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By M. Yavuz

As a branch of Operations Research, decision making is a widely used application in both science and social sciences. There are many different methods developed to solve decision making problems in the literature. In this study, Fuzzy Analytic Hierarchy Process (AHP) method is performed for the selection of reclamation project selection in an open pit mine and the optimal solution of the problem is investigated. Different reclamation project alternatives are prepared for an open pit mine, which continues to its production activities in magnesite sector in Turkey. The data obtained from Magnesite Cooperation is used in the application of the method. A decision-making process is prepared as considering the project alternatives for the purpose of selecting the most suitable reclamation project. The entire criteria that affect the decision-making process are identified and transformed into a hierarchical structure. The problem is solved by using Fuzzy AHP method developed according to this structure. It is found that Fuzzy AHP is a method that may help decision-makers in solving different decision-making problems in mining.

Aug 1, 2013

By Zoë Mullard

Just as a mine has a lifecycle, employees working within the mining sector also make several transitions throughout their career, from initial recruitment to retirement from the industry. Throughout the employment lifecycle, employees bring skills and knowledge that significantly contribute to the global economy. These skills are developed through education, professional training, coaching and through hands-on experience. Despite the current economic conditions and the demand for minerals, the mining industry is facing a substantial skills shortage due to the disparity between the number of new workers entering the mining industry and a largely ?graying workforce?. Although educational programs continue to evolve to attract people with a wide range of skills, the diversity of jobs and the strains of working in remote mining operations continue to present challenges for recruitment and retention of employees. This gap also presents challenges around knowledge transfer at a corporate and mine-site level; employers will require cultural and techno-sociological approaches to ease through these transitions. At the same time, there has been an explosion of social media tools that facilitate information sharing, cross-organizational collaboration, distance learning and knowledge capture. These tools have become increasingly popular in the last few years and their applications vary widely. The mining sector has started to adopt these tools for a number of purposes, including opportunities to harness social media to enhance human resources interactions, outreach and oversight. This paper will outline several case studies that explore leading practices for how the application of new media can assist organizations and individuals as they progress through their careers. This paper will illustrate how new social media communication technologies can be used to increase employee engagement and build organizational capacity in the mining industry. The paper will also include strategies for how to implement social media to enhance human resources applications and will cover ideas for monitoring and evaluation.

Aug 1, 2013

By Jean Dugas, Roger Sirois

The Mineral Deposits Service of the Quebec Department of Natural Resources is engaged in the preparation of metallogenic maps as a contribution to the Canadian Sub-Committee of the Metallogenic Map of North America. The preliminary work is being done on large-scale maps. The main objective is to clearly represent information on ore deposits in a suggestive way. The design of the legend to meet these requirements is discussed. As these maps are still only descriptive, a further step will be the interpretation of data into metallogenic maps with Jess emphasis on the individual deposits and more on the metallogenic factors. Both types of map should prove useful in the search for ore deposits; the first by providing at once a large amount of information, the second by suggesting the ore controls.

Jan 1, 1967

By C. H. Madsen

THE Hard Rock gold mine is in the Little Long Lac mining area, Thunder Bay district, northwestern Ontario. It is four miles by road from the town of Geraldton, which is on the Canadian National railway, 180 miles northeast of Port Arthur. The original discovery of gold-bearing quartz veins on the property was made in 1931. Shaft sinking began in the fall of 1934 and approximately 7,400 feet of lateral development on four levels was completed. In 1935, further discoveries were made half a mile west of the early workings, and the No. 2 shaft was sunk in this area in a porphyry zone. In January, 1938, a 20C-ton cyanide plant was completed and began drilling ore from the gold-bearing porphyry orebody. The daily feed was increased gradually to 300 tons in the next six months and a recovery of 97.5 per cent was effected. During the summer of the same year, a new and larger orebody was discovered to the north of the porphyry zone. It occurs in a band of iron formation and contains a high percentage of pyrite and arsenopyrite. Extensive tests were rr.ace on this sulphide ore in the Mines Branch ore dressing laboratory at Ottawa, in the laboratory of Canadian Industries, limited, at Toronto, and later at the mine, to find a suitable method of treatrr.ent. As a result of this research, a Potation plant was added to the original cyanide mill and on November 7th, 1938, differential flotation was used to separate the pyrite from the arsenopyrite fraction of the ore. The pyrite concentrate was re-ground and cyanide:l, and the arsenopyrire concentrate was stored for subsequent treatment. Differential flotation was discontinued in April, 1939, in favour of bulk formation of all the sulphides, and the whole cyanide residue was stored. On March 15th, 1939, a 10-ton pilot roaster was completed and rests were conducted on the arsenopyrite concentrate and the bulk concentrate. The results obtained led to the building of two roasters of the same type, large enough to roast all the concentrates. These roasters were put in operation on September 24th, 1939, and the calcines were cyanided in the original circuit.

