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By R. Baker

A novel electrochemical half-cell and corresponding working electrode were designed to evaluate the electro-catalytic activities of catalysts in an environment close to that of an operating proton exchange or polymer electrolyte fuel cell (PEMFC). Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) techniques were employed using the novel cell to characterize various methanol electro-oxidation parameters that contribute to the overall reaction on a fuel cell anode. The effect of temperature on methanol oxidation kinetics was examined in the potential range of 0.31 to 0.65V (vs. NHE). The data was collected in the temperature range of 20 to 80°C. Based on the experimental analysis and literature data, an equivalent circuit model (ECM) for methanol oxidation was proposed and was used to fit the EIS experimental data. The experimental data and ECM electrochemical data was used to extract electrochemical kinetic parameters for methanol oxidation such as the exchange current density, Tafel slope, and energy of activation for the reaction. Kinetic data, especially at different temperatures, is very limited in the literature.

Jan 1, 2005

By Boris Yacksic, R. W. Bruce

"The flotation of a cassiterite ore with oleic acid will recover primary or rougher concentrates assaying over 10 per cent Sn, with a recovery of 80 to 90 per cent. These rougher concentrates cannot be up-graded to a marketable grade by normal reflotation. Experiments were conducted on low-grade tin ores, and a process was developed for up-grading the rougher flotation concentrates by a reverse flotation technique. The process was tested on a number of samples of ore from the Catavi mine in Bolivia. The results of these tests showed that a concentrate assaying 40 to 60 per cent Sn could be readily produced, with a recovery of 60 to 75 per cent of the tin in the ore."

Jan 1, 1967

By C. H. Wright

Introduction The rapidly expanding and increasingly complex Canadian industrial structure, with the mining, metallurgical, and chemical industries as a large integral part, has, in recent years, brought greatly increased importance and value to our industrial minerals. In the modern economy of our mineral industry the importance which is due the non-metallics has been somewhat overshadowed by the great value of our large metal production and, in addition, by the glamour and fascination usually associated with the mining and treatment of gold ores. The term 'Industrial Mineral' is used in this paper in its usual sense and refers to non-metallics other than fuels. Coal and petroleum products, including natural gas, are considered as industrial minerals in those applications in which they are used for strictly chemical process purposes. Certain reduction metallurgical industries are so closely allied to chemical industries that for purposes been of this discussion no attempt has made to differentiate between them. Chemical industry in Canada today is a fairly large factor in our national economy, whereas in 1898, when the Canadian Mining Institute was born, it was very small indeed. Chemical concerns are largely dependent on industrial minerals for raw materials and process supplies and, as the country has developed industrially, so have the demands for non-metallics increased, not only by chemical industry but also by other large consumers, such as the construction and metallurgical industries. At the present time there is a greater than normal incentive prevailing for new discoveries, due to the serious lack of balance that exists in our import and export trade. This fact has resulted in intensive efforts to rectify the situation by locating new deposits and re-assessing those already known in an effort to enlarge and improve our home production of raw materials and also to extend their processing in Canada for our own needs and for export. The rapid advances in science and technology that have taken place since 1900 have also resulted in many cases of beneficiation and utilization of otherwise too low grade materials in order to satisfy current demands. The purpose of this paper is to indicate the history and the trends of the utilization of industrial minerals in established industry and to indicate the important part played by non-metallics in connection with the opening up of new industries. Some consideration has been given to the continual competition between natural and 'synthetic products and to the general tendency towards more rigid specifications.

Jan 1, 1948

By Michel Lefebvre, André Piché

Every organization performing R&D is faced with the challenge of introducing new technologies to its operations. Difficulties must be overcome if companies are to realize the benefits anticipated from such developments. This paper outlines the difficulties encountered in transferring to operations various technologies developed at the Mining and Exploration Division of the Noranda Technology Centre. The approach used in the selection of a privileged partner for the technology transfer, the criteria motivating the choice and the process followed to establish the partnership are presented.

