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By Niraj Bala

Boiler tubes of coal-fired boilers suffer severe erosion-corrosion (E-C). One method to counteract this problem is by the use of therma, spray protective coatings. Cold spray coating process was used to deposit Ni-20Cr powder on SA 516 (Grade 70) boiler steel. The bare as wel, as the coated steels were subjected to cyclic experimenta, studies, in the superheater zone of a coa, fired boiler. The weight change technique was used to establish kinetics of the erosion-corrosion. XRD, FE-SEM/EDS and X-ray mapping techniques were used to analyse the as-sprayed and corroded specimens.

Jan 1, 2010

By J. P. Jylhä, A. Jokilaakso

The Outotec Flash Smelting process is widely used in primary copper production. A layer of slag on top of matte (copper–iron sulphide melt) creates a barrier through which matte droplets descend. Droplets of different sizes settle through the layer at different rates, which increases possibility of copper losses as smaller matte droplets may be removed with the slag. In this work CFD-DEM (computational fluid dynamics – discrete element method) coupling was used to simulate matte droplets settling through the slag during slag tapping. Discrete droplets and slag flow were simulated with DEM and CFD, respectively. This new approach enables tracking and solving movement and interactions of individual droplets. User-defined models were created to take coalescence and reaction kinetics into account. Coalescence created larger droplets, while the reactions decreased droplet size and increased its density. Drag caused funnelling effect, which pulled droplets towards the centre line of the descending cluster. This research is the only study known by the present authors in modelling liquid-liquid systems with the CFD-DEM coupling. Simulating coalescence and chemical reactions for discrete droplets enables more realistic simulations. However, CFD- DEM simulations are computationally resource intensive already without additional models, so a full scale industrial settler modelling still waits for further increase in computer performance. INTRODUCTION Flash smelting is a method used in copper and nickel production. In the flash smelting process, oxidation of sulphides in a concentrate is used to release energy needed to smelt the feed. In the process, copper matte is formed. Matte has copper content in the range of 55 – 70% (Sridhar, Toguri, & Simeonov, 1997), the rest is mainly sulphur and iron but has still many other impurities (Taskinen, Seppälä, Laulumaa, & Poijärvi, 2001). Oxidized iron forms iron-silicate slag while SO2 is collected for acid production (Davenport & Partelpoeg, 2015). The Outotec flash smelting furnace (FSF) can be divided in four major component: concentrate burner, reaction shaft, settler and uptake. Concentrate, flux and oxygen enriched air are injected into the reactor through the concentrate burner. The mixture then reacts in the reaction shaft forming matte and slag, which are collected in the settler, while off-gases flow out of the reactor through uptake for heat and dust recovery, and SO2 collection for H2SO4 production. The matte and slag form separate layers due to immiscibility and density difference. Raw material feed is continuous, but the matte and the slag are tapped periodically. A flash smelting furnace is depicted in Figure 1.

Jan 1, 2019

By E. H. Rose

THE most useful guide to the role of lime in flotation is the view that the chemistry of any flotation operation is primarily a pattern in relative solubilities. We have the coming together of a number of minerals, reagents, fortuitous salts, water, and oxygen, many of which have not been previously in contact with each other, and every one of which is free, at least to some extent, to abandon old alliances and to form new ones. Of one thing the operator may be sure, and that is that, when equilibrium has been reached, those new chemical combinations will have formed which are the least soluble combinations possible to the environment. The laws of solution govern the operation, which means that relative concentrations are always a factor, and temperature frequently is. What the operator is really doing when he chooses his reagents .in the first place (empirically or otherwise) and works out their? optimum amounts, is to provide an environment in which (1) the least soluble possible compound of the mineral he desires to float is one which is also non-wettable, while at the same time (2) the least soluble compounds possible to the minerals he desires to depress are wettable. Since all metathesis is reversible, perfection is impossible to achieve, and the operator is constantly striving to establish that combination of concentrations which will drive each and every particular reaction as far as possible in the direction he desires it to go, in accordance with the law of molar concentration.

