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By J. Arzúa, L. R. Alejano, P. Rodríguez

"After six years of successful excavation with a support pattern, some roof failures have happened in a room-and-pillar underground mine excavated in a stratified rock mass. In this paper the authors give explanation to the failure mechanisms and redesign the support in order to solve the recent problems of roof collapse.The mine magnesite bed is approximately 14 m thick, and runs in the E-W direction with an average dip of 18º. Due to mine constraints and the inexpensiveness of the ore, the excavation is performed in the mineral itself, avoiding the need for mining dumps and waste excavation. Rooms and drifts are oriented in the mineral bed to form an angle of 19º to the direction of the strata, reducing the roadway gradients to less than 10%. Rooms are 11 m wide and pillars are 7 m wide. They are designed to leave a 1 meter thick magnesite bed in the roof of the rooms to act as a supporting beam. More often than not there is a layer of very poor quality marly shale up to 1 m thick resting on this magnesite beam. Overlying the poor quality marly shale there is a better quality, self-supporting sandy shale.First, a characterization of the involved rock masses (magnesite, marly shale and sandy shale) is performed, collecting the geotechnical data from previous studies and performing new in situ geotechnical surveys to check the soundness of the previous data. A distinction is made between different quality zones inside the mine by means of the RMR classification, associated to the occurrence of faults.Back-analysis of some of the failed rooms and data from exploration boreholes were used to determine the failure mechanisms (associated to Voussoir type failure or occurrence of sub-horizontal joints crossing the magnesite beam). Based on an understanding of these mechanisms, the method used to design the support and to analyse the stability of the different possible thicknesses of the magnesite beams of the rooms and drifts of the mine were improved.Numerical models of the most relevant conditions found in the mine were performed in order to better understand the behaviour of the roofs and to simulate the supporting solution obtained in the previous analyses.The most relevant conclusions with regard to the main elements causing the instability of the roof include the appearance of sub-horizontal discontinuities crossing the magnesite bed, which causes total instability of the roof and usually leads to collapse; excessive thinness of the magnesite beam in the problematic rooms; and the relaxation of the deepest (around 270 m in depth) zone of the mine because of existing faults."

Jan 1, 2015

By J. Lovering, M. Allan

"INTRODUCTIONThe Afton Mines property is located 180 air miles east-northeast of Vancouver and nine miles west of Kamloops, a city of 60,000 people in south central British Columbia. The deposit is located adjacent to the Trans-Canada Highway at an elevation of 2,231 feet above sea level.Interest in the property dates back to 1898, when a 330 foot shaft was sunk on the Pothook claim immediately south of the existing operations. Since that time many companies and individuals have investigated the possibilities of the area but it was not until 1972 that Afton Mines Ltd. located a significant zone of copper mineralization. The feasibility study was completed in the period 1974-1975, by Teck Corporation Ltd., who control Afton through 50% direct ownership and 65% ownership of Isa Mines, who own a further 23%. Construction began in March, 1976. Ore production started in August, 1977, and the first ore was fed to the mill on December 8. This was the third mine to be brought into operation by Teck since 1975, the others being Newfoundland Zinc and Niobec.The orebody is a porphyry copper deposit which has undergone supergene alteration. It is 1,700 feet long in a west-northwest by east-southeast direction, 300 feet wide and dips at 55° to the south. The mineralization in the supergene zone, which accounts for two-thirds of the known deposit, is rather unusual in that the copper is present primarily as native copper and chalcocite. The grade is one percent with the distribution: 70% native, 25% chalcocite, and 5% chalcopyrite with bornite, covellite, and cuprite."