Jan 1, 1941

By V. L. Mitsopoulos

This paper provides a summary of tailings disposal techniques and the improvements that have been made through the introduction of thickened tailings disposal. The general properties and characteristics of thickened tailings are described, as is a design process for selecting appropriate technologies for thickening, pumping, transporting and storing tailings. The factors affecting the selection of an appropriate disposal site and operational considerations for the effective utilisation of tailings storage areas are also documented.

Jan 1, 2006

By F. J. Reichhardt

Abstract -The Molopo Farms Complex is a major, layered ultramafic/mafic, early Proterozoic intrusion which is totally covered by sediments of the Karoo and Kalahari Formations and situated in southern Botswana and northeastern South Africa. The approximately 3000 m thick, generally fine- to medium-grained ultramafic and mafic cumulates are intrusive into equivalents of Transvaal Supergroup sediments and lavas. Multiphase deformation resulted in tilting and segmentation of the Complex into individual tectonic blocks. Sr isotopes document at least two chemically distinct parental liquids which interacted in a complex manner to form an approximately 1000 m thick rhythmically layered succession which straddles the ultramafic/mafic boundary. Repeated mixing resulted in a complex cryptic layering pattern and numerous sulfide-enriched layers which contain significant PGE +Au concentrations.

Jan 1, 1994

By W. G. Hubler

It has been within only the last two or three years that enough progress has been made in preferential flotation to warrant metallurgists in recommending the installation of commercial-sized plants for the treatment of copper-zinc-iron ores. Until the new processes had been worked out successfully, the treatment of this type of ore had proved a stumbling block in the path of metallurgical progress. Separation of lead-zinc ore is comparatively simple. A lead-zinc ore low in iron may be separated and concentrated by gravity con-centration, provided it is not necessary to grind too fine. Owing to the specific gravity of chalcopyrite and sphalerite being so nearly the same, however, their separation by gravity concentration is out of the question. Complex lead-zinc-iron ores in which the several minerals are intimately associated, requiring fine grinding to free them, have been successfully treated by flotation for the past fifteen years. Galena is easily floated, and its flotation, unlike that of chal¬copyrite, is not affected by the reagents used to inhibit the flotation of sphalerite and iron sulphides. When an attempt was made to use the methods of lead-zinc se-paration on copper-zinc ores, it was found that the depressant re-agents added to inhibit the flotation of the iron and zinc minerals would, under certain conditions, depress a large part of the copper. It was also recognized that, in the grinding of copper-zinc ore, soluble salts were generated which were detrimental to flotation unless properly controlled. The main part of this paper will be a discussion of solutions in the grinding circuit in relation to the pro¬duction of soluble salts and their effect on flotation.

Jan 1, 1931

By John Russell

"The South American mining community leads the world in recognition and adoption of the latest grinding mill relining technologies. Clearly this region has recognised the benefits of improved relining performance.Six of the seven RUSSELL TWIN 8 Mill Relining Systems, ordered to date, are either operating or being manufactured for South American mine sites.This paradigm shift, towards very short relining times, aims at displacing mill relining activities from the critical path of concentrator maintenance shutdown schedules.The first uses of the RUSSELL TWIN 8 Mill Relining System have seen some of the highest SAG mill new liner placement rates ever observed by RME, as would be expected with two, independent Machines working simultaneously in the one mill.The liner-replacement-rate, averaged over the whole reline, is good (27% improvement over single Machine System in the same mill) but short of full potential. This modest result can be attributed to reline crews unfamiliarity with RUSSELL TWIN 8 System operation.This paper compares a sample of conventional (single machine) RME Mill Relining System performance data with one ‘double head’ mill liner handler by others. Early performance of Escondida’s new RUSSELL TWIN 8 System performance is then compared with recent single Machine data from Escondida, immediately prior to RUSSELL TWIN 8 commissioning. RME and Escondida look to constantly improving RUSSELL TWIN 8 System performance as full operational familiarity is achieved.Also, the preparation of this paper revealed a need to develop a global industry standard for mill relining data collection. A web based platform, to develop and then distribute standardised data collection templates, is discussed in Annexure 1."

