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By Art Hamilton

The Zn-Pb-Cu-Ag ore deposits of the Boundary and N-5 zones near Bathurst, New Brunswick, occur in a polydeforrned volcano-sedimentary sequence that is part of the Ordovician Tetagouche Group. Massive and disseminated sulfides are hosted by an argillaceous to cherty sedimentary sequence that is stratigraphically Wlderlain by a siliceous fragmental unit and is overlain by a feldspar-rich crystal tuff and related tuffaceous rocks. The deposits have a low iron sulfide content relative to that of most stratabound sulfide deposits of the Bathurst-Newcastle mining district. The ore is commonly associated with chlorite- and talc-rich sediments. The N-5 deposit is considered to be the fault-displaced extension of the Boundary deposit. The Boundary deposit is estimated to contain 891 000 t grading 3.31% Pb, 7.96% Zn, 0.32% Cu and 44 g/t Ag; the estimate for the N-5 zone is 330 000 t grading 3.24% Pb, 7.15% Zn, 0.33% Cu, and 37 g/t Ag. The ore is processed at 1000 tpd at the Heath Steele mill.

Jan 1, 1992

By Yuwang Wang, Yanggeng Tan, Kezhang Qin, Zengqian Hou

Abstract- The large Derni Cu-Co (-Zn) deposit in Qinghai Province exhibits unusual geological features, and its genesis is controversial. Based on previous research and detailed field investigations, petrographic studies of the host volcanic rocks, isotope and trace element geochemistry of the sulfide ore, and comparison with typical ore deposits, this deposit is a VHMS (submarine volcanichosted massive sulfide deposit) type. This argues against previous interpretations of a magmatic or a hydrothermal replacement origin. Systematic rock, mineral and geochemical studies of the host serpentinites of the ore district indicate that the protoliths of several types of serpentinites that are widespread in the ore district are mainly ultramafic volcanic rocks. The mineralization formed within an ultramafic volcanic breccia, or between the breccia and its overlying Mg-rich carbonate rocks and volcanic sedimentary rocks. The ore-forming components were derived mainly from ultramafic rocks and partly from mafic rocks. The ultramafic rocks are MgO-rich, CaO-poor with a high MgO/FeO ratio, and the mafic rocks are rich in Na2O and poor in K2O. The chemical composition of the ultramafic rocks is similar to that of volcanic peridotite, or komatiite. The volcanic rocks that host the Derni deposit are among the most basic host rocks known for VHMS deposits, and the Derni deposit represents the most basic member in the VHMS deposit spectrum.

Jan 1, 2000

"The Kidd Creek concentrator is situated adjacent to Highway 101, twenty-four kilometres east of the center of the city of Timmins, Ontario. Sulphide ore, received by train from the minesite twenty-nine kilometres away, is processed at a rate of twelve thousand metric tonnes per day. Saleable concentrates of copper, zinc, lead and tin are produced.The concentrator contains secondary crushing, grinding, flotation, gravity separation and concentrate handling facilities. The total concentrator manpower complement is one hundred and sixty-four which includes supervision and operating personnel. Twenty-one shift personnel are required to operate the processes involved and they occupy fifteen different operating positions in addition to that of the supervisor. These positions include:1 Central Control Operatorl Metallurgical Leader1 Dryer Control Operatorl Crusher Leader3 Copper-Lead-Zinc Flotation Circuit Operators1 Pyrite Flotation Circuit Operator1 Tin Plant Operator2 Grinding Operators1 Concentrate Operator2 Crusher Operators1 Spare Operator1 Tailings Area Operator1 Automatic Sample System Operator1 Dryer Area Helper1 Crusher Helper1 Tin Plant Helper"

