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By Gaby Steinbach

A novel synthesis is described for the preparation of supported gold catalysts for low-temperature CO oxidation. The novel route is a variation of the inverse co-precipitation method and requires amphoteric metal hydroxides, with zinc and aluminium hydroxides chosen. Catalysts were prepared by inverse co-precipitation (ICPa) and by the novel route (ICPb) and tested for CO oxidation at 60ºC. Preliminary results showed the novel route to be superior to ICPa; the catalysts prepared by ICPb showed higher catalytic activities. The effect on catalytic activity of parameters such as pH, calcination temperature, washing of precursor and calcined catalysts and ageing was investigated. A preparation pH of 9 and a Zn to Al mass ratio of 3 proved to be optimal. It was possible to remove residual chloride by washing thereby enhancing catalyst performance. Ageing and Mg citrate addition were also shown to improve catalyst performance. Characterization of the catalysts revealed that better activities were obtained when the support was more crystalline and had a higher surface area. The presence of carbonate-containing species in the support decreased catalytic activity. 197Au Mössbauer Spectroscopy revealed the presence of Au3+ when catalysts were heat-treated at temperatures of 200ºC and below. Catalysts calcined at 400º had 75% of the gold present as Au0, with the remaining gold present as Au3+.

Oct 1, 2003

By Michael Drozd

"The operation of an activated charcoal system has five separate unit operations. These unit operations have common points for CIP, CIL and CIS system, which vary widely in application.The unit operations are:a. Absorptionb. Desorption (Stripping)c. Acid Washingd. Reactivatione. Carbon Handling (carbon transportation, sizing, dewatering, etc.)Cost optimization starts with the basic operating parameters (design philosophy) set down at the time of engineering design. These parameters undergo almost immediate change due to site specific ore requirements, throughput changes, operator requirements or reagent availability.Activated charcoal is sometimes viewed as simple, uncomplicated reagent that requires not optimization. To some extent, this statement is true, but under most circumstances, if the time necessary to optimize the use of activated charcoal is available, the effort is rewarded with significant savings. CPL-Carbon Link has embarked upon a program of supplying technical support with its activated charcoal. Several operations in the United States have undertaken to have CPL-Carbon Link do an operational survey to determine if potential savings are possible. CPL-Carbon Link has offered to do these surveys for projects that are clients or simply would like to have CPL-Carbon Link review their operation. The information accumulated by CPLCarbon Link is being used to attempt to fashion industry standards so that a common reference point can be established for activated charcoal usage."

Jan 1, 2008

By P. Nayak

"Comminution is an energy intensive and expensive process consuming approximately 40-50% of the total processing costs in a mining operation. This process poses an even greater challenge with gold ores due to their low elemental concentration and small particle size. Over 99.9% of the ore fed to the mill is waste which must be removed during the ore processing stage. Preconcentrating the Run of Mine (ROM) ore before feeding the mill will result in significant cost savings. In partnership with Sacré-Davey Engineering, Agnico Eagle Mines Limited identified this opportunity and is currently evaluating the implementation of sorting technology to preconcentrate the ore or upgrade the waste material at its operations. This paper will discuss the steps adopted by Agnico Eagle in the evaluation and installation of sorting technology at its operations. Since the Company has a large portfolio of operations, the first step in the project was to shortlist the operations that had the highest probability for successful application of the technology. Following this, the top three operations were selected for bench scale evaluation. The projects which showed the most economic potential were then considered for detailed evaluation and pilot plant installations. This paper provides an insight into the methodology followed by Agnico Eagle and Sacré-Davey in the evaluation of the technology.INTRODUCTION The benefits of ore sorting technology are being increasingly understood by the mining industry today. The application of ore sorting in gold mining is attractive due to the nature of the mineral distribution. The presence of high value minerals distributed in an extremely small mass of the ROM ore creates a tremendous opportunity for preconcentration with ore sorting. Since Agnico Eagle currently has a portfolio of eight operating mines and numerous development projects and exploration properties, the challenge was to identify the deposits which had the most favourable mineralogy and grade distribution for successful ore sorting. The success of ore sorting is mostly based on the minerals present in the deposit and the grade distribution. The minerals signify the amenability of the deposit for ore sorting and the kind of sensing technology to be used. On the other hand, the grade distribution demonstrates the amount of material that can be rejected without losing value. In order to understand a deposit’s characteristics, it is important to examine the sample’s behaviour with various sensors and then assay it to know its actual value. It is a common practice in the mining industry to document assay value of drill cores and/or material feeding in and out of the mill. However, those VALUES (are insufficient to understand the grade variability on a granular basis. To capture the ore variability in very high resolution and significantly improve the selectivity of the material feeding the mill, it is vital to assay the samples on a rock-by-rock basis, as this is the level of resolution which will be examined by the ore sorter during sorting. A careful and elaborate procedure was followed in evaluating the technology at Agnico Eagle’s operations which is discussed in this paper."

