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This paper comprises a description of on-stream analysis instrumentation, including sample handling, X-ray optics and data processing. It also includes a discussion of some typical applications of an on-stream analyzer as related to the mineral processing industry. Introduction T WO automatic X-ray spectrometers have been developed for the simultaneous analysis of as many as six elements in a given sample. These instruments, namely the On-Stream Analyzer and the new Vacuum Simultaneous Spectrometer, have been designed specifically for process control in industry where large numbers of static samples or a number of flowing sample streams must be analyzed continuously with both speed and accuracy. This paper is concerned particularly with the application of these instruments for the continuous analysis of dynamic samples. The Instruments The On-Stream Analyzer and the Vacuum Simultaneous Spectrometer are intended to serve industry by offering two basic approaches to the problem of continuous sampling of flowing sample streams. The On-stream Analyzer (Figure 1) is designed for the completely automatic and unattended analysis of flowing sample streams in a programmed cycle of operation.

Jan 1, 1965

By F. Rivard, M. G. Drouet, W. S. Ruff, P. Carabin

"In both the hot rotary-salt-furnace (RSF) treatment of aluminum dross and the cold ball-millsieving (BMS) treatment of zinc dross, enormous amounts of energy and recoverable metal are wasted and large amounts of greenhouse gas are produced. Such wastes and the environment pollution could be avoided by using the DROSRITE PLUS™ technology. Economic and GHG production comparisons between the presently used industrial treatment processes and DROSRITE PLUS™, supported by over one hundred tests conducted in Canada, the US and Europe, are presented. The savings, with DROSRITE PLUS™, would be about $191 and $418 per MT of aluminum and zinc dross, respectively.INTRODUCTIONDross is a material, which forms on the surface of molten non-ferrous metal, such as aluminum or zinc, during melting, metal holding and handling operations when the molten metal is in contact with a reactive atmosphere. Dross normally consists of metal oxides entraining a considerable quantity of molten free (unreacted) metal, and for economic reasons it is desirable to extract the free metal before discarding the residue. In the case of aluminum dross, recovery of the metal is usually carried out by treating the dross in a furnace at a high temperature (Peterson et al., 2002). By contrast, cold zinc dross is crushed in a ball mill followed by sieving to separate the coarse metal portion from the fine oxide residue.The conventional aluminum dross treatment process, using gas or oil-heated rotary salt furnaces (RSF), is thermally inefficient and environmentally unacceptable because of the salt slag and CO2 produced from the combustion of fossil fuels. In the past several years, a number of salt-free processes have been developed and some of these have found limited commercial use (Gripenberg et al., 1994; Lavoie et al., 1990). In all these dross treatment processes, heating of the cold dross in a rotary furnace requires an external energy input that varies between 375 and 2,500 kWh per (metric) tonne of dross. Molten metal separated during processing of the heated dross is tapped, and the remaining solid residue is discharged from the furnace."

Jan 1, 2012

By M. W. Grabinsky, B. D. Thompson

ABSTRACT: Use of cemented paste backfill (CPB) offers economic and environmental advantages over other backfill methods. However, many operations have limited knowledge of how their CPB behaves in situ. Therefore, to avoid over-pressuring containment barricades, backfilling strategies necessarily tend to be conservative. In situ monitoring at Barrick Gold Corporation’s Williams Mine and Inmet Mining Corporation’s Cayeli Mine has been conducted and factors controlling barricade pressures are demonstrated, including rise rates, binder content, stope geometry, and tailings properties. The application of barricade pressure monitoring on a stope-by-stope basis can increase backfilling efficiency and, thus, reduce stope cycle times, while maintaining optimal safety.

Jan 1, 2011

By C. A. Campbell

"There has been a significant reduction in maintenance hours and improved performance by maintenance crews at the MacLeod mine since the introduction of a Maintenance Control system which includes the use of maintenance standards. This paper deals with the steps taken to develop and implement the program. The objectives of the program and the organization and training of the control group are outlined. The work-order system, standards application, classification of work and the preventive maintenance procedures will be discussed.All maintenance information is processed on a Model 360-20 IBM computer, which turns out maintenance records and control reports for management action. Information in these reports, and reasons for reporting, will be discussed and the benefits resulting from the program reviewed."

