Search Documents

By A. R. Miller, G. Desrivières, M. C. Bétournay, D. L. Barnes, P. Laliberté

"Over the last four years, an international initiative, championed by Vehicle Projects LLC, the Fuelcell Propulsion Institute and Natural Resources Canada, has been active in carrying out research projects to prove out the concept of applying fuel cell technology to underground mining vehicles. These have been carried out by a consortium consisting of mining companies, equipment manufacturers, technology developers, national laboratories and consultants, with the participation of Canadian and U.S. mine regulatory agencies.This clean technology, which produces only water and electricity, would allow several advantages to be obtained, in the health area (by eliminating diesel emissions and reducing noise generation), in lowering production costs (such as reducing ventilation required) and lowering greenhouse gas emissions.This paper outlines the results obtained in several key areas, such as, the operation of fuel cells in underground conditions, risk issues related to underground and surface operation of hydrogen vehicles and hydrogen production and delivery systems, and the design and mining performance of the world’s first hydrogen mining vehicle, a mine production locomotive. The work to date on the fuel cell loader, designing the power plant and power transmission systems, operational requirements, and operating cost reductions is also presented."

Jan 1, 2003

By Marcel Vallee, D. C. Gagnon, C. CARBONNEAU, P. ST-JULIEN

The Magdalen Islands archipelago, a cluster of fifteen islands, is located near the centre of the Gulf of St. Lawrence on the thickest portion of the Carboniferous Fundy Basin of the Maritime Pro vinces. The bedrock of the Magdalen Platform includes a thick succession of evaporites of Visean Age, occurring as a series of thickenings, ridges, domes and diapirs reaching a probable vertical thickness of close to 6000 m. The emplacement of 1hese salt structures by flowage has much dislurbed 1he SlrOligraphic sequence of the rocks of the Windsor Group, particularly 1he Havre-aux-Maisons Formation. Subsequent tectonic movemenl has broken the overlying Cap-auxMeules Forma1ion info an assemblage of panels and blocks now slightly tilted. Following detailed gravimetric surveys and more than 30,000 m of diamond drilling, SOQUEM has discovered, at various dep1hs, seven salt domes on four of 1he main islands of the archipelago. These evaporite bodies generally are localized near the cemre of complex anticlinal struclUres where diapiric movements and faulting have disturbed the original stratigraphic succession. At Rocher du Dauphin near Grosse 1/e, in 1he northern part of the archipelago, Seleine a SOQUEM subsidiary is developing a mining complex with an annual capaci1y of 1,250,000 1onnes of deicing salt for 1he Canadian and Eas1ern United Swtes marke1s. The stan of operations is scheduled for April 1982.

Jan 1, 1984

By S. V. Burr

"A 28-year study of cross folds leads to the conclusion that the northwest-southeast folds recognized in many areas of North America are part of a regional pattern. Detailed examination of over 650 geological maps and reports of Ontario indicates that this folding can be traced across the province. Evidence is presented that this fold pattern played an important part in determining the pattern and scale of intrusion, that its recognition in the field can aid in defining stratigraphy, folding and faulting, and that it may have played an important role in channeling hydrothermal or magmatic mineralization. IntroductionThe concept of regional cross folding in Ontario is not new. W.H. Gross (1955) discussed regional cross folds in the Archean of Northwestern Ontario, and A.M. Goodwin (1961) referred to regional cross folds in the Archean of Ontario and Quebec. However, the interpretation in this paper is new.The writer saw a cross fold for the first time, underground, at Little Long Lac Gold Mines in Geraldton, Ontario, in 1951. This recalled the ""transverse folds"" on E.R. Faribault's classical maps of Nova Scotia, published by the Geological Survey around the turn of the century; M.E. Hurst's cross fold(s) at Timmins, Ontario (Figure I); and the cross folds mapped by A.W. Jolliffe in the Yellowknife area of the Northwest Territories. All these mapped cross folds had one thing in common with the fold at Little Long Lac: A northwest-southeast axial trend. Were such cross folds of purely local extent, or might they be indicative of a widespread regional fold pattern? If so, has such folding any significance for mineral exploration or potential?By 1959, based on a study of about 1000 Canadian geological maps and reports, including 291 in Ontario, the writer reached the conclusion that cross folding trending northwest-southeast is so widespread as to constitute a pattern of folding, and that such cross folding should produce changes in plunge along pre-existing greenstone fold belts."

