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By K. Parameswaran

This paper builds on presentations made at the Conference of Metallurgists (COM) 2015, COM 2017 and Extraction 2018 and associated papers published in the respective conference proceedings. Based on the classic Brundtland Commission definition of sustainable development as “development that meets the needs of the present without compromising the ability of future generations to meet their own needs,” the paper describes how metal mining can be compatible with sustainable development and how sustainability considerations have been applied in the primary copper industry, using several examples of sustainable mining practices from ASARCO LLC operations. Finally, the paper discusses how these considerations might be used in the future by discussing the need for developing a sustainable development strategy and how this strategy can be aligned with the United Nations Sustainable Development Goals. INTRODUCTION The primary copper industry comprises: mining (also referred to as “extraction”); mineral processing (also referred to as “beneficiation, “milling” or “concentration,”) which includes leaching, solvent extraction (SX), crushing, grinding, froth and flotation operations; and metallurgical processing which includes smelting and converting; refining, which includes fire-refining or anode refining and electro-refining; and electrowinning (EW). There are two routes for producing refined copper: hydrometallurgical and pyrometallurgical. The hydrometallurgical route comprises mining (open-pit and underground), mineral processing (crushing and grinding — for heap leaching only; leaching and SX) and metallurgical processing (EW). The pyrometallurgical route involves mining, mineral processing (crushing, grinding and froth flotation) and metallurgical processing (smelting, fire refining and electro- refining). The primary copper industry is capital, water, resource and energy intensive with the potential for significant environmental impacts, if the environmental aspects are not properly managed. ASARCO LLC (Asarco) was organized in 1899 as the American Smelting And Refining Company. Originally a consolidation of several lead-silver smelting companies, it evolved over the years into an integrated producer of primary non-ferrous metals, including copper, lead and zinc and associated co-products. Grupo México, S.A.B. de C.V (Grupo México) acquired Asarco in 1999. Today, Asarco is a vertically integrated producer of primary refined copper and associated co-products such as gold, silver, selenium and tellurium. Asarco operates three open-pit mines and mills, two leach, SX-EW plants, a copper smelter in Arizona and a copper electrolytic refinery in Texas.

Jan 1, 2019

By Cheryl Devine, Radhakrishnan Mahadevan, Vladimiros G. Papangelakis, Srinath Garg

The microbial-mediated recovery of valuable metals locked in mining wastes presents an economical alternative to conventional hydrometallurgical processes. The present study investigated the bioleaching response of a low-grade nickeliferous pyrrhotite tailings (0.6 wt% Ni) and an upgraded pyrrhotite tailings (1 wt% Ni) produced by Vale Base Metals in the Sudbury Basin of Ontario, with the ultimate aim of maximizing Ni recovery. The initial part of the study focused on the bacterial adaptive evolution protocol, by repeatedly sub-culturing an indigenous culture from an acid mine drainage site on 2% (w/v) pyrrhotite tailings. The results showed that the extent of Ni dissolution is positively correlated with microbial activity. Microbial profiling revealed A. ferroxidans to be the dominant member of the microbial consortium. The enriched culture was used for optimizing the growth medium by varying the concentration of essential growth nutrients. Finally, an aerated biotic and abiotic leach of a 10% (w/v) upgraded pyrrhotite tailings with and without pH control, showed a higher recovery of Ni in the pH controlled experiments. These results demonstrate that a high concentration of the oxidant Fe3+ in solution promotes the dissolution of Ni. Furthermore, the sulphide conversion into So was found to be higher in the pH controlled experiments (32%), relative to the experiment without pH control (10%).

Jan 1, 2015

By Manuel Sanchez, Marcial Medina, Matt Hurley, Hugo Granados, Pramod Kumar, Raj Rajamani, Jose A. Delgadillo

