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By D. Mu

A method is presented for evaluating the effective gas diffusion coefficient of porous media. A series of random-distributed porous solids with different porosity are generated, a solution of the gas diffusion equations inside the porous media is obtained using the finite element method (FEM), and then the effective gas diffusivities are computed. The results show that there is a percolation threshold sp, and this percolation threshold decreases with an increase in the connectivity of the pore network; the relationship between the effective diffusivity and the porosity is strongly nonlinear when the porosity £ is less than about 0.2; and is quasi linear for higher porosities. The threshold decreases with increasing the connectivity of the pore network. A formula relating the effective diffusion coefficient with porosity is proposed.

Jan 1, 2005

By Xiong Tong, Jiushuai Deng, Yingbo Mao, Lingyun Huang

Ammonium carbamate has been used as a reagent for the leaching of copper from the copper oxide ore found in the Honghe state, Yunnan province, China. In order to find the optimal conditions for the leaching of copper from this copper oxide ore,the effects of several processing parameters, including the concentration, time, temperature, particle size and stirring intensity have been investigated. The results of these optimization experiments showed that the leaching rate of copper reached up to 72.76% under the following conditions: liquid-to-solid ratio of 10:1, ammonium carbamate concentration of 2.5mol/L, leaching temperature of 45 °C, stirring speed of 300rpm, a reaction time of 1.5 h and 85% by weight thereof passes through a sieve having 0.074 mm.

Jan 1, 2015

By Jose R. Hernandez-Aguilar

"This paper revisits data from previous studies (Hernandez-Aguilar, 2010, 2011) to better understand the link between metallurgical performance and pulp-zone bubble size (Db) in full-scale flotation systems. To obtain conclusive evidence exclusively related to the pulp (collection) zone, the experiments were designed in those studies to control both the bubble generation method and the influence of the froth zone on the overall metallurgical performance in industrial and pilot-scale flotation columns. The results showed that Db had a significantly larger effect on the recovery of coarse (> 75 µm) particles compared to the effect on fine (< 16 µm) particles. It was observed that, under certain practical conditions, the recovery of coarse particles was close to zero, but dramatically increased by reducing Db. The evidence revealed an inconsistency of the so-called “k–PSb” model: at constant froth recovery, increasing Sb (i.e., the rate of production of bubble surface area) did not always result in higher recovery, as the model predicts. Furthermore, the evidence showed that it was not the Sb but the bubble size that proved to be a more reliable link to metallurgical performance. Only in the presence of suboptimal-sized bubbles (Db > 2 mm) did the froth zone seem to play a role, possibly reflecting an effect of pulp-zone bubble size on froth stability. However, the role of the froth was negligible for Db < 1 mm.High-resolution mineralogical measurements performed on process samples revealed that, regardless of the degree of liberation, Db had a profound effect on the shape of the recovery-by-size curve, particularly the coarse particle size fraction. This observation is key as it implies that the loss in efficiency associated with floating the coarse particles was not the result of neither particle hydrophobicity nor particle detachment issues: even in the absence of mechanical agitation, liberated and highly hydrophobic coarse particles did not seem to attach to the bubbles in the first place, an inefficiency that was corrected by reducing bubble size. The data analysis suggests that poor attachment efficiency can practically affect both fine and coarse particles but via different mechanisms which are discussed here."

Jan 1, 2017

By S. Mostaghel, S. Nicol, M. Y. Solar

Once upon a time, the process engineer developing the design criteria for a new saprolite ferronickel smelter had it easy: most ores were around 2.5% Ni, with a Fe/Ni ratio of 4 to 5 and a SiO2/MgO ratio of about 1.6; to use the French word: garnierites. The ferronickel grade selected was the conventional 20 to 25% Ni and the impurity levels could be predicted from well established [C], [Cr] and [Si] vs (FeO) graphs. However the process engineer can no longer depend on statistics to design smelters: Ni grades are decreasing while the goethite contents are increasing; SiO2/MgO ratios vary from 1 to 3; and Al2O3 concentrations are reaching levels that cannot be ignored. Mechanistic models must be developed to select or predict essential parameters such as kiln and furnace reductions, ferronickel grade, slag losses, metal and slag liquidus, operating temperatures, etc. But these models must be simplified so that they can be used on a routine basis; and they must be calibrated against a wide range of commercial operations in order to yield the most realistic predictions possible. The present paper proposes one possible approach, using FactSage as a basic source of thermodynamic data. The predictions thus obtained are compared to actual performance for two well documented operations, as well as to the predictions made with other tools that might be more accessible.