Jan 1, 2019

By M. Matthias

A study, part of a doctoral dissertation (Matthias, 1991), was conducted during 1987 and 1988 to establish the means by which professionals assess and maintain their competence during the various stages of their careers. The study elicited responses from fifty-nine subjects representing engineering, pharmacy and medicine (twenty subjects from engineering, nineteen from pharmacy and twenty from medicine) on their perception and assessment of continuing competence. The findings revealed a wide variation of how professionals perceived their continuing competence and the means they adopted to keep current. The implications of the study are significant for adult education practice and theory building. The author strongly believes that now, more than ever, engineers must take ownership of their careers and professional development activities. While management and supervision have a key role to play, it is the engineer, who is ultimately responsible for the scope, planning and implementation of her/ his professional development needs. An example from one high technology company will illustrate these points.

Jan 1, 1999

By L. C. Stevens

The particular purpose of this paper is to direct attention to the development of underground conveying as applied to methods of working coal in the mines of Alberta. Historical A retrospective view of coal mining discloses a continuous effort, on the part of those interested, to substitute mechanical contrivances for hand labour. A patent for a coal-cutting machine was granted to Michael Menzies in 1761, at which time much of the transportation of coal underground was accomplished by means of sledges. Early forms of cutting machines attempted to duplicate the action of a miner's pick, and one hundred years lacer than Menzies? patent we still find this class of machine, driven by water power or compressed air, in use to a limited extent. A coal-cutter using the principle of a circular saw and worked by hand was exhibited in London in 1851, and from these crude beginnings the machines of today have been evolved. Transportation of coal underground has similarly been subject to considerable improvement. The above mentioned Michael Menzies took out a patent in 1750 covering the use of a self-acting incline plane, which is probably the earliest record of any system devised to lighten the load of the crammer or car-pusher of those days. In the year 1868 the Gillot & Copley machine was patented, this being a compressed-air-driven disc coal-cutter which proved highly successful. The chain cutters were a natural development from this type, and for a number of reasons they have been even more successful in the majority of cases.

Jan 1, 1930

By B. M. Das, D. B. Cross

"In June 1983, the Computer Applications and Process Control Committee (CAPC) of the Canadian Institute of Mining and Metallurgy (CIM) circulated a questionnaire to coal mining, exploration and consulting companies in Canada to determine the industry's level of interest in holding a workshop-style meeting to introduce company personnel to ""state-of-the-art "" computer systems designed to carry out specific technical and management junctions. It was necessary to conduct the survey to determine the specific fields of application and the nature of training which are of most interest.Almost universally, the companies expressed interest in computer workshops and training for applications in the Canadian coal industry. The survey showed that all categories of personnel felt the need for some sort of training. Areas of specific interest identified were: exploration and geology, mine design, reserve calculations, coal mining technology, coal preparation, rock mechanics, ventilation, financial planning, and process simulation. The details of this survey together with an assessment of the significance of computer applications in the Canadian coal industry are presented in this paper."

Jan 1, 1986

By W. Cholewa, T. S. Golosinski, J. Wedzicha

"Power requirements of belt conveyor drives are usually estimated based on the calculated belt tension which equals the sum of unit resistances to motion which the belt has to overcome. In most situations, the value of various unit resistances can be accurately predicted using published information (5,6,8,12). A simpler approach calls for use of standard formula and tabulated values of related factors which reflect various features of both the conveyor and the transported material (2,3,7) . None of these approaches is reliable when materials with unique properties are conveyed, nor if applied to conveyors working in extreme climatic conditions. Such is the case of oil sand mines in northern Alberta.There the bitumen content of oil sand causes it to behave in a unique manner. Furthermore the conveyors operate year around, with winter temperatures often lower than - 40°C. It was the objective of presented investigations to quantify the power requirements of conveyors, and related resistance to motion for the conveyors used in oil sand mines during winter operations.The other objective was to quantify the drive power requirements of oil sand conveyors during start-up. These requirements are usually much higher than those during norm al operation, and their quantification is of paramount importance for operation of large conveyors."