Jan 1, 1979

By V. N. Bryant

"1.0 SYNOPSISThe Colomac property, located 137 miles by air northwest of Yellowknife in Canada's NWT. will recover gold from 10,000 tons per day of open pit ore.The decision to proceed with the project was based on a mineable ore reserve of 16 million tons (including dilution) averaging 0.064 oz/ton. After an in-fill drilling program in the latter half of 1988, Colomac's mineable, proven and probable ore reserves were increased to 28 million tons averaging 0.056 oz/ton of gold.A feasibility study completed by Wright Engineers for Neptune Resources in December 1987 examined the possibility of vat leaching followed by C.l.P. and electrowinning. A second feasibility study completed by Wright in February 1988 demonstrated that a conventional agitated leach circuit using a finer grind justified the higher capital cost of this process. This study was accepted and formed the basis of the project authorization.Preliminary engineering commenced in April 1988 and detailed engineering was started in September of that year with the objective of a mine/mill start-up by early 1990.The short time period available to meet the project deadline was additionally challenging, as site access is either by plane year round, and winter road from early February to late March. Normal lead times for equipment design, specifications, quotations and bid analyses were not possible, if the winter road time-slot was to be met."

Jan 1, 1990

By M. S. Fotheringham

Recognition of the Growing Importance of Iron and Steel Few Canadians have yet become aware that Canada's vast iron ore resources, the greater part of which is only now beginning to be developed, will inevitably have a profound effect on the entire Canadian economy, benefitting in some measure the lives of all Canadians. The great iron mining developments of Ontario, Newfoundland, Quebec, and Labrador are destined to make Canada one of the world's major producers and exporters of this material, on which our industrial civilization is?based. These developments will create new employment, new communities, new transportation facilities, and new investment opportunities. Iron ore is the foundation and the keystone of modern mechanized civilization. The most prosperous nations of the world are the highest per capita consumers of iron and steel, and in these countries the per capita consumption is increasing steadily despite the advent of light metals, plastics, and other competitive materials. Three-quarters of the human race have too little steel -and consequently too little mechanization -to provide for themselves the necessities and comforts of civilized living. Progressively they will demand, and acquire, the machines, the transportation and communication facilities now lacking, and they will win them by making greater use of the world's iron resources. It is the good fortune of this generation that Canada's 'iron age' is just getting well under way.

Jan 1, 1951

By József L. Margitfalvi

Different Au/MgO catalysts modified with Mn, and Fe were prepared by precipitation-deposition. The catalysts were characterized by XRD, FTIR, Temperature Programmed Reduction (TPR) and CO chemisorption and were tested in CO oxidation in the temperature range of 243-523 K. The catalytic tests using both Temperature Programmed Oxidation (TPO) technique and time on stream (TOS) experiments revealed the high activity of catalysts prepared. In TPO experiments the modification by Mn significantly increased the activity above 300 K, however in the subambient temperature range the activity decreased considerably. Catalysts modified by iron did not show any decrease in the activity below 300 K, while the activity at high temperature increased significantly. Catalysts modified by Mn, Fe showed higher activity, selectivity and stability in preferential CO oxidation, carried out in the presence of hydrogen than the unmodified Au/MgO catalysts. Results of in situ FTIR spectroscopy on both the base Au/MgO and the iron modified catalyst unambiguously revealed the formation of ionic gold in the presence of CO/O2 mixture. The formation of this species was strongly hindered in catalyst modified by manganese. Results obtained strongly support the need for the formation of "metal ion - metal nanocluster" ensemble sites. These sites are involved in the activation of the CO molecule prior to its reaction with atomic oxygen. It is suggested that at subambient temperature these ensemble sites contain mainly ionic forms of gold, while at higher temperature iron or manganese ions are involved in CO activation.