Jan 1, 1997

By The Mill Staff

Professor H.E.T. Haultain: Table 4, on page 131 of this paper, gives the assays of sized mill products. I am sure that there are many others besides myself who would be very interested to learn how the sizes 0-3 and 3-13 microns were obtained. * * * Mr. Del Davis, Mill Superintendent, Flin Flon Concentrator, on behalf of the authors of the paper, has kindly sent us the following information in reply to Professor Haultain's enquiry. Sub-Sieve Sizing by Sedimentation Procedure (As used by R. J. Digney & J. E. Ryan, 1940) Fractionation of Sub-Sieve Sizes General Method: A 1,050-gram sample of the material was pulped to 3 liters; 10 c.c. of sodium silicate and 0.2 grams of Na2C03 was added and thorough agitation given for two hours previous to settling. The material was assumed to consist wholly of particles of the same density as the most abundant particles. The time required for a particle of the upper limit of the lowest size-range to be separated, to fall a specified distance was calculated according to Stokes Law. The pulp was poured into the settling apparatus and, when the calculated time had elapsed, the suspended material was drained. The settled sediments and the process repeated until no more suspended material was obtained. The next larger size fraction was obtained in a similar manner, using the settled sediments which had been stripped of all smaller sizes as above. The fractions were arbitrarily set at 0-3, 3-13, 13-23, 23-33, and 33-43 microns (43 microns = 325 mesh).

Jan 1, 1946

By P. M. May, V. Gella

The deportment and speciation of trace elements during mining and minerals processing is becoming an area of increasing concern with regards to potential health and environment risks. The use of chemical modelling can enhance our basic understanding of the deportment and speciation of trace metals under conditions present in gold processing solutions, and assist in laboratory and field investigations. In this paper, we report the results of chemical speciation modelling using the JESS software package for the trace toxic elements Pb, Cd, Hg, Se and Te in cyanidation solutions of varying salinity and relate the models to experimental data. The speciation of mercury is examined in detail.

Jan 1, 2011

By Z. Bibak, S. Banisi, A. Ghasemi, E. Nematollahi

"The major importance of liners in grinding is their role in providing an appropriate trajectory for the charge. Since it is not possible to study the charge movement by direct observation in operating industrial mills, this task is accomplished by physical (laboratory), and/or, mathematical (software) methods. Because of the high cost and a longer time required for a physical analysis, mathematical simulations have become more common. Simulation of the effect of liner shape on the charge movement has provided a means to select a proper design based on the operational objectives and conditions. Furthermore, the liner shape changes due to wear and impact during operation, which will influence the charge trajectory. This adds more of an incentive to use simulation. These changes in liner could be predicted through liner profile measurements during operation and/or simulation. In this research, an inhouse developed DEM software called KMPCDEM © was used to simulate the charge movement in industrial plant SAG mills. A geometrical method of implementing the shell liners on SAG mills at the Sarcheshmeh (9.75×4.87 m) and the Gole-E-Ghohar (9×2.05 m) operations facilitated the software simulation. Point by point implementation of the measurements of liner profiles of these mills enabled the study to trend the change in the charge movement as the liners wear. Comparison of the simulation to a laboratory mill (1 m diameter) showed that the difference between the measured and predicted charge impact point, shoulder angle and toe angle were 6, 4 and 3°, respectively. INTRODUCTIONComminution is the most energy intensive operation constituting the major portion of operating and capital costs of a mineral processing plant. In the last decade, a vast number of research was aimed at studying various aspects of grinding with the aim of performance improvements (Davis, 1919; Mishra & Rajamani, 1990; kalala, Breetzke, & Moys, 2008). Mill liners transfer the input power to the charge and play a significant role in affecting the motion of the charge (Mclvor, 1983; Mishra & Rajamani, 1990; Radziszewski, 1997; Van Nierop, Glover, Hinde, & Moys, 2001; kalala et al., 2008). Lifters are usually used with mill liners to extend their life and to enhance the grinding and impact breakage efficiency. Mill lifters are used to raise the grinding media and ore to transfer the energy from the mill to the load (Rezaeizadeh, Fooladi, Powell, & Weerasekara, 2010)."

Jan 1, 2016

By Mike Dry, Mani Manimaran, Mykolas Gladkovas, Mariam Melashvili, Chris Fleming

Development of a new hydrometallurgical flowsheet requires quantitative description and optimisation of all chemical processes in each step in the process, as well as mass and energy balances across a fully integrated circuit incorporating all the unit operations. This paper covers steps leading to early modelling of a gold processing plant based on a bromine/bromide lixiviant. Research conducted at SGS Lakefield in collaboration with Albemarle provided the data that were used in the development of this model. A previous investigation in this series described the leaching behaviour of various mineral types in Stabilized Bromine reagent. This paper is concerned with the gold recovery operations associated with a conceptual bromine leaching process. The recovery of gold by different types of resin and activated carbon was studied, along with various methods of stripping the gold from the extractant. The circuit is closed by electrolysing the spent leach liquor to oxidize some of the contained bromide back to bromine that would allow recycling the regenerated leach solution back to the leach step in the process.

