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By M. Abumiya, N. Onodera

"The synthesis of large scorodite particles in non-ferrous metallurgical industries usually requires a high-cost operation involving heating and high-pressure autoclaving. To overcome these obstacles, an atmospheric-pressure process for scorodite synthesis (DMSP®) was developed, in which ferrous ions were oxidized by oxygen gas in the presence of pentavalent arsenic ions. This process gives scorodite of good crystallinity with particle sizes as large as 15-20 µm. The solutions used for scorodite synthesis in the DMSP® are prepared from various residues containing arsenic from non-ferrous smelters. The solutions may be contaminated with Cu, Sb, and Bi, for example, and therefore the effects of such impurities on the formation of crystalline scorodite need to be investigated. In this study, the effects of Cu, Sb, and Bi contaminants on the formation behaviors of scorodite particles in the DMSP® were investigated systematically.INTRODUCTIONThe synthesis of crystalline scorodite (FeAsO4·2H2O) is a suitable method for arsenic (As) stabilization and storage of As-containing by-products such as flue gas dusts in non-ferrous smelters. It is expected that the formation of large, highly-crystalline scorodite particles would be an ideal method for avoiding the release of arsenic to the environment. Generally, autoclave methods under pressurized oxidation conditions at temperatures above 100°C have been used for the formation of arsenic minerals such as scorodite. However, the autoclave method requires sealed vessels that are resistant to high pressure, heat and acids. This process is also unfavorable on account of the high construction expenses, and high running costs as a result of vapor heat loss. Processes for synthesizing scorodite under atmospheric conditions at temperatures below 100°C which do not need an autoclave have therefore been extensively investigated (Demopoulos, Droppert, & VanWeert, 1994; Demopoulos, 1996; Demopoulos, Lagno, Wang, & Singhania, 2003; Droppert, Demopoulos, & Harris, 1996; Filippou & Demopoulos, 1997).Recently, Fujita et al. (Fujita, Taguchi, Abumiya, Matsumoto, Shibata, & Nakamura, 2008a, 2008b, 2009; Fujita, Taguchi, Kubo, Shibata, & Nakamura, 2009; Fujita, Taguchi, Shibata, & Nakamura, 2009) developed a new method for producing large scorodite crystalline particles with improved filtration and washability properties at normal atmospheric pressure and temperatures below 100°C. In the new method, oxygen gas (O2) is blown into solutions containing a high concentration of arsenic ions (As(V)) and ferrous ions (Fe(II)). The Fe(II) ions were subsequently oxidized to ferric ions (Fe(III)), resulting in the formation of large scorodite particles. High supersaturation of solutes such as Fe(III) will result in excessive nucleation, and the formation of poorly crystalline phases. The scorodite formation must therefore be conducted in a manner that avoids the critical supersaturation level being exceeded. It is supposed that the oxidation of Fe(II) to Fe(III) by O2 gas in the new method suppressed the supersaturation of Fe(III) during scorodite formation. The low Fe(III) supersaturation resulted in formations of highly crystalline scorodite particles of size of around 20 µm. In June 2008, based on the developed process described above, DOWA began experiments to verify the industrial capability of a plant with a capacity of 30 MT/month of As. It was successfully proven that it is possible to produce crystalline scorodite industrially on a commercial scale. This process was named and trademarked as DMSP® (Kubo, Abumiya, & Matsumoto, 2010)."

Jan 1, 2012

By S. Esfahani, M. Barati, Y. Kauwachi

"Heat recovery from slag has gained attention due to its high potential in lowering energy intensity of metal extraction processes. A direct method to recover the thermal energy of slag is to use countercurrent air flow that extracts the heat from falling droplets. Often, the solidified slag is aimed to be used as a substitute for Portland cement, thus high cooling rates are required to form an amorphous slag with sufficiently strong hydaulicity. Rapid cooling however involves using large gas flow rates that in turn lower the thermal efficiency of the process. This article presents a mathematical model that was developed to determine the optimum conditions in the heat recovery process and to investigate the effect of the air flow and granule diameter on the cooling rate of the droplets as well as the thermal efficiency of the heat recovery system. INTRODUCTIONMetallurgical slags are the largest by-product of high temperature materials refining and extraction processes. The total amount of metallurgical slag produced in the year 2008 has been estimated at up to 422 million tonnes containing up to 222 TWh/y (Barati and Esfahani, 2011) of thermal energy. Over the past four decades attempts have been made to recover this substantial amount of energy as heat, electricity, or fuel, while none of the proposed method has been commercialized yet.During slow cooling the slag tends to crystallize the constituents (CaO, SiO2, Al2O3, etc.) into a hard, heavy solid. In the past, over 90% (Bengt, 1983) of the molten waste was discharged onto heaps and allowed to cool slowly, then crushed and used in road construction or land filling or as coarse aggregate for concrete. However, later it was found if cooled rapidly, the slag can be used as a substitute for Portland cement. As a result, processes such as wet granulation were created in which molten slag is fragmented with water, forming amorphous (glassy) phases. Despite its effectiveness in producing a suitable material, heat would not be recovered through this process. Thus, dry granulation was introduced in 1930’s and was developed further in 1970 – 1980’s."

