. From this fact alone, it is evident that proper equipment maintenance can add tremendous value to the bottom line. As organizations and equipment become more sophisticated, maintenance expectations begin to evolve. This evolution can be traced through three generations:The first generation (1940–1950): A “fix it when it broke” attitude prevailed during that time, mostly because the industry was not highly automated.The second generation (1950–1980): Automation and mechanization of the industry increased. The industry now was dependent on machines performing the majority of the work. Preventive maintenance (overhauls at fixed intervals) appeared as the first maintenance practice. Maintenance costs started to rise rapidly.The third generation (1980–): Assets become more complex. Failure modes are better understood and computerized maintenance methods are becoming mainstream. Condition-based maintenance (CBM) starts to gain ground as a cost-effective alternative, replacing the fixed interval overhauls. As corporations amalgamate and market places are becoming more complex multi-functional teams become responsible for maintenance.At the beginning of the third generation, maintenance organizations began embracing technology to provide efficiencies in maintenance management. A strong push was made to transition from reactive maintenance to proactive maintenance. At the forefront of this push is condition-based maintenance."

Jan 1, 2004

By G. A. Bezuidenhout, J. Davis, S. M. Bradshaw, J. P. T. Kapusta, D. K. Chibwe

"This research work forms part of an assessment to complement the feasibility of implementing high pressure sonic injection into relatively small (2.25 m I.D by 3.66 m I.L) Peirce-Smith converters (PSC) used at Lonmin Plc. Work has been carried out to characterize the fluid dynamics of three-phase (air, matte and slag) fluid flow in these converters using Computational Fluid Dynamics (CFD) simulations. The investigation has been done to study the flow pattern of the three phase system at high air pressure injection achieving sonic velocity at the tuyere exit into the converter. The 2-D and 3-D simulations of the three phase system were carried out using the volume of fluid (VOF) and realizable k -e turbulence models to account for the multiphase and turbulence nature of the flow, respectively. These models were implemented using the commercial CFD numerical code FLUENT. A detailed study of the flow pattern has been presented in the form of contour plots and the results obtained are useful for understanding plume extension and velocity distribution, shear wall stress distribution, and phase distribution characteristics in the system. The results provide a basis for further development of sonic injection technology into relatively small industrial Peirce-Smith converters with the ultimate objective of achieving lower energy consumption, improved process efficiency and increased throughput of the converting process. INTRODUCTIONPeirce-Smith converters (PSC) have been used in copper (Cu) and nickel (Ni) making smelters for more than a century for the purpose of removing iron (Fe) and sulphur (S) chemically associated with copper-nickel mattes through exothermic oxidation reactions. This process is commonly referred to as conversion. In principle, conversion is a submerged injection process, where typically air (or oxygen enriched air), at subsonic velocity (typically < 150 m/s), is laterally blown into liquid matte (Cu-Ni-Fe-S system). Oxygen preferentially reacts with Fe and S to produce iron oxide (FeO), which is slagged off, and sulphur dioxide (SO2), which reports to the process off gas."

Jan 1, 2012

By L. Sun

In this work, strontium doped lanthanum ferrite (LSF) and their composite cathodes were fabricated by screen printing on yttria-stabilized zirconia (YSZ) electrolytes. Their electrochemical properties were evaluated by using electrochemical impedance spectroscopy and steady-state polarization methods. All the cathodes were screened by comparing their total polarization resistances before and after activation processes at different temperatures. The improved LSF composite cathodes were also screen-printed on YSZ/NiO half cells to fabricate solid oxide fuel cells (SOFCs), which have reached the output power densities of 170 mW/cm2 at 650 °C, 230 mW/cm2 at 700 °C, 304 mW/cm2 at 750 °C and 388 mW/cm2 at 800 °C.