Oct 1, 2003

By J. Dilbeck, J. K. Ratliff, T. Petrov, Z. Brown

"In efforts to improve dust control during deep cut continuous mining a supplemental atomizing spray system, mounted on 14CM15 continuous miner, has been designed and successfully implemented in a U.S. coal mine. The mine is 2.1 m (7-ft) high and uses a blowing curtain face ventilation system with 1.1 m (3.5-ft) curtain offset from the rib. The face ventilation design parameters were set to 9.4 m3/s (20,000-cfm); 4.2 m3/s (9,000-cfm) line curtain flow rate, and 3.8 m3/s (8,000-cfm) scrubber capacity. The performed in-mine measurements, before and after the implementation of the atomizing spray system, showed a significant decrease in the respirable dust levels at the operator place as well as at the return. The paper describes the supplemental water spray system design and performance supported by three-dimensional computational fluid dynamics (CFD) simulations and in-mine test data.INTRODUCTIONThe work on this project have started in 2015 with a study of the conventionally applied face ventilation layouts. The specific behaviour of the face ventilation system have been analyzed trough in-mine measurements and computer modeling of typical cut scenarios. An computer modeling methodology have been developed for estimation the respirable dust concentration (RDC) using tracer gas to RDC contour mapping, calibrated by a single point value, provided by in-mine measurement. Utilizing the results of this study the engineering staff of the mine designed and implemented a supplemental atomizing spray system to improve the dust control during the deep cut continuous mining. Today the atomized spray system is successfully applied demonstrating steady performance and a significant decrease in respirable dust concentration on the working places of the continuous miner (CM) and coal transporters (CT) operators as well as at the return air stream. Information about the applied type of spray nozzles provided by other researchers (Cheng, 1973; Dick et al., 1996; Organiscak & Page, 1998; Pollock & Organiscak, 2007) and spray system manufacturers (Spraying System Co, 2011–2018; Steinen Mfg., 2016) have been used in this project. CFD code and simulation approach validated in a study conducted in 2000-2014 have been applied (Turner et al., 2002; Wala et al., 2004, 2007; Petrov, 2014)."

Jan 1, 2019

By V. Falmagne

The mining sequence at Noranda?s Bell-Allard mine calls for two mining fronts retreating toward a central pillar known as the Retreat Zone between pyramids A and C. It is clear from numerical modelling and rock mass characterization that the induced stress level in the pillar will exceed the rock mass capacity. A mining plan was developed including the re-dimensioning of stopes in the Retreat Zone, additional ground support and instrumentation in order to ensure the safety of the workforce and to maximize ore recovery while minimizing production delays. The mining strategy consists in allowing the rock mass to fracture and fail progressively while maintaining control of the existing openings with the appropriate support. A systematic analysis of rockbursting and caving hazards was conducted for all accesses and stopes in order to plan ground support and instrumentation needs.

Apr 1, 2004

By O. Kodym

The paper has focused on possibilities of interconnecting information sources concerning monitoring & control of mining industry technical processes (TP), and the related safety hazards. The key issue is the comprehensiveness of the information presented to users. Information can be presented by virtual reality means, when the seemingly true presentation of the production process scene along with user friendly presentation of related information is available. The user in its role of a process supervisor is not only a mere scene observer but, thanks to the interactive functions of virtual environment, he participates in the scene of his control. As such his control and management abilities increase because he can absorb, more easily understand and asses the information provided.

Aug 1, 2013

By V. Fiedler, H. Lachmund, R. Bruckhaus

"After producing some 50 million tonnes of crude steel the two BOF vessels at Dillinger Hüitte steel plant had to be replaced in 2000/01 due to large deformations. The new vessel design was optimised after a number of theoretical evaluations.Refractory investigations were carried out as well as temperature measurements of the shell to provide a basis for selecting a suitable steel grade. This was found in a DH-GTS development - P420M HT - with high strength at elevated temperatures and excellent weldability and made it also possible to build the vessel without any cooling system.After putting the first vessel into operation the metallurgical results showed no remarkable improvement compared to the old vessel, and were therefore not satisfying. With the help of cold model investigations the arrangement of the tuyeres was modified to improve the flow conditions and the interactions between oxygen jet and the heterogeneous plume of the bottom stirring gas. Further optimisations were obtained by a variation of lance tips and a newly developed lime addition model."

