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By C. Allen

In 2004, Boliden Odda underwent an extensive modernisation project targeting mainly the leaching section of the plant. Direct leach technology was introduced as part of this project. The Direct Leach process, developed by Outokumpu, is an atmospheric oxidative leach of zinc sulphide concentrate. The effects of this new processing operation on behaviour of iron in the plant are discussed. As well, the filterability of the new residue on belt filters prior to its deposition in mountain caverns is also discussed. The solids from the direct leach process have been analysed by scanning electron microscopy, and the results of these analyses are presented.

Jan 1, 2006

By Aleksandar N. Nikoloski, Tendekayi Tapera, Glen P. O’Malley

Chalcopyrite (CuFeS2) and enargite (Cu3AsS4) are among the most important copper sulfides. At present, many known deposits of these minerals are uneconomic to process because they are of too low grade, insufficient size or too remote to be cost effectively treated with conventional technologies that can deal with their refractory nature. Therefore, developing an effective, low cost extraction process for recovery of copper from them is important. The research presented in this paper will deal with potentially cost effective strategies involving catalysed processing, studied under conditions relevant to recycle heap leach conditions. The present account summarises some of the main findings from the research program carried out at Murdoch University between 2014 and 2018 that has investigated the effects of the common leaching parameters, major and minor species present in the leach system and additives on the rate and extent of copper extraction from low-grade ores, in which primary copper sulfide minerals such as chalcopyrite and enargite were the dominant copper minerals. The study involved batch leaching tests, detailed structural and mineralogical characterisation and thermochemical modelling under conditions relevant to heap leaching. The results have demonstrated that silver in particular has a strong catalysing effect on the extraction of copper from ore under the leach recycle conditions and, at an adequate dosage, can effectively overcome surface passivation, enabling almost complete extraction of copper from chalcopyrite as well as enargite. The aim of this paper is to present the effect of the studied additives and to briefly elaborate on the mechanism of the silver catalysed leaching process. In addition, the presence of certain secondary agents was shown to lower the critical dosage of silver and promote extraction. The data from the study allowed the development of a theory for the silver catalysed reaction mechanism, which enables further optimisation and cost-effective application of this strategy in practice. INTRODUCTION Researching the extraction of copper from chalcopyrite is important as it is the most abundant copper mineral in the earth’s crust. The majority of ores containing this mineral are processed by flotation to produce a concentrate, followed by smelting and electrorefining. However, most reserves available nowadays are of low grade or limited in size, and therefore not suitable for this conventional approach. Hydrometallurgical processing via heap leaching with or without the aid of bacteria has been shown to be potentially economical. Chalcopyrite is refractory though and suffers from slow leaching kinetics and poor overall extraction, so understanding the mechanism of how it leaches has received significant attention by researchers working in this field over the past 50 years. The refractoriness, which is the main issue with the hydrometallurgical approach, is generally described as passivation of the chalcopyrite surface whereby a surface coating is formed that blocks the reaction interface or wetting of the chalcopyrite, limiting the copper extraction. Exactly what this layer is made of or how the issue could be overcome has been the subject of intense study and debate for many years. One of the limitations of the work to date is that much of the research focus has been on typical initial leaching conditions, while there has been relatively little research into how the leaching is affected under recycle solution conditions where certain metal ions (Fe, Mg, Al) have often accumulated in the liquor. This occurs because the leach solution exiting a heap contains many species from the dissolution of gangue minerals and typically this solution is returned to irrigate the heap, once the copper has been removed, leading to an accumulation of these species.

Jan 1, 2019

By Donald Brisebois

The mining of high-grade, narrow vein deposits is an important field of activity in the precious metal mining sector. The principle factor that has undermined the profitability and effectiveness of mining such ore zones is the substantial dilution that occurs when blasting with explosives during extraction. In order to minimise dilution, the Thermal Fragmentation Mining Method enables the operator to extract a narrow mineralised corridor, 50 cm to 1 metre wide (according to the width of the vein), between two sub-level drifts. By inserting a strong burner powered by diesel fuel and compressed air into a pilot hole previously drilled directly into the vein, a thermal reaction is created, spalling the rock and enlarging the hole to 80 cm in diameter. The remaining ore between the thermal holes is broken loose using low powered explosives, leaving the waste walls intact. This patented method produces highly concentrated ore, resulting in 400% - 500% less dilution when compared to conventional mining methods. The mining method reduces the environmental affects of mining operations since much smaller quantities of rock are displaced, stockpiled, and treated using chemical agents. The fully mechanised equipment operated by a 2-person team (1 thermal fragmentation operator, 1 drilling operator) maximises the effectiveness of skilled personnel, and increases productivity and safety. The Thermal Fragmentation is currently employed in 3 mining operations in North America.