Jan 1, 2005

The influence of joint orientation and joint persistence, on the mechanical behaviour of jointed rock masses under uniaxial compression, has been studied systematically. The joint inclination angle ß was varied from 0° to 90° with an increment of 15°. The joint continuity factor k was taken as 0.2, 0.4, 0.6 and 0.8. The peak strength, Young’s modulus, the complete axial stress-axial strain curves, the cracking process and the characteristic of the fragments, were investigated. It was found that the anisotropic response of the jointed specimens was governed by the micro-mechanism, such as crack initiation, propagation and coalescence, crack opening or closing, and frictional slip of cracks or joints. With the increase of joint continuity factor, the axial stress-axial strain curves change from single-peak to multipeak, the peak strength and Young’s modulus decrease. The specimens with medium joint inclination angle (30°,45° and 60°) has lower energy dissipation and strength due to stepped or shear failure, while specimens with small and large joint inclination angle (0°, 15°, 75° and 90°) has higher energy dissipation and strength due to axial cleavage or crushing failure.

Jan 1, 2015

By L. Heber Cole

Introductory During the past few years, salt (sodium chloride) strata have been encountered in western Canada in a number of wells, while prospecting for oil and gas. The ever increasing number of such wells points to the presence of a vast salt basin, the boundaries of which are at present unknown. This basin extends in a northwesterly direction from a point near the United States boundary south of Regina, crosses the Saskatchewan- Alberta boundary northwest of Unity, Sask., and continues with more northerly trend to Waterways and beyond. The beds, as encountered, appear to have a general dip to the southwest of between 10 to 20 feet to the mile and a pitch along the strike to the southeast. Thus one finds the salt strata at Waterways, Alta., at 600 feet below the surface (121 feet above sea level) whereas at Radville, Sask. south of Regina, the top of the salt is at a depth of 6,643 feet below the surface (4,430 feet below sea level). Whether this is a continuous salt basin or a series of separate basins is not yet known. We do know however, that in some of the well~ more than one salt horizon occurs while in others which normally should have encountered corresponding beds, the salt strata are absent. This latter condition, however, may occur only in the southern part of Saskatchewan, where a barren area seems to come in from the southwest. In the northwestern part of the basin, on the other hand, the occurrence of the salt strata seems to be more regular and continuous, and depths at which salt should be encountered in a drill hole in this part of the basin may be predicted with a fair degree of accuracy.

Jan 1, 1948

By John R. Goode

"The year 2011 witnessed a major surge in rare earth prices as China, supplier of +95% of the world’s rare earths, reduced export quotas and increased export taxes and duties. In response, companies around the world are scrambling for alternative sources. In Canada too, there is a race to be the “first” rare earth producer. Something that is not generally realized is that Canada has a long history of rare earth production and was a major supplier from the early 1960’s to 1990. At one stage, Canada was said to be supplying more than one third of the world’s yttrium and probably supplied even more than that. Five decades ago, thorium was a key element in many non-nuclear applications and Canada became a major supplier of thorium from the late 1950’s to 1968, first as a by-product of uranium and then as a co-product of rare earths. This paper reviews the development of Canada’s original rare earth and thorium production facilities, which were located in the Elliot Lake uranium camp in Northern Ontario. The uses of these elements, geology, mineralogy, markets of the time, and processing are all discussed. Some of the lessons learned from these pioneering operations might be useful in today’s race to develop the next generation of rare earth production plants.INTRODUCTION The rare earths and thorium were first identified in the early 19th century but were little more than curiosities for the next century. However, in the mid-1960’s the invention of rare earth-based phosphors for the cathode ray tube in colour television sets launched a major demand for certain rare earths. The use of thorium as an alloying agent in aircraft and missiles grew rapidly in the late 1950’s. In the same period, demand for uranium for both weapons and power production soared. Also in the late 1950’s, the Elliot Lake uranium-thorium-rare earth deposits (also known as the Blind River deposits) were discovered. This conjugation of events led to uranium production in the Elliot Lake camp, quickly followed by the co-production of thorium and, later, the rare earths. Uranium production in the Elliot Lake camp continued from 1955 to 1996. Thorium was produced continuously from 1959 to 1969. Rare earths were produced, intermittently, from 1965 to 1990. Complete production records are not readily available for thorium and the rare earths but unquestionably Elliot Lake production made a significant contribution to world production. This paper is intended to present as much of the information that is available."