Jan 1, 1981

By I. B. Schalamuk, R. E. de Barrio, M. J. Pons, M. B. Franchini, L. Meinert

"Several Fe, Fe-Cu, and Cu-Ag prospects hosted by Mesozoic carbonate-rich sedimentary rocks that were intruded by diorite stocks define an approximately 20 × 200 km belt along the Andes Cordillera of southwest Mendoza province, Argentina (34°-36°S). This belt includes the Hierro Indio and Vegas Peladas Fe skarns, Las Choicas, and several other Cu-(Ag) prospects.The main features of the Fe skarns include: association with mantle-derived middle Miocene (~15-11 Ma) diorite stocks and sills; widespread alteration including epidote ± amphibole ± magnetite endoskarns, and zoned garnet (Grs0-66 Adr32.5-100) ± magnetite ± pyroxene (Di24-50 Jo2-9 Hd74-41) exoskarns formed from oxidized, saline, high-temperature brines (530º-660ºC; 60-70 wt.% NaCl equiv.); and magnetite-hematite orebodies associated with quartz ± epidote ± calcite ± actinolite formed at lower temperatures (290º-436ºC) from saline fluids (32-50 wt.% NaCl equiv.) of magmatic origin.West of the Fe skarn belt, the Valle Hermoso district covers more than 300 km2 and hosts several poorly known Cu-(Ag) prospects (estimated 30 Mt with 1.5% Cu and 20 g/t Ag). These prospects share many characteristics with the iron oxide copper-gold-type systems and manto-type Cu deposits of northern and central Chile. One of the prospects (Las Choicas) is located at the apex of a regional 015°-trending anticline, along the contact of stratified calcareous sandstone and limestone (Neocallovian-Oxfordian) with a diorite pluton. This pluton has positive Ta and Nb anomalies (on normalized diagrams) and a high Ti content, features uncommon in Miocene diorites associated with Fe skarns and of magmas derived from sub-arc mantle sources. Alteration at Las Choicas includes early widespread chlorite + calcite ± albite ± scapolite ± ilmenite or titanite ± apatite, and local actinolite ± hematite ± biotite alteration of diorite and sedimentary rocks along contacts. Later Cu mineralization (1%-10% Cu) is associated with calcite ± albite ± quartz alteration in fractures, vein networks, and crackle breccias. Mineralization is zoned from bornite ± chalcopyrite ± millerite with Zn, As, Mo, Ag, and U anomalies in the main orebody, through chalcopyrite-rich breccias with Zn anomalies, and chalcopyrite ± tetrahedrite vein networks with Sb, As, Ag, and Zn anomalies in the uppermost zone, to a Cu-depleted pyrite-rich envelope with Co anomalies, and finally to late, barren calcite veins in distal zones."

Jan 1, 2007

By Trent Hamilton

Cameco ? McArthur River Operation is a high-grade uranium mine in northern Saskatchewan. Average grades mined are nearly 20%, more than 20 times higher than other operating uranium mines in the world. The significant risks involved with mining this grade has been effectively mitigated using innovative and unique controls, implemented from development and production mining through to ore processing. The types and sources of radiation are presented and protection measures are discussed. McArthur River?s strong radiation culture is evidenced by continually low radiation exposures while transitioning to new mining zones.