Jan 1, 1992

By L. H. Shang

The 319 Al-Si alloy is one of the most prominently used aluminium-based alloys in motor vehicle and engine applications, Microporosity present in 319 alloy castings reduces the load bearing capacity of the castings, The quantitative prediction of microporosity levels in Al-Si castings has been a subject of much interest for several years. In this research a new criteria function, tf 1,98 R13° (tf: local solidification time, R: cooling rate) was developed by multiple regression analyses, correlating thermal data from simulation studies to experimentally obtained microporosity values. This new criteria function gives a general prediction of microporosity in 319 Al-Si castings.

Jan 1, 2005

By K. M. Wild, C. D. Martin, F. Amann

Peak laboratory strength data obtained from low permeability clay shales/rocks often display a bilinear or non-linear failure envelope. In many of these tests pore pressures are not measured because of issues associated with back-saturation prior to confined compressive loading. In such tests the effective state of stress at failure remains unknown and provides room for speculation. The non-linear shape of the failure envelope may have several reasons including the influence of capillary forces or the tendency of a saturated clay shale to dilate as the confining stress is changed. The former stems from sample preservation, preparation or core unloading effects and represents a partly saturated state (i.e., not representative for the in-situ state); the latter represents the response of a saturated material. This contribution discusses these issues based on a data set obtained from Opalinus Clay specimens, and concludes that without a careful back-saturation processes knowledge of the underpinning reasons for the non-linear failure envelope cannot be obtained.

Jan 1, 2015

By J. D. Aitken

"DEFINITION OF THE REGIONTHE REGION considered in this paper is bounded on the south by the 60th parallel, on the north by the Beau-fort Sea and Amundsen Gulf, on the east by Archean rocks or by highly deformed Proterozoic rocks of the Canadian Shield (certain weakly deformed Proterozoic strata being regarded as belonging to the Great Plains), and on the west mainly by the Mackenzie and Richardson Mountains.Only the unmetamorphosed strata of the region are considered; that is, the geology of the crystalline basement is ignored.SIGNIFICANCE OF THE REGIONThe region is significant from three points of view -namely, the economic, the scientific and the social. It constitutes 46 per cent of the area of the Western Canada Sedimentary Basin."

Jan 1, 1970

Mine Safety in Chile ?Since the year 2000 fatality rate averages 34 per year ?1% of world mining labour force but 8% of world?s mining fatalities San Jose Mine Safety ?From 1998 to 2010 eight fatalities ?In 2003 mine inspectors recognized no second means of egress and a raise system was developed ?In 2006 182 workers were injured, 56 of them seriously ?In January 2007, there was a fatality after a rock burst, and the government ordered the mine closed ?Less than a year later the mine was back in operations. It had not complied with some of the basic safety measures ordered. One of those measures was to complete the escape way ladder.

May 1, 2011

By Walter Nelson

Considerable thought and discussion had been devoted toward provision for increased milling capacity at the Allenby concentrator of The Granby Consolidated Mining, Smelting and Power Company operations as early as 1940. During the war, plans for the installation of an additional grindi.ng unit were formulated but were not carried out. It took considerable time after the war to prepare the mine again for its highest rate of production since, with the scarcity of men, development work had been sacrificed in favour of maximum ore shipments. In order to prepare for the expected competitive market in copper, the matter of increasing the capacity of the concentrator was again given serious attention. As ore became available in the mine and the output of the mill was increased, limitations for a satisfactory recovery were observed, due to the overloaded condition of the classifier units at the higher tonnages. From a metallurgical standpoint, the ore from the Copper Mountain mine had always been difficult to treat on account of the finely disseminated character of much of the mineralization and the difficulty of grinding to the desired fineness. This trouble has become aggravated with time as an increasing amount of wall-rock has diluted the ore and lower grade orebodies have been mined. It therefore has been, and is, the practice at the concentrator to maintain the maximum amount of reduction in size of material fed to the flotation units as is possible for the daily tonnage to be milled. This means that all the grinding units are operated for the maximum possible time, and that the classifiers are regulated to return as much feed ?as possible to the mills. The number of tons to be milled for ?the day is determined by the concentrator superintendent after ascertaining the availability of ore from the mine, the condition of the concentrator ore bins, and the need for repairs in the rolls plant. In order to maintain the tonnage des1red, hourly estimates are made of the rate of grinding by weighing the amount of ore contained on one foot of each of the belts conveying the feed to the various ball-mills, and adjustments are made accordingly.