Jan 1, 2014

By G. M. Ritcey, K. E. Haque, S. H. Lucas

"Laboratory-scale hydrochloric acid leach tests were conducted on an Elliot Lake uranium ore. Hydrochloric acid leaches without an oxidant or with molecular oxygen (i.e., air or pure oxygen gas) as an oxidant favoured uranium and radium extractions. Conditions for maximum uranium, thorium and radium extractions with hydrochloric acid in the presence of sodium chlorate were determined. The highest extractions of uranium (96%), thorium (81%) and radium (91%) were obtained using a mixture of 44.0 kg HCI and 2.5 kg NaCIOJ per tonne of ore at 75°C with 18 hours &apos; retention.Flowsheets for two-stage leaching are proposed. The residues obtained from the second-stage leach contain uranium (0.002%), thorium (0.006%) and radium (15 to 20 pCi/g). Tailings of this nature are considered suitable for mine backfill, and, if pyrite is removed, suitable for surfacedisposal.IntroductionThe nuclear energy industry forecasts an increasing demand for uranium. This increasing demand requires not only largescale mining and processing of conventional and complex uranium ores, but also leads to the consideration of new and nonconventional sources of uranium, e.g., black shales, phosphate rocks, granite, sea water and fossil-fuel ash.Sulphuric acid leaching is the most widely used process to extract uranium from the ore(l). The leach liquor is separated from the solids (tailings), purified, concentrated in various intermediate stages, and finally a semi-purified product, yellow cake (80-85070 U30 8) , is precipitated. The tailings, which constitute nearly 98% of the total bulk of most ores, are usually discarded in surface disposal areas.The Elliot Lake region of Ontario is one of the major uranium producing areas in Canada. The principal uranium minerals are brannerite and uraninite, present as microscopic grains in the matrix of quartz-pebble conglomerates. The average grade is between 0.10 and 0.15% UPs. Up to 6.5% pyrite is also present in the conglomerates. Because pyrite is less reactive toward sulphuric acid leaching, almost all the pyrite goes into the tailings and eventually into&apos; the disposal sites."

Jan 1, 1980

By W. H. Hastings

Introductory In the amount of her coal reserves, Saskatchewan ranks third among the provinces of the Dominion, with a total, as estimated by D. B. Dowling, of 59,812,000,000 tons. All the coal so far discovered in the Province is lignite, and it would appear unlikely that bituminous or higher grade coals exist. General Occurrence of the Coal The location of the coal-bearing formations in Saskatchewan is shown on the accompanying map. It will be seen that the areas lie principally in the southern part of the Province. The more darkly shaded areas indicate locations where development is taking place, or where coal-seams are known to occur, either through outcrops in valley-sides or through having been encountered during boring operations. The coal-seams are not necessarily continuous throughout the shaded areas, but in all pans of these there are coal possibilities. It is quite possible that small outliers of the coal-bearing formations may occur further north in the Province, but, generally speaking, coal is not likely to be found outside the shaded areas.

Jan 1, 1929

By Y. Nakamura, T. H. Okabe, S. A. Sunkar, K. Nose

Ruthenium (Ru) is known as a platinum group element with a very small production volume. In fact, the worldwide annual production of primary Ru metal is only about 20-30 tons, and it depends on the amount of Pt produced, since Ru is a byproduct from Pt smelting. The primary uses of Ru are as a material for resistors, as a catalyst for electrode materials, and as a sputtering target for hard disk memory storage. In order to recover Ru from the spent sand-blasting abrasive media generated during the cleaning of the apparatus used for Ru sputtering, a hydrometallurgical recovery process using hypochlorite solution has been investigated. In this study, various types of recycling processes that are presently under development are also introduced, and their features and differences are discussed. The advantages and disadvantages of the new recycling processes are evaluated, and the possibility of establishing new recycling processes in the future is discussed from a multilateral perspective.