Jan 1, 2012

By Y. M. Jubeli

"Gamma-ray spectrometry, an effective tool in geological mapping, was used to de?ne boundaries between various lithological formations in three adjacent areas of Central Syria, namely, the Syrian Desert, Ar Rassafeh Badiayat and the Northern Palmyrides mountains.This paper describes the role of an airborne gamma spectrometric survey which was originally undertaken to assist uranium exploration. Interpretation of the total count data obtained through the survey has led to signi?cant modi?cations and corrections to the previously published distribution map of the palaeogene phosphate rocks.Another important result of the survey is the discovery of four previously unknown phosphorite horizons in the Rasm Al-Aawabed area of the Northern Palmyrides. In addition, previously unknown phosphatic horizons are outlined in the other study areas. The importance of this technique as an effective prospecting method, not only for U but also for exploring for the economically important phosphorite formations in Syria, is emphasized. Furthermore, its role in geological mapping is stressed, especially in areas that lack suf?cient geological data."

Jan 1, 1997

By Julie Culverhouse, Dennis Grimm, Kieran Harding, Jean-Francois Boulanger

"Agrium’s Canadian Phosphate Business (CPB) is comprised of Kapuskasing Phosphate Operations (KPO) in Northern Ontario, Canada’s only operating phosphate mine, and Redwater Phosphate Operations (RPO) in Alberta, which manufactures the fertilizer from KPO’s concentrate.Production from KPO’s South Pit commenced in 2009 and introduced contaminant problems: high aluminium from crandallite and kaolinite clays. These issues caused a drastic decrease in P2O5 recovery and throughput in both plants. KPO attempted to reduce Al clays by means of aggressive desliming. Meanwhile RPO experienced high amounts of dissolved metals in their feed that are detrimental to fertilizer production.This paper covers the mineralogy of the problem, its impact on contaminant separation at KPO, on RPO’s process and on Agrium’s Canadian Phosphate Business as a whole.Potential solutions to the problem are discussed and analysed, including a process change to deslime high aluminium streams more aggressively and high grade ore flotation, which is atypical at KPO. The latter is a demonstration of the value of communication between the concentrator and the client, as KPO accepted a recovery loss and increased production costs in order to increase overall CPB profits. General lessons learned are discussed, followed by a section on ore blending.INTRODUCTIONAlthough the existence of the Kapuskasing phosphate deposit has been known since the 1970s, it’s only since 1999 that Agrium has been operating the Kapuskasing Phosphate Operations (KPO). The mine consists of three major pits (Center, North and South) from which a mining contractor hauls the apatite ore to the Agrium concentrator. The beneficiation plant processes the ore, separating contaminants such as Fe, Mg and Al which are detrimental to its client, Agrium’s Redwater Phosphate Operations (RPO). The KPO concentrate is finally thickened, filtered and dried before being shipped by rail to RPO.At the Redwater plant, the KPO concentrate is added to a sulfuric acid solution in an attack tank, to create a phosphoric acid solution and gypsum:"

Jan 1, 2011

By Mihaita Matei

An adaptive approach to control the deformation in tube hydroforming process is presented. This requires: the use of an existing non-linear FE software (ABAQUS) that incorporates a user material model (VUMAT), the development and implementation of an adaptive control strategy to coordinate the internal pressure and the axial load so as to prevent fracture and wrinkling failures (knowledge-base controller) and the application of the developed adaptive simulation approach for finding the optimal loading path required to hydroform a defect-free part with as uniform thickness distribution as possible (user&apos;s load subroutine (VDLOAD). In order to validate the approach, the case of conical hydroforming and the case of bending followed by hydroforming component is discussed.

