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By T. Hidayat

The distributions of minor elements between slag/metal and slag/matte in equilibrium with tridymite in the Cu-Fe-O-S-Si-Al-Ca system have been investigated in the range of conditions of interest to the high- temperature copper production, refining, and recycling processes. An improved experimental methodology has been used involving high temperature equilibration in controlled gas atmospheres, rapid quenching, and quantitative microanalysis techniques using Electron Probe X-ray Microanalysis (EPMA) and Laser Ablation Inductively Coupled Plasma Mass Spectrum (LAICPMS). The effect of oxygen partial pressure on the distributions of minor elements between slag/metal and slag/matte has been accurately measured. The effects of slagging components (Al2O3 and CaO) on the distributions of minor elements between slag/metal have also been experimentally determined. The present study is a part of a larger integrated experimental and thermodynamic modelling research program in the systems relevant to high-temperature copper processing. INTRODUCTION In the high temperature processing of copper, minor elements are distributed between different phases, i.e. liquid slag, liquid matte, and liquid metal. From a processing perspective, it is desired to have the valuable minor elements distribute predominantly in the metal and matte phases rather than in the slag phase, and to have the non-valuable minor elements distribute predominantly in the slag phase rather than in the metal and matte phases. Knowledge of the distributions of minor elements between phases in the smelting, converting, and refining processes is required if the distributions of minor elements between phases in these processes are to be optimized.

Jan 1, 2019

By Paul Stothart

Context ? Industry is active in urban, rural, and remote regions ? Faces a range of environmental challenges and ?social license? issues ? There are also Aboriginal and northern issues ? Also very active internationally, with associated challenges ? Environmental/social groups often target the industry ? The important contribution of the industry should not be overlooked Useful Minerals and Metals Minerals are intrinsic to the residential, municipal, communications, and transportation infrastructure of modern life. Examples: Hybrid motors - nickel hydride batteries Water purification systems ? nickel, rare earth elements Catalytic converters - cerium Screens and monitors - several rare earth elements Clean electricity - uranium Circuitry - gold, copper, aluminium, lithium, titanium, silver, cobalt, zinc Instruments - copper, silver, nickel, cobalt, copper, brass Protective products ? zinc, calcium carbonate, sulphur

May 1, 2008

By M. Azzaz

In this paper, we report on new mechanical tests, at high temperatures, performed with a supposed better aluminium nitride (A1N) material, containing fewer oxygen. Our purpose was twofold: (i) check whether creep resistance is modified and hopefully enhanced and (ii) determine the elementary mechanisms controlling plastic deformation through transmission electron microscopy (TEM) observations of deformed samples up 10% strain in compression at elevated temperatures (1823-1923 K) under constant stress in the range 150¬250 MPa. Stationary rates are lower by an order magnitude than those previously measured in MN with higher oxygen content. All dislocations imaged by TEM look undissociated, which clearly relates the formerly observed wide dissociation to oxygen in excess.

Jan 1, 2004

By M. P. Tibbs

An autonomous spray application system for a structural Thin Spray-on Liner (TSL) is targeting productivity and safety on underground coal continuous miners by potentially replacing steel mesh, and has broader applications as surface support and confinement in metalliferous mines and civil tunnelling. Polymer chemistry, coating formulation, geotechnical assessment and the autonomous application system are being developed as an integrated package as part of a continuous miner automation project. This polymer-based TSL system has significant benefits over conventional steel mesh skin confinement, including being more automatable by spray application, providing complete skin confinement and active skin reinforcement as a fast-curing composite with substrate, and having effective fire retardant properties for the polymer and the underlying coal. This paper presents a preliminary assessment of distance sensing systems that would enable autonomous adaptation of a nominal spray path to spray a consistent thickness of TSL (nominally 5mm) over an irregular topography. Two alternate sensors are assessed; firstly, a 2D LIDAR mounted on a linear axis is used to produce a 3D surface profile for generating an adapted spray path; and secondly, a robot end-effector-mounted ultrasonic sensor is assessed for wall following techniques to dynamically adapt a nominal spray path.