Jan 1, 1939

By Wm Petruk

"The tungsten-bismuth-molybdenum deposit in southwestern New Brunswick occurs in greisenized and silicified tuffite * and feldspar porphyry in and adjacent to volcanic necks. The ore minerals occur as veins and veinlets and as disseminated grains in gangue. These minerals can be grouped into three assemblages. Assemblage 1 consists of oxides and phosphates of W, Ti, Fe, Nb, Sn, Ta and rare-earth elements, with the main minerals being deposited in the sequence wolframite, rutile, cassiterite. Assemblage 2 consists of arsenopyrite, molybdenite and bismuth, and assemblage 3 of sulphides with minor cassiterite and arsenopyrite. Sphalerite is the main sulphide mineral, but it contains minute inclusions of copper-tin- and indium-bearing minerals. Textural relations suggest that most of the elements can be recovered from this ore by conventional mineral beneficiation and extraction methods, but a variety of techniques must be employed. It is expected that the wolframite and molybdenite can be recovered satisfactorily, but poor recoveries are expected for bismuth and cassiterite. A sphalerite concentrate can be readily obtained by flotation, but it would contain a wide variety of elements. It is suggested that leaching be used to recover the bismuth and the elements in the sphalerite concentrate."

Jan 1, 1973

By K. C. Corin, Z. G. Song, J. G. Wiese

In the present investigation flotation was used as a diagnostic to understand the effects of changes to the media during the grinding stage. The observations from flotation for different media are discussed in terms of particle size distribution, water recovery, solid recovery and valuable mineral recovery. The chemical parameters; pH, redox potential (Eh) and dissolved oxygen (DO) levels were measured. A Base Metal Sulphide (BMS) ore was ground under media of different shapes and compositions to determine the effect of different rod/ball material on the flotation performance of the ore. For a given grind (D80 = 75 µm), media shape had no effect on flotation performance of a BMS ore. Different grinding media had significant effect on slurry chemical properties and flotation performance. Mild steel rods (RMMS) produced the highest solids recovery, nickel and pyrrhotite (Po) recovery, with the highest ethylenediaminetetraacetic acid (EDTA) extractable iron and the lowest DO level. Chrome steel balls and stainless steel rods produced the lowest metal recovery, EDTA extractable iron and the highest DO level. A complementary study was conducted to investigate the effect of using different grinding media compositions, viz, ceramic, forged steel, 15% chrome steel, stainless steel and a mixture of stainless steel and 15% chrome steel (50:50) balls were investigated using a Platinum Group Mineral (PGM), UG2 ore. Grinding products of five different media produced the same solids and water recovery, but the grades and recoveries of Platinum Group Elements (PGE) and chromite were different. Grinding products of ceramic media showed the best flotation performance, with the highest PGE recovery and the lowest Cr2O3 recovery. While grinding products of stainless steel balls (SS) produced the lowest PGE recovery and highest Cr2O3 grade and recovery in the concentrates.

Jan 1, 2016

By Eric Konigsmann

"The Pogo project is located on the Goodpaster River, 38 miles north of Delta Junction in east central Alaska. Sumitomo Metal Mining and Teck Corporation are planning to develop a 2,500 ton per day underground mine and mill at Pogo. A preliminary resource of 5.5 million ounces of gold has been identified in two flat lying lenses. An underground adit has been developed to facilitate underground drilling of the deposit and to provide samples for bench and pilot scale metallurgical testwork.Flowsheet development included the evaluation of several processing options. The final flowsheet selected includes SAGhall mill grinding, gravity concentration with intensive cyanidation and direct electrowinning, sulfide flotation with ultrafine regrinding, and cyanide leaching and CIP gold recovery from the flotation concentrates. Flotation tailings will be filtered for placement in a dry stack storage facility or disposed of as paste backfill underground. All of the CIP tailings will be disposed of underground as paste backfill. A pilot plant was carried out to evaluate the proposed flowsheet described above and to confirm the gravity recovery predictions.Great care was taken in the development of the flowsheet and site layout concepts to mitigate the environmental impact of the proposed operation. An overview of the site water management concepts is presented and the impact of water issues on the process flowsheet is discussed."