Jan 1, 2004

By Robert E. McIvor

"The Functional Performance Equation for ball milling circuits allows us to isolate the circuit classification system efficiency (CSE) from the mill’s grinding performance. The factors which affect circuit CSE are reviewed, with emphasis on water usage at the classifiers. It is shown that manipulation of such water usage can be carried out to improve plant grinding circuit efficiency, at times by more than 30 percent.THE FUNCTIONAL PERFORMANCE EQUATIONObservation of the feed and product size distributions going into and discharging from the mill in grinding circuits with low versus high circulating load ratios initially led to the definition of “circuit classification system efficiency” (or CSE, McIvor, 1988a), and ultimately the discovery of the Functional Performance Equation (McIvor, 1988b, and McIvor et al, 1992). The CSE is the percentage of “coarse” (typically with reference to the plus P80) size material occupying the mill (versus “fines” or product size material, finer than the circuit P80), and can be calculated by taking the average of the percentage of coarse material in the mill feed and mill discharge. As this also represents the percentage of the mill energy expended on targeted, coarse size material, it is directly proportional to overall grinding circuit efficiency and production rate. This is all clearly expressed in the Functional Performance Equation for ball milling circuits, which is derived as follows.We define “fines” as any product size material, and “coarse” as that targeted to be further ground, the two typically differentiated by the circuit target P80. For any grinding circuit, the production rate of new, product size material (fines) must equal the specific grinding rate of the coarse material (i.e. fine product generated per unit of energy applied to the coarse material) times the power applied to the coarse material."

Jan 1, 2009

"The QEMSCAN system is the third generation of automated mineral analysis systems that began with the QEM*SEM at CSIRO 30 years ago (Butcher et al. 2000). It is now a successful commercial instrument with 39 instruments in operation around the world. Back Scattered Electrons (BSE) and Energy Dispersive (EDS) X-Ray spectra are used to create digital mineral images with mineral identification occurring online. Low-count EDS spectra are used preferentially to BSE brightness, allowing minerals to be accurately identified by chemical composition. Individual minerals or groups of similar compositions are identified by comparison to a comprehensive mineral database incorporated into the QEMSCAN software. Optical mineralogy and Scanning Electron Microscopy is a metallurgists’ tool for determining the ore process mineralogy and delivering a better flowsheet. These techniques have limitations, provide limited information and sometimes fail to provide representative information. In contrast, QEMSCAN provides information on the nature and occurrence of all mineral species present plus the liberation characteristics, looking at thousands of particles in the sample presented. Some of the data presented includes:• Particle and grain sizes• Dominant mineral species• Particle shape• Calculated metal content• Density• Deportment of elements of interest between the mineral phases• Quantitative mineralogy• Mineral associations, locking and liberation• Textural relationships (particle images)It can also be used on concentrates, polished sections or drill core. This is a significant improvement in ore characterisation providing lithology, mineralogy, liberation, ore grade and porosity from a sample. Theoretical grade-recovery curves can be created to be mineralogically limited from QEMSCAN analysis which, when compared with metallurgical results, are valuable in evaluating whether liberation or chemical selectivity is driving flotation performance. A number of case study examples are given where the QEMSCAN had a significant bearing on future project development at an early stage of exploration and mine development."

Jan 1, 2012

By Gurinder Kaur

Selenium (Se) based materials find wide applications in rectifiers, solar cells, photographic exposure meters, data storage devices, xerography and anticancer agents. They are also used in the glass industry to eliminate bubbles and remove undesirable tints produced by iron. In addition, Se is highly reactive towards a wealth of chemicals that can be potentially exploited to convert Se into other functional materials such as CdSe, ZnSe, Ag2Se. Here, we report a review of structural investigations of Se based materials in glassy and nanostructured forms. Glasses having varying amounts of Se and Tellurium (Te) were doped with group IV and V elements such as antimony and tin. Structural changes accompanying the composition variation were characterized with x-ray photoelectron spectroscopy, differential scanning calorimetry and x-ray absorption near edge spectroscopy. At the same time Se-Te nanoalloys were synthesized in aqueous micellar phase using Na2SeO3/Na2TeO3 as the Se/Te source. Morphology change from nanoparticles to nanoribbons was investigated using Scanning and Transmission Electron Microscopy (SEM/TEM) techniques. Structural investigations were also done for well defined morphologies of Se based nano-biomaterials obtained in the presence of water soluble protein bovine serum albumin (BSA).