Jan 1, 1980

By W. W. Rudolph, L. N. Trevani, P. R. Tremaine

UV-visible spectroscopy, Raman spectroscopy, and vibrating tube densimetry have been used in our laboratory to determine equilibrium constants of aqueous species at temperatures as high as 325 °C. The UV-visible and Raman spectra of solutions containing metal complexes and ionized acids or bases can be used to yield formation constants by applying curve fitting methods to resolve the contribution of each species. Colorimetric pH indicators identified by Johnston and coworkers at the University of Texas (Austin) provide an alternative means of determining ionization constants and the pH of complex mixtures. High precision density measurements over the same range yield standard partial molar volumes, which are key parameters for "equations of state" for aqueous species. Examples are given for the copper-ammonia system, simple carboxylic acids, and the iron-sulphate system.

Jan 1, 2004

By R. Laucournet, E. Billy, M. Joulié

Today Li-ion batteries are considered as one of the most attractive available energy storage solutions. However in order to overcome environmental, legislative and economic issues, the management of used batteries has to be considered and mainly the recycling. The present paper deals with the recycling of used Li-ion batteries and the recovery of high value metals from active materials of electrodes. Lithium nickel cobalt aluminum oxide (NCA) and lithium manganese nickel magnesium oxide (LMNM) cathodes, which contain most of valuable elements typically used in the composition of active materials for Li-ion batteries are investigated by a hydrometallurgy route. The process is divided into two steps: the materials leaching and the elements recovery by a selective chemical separation. Some experimental parameters (acid nature, concentration, time and temperature) are studied to determine the most efficient conditions of dissolution. Then, the valuable elements such as nickel, cobalt and manganese are selectively recovered with a high efficiency close to 100 % and with a high purity by precipitation. By this study, an adaptable hydrometallurgy process can be defined according to the composition of Li-ion batteries to recycle.

Jan 1, 2014

By R. Hamilton

"Louvicourt mine began operation in 1994. It is located in northwestern Quebec, 20 km east of Val d’Or. The mine is owned by Aur Resources (30%), which operates the mine, Teck/Cominco (25%) and Novicourt (45%). By the end of 2002 there were approximately 280 employees working on the site, including contractors. Production averages 4300 tons per day, working a massive sulphide body located between 415 m and 920 m underground.Maintenance expenses represent 27% to 29% of the operating costs, and the maintenance personnel represents 34% of the total workforce (including electrical, mechanical and concentrator maintenance staff). Considering these figures, in addition to capital costs and indirect costs, such as energy (electricity, fuel, gas, etc.), it is worthwhile to pay attention to how things are done in order to protect such investment. Every task performed to help understand the impact of Louvicourt’s practices must to be seen as an investment in the reliability of its operation."

Jan 1, 2003

By Fathi Habashi

"Hydrochloric acid (HCl), although more expensive than sulfuric, find uses as a leaching agent in reactions involving iron oxide. The reason for this substitution was the discovery that oxyhydrolysis of ferrous chloride by which HCl can be recycled economically. This avoided the pollution of the environment by ferrous sulfate. It was found further that the rate of leaching of sulfides is faster when HCl is used as compared with sulfuric apparently due to the formation of aqueous chlorine. In case of refractory gold ores, HCl leaching under pressure avoids the use of cyanide solution since gold chloride is produced which can be recovered by standard methods. Hydrochloric acid find also uses in the leaching of scheelite and apatite but its use in leaching clay and anorthosite is questionable.INTRODUCTION Sulfuric acid is the cheapest acid and is used as a leaching agent in many hydrometallurgical processes. However, hydrochloric acid (HCl), although more expensive since it is prepared by reaction of sulfuric with sodium chloride, has replaced sulfuric acid in many reactions involving iron oxide. It replaced sulfuric acid for the first time in 1960s in pickling of steel because of pollution problems (Habashi, 2000). Ferrous chloride produced in pickling can be economically decomposed to ferric oxide and HCl according to:2FeCl2 + 2H2O + 1/2O2 ? Fe2O3 + 4HCl (1)which also shows that the acid can be regenerated but ferrous sulfate cannot be economically decomposed to recover sulfuric acid for recycle. Since then, HCl has been used in many leaching processes. Hydrochloric acid is a corrosive acid and is usually handled in rubber-lined equipment. REGENERATION OF HYDROCHLORIC ACID Regeneration of HCl is conducted in fluidized bed or in spray roaster Fluidized bed oxyhydrolysis In a fluidized bed, ferrous chloride solution is introduced onto a bed of hot ferric oxide where heating is provided by the hot fluidizing combustion gases (Figure 1). The solution is fed on top of the bed of oxides. The liquid feed wets the outer layer of the hot oxide particles and is quickly evaporated to form a layer of new solid oxide on top of the existing oxide, thereby producing dense homogeneous particles."