Jan 1, 2002

By F. Bélanger, P. A. Fournier

"Modelling and optimization techniques used in the operation of the Detour Lake Mine leach circuit are contrasted to a 1973 review of contemporary techniques used by a major gold producer. The leach circuit at the Detour Lake Mine was modelled using a full factorial Design of Experiment of stirred tank reactor leach tests using circuit feed. Contour plots of extraction were applied in the plant to optimize addition rates of cyanide and the newly-commissioned lead nitrate system. Contour plot sections were used to understand the impact of sulphur in circuit feed at different operating dissolved oxygen concentrations. The 1973 review paper offers insight into industrially-applied modelling and optimization techniques. In particular, a mathematical model of plant data was developed using multilinear stepwise regression analysis. The model was presented using graphical representations available at the time and applied to optimize the rates of cyanide addition. Off-the-shelf software solutions of today allow mineral processors to quickly and easily visualize data, allowing them to re-allocate time and resources spent processing data to generating raw data and extracting actionable information.IntroductionModelling and optimization in mineral processing is the art of reducing reality through judicious use of assumptions to understand a process and leverage this knowledge to engineer practical solutions to metallurgical problems. Data analysis is at the core of this enterprise.While this paper showcases the modelling work done at the Detour Lake Mine (DLM), the primary objective is to pause and reflect on how far the field has progressed since the 1970’s. A snapshot of state-of-the-art gold cyanidation modelling at that time is a review paper of the Anglo American Group’s capabilities (Brittan & van Vuuren, 1973). The objective of this paper is not a play-by-play of the evolution of modelling and optimization since that time. Rather, it is a comparison of the field at two points in time.In 2016, DLM undertook an extensive bench-scale leach circuit modelling program to better understand the impact of cyanide, dissolved oxygen, lead nitrate, grind size, density, and pH on gold cyanidation (Fournier, 2016). Two major capital expenditure projects were anticipated for 2017: improvements to oxygen control and a lead nitrate distribution system. While the lead nitrate system was planned for construction, the design parameters had not yet been selected. Following the development of the model, plant trials were executed to validate aspects of the model and the methodology was expanded to address other plant issues, in particular the effect of talc chlorite and pyrrhotite in leach feed.The variables of the bench-scale study are summarized in Table 1. Dependent variables were varied using a full factorial design of experiment with two repetitions for each test condition, yielding a total of 300 tests. Test order was randomized to eliminate bias from independent variables."

Jan 1, 2018

By Earl T. Hayes

This paper briefly reviews the laws enacted in the United States governing the coal miner. It discusses amendments to the Coal Mine Safety Act and describes the provisions of the Metal and Non-Metallic Mine Safety Act.

Jan 1, 1969

By Niels Verbaan, Ernesto Bourricaudy, Ronald Molnar, James Brown, Sunil Jayasekera

"SGS Minerals commissioned an internal R&D program to develop in-house expertise to design, set up and operate REE separation pilot campaigns at its Lakefield, Canada site. A team approach was used that included expert consultants in the field of REE separation as well as in-house expertise supported by the on-site Analytical Laboratories.A mini pilot scale SX circuit was designed and constructed consisting of several modular banks of 30 stages each. About 80 stages of mixer-settlers were used to separate Pr and Nd from La and Ce contained in a synthetic REE chloride stream simulating the raffinate from an initial La-Nd|Sm-Lu+Y separation.Two pilot campaigns were operated totalling 25 days of 24/7 operation with 99.4% plant availability in the final 20 day campaign. Purities of > 99.9% in the Pr-Nd strip liquor and > 99% in the La- Ce raffinate were achieved and simultaneously sustained in the second campaign for prolonged operating periods. Key to controlling and adjusting the circuit was the rapid assay turnaround (as low as 2 hours) provided by the on-site SGS analytical lab. This permitted the operating team to modify conditions and observe the effect of changes relatively quickly considering the large number of stages. A portable XRF analyser was also used to track evolving assay trends in the circuit. The small physical size of the circuit enabled longer operation with a limited amount of sample.This paper discusses the design of the circuit, operating conditions, some of the key operating factors and controls and results obtained.INTRODUCTIONSGS Minerals commissioned the design of and built a solvent extraction (SX) pilot plant for the separation of rare earth elements (REE). The plant consists of a battery of 120 mixer-settlers set up in a dedicated piloting facility.The purpose of the programme was to develop capabilities and in-house expertise in REE SX separation technology. The program aimed to establish operating procedures, sampling regimes, and analytical methodologies and protocols for this type of process/plant. A team comprised of SGS personnel and several external consultants with prior industrial and REE separation piloting experience was assembled to achieve these objectives."