Jan 1, 2010

By A. Quilodran, B. Jakovljevic, T. McCallum, P. Wong

"Rare earth separation by solvent extraction (SX) requires multiple separation plants each consisting of many extract, scrub, and strip stages to separate the individual metals. SX modeling advances have brought benefits to circuit design and process optimization by quickly narrowing test conditions without the need for exhaustive laboratory studies. Modeling can be used to optimize circuit configuration, O/A ratios, and acidities, which allows for CAPEX and OPEX savings. A comparison between pilot plant data and the results expected from modeling is presented for rare earth separations with CYANEX® 572.INTRODUCTIONRare earth separations can be difficult due to limited separation between the elements (Xie, Zhang, Dreisinger, & Doyle, 2014). This requires relatively complex solvent extraction circuits utilizing multiple extract, scrub, and strip stages as well as multiple SX configurations to achieve the desired metal purities. Designing rare earth circuits can be complex, and significant time and testing may be necessary to determine the required staging and optimal conditions.Circuit modeling for rare earth separations has been introduced to the industry using CYANEX® 572 extractant (Soderstrom, McCallum, Jakovljevic, & Quilodran, 2014). CYANEX® 572 is an acidic organophosphorus extractant formulation which has a weaker ligand-metal complex strength than that of the traditionally used phosphonic acid extractants. This allows efficient extraction while requiring a significantly lower acid concentration for stripping (Wang, Li, Zhao, Dong, & Sun, 2015). The reduced acid requirement in strip is expected to provide OPEX savings.The modeling can be utilized to quickly determine the required acidity and organic/aqueous (O/A) ratio for a given separation. It is also expected to reduce CAPEX requirements as optimal staging can be determined, and implemented.CYANEX® 572, combined with modeling, was utilized to produce a purified dysprosium (Dy) stream. To achieve this separation, multiple SX circuits were designed and operational conditions specified to separate Dy from the mixed rare earth chloride feed."

Jan 1, 2016

By Richard J. Wardle, Ambrose F. Howse

The industrial minerals industry in Newfoundland and Labrador is a significant contributor to the provincial economy. The variety ofcommodities produced reflects the diverse geological environment from which they come. A highlight of the past decade has been the continuing development of dimension stone quarries, with producers now active in anorthosite, gabbro, granite and sandstone. Other dimension stone prospects have been identified and are in various stages of assessment and development. Western Newfoundland hosts a large resource of limestone, dolomite and marble. It provides raw material for industries that produce Portland cement, agricultural limestone and aggregate, as well as chemical-grade limestone and dolomite products. In western Labrador, dolomitic marble is quarried for use in the production of self-fluxing iron ore pellets. The recent opening of a new gypsum quarry at Fischells Brook signalled the beginning of a new era in the commercial production ofgypsum, a commodity which the province has produced since the 1950s. Hopefully it will emulate the nearby Flat Bay Quarry (now closed) which was a long-time exporter to markets along the U.S. eastern seaboard, in addition to supplying local demands. Oil production and continuing exploration in the Newfoundland offshore has renewed interest in local barite deposits for potential use in drilling fluids. Already there has been some production from the Collier Point deposit, and at Buchans, an existing plant is being refurbished to recover barite from a large tailings pond. Emerging new industries include the development of an antimony mine in central Newfoundland, the development of silica deposits near Labrador City for silicon metal production, and reactivation of the St. Lawrence fluorspar mine. The province has many deposits with development potential such as rare metals at Strange Lake, white marble at Roddickton and salt deposits near St. George's Bay region.