Aug 1, 2013

By Karim Ramji

The extractive sector today faces growing social, legal and political risks (SLPs) from so many different stakeholders including national and local governments, name and shame groups, civil society and environmental groups, and the ?Occupy? movement. Beyond these stakeholders, there are the indigenous peoples who have growing legal, social, political and economic influence which can often determine the outcome of the Project. The development curve in the extractive sector from initial exploration to mine start-up has become longer, steeper and more risky and expensive as these SLPs have grown in scope and complexity. Even if a project is permitted or starts commercial production, its ongoing development and operations are also facing these SLPs. The continuous assessment of these SLPs and the strategy to mitigate for them has now become critical for every project in the extractive sector. A project will only be successful if it is able to obtain the legal permits to operate, then withstand any judicial reviews, and then also to be able to gain and maintain the Social License to Operate (SLO). Stakeholder identification, management and engagement are key risk-mitigation tools. This paper focuses on the growing influence that indigenous peoples are now enjoying and the impacts on the extractive sector. Indigenous peoples are a unique stakeholder group because their legal rights and interests to lands and resources, their aboriginal title and rights, are gaining more recognition. When indigenous peoples form alliances with other stakeholders, this simply adds to their growing momentum and leverage, and this can become a daunting challenge for the extractive sector. More due diligence is required by companies to understand and assess the challenges posed by operating in areas claimed by indigenous peoples. There is a real need for mining companies to develop an effective indigenous engagement strategy to address these challenges in order to successfully convert risks into opportunities. Early identification and engagement with the indigenous peoples is required and the goal should be to conclude an Impact Benefits Agreement (IBA) with the affected indigenous peoples. The real objective must be to develop a real and transparent relationship between the company and the indigenous peoples so as to gain and maintain the SLO.

Aug 1, 2013

By F. Weinberg

"The recent development of the continuous casting process for steel has required basic understanding in a number of areas in the metallurgcal sciences. In some areas, information is still lacking. The success of the application of basic knowledge and research to the process is evidenced by the fact that a large percentage of the steel now produced in the world is produced by continuous casting.A number of areas in which metallurgical science has contributed and is currently contributing to better design and control of the continuous casting process and leading to a better quality product will be considered. These include:(a) heat transfer studies of the entire casting process;(b) fluid flow in the tundish, strand and liquid metal stream;(c) solidification structure and segregation;(d) strength and ductility of steel at high temperatures related to bulging and cracking; and(e) problems related to horizontal casting developments.IntroductionThe continuous casting of steel is a relatively new technology in steelmaking. It is now used extensively throughout the industry. In Japan, for example, continuous casting accounts for approximately 40010 of steel production, and this value is expected to increase to over 50% in the near future . New steel plants are now designed to use continuous casting exclusively. This means the process must work well and be completely reliable, because all the steel produced must go through the caster.The development of the continuous casting process in a short period of time has required concerted research and development in many areas . I shall cite a number of examples of these developments and refer to work done in Canada when applicable. No attempt will be made to review all of the research in continuous casting, nor refer to all of the workers in the field.The developments in continuous casting are based in many cases on metallurgical science, as described below. The use of metallurgical science in these developments is qualitative, in that concepts and idea s are used, as opposed to quantitative values calculated from fundamental equations. In general, most metallurgical problems are too complicated to enable fundamental equations to be used without the introduction of uncertain approximations and boundary conditions in the calculations.Starting at the beginning of the steelmaking process, very extensive research and development has been carried out to produce liquid steel of the required composition and temperature. The replacement of open hearth furnaces with BOF furnaces reduced refining time from many hours to roughly 30 minutes for 250 tons of steel. Two BOF furnaces effectively enable a continuous flow of steel to be available in a plant, essential for the introduction of the continuous casting process. This area of research will not be considered here."