Jan 1, 2017

By Jean-François Dorion

La corrosivité des environnements miniers souterrains est un phénomène peu étudié au Canada. En plus de détériorer les systèmes de soutènement, la corrosion s?attaque aussi à divers installations et équipements souterrains. Cette étude, débutée en janvier 2007, est l?établissement d?une banque de données afin de caractériser les environnements miniers souterrains selon leur potentiel de corrosivité pour les systèmes de support de terrains. Pour ce faire, cinq (5) mines ont été sélectionnées afin de comparer les environnements : Laronde, Géant-Dormant, Niobec, Mouska et Doyon. À chacune des mines, trois (3) endroits ont été étudiés. Les résultats préliminaires démontrent une grande variabilité des conditions d?une mine à l?autre ainsi qu?à l?intérieur même d?une mine. La minéralogie des roches et du gisement influence la composition des eaux souterraines et la présence des sulfures joue un rôle important sur l?agressivité de l?eau et de l?air des mines de l?étude. Afin de déterminer le potentiel de corrosivité, plusieurs paramètres doivent être considérés et la mine doit être zonée selon l?agressivité des endroits.

Feb 1, 2008

By J. A. MacLellan

"CONSTRUCI'ION OF SHERRITT'S CONCENTRATORSSherritt Gordon is operating two mills north of the 56th parallel, and is presently engaged in building a third. The author was closely involved in the design and construction of all three of these concentrators.The Lynn mill is the oldest of these three concentrators-it is a 4,000 ton per day nickel-copper plant built in 1953. The Fox mill is a 3,000 ton per day copper-zinc concentrator built in 1970. The Ruttan mill will be a 10,000 ton per day copper-zinc plant scheduled to go on line in July 1973.LYNN MILL The Lynn mill including the crushing, concentrating, drying and load out plant is about 69,700 square feet or 17.4 square feet per ton per day. '!his plant was originally built in 1927 at Sherridon, 150 miles south of Lynn Lake, as a 2,000 ton per day copper-zinc plant. In 1952 the plant was moved by tractor train to Lynn Lake. The whole plant was re-oriented within the original perimeter walls as a 2,000 ton per day nickel-copper plant. This plant was expanded to 4,000 tons per day by the addition of t1-Jo rod mills and a 5-1/2 short head crusher in 1959.The Sherridon mill processed its last ore in Sherridon in September 1951 and the first load of nickel concentrate was loaded at Lynn Lake on November 9, 1953 when the railroad arrived at Lynn Lake.The site for the Lynn Lake mill was cleared of overburden in the summer of 1952 and foundations for structural steel and SO!l8 equipment foundations were poured the late summer and fall of 1952 • Steel was erected from January to June 1953. Most of the equipment came in from January to March of 1953 by tractor sleighs. Sane sleighs upset but no equipment was lest through the ice."

Jan 1, 1972

By P. K. Kaiser, S. Maloney, S. Yazici

"This paper focusses on the strength or capacity of cable bolts and introduces a new perspective for cable bolt design by demonstrating that mining-induced stress changes may affect cables in a detrimental manner. The concept underlying a novel cable bolt pull-out resistanceor bond capacity model is described and its practical significance is demonstrated by application to a simple two dimensional scenario of a fall-of-ground.A number of practical implications emerging from the application of this model are discussed to provide guidance to ground control personnel jar improving cable bolt support systems in mining applications. These include cable layout optimization, use of cable pre-reinforcements, assessment of embedment length requirements, need for plated cables (or straps), use of bird-caged cables (or buttons), and grout quality issues.IntroductionDuring the last decade, cable bolting has become a standard support technique in mining for handling wide spans, reinforcing are passes, preventing or reducing dilution of ore in marginally stable stopes, and for many other rock support need s.In its infancy, many deficiencies in cable bolt supports resulted from improper installation techniques and, in particular, grout quality control problems and the use of empty breather tubes (Goris, 1990). The development of special grout pumps and fail proof placement procedures (Oliver, 1992; Bourchier and O'Flaherty, 1992) have eliminated many of these early problems. Nevertheless, there are still situations where cables seem to lose their capacity during mining, and in these cases the cables do not provide the expected and needed ground support. In some instances, cables perform extremely well, whereas in others the same support layout and quality of support installation seem to be insufficient, allowing falls-of-ground or progressive cavings to occur."