Jan 1, 2012

By J. Ouellet

"ABSTRACTA brief background on in-situ testing of mine backfill, as well as pressuremeter testing is briefly described, and results from an in-situ testing on paste backfill are presented. A series of self-boring pressuremeter tests were done from the top of a backfilled stope in an underground mine. The tests were conducted along a 20-metre vertical line in the centre of the stope. Some 14 tests were performed along this depth. The instrument used was a Camkometer built by Cam Insitu, Cambridge. The instrument proved to be efficient and reliable for underground testing in a cemented paste backfill. The testing program was conducted within the planned schedule with a high success rate. The test done in this study permitted the measurement of paste backfill strength, stiffness and in-situ horizontal stress within the backfill. RésuméUn bref historique des essais in situ dans le remblai minier est présenté. L’essai pressiométrique est décrit succinctement et des résultats d’une campagne d’essai dans un remblai en pâte sont présentés. Un programme d’essais au pressiomètre auto-foreur a été réalisé à partir du sommet d’un chantier remblayé sous terre. Les essais ont été réalisés le long d’un ligne vertical d’environ 20 mètres pour un total de 14 mesures. Le Camkometer de la firme Cam Insitu de Cambridge a été utilisé. Cet instrument s’est avéré efficace et fiable pour tester le remblai en pâte cimenté sous terre. Le programme d’essai s’est déroulé à l’intérieur de l’échéancier prévu avec un taux de réussite élevé. Ces essais ont permis de déterminer la résistance, la rigidité de ce remblai ainsi que les pressions in-situ prévalant dans le remblai."

Jan 1, 2000

By S. Beitler

The availability of renewable energy does not meet the demands of consumption. Hence, fossil fuels will continue to be an important energy source, and coal promises to cover the requirements for the coming decades. Because of its high energy content, deep lying bituminous coal and anthracite are important for energy generation. One trend in the future of coal mining is thin seam mining, because thick seams more and more have been exploited. A well-known and approved longwall mining method for thin seams is plowing which has big advantages compared to a shearer because of its compact design. The extraction of those thinner coal seams will become more and more important in coal industry and therefore the plow will receive more attention in future. Most approaches in longwall automation are focused on the shearer and need a more or less intelligent exploitation machine. Therefore those approaches cannot be used for the plow technology. The authors introduce a shield-data-based horizon control (SDHC). The developed approach integrates the shield data provided by the roof support and process monitoring into the horizon control process to keep the plow in seam even if the seam trend changes. This control concept can be used for the shearer as well as for the plow. The basic idea of SDHC for plow application will be introduced in this paper and first simulation results will be shown.

Aug 1, 2013

By W. Petruk

Mineralogical studies and concentration tests were conducted on samples from an oolitic iron deposit from the Peace River district in Alberta to determine what concentrate grades and metal recoveries could be obtained. The samples assayed 32 to 37 wt. % Fe, and consisted of goethite, nontronite, ferruginous opal, siderite , quartz, amorphous phosphate and illite . Flotation with fatty acids yielded the best over-all results. A flotation concentrate from a composite sample of the iron horizon assayed, by weight, 43.0% Fe, 12.3% SiO2 , 1.9% CaD, 0.9% MgO, 4.5% Al2O3 and 2.0% P2O5 and lost 17.2% on ignition, for an iron recovery of 48.8% and a silica rejection of 80%. When heated to drive off the water, the concentrate assayed 52 w t. % Fe and 14. 8% w t. % SiO2