Jan 1, 2016

By J. Sliwinski, H. Kikutani, J. Atwood, D. Larimer, J. Pyecha

"The Pogo mine start-up milling targets of 2005 are vastly different than the targets of today. Improvements have been driven by unintentional design oversight, continual circuit optimization or optimization due to changing mineralogy. The more significant process improvements to date have occurred in the gravity, flotation and leach/CIP unit operations. Details of the significant improvements are presented along with the impacts to the process.INTRODUCTION Deposit Overview Pogo mine is located along the Goodpaster River, southeast of Fairbanks, Alaska. This deposit sits in the center of the Tintina Gold Province (Figure 1), a region of similar Intrusion Related Gold deposits in Interior Alaska, the Yukon and British Columbia Canada (McCoy et al., 1997). The Pogo deposit is hosted in a rock sequence of amphibolite-grade gneisses intruded by mid-Cretaceous granitic plutons and dikes, which in turn, were cut by and host the auriferous quartz veins of the Pogo deposit.The Pogo deposit is comprised of three distinct zones of auriferous quartz veins spatially adjacent to each other. These are the Liese Zone, North Zone, and the East Deep Zone. The Liese Zone consists of three stacked, massive quartz veins, designated the L1, L2, and L3. Vein thickness averages 3.0 m, with variations from 0.3–18 m thick. The North Zone mineralization is comprised of four veins with more consistent thickness, between 1 and 1.5 m. The East Deep deposit lies northeast of the Liese Zone ore body. It is separated by a post mineralization, quartz diorite pluton. The East Deep Zone is comprised of two stacked massive quartz veins with similar orientation as the Liese Zone."

Jan 1, 2017

By J. D. Jorgenson

?? U.S. domestic production peaked at 120 Mt during years of the Korean Conflict120 Conflict ?? Pellet production increased, as highPellet high-grade ores decreasedores decreased ?? Until 1982 recession, most U.S. iron ore mines owned by steel companiesmines companies ?? Large Canadian iron ore mines brought into production after 1950into 1950