Jan 1, 1981

By A. M. Reyes

Flow field hydrodynamics of serpentine flow channels was investigated numerically using computational fluid dynamics (CFD). The velocity profile simulated by the CFD model was evaluated with respect to experimental results from the literature. Rectangular and tapered flow channels were compared with respect to mixing and water management capabilities, and pressure drop. The CFD model was further developed to account for electrochemical reaction on the cathode side to determine which channel configuration was most effective in reactant conversion. The velocity profile differences between the channels were found to impact reactant conversion, as the rectangular channel had the highest conversion. With respect to water management, although the tapered channel was found to have a higher overall pressure drop, the rectangular channel was found to have higher shear and pressure forces acting on simulated liquid water droplets in the channel.

Jan 1, 2005

By K. R. Coulter

"Good morning gentlemen. I am very pleased to have this opportunity to tell you a few of the things that happen within a completely unrelated activity, the electroplating industry, except that it does consume metals and has some slight similarity of problems so far as cyanide is concerned.First, just a few general terms about the industry. It is a relatively unsophisticated industry technically, and in many instances there are serious problems in obtaining staff that can operate the various systems that are currently available for destroying cyanide or precipitating metals.I would suggest to you that if you are investigating any system that you consider very seriously the personnel that are actually going to run it. The installation people; probably have some idea what it is all about but the operators must be chosen for their ability and not because they just happen to be available.We perhaps have another area in common. There is very little money for capital expenditures that produce no immediate return or even eventual return on the investment.The industry is largely made up of ""Jobbers"" who are strictly electroplating. There is another group in which the electroplating is captive as in large companions where it is a convenience operation. Also there are specialists, who do other things besides plating but it is a very major part of their operation. This applies to the automotive parts industry.Cyanide applications in the plating industry will be for copper, zinc, cadmium, silver, brass, and gold. Cyanide waste solutions come from those solutions adhering to the plated parts, and from the occasional discharge of the plating bath solutions. Also, in a related industry, the heat treating people with cyanide case hardening have some high concentrations of cyanide to dispose of. Concentrations of cyanide that we treat are 2500 parts per million or higher especially in wastes from heat treating. Solution volumes might be as low as 100 gallons per hour in a well run, carefully operated rinsing system. It may be as high as 3000 gallons per hour where dilution occurs."

Jan 1, 1973

By H. Zhu, Q. Jiang

The leaching kinetics of iron during the atmospheric direct leaching (ADL) of marmatite concentrate was studied under the following conditions: reaction temperature of 343-383 K, slurry pressure of 0.3-0.7 MPa, particle size of (-74 ?m, +63 ?m), (-63 ?m, +44 ?m), (100%-44 ?m). The statistical effects of reaction temperature, total pressure and particle size of concentrate on the extraction and the leaching rate of iron were analyzed. The results show that reaction temperature is a significant factor while slurry pressure and particle size are not statistically meaningful with respect to the extraction or the leaching rate. The extraction of iron fits better to the mixed-controlled shrinking core model and the apparent activation energy was calculated to be 37.66 kJ/mol. The leaching of iron is mixed controlled by the interfacial chemical reaction and diffusion across the product layer.

Jan 1, 2014

By T. Patching

"A GLANCE BACK AT what has happened in the past is often a useful guide to the future, although it should be used mainly to provide a sense of direction rather than a map that must be followed. As a preamble to discussing some of the questions posed by the organizing committee it may be appropriate to briefly review the distribution and careers of the graduates of our Department since the first degree in mining engineering was awarded in 1916. An attempt has been made to keep a record of the locations and careers of the Department's 540 graduates in mining and metallurgical engineering. Almost all of those who graduated before 1930 have now retired, but a very large proportion held positions as senior executives prior to retirement. A major proportion of those who graduated before 1950 are now in what might be considered senior management positions. Those who have 10 to 20 years of experience are generally in work of senior engineering responsibility or in supervisory or junior management ranks, while those who graduated in the last ten years appear to be generally in staff engineering or junior supervisory positions. This classification is admittedly imprecise because it is difficult to determine from a job description whether duties should be considered of an engineering or management nature - a distinction between the two terms is often over-emphasized. Nevertheless, the trend from technical engineering to management responsibilities with seniority and years of experience is clear in the careers that we have been able to follow."