Jan 1, 1973

By Gordon E. Agar, Brian Lyons, Gregory H. Styles, William B. Kipkie

"Rock rejection during the flotation of a copper-nickel ore was improved by adding carboxymethyl cellulose to both a rougher and cleaner flotation stage. The selection of the rock depressant was based on laboratory rates studies. Plant operating results are presented which confirm the laboratory selection of two particular brands of carboxymethyl cellulose.The rock assay of the concentrate was reduced from more than 40% to less than 15%.IntroductionThe traditional method of selecting flotation reagents relied upon batch bench scale tests, conducted under arbitrary conditions, to identify the effect of the reagent under examination. Too often these were ""one-off"" tests with little or no regard paid to the reproducibility of the results. Sophisticated researchers used statistical methods to design and evaluate the experiments but they were still obliged to rely on the arbitrary and often unreliable batch tests to generate the numbers that were analyzed statistically. An interesting side-effect of the enhanced sophistication of the statistical analysis was often that no significant effects would be uncovered in a series of experiments that would have generated many positive conclusions and much further experimentation if the same results had been evaluated by the traditional method.In the recent past, at least two groups of researchers a have directed their attention to the reliability of the batch experiments with a view toward improving the reproducibility of the test data. In this work the best of the improvements advocated by both of these groups have been adopted in order to generate kinetic data from batch tests that are as reproducible as possible.The objective of the work was to reduce the rock content of a bulk sulphide concentrate produced at Inco's Shebandowan mill. During 1982 the Shebandowan concentrate analyzed 3.5% Cu, 7.4010 Ni, 25% pyrrhotite and more than 40% rock, which resulted in an MgO content of 10.4%. Besides the expense of shipping all of this rock to Sudbury, the rock also contributed to the poor filterability of the concentrate. On favourable occasions the moisture content of the filter cake was slightly over 20% by weight. The magnesia content of the concentrate was deleterious to the reverberatory furnaces used by Inco for smelting nickel concentrate because the slag viscosity increased as the magnesia content increased, and the nickel lost in the slag went up."

Jan 1, 1987

By J. A. Russell

"UNTIL the last few years, the collieries of the Dominion Coal Company, Limited, while highly mechanized as to the cutting and transportation of the coal, still relied on the hand-loading of coal from the seam onto face conveyors. In these circumstances it was possible to assure that no large proportion of extraneous materials would be loaded with the coal, and the product could be quite well cleaned for the market by screening and hand-picking.Within the past few years, however, the Company has introduced an intensive programme of mechanization which will result in the virtual elimination of hand-loading .of coal. It has been the experience of other producers that mechanical loading inevitably leads to a very large increase in the amount of impurities in the product. This is occasioned by the fact that, at least up to the present, all types of loading machines have relied on the coal being broken from the seam by under-cutting and shooting. In this operation, a certain amount of roof and pavement material inevitably becomes mixed with the coal and, since selective loading is impossible with a loading machine, all this foreign material is loaded out with the product."

Jan 1, 1952

By Sergio Cattalani, David J. Kerr, Harold L. Gibson

Abstract - The Horne mine was truly a world class Cu and Au deposit. Between 1927 and 1989, it produced some 260 t of Au and 1.13 Mt of Cu from 53.7 Mt of ore that averaged 2.22% Cu, 6.1 g/t Au and 13 g/t Ag. The total value of Au and Cu production from the Horne deposit at metal prices of US$300/oz Au and US$1.00/lb Cu is an outstanding US$5.2 billion. The Horne mine was also a company builder. After optioning the property from Ed Horne (Tremoy Syndicate) in 1922, the Thomson-Chadbourne Syndicate discovered the deposit in 1923 and quickly grew to become Noranda, one of the world’s premier mining companies. This discovery fuelled exploration and, along with subsequent discoveries in the Val d’Or-Cadillac camps, led to the "economic development" of northwestern Quebec. The Horne deposit influenced and continues to influence genetic models for volcanogenic massive sulfide (VMS) deposits. Early observations at Horne contributed to an epigenetic replacement theory for VMS deposits. The most recent genetic model for the Horne, invoking sub-seafloor sulfide replacement of silicified and sericitized volcaniclastic host rocks within a graben, has subsequently been proposed for another giant VMS deposit, the Kidd Creek mine. The Horne and Kidd Creek deposits show many similarities, such as localization within synvolcanic grabens, long-lived hydrothermal activity uninterrupted by volcanism, sub-seafloor replacement sulfides, stacked sulfide lenses, zone refining, silicified footwall rocks characterized by high positive ?18O values, and association with FIII rhyolites. Notable differences between the two deposits include the lack of andesitic, basaltic or komatiitic flows at Horne, different inferred water depths, high Au content at Horne versus negligible Au, but sub-economic to economic concentrations of Sn, In and Cd at Kidd Creek.