May 1, 2011

By D. F. Malan

"This document highlights some of the topical problems associated with the design and support of deep tabular excavations in hard rock. The displacement discontinuity boundary element method has been used for at least five decades to analyse stress and displacement distributions around narrow width excavations with complex plan outlines. The assumption is made in most cases that the rock mass surrounding the excavation is perfectly elastic. Although this approach works well to minimise stress concentrations in practice, it has limitations as important parameters, such as the effect of mining rate, cannot be investigated. Recently, a limit equilibrium model has been studied as a means to enhance standard layout design exercises by including an interactive on-reef damage model. This approach can include explicit energy release dissipation computations. A second problem faced by engineers in the mining industry is the evaluation of pillar and remnant stress. The paper highlights two aspects namely the effect of element size in displacement discontinuity modeling on pillar stress and the difficulty to estimate the effect of total closure on the regeneration of stress in old mining areas. Regarding the support of the tabular excavations, current efforts are focussed on providing improved aerial coverage using hangingwall bolting and temporary nets. An unresolved issue is the installation of permanent mesh in low stoping width areas. INTRODUCTIONSince 1886, more than 50 000 tons of gold has been mined in the Witwatersrand Basin of South Africa (Hartnady, 2009). The nearby platinum mines also saw significant growth in recent years and more than 80% of the world’s platinum group metal reserves are contained in the Bushveld Complex of South Africa (Nell, 2004). Apart from the economic aspects, the mines served as an outstanding rock engineering “laboratory” for many decades owing to the deep, tabular nature of the excavations. The period from 1960 to 1980 was especially lucrative in terms of research and world-renowned researchers investigated the support and rockburst problems (e.g. see Cook et al., 1966; Salamon, 1968; Bienawski, 1973; Wagner, 1984). Many of the rock-related problems nevertheless persist up to the present day and this paper explores some of these problems and recent progress. The production of gold declined substantially in recent years (Hartnady, 2009) and well-directed rock engineering research can play a meaningful role to slow this trend. The objective of the document is to highlight critical areas requiring additional research and not to discuss the topics in detail. The reader is referred to the many references for additional information. The paper only focuses on three areas namely numerical modelling, pillar stress estimation and aerial support. Although these are diverse topics, it is included in one paper to illustrate the many unsolved and practical problems associated with deep tabular excavations."

Jan 1, 2015

By T. Rigg, J. N. Stone

"The process described has been developed to utilize low-grade scrap -turnings, borings, tin cans and other types of ferrons scrap which currently has been of limited or no use in conventional steelmaking processes. If scrap of this type can be converted into high-purity iron by chemical means then there is a potential saving of several million tons of metal annually in North America.The process is chemically quite simple and consists of dissolving ferrons scrap in hydrochloric acid, followed by evaporation and crystallization of the resultant solution to yield ferrons chloride crystal.s. These crystals are dries, briquetted and converted to non sponge by reduction in hot hydrogen. The HCl produced from the reduction step. is absorbed in water and the hydrochloric acid so produced is returned to the dissolver circuit. The hydrogen produced from the initial dissolution of the scrap is used to reduce the ferrons chloride. Purity is maintained by bleeding off impure chloride solutions from the evaporator-crystallizer circuit, and converting these chlorides to oxides and HCI in a high-temperature spray roaster. The HCl produced in the roaster is absorbed in water and the hydrochloric acid returned to the dissolver."

Jan 1, 1970

By P. G. Hallof

The exploration staff of Campbell-Chibougamau Mines Limited has used past experience to delineate several areas of geologic interest under Lake. Chibougamau. Du• ring the winter of 1964-65, a reconnaissance induced polarization survey was carried out on the lake. First, several lines were surveyed over the known mu1.erahza-tion at the Henderson mine; the grid was then extended into the areas of interest. Several anomalous zones were located and drilled; one, of these proved to be of economic interest.

Jan 1, 1967

By Jun Dai

Based upon research findings from several countries, the combination of microwave and mechanical means to break hard rock holds promise for the future. To achieve this goal, it is essential to understand the laws governing strength reduction of hard rock, such as granite, induced by microwave irradiation. Two aspects to consider are: 1) laws associated with the tensile strength of hard rock after microwave irradiation and 2) the sensitivity of different types of rock strengths to microwave energy. In this study, granite with a range of tensile strengths was exposed to microwaves for various time periods to compare the response of rocks with different strength values exposed to the same microwave irradiation. In addition, a method based on hotspots is presented to explain the mechanism by which granite strength is reduced by microwave irradiation. Granite extracted from Qinling Mountain in Shaanxi Province, China is used in the research. ?50 × 50 mm cylindrical granite specimens were exposed to microwaves at a specific power level. The strength values of the heated granite specimens were compared with those of unheated specimens. Through the comparison and analyses, relationships were determined between 1) reduction in granite strength and microwave irradiation time period, and 2) granite strength and sensitivity to a given energy of microwave irradiation. Finally, a mechanism to explain the experimental results is proposed. Research findings will aid in the design of a microwave + machine rock-breaking system for use in rock breakage in underground mines at depth and for future mine applications on earth and other planets. In addition, the experimental approach could be used to test other rock types to further our understanding of rock damage induced by microwave irradiation.