Jan 1, 2001

By C. Hudson, D. Tremblay, A. Frey

"A discussion of the design, challenges and successes associated with the commissioning of the gravity recovery circuit at Canada’s newest open pit gold mine - Atlantic Gold’s Moose River Consolidated Project in Nova Scotia, Canada is presented. An overview of the project, its historical significance and overall flowsheet is provided with special focus given to the design and selection of the gravity circuit equipment including the scalping screen, gravity concentrators and the novel intensive leaching technology selected for the project. The performance of the gravity circuit is benchmarked against the feasibility study process design specifications and the outcomes are discussed. Challenges encountered during commissioning are also presented, including the use of third-party automation and the effects of screen sizing on overall gravity circuit performance. Mechanical modifications made to the Sepro Leach Reactor for the Moose River project are also discussed. A detailed technical review of the mechanical and operational aspects of the Sepro Leach Reactor is provided with key operational data on leach times, recoveries, reagent usage, solid-liquid separation, pregnant solution quality and its influence on bullion purity.INTRODUCTION Atlantic Gold Corporation’s Moose River Touquoy Mill in Nova Scotia, Canada was commissioned in the fourth quarter of 2017 with commercial production declared in March of 2018. The 2 Mtpa process plant uses a conventional, gravity-CIL process. This site was previously mined in the 1870s. Interest waned in the early 1900s but resumed in the 1930s and the mine was brought back into production in 1935 until an underground mine collapse in 1936. This mining district became famous after CRBC radio commenced a ground breaking, around the clock, broadcast of the rescue operations. Over 100 million people listened to the broadcast from Canada, the United States and the United Kingdom. These broadcasts changed radio, transforming it from a medium for music to on the spot, breaking news reporting. The mill was constructed by Ausenco on a fixed price EPC contract in the historic Moose River gold mining district, 95 km north-east of Halifax by road. The mill will process ore from the adjacent Touquoy pit for the first 5+ years of operation; after the Touquoy reserves are exhausted, the mill will process ore trucked 37 km from the Beaver Dam deposit for an additional 5 years."

Jan 1, 2019

By Jérôme Girard, Shiu Kam, Sue Longo

"Historically, tailings management in a northern climate has involved the deposition of tailings into the Tailings Management Area (TMA) as conventional slurry. This type of system is obviously viable but presents challenges that are difficult to manage as circumstances change over the life of mine. These issues can include:? Increases in mill throughput, and? Life of the TMA for the life of mine.This case study will present how thickened, high-density, non-segregating tailings are used as an alternative to conventional slurry disposal to achieve greater storage capacity and enhanced environmental performance for a gold tailings facility in a northern climate. This paper will focus on how this change in deposition strategy accommodated the increased throughput of the mill and the increased life of mine. Specifically, the paper will discuss the addition and integration of new processes to the exiting mill system to accommodate the tailings management issues. It will highlight the challenges from laboratory testing to pre-feasibility to the engineered design of the thickened tailings system implemented at Musselwhite Mine.BACKGROUNDGoldcorp Canada’s Musselwhite Mine, in Northwestern Ontario (120 km north of Pickle Lake), is an underground gold mining operation that began production in 1997. The current mill throughput is about 4000 tpd (1.4 Mtpa). Gold extraction is based on a CIP process with cyanide destruction.The existing tailings management area (TMA) is located about 2 km southwest of the mill complex. The TMA is contained by high ground to the north and to the west and flanged by a moraine ridge along the south side. A number of dams have been constructed along this ridge. The dams were first built in 1996 and subsequently raised in 2000 and again in 2005. Excess tailings pond water is discharged to a polishing pond then released to the environment via a wetland.The TMA was originally designed to contain 13.7 Mt of tailings under a ponded surface for closure. The water cover was to inhibit adverse long-term environmental effects because the tailings contain pyrrhotite and other sulphide-bearing minerals that are potentially acid generating. The design was modified during Stage 3 Construction in 2005 to expand the storage capacity to 17.3 Mt (Golder, 2005). As of end of 2009, over 16 Mt of tailings had been deposited in the TMA. The slurried tailings were historically deposited at 50% solids."