Jan 1, 1972

By I. C. Brown, J. F. Henderson

"IntroductionThe Yellowknife greenstone belt lies along the west side of Yellowknife bay on the north shore of Great Slave lake, some 600 miles north of Edmonton, Alberta. The producing gold mines along the belt include the Con-Rycon and Negus which came into production in 1938 and 1939, and the Giant Yellowknife, which followed in 1948. In addition to these, the Akaitcho and Crestaurum mines are potential producers and there are several promising prospects.Early geological work along the belt was done by A. W. Jolliffe who first recognized a number of great faults, the largest of which is the West Bay fault with a horizontal movement of more than 3 miles. In 1943, A. S. Dadson, following an examination of the Giant-Yellowknife property, advanced the hypothesis that Baker Creek valley was underlain by a series of major gold-bearing shear zones. Subsequent diamond drilling in 1944 bore out the correctness of this view and outlined the great ore-bearing shear zones that are now being developed and mined by Giant Yellowknife Gold Mines. Near the south boundary of the Giant property, the shear zones are cut off by the West Bay fault. This prompted Neil Campbell, District Geologist for the Consolidated Mining and Smelting Company, to make a detailed study of the geology along the West Bay fault in the hope of finding the faulted extension of the Giant shear-zone system on the west side of this fault. In this he was entirely successful. By careful geological mapping he matched several faulted diabase dykes on both sides of the fault and, knowing their dip, determined the horizontal and vertical components of movement along the fault. Subsequent •diamond drilling based on Campbell's work located the presumed correlative of the Giant shear-zone system on the Con-Rycon and Negus properties, where it has been named the Campbell zone or system. At the present time, all production at the Negus Mines property is coming from orebodies along the Campbell zone."

Jan 1, 1950

By Thom Mambe, Angelo Fernando

The objective of this work was to identify key parameters related to the reduction of the sulphur content in ammonium diuranate (ADU), and the identification of solid products being formed under various operating conditions. A laboratory-scale, continuous ADU precipitation circuit was assembled using a glass reactor vessel immersed in a temperature-controlled water bath. A pre-prepared uranium feed solution was fed continuously using a peristaltic pump. Anhydrous ammonia mixed with compressed air was metered and pumped using a double-headed peristaltic pump. An over-head mixer was used to keep the solids in suspension. The precipitated ADU slurry was removed from the reactor at the same flow rate as the feed solution. The slurry was sampled to generate ADU solids for chemical and physical analysis after four hours of continuous operation to ensure steady-state conditions. The following variables were studied to determine their influence on the sulphur content in the resulting ADU. (a) sulphate:uranium molar ratio in the reactor (1:1, 1:5, 1:10 and 1:20) (b) precipitation pH ( pH 6, 6.5, 6.9, 7.5 and 9) and (c) precipitation temperature (40C and 60C) A total of 18 tests covering the above parameters were conducted, and the results indicated that the sulphur content in the resulting solids was highly dependent on the reaction pH. Out of the pH levels tested, tests completed at pH 6.9 and 7.5 generated solids containing the lowest sulphur contents, between 0.5 to 1.5% S uranium basis (UB). The sulphur content in solids was found to vary linearly with the sulphate:uranium ratio in the feed solution, showing a statistically valid correlation. The impact of temperature was minor between 40°C and 60°C, with a slight advantage at higher temperatures. Tests at a sulphate:uranium ratio of 1:1 produced solids with the lowest sulphur contents. The influence of pH or temperature on sulphur content in solids was almost non-existent at this sulphate:uranium ratio. Precipitation pH is the major factor influencing ADU sulphur content, followed by the uranium to sulphate ratio.

Jan 1, 2020