Aug 1, 2013

By W. L. Goodwin

Twenty-five years ago mining engineering in Canada was not a profession. To-day the members of the mining fraternity can fairly claim for 10themselves the professional status. If their pretension is not fully warranted by fact it is not for lack of any technical attainment or service to the public but by reason merely of their neglect to cultivate the cohesion and consciousness that are the outward and visible signs of a professional body. This paper is an attempt, first to sketch briefly the course of the events during the past thirty-five years that have resulted in organizing the mining industry of this country in its present form; then to notice the principal features of the professional organization of this day; and finally to point out that an important part of the work of the mining engineer remains in the state of chaos that characterized the whole of it three or four decades ago, and to suggest a remedy. Thirty years ago there came a great wave of interest in mining in Canada, based principally upon the discovery of gold-quartz and gold-copper throughout wide areas in Nova Scotia, Ontario and British Columbia.

Jan 1, 1926

By F. Ebbutt

The copper-bearing waters now treated successfully at Britannia for the recovery of their copper content are almost entirely derived from what is known as the Fairview mine; this was the first extensive copper producer of the Britannia ore-bodies, and consisted of a number of almost parallel veins, carrying good copper values, the ore consisting of chalcopyrite and pyrite in a quartz gangue. These veins occur in what is known as the ?Britannia shear zone' (Schofield, S. J., G.S.C. Sum. Rept., 1918, Pt. B), developed for roughly five miles in a roof-pendant in the well-known Coast Range batholith. This .pendant is made up of Palxozoic rocks known as the 'Britannia Formation' (LeRoy, O.E., Portion of Main Coast of B.C. and Adjacent Islands; G.S.C. Memoir No. 996, 1908). These consist of dark carbonaceous slates, quartzites; and tuffs or basic flows, and within them are large quartz porphyry siJls. These Britannia rocks are sheared and altered, the resultant rock being a fissile quartz-sericite or quartz-chlorite schist. The mineralization invariably occurs in this chlorite schist, which in the more productive areas has mottles or blobs of chlorite developed. A narrow, though persistent, band of grey slate forms the footwall of the productive portions of the shear zone.

Jan 1, 1928

By N. Saracoglu, J. P. Golightly, R. H. Wallis, J. J. Brummer

"The McClean uranium deposits are located 11 km west northwest of the Rabbit Lake Mine. Their average grade is 1.8 % U3O8 , and they contain 6. 350 tonnes of uranium oxide in seven pods of variable grade and mineral assemblage. They are hosted by both basal Athabasca Group and the regolith developed on the underlying crystalline basement. The major mineral facies are: sulphide, arsenide, 'bleached', and hematite, with the important uranium minerals being coffinite, uraninite and pitchblende. Abundances of carbon and sulphur isotopes are consistent with their derivation from pyritic graphite in basement gneisses. Isotopes of oxygen and hydrogen suggest equilibration at temperatures of about 200°C. Ar39/ Ar40 age determination of illite associated with ore suggest mineralization began about 1300 m.y. ago and that significant alteration had ceased by about 1170 m.y. ago though Pb/ U data suggest the deposits continued to evolve into the Mesozoic.IntroductionThe McClean deposits lie on the eastern side of the Athabasca Basin of northern Saskatchewan where they are part of a cluster of uranium deposits lying west of Wollaston Lake (Fig. 1). The general stratigraphy is schematically portrayed in Figure 2 which emphasizes that mineralization is hosted by both the Athabasca Group and the underlying regolith and also that the deposits are preserved at depth and have not suffered from preand post-Pleistocene weathering and erosion. This circumstance, combined with their simple shape and the presence of seven separate zones of mineralization (pods) allows a description, based on over 450 fully cored drill holes, to be made of the wide variation in chemistry, grade, alteration patterns and position relative to the sub-Athabasca Group unconformity. Ar39 / Ar40 age determinations have been made of illites associated with regolith, Athabasca Group and mineralization and studies are in progress on C, S, 0 and H isotopes of mineralized material and host rocks. Only some of these data have been published; Brummer et al., (1981); Golightly et al., (1982); Bray et al., (1982); and Saracoglu et al., (1983). The only other published data on McClean geology are by Tremblay (1982, 1983)."