Aug 1, 2013

By Masakazu Daté

Moisture effect has been studied for the CO oxidation over Au/TiO2, Au/Al2O3 and Au/SiO2, in the range of H2O concentration over four orders of magnitude. It has been found that the catalytic activity is generally enhanced by moisture in the reactant gas. The enhancement is as large as two orders of magnitude. Response to the moisture concentration, however, depends on the support oxide, indicating different contributions of the support to the reaction steps. The moisture effect is reversible and the activity is mainly determined by the amount of moisture absorbed by the catalyst. The apparent activation energies are not significantly influenced by moisture for Au/TiO2 and Au/Al2O3. On the contrary, non-uniform conversion curves versus temperature observed for Au/SiO2 are drastically changed, which indicates that the reaction over Au/SiO2 does not take place at low temperatures without moisture. The moisture effect may be probably attributed to the decomposition of carbonate species accumulated during the reaction, while the ?OH group might directly participate in the reaction pathways as a promoter.

Oct 1, 2003

By S. Shairp

Copper is an impurity as well as a necessary reagent in the processing of zinc sulfide concentrate at Hudson Bay Mining & Smelting Co., Limited's (HBMS) zinc pressure leach plant. Copper is present in the zinc concentrate as chalcopyrite, which consumes reagents necessary for zinc leaching. A small percentage of copper precipitates in the autoclaves, discharge lines, and flash tanks, requiring maintenance of the equipment and disposal of the solids. Copper also precipitates in the neutralization stages and is removed to low levels in a specific copper removal stage of purification. Yet some copper, as copper sulfate, is required, along with potassium antimony tartrate, in the final purification stage to improve cobalt removal from the zinc sulfate solution prior to electrowinning. The behaviour of copper experienced at HBMS's zinc pressure leach plant is discussed.

Jan 1, 2008

By William F. Caley, A. MacKinnon, P. W. Kingston

"The purpose of this paper is to identify a number of currently available opportunities for exploration and/or mine development in the industrial minerals field in southeastern Ontario. The paper is not intended as a complete review of the industrial minerals industry in southeastern Ontario, but highlights what are seen by the authors as areas where there are immediate opportunities for investment and growth.Traditional exploration targets in the Grenville Supergroup in southeastern Ontario have been vein-hosted gold deposits, industrial minerals, and base metals. In recent years, emphasis has increasingly shifted to industrial minerals, in response to changing technologies in the minerals-consuming manufacturing industries, and to an increasing awareness of the industrial mineral potential in this area.This paper examines the resurgence of interest in exploring for and developing a wide variety of industrial minerals, and it examines the work the Ontario Ministry of Northern Development and Mines has done under the current Canada-Ontario Mineral Development Agreement. Specific development opportunities are identified in various commodity areas. Use oj the industrial minerals wollastonite and nepheline as substitutes for fluorspar in the formulation of synthetic steelmaking slags is also discussed."

Jan 1, 1990

By R. Bonnar, R. J. McH. Clark

"The Cheminis gold mineralization zone is approximately 6.5 km west of the Kerr Addison Mine along the Larder Lake Shear Zone, in the southern part of the Abitibi Greenstone Belt. The zone is very similar in appearance to the flow ore at the Kerr Addison Mine and occurs at the same stratigraphic position. Drilling has demonstrated that the gold mineralization at Cheminis persists to a depth of over 3000 ft .The mineralization is hosted by a pyritic, tuffaceous sediment which occurs within a sequence of volcanics and sediments which have been pervasively carbonatized. The gold is largely enclosed within pyrite grains and the amount of gold in the layers of pyrite increases in the layers closest to a graphitic f ault zone.It is suggested that the gold mineralization may be primarily related to the syngenetic sulphide concentrations formed during fumarolic activity on the seafloor along the Larder Lake Shear Zone. At a later stage a hydrothermal event associated with alkalic volcanism may have resulted in regional carbonatization and further concentration of the gold in the vicinity of fault zones."