Aug 1, 2010

By Michel Aubertin

Les activités minières peuvent produire de grandes quantités de roches stériles, qui sont typiquement entreposées dans des empilements de surface, au dessus la nappe phréatique. Ces haldes peuvent occuper une superficie de plusieurs dizaines d?hectares, et s?élever à plus de cent mètres. Pour des exploitations en roches dures, les roches stériles ont usuellement une granulométrie qui contient des particules de la taille d?un sol silteux jusqu?à des cailloux et blocs de taille métrique. La structure interne d?une halde construite sur une surface relativement plane comprend généralement deux zones principales. La première zone se trouve au coeur de l?empilement, et elle est formée par la présence de plusieurs stratifications subhorizontales (avec des couches denses et lâches) due à l?effet des équipements lourds qui compactent et brisent les grains. La deuxième zone se trouve aux endroits où les stériles ont été déversés en crête, par des camions ou des butoirs, ce qui induit une ségrégation des particules sur les flancs, le long de la pente. Selon la séquence de mise en place, la distribution granulométrique et la hauteur des bancs, un grano-classement plus ou moins développé se produit, avec les particules les plus grosses au bas de la pente et les particules plus fines au sommet ; on observe aussi une stratification inclinée due à l?avancement latéral du front de déposition. Ces éléments de la structure interne d?une halde influencent la distribution et le mouvement de l?eau (et de l?air). Pour évaluer la distribution des propriétés des matériaux dans une halde, on doit usuellement avoir recours à une combinaison de techniques qui fournissent des informations sur les caractéristiques hydrogéologiques et géochimiques des roches stériles. A cet égard, certaines techniques géophysiques sont particulièrement intéressantes car elles permettent une cartographie tridimensionnelle des variations des propriétés. Les informations obtenues de diverses techniques de mesures utilisées conjointement peuvent alors être employées afin de construire un modèle numérique qui permet d?analyser les écoulements non saturés de l?eau et le transport réactif des contaminants. De telles simulations aident à mieux comprendre la réponse de la halde dans son état actuel et futur, ce qui fournit des arguments pour ajuster la séquence de déposition pour élaborer le plan de fermeture et pour sélectionner la stratégie d?instrumentation et de suivi de l?empilement. La présentation inclura un survol des diverses techniques qui ont été développées afin de caractériser les propriétés des matériaux en laboratoire et sur le terrain, et pour obtenir un portrait global de la structure interne d?une halde. Des résultats additionnels sur la modélisation du transport réactif seront aussi montrés afin d?illustrer l?influence de la structure interne d?un empilement sur sa réponse hydro-géochimique et environnementale.

Nov 1, 2008

By Kevin Ross

Feasibility Study Team Processing / Engineering?Hatch, Vancouver Mining / Reserves?Australian Mine Consultants, Brisbane Geology / Resources?Roscoe Postle Associates, Vancouver Environmental / Permitting?Rescan, Vancouver Tailings BGC, Kamloops Probable Mine Components Mining tending towards caving methods Underground mine accessed by shaft /conveyor & decline Processing plant producing copper concentrate containing gold Concentrate trucked to rail head for export Non saturated tailings disposal

May 1, 2006

By J. B. Hinzer, J. D. Harvey

"Noranda's Lyon Lake property in the Sturgeon Lake area of Northwestern Ontario was staked by Mattagami Lake Mines Limited in May 1969 to cover airborne Input anomalies. Subsequent ground geophysical and diamond drilling programs resulted in the disco very of the Boundary Extension, Lake and Creek ore zones. As of December 31, 1978, ore reserves were estimated at 3,945,000 tons assaying 6.53 per cent Zn, 1.24 per cent Cu, 0.63 per cent Pb, 3.42 oz/ton Ag and 0.010 oz/ton Au.These deposits are hosted within the South Sturgeon Lake volcanic pile of Archean age, which consists of several cycles of basic intermediate and felsic volcanic materials overlain by a sedimentary iron formation and built upon a plutonic base (Franklin , ' 1975). The top 50 m of the second felsic cycle, according to mine terminolo gy, contains the mineralization within Quartzphenocryst- bearing felsic lapilli tuff and underlying thin discontinuous graphitic sediments and altered coarse pyroclastics. The basal andesitic member of the overlying cycle forms the hanging wall to the ore deposits.Although there is no alteration pipe below the deposits, the coarse footwall rocks are permeated by chlorite, garnet, carbonate, iron sulphide and magnetitie-bearing veins intensifying from west to east.Immediate host rocks are alkali depleted and MnO, FeO, Zn and Cu enriched compared to Goodwin's (1972) average Archean rhyolites. Bedded pyrite-pyrrhotite-chalcopyrite lenses with sphalerite-rich tops are underlain by weakly developed stringer mineralization.Traversing eastward from the Lake Zone to the Creek Zone and toward the Sturgeon Lake Mine deposit, more rapid facies changes, more pronounced chloritic and carbonate alteration, the presence ofgarnets, greater MnO, FeO, CaO and Ag abundances, and increasing Zn/Cu and MnO/FeO ratios are apparent."