"Large-diameter ball mills have traditionally used steel liners—steel being a highly durable material that can be shaped into any desired geometry, among which the double-wave has been the preferred design. Such a design produces a purely cascading charge motion, which is ideal for the shearing action needed to produce a finer product. Today, however, rubber liners, which have been in existence for over forty years, are now preferred over traditional steel, largely because they weigh less and are easier to maintain. In this paper, we show the operating data from the Hudbay Minerals’ Constancia Mine, wherein the liners on a 26-by-40-foot mill were changed from conventional steel liners to PolyStl™ liners. It is then shown that this change reduced the amount of energy consumed whilst being able to maintain previous grind and throughput levels. The design is verified via discrete element simulations.IntroductionThe Constancia Mine (“Our Business: Peru,” 2016) is located in the southeastern Andes of Peru, at an elevation of approximately 4,200 m. It can be accessed via the CU-126 road, about 95 km from the town of Espinar in Espinar Province. The mine also contains both the Constancia and Pampacancha deposits in the Province of Chumbivilcas. Hudbay Minerals, Inc. acquired the mine in 2011, through the purchase of Norsemont Mining, Inc. and currently retains sole ownership of the property. Production of the Constancia Mine began in 2014, with commercial production levels being achieved in April 2015.The Constancia and Pampacancha deposits primarily include hypogene, supergene, and skarn ores. The Mine’s main products, however, are copper concentrate, with silver contents, and molybdenum concentrate. These mineral reserves are expected to last approximately 22 years. Constancia’s open-pit mine supplies a processing plant that is designed for 81,900 metric tons per day of throughput. Average annual copper production is estimated to be 82,000 mT (contained metal in concentrate). Actual plant production can be found in Table 1."

Jan 1, 2017

By James L. Parks, David M. Kjos

"Significant increases in mill liner life and plant availability can be achieved by following guidelines that have evolved from over twenty years of practical experience with autogenous grinding (A0) and semi-autogenous grinding (SA0) mills. A0 and SA0 mill liner functions, performance criteria, designs, wear-resistant materials and maintenance procedures are reviewed. Operating practices that can lead to accelerated wear and breakage are discussed.IntroductionEfforts to improve the performance of liners for autogenous grinding (AG) and semi-autogenous grinding (SAG) mills began as soon as the modern, large-diameter versions of these comminution machines were first intalled in commercial plants twenty years ago . While concentrators with conventional circuits were typically running at 95010 or better mill availability, many of the new autogenous and semi-autogenous circuits were struggling to achieve 80% availability. Liner maintenance, which involves not only material and labour costs but also loss of production, was quickly identified as one of the major reasons for downtime.Today, liner designs and materials have evolved to the point where virtually maintenance-free liner life of two to three years is possible in autogenous mills and one year in the more severe operating conditions encountered in semi-autogenous mills. Of concern, however, is that hard-won lessons from the past sometimes seem to be forgotten or ignored during the design of new mills and the operation of existing mills. As liner suppliers, we are often confronted with performance problems that could have been avoided by applying well-publicized guidelines for liner design and materials selection.This paper provides an overview of AG and SAG mill liner functions, criteria for evaluating performance, designs, wear-resistant materials and maintenance procedures. Also, operating conditions that can lead to accelerated wear and liner breakage are discussed in detail."

Jan 1, 1990

By Steve Dismuke, Tom Diment

In December 1994, Polaris decided to investigate the use of cemented rockfill (CRF) to supplement the existing frozen rockfill system. Extraction plans for the remaining ore reserves required a backfill with superior stiffness proper-ties and capable of developing high early strengths. Although CRF has been used success-fully at several mining operations, there was the additional challenge of making a reliable cemented product in permafrost conditions. There was also the challenge of procuring and storing one year’s supply (13 000 tonnes) of bulk cement. By the spring of 1995, following three months of research, test work and process design, the decision was made to proceed with the procurement and construction of a 3000 tpd batch plant. An ambitious completion date of December 1995 was set. Team Manufacturing of Langley, British Columbia was awarded the contract, complete with the considerable task of having the batch plant fabricated and ready for sea lift shipment by August, 1995.

Jan 1, 1996

By K. L. Eastwood

The ISA PROCESSTM cathode plate is characterised by its copper coated suspension bar, coupled with a blade employing austenitic stainless steel alloy 316L. The blade material has become the mainstay of the technology and has been closely copied by competing cathode designs. Improvement to the cathode plate design remains a key area for research, and ongoing developments by Xstrata Technology's ISA PROCESSTM have recently been commercialised. Two such developments are the ISA Cathode BRTM and ISA 2000 AB Cathode. The ISA BR cathode is a lower resistance cathode that has proven to enhance operating efficiencies. The AB cathode was designed to improve stripping inefficiencies in the ISA 2000 technology. These developments have now had time to mature and their long term performance will be discussed. Rising material costs and the desire to extend the operating boundaries of the standard 316L cathode plate has triggered a number of significant advances. These involve the use of different stainless steels as alternatives in some operational situations. The technical aspects and results of commercial trials on this development will also be discussed in this paper.