Jan 1, 2014

"Cambior now holds a 49% interest in the Valdez Creek Placer, having acquired American Barrick&apos;s 23.125% interest in May 1990. At the same time, the company assumed the management of the operation and received environmental permits to divert the river. Plans are underway to divert the Valdez River in order to continue mining the deposit upstream, and to construct a new, higher capacity wash plant (by 60%) closer to the operations. Mining operations, which were suspended in October 1989 pending higher gold prices, resumed in August 1990. The mine is expected to produce 10000 ounces of gold in 1990and more than 80 000 ounces in 1991.IntroductionThe Valdez Creek Placer is located in the Valdez Creek mining district of Alaska on the western flank of the Clearwater mountain range, about 150 miles northeast of Anchorage by air (Fig. I) . The mine is accessible by air or by road.The mine is situated at an elevation of about 3000 ft and is isolated from towns and villages. Consequently, the mine site contains the facilities necessary to house and feed 135 people at any given time. The Valdez Creek Placer has 159 employees, including 130hourly and 29 salaried employees. The hourly employees are divided into three rotating teams. The daily schedule consists of two shifts of 12 hours, and each team works 14 days followed by seven days off, resulting in a weekly rotation of teams.The salaried employees work normal hours for ten consecutive days followed by four days off. A weekly rotation ensures continuity of services and management.Gold was first discovered at Valdez Creek in 1903, when a team of four men led by Peter Monahan left the village of Valdez to explore the area up the Susitna River, to the east of Mount McKinley. They discovered gold at the mouth of a creek that they immediately named Valdez Creek, in honour of their native town. In 1904, they discovered the Tammany Channel to the right of Valdez Creek. This was the beginning of a long period of mining in the area which continued until the beginning of World War II .In 1980, the Denali Mining Co. was formed. Geophysical work and drilling carried out through 1980 and 1981 led to the discovery of Channel A, a second channel which is older than the Tammany Channel. In 1983, Denali Mining optioned its claims to Camindex to explore, develop and mine the Valdez Creek property. A joint venture agreement was signed among Camindex, Talcorp, BCP Alaska (Barrick), Sum Resources (Cambior), Norfran and WGM to form Valdez Creek Mining Co., Inc., and production began in 1984. Valdez Creek Mining Co., Inc. (VCMC) was subsequently restructured and in 1989 was held by the following three companies: Camindex Mines Ltd. - 51070; Cambior Inc. - 25.875%; and American Barrick - 23.125%.VCMC is managed by a committee of the partners. Decisions made by the committee are subject to a 70% majority vote. Cambior receives its share of production in kind, and contributes in the same proportion to the expenses of the joint venture (VCMC)."

Jan 1, 1990

By L. H. Thorleifson

Demand for both gem and industrial diamonds is very strong. Synthetic production supplies industrial uses, but synthetic gems remain inferior and expensive, so the large gem market is supplied by mining. Several major mines have been depleted, and the market is receptive to new sources of high quality gems. Canada&apos;s Precambrian terrane, extending across the Canadian Shield and under the Phanerozoic cover of the Plains and Hudson Bay, has excellent potential for diamonds, but exploration conditions are difficult due to recent glaciation. Early world exploration relying on recognition of diamond in alluvial sediments was adequate to launch pre- 1900 production from India, Brazil, and Africa. Exploration success in Canada, as was the case in Russia and other more recently discovered sources, however, had to await large investments in effort supported by advanced science and technology. Canadian exploration in many ways is similar to that in other regions, relying on analysis of tectonics, indicator minerals, geophysical surveys, and multiple stages of drilling and sampling. Very different from other regions, however, is Canada&apos;s surficial environment, in which recent glaciation has caused fresh indicator minerals to be transported hundreds of km. Exploration accelerated in Canada after 1960, first in Ontario and the Arctic Islands, then in Saskatchewan in 1988, and most importantly after the Chuck Fipke - Stew Blusson discovery at Lac de Gras, Northwest Territories, in 1991 that led to the billion-dollar BHP - Dia Met Ekati Mine that opened in 1998. In 2003, production from Ekati will be supplemented by that from the similar and nearby Diavik Mine of Rio Tinto and Aber. These mines will bring Canadian output to over 10% of world supply, and will position Canada with Botswana and Russia as world leaders in production of high quality gem diamonds. There could be other mines as well, as sites across the Arctic and in the south from Alberta to Québec are being explored by an array of companies, including De Beers, other majors, and several juniors.