Jan 1, 2015

By R W. Hutchinson

Cupreous pyrite deposits in Cyprus have many geologic similarities to Canadian massive sulphide copper-zinc ores as well as certain significant differences. A comparison of the Cyprus and Canadian deposits indicates a complex genetic history for the latter and suggests that their origin should be re-examined. The Cyprus ores occur in subaqueous extrusive rocks near and at the top of a Cretaceous volcanic pile or igneous complex. The rocks have not been deformed, nor have they been deeply buried or deeply eroded. Apparently the ores formed near or at surface in the top of the volcanic pile by a volcanic-exhalative process and from an ore-fluid of volcanic derivation. The Canadian deposits are of comparable composition and have similar geologic set-tings, but occur in the most ancient Precambrian rocks. Their enclosing Keewatin greenstones have, in most places, been deformed, regionally metamorphosed and invaded by granitic intrusions. Comparison suggests that the Canadian ores also formed initially near surface in ancient Keewatin volcanic complexes by a syngenetic, volcanic-exhalative process. Subsequently, during orogenesis, they were deformed, remobilized under conditions of elevated pressure-temperature and re-emplaced as epigenetic bodies into

Jan 1, 1965

By Walter Koellner

Today?s large electric mining shovels are significant users of power and represent peak loads of more than 3.5 MW to a mine?s distribution system. The power swings during normal operation can influence the line voltage at the Point of Common Coupling (PCC). The static converters for the shovel?s motions also create voltage and current harmonics which are fed back into the mine?s power grid. In addition, shovels themselves are affected by the power quality of the mine?s distribution system. This paper introduces the use of active IGBT rectifiers, also called Active Front Ends (AFE), as alternative to conventional, line commutated SCR thyristor rectifiers. The AFEs convert the AC line input into a controlled DC-link voltage. This DC voltage is then used as input to IGBT inverters, which power the AC motors of the shovel?s Hoist, Propel, Crowd, and Swing motions. The introduction of AFEs creates the following operational improvements: i) reduction of the Harmonic Current Distortion THDi from more than 40% to less than 4%; ii) full regenerative operation; iii) the potential for line voltage stabilization at the PCC; iv) high tolerance for line voltage fluctuations; v) improved dynamic performance, and, as result vi) higher availability and productivity of the shovel.

May 1, 2001

By C. Fleming, J. R. Goode

ABSTRACT: Data were produced from two uranium project studies that were conducted in 2008, both involving uranium recovery from leached slurry by resin-in-pulp (RIP) with strong base resins. In both studies, excellent metallurgical results were produced. The loaded resins were eluted with strong sulphuric acid and recycled through RIP circuits in an integrated process. Resin losses by either abrasion or mechanical breakage were immeasurably low. Metallurgical results from these two campaigns are presented, along with a case study economic analysis of RIP versus the alternative processes of counter-current-decantation or filtration and solvent extraction.

Jan 1, 2011

By Y. F. Jiang, K. Fang, Q. Q. Jiang, Q. Wu

Inter formational sliding of bedding planes between two different rock types in Badong formation is an important reason that leads to the instability and fracture of rock mass in this stratum. There are no specific research achievements on bedding planes between two different rock types in Badong formation. In order to study the shear mechanical properties of bedding planes between two different rock types. This paper using the software of particle flow code (PFC) and JRC model to establish several typical structures of different roughness coefficient of surface morphology based on the laboratory tests on silty mudstone and marlite in Badong formation. A great deal of numerical shear tests were carried out by ball production, radius expansion and servo infliction. The research results are as follows: First, shear strength of Badong formation is found to vary between that of silty mudstone and marlite isotropic planes by analyzing shear strength of the homogenous bedding planes and inhomogeneous rock types, we can find that the shearing strength in Badong formation is between silty mudstone and marlite isotropic planes and which is closer to the shearing strength of silty mudstone isotropic planes. Second, the basical friction angle of bedding planes between two different rock types in Badong formation is between silty mudstone and marlite isotropic planes and which is closer to the basical friction angle of silty mudstone between isotropic planes. Third, based on the experimental results, an expression is obtained to describe the relationship of the ratio of shearing strength between bedding planes of two different rock types and isotropic planes in soft rock, the rock combination coefficient, and the roughness coefficient. This study has important significance for further research on the shear mechanical properties of bedding planes between two different rock types.