Jan 1, 2007

By C. E. Cartwright

That the construction of the Pacific Great Eastern railway has not been accompanied by an immediate and great development of traffic is not due to lack of natural resources in the district traversed, but to conditions that have delayed their development. Prior to the commencement of construction of the railway there was no inducement to prospect for any other mineral than gold, on account of lack of transportation. The war began soon after the commencement of construction; diverting practically all capital that might have been available for opening up the country; and since the war, capital has continued shy of new investments. If the war had not occurred it is probable that prospecting and development would have been carried out concurrently with the railway construction. Moreover, much of the district is covered deeply with drift, marine and alluvial deposits, rendering prospecting for lode mines a more expensive and slower proceeding than can generally be undertaken by the ordinary prospector, without capital. On the other hand, the presence of large porphyry dykes, granitic intrusions, and the finding of rich float in places are indications that rich miIY.ral deposits probably exist in several localities in the Lillooet district, in the Cariboo proper, and also nearer the coast. Two or three mines producing the tonnage of the? Britannia would materially alter the earnings of the railway and pay interest on the bonds. There are, however, other possibilities, in addition to large metaliferous mines, in the non-metallic minerals of the district.

Jan 1, 1925

By C. C. Walden, D. W. Duncan, P. C. Trussell

Thiobacillus ferrooxidans released copper from -400-mesh chalcopyrite at a rate of 54 mg/I/hr. Any flotation chemicals remaining on the concentrate did not inhibit the leach rate. Zinc rougher tailings were also leachable. With bacteria, 75 per cent of the zinc and 68 per cent of the copper came into solution. In the sterile controls, only 16 per cent of the zinc and 10 per cent of the copper were released; 100 per cent of the copper and 36 per cent of the zinc were leached from pyrite cinders through the action of bacteria, and 17 per cent of the copper and 10 per cent of the zinc were solubilized in the sterile controls. Less than 0.027 per cent of ~he iron came into solution. The majority of the copper in a converter slag was acid-soluble, but a reverberatory slag responded to microbiological leaching. About 62 per cent of the copper came into solution, compared to 12 per cent in the sterile control. The various factors influencing the rate and extent of microbiological leaching are discussed.

Jan 1, 1966

By A. P. Paiva

The solvent extraction properties exhibited by some /V,N'-tetrasubstituted malonamides to efficiently and selectively recover iron(III) from concentrated chloride leaching solutions can be found in the recent literature. The iron(III) extractive chemistry exhibited by some of these derivatives is revisited, in order to compare their chemistry with that shown by a few of the new malonamide compounds. The generally good extraction efficiency towards Fe(III), from >4 M hydrochloric acid solutions, and the relative ease of Fe(III) stripping by distilled water are remarkable findings that are confirmed for the malonamide derivatives described in this work. Furthermore, additional data regarding their selectivity towards Fe(III) extraction over several base metal ions and their behavior when subjected to successive Fe(III) extraction-stripping tests are also presented and discussed.