Jan 1, 2000

By J. H. Pee, Y. J. Kim, H. U. Lee, G. H. Kim

The general recycling process of tungsten scrap to produce tungsten raw materials (tungstic acid, ammonium paratungstate (APT) and WO3) have been carried out by the oxidation, milling, sodium-fusion, dissolution, and extraction processes. Many studies on the high temperature oxidation of tungsten scrap have investigated various aspects such as swelling kinetics, fracture resistance, and the effect of alloying composition. However, the accelerating factors on the scrap oxidation rate during oxidation were not considered here. In general, oxidized products were fused with sodium carbonate or sodium hydroxide to produce Na2WO4. Later in the process, solid Na2WO4 was dissolved in water. This process required considerable reaction time and was a costly process. Therefore, the aim of this study was to increase the solubility of solid oxidized products to produce Na2WO4 solution by hydrothermal reflux method. Na2WO4 solution was used to produce CaWO4 and H2WO4 by general chemical reactions with calcium chloride and hydrochloric acid. Ammonia solution was also added to the tungstic acid to produce APT. In this study, the effect of ammonia addition on the APT precipitation process was investigated in detail.

Jan 1, 2015

By H. Sakurai, M. Kato, F. Tanaka

The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. The conditions in the CL- furnace change its settling efficiency, resulting in high variability of copper losses in slag. Modifications of the operation and maintenance procedures for the CL-furnace have significantly and sustainably reduced the copper losses in Gresik smelter to below 0.7%. A series of flow patterns evaluation in the CL-furnace demonstrated how the chemical reactions and settling conditions of the CL-furnace has been improved by the new operating procedures. Settling mechanisms for the matte droplets in the CL-furnace is also discussed using image analysis of solidified slag. INTRODUCTION The Mitsubishi Continuous Copper Smelting/Converting Process employs an electric furnace (CL- furnace) for settling the slag/matte mixture formed in the smelting furnace. Since the top-blowing in the S- furnace agitates the molten bath strongly, matte droplets are dispersed over the slag phase when melts flow out of the S-furnace. Thus, the CL-furnace has an important role to settle and recover matte droplets efficiently. Since many papers have ascribed major part of copper losses to matte droplets suspended in slag (Tanaka 2007; Genevski et al., 2008; Starodub et al., 2016), flow patterns of slag in the CL-furnace can affect greatly on the profitability of smelters which have adopted the Mitsubishi process. PROCESS DESCRIPTION Figure 1 illustrates the Mitsubishi process schematically. The Mitsubishi process is the only system for continuous production of blister copper from copper concentrates and consists of 3 furnaces connected by enclosed launders those ensure the minimum emission of fugitives. In a smelting furnace (S-furnace) copper concentrates are fed with flux, oxygen-enriched air to form a mixture of slag and matte which cascades down to a slag-cleaning furnace (CL-furnace). The CL-furnace settle matte droplets in the mixture on the crucible from which matte is siphoned to a converting furnace (C-furnace), while discharging the cleaned slag (CL-slag). The C-furnace converts matte to blister copper by the top-blowing of oxygen- enriched air.