Jan 1, 1992

By A. Mazhary

"Although sensor-based ore sorting has gained significant attention recently, sorting gold deposits still face a high level of skepticism by gold mining companies. In order to shed some light on the matter, this article looks at two different gold deposits that were examined using X-ray Fluorescence, Electromagnetic and X-ray Transmission sensors. The heterogeneity of each sample is measured based on the assay results of each particle and is related to its sortability. Multivariate linear regression analysis was also performed on the XRF results to find potential proxy elements for detecting gold. The results from these deposits were varied and each sample showed different levels of sortability. While both X-ray sensors proved efficient for different deposits, the electromagnetic sensor failed to produce any promising results. Despite unsatisfactory result for one sample, this technology can have significant advantages in terms of lowering the operational costs and improving head grades and recoveries providing that the deposit is amenable to such separation methods. Therefore, it is important to mention that sensor-based ore sorting is ore and sensor dependent, and as a result, it cannot be applied and be beneficial to all deposits. Therefore, amenability tests are required in order to examine the potential for sensor-based ore sorting before one can reject the idea.INTRODUCTION Although sensor-based ore sorting has gained significant attention recently, sorting gold deposits still face a high level of skepticism by gold mining companies. Except for a few cases presented previously, no new case studies have been published. Previously, mines such as Kloof Gold Mine in South Africa used an optical sorter to sort their waste stockpile in 2003–2004 (Von Ketelhodt, 2009) and then again in 2009 (Von Ketelhodt, Falcon, & Falcon, 2011). More recently, Coeur Operations utilized an XRT sorter for their Kensington Mine in Alaska (Lasley, 2014) and also Anglo-American Platinum used an XRF sorter to pre-concentrate Platinum Group Metals through an algorithm that used chrome, copper and nickel as proxies (Rule, Fouchee, & Swart, 2015)."

Jan 1, 2017

By C. Bernier

This paper deals with three major problems associated with mining operations during the winter. These are the maintenance of the cooling systems of diesel engines, the high incidence of hydraulic dump failures on packaging machines, and the build-up of frozen fines on wet-ore conveyor belts.

Jan 1, 1966

By Marc C. Bétournay

"Surface crown pillars, acting to safely protect underground workers and operations from surface elements, are recognized, herein, as distinct from conventional deeper underground pillars. Moreover, because of the variation in mining and geological conditions that exist from mine site to mine site, each case is viewed as unique. A review of numerous case studies and existing literature indicates that there is little general information or systematic problem-solving approach associated with them.A design process, not unlike that of other engineering disciplines, is presented to correct these deficiencies. As part of its purpose, it will inform operators of the key elements required for design and will address the problems of these appendages. The design, while taking into consideration possible surface crown pillar settings and inherent characteristics, is founded on a step-by-step procedure starting with site investigations through to monitoring or pillar recovery. The process is flexible, in that it incorporates decision making and changes in mining strategy. The purpose of each step is explained and each step is extensively described in terms of the required equipment and methods for field work, analysis and support measures. Analytical formulae and studies from several fields directly applicable to surface crown pillars are also given. Recommendations for future research studies are presented."

Jan 1, 1987

By F. G. Vetsch, F. A. Ronaghan

"Introduction1N THE FALL of 1951, Peace River Allied Fort St. John No. 1 well was drilled in Lsd. 1, Section 9 Township 83, Range 18, West of the 6th Meridian, on the flats of the north side of Peace river, six miles southeast of the village of Fort St. John, B.C. During this operation, non-commercial shows gas in three zones and of oil in one zone were obtained during the drill-stem tests. Further geological study indicated that this well was on the southeastern edge of the Fort St. St. John structure.Pacific Fort St. John No. 4, drilled shortly afterwards, obtained possible commercial gas flows on drill-stem test in five zones and thus encouraged development of what has become Canada's largest multizone gas field.In general, the productive horizons in this area possess fair per-meabilities and high porosities, a combination which provides for high reserves and moderate productivities. Development to date has therefore stressed experimental techniques in drilling and completion practice to provide high deliverability wells.Data and information of a specific nature apply, in all cases, to the pools in the Fort St. John structure."