Jan 1, 1987

By E. L. Day

"In the early 1930s during the course of test work with a simple gold ore, it was evident that the time required to dissolve the gold by cyanidation was very much longer than should have been needed theoretically for the maximum size gold particles in the ore, A similar conclusion appeared to be valid for other gold ores. In a cyanidation system there are many factors which can influence the dissolution rate of gold, and a decision was made to investigate the more obvious variables, because a literature survey at the time showed that with the exception of the work of Yamazarki on the dissolution of silver in cyanide solution, virtually no attention had been given to this subject, Our work was not reported because the intention was to do this on completion of the Study, but owing to the demands on the Section's personnel for other work the investigation was never completed. Although other investigators have since studied the problem, the methods which we adopted and some of the conclusions may be of interest to metallurgists concerned with gold ore treatment.Form of GoldExperiments with gold ores were not possible because of the number of uncontrollable variables present in a gold ore-cyanidation system, therefore pure metal and reagents were used. Initially some experiments were carried out with gold leaf, but it was soon apparent that metal in this form was unsuitable because the uneven thickness of the leaf caused it to break up into pieces and. there was difficulty in determining precisely when complete dissolution had taken place, Numerous factors both expected and unexpected were found to influence considerably the results and much experimental work was necessary to establish the procedures which were finally adopted, Experiments were carried out with gold in the form of foil, wire, rings and sols. Finally, gold foil in the form of cylinders was adopted for most of the experiments although some work with gold in the sol form was included in the programme. Also some experin1ents were carried out with a gold ore to see if effects which were obtained with sodium chloride on gold sols were applicable to gold ores."

Jan 1, 1967

By Rod Abbott

High Definition Scanning (laser scanning) is a proven technology that is accurate to within 6mm in 50m (¼? in 150?). It can capture in excess of one million 3D point measurements in an average 2 hour scan. It has numerous applications including brown-field retrofits, bridge measurement and analysis, verifying as-built conditions, and crime scene investigation. We most commonly use it for plant design to capture current site conditions, so as to prevent interferences and problems before construction begins. All vital information is captured in the first site visit, which limits the need for extra field trips.

Oct 1, 2010

By R. T. Erskine

"IntroductionIn this paper it will not be possible to cover all details of the reagent systems at Brunswick Mining and Smelting but it is hoped that a description of the evolution of these systems will be of some benefit. The concentrator of Brunswick Mining and Smelting located near Bathurst, New Brunswick was originally designed as a 3,000 ton per day operation but before construction commenced was uprated, with 4,500 tons per day being treated by the summer of 1964. Development of the open pit at another ore body five miles away was initiated in 1965 and additional concentrator and crusher facilities went into operation in September, 1966. Present total daily throughput is over 8,000 tons per day. The ore at Brunswick is very high grade but mineralization is very fine grained and requires grinds generally over 75% minus 400 mesh for liberation. The amount of surface exposed using grinds of this order understandably requires great quantities of reagents, Reagent mixing systems for the original concentrator allowed only for batch mixing and were very expensive in labour cost especially.During the first three years of operation total number of men employed in reagent handling reached a peak of four men per shift and six men on dayshift unloading cars for a total of 22 men. At present only one man is employed on shift, and four men on dayshift take care of unloading and mixing reagents, a total of 8 men. The man on shift is almost entirely occupied with checking feeder operation, flow rates, and head tank levels. Most commonly used reagents are tabulated in Fig. 1 showing average monthly and daily requirements in the Brunswick operation as well as pounds per ton of mill feed as found in 1969. It is very obvious that with over seventeen tons each of lime and soda ash and six tons of copper sulphate used each day, opening of bags and mixing batches of solution is an inefficient undertaking."