Jan 1, 2019

By C. Grisanti, E. Prina Howald

The major of Swiss territory is occupied by mountains. Natural events as floods, debris flows, landslides, rockfalls, and avalanches regularly threaten the safety of people and properties. On the one hand, extreme weather events cause great damages, on the other hand, the enhancement of territory’s exploitation increases the risk. The Swiss Government makes many efforts to deal with the prevention of natural hazards, especially through measures of land management. As stated by federal law, Swiss cantons are obliged to establish hazard maps and to take the risk into account in the land management. Hazard maps are based on the hazard matrix, whose abscissa and ordinate are probability and intensity of the event on site. This project focuses on rockfalls. It consists of three main parts: the creation of a database to collect data on site, the creation of a catalog with all type of measures, and the development of a methodology for the analysis of the effectiveness of protective measures. The creation of the database allows us to collect information: about the site, about protective structures implemented on it, and about failures. With many multiple choice fields and few free text fields, it can collect data in a homogeneous way, without redundancy. The catalog has to be a tool that gives a basis to make decisions. It collects information about all types of protective measures implemented on Canton Vaud’s territory or available on the Swiss market. Free text fields allow for data storage of specifics, to give a complete view of structure’s characteristics and potentials. Methodology consists of four steps. The core of the procedure is the structure’s evaluation following a score system; it allows for calculation of reduction factors that have to be applied to intensity and probability parameters of the structure. Then it is necessary to convert the reduced structure’s intensity value into a residual site’s intensity value. Although the first step enables us to choose suitable measure for a specific site, it is not necessary to perform it. Second step allows us to evaluate structures under scenario 0, where structures are in best conditions. Third step allows us to evaluate structures under six scenarios of possible failings. Fourth step allows us to convert structure’s reduced intensity into event’s residual intensity and to establish the new point on hazard matrix. While the procedure has already been defined, details of score system and conversion have to be developed during the second phase of the project.

Jan 1, 2015

By D. L. Putnam

Snap Lake Mine ?? Complex dyke ore body ?? Underground operation ?? 1.1 million tonnes per annum ?? 1.2 carats per tonne ?? On-site diesel power generation ?? Supply by ice road and air ?? Milestones ? Construction commenced in 2005 ? Commissioning 2007 ? First diamonds August 2007

May 1, 2008

By K. van Netten, T. P. Ernst

"Froth flotation has been used successfully for about a century in the beneficiation of both coal and mineral particles. With the on-going trend towards lower feed grades, however, there is a need to transform this technology in ways that can deliver ultrafast separations, with strong selectivity, and recovery, covering a broader size range. It should be recognised that the hydrophobic effect, with its highly selective and long-range interactions, will most likely underpin any new technology. We identified the separation of the concentrate from the tailings as the rate determining step of conventional flotation technology. This limitation was then addressed by developing a novel flotation technology, insuring the formation of a concentrate that could be separated more rapidly from the tailings. We introduced a novel binder medium, a highly concentrated water in oil emulsion, to act as the focal point for hydrophobic adhesion, effectively replacing the air bubbles used in conventional flotation. The hydrophobic particles adhere to and become embedded within the binder, forming saturated agglomerates that float upwards. Moreover, by forming these large and resilient agglomerates, the product can be quickly dewatered over a screen and separated almost immediately from the tailings. Remarkably, this new binder permits residence times in the order of a few seconds under batch conditions. This paper examines the performance of the technology as a function of the oil wt% added to the slurry. The paper also examines the performance of the technology as a function of the particle size, showing a decline as the particle size exceeds 0.50 mm.INTRODUCTIONFroth flotation involves the collision and adhesion of hydrophobic particles to rising air bubbles, the carrying of those particles from the bubbly-pulp zone into a froth zone, and subsequent drainage and migration of the pulp to achieve the final concentrate (Wills, 2006). Within a Jameson Cell the feed slurry and air bubbles are brought into intense contact within the active area of the downcomer, achieving rapid kinetics of hydrophobic particle adhesion to the air bubbles (Harbort et al., 1994). However, once the bubble laden product and tailings emerge from the downcomer there is the need for separation of the concentrate from the tailings, an inherently slower process. In other devices such as mechanical cells the initial kinetics of particle adhesion are far slower, relying on the turbulent eddies throughout the cell, while in a column the kinetics rely upon an even slower process of bubble interception with suspended and settling particles (Gorain, 2007). However, in all cases the driving force for segregating the bubbles from the tailings, and the drainage of the froth are inherently the same. We do note, however, recent advances by Galvin and co-workers in achieving so-called Fast Flotation, utilizing a system of inclined channels to dramatically increase the segregation rate of bubbles from the tailings, permitting much higher gas and feed fluxes to be applied, achieving up to a ten-fold throughput advantage (Dickinson et al., 2014). Any further improvement within the existing flotation paradigm would require the introduction of centrifugal forces, but this would also require the formation of much finer bubbles than is typically used given the tendency of relatively large bubbles to reach a limiting slip velocity due to deformations and increased drag. Across all flotation devices we argue the rate determining step remains the segregation of the bubbles from the tailings."