Jan 1, 1981

By David L. Huston, Wouter Bleeker, Bruce E. Taylor, Ron Cook, Bob Stewart, Elizabeth R. Koopman

"Abstract—Detailed oxygen isotope mapping of rhyolites in and around the Kidd Creek mine indicates that the orebodies are associated with relatively low (<12‰) whole rock values that extend up to 200 m laterally from ore. The zone of low d18O values is overlain stratigraphically by a carapace of higher (>13‰) values that extends up to 1.5 km laterally from and 300 m to 500 m above ore. Immediately above the stratigraphically highest orebody this carapace is cut by a zone of lower d18O values extending from the ore zone. Zones of higher d18O values also occur in massive rhyolite bodies that occur in the footwall of the orebodies.The zone of low d18O values partly coincides with a Na2O depletion anomaly associated with hydrothermal alteration, except that the Na2O depletion anomaly has a greater lateral extent, and the low d18O anomaly extends farther into the stratigraphic hanging wall. These data suggest that d18O mapping may detect hanging wall alteration above massive sulfide bodies more effectively than conventional lithogeochemistry. Zones of high d18O values, which define zones through which large quantities of low-temperature hydrothermal fluids have passed, may also have usefulness in exploration.Oxygen isotope variations at Kidd Creek record three stages of a hydrothermal system that evolved in temperature with time, as follows: (1) an early, low-temperature event that produced rocks with high d18O values, (2) a high-temperature event that produced rocks with lower d18O values, and (3) a later, low-temperature event that also produced rocks with high d18O values. The high d18O signature of the massive rhyolite was recorded during early-stage, low-temperature (<200°C) alteration, and was probably preserved owing to decreases in permeability associated with low-temperature silicification. The low d18O signature of cherty breccia and chloritite was recorded during the thermal peak at >300°C. High d18O values in the carapace above the deposit were recorded as the hydrothermal system waned."

Jan 1, 1995

By D. W. McDonald, N. A. Duke, R. L. Hauser

"The NERCO Con Mine is situated in the amphibolite facies aureole of the Western Plutonic Complex overprinting the Yellowknife Greenstone Belt. Metamorphic grade of the upright monoclinal basaltic succession decreases from hornblende-amphibolite facies along the border of the batholith to greenschist facies. Metamorphic isograds, subparalleling the faulted margin of the batholith, transect volcanic stratigraphy and coincide with major goldbearing shears.Gold mineralization is confined to north-striking, west-dipping shear zones where hangingwall amphibolite facies mineral assemblages retrogress to chlorite-carbonate-sericite-sulfide bearing schists hosting multiple generations of quartz-ankerite veins. The gold-producing portions of the Con and Campbell Shears occur where these structures transect an east trending thermal corridor. The corridor is defined by granitic plugs and a number of related breccia bodies, that can be traced outwards from the batholith across the greenstone belt.Prograde reactions of greenstone during amphibolitization effectively liberate fluids that partition metals. With retrograde reactions at shear zones, gold is precipitated with quartz due to the destabilization of sulfide and arsenic complexes. The coupling of regional prograde metamorphic and restricted retrograde metasomatic overprints suggest mineralization is temporally related to emplacement of the Western Plutonic Complex. Economic gold concentrations within the intrusive corridor indicates enhanced metamorphic overprint of hornfelsed greenstones enveloping satellite intrusives peripheral to the main batholith."

Jan 1, 1993

By Paul MacLean

MAC TSM ?Mining and Biodiversity Conservation 1.Corporate biodiversity conservation policy, accountability and communications 2.Facility-Level biodiversity conservation planning and implementation 3.Biodiversity conservation reporting ?Activities indicative of level AA -AAA (formerly 4-5) performance: ?Independent verification ?Integration into broader business strategy and planning processes ?Engagement with communities of interest ?Commitment to actively partner with other organisations for biodiversity conservation

May 1, 2011

By J. Makgatho, P. Condori, J. Winnett, Fischerm D.