Jan 1, 1977

By A-A. Bogno, M. Rappaz, J. Valloton, H. Henein

"Rapid solidification of Al-Cu droplets of eutectic composition was carried out using Impulse Atomization in an argon atmosphere, to study the microstructures forming at different cooling rates and undercoolings. Two distinct morphologies were observed within the investigated Al-33wt%Cu droplets microstructures: (i) A regular lamellar morphology and (ii) an undulated morphology. The volume fraction of each type of morphology was measured as a function of the droplet size and the nucleation undercooling was deduced using the hypercooling limit equation. The scale of the microstructures was determined through measurements of inter-lamellar spacing across and along the growth direction. Growth velocity and undercooling were deduced using Jackson and Hunt (1966) eutectic growth theory. Finally, mechanical properties were estimated through micro-hardness analysis using a Vickers hardness tester, revealing exceptional properties for an aluminum-copper alloy. Indeed, the hardness values, increasing with growth rate and undercooling, were 3 times higher than the values obtained in hypo-eutectic Al-Cu alloys.INTRODUCTION Eutectic alloys are very attractive due to their good fluidity allowing ready shaping of parts in casting processes as well as in thermal spray deposition. In addition, they yield microstructures with high mechanical properties, by the virtue of their scale/size which is defined by the solidification parameters and the thermodynamic and thermophysical properties of the given alloy. Therefore, it is important to understand the relationship between the microstructures and the solidification parameters of eutectic alloys in order to control their solidification path and mechanical properties. The latter could be improved by either adding an appropriate strengthening component to a base eutectic material (Böyük, MaraslI, Kaya, ÇadIrlI, & Keslioglu, 2009) or by refining the microstructures for more effective dislocation pinning (Campbell & Campbell, 2003). Tailoring the microstructure can also be beneficial to chemical (Freitas, Osório, Spinelli, & Garcia, 2014; Osório, Freire, Caram, & Garcia, 2012) or electrical (Kaya, 2012) properties of the material. Eutectic-type microstructures, usually formed from liquid (eutectic transformation) or solid (eutectoid transformation), are made up of two or more different phases, generally of lamellar or fibrous (rod like) morphologies (Kurz & Fisher, 1998). In general, a binary eutectic structure can be regular (when both phases are non-faceted) or irregular (one of the two phases is faceted), the two solid phases having roughly the composition of the liquid from which they are formed."

Jan 1, 2017

By K. Loutet, A. Guenkel, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985. Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. The sulphur dioxide (SO2) for this process can be supplied either as liquid SO2, SO2 gas or as a sulphite-based salt. The majority of SO2/air operations have used sulphite-based salts as the ‘SO2’ equivalent probably due to low capital cost. Liquid SO2 has also been used frequently, but due to concerns with safety and availability, this option is often not preferred. The solid salt sodium meta-bisulphite (SMBS) is commonly employed, but its cost is an order of magnitude higher than that of sulphur. Due to the high cost of SMBS, the increased capital cost for a sulphur-burning SO2 gas plant (green field or retrofit) usually has a pay-back of less than three years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas volume. Therefore, a SO2 gas plant will not trigger the Canadian Environmental Protection Act (CEPA) E2 Regulations or the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and El Boleo).This paper focuses on the production of sulphur dioxide gas generated on site and on demand for the use in hydrometallurgical processes. The capital and operational costs of a SO2 gas plant is compared to conventional process alternatives using sulphite-based salts or liquid SO2."

Jan 1, 2016

By J. A. Finch

The metallurgical performance of a flotation cell is strongly influenced by the features of the bubble population, characterized by the gas dispersion properties, a collective term including bubble size, superficial gas velocity and gas holdup. It is required that gas be well distributed throughout the cell. Gas distribution is estimated here by simultaneous measurement of gas velocity (Jg) at different distances from the center (radial Jg mapping). This communication describes a technique to perform radial Jg mapping together with fundamentals for the interpretation of the data.

Jan 1, 2009

By B. Erdem, N. Çelebi

An important problem associated with tandem dragline systems is that of matching the productive capability of individual draglines in the combination. In this paper, a dependence mechanism among draglines in a tandem system is described, and possible consequential problems in a poorly-matched system are defined. The rate of linear advance and the cost of stripping are determined as two major indications for an efficient operation. The proposed decision criteria and the underlying mechanism to select a synchronous couple are introduced and used in simulating tandem dragline systems. The developed model is tested on a hypothetical strip mine where pullback stripping is applied with a tandem dragline system.