Jan 1, 2011

By X. Louw

"This paper examines the change in surface properties of the Polyurea used on spirals at different operational times: unused spiral, 28 months in operation and 58 months in operation. This is being done to investigate the alleged statement that spirals have a decrease in spiral separation efficiency after a certain period of operational time. Observing the surface characteristics under 1.5x and 36x magnification it can be concluded that the surface roughness decreases with increased operational time. This may be explained by a decrease in air inclusions and streak lines as the spiral surface wears. Decreased surface roughness should in theory have a beneficial effect on spiral separation performance. This leads to the conclusion that if a decrease in spiral separation performance is observed after a certain period of operation, it can’t be attributed to the change in surface properties. Uneven wear of the spiral surface, material creep or application of force to the spiral will change the profile of the spiral and could cause an adverse effect on spiral separation performance. The metallurgical test work showed that the best results are obtained at 30 - 35% solids by mass in the spiral feed. The iron recovery was significantly higher in the new spiral in comparison to the 2012 and 2010 spirals. The mass yield to concentrate in the new spiral was approximately three times more than for the older spirals. In conclusion, the yield combined with the grade, which equals the recovery was the best for the new spiral.IntroductionAn investigation was launched to research the common belief that spirals experience a decrease in efficiency, and therefore recovery, after a certain period of operation (a period of seven years has been used in the industry). The properties of the spiral that may have an effect on the efficiency are:"

Jan 1, 2017

By David Hatton, Jacques van Wyngaard, Matheus Vilarinho, Neymayer Pereira Lima

The flotation of Brazilian fine iron ore particles presents well-documented challenges, particularly the high entrainment of iron into the quartz (tailings) stream, resulting in significant iron losses and reduced circuit efficiency. This paper evaluates the application of Woodgrove’s Direct Flotation Reactor (DFR®) technology, which has been piloted by Vale as a potential solution to these challenges. The DFR is assessed from a pilot scale and process design perspective, with emphasis on its staged flotation mechanism, energy dissipation characteristics, and concentrate handling mechanism that together collectively enhance the selective recovery of fine iron particles. The DFR’s operation is contrasted with conventional tank cells, highlighting its improved control over bubble-particle interactions, reduced entrainment, and potential for higher selectivity. The DFR pilot plant was used to perform reverse cationic flotation of a quartz-rich froth phase to upgrade the iron ore. Pilot plant results are presented, comparing DFR performance with pilot-scale conventional flotation tests on the same feed material and relevant industrial benchmarks. This paper compares a conventional mechanical cell circuit performance and design with a proposed DFR configuration for two -45μm deslimed size fraction samples, analysing parameters such as footprint, energy efficiency, reagent consumption, and overall metallurgical performance. The findings show that DFR technology has the potential to significantly improve the fine hematite selectivity in quartz flotation for iron ore applications, offering a pathway to increased resource efficiency and reduced losses to tailings.

May 2, 2026

By K. Winterton, Carruthers. J.

"Attempts have been made to produce hardened structures of a pseudomorphic type in various carbon and alloy steels. In order to obtain martensite with a fine distribution of cementite, an initial structure of fine lamellar or nodular pearlite is required; this may be obtained by conventional means. This is followed by partial austenitization and quenching.Two methods have been tried to induce partial austenitization:(a) A resistance (direct current) heating method involving rapid entry into the austenite field.(b) A new method, described as the ""threshold"" technique, involving homogenization of temperature just below A 1, followed by entry into the austenite field; two furnaces are required.The resulting structures have been examined for microstructures, hardness, tensile, and impact values. The tensile properties are comparable with those obtainable by conventional treatment methods. Impact values are disappointing, but this is explainable from the nature of the manifold changes occurring."