Jan 1, 2006

By M. du Plessis, D. F. Malan

"Crush pillars are designed to be in a crushed state whilst being formed at the mining face. The residual stress state of these failed pillars provides a local support function in mining stopes and is used in the majority of the intermediate depth South African platinum mines. On mines utilising crush pillars, the pillar dimensions are selected to achieve a width to height ratio of approximately two. This is not achieved in most cases as a result of practical mining problems and poor pillar-cutting discipline. Furthermore, pillar dimensions are seldom adjusted to compensate for the various factors governing crush pillar behaviour. The pillars should, however, be in a crushed state whilst being formed or whilst still in close proximity to the mining face to prevent potential damaging seismicity.An underground investigation was conducted into the behaviour of the crush pillars in a trial site on the Merensky Reef at Lonmin Plc. The aim of this investigation was to examine the mechanism of pillar crushing and the related rock mass behaviour. The underground test results and pillar behaviour are compared to a limit equilibrium model to investigate if the model provides a useful approximation of the behaviour of the crush pillars. This paper details some of the preliminary findings.INTRODUCTIONOn most mining operations, the design of crush pillars is based on trial and error. As the pillar strength is unknown, the pillar sizes are adjusted to obtain the correct behaviour. Crush pillar dimensions are generally selected to give a width to height ratio (w:h) of approximately 2:1, (Ryder and Jager, 2002). Several factors affect the behaviour of the crush pillars and in many cases satisfactory pillar crushing is not achieved. This results in a seismic hazard in many of the mines using crush pillars. If pillar crushing is not initiated whilst the pillar is being formed at the mining face, as the mining face advances and the pillars move to the back area of a stope, some pillars may burst while oversized pillars may punch into the footwall. If pillars are designed in such a way that they are fractured during cutting by the face abutment stresses so that the pillars will already have yielded and reached their residual strength, further compression of the pillars will be associated with an increase in load and stability will be ensured, (Ozbay and Roberts, 1988). The stiffness of the strata must therefore be greater than the post-peak stiffness of the pillar (Figure 1) or violent pillar failure and hanging wall instability will occur. The pillar design should be aimed at determining pillar dimensions for which the post-peak curve of the pillar is as flat as possible."

Jan 1, 2015

By David W. Smith

"This paper is devoted mainly to a discussion of the hydrocarbon potential of the offshore, with a few brief remarks concerning the inorganic mineral potential.OFFSHORE OIL AND GAS POTENTIALIN ORDER TO HAVE HYDROCARBON ACCUMULATIONS, we must satisfy three basic requirements. First, we re-quire a sufficient thickness of sedimentary rocks which contain some porous and permeable formations to act as reservoirs. Second, we require some type of trapping mechanism, such as faulting, folding or stratigraphie trapping. Finally, we require that large quantities of hydrocarbons have been generated within the sedimentary rocks and have migrated to the traps."

Jan 1, 1969

By L. Iacopetti, A. Calderara, M. Perego, P. Perrone, T. Furusawa

De Nora, a global leader in the development, manufacture and sale of all DSA® anodes based on titanium coated with mixed metal oxide (MMO) for electrochemical processes will present key advancements made to Self-Protected Anodes (SPA) for metal electrowinning. (DSA® is a registered trademark of Industrie De Nora S.p.A., Italy). In 2017 pre-commercial demonstration cells were operated in industrial environment. The program’s focus was to fully demonstrate the SPA anode’s superior mechanical and electrochemical robustness during normal and induced dendrite shorting occurrences while providing quality of plating in commercial operation. De Nora specialists focus on key components, in particular the engineering of the self-protection system, DSA® anodes and catalyst formulation capable to cope with high levels of pollutants while providing long service life in the meantime. Results of field trials confirmed the expected anode performance and enabled the selection of the most suitable “SPA” structure, based on resistive protective elements. Summarizing the economic benefits to copper electrowinning tankhouse operation with De Nora’s self- protected all DSA® anodes are; Double-digits power savings Cobalt-free electrolyte operations Minimal dendrite shorting damage incurred at the SPA anode Smoother, uniform cathode deposits with tangible improvement on current efficiency Tankhouse operations producing lead-free copper quality cathodes, in addition to elimination of lead waste for improved operator health and environment. INTRODUCTION De Nora’s engineered “Value Technology Package” (“VTP”) for electrowinning, consisting of our DSA® anodes coated with mixed metal oxide specifically formulated for copper electrowinning in conjunction with an advanced self-protected full titanium anode (“SPA”), underwent an intense field qualification program, inclusive of the behavior under massive short-circuits as part of the field investigation, with the goal to select and appoint the ultimate design configuration of “SPA”. Optimized wireless-based monitoring system was included in the field program, demonstrating good functionality for cell parameters monitoring and remote shorts detection.