Jan 1, 2011

By LUKE O. LINDOE

A major clay products industry in the Medicine Hat area since before 1910 has maintained a continued interest in the clays of the Cypress Hills. For the first forty years the materials used were local red-burning Cretaceous and Pleistocene clays and sands and high-quality stoneware clays of the Whitemud Formation at Eastend, Saskatchewan. Recently a much broader spectrum of raw materials has been brought into use. Including the exposures of the Eagle Butte structure, the Cypress Hills present a 1200 m section of clay-like sediments. Of this 1200 m about 94 per cent, the high montmorillonite shales of the Upper Cretaceous, can be considered useless, or nearly so; the remaining six per cent, all fresh-water beds, presents a wide variety of potentially useful materials. The development of these clay resources is complicated by deep surface creep on the south flank of the Cypress Hills, by largescale slumping on the north flank and by a structural complex in the Eagle Butte area.

Jan 1, 1984

By Andrew Kerr

Abstract - The base-metal and PGE contents of samples from magmatic sulfide mineralization are commonly correlated with their sulfide contents, indicating that the metal contents of bulk sulfides remain approximately constant within a given prospect or part thereof. Calculated sulfide metal contents provide valuable information in mineral exploration and research, but there are few formal descriptions and analyses of the procedures. Sulfide metal contents are best calculated using an assumed value (35.7% S) for a typical pyrrhotite-chalcopyrite-pentlandite mixture, and there appears to be little advantage in accounting for sulfide species separately. Regression of metal data against sulfur is probably the most rigorous approach, but is not always practical. Above 10% S, calculations are very robust, but lower sulfide contents generally demand at least some correction for non-sulfidehosted metals. Such corrections can become significant below 5% S, and/or in olivine-rich samples. They are best accomplished by mass-balance calculations, using concentration data from unmineralized host rocks. Significant uncertainties are introduced by analytical errors for sulfur, base-metals, and PGE, which are commonly measured from separate sample aliquots. These combined errors in sulfide metal contents generally exceed ±10%, but expand further at low S contents. In general, treatment of data from samples containing <2.5% S must be approached with caution, especially for PGE, for which the exact host minerals may not be known. Application of the method in simple grade-potential assessment is straightforward, but research studies involving sulfide-poor samples are inherently more complex. Under-correction or over-correction of data for non-sulfide-hosted metals can lead to false negative or positive correlations between sulfide metal contents and sulfide content. As the latter may itself be linked to geological parameters, such as depth within an intrusive body, undue significance could be ascribed to such trends. There are also valid geological reasons for such correlations, and such data require careful assessment to separate true and artificial variations. Propagated analytical uncertainties increase significantly in sulfide-poor samples, and must also be borne in mind whenever data from different localities or units are compared and contrasted.

Jan 1, 2001

By H. Itou

A mechanism of scorodite formation at ambient pressure was investigated using transmission electron microscopy (TEM). Several types of iron arsenate were obtained from Fe/As solutions (Fe/As = 1.0 and 1.5) at pH values of 1.0, 1.25 and 1.5 at 95°C. Amorphous FeAsO4.xH2O was precipitated from solutions having a higher mole ratio of Fe/As at pH l.5, even after 9 hours. A few micron sized particles were observed by SEM, but these proved to be agglomerates of 10-50 nm amorphous FeAsarxH2O particles when observed by TEM. This means that supersaturation of the solution causes the acceleration of nucleation of iron arsenate hydrate. Crystalline scorodite was obtained from a solution in which the Fe/As mole ratio was unity, at pH l.0 and pH 1.5, after 3 hours. Almond-type crystalline scorodite particles were observed by TEM and most of them showed high crystallinity. The addition of scorodite seed material enhanced the crystallization. Amorphous FeAsO4.xH2O, however, was observed at the surface of the seeds during the early stages of precipitation. It is postulated that crystalline scorodite is not directly precipitated even on crystalline scorodite seeds, but requires a certain time to crystallize on the seed material.