Jan 1, 2015

By François Robichaud

"The Laronde mill has been in operation since 1988. Actual milling rate ranges from 7,000 to 8,500 mtpd. Laronde uses SAG/ball mill grinding followed by copper and zinc flotation circuits. A cyanidation/Merrill-Crowe process recovers the remaining gold and silver in the flotation tails.In 1999, the carbon in pulp circuit was replaced by a Merrill-Crowe circuit in order to cope with a much higher ratio of silver/gold associated with the discovery of the Penna shaft. Marine type diatomaceous earth was used as filter aid in both clarifier pressure leaf filters and recessed pressure filter presses from 1999 to 2005. In 2005, this filter aid was gradually replaced by alpha-cellulose after several laboratory and plant filtration trials. The selected cellulose is considered to be much less sensitive to parameters such as pH and reagent concentration and have increased clarifier and filter press filtration performance. Also, since cellulose is exothermic, replacing diatomaceous earth with cellulose as filter aid in the filter presses has increased calcining and oxidation rates in the calcining ovens since cellulose is exothermic. Finally, better calcining conditions have resulted in energy and reagent savings at the arc furnaces.This paper describes how the filter aid replacement has contributed to increasing productivity and Net Smelter Return of the refinery while reducing worker’s hazards and operating cost.INTRODUCTIONAll Merrill-Crowe circuits in the world are operated with filter aids. For years, the market for precoat filter aid has been dominated by mineral filter aids such as diatomite and perlite. Flowsheet and equipment selection at the Laronde refinery were performed in the late nineties. At that time, some key parameters of the design criteria had clearly identified marine type diatomaceous earth (DE) as the most successful filter aid. Parameters such as reagent cost and availability, clarity of the filtrate solution and good historical filtration performance in other concentrators had designated DE as the best suited filter aid. Pregnant solution processed in the refinery from its start-up through 2001 was fairly stable in flow rate and reasonable in terms of impurity content (cationic and anionic compounds)."

Jan 1, 2007

By J. W. Craig

CHROME ore, which is used in Canada in the production of ferro-alloys, in a variety of refractories, and indirectly in many chemical industries, is both commercially important and scientifically interesting. The sight of chromium metal is familiar to all of us in the home, the office, the automobile. Chromium is synonymous with armaments: it is understood to be one of several essential metals in tanks, which played an important role in the defeat of France in the spring of 1940. Chromium, in other forms, comes into our daily lives by way of paint and leather, of the familiar green ginger-ale and beer bottles, and more indirectly in every pound of steel produced in the .Dominion. Necessary to our civilization in peace and war, the ores of chromium occur in many corners of the earth. This paper attempts to describe the chemical constitution of chrome ores, their world distribution, and the various chrome products and their industrial applications in Canada.

Jan 1, 1940

By A. W. F. Smith, P. B. Prangnell, D. N. Crowther, P. J. Apps

It is well known that the refinement of grain size in metals leads to a significant improvement in important mechanical properties. As part of a European collaborative project, processing schedules have been investigated aimed at producing a homogeneous ultra-fine ferrite and spheroidised carbide aggregate microstructure structure in high carbon (CMn) steels (0.6-1.2wt%C), via conventional 'warm' rolling and innovative Equal Channel Angular Extrusion (ECAE). Suitable deformation schedules were determined from dilatometry and thermo-mechanical Gleeble simulations. Evidence of an ultra-fine ferrite and carbide aggregate microstructure following 'warm' rolling is given. A significant improvement in tensile strength, particularly proof stress (0.2%) was also noted in comparison to material deformed at higher temperatures. Concurrent Equal Channel Angular Extrusion (ECAE) experiments investigated microstructural evolution with incremental strain. Extensive analysis was carried out using various techniques, including high resolution Electron Back Scattered Diffraction (EBSD). Evidence of ferrite grain refinement was noted in a eutectoid composition steel. A sub-micron ferrite structure was observed following high strains (E-3.33) and the mechanical properties exhibit a marked increase in tensile strength.

Jan 1, 2004

By J. A. Relf

The construction of refineries and gas conservation plants in the general Edmonton area in the early 1950's made available large quantities of by-product liquified petroleum gases (LPG). These gases, together with discovery of increasing reserves of natural gas in the Edmonton area, provided Canadian Chemical Company with two of the necessities for petrochemical production, namely, available and reasonably priced raw materials and fuel. This paper outlines the development of the $83 million Edmonton plant from its origin, together with a brief description of the processes and some of the interesting features involved. Several economic aspects of the petrochemical industry are high-lighted including its importance to the local community and the province. The paper reviews the relationship between the oil and gas industry and petrochemical manufacturing and indicates some of the factors that may affect the future growth of the petro-chemical industry in Wes tern Canada.