Jan 1, 1970

By Steve R. McCutcheon, Cees R. Van Staal, John P. Langton, Leslie R. Fyffe

The volcanic-dominated Tetagouche Group in northern New Brunswick contains numerous massive-sulfide deposits and intimately associated metalliferous sediments. The massive sulfides are generally hosted by Llanvirnian-Llandeilian volcaniclastic sedimentary rocks of the Nepisiguit Falls, Patrick Brook, and Boucher Brook formations. These formations are intercalated or closely associated with rhyolitic-dacitic flows and/or domes, and minor continental tholeiites of the Flat Landing Brook Formation. Pyroclastic rocks are relatively scarce in the silicic volcanic complex. Tuffites and epiclastic sandstones, of the Nepisiguit Falls and Patrick Brook formations, respectively, generally occur along the fringes of the silicic volcanic complex. The flows and tuffites are intruded by quartz- and feldspar-phyric rhyolite (porphyry) dykes, sills, and domes. Although the volume of the silicic volcanic complex is large, evidence for a previously proposed collapsed-caldera model is lacking. On the basis of host-rock type and stratigraphic position, the sediment-hosted massive sulfides have been divided into three groups: the Brunswick-, Caribou- and Halfmile Lake-type deposits. Syngenetic feeder pipes and asociated alteration zones are generally not present beneath the Caribou- and the Halfmile Lake-type deposits and, if present at all, are poorly developed underneath the Brunswick-type.

Jan 1, 1992

By A. B. Carino

Gulf Minerals (Canada) Limited's Rabbit Lake uranium operation is located in the northern portion of Saskatchewan, 198 miles southeast of Uranium City and /34 miles northwest of Lynn Lake, Manitoba. The paper follows the ore flow through crushing, grinding, sulphuric acid leaching, countercurrent decantation, solvent extraction, ammonium diuranate precipitation, thickening, drying and tailing neutralization.

Jan 1, 1979

By K. Waters, A. Navarra, T. Grammatikopoulos

Strategic decisions to develop a mineral deposit are subject to geological uncertainty, due to the sparsity of drill core samples. The selection of metallurgical equipment is especially critical, since it restricts the processing options that are available to different ore blocks, even as the nature of the deposit is still highly uncertain. Current approaches for long-term mine planning are successful at addressing geological uncertainty, but do not adequately represent alternate modes of operation for the mineral processing plant, nor do they provide sufficient guidance for developing processing options. Nonetheless, recent developments in stochastic optimization and computer data structures have resulted in a framework that can integrate operational modes into strategic mine planning algorithms. A logical next step is to incorporate geometallurgical models that relate mineralogical features to plant performance, as described in this paper.

Jan 1, 2017

By C. Han, S. J. Zhou, Y. B. Shen, D. Z. Wei, P. Fang

"Collecting property of two hydroxamic acid collectors have different type of nonpolar structure to hemimorphite has been comparatively studied via monomineral flotation test, and the reason causes different collecting performance has been discussed from the view of relationship between molecular structure and collecting property. The flotation tests results show that C5-9 hydroxamic acid has an unbranched linear alkyl nonpolar group shows better collecting property to hemimorphite than cyclohexyl hydroxamic acid which has a naphthenic nonpolar group. FTIR detecting results show that the adsorption type of collector adsorbed on hemimorphite surface is chemical adsorption. Calculation results of polar group’s geometric structure parameters, polar group’s electron density distribution, octanol-water partition coefficient (logP) and molecular frontier orbital energy show that the key factor caused different collecting property of two collectors to hemimorphite is the logP; unbranched linear alkyl nonpolar group is more conducive than naphthenic nonpolar group to make hemimorphite particle more hydrophobic.INTRODUCTIONZinc-bearing mineral recovered from lead-zinc ores is the main source that people can obtain zinc resource from nature. However, natural sulfide ores are currently getting depleted steadily for the primary zinc source. In order to satisfy the future demand of zinc resource, there is an obvious recognition that the recovery of zinc oxidized minerals from the ores is a crucial alternative (Hosseini & Forssberg, 2007; Navidi Kashani & Rashchi, 2008).But the fact that can’t be ignored is the flotation of zinc oxidized minerals is much more difficult than that of zinc sulfide minerals, which is mainly due to the flotation characteristics of these zinc oxidized minerals such as lower selectivity and higher reagent consumption, as well as complex and variety of lead-zinc ores. Presently, there have been many various beneficiation technologies used for recovering zinc oxidized minerals and dealing with ores for recovering metallic zinc such as flotation and hydrometallurgy (Abkhoshk, Jorjani, Al-Harahsheh, Rashchi, & Naazeri, 2014; Önal et al., 2005). But from an overall perspective, flotation is the most common method used for the beneficiation of zinc oxidized minerals, and there have been extensive investigations conducted on the flotation of zinc oxide ores (Ejtemaei, Gharabaghi, & Irannajad, 2014). Until now, the most well-known method used commercially for the flotation of zinc oxidized minerals is sulfidization with sodium sulfide and flotation with a cationic collector of amines containing from 8 to 18 carbon atoms. However, a major problem for this method is the large amount of fines and slime results in the increase of reagent consumption and promotes the phenomenon of slime-coating. For preclude this negative effect, the de-sliming and processing optimization is indispensible (Peres, Borges, & Galery, 1994; Salum, de Araujo, & Peres, 1992)."