Jan 1, 2016

By V. Feldman, I. Holl, J. Zampini

"The Renard Mine, 100% owned by Stornoway Diamonds, is located approximately 250 km north of the Cree community of Mistissini and 350 km north of Chibougamau in the James Bay region of north-central Québec. The project benefits from a large and growing resource, good mining conditions, strong social acceptance, a modest environmental footprint, and the development of direct-to-mine road infrastructure. Construction began on July 10, 2014; following the completion of a 946 million CAD project financing transaction. Now completed, the mine is the first diamond mine in Québec, and one of only six in Canada, employing approximately 500 people. First ore was delivered to the plant approximately 5 months ahead of schedule on July 15, 2016. Commercial production was declared on January 1, 2017. In general, the project ramp up has been characteristic of a type 1 McNulty curve. One of the challenges during production ramp-up was a redesign of processed kimberlite dewatering (replacing the dewatering centrifuge with two stages of hydrocyclones and a dewatering screen). A processing opportunity captured by Stornoway was the design and installation of an ore sorting facility which rejected free waste rock from the valuable host rock; kimberlite. Through tackling both challenges and opportunities, Stornoway has realised and is now exceeding their original design tonnage.PROJECT DESCRIPTION Stornoway Diamond Corporation (Stornoway) was established in 2003 resulting from to a plan of arrangement between Northern Empire Minerals Ltd. and Stornoway Ventures. In 2011, Stornoway acquired 100% interest of the Renard Mine. The construction of the Renard Mine began in 2014 and achieved full production in 2017 [1, 2]."

Jan 1, 2019

In terms of throughput, product size and power draw, grindcurves provide a measure of the response of the mill performance to changes in mill operating parameters ? usually mill filling. Since presenting the principle in 2006, grindcurves have been applied to a wide variety of AG and SAG mills. Mill response has been carefully measured for variations in: mill fillings from 15% to 40%; throughput by a factor of two; power by 50%; feed blends; liner profile; and mill speed from 65% to 80%. The outcomes of this extensive program of work are presented as the measured grindcurves. How they have enhanced our understanding of mill operation and how they may be applied to practical daily mill control is discussed. It is proposed that this technique provides a viable and valuable mill control tool that may find extensive application in the industry.

Jan 1, 2012

By A. J. Neale, B. C. Flintoff

"In most mineral processing operations the term audit is usually reserved for the exercise of checking financial records and/ or safety practices. While these activities are time consuming, no one disputes their necessity or value. If we subject these areas to such careful scrutiny, why is it that we don't normally apply the same principles to critically examine process operation. After all, the operating efficiency of the plant impacts directly on the measures of profitability.A mineral processing plant is a complex system that has a number of distinct, but mutually dependent elements: process equipment, instrumentation, operating policies, maintenance policies, control strategies and people. To ensure maximum economic performance, in the dynamic environment that characterizes a concentrator, requires a periodic review of each of these areas. However, to be useful, the study must be based on sound metallurgical principles and be conducted in a highly focused manner. Experience teaches us that the exercise is very revealing and potentially very rewarding.This paper will discuss the process audit process and illustrate its potential value through illustration taken from plant studies.IntroductionThe last twenty years have seen tremendous technological and organizational changes sweep the minerals industry. Process control systems, on-stream analyzers, and gold recovery techniques barely conceived twenty years ago are now incorporated in virtually all new installations in an effort to maximize operating efficiencies. In conjunction with these developments, changes in the way plants are managed, down-sizing of technical staff, reduction in the size of operating crews, and the flattening out of the management structure have significantly reduced operating costs. As a result, plants are making more efficient use of our natural resources, minimizing the costs of production, and in turn maximizing operating profits. Or are they?"