Jan 1, 1954

By Pizhi Zhao, Jingwei Zhao, Zhenshan Liu, Yiheng Cao

"A new Al-Mg-Si-Zn alloy designed for automotive outer panel was trial-produced with industrial procedure. The final product shows a strong planar anisotropy. X ray diffraction analysis shows such strong anisotropy is caused by the dominating cube texture component in the final product. The reason for such high cube texture component was investigated by tracing texture evolution starting from the hot roll slab. It is found that certain cube texture components already exists in the hot rolled slab. The density of cube texture component shows as a wavy change through the following1st cold rolling, inter-annealing, 2ndcold rolling and solution treatment. This study shows that the cold rolling in the laboratory can well represent the texture evolution during the industrial production. The results obtained by lab rolling hints that change of second cold rolling reduction has weak effect on the planar anisotropy, when the gauge of hot rolled slab and final sheet are fixed.INTRODUCTIONWith the rapid progress of light-weighting in the automotive industry, aluminum sheets get more and more application as closure panel and structure parts. Recently the dominating alloy for outer panel is 6xxx series, containing the main alloy elements Mg and Si. The popular gradesareAA6016,AA6111, AA6022, and AA6014. These alloys still cannot satisfy the various requirements from automotive manufacturers. Most suppliers of automotive aluminum sheets are developing their own specific grades according to the customer’s demand. To increase the baking response, anew Al-Mg-Si-Zn alloy was designed, concerning the high combination energy between Zn solutes and vacancies formed during the quenching stage of automotive sheet manufacture. This combination is helpful to the precipitation of ß”phase during the paint baking (Wang, 2015,2016; Yan, 2014).The plastic strain ratio (r value)is a key index of the formability of automotive body sheet. A high r value means a good formability. The r values in different directions can be used to evaluate the planar anisotropy of the metal sheets. The trial produced Al-Mg-Si-Zn sheet shows a strong planar anisotropy with respect to r values. Since the r value is tightly related with texture, the texture evolution from hot roll slab (HRS) to final T4P temper was analyzed with X ray diffraction (XRD) to find the reason for the high anisotropy. Besides, the cold rolling reduction (CRR) was varied in the laboratory to modify the texture distribution, i.e., the planar anisotropy."

Jan 1, 2018

By Jun Wang, Bo Zhang, Wenqing Qin, Guanzhou Qiu, Xiaozhen Ma, Key Lab of Biohydrometallurgy of Ministry of Education, Fen Jiao, Central South University, Yansheng Zhang

"Arsenic contained in minerals sulphides such as enargite and tennantite can represent not only a significant penalty element in base metals production, but also a disadvantage to the environment through producing the toxic emissions to the atmosphere. The achieving separation of arsenic bearing minerals either at an early stage in floatation or from the floatation concentration is significantly beneficial to the economic. However, there was no feasible commercial method of separation at the flotation stage because of its similar flotation properties with many other copper sulphides. In this work, the selective floatation of enargite from copper sulphide concentrate containing maily covllite, chalcoctie, bornite and enargite was investigated. A low arsenic concentrate with As 0.2%, Cu 22% and a high arsenic bulk concentrate with As 7.65%,Cu 33.65% were obtained. It was indicated that Ca(ClO)2 is the effective depressor and the optimum floatation condition was obtained. Most enargite could be floated at pH 11 and controlling the pulp potential at 290 mV SHE. Furthermore, the arsenic removal from the high arsenic bulk concentrate by hydrometallurgy methods was study. The results showed that the reaction temperature and the concentrations of NaOH were the most important variables affecting the rate of arsenic removal. A low arsenic concentrate with As 0.24%, Cu 37.80% was obtained in the optimum leaching condition.INTRODUCTIONArsenic is mainly produced as a by-product of base metals smelting, in particular copper concentrate. China has imposed an upper limit of 0.50% arsenic for concentrates entering (Long et al., 2012). Arsenic amount of copper concentrate within 0.40% has also been imposed in China, and above which will be introduced about 50 RMB penalties per ton for each 0.10% increasing by smelters now. Therefore, it is necessary to remove arsenic from the copper concentrate.In copper concentrate, arsenic is mainly in the form of arsenopyrite (FeAsS), enargite (Cu3AsS4) or tennantite (Cu12As4S13). There are two types of arsenic in the separation of copper and arsenic: arsenopyrite and arsenic bearing copper mineral. It is easier to separate arsenopyrite from the copper sulphide by flotation in comparsion with the separation of enargite or tennantite from non-arsenic copper minerals (Pineda et al., 2015). The main difficulty in the separation of arsenic copper mineral from non-arsenic copper sulphides is their extremely similar floatability, which depends on the fact that tennantite and enargite contain high copper content (Pineda et al., 2015)."