"Palabora Mining Copper (PMC) has two autogenous mills that have been in operation since 1976. The mills were originally designed to treat 30 000 t/d of open cast copper ore in a closed circuit with cyclones. As the ore body went deeper the open cast method of mining was changed to block caving, a consequence of this was the dolerite content (hardest barren material) increased significantly, increasing the production rate of pebbles and thus reducing the milling capacity. In order to cope with the increased ore hardness and to increase mill capacity, a second ball milling stage and pebble crushing were incorporated to the circuit. The above actions created new challenges to the circuit operation and bottlenecks in different areas of the milling circuit.This paper reports the holistic work performed on the Palabora autogenous milling circuit including the implementation of a mill constraint control scheme, the implementation of a pebble removal system from the circuit and a new circuit configuration."

Jan 1, 2012

By Victor A. Sowa

"Abstract - In 1938, a body of goethite and hematite was discovered beneath Steep Rock Lake near Atikokan, northwestern Ontario. This was at the time the largest and richest undeveloped iron ore body in North America. Mining began in 1944, fast-tracked by the needs of World War II, and through 1979 produced 79 Mt of 56.5% Fe. Production required the diversion of the Seine River, draining of Steep Rock Lake, building of a railroad, and a 25-fold increase of the local population. The mining project, at the time, was the largest project of its type undertaken in Canada. The current concepts of sustainable mine development and mine closures have advanced considerably since the period of operation and closure of the Steep Rock mines, and those operations would probably not have met current expectations of sustainability. However, some of the post-closure aspects of the mines provide illustrations of components of sustainability, which could form part of a basis for a post-mining sustainable land use plan. It is concluded that some of these components were successful in meeting current expectations of sustainable use, and although some aspects are unique to the circumstances at the Steep Rock mines, others could be applicable at other mine sites."

Jan 1, 2003

By Peter A. Witt

Highland Valley Copper is a conventional truck-shovel mining and flotation concentrator operation located some 75 kilometres southwest of Kamloops, B.C. (Figure 1). The ore is within a porphyry deposit and is mined at a rate of 135,000 metric tonnes per day from two separate open pits. The nearby mill produces concentrates containing 375 million pounds of copper and 5 million pounds of molybdenum metal yearly. Head grades are roughly 0.40% Cu at a 0.23% Cu equivalent cut-off. The strip ratio currently sits at 0.55:1 with waste quantities made up of separate rock and unconsolidated overburden units. From the mill, concentrates are trucked to nearby Ashcroft and then hauled by rail to ocean port facilities in Vancouver. The mine employs 950 persons and is planned to operate until 2009. The operation is a partnership between three owners: TeckCominco (61.4%), BHP Billiton (33.6%), and Highmont Mining (5%). Management is shared by the two principal owners and directed by an appointed committee.