Jan 1, 2006

By John G. Henning

Unplanned ore dilution has a direct and large influence on the cost of a stope, and ultimately on the profitability of a mining operation. This paper presents results of a study on the influence of a variety of factors on ore dilution in a blasthole stoping environment. A series of 3-D numerical models were developed and analyzed to examine the effect of mining depth, stope geometry and stope setting within the orezone extraction sequence. To quantify modelled ore dilution from the three-dimensional simulations, the ore Dilution Density (DD) is a term introduced in this study to denote potential hanging-wall overbreak. It was found that hanging-wall overbreak is not significantly influenced by depth alone, and that stopes with large or small axial ratios are more stable than large rectangular stopes. It was also demonstrated that, in addition to stope dimension, the amount of unplanned dilution differed according to stope type. Five stope types were identified, based on their position within a tabular blasthole mining sequence. The methodology presented in this paper can be adopted to develop mine-specific design tools for the estimation of ore dilution associated with a proposed mine design. This can prove extremely helpful in the process of underground mine planning and optimization.

May 1, 2007

By M. Nusheh, C. Bumby, A-H. Puichaud

"Vanadium-bearing titanomagnetite ironsand deposits occur along a 480 km stretch of the west coast of New Zealand. In the present study, the leaching behaviour of NZ ironsand was investigated in hydrochloric acid (2–10 M) solution at 50–80°C for 2 h. The resulting leaching liquors exhibited Fe/V ratios in the range 150–180. The distribution of trace element contaminants between solution and solid residue was investigated, and processing conditions have been determined for rapid and efficient dissolution of Fe, Ti and V into the leaching solution. In addition, mineralogical analysis of raw ironsand and leached residues was performed in order to study the leaching mechanism. Samples were characterized by scanning electron microscopy, energy dispersive X-ray spectroscopy (EDX), X-ray fluorescence spectroscopy, qualitative and quantitative X-ray diffraction and inductively coupled plasma mass spectrometry (ICP). Results indicate that the dominant dissolution process follows shrinking particle mechanism. However, ironsand particles containing ex-solution lamellae exhibited a different leaching behaviour compared to homogenous titanomagnetite particles.INTRODUCTION Titanomagnetite ironsand (blacksand) forms Quaternary onshore beach and dune deposits and offshore marine deposits (Figure 1) along 480 km of coastline from Kaipara Harbour south to Wanganui on the west coast of the North Island (Christie, 2016). It attracted the attention of scientists from the earliest times (Galbreath, 1998). The principal minerals in ironsand are titanomagnetite (TTM), ilmenite, quartz and ferromagnesian minerals such as augite, hornblende, diopside, and olivine with smaller amounts of rutile and apatite (Mauk, 2016).Several large ironsand deposits have been discovered and exploited since the late 1960’s. The Waikato North Head and Taharoa mines are currently operating and they have a 2015 measured resource of 400 million tonnes in total and provide over 2 million tonnes of concentrate per year by simple cost effective magnetic separation process (Christie, 2016; Christie & Brathwaite, 1997). The concentrate contains not only 7–8% TiO2 and 56–60% SFe, but also 0.3–0.6% V2O5, is both a valuable titanium mineral and a source of vanadium. All the production is used for steelmaking industries. The other potential for utilizing more of this resource without requirement of integration into an iron and steel producing plant is to develop a hydrometallurgical route with advantages of higher efficiency along with lower emissions. Currently, there is no existing commercial process capable of extracting all three of these elements as industrial-grade commodity products. Acid leaching of TTM concentrate with higher degrees of recovery and selectivity is a key step in any possible hydrometallurgical route."

Jan 1, 2017