May 1, 2003

By Michael G. Nelson

Control of the feed provided to mineral processing facilities is a continuing challenge. Much effort is currently being devoted to overcoming these problems. These projects are usually described under the general headings of Mine-to-Mill Integration or Mine-Mill Optimization. It should be possible to combine the knowledge of ore type, mineralogy, and other characteristics (located in the mine modelling system), with the advanced capabilities of state-of-the-art mill control systems, to achieve an improved level of control in mineral processing, allowing optimization of the mill processes on an almost realtime basis. This is not happening because mill feed it is often treated as a uniform material, when in reality it varies in composition and characteristics. The University of Utah is investigating the use of odor sensors for maintaining traceability in ore production and processing. Odor sensors now used in food processing, environmental monitoring, and other applications can detect the presence of very small amounts (0.1 - 500 ppm) of some molecules. An assortment of such molecules could be used to ?tag? blocks of ore as they are mined, according to their respective characteristics. Then, as the ore came into the mill, an array of ?electronic noses? could be used to assess its characteristics in real time.

May 1, 2004

By G. K. Lee, Whaley. H., F. D. Friedrich, I. C. G. Ogle

"IntroductionCurrent coal combustion activities at the Canadian Combustion Research Laboratory (CCRL) reflect the increasingly important contribution that coal is expected to make in meeting our future energy requirements and in reducing our dependence on foreign oil. Widespread use of coal will, however, be heavily dependent on the ability of conventional and emerging combustion systems to cope with the disruptive conflicts caused by variations in fuel quality, on requirements for better equipment availability .and on the implementation of progressively more stringent environmental constraints.To minimize these conflicts, Energy, Mines and Resources Canada has embarked on a systematic sequence of research, development and demonstration- scale (R, D and D) initiatives to stimulate the utilization and competitiveness of thermal coal in both domestic and export markets through a number of complementary in-house projects and external contracts, considered to have short- to intermediate-term benefits to industry and society.Many of the in-house projects are funded in part by industry, whereas the external contracts are either fully funded (100070 government funding) or jointly funded (50% government - 50% project proposer).External contracts and shared-cost projects are an important adjunct to the CCRL in-house effort on coal combustion, because research data can be more effectively transferred to industry and because the commercialization of novel combustion systems can be accelerated significantly."

Jan 1, 1980

By Mel Torrie

1 Want access to low level vehicle data so 3rd party apps can be applied as desired 2 Hardware Agnostic (COTS plug and play) 3 Common/Open protocols that facilitate integration and the coexistence of a variety of applications on a variety of equipment 4 Minimum computer hardware footprint 5 Technology Independence (including comm. backbone)