Jan 1, 1991

By Mingxia Liu, Hao Li, Qi Liu

"Laboratory batch flotation tests were carried out on fine (-20 µm) hematite to investigate the non-polar oil’s influences when sodium oleate, octyl hydroxamic acid, or oleyl hydroxamic acid were used as a collector. Batch flotation tests were performed with artificial mixed minerals (hematite:quartz = 1:1) under natural pH condition and kerosene was utilized as the model oil. The experimental results showed that kerosene emulsion behaved differently when used in conjunction with the three collectors. Kerosene helped improve the flotation when sodium oleate or oleyl hydroxamic acid was used as a collector. Nevertheless, it reduced concentrate weight yield, grade and recovery to a noticeable extent when octyl hydroxamic acid was used as a collector, especially at low dosages. In addition, single hematite batch flotation kinetics tests coupled with water recovery measurement were carried out to study the role of kerosene at different collector dosages. It was observed that water drainage and the resulting froth destabilization by kerosene was dominant at low collector dosages, especially in the flotation using octyl hydroxamic acid. At higher collector dosages, the water drainage and froth destabilization effect by kerosene was possibly counter-balanced by the higher hematite hydrophobicity and bubble surface tension gradient, which led to more stable froth layer.INTRODUCTION The minerals industry is facing a steady decline in ore grade, compounded by increasing complexity of mineral dissemination. As a result, the ore has to be ground sufficiently fine to have a suitable degree of mineral liberation, which produces large percentages of fine and ultrafine particles outside of optimal size range for ore dressing. Due to the unique characteristics of fine particles, i.e., small mass, high specific surface area, and problems such as increased solubility of complex minerals (Finkelstein, 1997; Finkelstein & Allison, 1976; Fornasiero & Ralston, 2005), high reagent consumption, fast surface oxidation in the case of sulfides (Collins & Read, 1971; Klassen & Mokrousov, 1963), severe particle entrainment (Subrahmanyam & Forssberg, 1988; Warren, 1984), low flotation rates (Glembotsky, 1953; Philippoff, 1952; Ye & Miller, 1988), slime coating (T. K. Mitchell et al., 2005; Parsonage, 1984), etc., flotation performance of these finely ground ores is very poor in terms of low concentrate grade and recovery."

Jan 1, 2017

By J. Kolacz

"A new sensor based sorting system has been developed, providing a possibility for laboratory scale testing and further scale-up of the separation results to the industrial operation. The new system contains different sensors as: X-ray detectors, visible light cameras, NIR cameras, ultraviolet cameras and magnetic sensors, in the same sorting unit. The sorting unit allows advanced calibration options and fine-tuning of the installed sensors to achieve the best separation effect under controlled conditions. Finally, the processed material can be analysed and separated by the rejection mechanism, similarly to the industrial scale operation. At the same time, the process is carried out with limited amount of material allowing detailed statistical calculations for processed particles and all sensor types. The optimal settings and sensor types are specified for the industrial application.The paper describes the scale up of the results achieved for iron ore and coal, where the test work was first carried out using the new laboratory sorting system and where the industrial scale sorting system has been built, in the final stage. The industrial scale sorting results showed a very good correlation between the laboratory and full scale operation. Thanks to the detailed study carried out in the laboratory equipment, the settings of the sensors in the full scale operation provided much better separation efficiency. It was especially important to provide proper setting for the X-ray sensor data calculations, which can be very critical for achieving the best results. During the industrial scale sorting of coal, the input material had 40-55% rock particles as the direct source of ash in the coal stream. The optimal laboratory unit settings and transferring these settings to the industrial sorter, provided 98.8% efficiency for removing rock particles with only few % losses of coal."

Jan 1, 2016

By K. E. Waters, N. Brodusch, R. Gauvin, A. Jordens, Teng. C., H. Demers

Rare earth elements (REEs) become increasingly significant for renewable energy devices and high-technology electronic products because of their large-scale popularity and applications. In this project, a field-emission scanning electron microscope was used to characterize the composition and distribution of REEs-bearing minerals. X-ray elemental maps were acquired with a large area x-ray detector (60 and 80 mm2 collecting area) and annular detector (60 mm2 collecting area), which allow fast x-ray acquisition at high count rate. These elemental maps were transformed into phase maps, which are used to identify the composition of the mineral phases and the REEs distribution over a large area. The phase maps are an easy way to distinguish the phases with and without REEs and compare the efficiency of different REEs extraction processes. Different methods (manual and automatic) for producing phase map were studied by comparing the distribution of REEs obtained from the same area.