Jan 1, 2019

By C. R. Edwards, D. G. Feasby

"Over the last 50 years disposal of uranium mill tailings has evolved from dumping untreated tailings into the nearest depression to depositing chemically-stabilized tailings into highly engineered management facilities. This paper describes the evolution of disposal methods and the criteria which have determined the development path followed. Remediation techniques to bring older and now unacceptable tailings deposits into satisfactory compliance with today's· regulations are reviewed.With the closure of the uranium mines in Elliot Lake, Ontario, considerable effort is being made on decommissioning the tailings areas by developing long term maintenance of water covers. The innovative methods being used to develop these water covers are detailed. Methods now under development in Saskatchewan for subaqueous deposition of high density or paste tailings for permanent disposal in mined out open pits are described.SummaryThe technology for uranium mill tailings disposal in Canada has evolved considerably over the past 51 years. This evolution has been driven by an improving understanding of how best to safely and permanently store tailings, in conjunction with stricter environmental protection regulations. Old sites are being decommissioned in situ, but may require long term care and maintenance. The use of water covers is an important technique in eastern Canada to prevent intrusion, radon evolution and, for the Elliot Lake tailings, acid generation. The major drawback of water covers in any above ground disposal method is the requirement that a long term maintenance and monitoring plan be put into effect for each site.New higher grade mines in Saskatchewan will increasingly use disposal in mined-out pits using the pervious surround method and/or paste tailings technology as a method to permanently dispose of these wastes and to permit “walkaway” after a few years of monitoring."

Jan 1, 1996

By N. E. Mkadmi

Backfilling increases the stability of underground stopes and may help reduce the environmental footprint from the mining operation. The barricades holding the backfill in place must be designed to prevent failure based on the total and effective stress states, which depend on fill properties, stope geometry, and filling rate. This paper presents results from a numerical study aimed at analyzing the stress states associated with the response of paste backfill following stope filling, with an emphasis on the short term behavior. The simulations illustrate how stresses evolve with backfill drainage and filling rate in a vertical stope.

May 1, 2011

By A. McIntyre, L. R. Plitt

Both the Bond and the Hardgrove grindability tests are widely used in the mineral industry to measure the ease of the comminution displayed by a material. The Hardgrove test is mainly used for coals, whereas the Bond grindabifity test is mainly applied to hardrock minerals. The Bond grindability has the advantage that it can be empirically related to the energy required for comminution (work index), whereas the Hardgrove grindabifity test has the advantage of being easier to perform. In an effort to establish a valid correlation between work index and Hardgrove grindability, a series of parallel grindability tests were carried out on a wide variety of rocks and minerals. The standard Hardgrove test was modified to allow for materials with a higher density than coal. A new, satisfactory relationship was established which permits rapid estimation of work index from Hardgrove test data.

Jan 1, 1980

By Andrew Bamber

Outline ?Background to Mine-Mill Research at UBC ?Mine Mill Integration ?In situ mining methods ?Underground Pre-concentration ?System Design and Supporting Technologies ?Case Studies: ?INCO -McCreedyEast Mine ?Placer Dome ?Porcupine JV ISL Study ?Musselwhite, South Deep ?Falconbridge ?Fraser Copper ?Thayer Lindsley ?Wayside Gold, other scoping studies? ?System Designs ?Summary ?Future work ?Conclusion

May 1, 2006

By R. K. Kandasami

"Naturally occurring geomaterials such as sandstone, limestone and other soft rocks, residual soils are composed of a particulates held together through a cohesive matrix, usually composed of argillaceous or siliceous cementing agents. Geo-materials such as these have been reconstituted in the laboratory using ordinary Portland cement in lieu of the naturally occurring cohesive matrix, in addition to using sand particulates. This cohesive frictional granular ensemble is an ideal model material for understanding the mechanical behaviour of transitional geomaterials such as soft rocks. An important consequence of this cohesion that pervades the inter particulate system is the enhanced tensile strength when compared to a purely granular ensemble. The assessment of strength of these soft rocks and cemented sands is often understood in the framework of continuum mechanics, i.e. considering the cemented sand to be a continuum, and performing simple elemental tests such as uniaxial compression or tension tests. A simple model to describe the behaviour of these cemented sands has been to use elements such as springs, sliders, and dashpots in parallel to describe the existence of a cohesive and frictional component of strength (Jiang et al. 2007). In the framework of continuum mechanics, the mechanical response of these cemented sands have been modeled using traditional plasticity theory, for example utilizing variants of the traditional Mohr Coulomb model, Modified cam clay (Sun and Matsuoka 1999) etc. The typical sand models are amended to include the effects of cohesion, as proposed by Lagoia and Nova (1995).The mechanical response of cemented sands is understood to be transitional to the behaviour of a typical particulate assemblage and a quasi-brittle material. However, the effect of length scale in these material systems has not been investigated. This paper presents a series of uniaxial compression experiments conducted on weakly cemented sand specimens of various sizes. The effect of length scale in these weakly cemented sands is investigated through unconfined compression tests."