May 1, 2013

By Ahmad Ghahreman, Lin Li

Silver and cupric ions have been proven to play the roles of catalysts to promote the oxidation kinetics of chalcopyrite in acid solution. In this study, the interaction between silver ions and cupric ions during ferric leaching of chalcopyrite in sulfuric acid solution has been investigated. The electrochemical study by Tafel analysis showed a significant boost of dissolution rate for chalcopyrite dissolution in Fe3+- Cu2+ containing sulfuric acid solution after Ag+ was added in the solution. For 10 ppm Ag addition, the dissolution rate of chalcopyrite increased to 7.94 ×10-6 A/cm2 from 3.2 ×10-7 A/cm2, when Ag+ was absent. On the other hand, the effect of Cu2+ on the dissolution of chalcopyrite in Fe3+-Ag+ containing sulfuric acid solution was not obvious from electrochemical measurements. The chalcopyrite leaching tests in different acid solutions showed that silver addition had an obvious catalytic effect on promoting chalcopyrite dissolution. Comparing the leaching rates of chalcopyrite leached in Fe3+ containing, Fe3+-Ag+ containing, Fe3+-Cu2+ containing and Fe3+-Cu2+-Ag+ containing sulfuric acid solutions, it was found in Ag+-Fe3+-Cu2+ containing sulfuric acid solution, the leaching rate was highest among all the aqueous acid systems. Further leaching tests suggested that with increase of the Ag+ concentration from 0 to 20 ppm, the leaching rate of chalcopyrite in Ag+-Fe3+-Cu2+ containing sulfuric acid solution also increased and reached 57.62% with 20 ppm Ag+ addition after 24 h. INTRODUCTION Chalcopyrite is the most important copper mineral in copper hydrometallurgy and it accounts for nearly 80% of the universal copper resource (Olvera, Rebolledo, Mora, Dixon, & Asselin, 2018). The hydrometallurgy of chalcopyrite has been intensively studied with emphasis on solving the slow dissolution kinetics of chalcopyrite in acid environment. A variety of aqueous systems, such as sulfate (Hiroyoshi, Miki, Hirajima, & Tsunekawa, 2001), chlorides (Liu, Chen, & Yang, 2017), and ammonia (Hua et al., 2018) have been studied to improve copper leaching. From another perspective, chalcopyrite leaching studies have indicated that the mechanism of chalcopyrite dissolution in acid solution is essentially electrochemical (Li, Kawashima, Li, Chandra, & Gerson, 2013). Therefore, extensive studies have recently been carried out to explain the dissolution kinetics of chalcopyrite in different media by various electrochemical techniques.

Jan 1, 2019

By R. Heikkilä

In this paper the utilisation of building information models (BIM) and construction automation on building sites is discussed. A lot of research has been carried out to develop new applications for using BIM to assist construction site planning, different operations and logistics. The methods of production control and management on site utilize BIM together with machine control and navigation systems. In Finland machine control systems and the automation of construction equipment is widely used in infrastructure construction. Recently similar methods have been introduced also in building construction. This paper describes some latest Finnish examples where BIM-software is used for the planning, execution and control of building construction operations. University of Oulu has studied methods and technologies to capitalize BIM-models. The research has been mainly in infrastructure construction but the activities have recently been extended to building construction. In this paper a BIM-based tower crane operation and control system is discussed as a case study. The aim of this study was to highlight the potential areas were automation can increase the crane productivity and improve site operations and logistics. The construction site managers and tower crane operators interviewed in this study were experienced in using BIM-models on site.

Aug 1, 2013

By J. Visman

The water cyclone washer has a number of advantages that makes it a desirable machine for the cleaning of fine-grained and friable materials such as 1,4 x 0" slack coals. In this paper results are presented of tests carried out on a shaly coal containing a high percentage of inter-grown materials from the Minto area, New Brunswick. The tests were con-ducted in the pilot plant of the Western Regional Laboratory in Edmonton. The test results show that the cleaning characteristics of this coal can be improved by lightly grinding the recirculating middlings fraction, which constitutes approximately 30 per cent (1.45-2.00 fraction) of the raw feed. • The cleaning of 1;4 x 0" fines by water cyclones compares favourably with other coal cleaning machines and has an added advantage of being extremely simple to operate, low in capital and operating cost, and high in capacity. The application of water cy-clones dates back approximately ten years, following its development at the Dutch State Mines. ( 3) A number of papers published d