May 1, 2010

By Robert B. Parsons

"The new Ontario Liberal government introduced its first budget in October. The changes to The Mining Tax Act proposed in the budget are mean t 10 simplify the current system without any loss of revenue to the government. It goes without saying that some operators will benefit from the changes while others will pay more taxes after 1985.With regard to ongoing matters at the federal level, the proposed carve-out legislation and the issue of northern allowances are being discussed with government officials, and a small victory has recently been scored with regard 10 the laxation of certain share transactions of prospectors and grubstakers. A report on these issues is provided herein.Ontario BudgetOn October 24, 1985, Ontario Finance Minister Robert F. Nixon tabled a budget proposing several significant changes to both the Ontario Mining Tax Act and the province’s income tax legislation.Mining Tax ActA flat rate of tax and reduced processing allowances highlight proposed changes to The Mining Tax Act. The proposed changes, with a comparison to the existing system, are set out in Table I.The most significant change is the replacement of the graduated tax rate schedule with a flat 20010 tax rate. This is a welcome change for most mine operators who viewed the high rate of 30% on profit over $20 million as counter-productive.However, the flat rate of ta x may not be welcome to all operators. Generally speaking, operators with less than $ 10 million annual profit are better off under the graduated rate system, while operators with annual profit exceeding $10 million will benefit from the 20010 tax rate."

Jan 1, 1986

By Kazuhide Nakaniwa

In this research, we devised a measurement method using total stations (TSs) which have ?the Baum? which is a concentric circle reticle, as substitute for crosshairs. The Baum owes its name to the similarity between the concentric circles and trees (Baum in German). By setting one circle on both of edges of cylinders, operators can set their sights on points on the center line of the cylinders, and also can measure positional coordinates of the points. Also, by measuring two different points on the center line, operators can measure the position and tilt of the axes of the cylinders. Furthermore, we developed a pile driving navigation system. Foundation piles are used for various structures, and their forms are generally cylindrical. Especially, although it is difficult to drive tilted pile foundations, their usage are expected to expand due to their high earthquake resistance. Yet, a method to accurately measure the tilts of piles has not been established. However, we proved that operators can obtain adequate accuracy to control foundation piles through the measurement experiment using this system. Using this system, the information of the pile is measured using a TS, transferred to a PDA, and displayed from the operator?s view of the piling machine.

Aug 1, 2013

By H. Craig Boyle, Craig H. B. Leitch

"The Trout Lake stockwork molybdenum deposit is located in the Selkirk Mountains of British Columbia, 50 km southeast of Revelstoke. The property is being explored by a joint venture between Newmont Exploration of Canada and Esso Minerals Canada.The deposit is associated with a small granodiorite stock of Upper Cretaceous age (76 Ma) which has variably altered the surrounding schists, argillites and marbles of the lower Paleozoic Lardeau Group to hornjelsic biotite schists and skarn. The intrusive is composed of a small stock and an intersecting network of northeast- and northwest-trending dykes at surface that coalesce downward into a larger stock. There are two main phases of intrusion, with an earlier quartz porphyritic granodiorite cut by an intra-mineral ""quartz diorite"" porphyry. A strong sub-vertical north-trending fault controls the distribution of the mineralized stock work and displays post-mineral movement.Molybdenite, accompanied by pyrite and pyrrhotite, is mainly present along the margins of veins in a well-developed quartz stock work, but occasionally is strongly disseminated in microfractured intrusives. The stock work is strongest in and around the contacts of the intrusive and its apophyses, and occurs over a vertical range of more than 1,000 m. As defined by the 0.10% MoS] contour, the main mineralized zone is up to 300 m long by 200m wide. Preliminary drill-indicated reserves, currently being revised, are approximately 50 million tonnes of 0.23% MoS2, within which are several zones of higher-grade material. Hydrothermal alteration, as defined by quantitative X-ray diffraction studies on composite core sections, is composed of a central quartz/K-feldspar/albite/minor biotite zone coincident with molybdenum mineralization, which is overlapped by a slightly later, antipathetic quartz/ sericite/pyrite zone. Ankeritic carbonate is also a common alteration mineral, but only traces of fluorite, and no topaz or sulfosalts, have been observed. Analysis for trace elements such as Sn, W, Bi, Sb, As, Hg, U, Ag, Au, Mn, Cu, Pb, Zn and F has been limited except for Sn and W, which appear to be zoned inside and outside the Mo zone respectively; the other elements do not show detectable patterns thus far."