Jan 1, 1950

By K. Meyer

"The largest cost centres of the David Bell Mine concentrator are grinding, leaching and effluent treatment. Optimizing results during the 6th year of operation are listed below: o SAG mill slurry density control and operating strategies improved liner life and media consumption by 10 and 25%, respectively.o Poly-met liners clad the SAG mill except for the feed end. Lower noise levels and reduced mill downtime have resulted in an improved and more efficient workplace (time required for liner changes is 2 to 3%).o A comparative grinding media study using seven different marked media at the same time showed media wear rates range 120 to 198 mg/kWh and ball mill charge replacement frequencies of 8.3 to 13.1 per year, and that a meaningful wear test must include all media to be tested at the same time in the same mill. High quality carbon steel cylinders had the best economics.o Pre-aeration, using pure gaseous oxygen is accomplished in pipe reactors. Small bubble generators provide oxygen in the first three leach tanks. 1500 to 3000 kg of oxygen is consumed per day. Leach kinetics have improved and trends indicate increases in gold recovery of three to seven ounces per day at reduced costs. Effects of reduced cyanidation of accessory metals on the effluent treatment plant will be discussed in a separate paper."

Jan 1, 1991

By J. Fournier, D. Fortin, F. Robichaud

Since milling began in 1988, the Laronde mill has been expanded several times, the most recent, increasing the milling rate from 5 000 to 7 000 mtpd. Laronde uses SAG/ball mill grinding followed by copper and zinc flotation circuits. A cyanidation/Merrill-Crowe process recovers the remaining gold and silver in the flotation tails in order to cope with high silver/gold ratio associated with the discovery of the Penna shaft. Since the commissioning of the Merrill-Crowe refinery in 2000, several modification and expansion projects were performed to reduce health and safety hazards. Remarkably, several of these improvements have contributed at increasing productivity and Net Smelter Return of the refinery while reducing worker's injuries. In 2004, the refinery was audited to evaluate and quantify the circuit performance. Metallurgical and mechanical operating conditions of the refinery are now understood and areas for further improvements are well defined. This paper describes some of the factors that have contributed to this improvement and describes how ergonomics and recovery can further be improved.

Jan 1, 2005

By Q. Li

"The precursor of In2O3 was prepared by hydrolysis precipitation/hydrothermal method using In(NO3)3 solution as the feed material and ammonium hydroxide as the neutralizing agent. The crystallinity, morphology and particle size of the products were characterized by SEM, XRD, BET and LPSA. The results showed that the hydrolysis product consists of an aggregate of cubic In(OH)3 particles with a short rod morphology. In the hydrothermal process, the structure, morphology and size of the particles changes through the mechanisms of Ostwald ripening and phase transition, respectively. When the hydrothermal temperature was less than 280 ?, the Ostwald ripening process took place, which changed the morphology of the particles from short rods to cuboids through dissolution-recrystallization. When the hydrothermal temperature was higher than 280 ?, the processes of Ostwald ripening and phase transition took place successively. Firstly, the morphology of the particles changed from short rods to cuboids through Ostwald ripening, and then, the phase transition from cubic In(OH)3 to orthorhombic InOOH occurred and the morphology of the particles changed from cuboids to polyhedron. INTRODUCTIONDue to its excellent electrical conductivity and optical transparency, indium tin oxide (ITO) film has been wildly used in flat-panel display, solar cell, antistatic coating and EMI shielding (Medvedovski et al., 2008). Indium oxide powder is one of the fundamental materials for preparing ITO film. Along with the development of ITO targets of both high density and large size, high quality indium oxide powders, such as single phase, nano-size, spherical morphology and mono-disperse, have been in high demand (Nakashima and Kumahara, 2002; Betz et al., 2006; Kim et al., 2007). The main preparation methods for indium tin oxide or indium oxide powders include chemical precipitation (Nam et al., 2001; Xu and Yu, 2007), melt atomizing-combustion (Chen et al., 2000) and spray pyrolysis (Ogi et al., 2009). Among them, chemical precipitation has been preferred, since it is simple, easy to control and suitable for industrial scale-up. In chemical precipitation method, indium oxide powders were prepared through the following steps: firstly, indium hydrate precursor was precipitated from an indium salt solution by neutralization using an alkali, such as ammonia; and then, indium oxide (In2O3) powders can be obtained from the precursor through calcination (Li et al., 2006), or solvothermal method (Lee and Choi, 2005), or hydrothermal processing/roasting (Xu et al., 2005; Chen and Li, 2007), respectively. However, the indium oxide powders obtained by direct roasting are polycrystalline, dispersable with a wide size distribution (Liao, 2006). The disadvantages of the solvothermal method are high cost, complicated after-treatment processes, as well as bad performances of the powders (Udawatte and Yanagisawa, 2000). Therefore, among three methods of obtaining indium oxide from the hydrolysis precursor, the hydrothermal process/roasting method is the most feasible to synthesize high quality In2O3 powder with uniform crystallinity and size (Kim et al., 2002; Zhu et al., 2004; Xu et al., 2005; Xu et al., 2005; Chen and Li, 2007; Seetha et al., 2009). However, current research on hydrothermal process-roasting method has been limited to the synthesis of a certain ITO or In2O3 powders under specific conditions. A systematic study on the phase transition, as well as the change of the morphology and size of the particles in the hydrothermal process is still missing. In this paper, the effects of hydrothermal processing on the mineralogy, morphology and size of products were investigated. The results showed that the evolution of crystal structure, morphology and size in the hydrothermal process was affected through the mechanisms of Ostwald ripening and phase transition successively. These results are novel and have guidance for improving the hydrothermal process for In2O3"