Jan 1, 1999

By R. Haecker, S. Bajic, R. Thorpe, A. Palko, M. Kalstrom

"Historically, mineral processors have used inferential data like plant instrumentation, assays, and grind sizes to monitor the performance of their plants. The ability to monitor the minerals themselves on a daily basis has eluded all but the very largest and richest of operations. The advent of a new generation of compact, robust, and user-friendly SEM-based automated mineralogy systems looks set to accomplish this, aiming to bring daily mineral monitoring of plant performance within the reach of all mills from mid-size upwards. This paper describes the use of this machine at Greens Creek Mine, a 2.5 ktpd Ag-Au-Pb-Zn operation with a complex flotation flowsheet. During the trial, the machine provided turnaround from sample collection to reporting averaging 24-36 h for key daily samples. All equipment was located within the compact mill, and proved highly reliable despite the challenging environment. Turnaround time was fast enough for metallurgists to understand, and, where possible, respond to ore and process changes while they were still happening. The plethora of data generated was filtered to a simple report whereby mill management could quickly absorb key daily mineral-based performance indicators. This paper will describe how the data was used to understand the key drivers behind metallurgical efficiency at Greens Creek, and how metallurgists began using the information to enhance daily mill performance."

Jan 1, 2014

By Joerg Hammerschmidt, Marcus Runkel, Steffen Haus

Given the limited number of new plant construction, focus is turning to the optimization of existing metallurgical roasting plants. To meet the goals of high process efficiency with limited capital expenditure, plant owners are looking for new strategies, including digitization and expert support. As a supplier for numerous roasting, gas cleaning and sulfuric acid plants, Outotec has intensified its effort in recent years to develop solutions to accommodate increasing customer need. This article presents a short review on how Outotec is applying advanced control tools for the fluidized bed industry. Focus will be given on how to transfer the existing technology (used in selected Zinc roasting plants for over a year now) to copper roasting. Outotec has developed the Pretium Roaster Optimizer, a system based on heat and mass-balanced simulation models. Direct experience with this technology will be shared and will highlight similarities to the Partial and Sulfate Copper roasting processes. Pretium detects equipment and plant bottlenecks and provides consistency in process development. The Pretium program combines 24/7 advanced online digitalization tools, along with expert personal support when required. INTRODUCTION Fluidized bed reactors have been used for commercial-scale zinc and copper roasting since the 1950s. While the principles of roasting remain unchanged, over time, the technology has advanced to improve process control of roasting plants. In the past, environmental and safety standards were the driving forces for improvement of equipment and plant design. Today, the emphasis is on plant efficiency and optimization. Another change has come in process control philosophy. While plant control and operation have traditionally been the responsibility of owner/operators, they have now shifted to include both integrated digital tools and specific know-how from engineering companies. This can be seen from the earliest design stages through commissioning and into production, as evidenced by zinc roasting plants in Mexico, Brazil and Turkey.

Jan 1, 2019

By A. Lee Barrett

"THE COAL INDUSTRY of the United States• and Canada has made great progress in recent years. Coal mining in •the old days represented one of the most arduous tasks for labour and industry, but over the years great progress has been made in reducing the effort required from labour. Also, the tonnage produced per man, the cost of the coal per ton, and the overall safety of the operation, have been greatly improved.Looking back over the past fifty years:, the era can be divided into four principal parts: (a) hand-loading, (b) track mining methods, (c) off-track mining methods, and (d) continuous mining. For many years, all of the coal was won by hand-mining methods. The first forms of mechanization •resembled the move from the horse •and buggy to the automobile. Early track mechanical mining methods were usually adaptations of the direct methods involved in hand-mining, with each improvement directed toward some specific process. A revolutionary development came about with off-track mining methods. The first efforts in this direction were provided by off-track mechanical loading machines, which loaded the cars •on track and differed from conventional track mining methods only in that the loading machines themselves operated on the mine floor. With the advent -of the shuttle car about ten years ago, true off-track mining came into being, and real progress in this direction began to be made.At the present time we •are at the beginning of a new era -.the era of continuous mining. There will be a period of development with some time needed before the system is generally applied throughout the industry, but -already enough •has been done to indicate rather dearly what the future holds in this direction."

Jan 1, 1953

By H. V. Kinsey

"IntroductionTITANIUM is probably the most widely publicized metal today. Much has been written, both in the lay press and the technical press, about its properties and potentialities. In view of the fact that Canada possesses large quantities of titanium-bearing ore, and could conceivably become a major producer of metallic titanium, it was felt that a paper dealing mainly with the physical metallurgy of titanium would be of interest to this Institute. This paper is concerned chiefly with the useful properties of titanium and its alloys and the fundamentals governing the modification of its properties by alloying.Physical Properties of TitaniumTitanium belongs to a family of metals that have been termed 'gas sensitive' (I), because their mechanical properties are altered by certain gases which they readily absorb and retain. Other metals of this group are zirconium, hafnium, vanadium, columbium, tantalum, and chromium. Titanium has a strong affinity for oxygen and nitrogen and once it has absorbed these gases they cannot be removed either by melting in vacuum or by any degassing agent. These gases, when present in excess of about half a per cent oxygen plus nitrogen, render the metal brittle and useless as a structural material.Some of the typical physical properties of titanium are listed in Table I along with those of common structural metals for comparison."