May 1, 2002

By Marcel Labbé

La largeur de l?armature peut être modifiée selon les besoins du client entre 48 " et 64" de largeur totale, donc 2 sections de 24" à 32". Ceci permet à l?opérateur d?effectuer le démantèlement de l?équipement pour le déplacement dans les endroits restreints. Le déménagement d?un niveau à un sous-niveau devrait se faire dans un quart de travail de 8 heures. L?option de largeur permet au client de choisir un équipement adapté à son environnement de travail (1). La largeur de la table de forage peut être modifiée selon les besoins du client entre 48" et 96". Cette particularité permet une meilleure stabilité, et plus de précision dans le forage (2). Il y a 4 pattes hydrauliques à chaque coin pour la stabilisation lors de forage (3). La table de forage a 360° d?angle de forage sur 3 côtés du transporteur. La table peut sortir de chaque côté du transporteur de 40 ½" à partir du centre du transporteur pour faciliter la mise en place de la foreuse dans les endroits difficiles d?accès. La plage de forage est considérablement agrandie. Cette caractéristique qui fonctionne hydraulique, permet à l?opérateur de forer sans être obligé de changer la position du transporteur pour des changements de trous. Tous les types de foreuse peuvent être installés sur cette table de forage (4). Sa petite dimension lui permet d?accéder, par des monteries de 30" de diamètre, à des sites de travail de 2,5 mètres de hauteur et largeur. C?est un équipement adapté aux gisements filoniens. Ce genre de gisement est de moins en moins rentable pour les compagnies minières. La mécanisation des ces gisements va permettre de les rentabilisés en augmentant la productivité et la santé du travailleur, en réduisant la dilution (5). Les manettes de contrôle de la foreuse, les mouvements de la table de forage ainsi que le déplacement du transporteur ont été installés selon les recommandations d?un ergonome. Des recherches ont été effectuées par ce spécialiste sur les cas d?accident survenus avec l?utilisation de ce genre d?équipement. Il a déterminé les positions le plus confortable que l?opérateur doit prendre pour éviter les douleurs prolongées (6). Le système de roulement est composé de 4 roues pleines installées sur 4 planétaires de 9000 à 15000 livres de capacité munis chacun d?un moteur hydraulique. Des freins ont été installés sur les planétaires pour assurer la sécurité de l?opérateur et faciliter le positionnement du transporteur lors du forage. Des roues rétractables peuvent être installées pour faciliter l?accès sur rail (7). Ce transporteur peut être alimenté par une puissance électrique plutôt que par une puissance pneumatique. Cette puissance électrique est fournie par un Power Pack qui transforme l?énergie en puissance hydraulique. Ce type d?alimentation est employé lors du forage de développement, mais il peut aussi être utilisé pour le forage long trou. Cet avantage permet au client qui a un problème de pression d?air d?utiliser l?électricité. Par contre si vous utilisez l?électricité mais que dans un secteur isolé le gros courant électrique n?est pas accessible vous pouvez utiliser votre équipement en utilisant la puissance pneumatique. Le changement d?alimentation énergétique se fait facilement (8). Cet équipement est construit pour effectuer 4 types d?activités : forage de développement de niveau et sousniveau avec l?installation d?un bras porteur, forage et pose de câbles d?encrage pour soutènement de terrain, forage de production long trou et forage de monterie ascendante et descendante. L?avantage est que vous investissez dans un seul équipement au lieu de 2 ou 3. Cet avantage vous fait économiser dans votre budget d?équipement. En plus cet équipement est construit pour de dure travaux et ne contient aucun système électronique (9).

May 1, 2001

By F. O. Verret, A. McKen, G. Chiasson

Several grindability tests were developed over the years to design grinding circuits or optimize existing operations. Each test has its own strengths and weaknesses and it is imperative to select the proper test procedure(s) to meet project deliverables and minimize the risk of a project. Pilot plant testing of large bulk samples historically constituted the traditional approach for AG or SAG design, but was gradually replaced by small-scale tests. Nowadays, conducting grindability tests requiring only a few kilos of material on several samples is a more typical approach to grinding mill design. This paper summarises the requirements and deliverables of various bench-scale test procedures, their strengths and weaknesses, and cases where AG/SAG pilot testing should still be performed.

Jan 1, 2012

By Malcolm Scoble

School Values ?? Each other; ?? Students, & helping them develop intellectually, personally & professionally; ?? Freedom to pursue educational & research opportunities; ?? Home-work-life balance; ?? The geographic-business community in which we operate ; ?? The pursuit of excellence; ?? Our contribution to society; ?? Creativity & innovation; ?? Teamwork & collaboration; ?? Career development, achievement & reward.