Jan 1, 1983

By H. E. Johnston

There are currently a number of options in terms of plant feed comminution tests: Bond work index tests, JK drop weight and SMC tests, SPI, low impact crusher work index tests, to name a few. However, information regarding specific energy requirements for regrind mills is often requested, which can be difficult or very expensive when only a small mass of concentrate is produced from bench-scale flotation tests. This research was aimed at developing a test methodology that would produce a similar result as an IsaMill Signature Plot but require less sample mass allowing for preliminary estimates of regrinding power at a lower cost. Initially, the laboratory test methodology was completed on a single sample in comparison to the IsaMill Signature Plot for that sample. Results indicated a very good correlation between the laboratory tests and the IsaMill Signature Plot for this sample, though some parameters did impact laboratory regrind mill efficiency. The developed methodology is subsequently being applied to a range of concentrates, investigating a range of material particle sizes and material types, in comparison to a full IsaMill Signature Plot on the same sample. This new test procedure has been called ‘The Eliason Test’.

Jan 1, 2014

By Mei-Yan Yang, Qiu-Ying Wang, Ltd. Yunnan Yuntong Zinc Co., Guo-Mu Chen, Meng-Yang Huang, Peng Zeng, Guo-Feng Li

"Historically, alot of jarosite was found in the leaching residue when leaching indium from secondary zinc oxide materials. The reasons for the formation of indium bearing jarosite were theoretically analyzed. The influence of controlling the acidity and the addition of reagents on the indium leaching yield during secondary zinc oxide processing was investigated. In order to increase the leaching yield of indium, a measure of controlling the creation and destruction of jarosite was proposed. The production data shows that the leaching yield of indium was increased from 60 to 96%, and the content of indium in leaching residue simultaneously decreased from 900g/t to 100–200g/t when implementing such controlling measures.INTRODUCTIONIndium does not occur as independent minerals in the earth’s crust and is mainly associated with complex sulphide minerals. Specifically some sphalerites can contain as much as 900g/t of indium. Most indium is recovered from by-products of copper, lead or zinc metallurgy. Therefore, the research on the recovery of by-products in non-ferrous metallurgy is important(Sinclair et al, 2006). The main technologies used for this objective in China include: •,pre-neutralization-reduction-precipitation indium process(Yu et al, 2008), •,countercurrent oxidizing acid leaching process and sulphation roasting-water leaching process(Cao, 2005), •,oxygen pressure acid leaching of zinc concentrate-P204 extraction process(Yang et al, 2006), •,doubleacid leaching-solvent extraction process on lead dross from a reverbatory furnace flue dust(Liu, 2003),•,an acid leaching-solvent extraction process on smelting ash(Zhouet al, 2005). Although high pressure and extreme conditions can be used to improve extraction from high iron bearing indium residues(autoclave processing), mild extraction with lower cost and lower environmental impact are preferred.This paper describes both how the indium extraction using mild conditions in a secondary zinc circuit was quite low and, how through XRD and chemical analysis jarosite formation was found as the main cause. The paper then proceeds to discuss a method for improving the leaching yield and the application of this method in industrial practice."

Jan 1, 2016

By M. Mohammadi Zahrani

The morphological modification of primary and eutectic Mg2Si phases by bismuth (Bi) addition in Mg-5wt.% Si in-situ composite was investigated. It was found that with addition of 0.5wt.% Bi, the morphology of primary Mg2Si precipitates was altered from coarse dendritic to polygonal shape, and their mean size was significantly decreased from more than 20 µm to about 8 µm. Moreover, the rod-like eutectic Mg2Si in Bi modified Mg-Si alloy solidified much finer than that of the base alloy. Such improved microstructure of the modified alloy resulted in 10% tensile strength and 20% elongation improvement. The isotropic growth manner of primary Mg2Si particles in modified alloy was attributed to the poisoning of growth in preferred directions by dissolving Bi atoms in Mg2Si lattice. The reduction in size of eutectic Mg2Si was found to be the result of Mg3Bi2 compound formation around eutectic Mg2Si rods.