Jan 1, 1960

By R. J. Chase, C. Davies

"Abstract- The Merelani graphite-tanzanite deposit is located in northeast Tanzania, 14 kilometers south of Kilirnajaro International Airport and in close proximity to the towns of Moshi and Arusha . The graphite mineralization is hosted by relatively undeformed linear Proterowic metasedimentary gneisses, several of which have been subjected to hydrothermal alteration resulting in tanzanite mineralization. Exploration work comprised detailed geological mapping coupled with pit and trench channel sampling and a subsequent 1500 meters of diamond drilling. In addition, metallurgical tests have shown the graphite to be of unusually coarse flake size, crystallinity and high purity.Feasibility studies have shown the economic viability of a major coarse flake graphite deposit with the measured resource to 50 meters in excess of 9 million tonnes assaying over 8o/o graphitic carbon . Production is due to start by the end of the first quarter of 1994 with the processing plant design capacity initially set at 15 000 tonnes per annum.ln addition to graphite production, tanzanite will be produced through selective mining within the graphite open pit in the upper horizon and from underground workings within the lower horizon.The Merelani graphite-tanzanite deposit will be the first major orebody to be exploited through means of private funding since Tanzania gained independence."

Jan 1, 1994

By G. Chung, W. Petruk, D. Doyle

"A series of tests was conducted on Carol Lake iron ore, which contains about 38 wt % hematite and 19 wt % magnetite, to establish a flowsheet for high weight yield by spirals. A pilot plant was run in parallel with the IOC concentrator to simultaneously test two flowsheets on the same feed material. The IOC concentrator processes the ore by treating it directly in a spiral circuit, whereas the pilot plant used a laconite flowsheet which had a low intensity magnetic separator (LIMS) at the front of the circuit. The LIMS produced a non-magnetic (hematite-rich) product and a magnetic (magnetite-rich) product prior to treating the ore in two separate spiral circuits. The results from about 150 tests were evaluated by chemical assays and materials balancing techniques, and a selected test was evaluated by the image analysis and materials balancing technique.The image analysis and materials balancing evaluation showed that a higher hematite recovery was obtained by the hematite spiral circuit than by the IOC concentrator spiral circuit, and a slightly lower magnetite recovery by the magnetite spiral circuit than by the IOC concentrator spiral circuit. Furthermore the hematite recovery by hematite spirals was higher than the magnetite recovery by magnetite spirals. The better hematite recovery was achieved because a higher liberation is obtained for hematite than for magnetite, and the hematite in the Carol Lake ore has a narrower grain size range than magnetite. Consequently, better spiral control can be maintained when processing a hematite-rich spiral feed, than when processing a magnetite-rich spiral feed. Since the feed to the IOC concentrator spiral is a mixture of hematite and magnetite, an intermediate hematite recovery is obtained by the IOC concentrator. INTRODUCTIONA study of characteristics that affect recoveries of hematite and magnetite from the Carol Lake ores of the Iron Ore Company of Canada (IOC), was carried out in connection with a project on designing a flowsheet for maximum weight yields. A pilot plant using a taconite flowsheet was run in parallel with the existing IOC concentrator which uses a classical iron ore flowsheet. About 150 tests were run to compare iron recoveries and weight yields by the spirals in the two flowsheets. Better iron recoveries were indicated for the taconite flowsheet, but the results were not consistent and the reasons for the observed differences were not apparent. The material from one test (Test 61), which gave better iron recoveries for the taconite flowsheet, was evaluated by the image analysis and materials balancing technique. A suite of samples was taken from 5 points in the IOC concentrator and from 8 points in a pilot plant (taconite flowsheet). The samples were analyzed to compare the behaviours of the Carol Lake hematite and magnetite in the spirals of the two flowsheets. The results provided a sound basis for further tests in designing a high weight yield flow sheet."

Jan 1, 1993

By K. L. Murphy, G. Multamaki, P. M. Huck

"A preliminary evaluation, based on existing data, has been made of the implications of placing radium-barium sludge in tailings areas. The study was restricted to a consideration of possible increases in the quantities of radionuclides escaping to the environment through either groundwater or surf ace water, considering the types of tailings treated and the effluent treatment systems currently operating in Canada.IntroductionIn the recovery of uranium from ore deposits, the tailings produced by mine/mill complexes are conveyed to impoundment areas in slurry form. After settling, the supernatant is discharged to the environment together with runoff from precipitation on the tailings bas in. Currently, all operating uranium mines in Canada employ barium chloride treatment to control the release of dissolved radium to the aquatic environment. The dissolved radium in the tailings decant is precipitated with barium chloride, forming (Ra,Ba)SO4, and allowed to settle in ponds or lakes. In some instances, settling tanks have replaced ponds and flocculants have been added to aid settling. Because the Atomic Energy Control Board does not consider the precipitation ponds to be suitable for final disposal of these sludges, acceptable sites must be found. Options which have been suggested for sludge management include underground placement either in worked-out mine areas or in special chambers, or placement in the tailings areas. Conceptually, the latter alternative is attractive and probably would minimize sludge handling. This alternative would be subject to the AECB policy which requires that upon abandonment, radioactive releases from a tailings area must be within present regulatory limits and that treatment to meet these limits should not be required in perpetuity.No quantitative data exist concerning either the effect of physical and chemical conditions in the tailings on resolubilization of radium from precipitated sludges or the fraction of this additional radium which would be released."