Jan 1, 1953

By V. V. Pankov, W. R. Chen, L. R. Zhao

Diffusion nickel aluminide and overlay NiCrAlY coatings were deposited on single crystal Ni-base superalloy CMSX-4 substrate using the chemical vapour deposition and cathodic arc evaporation techniques, respectively. The NiCrAlY coating underwent a post-deposition heat treatment in an argon atmosphere at 1100°C for 2 hours. All the coated specimens were subjected to furnace cyclic oxidation testing at 1000°C up to 1500 one-hour cycles. The morphology, elemental composition and phase constituents of the oxide scales formed on the coating surface were analyzed using scanning electron microscopy, energy-dispersive spectroscopy and X-ray diffraction. It was observed that the diffusion aluminide coating experienced accelerated weight gain at an early stage of the test (150-400 cycles), whereas the overlay NiCrAlY coating fabricated by cathodic arc evaporation maintained steady-state weight gain throughout the entire 1500 cycle test duration. This difference in oxidation behaviour between the two types of coatings is attributed to the early development of nickel-aluminum spinel on the surface of the diffusion aluminide coating, in contrast to the stable aluminum oxide scale formed on the overlay NiCrAlY coating during cyclic oxidation testing.

Jan 1, 2015

By B. Surender Mohan

Mother Earth being a treasure of minerals, it is prime duty of the mankind to preserve this natural source to ensure steady growth of the nation. Utmost care is to be taken to see that these natural resources are explored and exploited scientifically in a sustained manner to ensure that the resource base improves and last longer. In this backdrop, the topic of ?Lignite - its resource and technology options to exploit deep seated deposits? is an apt subject to be deliberated upon in the present context, where the shallow deposits may slowly get dwindled. I shall deliberate upon the resource base of lignite, production profiles of the last five decades, consumption pattern, demand / supply projections, future available technology options to exploit the deep seated deposits, growth trends of the sector etc. in my paper. With the available resource base and future technology options, I can confidentially make a statement that ?lignite will remain as cocontributor along with coal to India?s energy generation and may well maintain its same status in the 21st century too, as it has been in the later part of the twentieth century?.

Aug 1, 2013

By A. A. Shirzadi, E. R. Wallach

"Liquid gallium has been used successfully to modify/remove the surface oxides prior to diffusion bonding similar and dissimilar nickel-base superalloys. Using this approach, bonds in nickel-base superalloys with ""virtually invisible interfaces"" were produced, and the compositions in the bond region were very close to those of the bulk alloys. Room temperature tensile and bend tests showed no preferentially failure at the bond lines. Creep tests on samples made between two different Inconel alloys also showed failure away from the joint, i.e. in the parent metal of the Inconel alloy with lower creep resistance. The high temperature lifetimes of these samples were as long as those of the unbounded Inconel, confirming that the joining approach has no adverse effect on the nickel-base superalloys being joined."

Jan 1, 2006

By A. A. Holland

Introduction The world's largest known deposits of natural sodium sulphate (Glauber salt), generally termed 'alkali ' throughout western Canada, are located in the Province of Saskatchewan: reserves are estimated to exceed 200,000,000 tons. These are surface deposits resulting from the recent or present-day natural evaporation of brines, in which respect they are similar to those occurring in certain other parts of the world, as in semi-arid sections of the United States, Russia, Germany and Austria. In some areas, underground deposits formed hundreds of thousands of years ago have been _encountered in drilling, and indications are that they also were formed under arid or semi-arid conditions. The master key to the formation of deposits of natural sodium sulphate, wherever they occur, is a climate, either past or present, under which evaporation exceeds precipitation over a considerable period of time. Commercial development of the Saskatchewan deposits began about thirty years ago. Previously, the demand for sodium sulphate had largely been met by salt cake produced as a by-product in the manufacture of hydrochloric acid from common salt. The rapid increase in the production of Kraft paper and, more recently, the development of synthetic detergent materials, have caused a marked increase in the market for sodium sulphate. This chemical gives the extra toughness to Kraft paper and is used in detergent compositions in proportions as high as 75 per cent. Saskatchewan now has six commercial plants producing natural sodium sulphate. Production from each in the fiscal years 1947 and 1948 is shown in Table I. The newest and latest plant is that of Saskatchewan Minerals, at Chaplin, which 1s designed to produce up to 150,000 tons of salt cake, 98.5 to 99.5 per cent pure, yearly. This is equivalent to about 24 percent of the total United States production of crude commercial salt cake for 1947.