Oct 1, 2011

By F. Kapeller, G. Herget

"The need for monitoring the effect of changes in ground stresses due to mining in hard rock has existed for many years. The Mining Research Laboratories of CANMET, EMR have developed a new tool which monitors with high precision the radial deformation in boreholes. The result is the Mining Research Laboratories strain monitoring system (MSMS) which uses the highly stable and very sensitive vibrating wire principle to monitor deformations in relatively large boreholes, e.g. 76 mm to 153 mm diameter.The vibrating wire is strung across a relatively large proving ring and operates at a frequency between 600 to 1800 Hz. The read-out system is based on continuous vibration.The ring is installed with a hydraulic tool and brought into contact with the surrounding rock through precisely machined and guided wedges. The resolution of the system is in the neighbourhood of 4 x 10-4 min/ Hz. The data collection can be carried out with a portable read-out unit and provisions are available for automatic data collection. Stresses may be calculated from strain readings.The system was tested in cooperation with the Centre de recherches minérales at the Niobec Mine in Quebec for the purpose of monitoring the effects of drill drift development and slope mining on surrounding ground stresses.After access was available to the site, 153 mm diameter holes were drilled for the determination of in situ ground stresses. These holes were then used to install the strain monitoring system. The effect of drill drift development and production blasting in stopes C-203-13 and C-203-15 on ground stress distribution could be observed clearly.The horizontal relaxation in the core of a pillar which occurred during mining of adjacent rooms was between 0.082 mm to 0.111 mm. Calculations of stresses from these deformations indicate that the rock material is still in an elastic condition.Roctest of Montreal has obtained a license on the manufacturing and distribution rights. A patent has been registered and CANMET will assist in installation of the MRL strain monitoring system and the interpretation of records."

Jan 1, 1989

By N. Kolev, M. Poibrenski, I. Nishkov

"The following paper examines the flotation of copper porphyry ores in Assarel concentrator with focus on the reasons for low molybdenum recovery in the final copper concentrate. The copper-porphyry ore of the Assarel deposit is characterized by its variable mineral composition and high clay content, which influence the process efficiency of their concentration. Particle size distribution, chemical and mineralogical analyses have been made on various flotation products showing the distribution of the main elements of interest - copper and molybdenum. It was found that molybdenum is not concentrated into the final copper concentrate as usual in the flotation of copper-molybdenum ores but into the tailings of the copper selective flotation (cleaner tailings). An attempt to explain these results has been made with proposals to improve molybdenum flotation. Low floatability of molybdenite is caused by the ultrafine clay minerals content in both the run-of-mine ore and copper flotation streams. In order to achieve selectivity of copper minerals against pyrite a significant amount of lime is used in the plant leading to higher pH conditions, which could be another possible explanation for the molybdenite depression. The results obtained after the laboratory experiments, showed that it is possible to restore molybdenite floatability using traditional reagents such as diesel, kerosene, etc., and introducing a new polymeric reagent as froth modifier.INTRODUCTIONOne of the main technical difficulties in the area of copper-molybdenum flotation is the selective recovery of both metals, especially the fine (<40 micron) mineral particles. The problem is even more serious when Cu-Mo ore treated contains a lot of natural fine particles, predominantly clays, micas and other gangue minerals. Peng and Zhao (2011) conclude that the mineral processing industry is well aware of the difficulty in treating ores in the presence of clay minerals. Tremolada et al (2010) found that clay minerals have been named as the main problem in ore beneficiation processes due to their small size, which cause a higher viscosity in grinding. In flotation, these clay minerals have natural hydrophobicity or float by entrainment.The impact of clay mineralogy on flotation performance has been reviewed in the literature and the various deleterious roles of clay minerals have been investigated (Bulatovic, Wyslouzil & Kant 1999; Jorjani et al, 2011; Farrokhpay, Bradshaw & Dunn, 2013). It is widely accepted that the actual flotation recovery problem appears to be caused by the properties of these fine particles: small mass (and/or momentum) – high interfacial free energy (Rubio et al., 2007; Farrokhpay, 2011). In most cases, the loss in recovery is found to be insignificant, but the detrimental effect on the concentrate grade is found to be more prominent. The main reasons for the flotation inefficiency are the low probability of bubble-particle collision and adhesion, formation of dense froths and as a result - low process kinetics. A great deal of fine valuable minerals is discarded as slime in flotation due to lack of effective recovery methods."