Jan 1, 1982

By Peter R. Drummond

THE paper consists of four sections: (1) a discussion of early work; (2) presentation of the results of a chemical investigation of Falcon-bridge nickel-copper blast-furnace matte; (3) application of the results of this investigation to mattes in general; and ( 4) a summary of conclusions. All general discussion will be confined to the fundamental system of ferrous-cuprous sulphides (FeS-Cu2S). Nickel-, lead-, and zinc-bearing mattes will be treated as minor varieties of the parent system. DISCUSSION OF EARLY INVESTIGATIONS Matte investigations may be divided into three classes: first, those treating the sulphides as alloys-theoretical studies of the system FeS-Cu2S, such as those of Hofman (ll)t or Carpenter and Hayward (2); second, chemical research on mattes made under smelter conditions, such as that carried out by Hawley (3) or Avetision ( 4); third, combinations of the . above, such as the investigations of Gibb and Philp (5) or Fulton and Goodner (6). Much research in the first of these classes, including determinations of . freezing points and of data for structure-composition diagrams of the system FeS-Cu2S, was carried out in the period 1890-1910. LeChatelier and Ziegler (1, 13) proved that FeS, when heated alone above its melting point, dissociated in part, and Friedrich ( quoted by Fulton, 6) showed the same for Cu2S. The reactions may be expressed by the following equations: [xFeS yFe + yS (volatilized)+ (x -y)FeS xCu2S )'Cu+ yS ( vohtilized) + (x -)')Cu,S ] Sulphur is lost by volatilization, leaving a melt of metallic iron plus ferrous sulphide in the one case, and of metallic copper plus cuprous sulphide in the other. If the mixed sulphides are heated far above their melting points, there results either an iron-rich matte containing Fe-FeS-Cu2S or a copper-rich matte containing FeS-Cu2S3-Cu, depending on the relative amounts of each sulphide in the mixture.

Jan 1, 1940

By B. J. McKay, K. Schneider, H. B. Nadendla

"A series of experiments were conducted to assess the impact of zinc additions on the morphology and soundness of the interface of Al-Mg compound castings. It was found that high amounts of zinc (>15wt%) are necessary to affect the morphology and microstructure of the interface. At these zinc concentration levels, the formation of the zinc-rich phases t1 and ? were observed along with the Al-Mg intermetallic phases ß and ?. The micro hardness of all phases across the interface was found to be similar, ~200 Hv. This even hardness gradient is thought to avoid mechanical failure in the interface under load. In samples containing large concentrations of zinc (>15wt%), the formation of bubble shaped voids as well as the complete transformation of the aluminium alloy was observed. While the exact mechanism causing the voids has not been identified it thought to be connected to the Kirkendall effect. INTRODUCTION Conventional single material components are increasingly failing to meet the demands, in terms of cost and performance, of the transport industry. Compound castings have been identified as a promising alternative as they possess a number of benefits (Bührig-Polaczek, Röth, Baumeister, Nowack, & Sussmann, 2006). Compound casting is described as a process in which a metallic melt is cast around a solid metal shape. Preliminary research has concluded that for the stability of such a resultant hybrid structure it is imperative that both metals form a sound connection via form closure, force closure, or material bonding. A continuous material bond between the two metals is also highly desirable as the formation of a crevice between the metals could lead to galvanic corrosion, particular in a humid environment (Lao, 2013; Rübner, Günzl, Körner, & Singer, 2011). Even though Al-Mg compound castings could offer the biggest potential in terms of weight savings to date only a limited amount of research concerning such structures exists."

Jan 1, 2018