Jan 1, 1962

By Peter Moser, Thoma Oberndorfer

"Within the research project “Mine Development” (Fettweis and Moser, 1990) a PC-based mine database has been built up since 1991 and so far includes detailed technical and economic data of about 150 under-ground hardrock mines in industrialized countries worldwide. These data represent about 50% of the underground hardrock mines in west and central Europe, Scandinavia, United States, Canada and Australia (Fig. 1). The mining operations included in the database have been visited directly and analyzed with respect to their deposit conditions, their general design and layout and also their operational and economic performance.The main aim of the Mine Database is to make a contribution to an improved planning of new underground hardrock mines. An analysis of current mine planning practices shows, that both personnel and company experience is still a dominant factor in planning new underground hardrock operations. Through the information included in the Mine Database the experience of a single per-son or company is supplemented by the experience of a wider group of people. The Mine Database makes the huge amount of experience that is available worldwide in the field of under-ground mining accessible for new mining projects. From that a contribution to a more reliable mine planning procedure based on the performance of existing mining operations is expected.In addition to its use in planning new mining operations, the Mine Database can con-tribute to the exchange of technical data among different mining operations, especially on equipment performance, etc. Such an information service is offered by the Department of Mining Engineering & Mineral Economics in Leoben and is already being used by different mining companies. To respect proprietory information, company specific information is not released under any circumstances.The cost of building up the Mine Database, so far, is about US$500.000 — two thirds of which is labour, and one third, travel."

Jan 1, 1996

By A. L. Irwin

THE problem of compensation for labour is probably the oldest and most complicated one in history. The wage that a man receives is possibly the most concrete thing he gets out of his job and, rightly or wrongly, is generally considered by him to be the most important item in connection with his daily work. How today workers in an equitable way has been the study of industrialists for many years, and a great number of ideas have been tried out in an effort to arrive at a reasonable solution of the question. The idea of establishing a measuring stick for various types of work has intrigued industrial management for a long time and, after considerable study, the principle of Job Evaluation has taken form unti1, at the present time, it is becoming increasingly useful to industry at large. Job evaluation is a plan which is used to determine the relative worth of occupations by means of arbitrary measuring scales. These scales are developed for individual industries and are generally 'tailor made' for each particular case. There are as yet no absolute methods of measuring the work done by human beings and, as a result, one has to depend on comparative values to arrive at conclusions. However, job evaluation has provided us with a basis of negotiation for wage rates which is more satisfactory than mere guess work or persona! opinion. It supplies a common ground for discussion which is understandable by all taking part and ensures that thinking with regard to wage setting is carried out along standard lines.

Jan 1, 1943

By M. A. Nagle

Various strategic projects were carried out in 2002 to increase the capacity of Teck Cominco's integrated zinc-lead smelter at the Trail operations site in British Columbia, Canada. The lead smelter treats the iron residue from the zinc plant and optimizes the overall zinc recovery. This paper summarizes two options that were considered to reduce the zinc content in the leaching iron residue. The first option involved increasing the capacity of an existing hot acid leach circuit up to the iron loading constraints of the circuit. The second sought to maximize the hot acid leach capability by separating the ferrite-rich solids, followed by aggressive hot acid leaching (>100°C) and subsequent iron precipitation. Different forms of iron precipitation were reviewed in order to determine the most effective and economical approach. Among these, was a novel high temperature ferrite conversion process. The technical results and selection criteria are presented together with possible ways to integrate the process concepts into the current sulphide leaching plant circuit. The first option was selected for implementation and is currently being operated successfully.

Jan 1, 2006

By Bennett McLaughlin

The Penna Shaft is the deepest single?lift shaft in North America. AGNICO-EAGLE started sinking the Penna shaft in 1995 with a hoisting plant capable of hoisting 1 800 tonnes per day from a 2 240-metre deep shaft. Exploration success at depth lead to the replacement of the existing double drum hoist by another double drum hoist capable of hoisting 7 000 tonnes per day. The use of another double drum hoist, instead of a Blair Multi-Rope winder, to hoist 24,5-tonne skips was only made possible by lowering the safety factor. This paper describes recent experiences at Penna and in South Africa, and examines the possibility of extending the double drum hoisting system to a depth of three kilometres.

May 1, 2003