Jan 1, 1961

By Benedetto Corain

The production and dispersion of metal nanoclusters onto inorganic supports and amorphous carbon rest on well consolidated technologies belonging to the realm of industrial catalysis and of basic catalysis research (1). In spite of the existence of a variety of specific synthetic strategies, their very rationale relies on three main approaches i. e.: A: precursors of both the metal nanoparticles and of the relevant supports (or the support itself) are intimately mixed (even let to react) at ambient conditions and then thermo-reduced according to very controlled protocols (2); B: precursors of metal nanoclusters are let to be adsorbed onto suitable supports from the gas or liquid phase and subsequently thermally decomposed (3); C: metastable size-controlled metal nanoclusters are previously generated in a liquid medium and subsequently transferred onto pre-formed support particles (4). The production and dispersion of metal nanoclusters onto organic soluble supports is also a rather well documented academic praxis (5, 6, 7, 8) able to provide e.g. size-controlled Au0 nanoclusters of 4.4±1.7 nm (5). Our group started in 1997 developing (9) an innovative approach to the synthesis of metal nanoclusters dispersed inside insoluble, albeit accessible (see below) mechanically robust gel-type resins (10), which procedure was tested so far on palladium metal. Metal ions are previously dispersed upon ion-exchange inside of the polymer framework, followed by chemical reduction and by the aggregation of born metal atoms into nanoclusters, the size of which is templated (11, 12) by the three-dimensional intercommunicating meshes that build up the overall polymer framework (Figure 1).

Oct 1, 2003

By A. N. Shen

Fe3A1 intermetallics are potential inexpensive candidate for hot applications. In this project, torsion tests on hot-rolled and annealed Fe3A1 (Fe-15.5A1-5.8Cr-1.0Nb¬0.05C) were carried out over the ranges 750-950°C and 0.01~1s-1 . The experimental results showed that when peak stress op>90MPa (LogZ>16s-1 , Z: temperature-compensated strain rate), specimens cracked at randomly low strains. Optical microscopy exhibited original elongated grains and many grain boundary cracks associated with segregation. With op<40MPa (LogZ<16s-&apos;), specimens deformed with low random op but considerably high fracture strains; slowly propagating cracks may explain the reduced flow stress. Optical microscopy showed both elongated grains and equiaxed subgrains with some indications of geometric dynamic recrystallization (gDRX) and of static recrystallization (SRX). Compression tests gave higher stress with little effect of the preexisting cracks. The activation energy Quw of current material in satisfactory torsion and compression tests is about 10% higher than previously published. Fe3A1 has body-centered cubic structure in the experimental range, so it was compared with ferritic stainless steel 434C (Fe- 16.55Cr-0.96Mo-0.21Ni). Constitutive constants and restoration mechanism are compared between these materials. While Fe3A1 is hardly a light metal, it is considerably lighter than most steels. Furthermore, like the other body centered cubic metals (BCC) (a-Fe, ß-Ti, ß-Zr and ß-brass), it exhibits a high degree of dynamic recovery (DRV) like Al alloys, producing easier hot workability than that of austentic stainless steels.

Jan 1, 2007

By M. Rylatt, E. Legault-Seguin, C. Mohns

"With energy costs increasing and ore grades diminishing, the role of preconcentration in hard-rock mining operations has gained greater interest. Dense medium separation is a process that can be conducted at particle sizes from 250 to 0.50 mm with high separation efficiency, depending on liberation characteristics of the valuable minerals. Pilot-plant case studies conducted at the SGS Lakefield site are presented, including mineral systems such as spodumene, sulfide-bearing gold ores, and complex sulfide ores. These case studies demonstrate that, for amenable ores, mass rejection of 20–60% is possible while maintaining recoveries of greater than 90%.RÉSUMÉ Au vu de la hausse des coûts liés à l’énergie et du déclin de la teneur des minerais, le rôle de la préconcentration dans les exploitations minières en roche dure présente un intérêt croissant. La séparation (ou concentration) en milieu dense est un processus pouvant être mené sur des calibres de grains de 250 à 0.50 mm avec un rendement élevé de séparation, en fonction des caractéristiques de libération des constituants des minéraux métallifères. Sont présentées dans cet article des études de cas menées dans des usines pilotes du site de Lakefield de SGS, lesquelles incluent des systèmes de minéraux tels que le spodumène, les minerais aurifères sulfurés et les minerais sulfurés complexes. Ces études de cas montrent que pour les minerais présentant les caractéristiques de libération appropriées, il est possible d’atteindre un rejet en masse de 20 à 60 %, tout en maintenant des récupérations supérieures à 90 %.INTRODUCTIONPreconcentration is the process of rejecting gangue minerals while ensuring recovery of valuable minerals prior to more intensive, downstream processing. Preconcentration has been practiced in the industry for many years, and is gaining greater interest as the industry copes with processing lower grade, more difficult ores, which typically require finer grind sizes and incur higher energy costs.The benefits of preconcentration are:• lower mining costs, which allows for nonselective mining;• lower process capital and operating costs (e.g., resulting from reduced grinding, flotation, and fines disposal stages);• increased ore reserves, which provides the potential to treat lower grade ore;• increased mine production without expansion of the existing plant or concentrator;• reduced overall tailings impoundment by converting the reject into a byproduct (e.g., underground backfill or aggregate);• improved efficiency of downstream processes (e.g., silica removal in electric arc furnace feed, removal of softer sliming minerals prior to grinding);• potential application to brownfield operations and greenfield projects; and• a “green” process option, which reduces processing energy consumption;– reduces mill feed;– increases stage metal recovery (higher grade feed);– increases mill metal output per tonne processed;– reduces surface plant, tailings dump, and tailings pond requirements because the plant has a small footprint and can be installed underground; and– can be applied to retreatment of old tailings dumps to recover metal values and reduce environmental impacts (e.g., dissolved metal runoff, acid drainage)."