Jan 1, 2012

By Michael Young, Peter Allum, Mingwei Gao

"Tough economical conditions and high grade but fine-grained ore processing have forced the mining industry to look for more efficient processes. Isa Mill Technology for ultra-fine and fine grinding is one such process employed at several mining operations in Australia including Mount Isa Mines Limited in Australia. Mount Isa Mines is a business unit of MIM Holdings Limited. MIM is an Australian-based international mining and mineral processing company with around 8000 employees worldwide. Major products include copper, gold, zinc-lead-silver, coal and technology sales.The Isa Mill is a horizontal stirred mill with sizes up to 3 m3 chamber net volume and 1 120 kW installed motor. It was jointly invented by Mount Isa Mines of Australia and Netzsch Feinmahltecknik GmbH of Germany for ultra-fine and fine grinding duties in the minerals industry. Isa Mill operations started in 1994 at the Mount Isa Mines Leadzinc Concentrator and then at MIM’s McArthur River Mine in 1995. These Isa Mills have been used to liberate sphalerite and galena at Mount Isa and silica at McArthur River by grinding to less than 7 micron.This paper discusses the Isa Mill Technology and reports on the metallurgical performance of the Isa Mills at Mount Isa Mines, including work done over the last 9 years to improve mill design, process efficiency and maintenance, which has resulted in the current state-of-the-art Isa Mill Technology.INTRODUCTIONThe current leadzinc deposits at Mount Isa Mines (George Fisher, Hilton and Isa) have an average grade of 10.5% zinc, 7.2% lead and 165g/t silver. Fine grinding, in particular in the zinc retreatment circuit requiring a milled product P80 of 7 micron, is essential to treat the ores from the Mount Isa Mines deposits. Every one micron size reduction in the zinc retreatment circuit below a P80 of 10 micron improves the overall plant zinc recovery by 1%, resulting in an increase in revenue of about 1 million dollars per annum."

Jan 1, 2002

By F. G. Smith

Abstract Laboratory methods are now in use whereby the temperature and pressure during the crystallization of hydrothermal minerals can be determined. The techniques include the use of the decrepitation method of studying liquid inclusions, and electrical measurements of pyrite. The determinations are sufficiently accurate that the data can be used in solving a variety of ore deposition problems. Within the last year, several new laboratory techniques have been developed in the Geochemical Laboratory of the Department of Geological Sciences, University of Toronto. The results of several tests of ore by these methods have proved to be useful in treating some problems which previously were considered unsolvable. It is now possible to determine the temperature of deposition of most of the minerals in a hydrothermal ore deposit, also the depth below the surface during deposition. Measurements can also be made of the reopening history of a complex ore. The temperature-pressure determinations depend upon the fact that minerals deposited from a hydrothermal solution always trap a small amount of the solution at the time of crystallization. The solution, being predominantly composed of water, has a density which depends upon the temperature and the pressure prevailing during crystallization. After ore deposition is complete, erosion and isostatic uplift finally exhumes the vein. During this slow fall in temperature and pressure, the solution contracts and a gas bubble appears. If the trapped solution in the mineral is examined, the gas-liquid ratio records the density of the solution at the time the mineral was deposited (except for a slight change in the volume of the mineral). The thermal expansion and compressibility of water and water solutions are known to a sufficient degree that, if the gas /liquid ratio can be determined, the temperature-pressure relations during deposition can be calculated.