Jan 1, 2015

By James Scott

Outline Deposit Overview and Brief History ?Geologic Setting ?Local Geology ?Petrography ?Geochemistry ?Mineralization ?Geochronology ?Conclusions Deposit Overview ?Porphyry Cu-Mo-Au ?Discovered 1957 (BIK Syndicate) ?Various programs, most significant: ?Hecla(1970s) ?Teck(Late 1970s Early 1980s) ?Copper Fox Metals (2005 -Ongoing ?optioned from TeckComincoin 2002) ?Measured and Indicated Resources: ?847Mt grading: ?0.292% Cu ?0.019% Mo ?0.202g/t Au ?1.796g/t Ag ?Total ~ 0.485 % Cu Eq.

May 1, 2006

By Ye Chen, Jianhua Chen, Xianhao Long, Qingxia Liu, Zhenghe Xu

"It is crucial to understand the mechanism of the collector interacting with the mineral surface in the presence of water molecules, which could influence the relaxation and electronic properties of sulphide mineral surface due to the proximity effect for narrow band gap of semiconductors. The adsorptions of three typical collector molecules (xanthate, dithiocarbamate and dithiophosphate) on the sulphide mineral surfaces in the absence and presence of water molecule have been simulated by density-functional theory (DFT). The calculated results show that the adsorptions of collectors on clean mineral surface in vacuum are not in agreement with the observed flotation behaviours. The presence of water molecules has a great influence on the adsorption of collectors. The analysis of density of states of the mineral surface atom suggests that the adsorption of water molecules could influence the electronic properties of mineral surface and consequently influence the adsorption between the surface and the collector molecule.INTRODUCTIONIn the separation of multi-metal sulphide ores, the selectivity of a collector is a key factor for the efficient recovery of the aimed mineral. Xanthate, dithiocarbamate (DTC) and dithiophosphate (DTP) are the most common collectors used in the flotation of sulfide minerals. Generally, xanthate exhibits powerful collecting property but lack of selectivity. While dithiophosphate and dithiocarbamate show the good selectivity in the lead and copper sulphide mineral flotation. The mechanisms of these collectors interacting with the sulphide mineral had been attracted many attentions and several mechanism based on experimental results had been reported (Chander & Fuerstenau, 1974; Fuerstenau, 1990; Raju & Forsling, 1991; Crozier, 1991; Bradshaw, Cruywagen & O’Connor, 1995; Guler, Hicyilmaz, Gokagac & Emekci, 2006). However, the micro-mechanisms of the selectivity of these three thiol collectors on different sulphide mineral surfaces are not fully understood."

Jan 1, 2016

By E. R. Lea

The B. M. & S. orebodies, consisting of the No. 6 (Brunswick) and the No. 12 (Anacn Leadridgz, have the distinction of being the first major 1base metal ore deposits to be found in the Province of New Brunswick. They are massive sulphide de-posits consisting of pyrite (pre-dominantly) and base metal sulphides, and they carry values in lead, zinc, copper, and silver. These orebodies are localized within favourable drag fold structures believed to be related in their origin to external forces set up in the area subsequent to the primary regional folding. Both orebodies are characterized by the presence of magnetite 'iron formation' which, in certain 'Portions of each orebody, may be found as relics within the massive sulphides. Studies show the magnetite to be the first metallic mineral within the ore ?zones, followed by pyrite, Sphalerite, galena, and finally chakopyrite. The shape of these massive pyritk orebod:es as well as the distribution of values within them is controlled to a large degree by the ore-ore drag fold structures. A possible relationship is discussed between the basic intrusives in the area ?and the magnetite deposits. It is suggested that a large portion of ?the iron content of the massive suplhedes has been derived from the earlier magnetite. Intermittent movements in the area during the sulphide mineralization are believed to belong to the last stages of deformation in the area. These late movements may have been caused by the intrusion of the granite into the area. The granite may have a genetic relationship to the B. M. & S. orebodies.

Jan 1, 1958