May 1, 2008

By Qiling Zhang, Zengqian Hou, Xiaoming Qu

Abstract - The Okinawa trough is an active back-arc-spreading center in which submarine hydrothermal exhalation (black chimneys) and sulfide mineralization are forming. Fluid inclusion composition in minerals of the hydrothermal feeder zones in the JADE field shows that the hydrothermal systems are extremely gas-rich. There are two independent and co-existing fluids, CO2-hydrocarbon and saline fluids. Microthermometry and Laser Raman Microprobe (LRM) analyses on individual fluid inclusions of the CO2-hydrocarbon type, dominated by CO2 and containing minor CH4, C2H4, C2H6, N2 and H2S, are almost equivalent to the fluid inclusion composition of a natural gas field. The saline fluid is mainly composed of H2O and contains minor Na+ and K+. It is close to a H2O-NaCl, or H2O-NaCl-KCl system, with salinities from 3.7% to 7.5% NaCl eq. Before venting on the seafloor, the fluids experienced immiscible separation. One of the end-member fluids is downward circulating seawater that interacted with sub-seafloor rocks. The other was gas (volatile)-rich fluid derived from a shallow magma chamber. The immiscibility separation of fluids resulted from the decrease of temperature and pressure of the hydrothermal system and continuous input of magmatic volatiles. The saline fluids in this system are discharging to form sulfide chimneys and black smoke. Meanwhile, CO2-rich fluid discharges as CO2 bubbles through hydrate pipes. A large amount of CO2-CH4-H2S gas or fluid in the upper part of the hydrothermal system, and reaction of this gas or fluid with saline fluids, finally enables the accumulation of metal sulfides.

Jan 1, 1999

By N. Morrison, I. Holl, R. Welyhorsky, A. Hempstock

ABSTRACT: The Victor diamond mine is located in the James Bay lowlands, 90 km west of the First Nations village of Attawapiskat. The project was the first of its kind in northern Ontario. The process plant was designed to produce a 95 to 98% by weight diamond concentrate through three stages of comminution, dense medium separation, and proprietary X-ray technology for final recovery. The plant was commissioned over a period of six months, commencing prior to substantial completion of construction. Through effective planning of the commissioning phase, the Victor mine start-up was safely completed nine months ahead of schedule.

Jan 1, 2011

By Andrea R. Gerson, Roger St. C. Smart, Russell Schumann, Joan E. Thomas, Warwick Stewart, Stuart Miller

Sequential Net Acid Generation (NAG) accelerated oxidation testing using peroxide was carried out on single sulfide mineral samples. The calculation of the nett acid production potential (NAPP) assumes that all the sulfide is present as pyrite and that dissolution results in a 2:1 ratio of H+:SO42-. NAPP as kg H2SO4/t is calculated as 30.6 x wt.% S present. To test whether this calculation is valid a NAPP* value was defined in which instead of using the wt.% S present for the calculation the wt.% S dissolved is used. Stoichiometric analysis of the dissolution products of the sulfide minerals as they would occur at pH 7 indicates, that in all cases, the ratio of H+:SO42- of 2:1 is viable. The NAG to pH 7 and NAPP* closely coincided for pyrite, bornite, chalcocite and covellite. For the three Cu-containing minerals, the NAG to pH 4.5 value was 0 as is predicted on the basis of the speciation likely to be present at pH 4.5. Acid generation is due to hydroxylation of the dissolved Cu between pH 4.5 and 7.0. The NAG to pH 7 and NAPP* values for chalcopyrite, arsenopyrite and pyrrhotite were in reasonable agreement but were not for either sphalerite or galena. Zn is not completely hydroxylated at pH 7 as is assumed by the calculation. For galena, surface analysis identified polysulfide formation on of the leach residue polysulfide. The formation of polysulfide is an acid consuming reaction. Therefore under conditions of accelerated oxidation the NAPP value is a reasonable estimate of the possible acid production in all cases except for sphalerite and galena. However, under conditions of less intense oxidation, for instance in columns, waste rock and tailings dumps, the formation of polysulfides is likely to be more widespread thus reducing the correlation between NAPP and the maximum possible acid production.

Jan 1, 2004