Jan 1, 1949

Adaptive Processing as proposed in geometallurgy has to rely on spatially interpolated information on geometallurgical parameters like phase composition, size distributions of particles of different phases, grain shape parameters, and portions of value elements in different grains. Using the geostatistically predicted values for adaptive processing, e.g. for the selection of milling diameters, thresholds in physical separation, or choices on using an extra pre-separation step, is typically not optimal. Mathematically this effect is introduced by two forms of nonlinearities: 1) The nonlinear scales of compositions, distributions, and shapes have special properties with respect to geostatistics. Classical geostatistics creates some artefacts for these nonlinear scales. On the other hand, modern geostatistical procedures adapted to these scales do not provide unbiased results with respect to linear transformations of the data (e.g. biased block estimates). 2) Neither economic nor ecological effects (e.g. monetary gain) of processing decisions are linear in the interpolated geometallurgical parameters. These nonlinear transforms are not unbiasedly estimated by the likewise transformed unbiased geostatistical predictions of the geometallurgical parameters. Furthermore, we need to optimize the conditional expectation of the gain, rather than obtain an unbiased estimate. Standard geostatistics as such does not provide the "right sort" of estimates for adaptive processing. A nonlinear kriging procedure is needed to approximate the nonlinearities mentioned before. We propose to solve these problems simultaneously using a nonlinear geostatistical technique for predicting the target function (the monetary gain), rather than to predict the geometallurgical parameters and compute the gain from them. The optimization can then be performed directly on this estimated function. It can be shown that this optimization performed on the conditional expectations, not on unbiased predictions, would yield the best possible processing choice. We propose a procedure choosing the processing parameters on an approximation of the conditional expectation. The difficulties with the classical approach and the effectiveness of this new approach are illustrated by a simplified simulation example with a single processing parameter and a simple dependence on the microstructure.

Aug 1, 2013

By T. A. Kirk

"The Linatex Dewatering System is a compact, low capital and maintenance cost matched set of processing equipment suitable for solids recovery, dewatering and desliming sand-like materials in the range 3/8"" to 325 mesh ( 1). Since its introduction to North America in the early 1970s, various elements of the system have been successfully installed in a variety of applic11tions both in Canada and the U.S.A. Examples are chosen from the coal, fine aggregates, iron ore and industrial minerals industries.II. Elements of the Linatex Solids Recovery System(A) The Linatex Separator (See Fig.I)The Linatex Separator, which is the heart of the system, is a specialized type of hydrocyclone designed to give a self regulating rope discharge product. It has the familiar cyclone geometry of cylindrical and conical section, tangential inlet, apex and vortex finder. The apex is enclosed in a unique patented automatic underflow regulator consisting of a collapsible rubber sleeve, and the overflow line is a siphon-leg, with a controlled air bleed valve. The siphon leg is adjusted so as to balance the internal negative pressure acting as a closing force on the underflow regulator against the mass of slurry pressing down on it from the cone section of the Separator. With correct adjustment the underflow regulator will close drip-tight on a water only feed. As solids accumulate in the apex of the cone the weight of solids counterbalances the vacuum and cat1ses the underflow regulator to open and discharge classified material at a controlled density."

Jan 1, 1978

By A. Rodriguez-Prado, P. Kuschk, R. L. Legge, W. C. Lennox

Using constructed wetlands to chemically reduce hexavalent chromium Cr(VI) to Cr(III) from industrial and mining wastewater has proven to be feasible and efficient. Applying first-order kinetics to describe the process is simple, but in some cases a more accurate model is required to reflect the process. This paper studies the feasibility of using non–first-order kinetics to describe the reduction process. Results indicate that half- and second-order kinetics adequately described Cr(VI) reduction in laboratory wetland mesocosms. The organic carbon content played a relevant role, whether it was built up by plant growth or spiked into the feed water.

Jan 1, 2014