Jan 1, 2016

By J. Stiksma, J. Dennett, R. Kalanchey, J. Ji, M. Collins, T. Chan, R. Berezowsky

A pilot plant campaign has been conducted by Sherritt Technologies in support of Eldorado Gold Corporation’s evaluation of pressure oxidation technology for the treatment of refractory gold concentrates from the Certej deposit in Romania. Four separate concentrates, containing 3.5 to 5.4 g/t Au, 13.0 to 14.5% S2- and 12.0 to 32.5 g/t Ag, were tested in the eight-day campaign. The major gold-bearing mineral was pyrite. Preliminary batch tests indicated that gold extraction from the oxidized concentrates in subsequent cyanide leaching was adversely affected by the presence of organic carbon in the pressure oxidation feed when chloride in solution was at an elevated level. As such, the process conditions that were tested during the pilot plant operation were selected to either counteract the negative impact of the organic carbon, or to deactivate it during pressure oxidation. Both process routes proved feasible, yielding gold extraction of 95 to 98% in cyanide leaching of the oxidized concentrates. Silver extraction was typically in the range of 80 to 90%, provided that the oxidized concentrates were also processed in a lime boil step prior to cyanide leaching.

Jan 1, 2014

By A. Montini, M. H. Moys

"A conductivity probe mounted in the shell of the mill has been used to measure the behaviour of the load in the mill as a function of operating variables. It was found that certain properties of the conductivity signal correlate strongly with the per cent solids of the slurry passing through the mill; in particular the angular location ?D of the shoulder of the load is an increasing function of the per cent solids. A method for measuring the viscosity of the pulp discharging from the mill has also been developed. The use of the measurements in mill control is illustrated by simulating various control strategies for open circuit milling. It is shown that the use of ?D allows very tight but imprecise control of the slurry rheology in the mill, while the use of viscosity is subject to severe limitations in speed of response. A cascade control system involving both measurements provides adequate control of slurry rheology within the mill. Applications to closed circuit milling are discussed.IntroductionMultivariable control of milling circuits continues to receive a lot of attention in the literature. Hulbert and co-workers and Niemi, et al. have described the use of Inverse Nyquist Array (INA) techniques while Herbst has recently described the use of Optimal Control. It is significant that in neither of these three projects was any variable associated with the grinding mill itself (e.g. power or properties of the mill discharge) used in the control strategy. Pauw, et al.do, however, use mill power in their multivariable peak-seeking controller for pebble-mill control. Little work has been published on the use of measurements of the properties of the slurry being discharged from grinding mills, in spite of the fact that milling efficiency is known to be strongly affected by slurry rheology».Moys has recently developed a technique for measuring the dynamic behaviour of the load in the grinding mill. This method involves the monitoring of the response of a conductivity probe mounted in the shell of the mill which gives a measurement of the orientation of the load inside the mill. It was found that the load behaviour was strongly influenced by slurry rheology. In this project a technique was also developed for the measurement of the viscosity of the slurry in the mill discharge. It was, thus, decided that it would be worth investigating the use of these measurements in mill control schemes since direct control of the slurry rheology in the mill must inevitably increase the efficiency and productivity of the grinding circuit as a whole.This will be done by using the dynamic responses measured by Moys and Montini to simulate the behaviour of an open circuit ball mill. While the control of open circuit mills is of little interest, this simulation provides a simple but powerful demonstration of the advantage provided by these measurements, advantages which should apply to closed circuit operation of any mill type (including autogenous milling). Investigations into multivariable control of a closed circuit ball mill are currently nearing completion and will be published soon."