Jan 1, 2016

By B. A. Peppley

The current most common method of hydrogen production for fuel cell systems, including SOFC systems, is autothermal reforming. Autothermal reformers have a number of advantages including fast start up and load following and ease of control. However, there are a number of problems inherent with the addition of air into a system connected to the anode feed such as dilution of the fuel with nitrogen and the potential for oxygen to reach the anode chamber directly. Pure steam reforming, which does not involve air addition, provides a richer fuel mixture to the SOFC anode and is inherently safer than autothermal reforming. Although in theory pure steam reforming can be shown to provide these advantages, a number of technical problems need to be overcome before such a system can be practical. In particular, issues such as catalyst degradation due to poisoning and thermal sintering, coking, as well as fuel-steam mixing need to be addressed. Experimental results from a prototype reformer will be presented to illustrate a number of these points. This paper will compare differences in system efficiency, safety and complexity between autothermal/SOFC systems versus a steam reformer/SOFC system. A system simulation will be utilized that is able to account for material and energy balances for a SOFC power generator operating on diesel fuel. The requirements for improved catalysts will be discussed and an analysis of the potential benefits of sulfur tolerance and lower temperature activity will be considered.

Jan 1, 2005

By J. F. Wright

Gold-bearing quartz veins and replacement chalcopyrite deposits are the two important types of metallic mineral deposits of the east central Manitoba mining district. The gold-bearing veins occur along Manigotagan valley, northwest for 25 miles from Beresford lake, and the copper deposits along Oiseau valley, between Oiseau lake and the east end of Lac du Bonnet. Lithium-bearing minerals of possible commercial value have recently been discovered in pegmatite along Winnipeg river about 10 miles east of Point du Bois. There are also prospect pits with showings of galena, sphalerite, cobaltite, pentlandite, nickeliferous pyrrhotite, arsenopyrite, pyrite, molybdenite, cassiterite, and other minerals, but the various occurrences of these minerals, as exposed, are small. The bedrock and mineral deposits of this mining district are Precambrian and resemble in many respects the formations and mip.eral occurrences of western and northern Ontario. Although prospectors visited eastern Manitoba at intervals during the last fifty years, effective prospecting did not begin until 1913 or 1914, and not until 1923 were skilfully directed, systematic explorations undertaken. It is true, that between 1913 and 1923 considerable sums were expended in a number of attempts at mining and milling the gold-quartz ore, but these enterprises failed partly through poor management or attempts to develop veins that were too small or too low-grade to be worked at a profit under the existing conditions of transportation and power supply.

Jan 1, 1925

By E. R. Olson

The introduction gives not only a historical background but also touches on shaft sinking and surface construction and gives some general information on the Potash Conservation Regulations which the Saskatchewan government introduced in 1969. It also gives information on the corporate and local organization of Alwinsal Potash.

Jan 1, 1972

By Frank Cappuccitti, James A. Finch, Stéphanie Gélinas

"A colorimetric technique, originally developed for methyl iso butyl carbinol (MIBC) based on the Komarowsky reaction, has been extended to a wide range of common mineral flotation frothers. The procedure, which is briefly described, is shown suited to on-site determinations in a campaign at Kennecott Utah Copper Copperton Concentrator (Rio Tinto). Some observations are described, including: frother (MIBC) concentration evolution down a bank, frother distribution between pulp and froth phases, and loss of frother over time due to adsorption on certain minerals. A possible interference with a fuel oil addition was overcome. MIBC in recycle water was also measured.The ability to monitor frother easily will help interpret gas dispersion behaviour and should permit further optimization of flotation cell hydrodynamics and chemistry. The capability to directly measure should help optimize the type, amount and location of frother addition, and to assess frother recycled with reclaim process water.INTRODUCTIONOwing to the lack of analytical methods, the task of determining frother concentration in plant flotation circuits is not routinely performed. Industrial sites seldom outsource analyses that are both costly and inconvenient, due to the necessity of shipping freeze-dried samples to remote testing facilities. A more direct colorimetric method has recently been demonstrated for the laboratory characterization of common industrial frothers (Gélinas and Finch, 2004). The approach, based on the Komarowsky reaction (Penniman et al., 1936; Coles et al., 1942; Duke, 1947), was previously described by Parkhomovski et al. (1976) for methyl iso butyl carbinol (MIBC). The reaction involves the interaction of the OH group of a higher alcohol, concentrated sulphuric acid, and salicylaldehyde, to yield coloured solutions with intensities that can be analyzed by UV-visible spectrophotometry."

Jan 1, 2005