Jan 1, 1986

By A. A. Beland, R. J. Dawson, S. Shewchuk

"Shovel buckets, scraper blades, dipper teeth, mine car wheels and hammermills are examples of equipment which require routine maintenance due to abrasion. Service life can be extended by the use 0/hard/acing and buildup materials. Mining and milling applications are described and field welding procedures discussed.A high-stress abrasion test used to select hard/acing and buildup materials/or hammers in a hammermill is described in detail. Field tests of the selected alloys confirmed their performance, and maintenance records showed a significant saving in down time and cost.The relationship between the abrasion resistance of the alloys and their hardness, work hardening, composition and microstructure is summarized. IntroductionLarge volumes of ore are handled daily by the mining industry. The abrasive nature of most ores results in extensive wear to both handling and processing equipment. If such wear is neglected it may cause lost production time and also, in extreme cases, require the complete replacement of expensive equipment. The well-planned maintenance of components subject to abrasive wear by means of buildup materials and hard facing can result in substantial economic benefits. Such benefits can , however, only be realized through the correct choice of welding process, consumables and deposition methods available to maintenance personnel. Hardfacing MethodsHardfacing is applied by a variety of methods; the three most widely used being arc welding, oxyfuel gas and thermal spraying. Table 1 summarizes the major processes used within each method. Filler metals in the form of rod, wire or powder are necessary to fulfill the individual requirements of each process. The filler rods are available in the cast form or, in the case of ductile metals or alloys, as wrought rod or tube. All types are supplied bare or flux covered. Wire is supplied in two forms, drawn flux cored and drawn solid. Powder filler metals are available in many metals or alloys; they may be simple mechanical mixtures or prefused and atomized alloys made to a specific size range and shape for optimum results for each applicable process."

Jan 1, 1980

By M. Tadie, J. Wiese, K. Corin

The use of potential control in the flotation of ores has been applied in a variety of operations and presents an opportunity for improvement of selectivity and recovery of valuable minerals. Although it is possible to vary the redox potential (Eh) using chemical additives such as sodium hypochlorite or hydrogen peroxide this is more commonly done by varying the pH and dissolved oxygen (DO) concentration. The present study involves an investigation into the effect of varying dissolved oxygen concentration, ionic strength (IS) and pH on the flotation response with the aim of application to a South African lead-zinc ore. In all cases the Eh is measured as a function of the different DO, IS and pH values. The main objective was to achieve selective flotation of galena from sphalerite. The first part of the work was micro-flotation tests conducted on single minerals with galena used as the basis for effect of the factors studied on redox potential and ultimately recovery. The DO was varied by alternating between the use of air and nitrogen as the gas source to the micro-flotation cell. PH was varied between pH 9.2 and pH 11.8 using sodium hydroxide. In the first part of this study a factorial design approach was used to determine the interactive effects of the variables tested, viz. DO, ionic strength and pH, on the Eh and on the recovery. Redox potential was measured using a combination electrode made up of platinum wire and Ag/AgCl reference combination. Recoveries indicated that pH had the most significant effect on recovery and Eh. The influence of redox potential on recovery was found to be of relevance to the condition of high dissolved oxygen concentration and less so at low dissolved oxygen concentrations. It was also noted that that the combined interaction between ionic strength and dissolved oxygen concentration had a positive effect on recoveries, however this was not so with Eh. The chemistry of the ions in solution was observed to play a dominant role on the recovery due to changes in solubility arising to pH modification. The longer term objective of this work is to determine the optimal Eh conditions for the separation of galena from sphalerite.

Jan 1, 2016