Jan 1, 1987

By Desmond M. Connor

"The State of the EnvironmentRecent data from a State of the Environment report prepared in January 1991 and released in April (see references) , indicates that the physical and biological environment across Canada is deteriorating in some important ways. For example: • emissions and atmospheric levels of CO2 are rising at a rate more than 50% of the U.S. increase; global temperature continues to rise, especially during the last decade;• while S02 emissions have been falling since 1984, NOz has declined only slightly since that time; N02 in Canada rose 43% during 1970-87, compared with a 7% rise in the U.S.;• municipal discharges of phosphorus and BOD (biochemical oxygen demand) to fresh water have been rising steadily since 1983);• pulp and paper mill discharges to fresh and Pacific coastal waters have been rising, 1970-87;• migratory game bird populations (Prairie Mallard, Northern Pintail) have been declining for the last 20 years;• total per capita energy use continues to climb.The State of the PublicSimilarly, data from recent public opinion surveys shows that public concerns about the environment are either rising, or are remaining at a high level despite the competing claims of the economy and political events for attention.For example, Professor Reginald Bibby&apos;s national survey this year shows that Canadians rank our top three issues as theeconomy, the environment and government incompetence.An Angus Reid survey commissioned by the Mining Association of Canada and other mining organizations in 1989 showsthat, despite general support for its economic benefits:• 67% of the general public perceive the mining industry to be a major source of pollution and environmental contamination;• 68% believe that a new mine should not be developed if it will disturb local wildlife;• 52% would prohibit a new mine if it required a road through a national park;• 49% would disallow mine development if it took as much land as an average farm in an agricultural area or if it limited sports fishing in a local lake."

Jan 1, 1991

Advanced high temperature electrochemical systems such as fuel cells, electrolyzers and ionic transport membranes are currently being developed for a wide variety of energy conversion, storage and gas cleanup applications. These systems offer high electrical efficiency, multi fuel capability, modular construction, no/negligible emissions (SOx, NOx, VOC, particulate matters) with capability to sequester green house gas emissions (GHG). Electrochemical processes and electrode reactions will be discussed. Cell and stack component materials and fabrication processes will be presented. Bulk, surface and interface degradation processes responsible for cell and stack performance degradation will be examined.

Jan 1, 2005

"Here, we statistically proved that giant earthquakes occur at lunar phases specific to each subduction zone. Enough attention during the lunar period, especially when seismicity is occurring, will significantly reduce damage from giant earthquakes. Two case studies in which giant earthquakes occurred after seismicity in dangerous lunar phases were discussed, and the mechanisms underlying why giant earthquakes occur around neap tide at some subduction zones were explained by prohibition of giant earthquake occurrences due to high strain rates at spring tides at N–S subduction zones. The prohibition was statistically proven for uniaxial creep tests on Inada granite with slight stress disturbances. INTRODUCTIONIn previous studies, we showed that from 1900 to present, giant earthquakes (MW ??8) have occurred at lunar phases specific to each subduction zone (Fujii & Ozaki, 2012; Ozaki & Fujii, 2012). Although we later proposed a possible reason for these occurrences, the study lacked statistical analyses (Fujii et al., 2013). Therefore, this paper shows the results of such statistical testing and presents case studies for the Tohoku 2011 and Chile 2014 events, thereby providing updated data on giant earthquakes through July 2014."

Jan 1, 2015

By P. R. G. Brandão, E. E. Ferreira

The presence of metallic cations in solution will affect the aggregation or dispersion of the fine hematite particles, depending on the type of cation adsorption: either specific or non specific adsorption. In this work, the zeta potential measurements were carried out on a sample of pure hematite as a function of pH and metallic cations concentration (Ca2, Mg2+, Mn2+, K+, Na+ and Al3+). The objective of these studies was to clarify the effect of these metallic cations on the surface chemical properties of pure hematite. The cations K+ and Na+ adsorbed as non-specific species and caused only the reduction on the values of zeta potential (in terms of absolute value) over the entire range of pH values tested. For the Al3+ cation, in the acidic pH range it adsorbed as a specific species and increased the zeta potential values. The cations Ca2+, Mg2+ and Mn2+, adsorbed as a non specific species at pH levels less than 6.0 and caused the reduction of zeta potential due to the compression of the electrical double layer. However, for pH values greater than 6.0, these cations adsorbed as a specific species causing the zeta potential to increase and became more positive as the pH value increased (alkaline). This effect could be due to the adsorption of some hidroxy complex species of these cations, which contributed to the positive charge. The effect of metallic cations (Ca2+, Mg2+ and Al3+ concentration, at pH 4.0, 7.0 and 10, showed the following results: a) at pH 4.0, increasing the concentrations of Ca2+ and Mg2+ resulted in on a small reduction in the value of the zeta potential. At this pH, increasing the concentration of A131 cations caused the zeta potential to increase due to specific adsorption of a negatively charged Al3+ hydroxy complex b) at pH 7 and 10, increasing the concentrations of Ca2+ and Mg2+ caused the zeta potential to change its charge from negative to positive.