Jan 1, 2017

By M. Hamamoto, M. Furuta, S. Tanaka

The Tamano smelter and refinery has expanded its production from 228kt/y to 260kt/y since 2006. It was not a big jump, but efficient and economical improvements were executed. These were not only de-bottlenecking and modernization of the smelting plant, including the acid plant, but also additional processes were commissioned, e.g. slag cleaning furnace and steam dryer. On the other hand, a conversion to permanent cathode process in the #2 tank house made the biggest impact on production efficiency for the refinery plant. In order to overcome the drastic change of copper business, although each scale is not so big, continuous improvements are very important to survive. This paper mainly describes the recent improvements of the smelting plant.

Jan 1, 2007

By K. Kryst, K. Elkayar

The increasing need to process lower grade contaminated copper concentrates and simultaneously produce higher purity copper cathodes necessitates a more diligent control in the electrorefining process. Ion exchange processes can be a powerful tool in controlling electrolyte impurities to ensure trouble free operation within the tankhouse and to help maintain cathode purity. In addition, some impurities can be recovered as a value added product. The use of a short bed ion exchange process provides a unique opportunity for impurity management in copper refineries. Several metals are discussed in this paper, including Sb, Bi, As and Ni and their methods of control and recovery within the copper electrolyte circuit. INTRODUCTION To produce a high purity copper product by electro-refining a copper electrolyte, it is important to control the concentration of impurities such as arsenic (As), bismuth (Bi), antimony (Sb), and nickel (Ni). These impurities are introduced into the electrolyte from the copper anode and can affect the copper product and the production operation. The presence of As in the copper product results in a lower electric conductivity and reduced workability of the copper. High levels of Bi in the electrolyte will result in a copper cathode product containing Bi. High Sb concentration will cause undesired floating slimes. A variety of methods have been developed to control the level of these impurities in the copper electrolyte including precipitation, liquid extraction, and ion exchange. These impurities can be recovered and used. This paper discusses novel methods that utilize short bed ion exchange technology to control these impurities. Also, the use of ion exchange to recover acid from the liberator cells bleed for reuse in the tankhouse is reviewed. SHORT BED ION EXCHANGE Short bed ion exchange technology has been employed extensively in the metal finishing industries for over forty years. Unlike conventional ion exchange, short beds are fixed beds without freeboard space. The application of short bed technology results in significant benefits when compared to conventional ion exchange. The resin used in this technology has a significantly smaller diameter than conventional ion exchange resin. As a result of the smaller resin size, exchange kinetics improves dramatically. This facilitates operation at higher flow rates and the use of smaller beds with a small mass transfer zone length. Smaller beds are especially important for applications that use chelating resins due to the high cost of the resin.

Jan 1, 2019