Jan 1, 2016

By M. Bertrand

Oxalic precipitation is usually applied to process radioactive wastes or to recover actinides from a multicomponent solution. Precipitation reactions being highly sensitive to many operation parameters, the computer simulation appears to be a very effective tool to forecast the evolutions of the system subjected to various operating conditions. This study focuses on the tetravalent uranium oxalate precipitation modelling which combines population balance and hydrodynamics. Both experimental and numerical studies are carried out in order to analyse the reactor design influence on the precipitate characteristics. The simulations taking into account primary nucleation and crystal growth are in agreement with experiments.

Aug 1, 2010

By M. B. Kime

"Discrete-element method (DEM) modelling is a powerful tool for studying particulate systems within the mineral processing industry. DEM simulations were conducted to investigate the power draw, load behaviour, and impact energy profile of an experimental ball mill under different milling conditions. The variables considered were mill rotational speed (percent critical speed), ball size, and lifter face angle. The simulation results indicated that the grinding efficiency would be enhanced by using 80% critical speed, 30 mm ball diameter, and 45° lifter face angle. These findings can be useful in guiding actual ball milling tests involving an ore sample.RÉSUMÉ La modélisation par méthode des éléments distincts (MED) est un outil puissant qui permet d’étudier les systèmes particulaires au sein de l’industrie de traitement des minerais. Des simulations par MED ont été menées de façon à étudier le profil de la consommation énergétique, du comportement de la charge et de l’énergie de rupture d’un broyeur à boulets expérimental dans diverses conditions de broyage. Parmi les variables prises en compte figuraient la vitesse de rotation du broyeur (vitesse critique en pourcentage), la taille des boulets et l’angle de coupe de la cornière élévatrice. D’après les résultats de la simulation, on pourrait améliorer l’efficacité de broyage en utilisant une vitesse critique de 80 %, un diamètre de boulet de 30 mm et un angle de coupe de 45 ° de la cornière élévatrice. Ces résultats peuvent se révéler utiles pour les essais concrets de broyage à boulets impliquant un échantillon de minerai."

Jan 1, 2017

By G. Kordosky

The experience of one plant regarding degradation of copper solvent extraction reagents in the presence of 20 to 30 g/1 nitrate in the leach solution was described at Cobre 2003. However, little information is available about the degradation of copper solvent extraction reagents where the nitrate concentration of leach solution is much lower. Analysis of plant organic samples taken from an operating copper SX plant over a long period of time shows that small amounts of nitrate in the leach liquor can be a significant contributor to reagent degradation provided certain other conditions are present. These conditions are discussed and cautionary suggestions on copper SX plant operations in the presence of even low levels of nitrate in the pregnant leach are made based on industry experience with copper solvent extraction plants and copper solvent extraction reagents.