Jan 1, 1949

By D. J. W. Piper, T. Hundert, G. Pe-Piper

"Abstract - Potentially commercial deposits of kaolin are found in the fluvial Lower Cretaceous Chaswood Formation, the sedimentologically proximal equivalent of deltaic sediments of the offshore Scotian basin. The geological setting of the kaolin deposits has been interpreted from high-resolution seismic-reflection profiles and boreholes, and mineralogical studies on one reference borehole. The kaolin is a product of early diagenesis involving meteoric water below the water table. The distribution of kaolin is controlled by the presence of intraformational unconformities that were sites of ground water recharge, and are marked by the development of oxisols above the water table. Such diagenesis was facilitated by interbedded, loosely consolidated, permeable sandstone. The highest-grade kaolin deposits are found in areas close to river belts, where overbank muds were not sufficiently drained to develop paleosols, but where later uplift created intraformational unconformities. In the sandstone, meteoric water flow altered feldspars to kaolin, thus yielding commercial silica sand deposits. It also altered ilmenite to rutile, which is concentrated as secondary placers in modern rivers that have eroded the Chaswood Formation and tills derived therefrom. Sommaire - Des dépôts de kaolin potentiellement économiques ont été notés dans la Formation de Chaswood d'’âge Crétacé Inférieur, laquelle constitue un équivalent latéral en milieu fluviatile aux sédiments deltaïques du bassin de Scotian. Le contexte géologique de ces dépôts de kaolin a été interprété a partir de profils de seismique-réflection à haute résolution, de sondages, et d’études minéralogiques sur un sondage de référence. Ce kaolin est un produit diagénétique précoce formé par de l’eau météorique sous le niveau de la nappe phréatique. La distribution du kaolin est contrôlée par la présence de zones de recharge associées à des discordances intraformationelles marquées par le développement d’oxisols au-dessus du niveau de la nappe phréatique. La présence d’interlits de grès perméables faiblement consolidés a contribué à l’efficacité de ce processus diagénétique. Les dépôts de kaolin les plus riches se trouvent en périphérie des rivières, là ou les boues de la plaine d’inondation n’étaient pas suffisamment bien drainées pour permettre le développement de paléosols, mais où des mouvements verticaux subséquents ont crée des discordances intraformationelles. La circulation d’eau météorique dans les grès a entraîné l’altération des feldspaths en kaolin, générant ainsi des dépôts économiques de sable de silice. Elle a aussi causé l’altération de l’ilménite en rutile, que l’on trouve dans des placers secondaires situés dans des rivières contemporaines qui ont érodé la Formation de Chaswood et les tills qui en sont dérivés."

Jan 1, 2006

By K. S. Coley, M. A. Rhamdhani, G. A. Brooks

Interfacial phenomena in high temperature reactions such as between iron alloy and slag is well documented but not fully understood. It is believed that a gradient of oxygen concentration plays an important role to the occurrence of such phenomena. This article describes the results from the continuation of the study of interfacial phenomena between Fe-Al alloy droplets and CaO-SiO2-Al2O3 slag. Materials characterization techniques involving microscopic observations, depth profiling, bulk, point analysis and were carried out. The roles of oxygen as well as other factors that contribute to the interfacial phenomena were evaluated. The results and their implications to steelmaking will be discussed.

Jan 1, 2004

By D. Perednis

Fuel cells with thin samaria-doped ceria (SDC) electrolyte films deposited onto an anode support using spray pyrolysis were fabricated. The SDC films were deposited onto porous NiO-YSZ substrates at deposition temperatures between 400°C and 450°C. The influence of process parameters such as deposition temperature, flow rate, type of salt and salt concentration on the quality of the film was studied. A smooth dense film was successfully deposited using the precursor cerium ammonium nitrate and samarium nitrate dissolved in butyl carbitol (33.3 vol.%), 2-methoxy-l-propanol (33.3 vol.%), and ethanol (33.3 vol.%) solvent mixture. A deposition rate of 125 nm/h was achieved.

Jan 1, 2005