Jan 1, 2004

By Arnfinn F. Prugger, Fritz F. Prugger

"The Saskatchewan potash beds are overlain by a number of water-bearing formations. There are water zones in the footwall as well. These aquifers created difficulties during the construction of shafts to the potash beds at 1()(}() m depth, and they pose a continuous threat to the safe and efficient operation of potash mines in the province.The first shafts to be sunk in Saskatchewan encountered major problems during shaft sinking. Of the 17 potash shafts started in the province, five had major water inflows during shaft sinking or after production startup, and one was abandoned because of water problems. The biggest obstacle encountered during shaft sinking was a poorly consolidated sand-shale-clay-siltstone unit commonly called the Blairmore Formation, which occurs at a depth of about 500 m. The initial problems with shaft sinking were overcome in the 19605by using European methods of freezing and the installation of cast-iron tubbings or a double-steel lining through water bearing horizons.From the start of production in the early 19605, operators have been aware of the ever-present hazard of potential water inflows into mine openings from permeable units in both the hanging wall (carbonates of the Dawson Bay Formation which occur 15 m to 50 m above the mining level) and the footwall (carbonates of the Winnipegosis Formation which occur 50 m to 150m below). This awareness has been reflected in conservative over-all extraction rates and mining layouts specific to local conditions. In spite of this consciousness, a number of water problems have occurred in operating mines. These have resulted in everything from simple increases in expenditure to the shut-down of one mine in 1987.In this paper a history of water problems in the Saskatchewan potash industry is given, followed by a summary of measures that are now commonly used to avoid these problems. A description of each inflow event is given, and the attempt is made to analyze the causes of each occurrence. Based on what was learned f rom each event, suggestions are made to prevent future water inflows into potash mines."

Jan 1, 1991

By Jean-Marc Simard, Richard Genest

"La mine Agnico-Eagle, localisée près de Joutel, a été découverte en 1962 par le forage d'anomalies électromagnétiques. Exploitée à partir de 1974, elle a déjà produit près de 30 tonnes d’or à partir de 2 puits, le puits Eagle et le puits Telbel, distants de 1,3 km.Le gisement est situé entre le sommet du complexe volcanique de Joutel, à dominante felsique, et la base de l'ensemble sédimentaire de la rivière Harricana. Ces deux unités ont une extension régionale; elles sont orientées NW-SE avec une polarité NE et des pendages subverticaux. Une faille majeure, la faille Harricana, passe de façon subconcordante au contact de ces deux ensembles.La minéralisation aurifère, de 2 à 5 m d’épaisseur moyenne, est liée a une zone carbonatée, comprise entre des tufs felsiques, argilites et sédiments chimiques (éponte inferieure) et des argilites carbonatées (éponte supérieure). Le minerai est constitué habituellement de 20% de fine pyrite disséminée. L’or est en fines particules associées directement à ces grains de pyrite de texture cataclastique.Deux modelés ont été for mules jusqu' a présent pour expliquer la genèse du gisement: une thèse syngenetique (Barnett et a/.1982) et une thèse épigénétique (Wyman et al. 1986). Cette dernière apparalt comme la plus probable du fait de la présence de la minéralisation dans les zones cisaillées a carbonates secondaires et pyrite cataclastique."

Jan 1, 1990

By J. Beddoes

The various microstructural factors that influence the creep resistance of y-titanium aluminides are presented and discussed. Titanium aluminides have potential for a variety of intermediate temperature applications in both gas turbine and reciprocating engines. While it is well established that the &apos;fully lamellar&apos; titanium aluminide microstructure offers superior creep properties, the particular influence of lamellar morphology, third phase precipitation, and grain boundary structure in controlling both the primary and tertiary creep behaviour is presented. The results are primarily based on tensile creep experiments undertaken using several titanium aluminide intermetallic compositions processed via powder metallurgical techniques, investment casting and Bridgman directional solidification. The results indicate that lamellar structure and precipitate formation have a major impact on primary creep, while microstructural degradation through both lamellar and precipitate coarsening influence on the onset of tertiary creep leading to fracture. The results are used to design a creep resistant microstructure produced by directional solidification and the effectiveness of this designed microstructure is demonstrated through 10,000 hour creep tests.

Jan 1, 2004