Jan 1, 2007

By B. Damjanac, S. Maxwell, D. Chorney, M. Grob, F. Zhang, J. Hazzard

"A hybrid discrete-continuum numerical scheme is developed to study the behavior of hydraulic fractures crossing natural fractures. The fully coupled hybrid scheme utilizes a discrete element model for a core domain, within which the hydraulic fracture propagates and interacts with natural fractures, and a surrounding continuum domain to better approximate boundary effects. The results show that the behavior of hydraulic fractures crossing natural fractures is affected by a combination of factors. Nevertheless, three fundamental crossing scenarios can be identified from all of the simulations: no crossing, partial crossing, and direct crossing. Each crossing scenario has a distinct injection pressure history which may suggest guidelines for interpreting field hydraulic fracture injection data. Additionally, the capability for these models to generate synthetic microseismicity makes them appealing for the integration of microseismic field data with the reservoir geomechanics for ultimately providing a practical engineering tool for improvement of well completion and stimulation. The model is capable of examining and verifying four different shear deformation mechanisms associated with a propagating hydraulic fracture. The natural fracture can fail solely due to the stress perturbation of the passing hydraulic fracture or it can fail due to a combination of stress and pore pressure changes across different types of interaction scenarios. The simulations also illustrate that the level of fracturing complexity increases as the number and extent of the natural fractures increase. INTRODUCTIONAlthough hydraulic fracturing technique has been applied extensively as a reservoir stimulation technique in the oil and gas industry for over 60 years (Economides & Nolte, 2000), it is one of the key factors promoting the shale gas boom in the past decade (King, 2010; International Energy Agency, 2014). The hydraulic fracturing of shales can be differentiated from hydraulic fracturing of conventional reservoirs by the fact that shale formations often have a pre-existing discrete fracture networks which greatly impact the hydraulic fracture propagation. Based upon field production data as well as microseismic observations, it is believed that so called “fracture complexity” may result from interactions between a created hydraulic fracture and pre-existing natural fractures and planes of weakness (Warpinski, 2009; Maxwell & Cipolla, 2011)."

Jan 1, 2015

By Y. Rama Murthy, Amit Ranjan, Pankaj Satija, Sunil K. Tripathy

"Chromite ore is one of the essential raw materials for ferroalloy and steel industry. Boula-Nuasahi belt of Sukinda region, Odisha, is the only resource of chrome ore in India. The Indian deposits are typically characterized as ferruginous and siliceous type ores. Chrome ore is generally mined by open cast mechanized mining method in these areas. The run-off-mine (ROM) ore from the various mines is sent to beneficiation plant via stack yard for further up gradation. The chrome ore beneficiation plant (COB) has two major circuits: comminution (feed preparation) circuit and beneficiation circuit. In the comminution circuit, the ore is reduced to <1 mm size ( for complete liberation of chromite) from -220 mm size in stage wise crushing (primary and secondary crusher) followed by screening and single stage grinding in a ball mill. Fraction having size <1 mm is further upgraded in the beneficiation circuit to produce three different concentrates having specific chemical composition and Cr: Fe ratio. The beneficiation plant is a complex circuit comprising of combination of unit operations (spiral concentrator, Floatex density separator, hydrocyclone, wet shaking tables). In the recent years the overall performance efficiency (grade and recovery) of the beneficiation circuit got affected with numerous changes in the run-off-mine ore quality (physical and chemical), mineralogical composition, etc.In this article, attempts made for improving the performance of chrome ore beneficiation circuit is discussed. The approach adopted and practical problems encountered while the process were also highlighted. The results of the trials has shown an improvement in the performance of the cyclone (d50 : 56 µm – 40 µm) and chromite losses into tailing to <12%.INTRODUCTIONChromite has a wide range of application, from refractories to metallurgical industries, and from chemical to non-ferrous alloy industries. Chromium ore (Fe2+, Mg) [Cr, Al, Fe3+]2O4) occurs exclusively in rocks formed by the intrusion and solidification of molten lava or magma which is very rich in the heavy, iron containing minerals such as pyroxene and olivine. With the richness of silica and iron, the chrome ores are broadly classified as siliceous type and ferruginous type. Pure chromite with composition FeCr2O4 is rare because magnesium usually substitutes for ferrous ion and aluminum and ferrous ion substitutes for chromium. Generally the associated gangue minerals are talc, quartz, hematite, goethite, limonite, gabro, serpentine, anorthosite, dunite, pyroxinite, etc. Around 96% of the chromite ore production is consumed for metallurgical applications of which 94% is converted into different grades of ferrochrome i.e., high carbon ferrochrome and charge chrome as shown in Figure 1. Stainless steel being the leading consumer of ferrochrome, any change in the dynamics of the stainless steel industry impacts overall chrome ore demands significantly."

Jan 1, 2016