Jan 1, 2015

By R. Khanna, K. Hyun Ko, A. J. Berkovich, J. Hook

"The co-pyrolysis of synthetic polymer polyethylene terephthalate (PET) and agricultural wastes (naturally occurring polymer-macadamia nut shell) was investigated in the temperature range 473K to 1273K using a horizontal furnace with an aim to understand their thermal degradation under isothermal conditions. In-depth characterization of pyrolysis residues was carried out using x-ray diffraction (XRD) and solid state nuclear magnetic resonance (NMR) for carbon structure, and through determination of the concentration of unpaired electrons using electron paramagnetic resonance (EPR). In previous studies, it has been found that PET thermally decomposes ~ 650K-700K, releasing (~80 wt % of initial weight) gaseous products due to random chain scission. In the case of macadamia nut shell, three types of byproduct can be obtained from pyrolysis: char, tar and gaseous products. In the co-pyrolysis of macadamia nut shell with PET in 50-50 wt% ratio, total product weight ratio could be modified with the addition of PET acting as a hydrogen source. This is because a recombination of thermal cracking products of cellulose could be suppressed by hydrogen from PET, which will later lead to an enhancement of tar formation. In addition, pyrolysis around 673K is sufficient for bond cleavage to occur in cellulose and lignin leading to the formation of negatively charged activated carbon with high surface area, providing bonding sites for volatiles evolving from PET. Therefore the co-pyrolysis may be able to enhance the product yield (tar/char/solid carbon residue) along with a reduction in the release of gaseous products. During the co-pyrolysis, temperature was found to have a significant influence on the kinetics of thermal degradation and solid residual by-products after co-pyrolysis.INTRODUCTIONPlastics are being used worldwide in a wide range of applications in the modern society; their usage has resulted in increasingly a massive waste problem. The production of most synthetic plastics requires hydrocarbons that are produced from petrochemicals derived from fossil oil and natural gas, a non-renewable source (Speight 2011). Currently, plastic manufacture utilizes ~4% of world oil and gas production, and it is expected to drive further increases in petroleum demand by 1-2% due to their large volume of manufacture (Hopewell, Dvorak et al. 2009). Landfilling and incineration of plastic waste are the two main routes to plastic waste management (Encinar and González 2008). In Australia, only 10% of waste plastics were recycled in 2006 (White and Hyde 2011). This means that large amount of fossil fuels from plastics has either been simply burned for energy recovery or buried in the ground. There is an urgent need for developing alternative avenues for recycling waste plastics. Our group at UNSW has carried out extensive research on the recycling of waste polymers as carbon resource in steelmaking including slag foaming and carbon dissolution from waste plastics into liquid steel at 1600°C; the effect of basic plastic characteristics such as chemical composition, structure, bonding network etc. was examined (Sahajwalla, Rahman et al. 2009)"

Jan 1, 2012

By D. Gendzwill, N. Martin

"In early 1987, the Patience Lake potash mine near Saskatoon, Saskatchewan, was closed due to uncontrollable floodingWater inflows were first encountered during routine mining in 1975 at the south boundary of the mine lease. Underground grouting and construction of bulkheads limited the flo but did not completely stop it. Subsequent seismic surveys showed that the mine had approached the edge of a large collapse structure in which the salt and potash had been partly dissolved and removed by groundwater.In 1986, the small flow into the mine started to grow. Despite renewed grouting, the flood increased and outstripped pump capacity. The grouting program temporarily slowed the inflow but was unable to stop it. Eventually, from seismic and drilling evidence, it became clear that the water source was an extensive system of vertical fractures which would be impossible to seal by drilling and grouting from underground. A new plan to install 14 bulkheads underground would have sealed the water source from the rest of the mine but the construction program could not be completed before rapidly increasing inflow threatened to fill the mine. The underground mine was closed and a new solution mine started in 1988."

Jan 1, 1996